含黑云母断层岩碎屑在热水条件下的摩擦滑动实验研究——含弱矿物断层的力学性质研究

<正>弱断层的成因一直是一个热门的问题,而通过实验室对弱矿物力学性质进行研究是探索弱断层成因的较直接手段。黑云母是自然界中常见的层状硅酸盐矿物,已有室温条件下的摩擦实验结果显示其具有低的摩擦强度。关于黑云母的熔融实验结果显示,其可以稳定存在的温度范围很广,至少在700℃以内可以稳定存在。由于其在地壳内部地震成核的深度范围内可以稳定存在,并且常常出现在断层岩中,对黑云母在高温、含水条件下摩擦性质的研究有     

二云母花岗岩与含硼流体反应的实验研究:对电气石花岗岩成因的启示

了解不同类型花岗岩的成因联系是认识花岗质岩浆形成和演化过程的关键.文章报道了在600～700℃、200MPa条件下,含硼(B)流体与二云母花岗岩的交代反应实验,重点研究了温度和流体B含量对交代反应产物的影响.实验结果表明,富B流体与二云母花岗岩反应可以形成电气石花岗岩.在700℃条件下,富B流体的加入会使二云母花岗岩发生部分熔融(包括黑云母和白云母含水部分熔融),电气石从部分熔融熔体中结晶.对比实验显示,增加流体的B含量能够明显促进二云母花岗岩的部分熔融以及电石气的生长. 600℃实验中未产生熔体,富B流体使黑云母发生分解,形成磁铁矿,其余Fe、Mg和Al与流体中的B结合形成电气石,黑云母分解产生的K与斜长石中Na发生Na/K离子交换,为电气石结晶提供了Na.实验产生的电气石普遍具有核-边结构,显示矿物结晶过程伴随熔体或者流体成分的改变.由实验结果可以推断,含B花岗质岩浆房结晶晚期脱挥发分作用产生的富B流体在上升运移过程中,可能与岩浆房边缘相的二云母花岗岩发生反应,形成电气石花岗岩岩株或岩脉.本研究表明,岩浆演化晚期富B流体参与的自交代反应可能是电气石花岗岩的重要成因之一.     

热水条件下黑云母断层泥的摩擦强度与稳定性

黑云母是自然界常见的层状硅酸盐矿物,其摩擦系数不高且化学稳定性好,对其摩擦性质的关注可能会对弱断层的研究有所帮助.本次工作选取的实验温度条件对应于典型地壳强度模型中脆塑性转化带的范围,为300 ℃和400 ℃.有效正应力为200 MPa,孔隙水压包括10 MPa和30 MPa,在此条件下对黑云母模拟断层泥进行摩擦实验研究.实验得出黑云母的摩擦系数平均在0.36左右.速度依赖性随温度升高速度弱化的程度增强,表现为300 ℃为十分微弱的速度弱化,而在400 ℃出现了黏滑行为,代表了更强的速度弱化.显微结构中同时出现了脆性剪切变形和塑性扭折变形,但决定宏观力学性质的显然是脆性剪切变形.在黑云母存在的情况下,本研究的实验结果有助于理解大陆地壳脆塑性转化带中地震的可能性和弱断层深部的变形机制、宏观力学行为以及地震活动.     

闽西南地区燕山晚期花岗岩黑云母特征及成因意义

本文通过黑云母的电子探针方法测试,分析闽西南地区才溪岩体、四方岩体及罗卜岭岩体中黑云母的地球化学特征及其成因意义。测试结果表明,才溪二长花岗岩中的黑云母为高铁黑云母,而四方花岗闪长岩及罗卜岭花岗闪长斑岩中的黑云母为高镁黑云母,在由黑云母成分确定的物质来源图上,它们均落入壳-幔混合源区域,表明其成因类型都是壳-幔混源型花岗岩,但随着形成时代的逐渐变新,其物质组成成分中幔源组分逐渐增多。     

高温高压下地幔矿物水溶解度的研究进展

本文简要阐述地幔矿物中水溶解度的研究方法及过程,探讨晶体结构、化学组成、水逸度、温度、压力、氧逸度、硅活度等对溶解度的影响,结合橄榄石、辉石、石榴石、瓦兹利石、林伍德石等主要造岩矿物的研究成果,分析了地幔的储水能力,并指出存在的问题及今后的研究方向.     

