Assessment of Water Quality in the Elbe River at Flood Water Conditions Based on Cluster Analysis,Principle Components Analysis,and Source Apportionment

An assessment of water quality measurements during a spring flood in the Elbe River is presented. Daily samples were taken at a site in the middle Elbe, which is part of the network of the International Commission for the Protection of the Elbe River (IKSE/MKOL). Cluster analysis (CA), principal components analysis (PCA), and source apportionment (APCS apportioning) were used to assess the flood‐dependent matter transport. As a result, three main components could be extracted as important to the matter transport in the Elbe River basin during flood events: (i) re‐suspended contaminated sediments, which led to temporarily increased concentrations of suspended matter and of most of the investigated heavy metals; (ii) water discharge related concentrations of pedogenic dissolved organic matter (DOM) as well as preliminary diluted concentrations of uranium and chloride, parameters with stable pollution background in the river basin; and (iii) abandoned mines, i.e., their dewatering systems, with particular influence on nickel, manganese, and zinc concentrations.     

Spatial evolution of nitrogen and phosphorus loads along a small Mediterranean river: implication of bed sediments

This study addresses the spatial variations in water quality along the River Vène (France). The Vène drains a 67 km² rural basin, with a large karstic area, located in a Mediterranean context. A 1 day sampling campaign was conducted along the river, in winter low‐flow conditions (February 2003). Physico‐chemical parameters and water flow discharge were measured in situ during the sampling campaign. Water quality was evaluated by determining the concentrations of nitrogen and phosphorus in water and bed‐sediment samples. Nitrogen and phosphorus loads were evaluated taking into account the measured concentrations and discharge. The campaign included 18 sampling points and concerned the whole river from the spring to the outlet, plus the main inputs, i.e. sewage treatment works, main tributaries and karstic springs. The spatial evolution of nitrogen and phosphorus loads along the river allowed the significant role of point‐source inputs to be demonstrated. The decrease in nutrient loads along the river occurred mainly in specific reaches where fine sediments had accumulated. In these zones, phosphorus is trapped in the bed sediments in calcium‐bound phosphates due to precipitation processes. Copyright © 2005 John Wiley & Sons, Ltd.     

The dynamics of phytoplankton, bacteria and heterotrophic flagellates at two Banks near Magdeburg in the River Elbe (Germany)

The main objectives of this study were to describe the seasonal standing stock dynamics of phytoplankton, bacterioplankton and heterotrophic flagellates in the highly eutrophic River Elbe (Germany), and to compare the seasonal patterns observed with other streams. Emphasis was placed on examining and assessing abiotic and biotic controlling factors influencing the structure and dynamics of the riverine plankton. All the physico-chemical and biological parameters determined were within the range or somewhat higher (in the case of phytoplankton abundance and biomass) than reported for other large streams. The underwater light conditions resulting from atypically short phytoplankton growth periods of about 6 months per year and the low phytoplankton carbon to chl a ratio of 23 were identified as a major limiting factor for phytoplankton development in the River Elbe. The seasonal distribution pattern of bacterioplankton indicated probable tight trophodynamical coupling both with phytoplankton and with heterotrophic flagellates, whereas heterotrophic flagellates showed a more trophic link with bacterial densities. Although approximately constant DOC and DON levels throughout the year sustained bacterial growth rates, during the phytoplankton growing season an increase of bacterial standing stocks was observed. Although the left-bank sampling site of the Elbe is strongly influenced by the tributaries Mulde and Saale containing higher concentrations of chloride, nitrogen nutrients, heavy metals and organic pollutants, no clear differences were observed between the two sides of the river concerning the biological parameters measured. Possible reasons and the slightly higher phytoplankton abundance and diversity at the right bank are discussed.     

Application of Ultrafiltration for Characterization of the DOC of Elbe River Water

