应用核磁共振技术分析干盐湖地区地下卤水空间分布特征——以昆特依干盐湖为例

昆特依干盐湖位于柴达木盆地西北部,为特大型综合盐类矿床.大盐滩是昆特依干盐湖内最大的盐滩,地下赋存有一定量的卤水矿床,但该矿床的水文地质条件差,主要卤水矿层含水性弱,开采难度大.核磁共振找水方法作为当今世界上唯一的直接找水地球物理新方法,具有高分辨力、高效率、信息量丰富和解的唯一性等优点,本文运用该方法对昆特依干盐滩地区地下卤水空间分布特征进行研究,通过对核磁共振数据进行处理与反演,结合已有的地质与钻井资料,对测点进行综合地质-地球物理解释,获得以下认识:1)大盐滩0~130 m深度范围内,共存在3个卤水含水层,主要呈扁平状或漏斗状、近似层状展布,W1为晶间潜卤水层,渗透系数较大,颗粒较粗,单位体积含水量为0.4%~2.7%,W2和W3为晶间承压卤水层,渗透系数较小,颗粒较粗,单位体积含水量分别为0.2%~1.1%和0.1%~0.8%;2)大盐滩地区存在两个卤水富集区,分别为研究区西南部沉积盆地中心的Ⅰ号富卤区和盆地东北部的Ⅱ号富卤区;3)根据区域内卤水富集分布以及构造情况,划定大盐滩向斜沉积中心、大盐滩北侧F1~F8及遥F6断裂发育区和冷湖构造带为区域内主要的找矿找水远景区;4)GMR核磁共振系统在干盐滩地区理论探测深度为130 m,该系统不仅可以有效地探测自由水,而且可以依据束缚水的分布解译地下各类含水盐类矿物和含水黏土矿物的存在与分布.     

柴达本盆地沙下盐湖的卤水化学及矿物沉积特征——以察尔汗盐湖区北部外围地带为例

对柴达木盆地察尔汗盐湖区外围沙下盐湖的卤水及沉积进行了综合研究。沙下盐湖卤水化学组成与地表径流和开放性盐湖卤水之间存在明显的差异性,具有高Na⁺+Cl^-、低Mg²⁺+Ca²⁺+SO₄^2-、贫K⁺+CO₃^2-+HCO₃^-等特征。沙下盐湖析盐层位含有新生矿物并夹带碎屑矿物,其盐类矿物组合为:石盐+羟氯镁铝石+光卤石。25℃等温蒸发相图表明,其卤水演化方向往光卤石析出区迁移,在穿越上覆盖层通道中卤水发生的物理化学反应与独特的沉积特征,可以作为继续寻找沙下盐湖的指导。     

内蒙古察干淖尔盐湖29-8ka时段的湖面波动

以内蒙古锡林郭勒盟苏尼特右旗的察干淖尔盐湖为研究对象,利用OSL(Optically Stimulated Luminescence)测年技术和DEM(Digital Elevation Model)数字高程模型,重建湖面波动历史,探讨湖泊形成与环境变化过程.通过对察干淖尔盐湖周边大量的野外考察,发现湖泊周围存在海拔高程为1020、978和973 m的三级古湖岸阶地,其OSL测年结果分别为29.2±1.3、18.4±0.8及8.2 8.0 ka.通过湖岸阶地高程恢复的上述3个时期的古湖面积分别为3600、500和400 km~2.与现今的干旱盐湖景观迥然不同.     

Isotopic composition of waters from the Danakil depression (Ethiopia)

During two expeditions in the Danakil depression (Ethiopia), water samples were collected from: (a) hot springs in Dallol, Salt Plain, in the north of the depression; (b) cold and hot springs around Lake Giulietti; and c) Lake Giulietti.The isotopic results indicate: the water from Dallol hot springs is enriched in¹⁸O by isotopic exchange with the rocks as has been observed in many other geothermal areas of the world; b) the isotopic composition of the Lake Giulietti water changes with depth, probably as a consequence of a seasonal stratification; c) the springs in the Lake Giulietti region contain waters which result from the mixing of local meteoric water with a brine, or with lake waters.     

