福建省上杭县罗卜岭斑岩铜钼矿床构造控矿规律研究

罗卜岭铜(钼)矿区位于紫金山矿田的东北部,是与晚中生代花岗闪长斑岩体有关的隐伏斑岩型铜钼矿床;主要斑岩矿体产于绿泥石化-绢英岩化和(弱)钾化-绢英岩化带中,矿石矿物组合为黄铜矿+辉钼矿;少量过渡类型矿体产于高级泥化带中,矿石矿物组合为蓝辉铜矿+铜蓝+辉钼矿。罗卜岭矿区地表露头含矿裂隙的统计结果显示,罗卜岭成矿晚期的含矿裂隙具有明显的方向性。远离斑岩体的含矿裂隙与其附近的区域构造方位或侵入体走向相近,表明受到北东向区域构造活动控制;而斑岩体西侧露头附近的含矿裂隙呈放射状,主要受到斑岩体侵入作用的影响。深部隐伏矿体则受到区域断裂和花岗闪长(斑)岩侵入体的共同控制,具体表现为:垂向上,以隐伏似斑状花岗闪长岩为中心,由深至浅,矿体铜钼品位比值依次变大,显示了Mo\Cu-Mo\Cu(Mo)的元素垂向分带;平面上,铜、钼元素沿着北东向、北西向断裂和岩体接触带附近有明显富集;斑岩型铜钼矿体主要产于似斑状花岗闪长岩外接触带的花岗闪长斑岩中,形态和产状受到区域北东向断裂或岩体接触带构造影响;蓝辉铜矿体主要产于罗卜岭花岗闪长斑岩外接触带的花岗闪长岩体内,形态和产状受接触带控制。区域构造和斑岩侵入体对斑岩型铜钼矿化有不同的影响,浅部铜、钼矿化受区域断裂构造控制作用明显,而深部矿体主要受花岗闪长(斑)岩体和断裂构造共同控制。区域上北东向背斜构造和北东、北西向断裂构造控制了花岗闪长质侵入岩体的侵位,矿区尺度的断裂构造对斑岩体的就位和成矿作用有一定的影响,罗卜岭花岗闪长斑岩体及其接触带则直接控制了斑岩型矿体的产出,这一规律对紫金山矿田深部和外围隐伏斑岩型矿体的勘查工作具有重要的参考意义。     

中甸火山-岩浆弧燕山期热林复式岩体演化 与Ar-Ar 定年及铜钼矿化

产于中甸印支期火山一岩浆弧北东缘的燕山期热林复式岩体,从早至晚边部到中部划分出主期由细粒似斑状二长花岗岩→中粒似斑状二长花岗岩和边部补充期二长花岗斑岩5个侵入体组成的同源岩浆细粒→中粒→斑状结构演化系列.岩体岩石化学、稀土和微量元素总体反映为同熔型花岗岩特征.在复式岩体Ⅱ号侵入体中粒似斑状二长花岗岩中获黑云母Ar-Ar同位素等时年龄81.7±1.1Ma,坪年龄82.01±0.86 Ma,属燕山晚期侵入体.铜钼矿主要产于晚期侵入体中,边部细粒花岗岩和角岩内带具有细脉状黄铜矿、团块状辉钼矿化;中部发生二长花岗(斑)岩热液蚀变充填交代辉钼矿化--辉钼矿石英细脉、中粗晶浸染状;以及沿裂隙发育岩浆期后含矿热液充填交代辉钼矿化,构成燕山期花岗斑岩铜钼成矿亚系列.成因类型:蚀变花岗斑岩、石英脉型和角岩型3种,指示了燕山期二长花岗斑岩类具有较好的铜钼找矿潜力.     