An ultrafiltration methodology and the results of its application on Elbe river water are presented. Compared with other methods, Ultrafiltration allows fractionation of the molecular-weight fractions of DOC for higher volumes of solution in a shorter time. To characterize the molecular-weight fractions, the sum parameter DOC (β(DOC)) and the absorption coefficient at 254 nm a₂₅₄ were measured, together with determination of a₂₅₄/ β(DOC) for further characterization of the DOC fractions and to provide information about changes in parts of the UV-active substances of the total dissolved organic material. In the period May 1992 to November 1994, the DOC molecular-weight composition of 65 samples of Elbe river water were determined. At two sampling locations (Torgau-East and Meissen), the DOC content β(DOC) was approximately 6 mg/L. The high-molecular weight fraction (> 10000 g/mol) gave a mean of 13% of the total DOC content β₀(DOC). The measurements showed that the molecular composition of DOC in the Elbe does not greatly differ. There was also no clear seasonal influence on the molecular-weight composition of the DOC content. During the period of investigation, the percentage part of β(DOC) and a₂₅₄/β(DOC) of the high-molecular weight fraction of the total dissolved organic material increased, while the a₂₅₄/β(DOC) values of the middle molecular-weight fraction remained fairly constant. The dependence of β(DOC) on discharge of the Elbe river is low. Changes in molecularweight composition of DOC were only observed during the steepest increase in river discharge during a flood event, with another spectrum of substances responsible for the increase in β(DOC) when compared with the β(DOC) for low or middle water level.     

Water‐quality response to a high‐elevation wildfire in the Colorado Front Range

Water quality of the Big Thompson River in the Front Range of Colorado was studied for 2 years following a high‐elevation wildfire that started in October 2012 and burned 15% of the watershed. A combination of fixed‐interval sampling and continuous water‐quality monitors was used to examine the timing and magnitude of water‐quality changes caused by the wildfire. Prefire water quality was well characterized because the site has been monitored at least monthly since the early 2000s. Major ions and nitrate showed the largest changes in concentrations; major ion increases were greatest in the first postfire snowmelt period, but nitrate increases were greatest in the second snowmelt period. The delay in nitrate release until the second snowmelt season likely reflected a combination of factors including fire timing, hydrologic regime, and rates of nitrogen transformations. Despite the small size of the fire, annual yields of dissolved constituents from the watershed increased 20–52% in the first 2 years following the fire. Turbidity data from the continuous sensor indicated high‐intensity summer rain storms had a much greater effect on sediment transport compared to snowmelt. High‐frequency sensor data also revealed that weekly sampling missed the concentration peak during snowmelt and short‐duration spikes during rain events, underscoring the challenge of characterizing postfire water‐quality response with fixed‐interval sampling. Copyright © 2015 John Wiley & Sons, Ltd.     

Hydrograph separation using tracers and digital filters to quantify runoff components in a semi‐arid mesoscale catchment

Chemical hydrograph separation using electrical conductivity and digital filters is applied to quantify runoff components in the 1,640 km² semi‐arid Kaap River catchment and its subcatchments in South Africa. A rich data set of weekly to monthly water quality data ranging from 1978 to 2012 (450 to 940 samples per site) was analysed at 4 sampling locations in the catchment. The data were routinely collected by South Africa's national Department of Water and Sanitation, using standard sampling procedures. Chemical hydrograph separation using electrical conductivity (EC) as a tracer was used as reference and a recursive digital filter was then calibrated for the catchment. Results of the two‐component hydrograph separation indicate the dominance of baseflow in the low flow regime, with a contribution of about 90% of total flow; however, during the wet season, baseflow accounts for 50% of total flow. The digital filter parameters were very sensitive and required calibration, using chemical hydrograph separation as a reference. Calibrated baseflow estimates ranged from 40% of total flow at the catchment outlet to 70% in the tributaries. The study demonstrates that routinely monitored water quality data, especially EC, can be used as a meaningful tracer, which could also aid in the calibration of a digital filter method and reduce uncertainty of estimated flow components. This information enhances our understanding of how baseflow is generated and contributed to streamflow throughout the year, which can aid in quantification of environmental flows, as well as to better parameterize hydrological models used for water resources planning and management. Baseflow estimates can also be useful for groundwater and water quality management.     

Concentration–discharge relationships in the coal mined region of the New River basin and Indian Fork sub‐basin,Tennessee, USA

For many basins, identifying changes to water quality over time and understanding current hydrologic processes are hindered by fragmented and discontinuous water‐quality and hydrology data. In the coal mined region of the New River basin and Indian Fork sub‐basin, muted and pronounced changes, respectively, to concentration–discharge (C–Q) relationships were identified using linear regression on log‐transformed historical (1970s–1980s) and recent (2000s) water‐quality and streamflow data. Changes to C–Q relationships were related to coal mining histories and shifts in land use. Hysteresis plots of individual storms from 2007 (New River) and the fall of 2009 (Indian Fork) were used to understand current hydrologic processes in the basins. In the New River, storm magnitude was found to be closely related to the reversal of loop rotation in hysteresis plots; a peak‐flow threshold of 25 cubic meters per second (m³/s) segregates hysteresis patterns into clockwise and counterclockwise rotational groups. Small storms with peak flow less than 25 m³/s often resulted in dilution of constituent concentrations in headwater tributaries like Indian Fork and concentration of constituents downstream in the mainstem of the New River. Conceptual two or three component mixing models for the basins were used to infer the influence of water derived from spoil material on water quality. Copyright © 2012 John Wiley & Sons, Ltd.     

