北天山泥火山对2012年6月30日 新源-和静MS6.6地震的响应

2012年6月30日新源-和静M_S6.6地震前后, 北天山泥火山出现了喷溢和地球化学异常变化. 该地震前、 后4天内两次观测了北天山泥火山, 采集了两批温泉和泥火山气体样品, 测定了样品的气体组分和He、 Ne同位素及CH₄、 CO₂的碳同位素组成. 结果表明, 泥火山发生了同震喷发, 气体排放量增加, 温泉和泥火山气体出现了不同程度的微量气体浓度异常, 独山子泥火山震前出现了3He/4He高值异常. 研究结果有利于确定利用泥火山和温泉监测地震活动的方法和指标.      

甘肃东南地区温泉流体地球化学特征

根据氢、 氧、 氦同位素与水化学组分资料, 讨论了甘肃东南地区温泉水的来源、 地球化学变化及其与2008年汶川M_S8.0地震的关系。 测定结果表明: 样品的溶解性固体总量(TDS)范围为241.7~2 372.1 mg/L。 采集的7处温泉(通渭汤池河温泉、 清水地震台、 天水地震台、 武山地震台、 武山22号井、 成县地震台、 武都地震台)水样可归为四种化学类型: Na·Ca-SO₄、 Ca·Mg-SO₄、 Na-HCO₃·SO₄、 Ca·Mg-SO₄·HCO₃。 地下热水的化学类型与裂隙深度和围岩的岩性有关, 离子浓度和断裂深度基本成正相关。 通渭汤池河温泉和武都地震台的δ18O和δD值分别在-11.4‰ ~ -7.6‰和-85.7‰ ~ -57.1‰的范围内, 通渭汤池河温泉和武都地震台中³He/⁴He的值分别为0.4×10^-7和12.7×10^-7。 氢、 氧、 氦同位素组成特征表明温泉水源于大气降水, 在循环过程中经历了水岩反应, 且可能有地表水的混入。 2008年汶川M_S8.0地震发生后, 研究区域内温泉水中K⁺、 Ca²⁺含量总体上升, SO^2-₄、 Cl^-含量总体下降, Na⁺含量变化不明显; 热水循环深度受地震影响发生变化。 本文确定了甘肃东南地区温泉来源、 水化学类型成因及其与汶川M_S8.0地震的关系。     

龙门山断裂带温泉水文地球化学特征

对地震活动强烈地区进行水文地球化学监测可以很好地获取与地震相关的深部流体地球化学信息。通过研究龙门山断裂带及其周围13个温泉及观测井的水文地球化学特征,建立该断裂带温泉水文循环模型,揭示其水化学变化与地震活动的关系。结果表明:(1)龙门山断裂带温泉水主要来自其周围0.8～3.2 km高山的大气降水;(2)温泉水化学类型沿龙门山断裂从北到南、从西到东依次为重碳酸型、硫酸型、氯化物型,温泉水的循环深度、水岩反应程度及微量元素富集因子不断增加;(3)在汶川M_S8.0地震、芦山M_S7.0地震发生后,震中距200 km以内的温泉的离子组分呈下降趋势,这可能是在震后愈合过程中,龙门山断裂内部渗透性减弱、水岩反应程度衰减所致。     

北天山地区泥火山地球化学成因研究

<正>泥火山是特定地质构造及水文地质环境下的一种构造流体地质现象。由于泥火山喷发时可以将大量有价值的信息带到地表,因此,不少科学家将泥火山称为深度可达12 km的"天赐钻井"。新疆泥火山的构造位置是准格尔-北天山盆山过渡带。该过渡带NWW走向,东西延伸长度约350~500 km,南北影响宽度约100km左右。自西向东依次分布着温泉县泥火山群、乌苏市白杨沟泥火山群、乌苏市艾其沟泥火山群、独山子泥火山群、沙湾霍尔果斯泥火山等。2010年6月,2011年6月和2012年6月,课题组沿着温泉、乌苏、独山     