高温高压下地幔矿物岩石电导率影响因素研究进展

实验室高温高压条件下获得的地幔矿物岩石电导率值可以帮助获得地球内部物质组成、物质运动变化状态和解释地球物理探测资料.研究表明,电导率测量影响因素(外部因素和内部因素)控制不当将使得测量的电导率值产生较大差异.本文综述了近20年来这些影响因素对地幔矿物岩石电导率的影响程度及进展情况,电导率随着温度,铁含量和水含量的增加而增加;不含水条件下,电导率随着氧逸度和压力的增加分别增加和减小,含水条件下则恰恰相反;忽略颗粒边界的影响;测量频率和结晶方向对电导率的影响尚存在一定争议;进行电导率测量时有必要考虑系统平衡时间和样品中铁含量的流失.最后探讨了高温高压条件下电导率实验研究的不足和发展方向.     

基于岩石成因的测井地质属性研究方法

测井曲线是多成因的产物.从测量成因看,它与测井仪器的原理密不可分;从测量对象看,它与地质背景相互关联;从井眼环境看,它也包含井眼条件的变化信息.由此可见,测井曲线本身就是地球物理、地质及工程等多因素的响应纠缠体,其中,每一种因素,因其测井响应的成因条件完全不同,它只会按自身固有模式变化.前人对于测井曲线的仪器成因研究较系统,因此,基于仪器原理的测井评价方法也比较成功,但对于地质背景与测井曲线的成因关系识别一直缺乏有效方法,致使测井曲线本身内含的地质信号难以得到有效利用.根据地质成因的某一固有机理,推测或在测井曲线上寻找与该固有机理相吻合的共性变化,是研究测井曲线内含地质属性的一个可能途径,岩石成因就是一个值得探索的切入点.研究表明,岩石成因的主要差别在于形成条件不同,岩石形成条件是决定测井曲线内含地质专属性特征的要因之一.本文分别从成岩时期、成岩物质、成岩温度、沉积相、成岩相及物性特征等多个岩石成因条件的差异,讨论了岩石成因条件的差异与测井地质属性识别的关系.     

江西省大湖塘石门寺矿区超大型钨矿的发现及找矿意义

江西省武宁县大湖塘石门寺超大型钨矿的成功勘查是我国地质找矿工作的重大发现。矿化类型划分为细脉浸染型、隐爆角砾岩型和石英大脉型。前者占总储量的74％,该类型以晋宁晚期黑云母花岗闪长岩为容矿围岩,以燕山中期酸性深成至浅成花岗岩为成矿母岩。矿体厚大且产状平缓,大致平行于黑云母花岗闪长岩与似斑状黑云母花岗岩株顶部的接触面分布,以外接触带为主（I1矿体）,水平投影面积1．50km2,单工程最大厚度389．33m,平均厚度143．67m,平均品位0．193％,厚度变化系数63．7％,品位变化系数115．8％。工业矿物主要为白钨矿、黑钨矿、黄铜矿、辉钼矿。矿石组构类型主要有结晶结构、交代结构、细脉状构造、浸染状构造,常见近矿围岩蚀变为黑鳞云母化、云英岩化、绿泥石化,成因类型属岩浆期后高中温热液矿床,工业类型可划归为细脉浸染型白钨矿。石门寺矿区以黑云母花岗闪长岩为容矿围岩的细脉浸染状白钨的发现,改变了以往只专注评价石英大脉型黑钨矿的找矿思路,为矿区及九岭矿集区实现钨多金属找矿突破指明了新的方向。     

