再生水干湿交替回灌过程氮素动态变化特征研究

再生水地下回灌过程中,研究了前处理和含水层中氮污染物在干湿交替回灌过程中的变化特征。结果表明:回灌期间,在臭氧氧化作用下会发生硝化反应,使NH4-N平均浓度降低0.196 mg/L,NO_3-N平均浓度上升为2.26 mg/L。再生水进入含水层后,水中游离氧仍然较高(6.89 mg/L),注入井附近会继续发生硝化反应,使5#井中NH4-N下降至0.07 mg/L;NO_3-N浓度在3#井到5#井之间符合线性方程y=-0.172 8 x+31.245;NO_2-N在3#井、4#井和5#井中平均浓度分别为2.02 mg/L、2.023 mg/L和2.427 mg/L。非回灌期地下水中反硝化反应使NO_3-N降低了12.241 mg/L,NO_2-N均上升了0.918 mg/L。另外,TN的变化规律与NO_3-N类似,非回灌期5#井中TN的去除率达56.6%。     

人工回灌条件下的水岩作用室内实验研究

人工回灌过程中所发生的水岩作用是影响含水层地下水环境质量的重要因素。本次采用室内实验技术对人工回灌过程中的水文地球化学作用和各主要离子的来源进行了分析。结果表明：人工回灌过程中地下水中的Na＋不仅受混合作用的影响,还伴随有相应的阳离子交换反应和含Na矿物的溶解反应等,而且回灌过程对原始地下水中的Na＋、Cl-有稀释作用;K＋主要受到钾长石矿物溶解的影响;人工回灌过程中存在石膏、方解石等矿物组分溶解,并且介质中的含锰矿物和含铁矿物发生了溶解反应。     

屋顶雨水回灌裂隙岩溶含水层连通示踪试验

雨水回灌后对岩溶水的影响分析和效果需要对回灌井和下游的观测井监测数据说明。由于岩溶含水层中岩溶发育极不均匀,在测定地下水位并判定出地下水流向的基础上,连通示踪试验是选择与回灌井相对应的观测井的有效办法。用氯化钠作为示踪剂,监测不同测井不同埋深地下水电导率随时间变化的方法确定了岩溶水观测井选址、岩溶含水层的结构及水文地质条件。示踪试验结果表明,3#观测井(西院井)可用来监测雨水回灌效果,并计算出该地区的地下水势流速在9 m/h～20 m/h之间。该成果对北方地区岩溶含水层回灌和环境评价具有重要的参考价值。     

人工回灌过程中的水-岩相互作用模拟

人工回灌过程中所发生的水-岩相互作用是影响回灌层位地下水环境质量的重要因素。采用室内实验和水文地球化学模拟等技术对人工回灌过程中的水-岩相互作用机理进行了分析。研究结果表明：受混合作用影响,随着回灌水比例的增加,混合水中TDS质量浓度降低,水化学类型由Cl·HCO₃-Na型水逐渐转变为HCO₃·Cl-Na·Ca型水;受水-岩作用影响,在同一混合比例条件下,随着水-岩作用的进行,混合水中TDS质量浓度升高,各主要离子质量浓度呈现升高的趋势,但只有回灌水比例占10%时,混合水TDS质量浓度才大于原始地下水（涨幅约5%）。实验介质溶解于水的离子中,Ca²⁺、Mg²⁺和HCO^-₃主要来源于碳酸盐矿物的溶解, Na⁺主要来自岩盐的溶解。在人工回灌过程中,发生的水-岩相互作用主要包括方解石、白云石、钾长石、岩盐、CO₂的溶解和伊利石的沉淀。其中:钾长石溶解量与伊利石沉淀量、碳酸盐矿物溶解量与CO₂溶解量的相关性较强,其相关系数分别为1.00和0.78（显著性水平为0.05）;硅酸盐矿物反应量和回灌水比例之间的相关系数为0.97（显著性水平为0.01）,相关性极强;而碳酸盐矿物反应量和回灌水比例之间的相关系数为0.52（显著性水平为0.01）,相关性较弱。上述相关性分析为确定人工回灌过程中的水-岩相互作用机理、地下水中主要离子组分的来源途径以及定量分析人工回灌对含水层介质的影响提供了依据。     

