生态型水源水体生态净化及其影响因素

水库水体污染控制及富营养化防治是保障城市原水供应安全的重要环节.本研究针对金泽水源水库太浦河来水氮、磷浓度较高的特点,自行设计建设了5个面积均为240 m~2的生态净化模拟试验池(A、B、C、D和对照)开展模拟试验,研究了不同水库形态、水生植物种植面积比例及种植方式对水体氮、磷污染物去除的影响.结果表明,通过模拟试验池的生态净化,原水中铵态氮(NH_4~+-N)、总磷(TP)和总氮(TN)的平均去除率分别为50.36%、53.73%和22.25%,C池TN和NH_4~+-N去除率最高分别达到了24.97%和54.61%,D池TP去除率最高,达到62.16%,水体溶解氧(DO)平均浓度提高了1.11 mg/L,平均透明度提高了27.6 cm,均显著高于对照池.水库形态结构、水生植物面积比例及种植方式对水体氮、磷污染物净化效果影响明显,增大水库浅水区面积能有效提高对水体氮、磷污染物的去除能力,增加水生植物种植面积能有效提高水体氮污染物去除和DO、透明度的提升能力,采用浮床种植方式能有效提高水体磷污染物去除和透明度提升能力.本研究结果能为金泽水源水库及其他类似水库的设计和建设提供科学依据.     

Hydrograph separation to improve understanding of Dissolved Organic Carbon Dynamics in Headwater catchments

Dissolved organic carbon (DOC) is a key component of the global carbon cycle, but, to date, large uncertainties still exist on its source and fate in first‐order streams. In a 23 ha rangeland and steep‐slope headwater of South Africa, our aim was to quantify the contribution of overland flow (OF), soil water (SW) and ground water (GW) to DOC fluxes (DOC_F), and to interpret the results in terms of DOC sources and fate. The average 2010–2011 DOC concentration (DOC_C) at the catchment outlet was 4.7 mg C l^?1 with a standard error of ±2.5 mg C l^?1, which was significantly lower than in SW (15.2 ± 1.6 mg C l^?1) and OF (11.9 ± 0.8 mg C l^?1), but higher than in GW (2.3 ± 0.6 mg C l^?1). Based on end‐member mixing using Si and Na concentration in the water compartments, the average SW contribution to DOC_F was 66.4%, followed by OF (30.0%) and GW (3.6%). The resulting estimated DOC_F at the catchment outlet was 8.05 g C m² y^?1. This was much higher than the observed value of 2.80 g C m² y^?1, meaning that 5.25 g C m² y^?1 or 65% of the DOC is lost during its downslope and/or downstream transport to the catchment outlet. Complementary investigations revealed that the DOC_C in SW dropped from 15.2 ± 1.6 to 2.6 ± 0.3 mg C l^?1 during its downslope transport to the river system, which corresponded to a net loss of 5.10 g C m² y^?1, or 97% of the catchment DOC losses. These results on DOC sources and potential fate in headwaters are expected to improve our understanding of the impact of hydrology on the global C‐cycle. Copyright © 2013 John Wiley & Sons, Ltd.     