南岭及邻区中生代含锡花岗岩的多样性:显著的矿物特征差异

南岭及邻区分布一系列与中生代花岗岩有关的锡矿床,这些岩石可以是含角闪石黑云母花岗岩,或是(黄玉)钠长石-(铁)锂云母花岗岩,其岩石化学特征指示它们分别对应于准铝质和过铝质花岗岩.细致的矿物学研究表明它们具有完全不同的矿物学特征.准铝质含锡花岗岩的矿物学特征表现为:(1)角闪石、黑云母、条纹长石等组成特征性的造岩矿物组合:(2)标志性副矿物榍石、磁铁矿等显示其原始岩浆具有较高的氧逸度;(3)含锡矿物为锡石、黑云母、榍石等;(4)锡石的成分比较纯,微量元素含量低.过铝质含锡花岗岩的矿物学特征主要表现为:(1)铁锂云母-锂云母、钾长石、钠长石为典型造岩矿物;(2)富铝矿物黄玉是较常见的副矿物,与花岗岩铝过饱和特征相符;(3)锡石是重要的锡矿物,且富含Nb、Ta.造成两类含锡花岗岩显著矿物学差异的原因可能包括熔体的氧逸度、挥发组分和岩浆分异程度的差异.氧化型准铝质花岗岩熔体中锡以四价为主,这导致锡容易富集在含钛的造岩矿物或副矿物中,在岩浆结晶分异阶段形成富锡矿物;这些富锡矿物可成为含锡花岗岩的标志性矿物.相对还原的过铝质花岗岩熔体中锡以二价为主,不易进入造岩矿物和副矿物,常常在岩浆结晶分异阶段形成岩浆成因的锡石;因此,岩浆成因锡石成为这类花岗岩的重要成矿和找矿标志.岩浆性质和锡在两类花岗岩岩浆中地球化学行为的差异,导致形成的矿床类型有所不同.准铝质花岗岩主要形成岩体浸染型、绿泥石-石英脉型、云英岩型、矽卡岩型等矿床,而过铝质花岗岩除形成云英岩型、矽卡岩型、石英脉型等矿床外,更易形成岩体浸染型锡矿化.     

中地壳的水和水岩相互作用实验及其地球物理涵义

本文重点报道了高温高压下流体与流体-岩石相互作用实验结果,提供了中地壳条件下流体性质和水岩反应速率数据.这些数据有助于理解中地壳的一些地球物理现象.作者进行了25℃~435℃和22~39 MPa条件下水-岩相互作用反应动力学实验.同时,研究水在近临界区至超临界区的性质.一般地说,中地壳大致位于10(15)至25 km的深度范围.各地的地壳厚度不同,但是中地壳高导-低速层的深度范围十分相似.中地壳的顶界温度处于300℃,底界大致为450℃范围,压力高达200 MPa以上.流体-岩石相互作用实验表明:硅酸盐矿物和岩石的硅最大溶解速率出现在300℃~400℃.此时,硅酸盐矿物格架解体.通常,地壳里普遍存在水、流体.地壳构造活动导致断裂空隙、减压、流体流动.这时,有可能导致中地壳处于300℃~450℃流体的压力减低,由超临界区进入临界态、亚临界态.这会引发强烈流动的水与岩石相互作用.溶解反应导致岩层的硅淋失,硅的强烈淋失又会导致硅酸盐矿物格架解体,岩石崩塌.同时,进一步促进流体的流动.实验表明300℃~400℃下的强烈水岩相互作用促进了岩石破坏,并有可能影响岩层的地球物理性质,如高导层出现.另外,实验和理论研究表明处于300℃~400℃流体具有高电导率性质.这些水岩相互作用会使中地壳出现高导-低速层.     

SR isotope geochemistry of voluminous rhyolite of the Tamagawa Welded Tuffs, related rocks and andesite of the young volcanics, in Hachimantai geothermal area, Northeast Japan