13.8ka以来内蒙古吉兰泰盐湖的演化过程

通过系统分析吉兰泰盐湖JLT-2010孔蒸发盐类矿物、碳酸盐矿物、碎屑岩矿物等,结合AMS14C测年获得的年代序列,研究该湖13.8 ka以来的演化过程.结果表明:吉兰泰盐湖13.8-11.7 cal ka BP期间水体较淡;11.7-10.2 cal ka BP期间湖泊开始萎缩、咸化,进入咸水湖阶段;10.2-5.5 cal ka BP期间湖泊进入硫酸盐沉积阶段,其中9.0-8.2 cal ka BP经历了一个明显的淡化过程;5.5 cal ka BP以来,湖泊成盐作用进一步加强,由前期的硫酸盐沉积转变为氯化物沉积,其中3.7-2.0 cal ka BP达到全面氯化物沉积阶段,2.0-1.7 cal ka BP又经历了一个短暂而明显的淡化过程;目前,该盐湖已进入干盐湖发展阶段.总体而言,吉兰泰盐湖蒸发盐类矿物主要是在全新世增温的背景条件下逐步萎缩形成的,由于区域性干旱气候的持续影响,吉兰泰盐湖逐步萎缩、咸化,进而析盐.     

黄壁庄水库降水效应的分析

南极洲万达盐湖为饱和方解石湖水。计算出的方解石饱和指数随水深增加而变化。在Ca~(2+)及HCO_3~-活度值均一的上部氧化环境湖水中,pH及溶解氧(DO)是控制该变化的主要因素,在下部还原环境湖水中,Ca~(2+)及HCO_3~-的活度对方解石的饱和指数SI的变化起主要作用。这充分揭示了湖底部近代沉积物中分布较多方解石矿物的原因。     

Metal binding by dissolved organic matter in hypersaline water: A size fractionation study using different isolation methods

The influence of dissolved organic matter (DOM) on mineral extraction from salt lake brines depend on DOM quality. This study contributes to our knowledge of DOM’s metal binding behavior in hypersaline environments by characterization of DOM from lakes in the Qaidam Basin, i.e., Qarhan Lake (LQDOM), Da Qaidam (DQDOM) and West Ginair Salt Lake (WGDOM). The DOM was fractionated based on solid phase extraction (SPE) and ultrafiltration (UF), and the spectral and metal binding behavior of these fractions were studied by absorption spectroscopy, Pb(II) titration techniques and fluorescence parallel factor (PARAFAC) analysis. The results showed that bulk DOM generally contained more dissolved organic carbon (DOC), lower specific UV absorbance (SUVA₂₅₄), higher fluorescence and biological indices, comparable humification index, and lower condition stability constants compared to the other nature waters. Compared with UF, SPE-derived DOM exhibited higher DOC recovery and aromaticity and lower carbohydrate yield. It appeared that the SPE procedure used affects the spectral composition of bulk DOM to a larger extent than UF. Source and molecular weight (MW)-dependent differences in abundance and quality of brine DOM was indicated by higher SUVA₂₅₄ in high MW DOM, for LQDOM and DQDOM, and humic-like fluorophores were mainly in high MW-DOM in each lake. Moreover, the high MW humic-like component exhibited higher metal binding potential than the bulk and low MW counterparts for LQDOM and DQDOM, while the inverse was observed for WGDOM. This study revealed the effects of isolation techniques on interpretation of DOM characteristics, and meanwhile highlighted the importance of origin- and MW-dependent DOM in manipulating the behavior, fate, and bioavailability of heavy metals in salt lake brine.     

南极洲万达盐湖水中方解石饱和指数的垂直变化及其控制因素

南极洲万达盐湖为饱和方解石湖水。计算出的方解石饱和指数随水深增加而变化。在Ca²⁺及HCO₃^-活度值均一的上部氧化环境湖水中,pH及溶解氧(DO)是控制该变化的主要因素,在下部还原环境湖水中,Ca²⁺及HCO₃^-的活度对方解石的饱和指数SI的变化起主要作用。这充分揭示了湖底部近代沉积物中分布较多方解石矿物的原因。     

Modelling hydrodynamics in Yachiyo Lake using a non‐hydrostatic general circulation model with spatially and temporally varying meteorological conditions

