Microstructure characteristics of illite from Chuanlingou Formation of Changcheng System in Jixian County,Tianjin City

The microstructure charateristics of illite from the Chuanlinggou Formation of Changcheng System (Chch) in Jixian County, Tianjin City has been studied by means of high-resolution transmission electron microscopy (HRTEM), selected-area electron diffraction (SAED), X-ray energy dispersive spectrum (EDS) and X-ray powder diffraction (XRD). The Kübler index of "illite crystallinity" is 0.505°△2θ, which indicates that the host rock is in a middle diagenetic stage. The chemical analyses of EDS for illite studied indicate a heavily absent in interlayer cation and an average chemical formula of K0.57(Al1.80Mg0.42Fe2 0.12)∑=2.34 (Si2.92Al1.08)∑=4O10(OH)2. It is found, from one-dimensional lattice images, that the layers of illite not only stack in a flat way but also in a curving way. A "matting fabric" illite structure results from stacking faults. Combined with SAED analysis the illite studied can be affirmed as 1M illite. The two-dimensional lattice images are obtained from [100] and [110] incidences, whose lattice images have the same d-values but different intersecting angles. The two-dimensional lattice image with [100] incidence is orthogonal to each other, whilst that with [110] incidence is oblique. This paper provides some important structure information of authigenic clay minerals for the well-known mesoproterozoic section of Jixian County.     

断层泥伊利石物理化学特征及其意义

通过X射线衍射和化学分析等方法,研究了云南水电站断层泥中伊利石物理化学特征,结果显示：①伊利石物质的X射线衍射特征为⊿[（002）-（001）] ＞8,Ir＞1,BB1 ＜4°,属I＋ISII有序混层,膨胀层小于15％,晶胞参数b0=8.991A,1M多型结构;②K2O的平均含量9.1％变化范围在8.5％-10％之间;③K2O和Fe2O3含量之间为负相关,K2O含量与⊿[（002）-（001）] 2θ值呈正相关,而K2O与Ir值呈负相关.上述特征表明该断层泥伊利石是在低温（小于200℃）低压环境下生成.它的形成与断层稳定滑动机制有关.由此推测该断层未来发生大地震的可能性较小.     

The occurrence state of vanadium in the black shale-hosted vanadium deposits in Shangling of Guangxi Province,China

The Shangling vanadium deposit, which occurs in the Lower Devonian Tangding formation black rock series strata, has V2O5 reserves of more than 1.5 million tons and prospective reserves of more than 2 million tons. Preliminary studies on the occurrence state of vanadium(V) in this deposit have been conducted by artificial heavy minerals concentrates, leaching experiments, scanning and transmission electron microscopy and X-ray powder diffraction.These experiments have revealed no independent vanadium mineral occurrences in the Shangling vanadium deposit and the percentages of water-soluble vanadium, hydrochloric acid soluble vanadium and HF soluble vanadium were1.93 %, 21.42 % and 76.47 %, respectively. Based on our data and earlier research, we estimate that the valences state of V absorbed onto the surface of organic matter or clastic particles are +5 and +4, accounting for 10.00 % and13.35 % of the total amount of V, respectively and the valences state of V that exist in the octahedral crystal lattice of authigenic illite include +3 and +4, accounting for71.64 % and 4.83 % of the total amount of V, respectively.By calculating the correlation between the total organic carbon and V, we infer that after deposition and before entering the crystal lattice of illite, V occurs in the form of humate complex or is adsorbed by organic matter. About4.24 % of the Al is in the octahedral crystal lattice of illite,which was replaced by the vanadium under the metallogenic environments of Shanglin.     