浅层地下水人工回灌应用于上海市工程性地面沉降防治的试验研究

上海地面沉降主要由过量开采地下水资源和大规模工程建设等因素共同影响,工程性地面沉降引起的地面沉降漏斗严重影响了周边地区生命线工程的建设及运营安全。通过开展试验研究,将深部承压含水层中应用成熟的地下水人工回灌技术引入浅部含水层中,但由于浅部含水层砂层结构及水动力条件与深部含水层差异较大,回灌工艺及方法也存在差异。本次试验工作中,改进了地下水人工回灌工艺流程,并通过同步地面形变监测分析了浅层地下水人工回灌对控制地面沉降的作用效果。结合上海地区实际地层特征以及各种回灌工艺的实际效果,评价了浅层地下水人工回灌技术在防治工程型地面沉降中推广应用的可行性及适用性。     

人工回灌井微生物生长与水质恶化

上海市人工回灌地下水措施,在缓和地面沉降、含水层储能等方面取得了预期效果。但某些人工回灌井水质恶化和深井腐蚀的加剧及出水堵塞等环境地质问题也随之而来。它们是化学的、物理的、生物的,多方面综合作用的结果。其中微生物的水文地球化学作用是一个重要的方面。这里重点就微生物生长与水质恶化作一探讨。     

基于现场试验研究的浅层地下水人工回灌影响因素分析

近年来上海工程性地面沉降引起的地面沉降漏斗严重影响了周边地区生命线工程的建设及运营安全,浅层地下水人工回灌技术在工程性地面沉降防治中的应用已受到关注。通过现场试验研究,对浅层地下水人工回灌试验中影响回灌量的各因素,包括回灌井结构、回灌井压力以及回灌井使用时间等进行了分析探讨。     

地下水回灌技术在浅层承压含水层中的实践与探讨

上海地区承压含水层埋深较深,深基坑围护的止水帷幕难以深入到承压含水层底板进行地下水水平向的完全阻隔,减压降水过程势必对周边环境产生一定影响。以上海盛大国际金融中心深基坑回灌试验为依据,表明人工回灌地下水对控制承压水位具有一定效果,并运用数值方法模拟了不同回灌条件下坑外承压水位的变化。     

人工回灌对地下水水质影响的室内模拟实验

人工回灌过程中的水岩相互作用机制较为复杂,目前有关评价人工回灌过程对地下水化学场影响范围和影响程度的研究还十分缺乏。以上海市某人工回灌试验场为例,采用室内模拟实验手段,对人工回灌过程中地下水主要溶质组分的变化趋势及其相关水岩反应进行分析。实验结果表明:回灌过程中,地下水的主要离子成分主要受混合作用、阳离子交换吸附作用及含水层矿物相(方解石、白云石、钾长石)溶解作用的影响;受回灌过程中地下厌氧环境向好氧环境发展的影响,含水介质中的As、Cr、Fe等元素存在溶出趋势,回灌后As-Fe元素的变化量表现出较好的相关性;随着回灌时间的增加,地下水水质的影响范围逐渐扩大,其水化学类型由初始的Cl-HCO3-Na型逐步向Cl-HCO3-Na-Ca型转变。     

地下水位抬升对人工回灌中悬浮物堵塞的影响

为了研究人工回灌条件下地下水位抬升对悬浮颗粒在含水层中的迁移-沉积的影响机理,在室内模拟实验中,采用100 mg/L的金刚砂悬浊水回灌中粒石英砂介质,分别研究了不同抬升速率(0、2、4cm/h)条件下人工回灌过程中的悬浮物堵塞规律。实验结果表明:地下水位抬升速率对堵塞位置和堵塞位置处悬浮物的级配影响不大,悬浮物主要淤积在0~2cm深度处;在26h前地下水位抬升引起的入渗量比地下水位固定的入渗量小,在26h后二者相反;水位抬升使介质表层堵塞发展速度减慢,非堵塞层渗流状态出现非饱和时刻滞后;在堵塞层0~2cm处地下水位抬升使堵塞速率小于地下水位固定的堵塞速率。     

再生水地表回灌补给地下水的水质安全保障体系

把城市污水净化处理为符合回灌标准的再生水并安全回灌补给地下水, 对于实现污水资源化、含水层恢复、缓解我国水资源供需矛盾和环境污染态势具有重要意义.针对再生水回灌地下水存在的水质安全问题, 通过理论分析、系列实验和技术集成形成了再生水地表回灌补给地下水的水质安全保障体系及关键技术.该安全保障体系包括场地选择与勘查、高效低成本的再生水处理技术、土壤—含水层系统数学模型和回灌方案设计技术、水质监控系统、安全评价技术以及回灌管理法规等.这些要素相互依赖、相互作用, 构成一个完整的体系.郑州郊区示范工程证实了该水质安全保障体系的可行性.2年示范工程表明, 处理的再生水水质达到《城市污水再生利用地下水回灌水质》(GB/T 19772-2005)标准, 优于场地背景地下水水质, 补给含水层后的地下水基本达到《地下水质量标准》(GB/T 14818-1993)Ⅲ类水标准.建议有关政府部门把再生水利用及回灌补给地下水, 纳入水资源开发利用及环境保护规划的整体框架中, 尽快制定或完善再生水回灌补给地下水的相关法律、法规和标准体系, 建立再生水回灌许可证制度, 有序推进再生水回灌工程.      