Nested‐Scale Nutrient Flux in a Mixed‐Land‐Use Urbanizing Watershed

To improve quantitative understanding of mixed‐land‐use impacts on nutrient yields, a nested‐scale experimental watershed study design (n = 5) was applied in a 303(d), clean water act impaired urbanizing watershed of the lower Missouri River Basin, USA. From 2010 to 2013, water samples (n = 858 sample days per site) were analysed for total inorganic nitrogen (TIN‐N), nitrite (NO₂–N) nitrate (NO₃–N), ammonia (NH₃–N), and total phosphorus (TP‐P). Annual, seasonal, and monthly flow‐weighted concentrations (FWCs) and nutrient yields were estimated. Mean nutrient concentrations were highest where agricultural land use comprised 58% of the drainage area (NH₃ = 0.111 mg/l; NO₂ = 0.045 mg/l; NO₃ = 0.684 mg/l, TIN = 0.840 mg/l; TP = 0.127 mg/l). Average TP‐P increased by 15% with 20% increased urban land use area. Highly variable annual precipitation was observed during the study with highest nutrient yields during 2010 (record setting wet year) and lowest nutrient yields during 2012 (extreme drought year). Annual TIN‐N and TP‐P yields exceeded 10.3 and 2.04 kg ha^?1 yr^?1 from the agricultural dominated headwaters. Mean annual NH₃–N, NO₂–N, NO₃–N, TIN‐N, and TP‐P yields were 0.742, 0.400, 4.24, 5.38, and 0.979 kg ha^?1 yr^?1, respectively near the watershed outlet. Precipitation accounted for the majority of the explained variance in nutrient yields (R² values from 0.68 to 0.85). Nutrient yields were also dependent on annual precipitation of the preceding year (R² values from 0.87 to 0.91) thus enforcing the great complexity of variable mixed‐land‐use mediated source‐sink nutrient yield relationships. Study results better inform land managers and best management practices designed to mitigate nutrient pollution issues in mixed‐land‐use freshwater ecosystems. Copyright © 2015 John Wiley & Sons, Ltd.     

Biofiltration of Pyridine by Shewanella putrefaciens in a Corn‐Cob Packed Biotrickling Filter

In this study, a new strain of microorganism Shewanella putrefaciens was used for biofiltration of a pyridine laden air stream in a corn‐cob packed biotrickling filter. In the biotrickling filter tested with S. putrefaciens, the maximum removal of pyridine is determined to be 100% at less than the average inlet concentration of 0.653 g m^–3 and more than 93% at a higher average inlet concentration of 1.748 g m^–3 (phase VIII) with an empty bed residence time (EBRT) of 106 s. However, when the biotrickling filter was operated at a low EBRT of 53 s and almost the same average inlet concentration of 1.752 g m^–3 (phase VII), the removal level attained was not greater than 85%. The maximum elimination capacity (EC) of the biotrickling filter was 102.34 g m^–3h^–1 at an inlet pyridine load of 119.62 g m^–3h^–1 with an EBRT of 53 s in phase VII. The maximum deviation of the EC from the 100% conversion line varied from 0.257 to 10.166% when going from phase I to VIII. Kinetic analysis showed that the maximum removal rate, r_max, and saturation constant, K_s, values for pyridine were calculated as 0.24 g m^–3h^–1 and 6.44 g m^–3, respectively, with a correlation coefficient, R², of 0.9939 and a standard deviation of error of 23.94%. The information contained herein indicates that the corn‐cob packed biotrickling filter inoculated by S. putrefaciens should provide excellent performance in the removal of gaseous pyridine.     

冷季不同植物人工湿地处理生活污水的工程实例分析

本实验以亚热带地区福建省永春县农村生活污水作为处理对象,选取10种湿地植物,构建具有不同植物类型的表面流人工湿地的实例工程,比较不同植物配置人工湿地的处理能力,以及湿地植物的生物量和植物体内氮、磷累积能力.研究结果表明,水龙和美人蕉人工湿地具有较高的铵态氮去除能力,去除率可分别达到76.7%和87.7%;两者同时也对总氮表现出较好的去除效果,尤其是美人蕉人工湿地在冬季节对总氮的去除率可维持在80.3%以上;2014年初冬季节实验结果表明,水龙还具有一定的总磷去除能力,去除率可达到69.0%.水龙和美人蕉具有较大的生物量,其单位面积干重可分别达到0.46和0.30 kg/m~2,又能较好地积累氮、磷元素,其体内氮含量可分别达到6.43和4.60 g/m~2,磷含量可分别达到0.50和1.01 g/m~2.综上所述,种植水龙和美人蕉的人工湿地总体处理效果较好,同时又能更多地积累氮、磷元素,且具有更大的生物量,可选为相对适宜用于处理生活污水的适合亚热带地区应用的人工湿地植物.     