黑龙江省东宁县洋灰洞子铜矿床成矿岩体特征

通过对洋灰洞子铜矿床的成矿岩体进行研究，进一步明确了其成矿地质背景，着重研究与铜钼矿床关系密切的花岗闪长岩体和花岗闪长斑岩体的岩性特征、岩石类型、岩石化学特点、成岩时代、物质来源及侵位方式等，确定了该区花岗闪长岩和花岗闪长斑岩为洋灰洞子斑岩型铜钼矿床的成矿母岩。     

太行山北段赤瓦屋铜钨矿化区花岗质岩石的锆石U-Pb年龄及其地质意义

太行山北段位于华北克拉通中部,以发育中生代中酸性岩浆岩及多个大中型斑岩-矽卡岩铜钼矿床和金矿床为主要特征,最近在南部赤瓦屋岩体内部发现新类型铜钨矿体。文章选择赤瓦屋岩体为对象,开展不同岩相详细的野外地质和锆石U-Pb测年工作,确定赤瓦屋岩体不同岩性的成岩时代,探讨其地质意义。研究表明,赤瓦屋岩体有边缘相石英闪长岩、边缘相花岗闪长岩和中心相斑状花岗闪长岩及晚期中酸性岩脉,其中铜钨矿化主要发育于中心相斑状花岗闪长岩。石英闪长岩、花岗闪长岩、斑状花岗闪长岩和花岗闪长斑岩脉的锆石U-Pb谐和年龄分别为(134±1)Ma、(133±1)Ma、(131±2)Ma和(128±1)Ma,表明赤瓦屋岩体不同岩相体形成于早白垩世(134~131Ma)。结合区域年代学资料,提出太行山北段晚中生代至少存在两期岩浆-成矿事件。     

粤北大宝山矿区船肚岩体和大宝山花岗斑岩锆石LA-ICP-MS U-Pb年龄及多阶段成矿分析

粤北大宝山矿床矿区出露船肚和大宝山矿化岩体。本文分析了两个岩体矿物组成特征和锆石LA-ICP-MS U-Pb年龄。船肚岩体为似斑状结构,块状构造,主要由似斑状花岗岩、似斑状二长花岗岩及似斑状花岗闪长岩等组成,和云英岩型及矽卡岩型Mo-W矿化紧密共生。大宝山岩体为斑状结构,块状构造,主要由碱长花岗斑岩、普通花岗斑岩、二长花岗斑岩及花岗闪长斑岩组成,矿物组成和船肚岩体的基本相同,和细脉浸染状Mo-W矿化紧密共生。船肚似斑状二长花岗岩和大宝山二长花岗斑岩锆石LA-ICP-MS U-Pb年龄分别为162.1±1.6 Ma,MSWD=2.72和165.8±2.0 Ma,MSWD=1.38。据船肚和大宝山岩体矿物组成基本相同、岩石结构不同及两者锆石Th/U比值不同和U-Pb年龄存在约4 Ma左右时差,提出大宝山矿区在燕山期发生了两阶段岩浆成矿事件,第一阶段岩浆成矿事件发生在166 Ma左右,形成大宝山斑岩型矿床,第二阶段岩浆成矿的形成时间约为162 Ma左右,形成船肚似斑状二长花岗岩及与岩体紧密共生的矽卡岩型和云英岩型矿化;大宝山斑岩体和船肚似斑状岩体是同一岩浆房两次脉动侵入形成的。     

河南汝阳东沟超大型钼矿床地质特征及找矿标志

东沟钼矿属斑岩型钼矿床,矿床(体)赋存于下铺花岗斑岩体内外接触带中,沿岩体呈似层状(帽状)分布,钼矿化与岩石中裂隙发育程度关系密切,矿厚一般130～170 m,最大259.62m.主要矿石类型有安山岩型、英安岩型、闪长细晶岩型和花岗斑岩型辉钼矿矿石,矿化蚀变具典型斑岩型矿床的特征,地球化学异常和花岗斑岩体是主要找矿标志.     

西藏尼木县厅宫、白容铜矿区矿床地质的几个问题

近期钻孔资料揭示,西藏尼木县厅宫铜矿区主要为二长花岗(斑)岩、花岗闪长斑岩、钾长花岗(斑)岩和石英闪长玢岩构成的复式斑岩体,白容铜矿区的容矿岩石为花岗闪长斑岩、闪长玢岩,以及正长斑岩、安山玢岩脉;铜(钼)矿化呈面型分布,含矿斑岩体几乎全岩矿化,与围岩接触带附近矿化强度增强;矿化垂向厚度达数百米,强弱不均,自上而下可分为氧化带、过渡带、原生带;硅化、绢云母化、高岭土化、黄铁矿化等蚀变广泛而强烈.     

