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1.
《Chemie der Erde / Geochemistry》2014,74(4):577-584
The Alvand plutonic complex consists of gabbroic and felsic rocks, the latter can be divided into (1) porphyritic, fine-grained and mylonitic granites and (2) leucocratic granitoids. We investigated the external zircon morphology and their internal structures from all major granitoids of the pluton employing the classic Pupin method supplemented by electron microscope analyses. Zircons of gabbroic rocks are free of visible cores or inclusions and are commonly characterized by {1 0 1} pyramids and {1 0 0} prisms and show mainly zircon types P5 and D typical for mantel-derived rocks. The zircon population from the porphyritic granite is characterized by the predominance of the pyramidal {2 1 1} and prism {1 1 0} forms and mainly composed of the subtypes S1, S2, S6 and S7 typical for peraluminous granites of crustal origin. Melt inclusions, recrystallization patches and low-CL intensity rims are typical features in these grains. Zircons from the fine-grained granites are characterized by the predominance of the pyramidal {2 1 1} and the prism face {1 1 0} and by a preponderance of the subtypes S3, S4, S7 and especially S12 and occasionally S2, L2, L3 and L4, typical for aluminous monzogranites and granodiorites of crustal origin. Some grains have pre-magmatic inherited domains with overgrow rims. The mylonitized granites contain zircons with {1 0 1} pyramids and {1 1 0} prisms and include subtypes G1, P1, P2, S5 whereas P3, S4, L5 are rarely present, typical for I-type granites. Metamictization, radial cracks and partial overgrowths are prevalent in these zircons. Zircons from the leucocratic granitoids have well-developed magmatic oscillatory zonation and pre-magmatic zircon cores. They are characterized by {1 0 1} pyramids and {1 1 0} prisms and are mainly composed of subtypes L5, S5, S10 and rarely P1, P2, S2, S3, S4, S7, G1 typical for hybrid calc-alkaline granites. 相似文献
2.
The solubility of pentatungstate of sodium (PTS) Na2W5O16 · H2O and sodium tungsten bronzes (STB) Na0.16WO3 in acid chloride solutions containing 0.026, 0.26, and 3.02m NaCl have been studied at 500°C, 1000 bar, given fO2 (Co-CoO, Ni-NiO, PTS-STB buffers), and constant NaCl/HCl ratio (Ta2O5-Na2Ta4O11 buffer). Depending on experimental conditions, the tungsten content in the solutions after experiments varied from 10−3 to 2 × 10−2 mol/kg H2O. Obtained data were used to calculate the formation constants of predominant tungsten complexes (VI, V): H3W3VIO123−, W3VO93−, [WVW4VIO16]3−, for reactions
$
\begin{gathered}
3H_2 WO_4^0 \leftrightarrow H_3 W_3 O_{12}^{3 - } + 3H^ + \log K_p = - 7.5 \pm 0.1, \hfill \\
3H_2 WO_4^0 \leftrightarrow W_3 O_9^{3 - } + 1.5H_2 O + 3H^ + + 0.75O_2 \log K_p = - 25.7 \pm 0.2, \hfill \\
5H_2 WO_4^0 \leftrightarrow \left[ {W^V W_4^{VI} O_{16} } \right]^{3 - } + 3H^ + + 3.5H_2 O + 0.25O_2 \log K_p = - 4.6 \pm 0.1 \hfill \\
\end{gathered}
$
\begin{gathered}
3H_2 WO_4^0 \leftrightarrow H_3 W_3 O_{12}^{3 - } + 3H^ + \log K_p = - 7.5 \pm 0.1, \hfill \\
3H_2 WO_4^0 \leftrightarrow W_3 O_9^{3 - } + 1.5H_2 O + 3H^ + + 0.75O_2 \log K_p = - 25.7 \pm 0.2, \hfill \\
5H_2 WO_4^0 \leftrightarrow \left[ {W^V W_4^{VI} O_{16} } \right]^{3 - } + 3H^ + + 3.5H_2 O + 0.25O_2 \log K_p = - 4.6 \pm 0.1 \hfill \\
\end{gathered}
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3.
Synthetic spinel harzburgite and lherzolite assemblages were equilibrated between 1040 and 1300° C and 0.3 to 2.7 GPa, under
controlled oxygen fugacity (f
O
2). f
O
2 was buffered with conventional and open double-capsule techniques, using the Fe−FeO, WC-WO2-C, Ni−NiO, and Fe3O4−Fe2O3 buffers, and graphite, olivine, and PdAg alloys as sample containers. Experiments were carried out in a piston-cylinder apparatus
under fluid-excess conditions. Within the P-T-X range of the experiments, the redox ratio Fe3+/ΣFe in spinel is a linear function of f
O
2 (0.02 at IW, 0.1 at WCO, 0.25 at NNO, and 0.75 at MH). It is independent of temperature at given Δlog(f
O
2), but decreases slightly with increasing Cr content in spinel. The Fe3+/ΣFe ratio falls with increasing pressure at given Δlog(f
O
2), consistent with a pressure correction based on partial molar volume data. At a specific temperature, degree of melting
and bulk composition, the Cr/(Cr+Al) ratio of a spinel rises with increasing f
O
2. A linear least-squares fit to the experimental data gives the semi-empirical oxygen barometer in terms of divergence from
the fayalite-magnetite-quartz (FMQ) buffer:
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