甘肃岷县漳县MS6.6地震前后岷县植被覆盖度动态变化

利用Landsat8遥感影像数据,应用像元二分模型估算了岷县植被覆盖度,分析了岷县漳县地震前后岷县植被覆盖度动态变化,并结合高程和坡度数据,研究了地形因素对植被受损和恢复的影响,结果表明:3个时段岷县植被覆盖度以中高和高植被覆盖度为主,反映出研究区植被覆盖状况良好。①空间分布上来看,中高和高植被覆盖度主要分布在岷县西南和东南部的高海拔地区,低植被覆盖区由岷县县城所在地向西北方向两侧沿居民地延展;②2013-2014年平均植被覆盖度下降了0.09,受损面积达到96.53%,主要为高植被覆盖度植被受损,植被受损在高程上主要分布在2 344~3 283 m,坡度5°~35°范围是植被受损的主要区域;③2014-2017年平均植被覆盖度回升至0.43,恢复面积达2 901.93 km^2,以高植被覆盖度植被恢复为主,其次为低植被覆盖度;植被恢复在高程2 031~2 970 m,呈增长趋势,随后开始下降,在坡度0°~25°范围内植被恢复面积呈增加趋势,随后降低。     

Electron microscopy study of the sakhaite from endogenous borate deposit in Hunan, China

Sakhaite was first discovered by Ostrovskaya, Pertsev and Nikitina at Siberia in the former Soviet Union. By using the X-ray diffraction technique, they proved that the crystal system of sakhaite was cubic (a = 1.464 nm), its possible space groups were Fm3m, F432, F43m, Fm3, F23, and its crystal chemical for-mula was Ca48Mg16(CO3)16(BO3)28Cl4(OH)8 4H2O[1]. Chichagov, Simonov and Belov studied the crystal structure of synthetic sakhaite and determined that its space group was F4132, …     

Mineralogical characteristics of airborne particles collected in Beijing during a severe Asian dust storm period in spring 2002

Asian dust storm (ADS) samples were collected on March 20,2002 in Beijing,China. High-resolution field emission scanning electron microscopy with energy dispersive X-ray detector (FESEM-EDX) and X-ray diffraction (XRD) were used to study the morphology,chemical compositions,number-size dis-tributions and mineralogical compositions of ADS particles. The mineral particles were major compo-nents in the ADS samples,accounting for 94% by number. The XRD analysis indicated that the dust particles were dominated by clay (40.3%),and quartz (19.5%),followed by plagioclase (8.4%),calcite (7.5%),K-feldspar (1.5%),hematite (0.9%),pyrite (0.9%),hornblende (0.4%) and gypsum (0.3%),with a certain amount of noncrystalline materials (20.3%). Clay minerals were mainly illite/smectite mixed lay-ers (78%),followed by illite (9%),kaolinite (6%),and chlorite (7%). In addition to these main minerals,FESEM-EDX also detected some trace minerals,such as dolomite,pyrite,thenardite,as well as heavy minerals represented by rutile,ilmenite and apatite. The mineralogical compositions of the 2002-03-20 Asian dust storm and the Saharan dust plumes were similar but the clay mineralogy showed a great distinction,with the illite/smectite mixed layers being common in the Asian dust storm but illite being common in the Saharan dust plumes.     

基于高分辨率影像的九寨沟7.0级地震道路震害评估

2017年8月8日九寨沟7.0级地震引发贯通重灾区的S301省道、Z120县道多处损坏,给应急救援和灾后重建带来较大困难。利用高分辨率无人机和卫星影像可以对道路震害情况进行评估。本文首先对道路震害进行破坏类型和破坏等级的划分,针对不同分辨率影像所表现的道路破坏特征,建立各破坏等级、各损坏类型的解译标志,并完成灾区遥感图像覆盖范围内主要道路震害的研判与评估。经统计分析,研究区域共出现110处明显破坏,其中,68处为部分损坏,42处为完全损毁,道路整体破坏严重。     

Distribution and significance of hydrothermal alteration minerals in the Tuzla hydrothermal system, Çanakkale, Turkey