三轴压力下水与砂岩反应的实验研究

通过饱水砂岩的三轴压缩实验, 研究了含水层砂岩的破裂过程及其伴随的水化学变化, 并探讨了砂岩在蠕变和剪切破裂过程中地震水化异常现象的形成机理。 用离子色谱仪(IC)和等离子原子发射光谱仪(ICP-OES)测定了不同压力条件下实验溶液的F^-、 Cl^-、 NO^-₃、 SO^2-₄、 Ca²⁺、 Mg²⁺、 Na⁺浓度。 饱水砂岩在差应力作用下, 随着蠕变时间延长和剪切作用的强化实验, 溶液中主要离子的浓度均有不同程度的增大, 仅Mg²⁺浓度是降低的。 F^-和Cl^-浓度变化最明显, 在2~12小时的蠕变时间内分别增大约10倍和4倍, 而随剪切作用的强化分别增大约5倍和3倍。 这种变化主要与矿物的溶解和流体包裹体的混入有关。 实验结果表明, F^-、 Cl^-和Ca²⁺可作为砂岩含水层地震水化前兆监测的灵敏组分。     

昆明地震台流体观测井水文地球化学特征

以昆明地震台井水、渔塘水为研究对象,通过水质、同位素分析方法并结合水文地质、构造地质等资料,探究井水地球化学特征及意义,以及井水与渔塘水之间的水力关系。研究结果显示：昆明地震台井水、渔塘水水化学类型为HCO₃—Ca型,水质受含水层和隔水层岩性控制,与2018年相比2020年井水水化学特征发生了显著变化,K⁺、HCO₃^-浓度降低,这反映了昆明地震台井—含水层渗透性有所增加;SO₄^2-、Cl^-浓度的增加则表明昆明地震台井水会受到人为干扰。研究区构造活动平稳,井水为未成熟水,演化程度较低,因含水层渗透性增强和人为干扰,自2018年7月至2020年11月昆明地震台井水—岩作用有所增强,表现为δD、δ¹⁸O富集,Mg²⁺浓度升高。井水补给来源为大气降水,补给区位于观测井正北的石关一带。渔塘水与昆明地震台井水间存在水力关系,在分析地表水对昆明地震台井的影响时应予以考虑,但渔塘水不是影响井水的主要因素。     

北天山地区泥火山的地球化学成因

泥火山是特定地质构造及水文地质环境下的一种构造流体地质现象,泥火山喷发时可以将大量有价值的信息带到地表,因此,不少科学家将泥火山称为深度可达12km的"天赐钻井"。在对新疆北天山地区分布的众多泥火山进行地形地貌、地质-水文地质条件、泥火山堆积物特征调查研究的基础上,系统分析了温泉、乌苏、艾其沟、独山子、沙湾-霍尔果斯各泥火山喷出物的流体地球化学组成(固体、气体、离子、同位素等),初步得到了基于地球化学成分特点的泥火山成因;区域地壳构造应力的不断增强既可以导致地震的孕育和发生,也可以使泥火山打破原有周期而出现显著活动,可见二者具有一定的同源关系。     

贺兰山东麓断裂地下水水文地球化学特征

以贺兰山东麓断裂带内地下水为研究对象,运用Piper三线图、离子比值等方法对研究区内丰水期与枯水期地下水的水化学特征进行分析,探讨了断裂与水化学组成及地震活动的关系,并建立贺兰山东麓地区地下水成因模型。结果表明：(1)区域地下水总体偏弱碱性,阳离子以Ca²⁺和Na⁺为主,阴离子以HCO^-₃和SO^2-₄为主;(2)区域地下水主要受大气降水补给,补给高程为1.07～2.04 km。Na-K-Mg三角图显示,研究区地下水为“未成熟水”。绝大多数水样的矿物饱和指数SI<0,表明区域地下水中各个离子含量大体处于未饱和状态。利用温标法估算该区域地下水的热储温度为74.6℃～114.1℃,循环深度为1.7～2.8 km;(3)地下水样中的Sr、Ba、Li等微量元素富集因子EF>1,富集程度高,其余大部分微量元素含量较低,说明当地地下水为未成熟水,矿化度低,水岩反应程度不强。(4)研究区地下水出露点主要沿贺兰山东麓断裂展布,水温、矿化度、矿物饱和指数及水循环深...     