Treatment of Synthetic Olefin Plant Wastewater at Various Salt Concentrations in a Membrane Bioreactor

The objective of this study was to investigate the effect of salt concentration on performance of a membrane bioreactor (MBR) for treating an olefin plant wastewater. For this purpose, a lab‐scale submerged MBR with a flat‐sheet ultrafiltration membrane was used for treatment of synthetic wastewater according to oxidation and neutralization unit of olefin plant. The synthetic wastewater was adjusted to have 500 mg/L chemical oxygen demand (COD). Trials on different concentrations of sodium sulfate (Na₂SO₄) (0–20 000 ppm) in the feed were conducted under aerobic conditions in the MBR. The results showed that increasing the salt concentrations causes an increase in the effluent COD, phenol, and oil concentrations. These results are due to reduction of the membrane filtration efficiency and also decline in the microbial activity that it is indicated by decreasing the sOUR in MBR. But in all the trials, the effluent COD and oil concentration was well within the local discharge limit of 100 and 10 mg/L, respectively. These results indicate that the MBR system is highly efficient for treating the olefin plant wastewater, and although high salt concentrations decreased organic contaminant removal rates in the MBR, the effluent still met the discharge limits for treating the olefin plant wastewater.     

Removal of Hydrogen Sulfide by Physico‐Biological Filter Using Mixed Rice Husk Silica and Dried Activated Sludge

This study investigated the effectiveness of a new packing material, namely mixed rice husk silica with dried activated sludge for removing H₂S. Dried sewage sludge was collected from Putrajaya sewage treatment plant in Malaysia. Rice husk silica was prepared at temperature of 800°C, after acid leaching and mixed with dried sewage sludge to be utilized in a polyvinyl chloride filter. The system was operated under variable conditions of two parameters, different inlet gas concentration and different inlet flow rate. H₂S was passed through the filter with one liter of the packing material. More than 99.96% removal efficiency (RE) with empty bed residence time (EBRT) of 90–45 s and 300 ppm inlet concentration was observed. However, the RE decreased to 96.87% with the EBRT of 30 s. The maximum elimination capacity (EC) of 52.32 g/m³/h was obtained with the RE of 96.87% and H₂S mass loading rate of 54 g/m³/h, while at the RE of 99.96%, maximum EC was 26.99 g/m³/h with the H₂S mass‐loading rate of 27 g/m³/h. A strong significant correlation between increasing of H₂S mass loading rate and pressure drop was also detected (p < 0.01). Maximum pressure drop was 3.0 mm H₂O after 53 days of operating time, the EBRT of 30 s, and 54 g/m³/h of H₂S loading rate. These observations suggest that the mixture of rice husk silica with dried activated sludge is a suitable physico‐biological filter for H₂S removal.     

Studies on Adsorptive Desulfurization by Activated Carbon

Sulfur removal using adsorption requires a proper process parametric study to determine its optimal performance characteristics. In this study, response surface methodology was employed for sulfur removal from model oil (dibenzothiophene; DBT dissolved in iso‐octane) using commercial activated carbon (CAC) as an adsorbent. Experiments were carried out as per central composite design with four input parameters such as initial concentration (C₀: 100–900 mg/L), adsorbent dosage (m: 2–22 g/L), time of adsorption (t: 15–735 min), and temperature (T: 10–50°C). Regression analysis showed good fit of the experimental data to the second‐order polynomial model with coefficient of determination R²‐value of 0.9390 and Fisher F‐value of 16.5. The highest removal of sulfur by CAC was obtained with m = 20 g/L, t = 6 h, and T = 30°C.     

Removal of the Alphazurine FG Dye from Simulated Solution by Electrocoagulation

The removal of Alphazurine FG (AF) dye from water by an electrocoagulation process has been studied. The effect of some operational parameters, such as anode material, current density, initial dye concentration, pH of solution, conductivity, and inter‐electrode distance, on the removal efficiency was investigated. Iron and aluminum were used as anodes in the electrocoagulation cell. It was found that the efficiency of the iron anode was better than that of the aluminum anode for AF removal. The factors that affected the removal efficiency were the current density and the initial dye concentration. The removal efficiency increased from about 35% at 25 A m^–2 to about 97% at 100 A m^–2, during 4 min of electrocoagulation. The results exhibited pseudo‐first‐order kinetics for AF removal by electrocoagulation. In addition, a mathematical model was successfully established for predicting the removal efficiency. A comparison between the model results and experimental data gave a high correlation coefficient (R² = 0.9925), which indicates that the model is able to predict the removal efficiency of AF.     