Hydrothermal alteration zones have been investigated by X-ray diffraction, mineralogical–petrographical techniques, and geochemical analysis. Examination of cores and cuttings from two drill sites, obtained from a depth of about 814–1020 m, show that the hydrothermal minerals occuring in the rock include: K-feldspar, albite, chlorite, alunite, kaolinite, smectite, illite, and opaque minerals.In the studied area, silicified, smectite, illite, alunite, and opal zones have been recognized. These alteration mineral assemblages indicate that there are geothermal fluids, which have temperatures of 150–220°C in the reservoir.The distribution of the hydrothermal minerals shows changes in the chemical composition of the hydrothermal fluid, which are probably due not only to interaction with host rock, but also to dilution of the Na–K–Cl-rich hydrothermal fluid of the deep reservoir by cold sea water at shallow levels. Geochemical analyses of the solid and liquid phases indicate that the hydrothermal fluids of the Tuzla geothermal system are in equilibrium with alteration products.The tectonic structure of the studied area is caused by NW–SE and NE–SW directional forces. The volcanic rocks where hydrothermal zones are observed in the studied area are of Lower–Middle Miocene age comprise latite, andesite, dacite, rhyolite-type lavas, tuff, and ignimbrites.     

基于二维图像的数字岩心电导率计算方法研究

电导率是表征岩石电学性质的重要物理参数,在地质资源勘查和测井解释等领域发挥着巨大作用.快速、准确地确定岩石电导率具有重要的理论和实践意义.作为近年来发展的一种岩石物理数值模拟工具,数字岩心技术在定量计算电导率等物性参数方面应用广泛.三维微观结构的准确获取是数字岩心技术计算岩石电导率的关键,但传统获取岩石三维微观结构的方法较为复杂费时.为了方便快速地通过数字岩心技术计算岩石的电导率,本文研究了岩石二维与三维数字岩心的电导率联系.我们基于微米级X射线CT扫描得到的三个砂岩样品的微观结构信息建立了三维数字岩心,并通过有限元法计算的三维数字岩心电导率与实验数据的对比验证数值计算方法的有效性.随后我们数字地扩展了岩石的孔隙,产生了较大孔隙度的三维数字岩心样本,在此基础上,计算了三维数字岩心和相应二维数字岩心的电导率,并通过Archie公式分别拟合了电导率与孔隙度之间的关系,得到了相应的胶结系数.结果表明,三维数字岩心的胶结系数小于二维数字岩心的胶结系数,且二者的比值与岩石实测孔隙度呈线性负相关关系.以该联系为纽带,通过二维图像快速计算得到的电导率与孔隙度关系,确定了三维数字岩心的电导率与孔隙度关系,并进一步通过三维数字岩心的孔隙度计算其电导率.该方法计算得到的人工砂岩样品的电导率与其三维数字岩心电导率相关系数高于96%,验证了基于二维图像的数字岩心电导率计算方法的有效性.本文的研究结果为快速、准确地计算岩石电导率提供了新的思路,在油气勘探开发中有广阔的应用前景.     

Applications of scanning electron microscopy in earth sciences

This paper expounds upon the basic principle of scanning electron microscopy(SEM),the main features of image types,and different signals,and the applications and prospects in earth sciences research are reviewed.High-resolution field emission SEM allows observation and investigation of a very fine micro area in situ.Using low-vacuum mode SEM,geological insulating samples can be analyzed directly without coating,demonstrating the wide application prospect.Combined with backscatter detector(BSE),energy dispersal X-ray spectroscopy(EDS),cathodoluminescence spectrometry(CL),and electron back-scattering diffraction(EBSD),SEM can yield multiple types of information about geological samples at the same time,such as superficial microstructure,CL analysis,BSE image,component analysis,and crystal structure features.In this paper,we use examples to discuss the geological application of SEM.We stress that we should not only focus on the CL image analysis,but strengthen CL spectrum analyses of minerals.These results will effectively reveal the mineral crystal lattice defects and trace element composition and can help to reconstruct mineral growth conditions precisely.     