Spatial–temporal variability in water quality and macro-invertebrate assemblages in the Upper Mara River basin,Kenya

Tropical rivers display profound temporal and spatial heterogeneity in terms of environmental conditions. This aspect needs to be considered when designing a monitoring program for water quality in rivers. Therefore, the physico-chemical composition and the nutrient loading of the Upper Mara River and its two main tributaries, the Amala and Nyangores were monitored. Initial daily, and later a weekly monitoring schedule for 4 months spanning through the wet and dry seasons was adopted. Benthic macro-invertebrates were also collected during the initial sampling to be used as indicators of water quality. The aim of the current study was to investigate the physico-chemical status and biological integrity of the Upper Mara River basin. This was achieved by examining trends in nutrient concentrations and analyzing the structure, diversity and abundance of benthic macro-invertebrates in relation to varying land use patterns. Sampling sites were selected based on catchment land use and the level of human disturbance, and using historical records of previous water quality studies. River water pH, dissolved oxygen, electrical conductivity (EC), temperature, and turbidity were determined in situ. All investigated parameters except iron and manganese had concentration values within allowable limits according to Kenyan and international standards for drinking water. The Amala tributary is more mineralized and also shows higher levels of pH and EC than water from the Nyangores tributary. The latter, however, has a higher variability in both the total phosphorus (TP) and total nitrogen (TN) concentrations. The variability in TP and TN concentrations increases downstream for both tributaries and is more pronounced for TN than for TP. Macro-invertebrate assemblages responded to the changes in land use and water quality in terms of community composition and diversity. The study recommends detailed continuous monitoring of the water quality at shorter time intervals and to identify key macro-invertebrate taxa that can be used to monitor changes of the water quality in rivers of the Mara basin as a result of anthropogenic changes.     

River discharge,land use change,and surface water quality in the Xiangjiang River,China

To compare the impacts of river discharge on the surface water quality of the Xiangjiang River in China, 12 surface water quality parameters recorded at 31 sampling sites from January 1998 to December 2008 along the river and its main tributaries were analyzed. Significantly higher concentrations of total nitrogen, ammoniacal nitrogen, and total phosphorus, and biochemical oxygen demand were observed during low‐flow periods than during high‐flow periods, implying a higher risk to local residents drinking untreated water during low‐flow periods. Pollution indexes, including the inorganic pollution index and integrated pollution index (IPI), were negatively related to impervious surface area (ISA) and cropland area (CLA) when ISA (CLA) was less than 160 (3000) km². However, the relationship was positive when ISA (CLA) was larger than 160 (3000) km², which provided a reasonable explanation for the observed spatial patterns of water quality. Distinct increasing temporal trends for two kinds of pollution indexes were also found. The annual ISA was significantly related to the rapid degradation of water quality from 1998 to 2008, with correlation coefficient (r) values of 0.816 (p = 0.002) and 0.711 (p = 0.014) for the organic pollution index (OPI) and IPI, respectively. However, annual rainfall was negatively correlated with the two indexes with r values of 0.785 (p = 0.002) and 0.448 (p = 0.093) for OPI and IPI, respectively. Our study highlights that decision makers should be more aware of recent increases in the pollution of the Xiangjiang River, especially at downriver sites and during low‐flow periods. Copyright © 2013 John Wiley & Sons, Ltd.     

Preliminary evaluation of the runoff processes in a remote montane cloud forest basin using Mixing Model Analysis and Mean Transit Time