2020年新疆于田MS6.4地震温泉水文地球化学异常特征研究

2020年6月26日新疆于田县发生M_S6.4地震, 地震发生前后对震中80 km内的两个温泉在2019年9月至2020年10月的水文地球化学的变化特征进行了研究, 结果表明: ①温泉水的来源为其周围昆仑山的冰川融水, ②克孜勒沙衣温泉补给高程6 km, 水化学类型为Na-HCO₃、 部分平衡水、 温泉循环深度达到1.7 km左右, 其主要气体组分为N₂, 幔源氦占10.6%。 ③乌什开布隆温泉补给高程为3.1 km, Ca·Na-HCO₃·SO₄型, 未成熟水, 可能与浅层冷水发生了混合作用, 循环深度仅达到0.5 km, 该温泉的水化学组分对周围的地震活动有明显的异常响应, 伽师M_S6.4地震前, 区域应力的不断加载使断裂带内裂隙发生明显变化, 从而温泉流体行为发生变化, 使乌什开布隆温泉的离子浓度小幅度上升, 且Cl^-含量在于田M_S6.4地震后16天突增。 因此, 对乌什开布隆温泉及克孜勒沙衣温泉的流体地球化学特征进行连续监测, 可以为未来阿尔金断裂及西昆仑断裂的交会区地震危险性提供有效判断指标。     

天山地区地震监测井(泉)水文地球化学特征

为研究天山地区地震监测井(泉)地下水化学特征,系统采集了20个天山断裂带地震监测点地下水化学样品,综合运用氢氧同位素、Gibbs图、离子比值、Piper三线图、Na-K-Mg三角图和舒卡列夫分类等方法探讨了监测点的水化学及水文地球化学特征。结果如下:(1)天山地区地震监测井(泉)水中主导阳离子为Na⁺,阴离子分别为HCO₃^-、SO₄^2-和Cl^-,TDS介于249.9～10 272.3mg·L^-1之间,多数为淡水。(2) δD、δ¹⁸O结果表明天山地区地震监测井(泉)水主要来源于大气降水。Gibbs图表明研究区监测点地下水元素主要受岩石溶滤控制,南天山和乌鲁木齐监测点地下水受到一定蒸发浓缩控制。离子比值显示碳酸盐和硫酸盐矿物溶解是控制地下水主要离子组分主要因素。(3) Na-K-Mg三角图表明天山地区地震监测井(泉)水多数为“部分平衡水”,部分为“未成熟水”,水—岩反应处于较为活跃的程度,有利于孕震信息的传递,适合...     

THE FLUID GEOCHEMICAL VARIATION CHARACTERISTICS OF THE WUSU MUD VOLCANOES BEFORE THE JINGHE EARTHQUAKE OF MS6.6 ON AUGUST 9, 2017

Mud volcano is a conical sedimentary body formed by high-pressure mud and gas-dominated fluid migrated to the surface through faults and other channels deep underground, which looks like a volcanic cone formed by magma-volcanism. As a product of crustal movement, mud volcano can bring a large amount of valuable information from deep to the surface when erupting. Therefore, mud volcano is called "god-given borehole" with a depth of 7~12km. Mud volcanoes are the result of upthrust of trapped gases released by the pressure in the stratum and also the channel for the upward migration of gases in the earth. The submarine mud volcano is one of the signs of hydrate and the living evidence of hydrate. The Wusu mud volcanoes are located in the northern Tianshan tectonic belt. Since the mud volcamoes locate in the active part of the tectonic belt and are well connected to the underground, their active degree has a good correlation with the seismicity. The earthquake cases studies based on the 7a long real-time macroscopic monitoring data and the more than 3a long geochemical monitoring data of the Wusu mud volcanoes show that in the earthquake cases of M_S ≥ 5.0 within the range of 300km around the Wusu mud volcanoes, the abnormal mud gushing quantity obviously increased by macroscopic monitoring before 9 out of 13 earthquakes. The geochemical microcosmic monitoring data showed obvious abnormal changes before 3 out of 6 earthquakes. The anomalous duration from the emergence of the anomaly to the occurrence of the earthquake is mainly of the mid-term(6~12 months). Before the Jinghe M_S6.6 earthquake on August 9, 2017, the Wusu mud volcanoes spewed violently and the chemical components showed an obvious high value anomaly. In January 2017, there was a significant increase in the amount of mud spewing in Aiqigou No.1mud volcano and Baiyanggou No.1mud volcano, and one month before the earthquake, there was the phenomenon that mud gushing amount of Aiqigou No.2 mud volcano gradually increased and the volcano was from dormant to active. There were obvious high values appearing before the earthquake in F^-and SO₄^2- in the Aiqigou No.1mud volcano and in F^-, CO₃^2-, SO₄^2-, Rn(gas), CH₄, Ar and N₂ in Baiyanggou(No.1 and 2)mud volcanoes. The values of F^-, CO₃^2-, SO₄^2-, Ar and N₂ showed short-term anomalies, while CH₄ and Rn(gas)showed medium term anomalies. Giggenbach triangular diagram (Na-K-Mg) indicates that the water-rock reaction of Baiyanggou mud volcanoes is complete and little disturbed by the outside. The water-rock reaction of the Aiqigou mud volcanoes is still ongoing, which can explain why the precursor anomaly of the chemical components of the Baiyanggou mud volcanoes is more obvious than that of the Aiqigou mud volcanoes. The geothermal reservoir temperature of the study area is estimated by using a cationic (Na-K, K-Mg, Na-K-Ca) geothermometer. The geothermal reservoir temperature of the Wusu mud volcanoes is about 70℃, and the circulation depth is about 3km. In the process of earthquake preparation, the mud carries deep chemical components to the ground surface due to the effect of compression stress(the result of focal mechanism)or the concentration of regional tectonic stress with earthquake preparation; Or the rock strata in or near the seismogenic area are deformed, the depth of liquid circulation will increase, and the water-rock reaction will be accelerated, which will increase the concentration of some ionic components, and the squeezing process will cause a large number of mud to gush out of the ground, carrying geochemical components. Therefore, the gushing quantity and some chemical components of the mud volcanoes were obviously abnormal before the earthquake.     