In this study, a three‐dimensional (3D) non‐hydrostatic circulation model was applied to study the thermal structure, its evolution and water circulation of Yachiyo Lake in Hiroshima, Japan. The simulations were conducted for 1 month during July 2006. The meteorological forcing variables such as wind stress, surface atmospheric pressure and heat flux transfer through the lake surface were provided by an atmospheric mesoscale model run. The vertical mixing process of the lake was calculated using the Mellor‐Yamada turbulence model. The 1‐month numerical simulation revealed the wind‐induced currents of the lake, two gyres in the mid‐layer, and depth‐averaged monthly mean currents. Further numerical experiments studying the mechanism of the two gyres in the lake showed the important role of topography in gyre formation. The thermal structure of the lake and its evolution both in space and in time as predicted by the model showed very good agreement with the observed values and characteristics of Yachiyo Lake. The internal gravity waves, which are crucial for mixing in the stratified lake, are depicted by the vertical fluctuation of isotherms. Using the non‐dimensional gradient Richardson number, Yachiyo Lake was determined to be stable under strong stratification during the study period, and therefore very sensitive to wind stress. Copyright © 2009 John Wiley & Sons, Ltd.     

Sensitivity of the multiannual thermal dynamics of a deep pre‐alpine lake to climatic change

The study of the multiannual thermal dynamics of Lake Iseo, a deep lake in the Italian pre‐alpine area, is presented. Interflow was found to be the dominant river entrance mode, suggesting future susceptibility of the lake thermal structure to the overall effects of climate change expected in the upstream alpine watershed. A lake model employed the results of a long‐term hydrologic model to simulate the effects of a climate change scenario on the lake's thermal evolution for the period 2012–2050. The model predicts an overall average increase in the lake water temperature of 0.012 °C/year and a reinforced Schmidt thermal stability of the water column in the winter up to 800 J/m². Both these effects may further hinder the deep circulation process, which is vital for the oxygenation of deep water. Copyright © 2014 John Wiley & Sons, Ltd.     

Geochemical evidence of hydrothermal recharge in Lake Baringo,central Kenya Rift Valley

Lake Baringo, a freshwater lake in the central Kenya Rift Valley, is fed by perennial and ephemeral rivers, direct rainfall, and hot springs on Ol Kokwe Island near the centre of the lake. The lake has no surface outlet, but despite high evaporation rates it maintains dilute waters by subsurface seepage through permeable sediments and faulted lavas. New geochemical analyses (major ions, trace elements) of the river, lake, and hot spring waters and the suspended sediments have been made to determine the main controls of lake water quality. The results show that evaporative concentration and the binary mixing between two end members (rivers and thermal waters) can explain the hydrochemistry of the lake waters. Two zones are recognized from water composition. The southern part of the lake near sites of perennial river inflow is weakly influenced by evaporation, has low total dissolved species (TDS), and has a seasonally variable load of mainly detrital suspended sediments. In contrast, waters of the northern part of the lake show evidence for strong evaporation (TDS of up to eight times inflow). Authigenic clay minerals and calcite may be precipitating from those more concentrated fluids. The subaerial hot‐spring waters have a distinctive chemistry and are enriched in some elements that are also present in the lake water. Comparison of the chemical composition of the inflowing surface waters and lake water shows (1) an enrichment of some species (HCO₃^?, Cl, SO₄^2?, F, Na, B, V, Cr, As, Mo, Ba and U) in the lake, (2) a depletion in SiO₂ in the lake, and (3) a possible hydrothermal origin for most F. The rare earth element distribution and the F/Cl and Na/Cl ratios give valuable information on the rate of mixing of the river and hydrothermal fluids in the lake water. Calculations imply that thermal fluids may be seeping upward locally into the lake through grid‐faulted lavas, particularly south of Ol Kokwe Island. Copyright © 2006 John Wiley & Sons, Ltd.     