微型生态系统中鲢、鳙下行影响的实验研究——2.营养物水平

链、镛放养使微型生态系统的水柱氮、磷浓度和磷的分布发生了明显的变化。至实验结束时,各实验组的水柱颗粒磷、总磷和氨氮浓度都比对照组高,而正磷酸盐浓试和沉积物磷的量均低于对照组。这种变化以鳙单养系统为最大,其次是链、镛混养系统,链单养系统的变化最小。微型生态系统中正磷酸盐浓度同浮游动、植物密度和初级生产力显著相关,氨氮浓度同所述变量之间的相关关系则多半与正磷酸盐相反。实验观测期间浮游植物密度与总磷浓度     

Growing Spirodela polyrrhiza in Swine Wastewater for the Production of Animal Feed and Fuel Ethanol: A Pilot Study

To evaluate the performance of Spirodela polyrrhiza grown in swine wastewater for protein and starch production under field conditions, a pilot‐scale duckweed culture pond was installed at Barham Farm, Zebulon, North Carolina and operated from May to November 2010. The anaerobically treated swine wastewater was fed to the duckweed pond intermittently to provide nutrients for the growth of duckweed, and the duckweed biomass was harvested regularly from the pond and prepared as a protein‐ or starch‐rich feedstock for the production of animal feed or fuel ethanol. Over the experimental period, the duckweed pond produced protein and starch at rates of 2.68 and 1.88 g m^?2 day^?1, respectively. During the same time, NH₄–N and o‐PO₄–P in the wastewater were, respectively, removed at rates of 92.9 and 2.90 mmol m^?2 day^?1.     

Changes in carbon and nutrient fluxes from headwaters to ocean in a mountainous temperate to subtropical basin

Water erosion provides major links in global cycles of carbon (C), nitrogen (N) and phosphorus (P). Although significant research on erosion mechanisms has been done, there is still little knowledge on C, N and P fluxes across landscapes to the ocean and their controlling factors in subtropical climates. A four‐year study quantifying and comparing particulate and dissolved C, N and P from multiple scales (microplot, plot, microcatchment, subcatchment, catchment, sub‐basin and basin) was performed in Thukela basin (≈30 000 km²), South Africa. The basin climate was largely subtropical‐humid [mean annual precipitation (MAP) > 980 mm yr^‐1], but temperate (MAP >2000 mm yr^‐1) on the highlands. Open grassland, cropland and bushland were the major land uses. On average, 65, 24 and 4 g m^‐2 yr^‐1 C, N and P were displaced from original topsoil positions, but only 0.33, 0.005 and 0.002 mg m^‐2 yr^‐1 were, respectively, exported to the ocean. The fluxes decreased by 95, 97 and 84%, respectively, from plot to microcatchment outlet; and decreased further in downstream direction by >99% from microcatchment to basin outlet. The hillslope (microplot to microcatchment) fluxes correlated strongly with rainfall parameters. Particulate contributions dominated hillslope fluxes at 73, 81 and 76% of total annual C, N and P, respectively. Although particulate C dominated in the microcatchment‐catchment reach (55%), N (54%) and P (69%) were dominated by dissolved forms. The lower basin zone was dominated by dissolved flux contributions at 93, 81 and 78% for C, N and P for the sub‐basin outlet. These results suggested spatially varying drivers of C, N and P losses from the landscape to the ocean, via the river network. Deposition was envisaged the dominant hillslope level loss process, which gradually gave way to mineralization and biotic uptake in the river network as flux contributions shifted from being predominantly particulate to dissolved forms. Copyright © 2017 John Wiley & Sons, Ltd.     