新疆北天山泥火山固体喷出物特征及成因机制初探

北天山泥火山位于新疆天山北麓山前拗陷带内,均处在背斜褶皱的轴部。在了解泥火山的地质背景、活动现状的基础上,对该区泥火山进行了详细的野外考察,对所采样品进行粒度、显微形貌及成分分析。研究发现:该区域的泥火山样品粒径主要集中在0.3~100μm,平均值相近,分选较差,分布对称性呈极正偏。矿物颗粒以石英、长石为主,基质为黏土矿物,白杨沟和艾其沟样品中均含有铁矿物质。根据上述分析结果对北天山泥火山成因机制进行了初步探讨,认为该区域的泥火山物源相同,泥浆最深来源于下中侏罗统,地层压力以构造活动为主。目前泥火山处于弱活动期,短期内造成较大灾害的可能性很小。     

花岗岩水岩反应中水化学变化实验研究

大量震例表明地震前后可以观测到地下水成分的变化。 本文通过差应力下花岗岩与水反应实验模拟研究花岗岩含水层在应力积累至破裂过程中水化学组分的变化, 并探讨了地震水化异常的形成机理。 实验结果表明, 随着差应力及其加载时间的增加, 溶液中不同离子浓度均呈现不同程度的增加, 其中Na⁺、 K⁺和Cl^-的浓度变化最明显。 随着差应力的增加, 三种离子浓度分别增加到3.3、 2.5和11.6倍。 随着加载时间的增加, 三种离子浓度分别增加到3.2、 3.1和12.5倍。 这种变化可能主要与花岗岩中矿物的溶解有关, Na⁺、 K⁺和Cl^-可作为花岗岩含水层地震水化前兆监测的灵敏组分。     

新疆北天山艾其沟泥火山强震前显著喷涌现象及其变化机理分析

泥火山形成于特定的水文地质及构造环境,其喷发活动是内部大量气体聚集引起异常高压的一种释放,可以将大量地下信息携带到地表,被称为"天赐钻井"。新疆乌苏艾其沟泥火山实时观测始于2011年8月,自观测以来,在其周围200m范围内,共发生了4次6级以上地震,分别是2011年11月1日新疆尼勒克M_S6.0、2012年6月30日新疆新源M_S6.6、2016年12月8日新疆呼图壁县M_S6.2及2017年8月9日精河M_S6.6地震。在4次地震前后,艾其沟泥火山喷发活动均出现了"背景值—上升—转折—下降—背景值"的宏观异常变化现象,地震则发生在泥火山喷发活动由强到弱的过程中,尤其是在2017年精河M_S6.6地震时,乌苏艾其沟泥火山的喷发活动异常变化现象为新疆地震局做出震情形势判定提供了一部分依据,具有一定的减灾实效。     