青藏高原盐湖卤水中溴的分布特征及来源初探

溴是完备工业体系的关键必备元素。盐湖卤水是溴的重要来源。青藏高原盐湖众多,富含钾、锂、硼等资源元素,开发潜力巨大。然而,目前针对青藏高原盐湖溴浓度、分布特征及其物源的研究仍然薄弱。本次研究采集了26个青藏高原盐湖表卤水样品并分析其溴浓度,进一步总结其他64个已报道盐湖数据,系统分析了青藏高原盐湖溴浓度分布特征,并进一步探讨了溴的可能物源。结果表明:青藏高原盐湖表卤水溴分布在0.5~246.8 mg/L之间,平均为41.1 mg/L,其中,碳酸盐型盐湖卤水平均溴浓度最高(47.0 mg/L),且集中分布在高原南部,而氯化物型盐湖平均溴浓度最低(30.1 mg/L),盐湖溴浓度呈现自南向北降低的趋势;青藏高原盐湖中溴有多种来源,高原南部富溴盐湖溴的来源可能主要与热泉补给有关,而柴达木盆地盐湖高溴来源可能主要与深部地层水(如油田水、背斜构造裂隙孔隙水、砂砾孔隙卤水、气田水等)补给有关。     

Hydrochemical processes in ground water-discharge playas,Central Australia

A large groundwater system in the Amadeus Basin, central Australia, discharges to a chain of playa lakes 500 km long. The playas contain highly concentrated brines; these are sodium-chloride rich waters with appreciable magnesium and sulphate and very low concentrations of calcium and bicarbonate. Gypsum, glauberite, and other evaporite minerals are precipitating in the playas. The groundwaters evolve to brine by concurrent processes of dissolution, evaporative concentration, mineral precipitation, and mineralogical change. Chemical evolution is considered with reference to a concentration factor based on chloride. Ion transfer calculations demonstrate losses of magnesium and bicarbonate throughout, as a result of precipitation. Sodium, potassium, calcium, and sulphate are gained initially as a result of dissolution but lost subsequently as a result of precipitation. Larger playas in the chain, exemplified by Lake Amadeus, have dual shallow and deep groundwater flow paths whereas the smaller playas, exemplified by Spring Lake, have only shallow flow paths. Brines in the larger playas are diluted by deep groundwaters and this is reflected in the degree of saturation attained with respect to particular minerals. Thus, saturation with respect to gypsum and glauberite is attained earlier in Spring Lake than in Lake Amadeus. Saturation with respect to halite is attained in Spring Lake but not in Lake Amadeus. Both playas are undersaturated with respect to hexahydrite and sylvite although these minerals occur in efflorescent crusts in Spring Lake.     

Water chemistry of Lake Quilotoa (Ecuador) and assessment of natural hazards

A geochemical survey carried out in November 1993 revealed that Lake Quilotoa was composed by a thin (14 m) oxic epilimnion overlying a 200 m-thick anoxic hypolimnion. Dissolved CO₂ concentrations reached 1000 mg/kg in the lower stratum. Loss of CO₂ from epilimnetic waters, followed by calcite precipitation and a consequent lowering in density, was the apparent cause of the stratification.The Cl, SO₄ and HCO₃ contents of Lake Quilotoa are intermediate between those of acid–SO₄–Cl Crater lakes and those of neutral-HCO₃ Crater lakes, indicating that Lake Quilotoa has a ‘memory’ of the inflow and absorption of HC1- and S-bearing volcanic (magmatic) gases. The Mg/Ca ratios of the lake waters are governed by dissolution of local volcanic rocks or magmas, but K/Na ratios were likely modified by precipitation of alunite, a typical mineral in acid–SO₄–Cl Crater lakes.The constant concentrations of several conservative chemical species from lake surface to lake bottom suggest that physical, chemical and biological processes did not have enough time, after the last overturn, to cause significant changes in the contents of these chemical species. This lapse of time might be relatively large, but it cannot be established on the basis of available data. Besides, the lake may not be close to steady state. Mixing of Lake Quilotoa waters could presently be triggered by either cooling epilimnetic waters by 4°C or providing heat to hypolimnetic waters or by seismic activity.Although Quilotoa lake contains a huge amount of dissolved CO₂ (3×10¹¹ g), at present the risk of a dangerous limnic eruption seems to be nil even though some gas exsolution might occur if deep lake waters were brought to the surface. Carbon dioxide could build up to higher levels in deep waters than at present without any volcanic re-awakening, due to either a large inflow of relatively cool CO₂-rich gases, or possibly a long interval between overturns. Periodical geochemical surveys of Lake Quilotoa are, therefore, recommended.     