The volcanic rocks from the Hachimantai geothermal area, Northeast Japan, are divided into the following five groups: (1) rhyolite of the Tamagawa Welded Tuffs (about 500 km³, 2.0–1.4 Ma); (2) andesite related to the Tamagawa Welded Tuffs (about 10 km³, 1.5 Ma); (3) andesite of the Matsukawa Andesite (about 100 km³, 1.8-1.2 Ma); (4) dacite of the Kashinai Formation (about 100 km³, 1.1 Ma); and (5) andesite of the Young Volcanics (about 300 km³, younger than 1 Ma). ratios of less-altered samples of the five groups range from 0.7038 to 0.7046. There is no significant difference in ratios among the five groups in spite of differences in age and chemical composition. Therefore, fusion of or contamination by old acidic crust can be ruled out for the genesis of the voluminous acidic magma which produced the rhyolite of the Tamagawa Welded Tuffs and the dacite of the Kashinai Formation.The low ratios and the chemistry suggest two possibilities for the genesis of the acidic rocks. One is a low degree of partial melting of the basic crust, which has a low ratio, under high temperature. Another is a high degree of fractional crystallization from basic magma derived from the mantle.     

Mineral chemistry of a Cenozoic igneous complex,the Urumieh–Dokhtar magmatic belt,Iran: Petrological implications for the plutonic rocks

The Niyasar plutonic complex, one of the Cenozoic magmatic assemblages in the Urumieh‐Dokhtar magmatic belt, was the subject of detailed petrographic and mineralogical investigations. The Niyasar magmatic complex is composed of Eocene to Oligocene mafic rocks and Miocene granitoids. Eleven samples, representing the major rock units in the Niyasar magmatic complex and contact aureole were chosen for mineral chemical studies and for estimation of the pressure, temperature, and oxygen fugacity conditions of mineral crystallization during emplacement of various magmatic bodies. The analyzed samples are composed of varying proportions of quartz, plagioclase, K‐feldspar, hornblende, biotite, titanite, magnetite, apatite, zircon, garnet, and clinopyroxene. Application of the Al‐in‐hornblende barometer indicates pressures of around 0.2 to 0.4 kbar for the Eocene–Oligocene mafic bodies and around 0.5 to 1.7 kbar for the Miocene granitoids. Hornblende‐plagioclase thermometry yields relatively low temperatures (661–780 °C), which probably reflect late stage re‐equilibration of these minerals. The assemblage titanite–magnetite–quartz as well as hornblende composition were used to constrain the oxygen fugacity and H₂O content during the crystallization of the parent magmas in the Miocene plutons. The results show that the Miocene granitoids crystallized from magmas with relatively high oxygen fugacity and high H₂O content (~5 wt% H₂O). The Miocene granitoids show similar range of oxygen fugacity, H₂O contents and mineral chemical compositions, which indicate a common source for their magmas. Although the crystallization pressures of the Miocene plutons discriminate various categories of plutonic bodies emplaced at depths of about 5.7–6.5 km (Marfioun pluton), about 4.2 km (Ghalhar pluton) and 1.9–2.3 km (Poudalg pluton), they were later uplifted to the same level by vertical displacement of faults. The emplacement depths of the Niyasar plutons suggest that the central part of the Urumieh‐Dokhtar magmatic belt has experienced an uplift rate of ca. 0.25–0.4 mm/yr from the Miocene onwards.     

南海礼乐盆地礁体水热循环及其对地温场的影响

南海礼乐盆地自渐新世以来持续发育碳酸盐岩礁体,礁体区地温场可能受到礁体与周围低温海水间水热循环的扰动.为了解礁体与周围海水间的热交换过程及其对礁体区地温场的影响,以便从位于礁体区的钻井测温数据中提取深部热信息,本文以过礁体区S-1井的地震剖面为基础,在流热耦合条件下对礁体内的水热活动进行数值模拟.结果表明,礁体与海水间存在水热交换,该水热活动对礁体区温度场有明显的扰动,使得礁体上部温度和地温梯度明显降低,进入礁体下伏地层后,地温梯度逐渐趋于正常;水热循环对礁体区地温场的影响程度与礁体的厚度和渗透率密切相关,礁体厚度越大、渗透率越高,礁体及其下伏地层温度越低;计算剖面中,2100 m厚礁体之下可能存在约400 m厚、渗透率约为3×10^-12 m^2的高渗碎屑岩层,高渗层上覆礁体平均渗透率估计介于1×10^-13~5×10^-12 m^2之间.分析表明,在受水热活动影响的礁体区,礁体下伏地层中的热流可近似代表礁体区的深部热背景,S-1钻井深部热流介于65~75 mW·m^-2之间.     