西准包古图呼的合铜矿地质特征、成因及成矿规律研究

新疆西准包古图矿区呼的合铜矿位于巴尔喀什华力西期斑岩成矿带.大地构造位置属哈萨克斯坦-准噶尔板块,唐巴勒-卡拉麦里古生代复合沟孤带,包古图岛弧区.矿床处于达尔布特和克乌深大断裂间,次级NS向与NE向断裂交汇处.Ⅴ号岩体属深源、浅成中酸性复合相岩体.含矿岩石以中粗粒、斑状、似斑状结构的石英闪长岩、花岗闪长斑岩为主,次有花岗闪长岩、花岗斑岩、黑云母花岗闪长岩等,形成时间为320~300 Ma,岩石蚀变强烈,蚀变分带自岩体中心向外构成钾长石和粒状石英核-钾化带-绢英化带-青盤岩化带.金属矿物组合自岩体中心向外变化规律为:(黄铁矿-辉钼矿-黄铜矿)→(黄铁矿-黄铜矿-闪锌矿-辉钼矿)→(黄铁矿-黄铜矿-毒砂-Te-Bi-Ag-Au的矿物).有益元素主要为铜、钼、金、银等元素,矿石类型自岩体中心向外的变化规律为:Mo(Cu)→Cu(Mo)→Cu(Au)→Au.矿石构造为细粒浸染状和细脉浸染状.矿石品位低、矿化均匀,成矿物质主要来自与其共生的岩浆岩,属典型斑岩型铜矿.构造、岩石、蚀变、矿物、及成矿元素在空间、时间上变化规律较强,与矿化富集有密切联系.     

内蒙古八大关斑岩型铜钼矿床成岩成矿年代学研究

八大关斑岩铜钼矿床是中国内蒙大兴安岭地区典型的斑岩型铜钼矿床之一。对矿区Ⅱ号岩体不同位置的2件岩石样品采用高精度的LA_ICP_MS锆石U_Pb测年,获得的锆石U_Pb年龄分别为(230.6±2.8)Ma和(230.5±4.4)Ma,两者在误差范围内非常一致,由此确认花岗闪长斑岩体的形成年龄约为230 Ma;对矿区7件辉钼矿样品采用Re_Os同位素测年,获得的Re_Os等时线年龄为(228.7±3.1)Ma,指示了八大关铜钼矿床辉钼矿的沉淀时间约为228.7 Ma。结合矿区岩相学、矿物学特征,辉钼矿呈浸染状分布于花岗闪长斑岩体内,且辉钼矿与黄铜矿密切共生,以及上述2种精确方法获得的年龄在误差范围内的一致性,说明花岗闪长斑岩即为成矿岩体,成岩与成矿大致同时或成矿略晚于成岩,表明八大关铜钼矿床形成于中三叠世,属于印支期成矿。     

青海省卡尔却卡铜多金属矿床A区斑岩型和B区矽卡岩型成矿岩体特征对比

青海省卡尔却卡铜多金属矿兼有斑岩-矽卡岩-热液系列的成矿特征,分A、B、C 3个区。其中A区主要为斑岩型成矿,B区为矽卡岩型矿化。铜多金属矿体主要产于花岗闪长岩、似斑状黑云母二长花岗岩体与寒武—奥陶纪滩间山群接触部位的矽卡岩带及似斑状二长花岗岩的斑岩矿化带中。笔者通过成矿岩体的岩石矿物组合和岩石地球化学特征对比,认为卡尔却卡B区的似斑状二长花岗岩的矽卡岩化成矿作用为早期的加里东俯冲碰撞阶段的产物。卡尔却卡矿区A区似斑状二长花岗岩的斑岩成矿作用和B区的花岗闪长岩矽卡岩成矿作用均是印支期晚期晚三叠世的大规模俯冲碰撞造山阶段的产物,构成了一个典型的斑岩型矿床成矿系统,叠加在早期的加里东期成矿作用上,形成了较大型的铜钼矿床。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。