In this study, the Mean Transit Time and Mixing Model Analysis methods are combined to unravel the runoff generation process of the San Francisco River basin (73.5 km²) situated on the Amazonian side of the Cordillera Real in the southernmost Andes of Ecuador. The montane basin is covered with cloud forest, sub‐páramo, pasture and ferns. Nested sampling was applied for the collection of streamwater samples and discharge measurements in the main tributaries and outlet of the basin, and for the collection of soil and rock water samples. Weekly to biweekly water grab samples were taken at all stations in the period April 2007–November 2008. Hydrometric data, Mean Transit Time and Mixing Model Analysis allowed preliminary evaluation of the processes controlling the runoff in the San Francisco River basin. Results suggest that flow during dry conditions mainly consists of lateral flow through the C‐horizon and cracks in the top weathered bedrock layer, and that all subcatchments have an important contribution of this deep water to runoff, no matter whether pristine or deforested. During normal to low precipitation intensities, when antecedent soil moisture conditions favour water infiltration, vertical flow paths to deeper soil horizons with subsequent lateral subsurface flow contribute most to streamflow. Under wet conditions in forested catchments, streamflow is controlled by near surface lateral flow through the organic horizon. Exceptionally, saturation excess overland flow occurs. By absence of the litter layer in pasture, streamflow under wet conditions originates from the A horizon, and overland flow. Copyright © 2011 John Wiley & Sons, Ltd.     

Spatial delineation of groundwater–surface water interactions through intensive in‐stream profiling

The dominance of ‘old’ pre‐event water in headwater storm runoff has been recorded in numerous upland catchment studies; however, the mechanisms by which this pre‐event water enters the stream channel are poorly understood. Understanding these processes is fundamental to determining the controls on surface water quality and associated impacts on stream ecology. Previous studies in the upland forested catchment of the Afon Hafren (River Severn) at Plynlimon, mid‐Wales, identified an active bedrock groundwater system that was discharging into the stream channel during storm response. Detailed analysis showed that these discharges were small and could not account for the majority of pre‐event storm water response identified at this site; pre‐event storm runoff had to be sourced predominantly from further upstream. An intensive stream survey was used to determine the spatial nature of groundwater–surface water (GW–SW) interactions in the Hafren Catchment. Detailed physico‐chemical in‐stream profiling identified a marked change in water quality indicating a significant discrete point of bedrock groundwater discharge upstream of the Hafren Transect study site. The in‐stream profiling showed the importance of high spatial resolution sampling as a key to understanding processes of GW–SW interaction and how quick and cost‐effective measurements of specific electrical conductance of stream waters could be used to highlight in‐stream heterogeneity. This approach is recommended for use in headwater catchments for initial characterisation of the stream channel in order to better locate instrumentation and to determine more effective targeted sampling protocols in upland catchment research. Copyright © 2012 John Wiley & Sons, Ltd.     

The effects of floods on the temperature of riparian groundwater

The transition area between rivers and their adjacent riparian aquifers, which may comprise the hyporheic zone, hosts important biochemical reactions, which control water quality. The rates of these reactions and metabolic processes are temperature dependent. Yet the thermal dynamics of riparian aquifers, especially during flooding and dynamic groundwater flow conditions, has seldom been studied. Thus, we investigated heat transport in riparian aquifers during 3 flood events of different magnitudes at 2 sites along the same river. River and riparian aquifer temperature and water‐level data along the Lower Colorado River in Central Texas, USA, were monitored across 2‐dimensional vertical sections perpendicular to the bank. At the downstream site, preflood temperature penetration distance into the bank suggested that advective heat transport from lateral hyporheic exchange of river water into the riparian aquifer was occurring during relatively steady low‐flow river conditions. Although a small (20‐cm stage increase) dam‐controlled flood pulse had no observable influence on groundwater temperature, larger floods (40‐cm and >3‐m stage increases) caused lateral movement of distinct heat plumes away from the river during flood stage, which then retreated back towards the river after flood recession. These plumes result from advective heat transport caused by flood waters being forced into the riparian aquifer. These flood‐induced temperature responses were controlled by the size of the flood, river water temperature during the flood, and local factors at the study sites, such as topography and local ambient water table configuration. For the intermediate and large floods, the thermal disturbance in the riparian aquifer lasted days after flood waters receded. Large floods therefore have impacts on the temperature regime of riparian aquifers lasting long beyond the flood's timescale. These persistent thermal disturbances may have a significant impact on biochemical reaction rates, nutrient cycling, and ecological niches in the river corridor.     

Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana

The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the ⁸⁷Sr/⁸⁶Sr, δ¹³C_DIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.     