Sediment concentrations in run‐off varying with spatial scale in an agricultural subwatershed of the Chinese Loess Plateau

Information is scarce on the spatial‐scale effect on sediment concentrations in run‐off. This study addressed this issue within an agricultural subwatershed of the Chinese Loess Plateau, using data observed at a hilltop plot, three nested hillslope plots, two entire‐slope plots (a combination of hillslope and valley side slope) and the subwatershed outlet. Dominated by the splash and sheet erosions, the hilltop plot has a minimum C_ae (mean sediment concentration for all recorded events) of 45 kg m^?3. Unexpectedly, the high sediment concentrations at the hilltop do not occur at high rainfall intensities or large run‐off events because of the protection of surface soils by relatively thick sheet flows. Because of the emergence of rills, C_ae is as high as 310 kg m^?3 even on the most upper hillslope. Downslope, both C_ae and ESC (extreme large values of recorded sediment concentrations) increase; such a slope length effect attenuates with increasing slope length and event magnitude as a result of insufficient sediment availability associated with rill development. Active mass wastings ensure sufficient sediment supply and thus a spatially invariant C_ae (approximately 700 kg m^?3) and ESC (approximately 1000 kg m^?3) at the scale of the entire slope and subwatershed. Detailed examination shows that most small events experience a decrease in sediment concentrations when moving from the entire slope to the subwatershed, indicating that the spatially invariant sediment concentration is valid only for large run‐off events. This study highlights the control of the spatial scale, which determines the dominant erosional process, on erosional regime. Copyright © 2015 John Wiley & Sons, Ltd.     

Beach–dune sediment budgets and dune morphodynamics following coastal dune restoration,Wickaninnish Dunes,Canada

The results from three years of surveying and monitoring a dynamic foredune and dunefield restoration effort on Vancouver Island, Canada is presented. Complete removal of foredune vegetation occurred in three phases spaced a year apart in an effort to control invasive Ammophila spp. The collection of airborne LiDAR, orthophotographs, and bi‐monthly topographic surveys provided a means to quantify and examine sediment budgets and geomorphic responses. Three survey swaths, corresponding with each phase of vegetation removal, were established to provide detailed topographic coverage over the impacted beach, foredune, and dunefield landscape units. The swath corresponding with the first phase of removal recorded a positive sediment budget of 1·3 m³ m^?2 after three years. A control swath, with data collected for a year prior and two years following removal, exhibited a distinct pulse of sediment delivery into the dunefield unit with a maximum gain of 0·03 m³ m^?2 pre‐removal compared to 0·11 m³ m^?2 post‐removal. Vegetation analysis zones, associated with each of the three swaths, demonstrate a range of vegetation responses due to variation in the vegetation removal and subsequent re‐invasion or removal methods employed. The first site to be cleared of vegetation, received ongoing invasive re‐growth control, and three years following removal vegetation cover dropped from 57% in 2009 to 13% in 2012 (?44%). An adjacent site was cleared of vegetation two years later (only one year of recovery) but experienced rapid Ammophila re‐invasion and percent cover changed from 61% in 2009 to 26% in 2012 (?35%). The data presented provides insights for improving the application of sediment budget monitoring in dynamic restorations and discusses the potential for detailed spatial–temporal survey data to improve our understanding of meso‐scale landscape morphodynamics following foredune disturbance. Overall, the vegetation removal treatments reduced the extent of invasive grass and increased dunefield mobility and dynamic activity. Copyright © 2016 John Wiley & Sons, Ltd.     

Adsorption of Cadmium Ions from Aqueous Solution Using Granular Activated Carbon and Activated Clay

The present study was aimed at removing cadmium ions from aqueous solution through batch studies using adsorbents, such as, granular activated carbon (GAC) and activated clay (A‐clay). GAC was of commercial grade where as the A‐clay was prepared by acid treatment of clay with 1 mol/L of H₂SO₄. Bulk densities of A‐clay and GAC were 1132 and 599 kg/m³, respectively. The surface areas were 358 m²/g for GAC and 90 m²/g for A‐clay. The adsorption studies were carried out to optimize the process parameters, such as, pH, adsorbent dosage, and contact time. The results obtained were analyzed for kinetics and adsorption isotherm studies. The pH value was optimized at pH 6 giving maximum Cd removal of 84 and 75.2% with GAC and A‐clay, respectively. The adsorbent dosage was optimized and was found to be 5 g/L for GAC and 10 g/L for A‐clay. Batch adsorption studies were carried out with initial adsorbate (Cd) concentration of 100 mg/L and adsorbent dosage of 10 g/L at pH 6. The optimum contact time was found to be 5 h for both the adsorbents. Kinetic studies showed Cd removal a pseudo second order process. The isotherm studies revealed Langmuir isotherm to better fit the data than Freundlich isotherm.     