Element geochemistry and cleaning potential of the No. 11 coal seam from Antaibao mining district

It has aroused great attention that the mobilization of potential toxic substance during coal mining, pro- cessing and using has serious negative influence on environment. Clearly, the coal cleaning can be prop-erly applied to removing hazardous elements or re-ducing their concentrations prior to combustion, which also is considered as an economical and effective technique in minimizing some of these problems[1]. Unfortunately, there are fairly few studies on the parti-tioning behavior of trac…     

Texture development and deformation mechanisms in ringwoodite

Ringwoodite Mg₂SiO₄ with spinel structure is an important phase in the earth's mantle transition zone. Controlled deformation experiments showed that ringwoodite underwent ductile deformation when compressed axially at 6-10 GPa and at room temperature in a multianvil D-DIA deformation apparatus. Texture evolution during cyclic compression has been recorded in situ using X-ray transparent anvils with monochromatic synchrotron X-ray diffraction and a two-dimensional detector. Quantitative analysis of the images with the Rietveld method revealed a 1 1 0 fiber texture. By comparing this texture pattern with polycrystal plasticity simulations, it is inferred that {1 1 1}〈 1 0〉 slip is the dominant deformation mechanism in ringwoodite, consistent with high temperature mechanisms observed in other spinel-structured materials. Although strong ringwoodite textures may develop in the transition zone, the contribution to bulk anisotropy is minimal due to the weak single-crystal anisotropy.     

蓟县地震台小辛庄山洞定点形变观测干扰

整理蓟县地震台小辛庄山洞定点形变观测资料,分析强降雨、气压变化、机井抽水、爆破、仪器故障和标定、人为干扰等因素对观测数据的影响,强化认识干扰特征和一般规律,为地震前地球物理异常判定提供准确可靠依据,为同类型地震观测台站提供借鉴。     

蓟县地震台小辛庄山洞定点形变观测干扰

整理蓟县地震台小辛庄山洞定点形变观测资料,分析强降雨、气压变化、机井抽水、爆破、仪器故障和标定、人为干扰等因素对观测数据的影响,强化认识干扰特征和一般规律,为地震前地球物理异常判定提供准确可靠依据,为同类型地震观测台站提供借鉴。     

Characterising the hydrothermal alteration of the Broadlands–Ohaaki geothermal system, New Zealand, using short-wave infrared spectroscopy

Hydrothermal clay minerals present in the Broadlands–Ohaaki geothermal field were characterised by field portable short-wave infrared spectroscopy. Three major alteration zones, an upper smectite, a middle illite and a lower illite–chlorite, are spectrally separable. The zoning pattern is generally consistent with the thermal structure of the geothermal field, although occasionally zone boundaries cut present-day isotherms. The data indicate that temperature is the major control on clay zoning and permeability plays a subordinate role.Both beidellite and montmorillonite are common in the upper, low-temperature smectite zone. Kaolinite, mainly of low crystallinity, marks the margin of the field where cool acidic ground waters inflow. In the middle alteration zone, illite, dominantly K-rich, shows a narrow compositional variability. Some highly permeable zones are characterised by illite with low octahedral Al contents. Ammonium-bearing illite and buddingtonite are present locally in permeable horizons within the illite zone, where temperatures are above 200°C. Chlorite is most abundant in the lower alteration zone (temperature >250°C), although it also occurs unevenly in the upper and middle alteration zones. Chlorite varies from Mg- to Fe-rich varieties (but mostly with Mg# values <0.5), but no compositional trends with respect to depth are spectrally detectable.     