花岗岩铀地球化学特征新认识——以赣南富城产铀花岗岩体为例

对富城花岗岩U、Th含量分析结果进行的频数统计分析表明富城花岗岩U的均值为8．92×10＾－6、众数为8．0×10＾－6、中位数为7．03×10＾－6,其概率密度曲线偏向高端呈右偏非对称分布（偏度系数CSK＝1．10）。Th的均值、众数和中位数三者一致,分别为25．7×10＾－6,25．75×10＾－6,25．8×10＾－6,其概率密度曲线呈对称正态分布（偏度系数CsK＝0．11）。核诱发裂变径迹研究查明富城花岗岩中铀有4种存在形式：（1）显微粒状铀矿物（晶质铀矿）;（2）以类质同像形式存在于锆石、磷灰石等副矿物之中;（3）均匀分散赋存在造岩矿物晶格之中的结构铀;（4）沿造岩矿物（长石、石英）微裂隙及粒间分布的非结构铀。对富城花岗岩铀配分研究发现,赋存在造岩矿物中均匀分散状的结构铀含量与全岩铀不呈消长关系,而是存在一定的极限值：长石、石英〈3X10＾－6,白云母〈5×10＾－6,黑云母〈9×10＾－6。溶浸实验结果表明,富城花岗岩活动性铀浸出率很高（平均值52％）,为富城花岗岩具有较大铀成矿潜力提供了佐证。     

The nature and petrogenesis of intra-oceanic plate alkaline eruptive and plutonic rocks: King's Trough, Northeast Atlantic

Basalts, diorites, and gabbros dredged from the side of King's Trough — a mid-plate fracture on the northeast Atlantic sea floor — are alkaline in character based on major- and trace-element chemistry and mineralogy. The variation in bulk chemical composition and in mineral paragenesis and composition suggest differentiation in a large magma chamber beneath a seamount volcano. Fractional crystallization took place in a hydrous magma and is characterized by early formation of a Ti-rich biotite as rims on olivine. Thus, pyroxene compositions are unusual in having relatively low molar Ti/Al ratios, and increasing differentiation is marked by progressively decreasing ratios of K to Na.     

地球的化学成因

大量的地球化学资料充分地说明地球和隕星的化学成分属于同一类型.隕星中的隕石相和地壳上的超基性岩石的化学成分很相近似.二者之間的同位素比值,如He~3、C~(13)、S~(34)、Fe~(54)、Fe~(57)、F~(58)、K~(40)等都属于同一数量級.地球起源于隕星的假說有其一定的化学根据. 为了探索地球的成因,我們首先探索隕星的化学成因,第二步再探索地壳的化学成因. 本文采用热力学或物理化学的方法,这些方法在近代文献中多次被指出和試用.     

New challenges for tafoni research. A new approach to understand processes and weathering rates

Cavernous tafoni‐type weathering is a common and conspicuous global feature, creating artistic sculptures, which may be relevant for geochemical budgets. Weathering processes and rates are still a matter of discussion. Field evidence in the type locality Corsica revealed no trend of size variability from the coast to subalpine elevations and the aspect of tafoni seems to be governed primarily by the directions of local fault systems and cleavage, and only subordinately by wind directions or the aspect of insulation. REM analysis of fresh tafone chips confirmed mechanical weathering by the crystallization of salts, as conchoidal fracturing of quartz is observed. The salts are only subordinately provided by sea spray, as calcium and sodium sulfates rather than halite dominate even close to the coast. Characteristic element ratios compare well with aerosols from mixed African and European air masses. Sulfates are largely derived from Sahara dust, indicated by their sulfur isotopic composition. Salt crystals form by capillary rise within the rock and subsequent crystallization in micro‐cracks and at grain boundaries inside rain‐protected overhangs. Siderophile bacteria identified by raster electron microscopy (REM) analysis of tafone debris contribute to accelerated weathering of biotite and tiny sulfide ore minerals. By applying ¹⁰Be‐exposure dating, weathering rates of large mature tafone structures were found to be about an order of magnitude higher than those on the exposed top of the affected granite blocks. Copyright © 2010 John Wiley & Sons, Ltd.     