Influence of grass soil cover on water runoff and soil detachment under rainfall simulation in a sub‐humid South African degraded rangeland

In most regions of the world overgrazing plays a major role in land degradation and thus creates a major threat to natural ecosystems. Several feedbacks exist between overgrazing, vegetation, soil infiltration by water and soil erosion that need to be better understood. In this study of a sub‐humid overgrazed rangeland in South Africa, the main objective was to evaluate the impact of grass cover on soil infiltration by water and soil detachment. Artificial rains of 30 and 60 mm h^?1 were applied for 30 min on 1 m² micro‐plots showing similar sandy‐loam Acrisols with different proportions of soil surface coverage by grass (Class A: 75–100%; B: 75–50%; C: 50–25%; D: 25–5%; E: 5–0% with an outcropping A horizon; F: 0% with an outcropping B horizon) to evaluate pre‐runoff rainfall (Pr), steady state water infiltration (I), sediment concentration (SC) and soil losses (SL). Whatever the class of vegetal cover and the rainfall intensity, with the exception of two plots probably affected by biological activity, I decreased regularly to a steady rate <2 mm h^?1 after 15 min rain. There was no significant correlation between I and Pr with vegetal cover. The average SC computed from the two rains increased from 0·16 g L^?1 (class A) to 48·5 g L^?1 (class F) while SL was varied between 4 g m^?2 h^?1 for A and 1883 g m^?2 h^?1 for F. SL increased significantly with decreasing vegetal cover with an exponential increase while the removal of the A horizon increased SC and SL by a factor of 4. The results support the belief that soil vegetation cover and overgrazing plays a major role in soil infiltration by water but also suggest that the interrill erosion process is self‐increasing. Abandoned cultivated lands and animal preferred pathways are more vulnerable to erosive processes than simply overgrazed rangelands. Copyright © 2011 John Wiley & Sons, Ltd.     

Reduction of Ammonia,Hydrogen Sulfide,and Short‐Chain Fatty Acids Emission during the Sewage Sludge Composting

The effect of mature compost (MC) used as a bulking agent on ammonia, hydrogen sulfide, and short‐chain fatty acids emission reduction during sewage sludge (SS) composting process was studied in this paper. Three types of mixtures, single SS, SS + wood chips (SS + WC), and SS + MC, were composted in a laboratory reactor. Among the different treatments, decrement rates of NH₃ emission (based on initial TN) from SS to SS + MC and SS + WC to SS + MC were 63 and 59%, respectively. The H₂S concentration ranged from 0.759 to 1.140 mg m^?3 for SS, from 0.075 to 0.455 mg m^?3 for SS + WC, and from 0.075 to 0.425 mg m^?3 for SS + MC and the short‐chain fatty acids (C₂–C₅) concentration ranged from 0.10 to 1.00 ppm for SS, from 0.10 to 1.50 ppm for SS + WC, and from 0.10 to 0.80 ppm for SS + MC. In addition, the temperature apparently, as well as the thermophilic stage, was also elevated by bulking agent addition, especially by the MC addition. The denaturing gradient gel electrophoresis analysis indicated that there was more diversity of the bacterial community during the SS + MC process. According to these results, MC was a suitable bulking agent for reduction ammonia, hydrogen sulfide, and short‐chain fatty acids emission during the SS composting.     