Intensifying groundwater acidification at Birkenes, southern Norway

Groundwater chemical data from Birkenes, southern Norway, collected during the period October 1980 to November 1993, reveal intensifying acidification in the 1990s, as evidenced by decreases in pH, acid-neutralising capacity and alkalinity, and increases in hardness/alkalinity ratio, ‘acidification’, nitrate, non-marine sulphate (SO₄^*), non-marine hardness (Ca^* + Mg^*) and dissolved aluminium. The whole monitoring period is characterised by slopes of four or more on a plot of (Ca^* + Mg^*) vs. alkalinity.

Owing to its proximity to the sea, the Birkenes catchment receives seasalt-influenced precipitation, which results in episodic, natural acidification of the groundwater via cation exchange of marine Na⁺ with soil-bound H⁺ and/or Al³⁺. However, it is uncertain whether all of the recent groundwater acidification can be attributed to intensifying seasalt deposition alone: the steep slopes on the (Ca^* + Mg^*) vs. alkalinity plot and the increase in groundwater SO₄^* suggest that strong acids, of possible anthropogenic origin, may be involved. Additionally, seasalt deposition appears not to have increased during the 1990s: Cl⁻ content in precipitation has not increased significantly and river water pH has not decreased significantly over the period 1990–1993. The suggestion is made that the observed intensification in groundwater acidification at Birkenes partly results from the exhaustion or weakening of an acid buffering system caused by soil acidification, under persisting, even if abating, anthropogenic acid loading.     

Dispersion of naturally occurring ions in groundwater from various rock types in a portion of the San Pedro river basin, Arizona

The groundwater in an alluvial basin in southern Arizona was analyzed for concentrations of Ca⁺⁺, Mg⁺⁺, Na⁺, and Cl⁻, ions.

The variety of rock types in the area, plus the undisturbed state of the groundwater basin, make comparative rock mineralization-groundwater ionization interpretations possible. Ionic dispersion in groundwater eminating from source areas composed of differing rock types is plotted as isogram maps. These isolated areas of differing mineral composition each exhibit a unique ionic contribution to groundwater. The ion concentrations in groundwater were then used as naturally occurring tracers to determine source areas of recharge and to delineate subsurface barriers to the normal basin flow net. Ion dispersion plots reveal the carbonates of the Dragoon Mountains to be a major contributor of Ca⁺⁺ and Mg⁺⁺ to the deep alluvial portion of the basin. Cl⁻ dispersion patterns show the granitic intrusives of the Tombstone Hills produce a barrier effect in the normal flow pattern of the basin as well as being a contributor of Cl⁻ to groundwater.     

新疆泥火山群地震前兆异常实时监测与预报的研究

基于网络技术的视频监控服务,实现了对新疆北天山地区3个泥火山点的实时监测,可在线实时查看泥火山活动情况,分析预报人员依据泥火山活动图像可开展地震预测研究。新疆艾其沟泥火山网络视频监控服务系统扑捉到了2次6级地震前火山液面明显的宏观异常变化现象,这说明基于宽带网络技术的网络视频监控服务,可实现互联网用户使用客户端远程软件连接服务器,实现在线实时查看泥火山活动情况的监控画面,并依据泥火山群地震观测网,捕捉泥火山群地震前兆异常。     

origin of the mud volcano in northern tianshan constrained by geochemical investigation

Mud volcano is a kind of structural geological phenomena under certain hydrogeological environment and can bring plenty of valuable information to the ground when it erupts, therefore, many researchers call it as "Heaven granted well" whose depth can be up to 12km. Mud volcanoes in Xinjiang are distributed in the central-west region of North Tianshan, and five of them are representative, namely, Horgus, Dushanzi, Wenquan, Poplar valley, and Sailetike. We tested the gas, fluid and solid components of these mud volcanoes through investigations and studies of topography and geomorphology, geological and hydrogeological conditions, and mud debris characteristics, and preliminary obtained the origin of these mud volcanoes based on geochemical features. Finally, the paper describes briefly that the continuous enchancement of regional crustal tectonic stress can not only give rise to the seismogenesis and earthquake occurrence, but also break the original cycle of mud volcano to bring about significant activity, therefore, the two have a certain homology relationship.