柴达木盆地西北缘昆特依凹陷的双层钾盐成矿模式特征及成因

柴达木盆地是我国和世界重要的钾盐产地,目前对地表浅层盐湖钾盐研究颇多,但对深部碎屑孔隙钾盐研究较少.本文以昆特依凹陷为例,总结柴达木盆地钾盐成矿的时空变化规律,通过对该区地质、水文、古环境及卤水储层特征等分析建立“双层钾盐”成矿模式:上层为赋存在Q p2-h盐湖相化学盐类晶体裂隙间的晶间卤水,下层是Q p1冲洪积相砂砾孔隙卤水.采用聚类分析、特征系数、介稳相图、piper三线图及氢氧同位素等数理、地球化学手段分析上、下层卤水离子含量,探讨“双层钾盐”模式成因和上、下层卤水的内在联系.研究认为,昆特依凹陷内“双层钾盐”赋存卤水均为陆相沉积环境中的盐岩溶滤水,其中上层晶间卤水更多表现为盐岩溶解,但也不乏溶滤作用,下层砂砾孔隙卤水则着重表现为石盐的溶解;上层晶间卤水表现出下层砂砾孔隙卤水深度演化的特征,下层砂砾孔隙卤水具有对深部古盐岩层及上层晶间层的继承性;昆特依凹陷周边的新近纪背斜构造区油田水在成因上也与“双层钾盐”卤水密切相关.     

Geochemical types of natural waters in the interfluve of the Enzor’yakhi and the Yun’yakhi (eastern slope of the Polar Urals)

Natural-water chemistry in the interfluve of the Enzor’yakhi and the Yun’yakhi rivers (the eastern slope of the Polar Urals) is characterized in terms of the ratios of major ions belonging to hydrocarbonate calcium-magnesium and magnesium-calcium chemical types. From the viewpoint of evolution of the water-rock system in the region, five geochemical types of water were identified by the degree of their equilibrium with secondary minerals, reflecting different formation conditions of their chemistry. A specific feature of the region is the formation of waters of organogenic geochemical type, which are considerably enriched by organic matter, determining the specifics of migration of some chemical elements in such waters.     

Geochemical and isotopic evidence for seawater contamination of the hydrothermal system of Taal Volcano, Luzon, the Philippines

 The hydrologic structure of Taal Volcano has favored development of an extensive hydrothermal system whose prominent feature is the acidic Main Crater Lake (pH<3) lying in the center of an active vent complex, which is surrounded by a slightly alkaline caldera lake (Lake Taal). This peculiar situation makes Taal prone to frequent, and sometimes catastrophic, hydrovolcanic eruptions. Fumaroles, hot springs, and lake waters were sampled in 1991, 1992, and 1995 in order to develop a geochemical model for the hydrothermal system. The low-temperature fumarole compositions indicate strong interaction of magmatic vapors with the hydrothermal system under relatively oxidizing conditions. The thermal waters consist of highly, moderately, and weakly mineralized solutions, but none of them corresponds to either water–rock equilibrium or rock dissolution. The concentrated discharges have high Na contents (>3500 mg/kg) and low SO₄/Cl ratios (<0.3). The Br/Cl ratio of most samples suggests incorporation of seawater into the hydrothermal system. Water and dissolved sulfate isotopic compositions reveal that the Main Crater Lake and spring discharges are derived from a deep parent fluid (T≈300  °C), which is a mixture of seawater, volcanic water, and Lake Taal water. The volcanic end member is probably produced in the magmatic-hydrothermal environment during absorption of high-temperature gases into groundwater. Boiling and mixing of the parent water give rise to the range of chemical and isotopic characteristics observed in the thermal discharges. Incursion of seawater from the coastal region to the central part of the volcano is supported by the low water levels of the lakes and by the fact that Lake Taal was directly connected to the China sea until the sixteenth century. The depth to the seawater-meteoric water interface is calculated to be 80 and 160 m for the Main Crater Lake and Lake Taal, respectively. Additional data are required to infer the hydrologic structure of Taal. Geochemical surveillance of the Main Crater Lake using the SO₄/Cl, Na/K, or Mg/Cl ratio cannot be applied straightforwardly due to the presence of seawater in the hydrothermal system. Received: 12 February 1997 / Accepted: 26 January 1998     