Determination of suspended particulate matter concentration from turbidity measurements: particle size effects and calibration procedures

Measurements of suspended particulate matter concentration and turbidity point towards the possibility of a site‐specific algorithm (SPM), relating SPM to nephelometric turbidity units (NTU). In this paper regression models are presented that account for changes in the relationship of SPM and NTU as a result of changes in particle properties. The models have been developed by the use of daily measurements of SPM concentration and a continuous record of turbidity for the period from June 1996 to February 2001 in the River Elbe, a major river in the eastern part of Germany. The effect of changes in the particle properties with increasing water discharge was taken into account by varying the slope of a linear regression equation according to a logistic function. Water discharge, Q, was defined to be the only variable of this function—as an adequate substitute of the parameter bottom shear stress, which cannot be measured directly. Measurements of flow velocity in the River Elbe show that bottom shear stress is related almost linearly to water discharge up to bankful discharges. Regression models with slopes varying continuously with hydraulic parameters may account for the effects resulting from changes of particle characteristics and thus may have some advantages compared with models with a constant slope or models calibrated for different seasons. Copyright © 2003 John Wiley & Sons, Ltd.     

Water source dynamics of high Arctic river basins

Arctic river basins are amongst the most vulnerable to climate change. However, there is currently limited knowledge of the hydrological processes that govern flow dynamics in Arctic river basins. We address this research gap using natural hydrochemical and isotopic tracers to identify water sources that contributed to runoff in river basins spanning a gradient of glacierization (0–61%) in Svalbard during summer 2010 and 2011. Spatially distinct hydrological processes operating over diurnal, weekly and seasonal timescales were characterized by river hydrochemistry and isotopic composition. Two conceptual water sources (‘meltwater’ and ‘groundwater’) were identified and used as a basis for end‐member mixing analyses to assess seasonal and year‐to‐year variability in water source dynamics. In glacier‐fed rivers, meltwater dominated flows at all sites (typically >80%) with the highest contributions observed at the beginning of each study period in early July when snow cover was most extensive. Rivers in non‐glacierized basins were sourced initially from snowmelt but became increasingly dependent on groundwater inputs (up to 100% of total flow volume) by late summer. These hydrological changes were attributed to the depletion of snowpacks and enhanced soil water storage capacity as the active layer expanded throughout each melt season. These findings provide insight into the processes that underpin water source dynamics in Arctic river systems and potential future changes in Arctic hydrology that might be expected under a changing climate. Copyright © 2013 John Wiley & Sons, Ltd.     

Hydroclimatic controls on dissolved organic matter (DOM) characteristics and implications for trace metal transport in Hwangryong River Watershed,Korea, during a summer monsoon period

Frequent heavy rainfalls during the East Asian summer monsoon drastically increase water flow and chemical loadings to surface waters. A solid understanding of hydroclimatic controls on watershed biogeochemical processes is crucial for water quality control during the monsoon period. We investigated spatio‐temporal variations in the concentrations and spectroscopic properties of dissolved organic matter (DOM) and the concentrations of trace metals in Hwangryong River, Korea, during a summer period from the relatively dry month of June through the following months with heavy rainfall. DOM and its spectroscopic properties differed spatially along the river, and also depended on storm and flow characteristics around each sampling time. At a headwater stream draining a forested watershed, the concentrations (measured as dissolved organic carbon (DOC)), aromaticity (measured as specific UV absorbance at 254 nm), and fulvic acid‐ and protein‐like fluorescence of DOM were higher in stormflow than in baseflow waters. DOC concentrations and fluorescence intensities increased along the downstream rural and urban sites, in which DOC and fluorescence were not higher in stormflow waters, except for the ‘first flush’ at the urban site. The response of DOM in reservoir waters to monsoon rainfalls differed from that of stream and river waters, as illustrated by storm‐induced increases in DOM aromaticity and fulvic‐like fluorescence, and no significant changes in protein‐like fluorescence. The results suggest that surface water DOM and its spectroscopic properties differentially respond to changes in hydroclimatic conditions, depending on watershed characteristics and the influence of anthropogenic organic matter loadings. DOC concentrations and intensities of spectroscopic parameters were positively correlated with some of the measured trace metals (As, Co, and Fe). Further research will be needed to obtain a better understanding of climate effects on the interaction between DOM and trace metals. Copyright © 2006 John Wiley & Sons, Ltd.     