通过磁共振物理参数估计实现磁共振图像的分解

近年来,单谱与多谱磁共振图像的分割方法研究已经取得了很大进展,并应用于正常年龄的脑发育和脑疾病的诊断研究,例如老年痴呆综合征、脑损伤、脑肿瘤等的临床研究等。据此可以通过多谱MR图像获得多种对比度信息,更加准确表达人体组织及其病理情况。现已提出的大多数方法,把组织分割问题考虑成统计决策、模式识别和聚类、图像处理和分析等问题。在这些方法中用于组织分割的特征主要是单谱/多谱图像的灰度值/矢量,它们不能直接反映组织的物理特征。而且,这些方法将组织分割问题表述成组织磁共振图像中像素不同成分的有限集合。所以,这些组织分割的方法所取得的结果在某种意义上是不够合理的。这篇论文提出了一种基于磁共振图像谱分解的新的组织分割方法,该方法将组织分割问题考虑成组织的磁共振物理参数的估计问题。这个方法不仅用于磁共振成像中脂肪信号的抑止,也用于核磁共振谱中的水信号抑止。因此,这个方法可以称为空间和谱MR成像。     

沂沭断裂带断层泥中 K-Ar、FT 和 TL 体系年代学含义的初步研究

本文报道了利用K-Ar法、TL法和FT法,分别测定断层泥中1Md伊利石(<1μ粒级组份)、石英(2-10μ粒级组份)和磷灰石单矿物的年龄结果;给出了沂沭断裂带三次强烈活动的年龄区间及强度逐渐减弱的变化趋势。首先提出了利用这三种测年手段,测定断层泥中三种不同物质的年龄,进而研究断层活动(强度和时间)的新方法     

神经网络模型在X射线图像融合中的应用

当前航空安全形势紧张,所有国家都正在加强其安全检测系统.鉴于危险物品的特殊性,对含有危险物品的行李包的X射线图像进行模拟是一种有效培训安检人员的方式.这种模拟方式可以增强安检人员对不同背景环境下危险物品X射线特征的敏感度.在本文中,首先对X射线图像融合的物理过程进行了分析并且介绍了当前此领域中普遍使用的融合算法,随后采...     

On a method of computing the gravitational fields of inhomogeneous bodies

Summary A solution of the direct gravity problem for a finite body with variable density is given. The method is based on Green's formula and is applicable when a particular solution of Poisson's equation is known. The attraction due to the body is expressed by integrals over its surface The exact solution of the direct gravity problem, as known from the theory of two-dimensional fields [1–3], is closely connected with the problem of the analytic continuation of the exterior field of the attracting mass system into its interior. In the first place, this is a problem of determining the singularities of the exterior field, their distribution within the system and their nature. This approach to the solution of the direct problem is also meaningful from the point of view of determining the characteristics of the attracting system and, therefore, also of solving the inverse problem. In the case of two-dimensional fields the methods of analytical continuation were widely developed in a series of well-known papers by V. N. Strakhov, and they are mainly based on the methods of the theory of the functions of the complex variable. These methods were also successfully applied by Tsirulskii and Golizdra [1, 2] in treating the homogeneous and inhomogeneous, two-dimensional direct problem by means of Cauchy's integrals. However, as regards three-dimensional fields a number of fundamental problems has not been solved in this respect.Dedicated to 90th Birthday of Professor Frantiek Fiala     

虹口八角庙-深溪沟炭质泥岩同震断层泥的X射线衍射分析结果

5.12汶川地震同震地表破裂带在虹口八角-深溪沟一带主要出露于三叠系须家河组的炭质泥岩中,同震断层泥在颜色、结构上与老断层泥和围岩类似。通过开挖探槽,系统采样,采用粉晶X射线衍射定量分析方法,研究了同震地表破裂带的围岩、断层角砾岩、老断层泥和新断层泥的矿物成分特征。同震断层泥的主要成分为石英和黏土矿物,含微量长石和白云石;断层泥的显著特征为高黏土矿物含量,从同震断层泥、老断层泥、角砾岩到围岩黏土矿物含量依次降低,黏土矿物以伊利石和伊蒙混层为主,含微量绿泥石和高岭石,矿物组成明显比地表破裂带北段同震断层泥简单。不同颜色的同震断层泥成分略有不同,黑色断层泥中伊利石含量明显高于白色断层泥;老断层泥中含有方解石和白云石,而同震断层泥不含方解石,只含微量白云石。同震断层泥中伊蒙混层高含量表明,在本次地震错动中有富含K的流体参与。