Distribution Study of U,V, Mo,and Zr in Different Sites of Lakes Van and Hazar,River and Seawater Samples by ICP‐MS

The aim of this study is to investigate the concentrations of U, Th, V, Mo, and Zr in natural waters taken from Turkey. Among these water species, Lake Van is the largest soda lake and the fourth largest closed basin on Earth. The water samples were collected from 51 locations between 2008 and 2009. The inductively coupled plasma‐MS was used for determinations. The obtained U and Zr concentrations are in the range of 37–110 µg L^?1 and 17–78 µg L^?1 in Lake Van and 0.53–0.81 µg L^?1 and 0.15–0.19 µg L^?1 in Lake Hazar, respectively. The concentration of uranium in other studied waters varies from the lowest 0.09 µg L^?1 in Tigris (Dicle) river to the highest 4.0 µg L^?1 in Mediterranean Sea water. Mean Mo and V concentrations in the studied water samples were found to be in ranges of 0.1–17 and 2.7–113 µg L^?1, respectively. The obtained highest U concentration in Lake Van correlates with the highest Mo and Zr levels compared to the Lake Hazar and river waters. These results imply that there is a young occurrence of uranium minerals around Lake Van. It is concluded that there is about 50.000 ton of uranium in Lake Van water.     

Hydrogeochemistry of thermal and mineral water springs of the Azores archipelago (Portugal)

Mineral and thermal water chemistry from the Azores archipelago was investigated in order to discriminate among hydrochemical facies and isotopic groups and identify the major geochemical processes that affect water composition. A systematic geochemical survey of mineral and thermal water chemistry was carried out, incorporating new data as well as results from the literature. The Azores are a volcanic archipelago consisting of nine islands and samples were collected at São Miguel, Graciosa, Faial, São Jorge, Pico and Flores islands. Hydrothermal manifestations show the effects of active volcanism on several islands. Discharges are mainly related to active Quaternary central volcanoes, of basaltic to trachytic composition, but also some springs are related to older dormant or extinct volcanoes.Multivariate analysis – principal component and cluster analysis – enables classification of water compositions into 4 groups and interpretation of processes affecting water compositions. Groups 1 and 2 discharge from perched-water bodies, and mostly correspond to Na–HCO₃ and Na–HCO₃–Cl type waters. These groups comprise of cold, thermal (27 °C–75 °C) and boiling waters (92.2 °C–93.2 °C), with a wide TDS range (77.3–27, 145.7 mg/L). Group 3 is made of samples of dominated Na–SO₄ from very acid boiling pools (pH range of 2.02–2.27) which are fed by steam-heated perched-water bodies. Group 4 is representative of springs from the basal aquifer system and corresponds to Na–Cl type fluids, with compositions dominated by seawater.Results are used to further develop a conceptual model characterizing the geochemical evolution of the studied waters. Mineral and thermal waters discharging from perched-water bodies are of meteoric origin and chemically evolve by absorption of magmatic volatiles (CO₂) and by a limited degree of rock leaching. Existing data also suggest mixture between cold waters and thermal water. Water chemistry from springs that discharge from the basal aquifer system evolves by mixing with seawater; although, processes such as absorption of magmatic volatiles (CO₂), rock leaching and mixture with hydrothermal waters are not excluded by the data because the actual composition of these waters deviates from that expected considering only conservative mixing between fresh and seawater.     

青藏高原盐湖类沉积及盐湖矿物

上新世盐类沉积仅分布于柴达木盆地两部、昆仑山和唐古拉山北坡;晚更新世-全新世盐类沉积广布于羌塘和柴达木盆地。盐湖沉积只有蒸发岩和碎屑沉积物互层特点, 系干湿交替的内陆气候和动荡浅水环境下的湖相沉积。迄今已发现62种盐类矿物, 其析出具有阶段性特征, 青藏更新世-全新世盐湖自析阶段的起始时间分别为¹⁴C 24000和9000a B.P., 钾盐和硼酸盐各有两种典型的矿物共生组合。丰富的盐湖矿物资源是该区走向繁荣的物质基础之一。