Long‐wave radiation and heat flux estimates within a small tributary in Catamaran Brook (New Brunswick,Canada)

River water temperature is an important water quality parameter that also influences most aquatic life. Physical processes influencing water temperature in rivers are highly complex. This is especially true for the estimation of river heat exchange processes that are highly dependent on good estimates of radiation fluxes. Furthermore, very few studies were found within the stream temperature dynamic literature where the different radiation components have been measured and compared at the stream level (at microclimate conditions). Therefore, this study presents results on hydrometeorological conditions for a small tributary within Catamaran Brook (part of the Miramichi River system, New Brunswick, Canada) with the following specific objectives: (1) to compare between stream microclimate and remote meteorological conditions, (2) to compare measured long‐wave radiation data with those calculated from an analytical model, and (3), to calculate the corresponding river heat fluxes. The most salient findings of this study are (1) solar radiation and wind speed are parameters that are highly site specific within the river environment and play an important role in the estimation of river heat fluxes; (2) the incoming, outgoing, and net long‐wave radiation within the stream environment (under the forest canopy) can be effectively calculated using empirical formula; (3) at the study site more than 80% of the incoming long‐wave radiation was coming from the forest; (4) total energy gains were dominated by solar radiation flux (for all the study periods) followed by the net long‐wave radiation (during some periods) whereas energy losses were coming from both the net long‐wave radiation and evaporation. Conductive heat fluxes have a minor contribution from the overall heat budget (<3·5%); (5) the reflected short‐wave radiation at the water surface was calculated on average as 3·2%, which is consistent with literature values. Results of this study contribute towards a better understanding of river heat fluxes and water temperature models as well as for more effective aquatic resources and fisheries management. Copyright © 2011 John Wiley & Sons, Ltd.     

Water Quality of the River Yamuna in the Delhi Stretch: Key Determinants and Management Issues

The assessment of water quality of the River Yamuna in the Delhi stretch was carried out by determining changes in the concentration levels of 19 physico‐chemical parameters. It was observed that vegetation plays an important role in acting as a biological sink for mineral nutrients, thereby restoring the water quality. It is proposed that restoration of the inundation pattern of floodplains would greatly help in re‐aeration of the overlying water and re‐absorption of pollutants through mud/water exchanges.     

High‐frequency water quality monitoring in an urban catchment: hydrochemical dynamics,primary production and implications for the Water Framework Directive

This paper describes the hydrochemistry of a lowland, urbanised river‐system, The Cut in England, using in situ sub‐daily sampling. The Cut receives effluent discharges from four major sewage treatment works serving around 190 000 people. These discharges consist largely of treated water, originally abstracted from the River Thames and returned via the water supply network, substantially increasing the natural flow. The hourly water quality data were supplemented by weekly manual sampling with laboratory analysis to check the hourly data and measure further determinands. Mean phosphorus and nitrate concentrations were very high, breaching standards set by EU legislation. Although 56% of the catchment area is agricultural, the hydrochemical dynamics were significantly impacted by effluent discharges which accounted for approximately 50% of the annual P catchment input loads and, on average, 59% of river flow at the monitoring point. Diurnal dissolved oxygen data demonstrated high in‐stream productivity. From a comparison of high frequency and conventional monitoring data, it is inferred that much of the primary production was dominated by benthic algae, largely diatoms. Despite the high productivity and nutrient concentrations, the river water did not become anoxic, and major phytoplankton blooms were not observed. The strong diurnal and annual variation observed showed that assessments of water quality made under the Water Framework Directive (WFD) are sensitive to the time and season of sampling. It is recommended that specific sampling time windows be specified for each determinand, and that WFD targets should be applied in combination to help identify periods of greatest ecological risk. © 2015 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

太湖流域上游西苕溪支流的营养状态特征及成因分析

为了解太湖流域上游支流水体的营养状态特征及流域附近土地利用对水质的影响,选取了入湖水系西苕溪的10条主要支流进行了野外采样和实验室研究.研究结果表明,支流总磷(TP)、颗粒磷(PP)、总溶解性磷(TDP)、总氮(TN)、铵态氮(NH+4-N)、硝态氮(NO-3-N)含量季节间差异较大,TP含量范围为0.033~0.205 mg/L,PP含量范围为0.007~0.104 mg/L,TN含量范围为2.014~5.921 mg/L,NH+4-N含量范围0.021~1.659 mg/L,NO-3-N含量范围1.082~3.415mg/L,COD范围为6.5~15.5 mg/L.总体上呈现为枯水期平水期丰水期.部分支流受到不同程度的氮污染.利用水质参数进行聚类分析,可以将10条支流分成4类,其水体营养特征与周围环境相联系.支流营养盐、COD的通量明显受流量控制,表现为丰水期平水期枯水期.土地利用类型的差异是导致其水质变化的主要原因,耕地和居民地主要起源的作用,林地和草地主要起汇的作用.在丰水期和枯水期,对各指标影响最大的土地利用类型为耕地和林地;在平水期,对TP影响最大的是居民地,而对TN影响最大的是林地.