Yukon River Basin long‐term (1977–2006) hydrologic and climatic analysis

In this study, long‐term discharge data and climate records, such as temperature and precipitation during 1977–2006, have been used to define basin climatic and hydrologic regimes and changes. Discharge analyses at four key gauging stations (Eagle, Stevens Village, Nenana, and Pilot Station) in the Yukon River Basin show that the runoff in the cold season (November to April) is low with small variations, whereas it is high (28 500–177 000 ft³/s; 810–5000 m³/s) with high fluctuations in the warm season (May to October). The Stevens Village Station is in the upper basin and has similar changes with the flow near basin outlet. Flow increases in May (61 074 ft³/s; 1729 m³/s) and September (23 325 ft³/s; 660 m³/s); and decreases in July (35 174 ft³/s; 996 m³/s) and August (6809 ft³/s; 193 m³/s). Discharge in May at the Pilot Station (near the basin outlet) shows a positive trend (177 000 ft³/s; 5010 m³/s). Daily flow analyses show high fluctuation during the warm season and very low flow during the cold season; the 10‐year average analyses of daily flow at Pilot Station show a small increase in the peak and its timing shifted to a little earlier date. The annual flow, average of 227 900 ft³/s (6450 m³/s) with high inter‐annual fluctuations, has increased by 18 200 ft³/s (or 8%; 520 m³/s) during 1977–2006. From 1977 to 2006, basin air temperature in June has increased by 3.9 °F (2.2 °C) and decreased by 10.5 °F (5.8 °C) in January. A strong and positive correlation exists between air temperature in April and discharge in May, whereas a strong and negative correlation relates August temperature and September discharge. Negative trend during 1977–2006 is observed for precipitation in June (0.6 in.; 15 mm) with a confidence over 93%. Precipitation in August and September has strong and positive correlations with discharge in September and October at basin outlet; the precipitation in other months has weak correlation with the discharge. The mean annual precipitation during 1977–2006 increased by 1.1 in. (or 8%; 28 mm), which contributes to the annual flow increase during the study period. Copyright © 2012 John Wiley & Sons, Ltd.     

CONTRIBUTION OF NITROGEN SPECIES AND PHOSPHORUS FRACTIONS TO STREAM WATER QUALITY IN AGRICULTURAL CATCHMENTS

The contribution from agricultural catchments to stream nitrogen and phosphorus concentrations was assessed by evaluation of the chemical composition of these nutrients in agricultural runoff for both surface and subsurface flow pathways. A range of land uses (grazed and ungrazed grassland, cereals, roots) in intensive agricultural systems was studied at scales from hillslope plots (0.5 m²) to large catchment (>300 km²). By fractionating the total nutrient load it was possible to establish that most of the phosphorus was transported in the unreactive (particulate and organic) fraction via surface runoff. This was true regardless of the scale of measurement. The form of the nitrogen load varied with land use and grazing intensity. High loads of dissolved inorganic nitrogen (with >90% transported as NH₄-N) were recorded in surface runoff from heavily grazed land. In subsurface flow from small (2 km²) subcatchments and in larger (>300 km²) catchments, organic nitrogen was found to be an important secondary constituent of the total nitrogen load, comprising 40% of the total annual load.     

曝气充氧对城市污染河道内源铵态氮释放的控制

以城市污染河道沉积物和上覆水为研究对象,利用模拟实验方法,探讨不同曝气充氧方式(水曝气EW、底泥曝气ES)对污染河道內源铵态氮(NH4+-N)释放的影响.研究结果发现:从间隙水和沉积物中NH4+-N的削减效果来看,底泥曝气均要优于水曝气;实验结束后,底泥曝气组沉积物与间隙水中NH4+-N含量分别减少63.39%和43.33%,水曝气组分别减少了7.54%和13.98%;从沉积物-水界面NH4+-N的扩散通量变化来看,水曝气组界面通量高于对照组,其变化规律与对照组相似;底泥曝气组沉积物-水界面NH4+-N扩散通量变化过程完全不同于其它两组,在整个试验周期内(除第5 d以外),底泥曝气组的通量低于水曝气组,在第15 d最低,为13.73 mg/(m2.d),仅为水曝气组和对照组的14.68%和19.93%,表明底泥曝气组沉积物NH4+-N的释放潜力低于水曝气组沉积物.