Thermodynamic modeling of post-entrapment crystallization in igneous phases

Inclusions of quenched silicate liquid in igneous phenocryst phases represent important windows into the pre-eruption chemistry of volcanic rocks. Melt inclusions are subject to a variety of potential modifications after entrapment, which obscure the connection between final inclusion composition, and entrapment conditions. We concentrate on the effects of post-entrapment crystallization (PEC) in the cooling inclusion. PEC is neither an isobaric nor an isochoric process. Pressure decreases between 2 and 27 bars per degree of cooling, depending on the chemistry of melt and host and on the degree of PEC. In the equilibrium case, between about 50% and 65% of this pressure effect is due to thermal expansivity of the liquid, 10–35% from thermal expansivity of the host, and 5–40% from mass transfer between the inclusion and host. This complicates the application of simple element-partitioning schemes for back-calculating the effects of post-entrapment crystallization except in the simplest cases. We present a thermodynamic algorithm for PEC correction. This method is based on the self-consistent thermodynamic model set used in the MELTS software package. The algorithm moves backward through the PEC process, incrementally adding equilibrium crystal composition to the liquid while accounting for consequent variations in pressure and oxygen fugacity. Entrapment conditions are assumed to have been reached when the instantaneous liquidus solid composition most closely matches that of the bulk host crystal. Besides giving information on the degree of PEC and initial inclusion composition, the proposed algorithm can provide constraints on the pressure, temperature and oxygen fugacity at the time of entrapment. Olivine- and orthopyroxene-hosted inclusions from Popocatépetl, Mexico help constrain pre-eruption conditions for mixed magmas from recent eruptive products. Feldspar-hosted inclusions from Satsuma-Iwojima, Japan suggest that these magmas were substantially undersaturated with respect to supercritical vapor phase at the time of entrapment and underwent on the order of 29% post-entrapment crystallization. Quartz-hosted inclusions can potentially be employed in more silicic compositions, but this will require refinement of existing thermodynamic models.     

Magma mingling in the ∼50 ka Rotoiti eruption from Okataina Volcanic Centre: implications for geochemical diversity and chronology of large volume rhyolites

Examination of glass and crystal chemistry in the Rotoiti Pyroclastics (>100 km³ of magma) demonstrates that compositional diversity was produced by mingling of the main rhyolite magma body with small volumes of other magmas that had been crystallizing in separate stagnant magma chambers. Most (>90%) of the Rotoiti deposits were derived from a low-K₂O, cummingtonite-bearing, rhyolitic magma (T1) discharged throughout the eruption sequence. T1 magma is homogeneous in composition (melt SiO₂=77.80±0.28 wt.%), temperature (766±13 °C) and oxygen fugacity (NNO+0.92±0.09). Most T1 phenocrysts formed in a shallow (∼200 MPa), near water-saturated (a_water=0.8) storage chamber shortly before eruption. Basaltic scoria erupted immediately before the rhyolites, and glass-bearing microdiorite inclusions within the rhyolite deposits, suggest that basalt emplaced on the floor of the chamber drove vigorous convection to produce the well-mixed T1 magma. Lithic lag breccias contain melt-bearing biotite granitoid inclusions that are compositionally distinct from T1 magma. The breccias which overlie the voluminous T1 pyroclastic flow deposits resulted from collapse of the syn-Rotoiti caldera. Post-collapse Rotoiti pumices contain T1 magma mingled with another magma (T2) that is characterized by high-K glass and biotite, and was cooler and less oxidised (712±16 °C; NNO−0.16±0.16). The mingled clasts contain bimodal disequilibrium populations of all crystal phases. The granitoid inclusions and the T2 magma are interpreted as derived from high-K magma bodies of varying ages and states of crystallization, which were adjacent to but not part of the large T1 magma body. We demonstrate that these high-K magmas contaminated the erupting T1 magma on a single pumice clast scale. This contamination could explain the reported wide range of zircon U–Th ages in Rotoiti pumices, rather than slow crystallization of a single large magma body.