Determining groundwater degradation from irrigation in desert-marginal northern China

Groundwater degradation from irrigated agriculture is of concern in semi-arid northern China. Data-scarcity often means the causes and extent of problems are not fully understood. An irrigated area in Inner Mongolia was studied, where abstraction from an unconfined Quaternary aquifer has increased threefold over 20 years to 20 million m³/year; groundwater levels are falling at up to 0.5 m/year; and groundwater is increasingly mineralised (TDS increase from 400 to 700–1,900 mg/L), with nitrate concentrations up to 137 mg/L N. Residence-time (chlorofluorocarbons), stable-isotope and hydrogeochemical indicators helped develop a conceptual model of groundwater system evolution, demonstrating a direct relationship between modern water proportion and the degree of groundwater mineralisation, indicating that irrigation-water recycling is reducing groundwater quality. The investigations suggest that before irrigation development, active recharge to the aquifer from wadis significantly exceeded groundwater inflow from nearby mountains, previously held to be the main groundwater input. Away from active wadis, groundwater is older with a probable pre-Holocene component. Proof-of-concept groundwater modelling supports geochemical evidence, indicating the importance of wadi recharge and irrigation return flows. Engineering works protecting the irrigated area from flooding have reduced good quality recharge; active recharge is now dominated by irrigation returns, which are degrading the aquifer.     

大清河流域平原区地下水人工补给潜力与补给方式分析

为了有效提升大清河流域平原区地下水水位,亟需在此区域开展地下水人工补给工程,并确定合理的建设位置及有效的补给方式。首先基于研究区可利用补给水源、地下水位、地表高程、地表坡度及与河道距离5个指标的分布特征,构建地下水补给潜力评价体系,采用ArcGIS空间分析功能对研究区进行了地下水人工补给潜力区划;然后在此评价体系基础上,在典型人工补给高潜力区进一步开展系列野外现场试验,探讨适宜可行的地下水人工补给方式。结果表明：研究区西北部及南部河道附近区域开展人工补给工程潜力较高,而中部、北部及西南部远离河道的区域潜力较低。高潜力区——白沟引河地段包气带及含水层渗透性良好,整体渗透系数均在5 m/d左右或更高,适宜地表补给,但河床渗透性较差,渗透系数基本在0.01~0.09 m/d间,若通过河道补给需配合清淤等措施。其中,在上游及中游沿岸适宜将河道水通过生态水渠引至修建的地表入渗池或借助天然渗坑内入渗补给,在中下游沿岸区域适宜将补给水进行严格的水处理后采用井灌方式补给,在白沟引河中下游河道适宜修建拦水坝,利用河道进行入渗补给。     

Artificial groundwater recharge to a semi-arid basin: case study of Mujib aquifer,Jordan

Mujib watershed is an important groundwater basin which is considered a major source for drinking and irrigation water in Jordan. Increased dependence on groundwater needs improved aquifer management with respect to understanding deeply recharge and discharge issues, planning rates withdrawal, and facing water quality problems arising from industrial and agricultural contamination. The efficient management of this source depends on reliable estimates of the recharge to groundwater and is needed in order to protect Mujib basin from depletion. Artificial groundwater recharge was investigated in this study as one of the important options to face water scarcity and to improve groundwater storage in the aquifer. A groundwater model based on the MODFLOW program, calibrated under both steady- and unsteady-state conditions, was used to investigate different groundwater management scenarios that aim at protecting the Mujib basin. The scenarios include variations of abstraction levels combined with different artificial groundwater recharge quantities. The possibilities of artificial groundwater recharge from existing and proposed dams as well as reclaimed municipal wastewater were investigated. Artificial recharge options considered in this study are mainly through injecting water directly to the aquifer and through infiltration from reservoir. Three scenarios were performed to predict the aquifer system response under different artificial recharge options (low, moderate, and high) which then compared with no action (recharge) scenario. The best scenario that provides a good recovery for the groundwater table and that can be feasible is founded to be by reducing current abstraction rates by 20% and implementing the moderate artificial recharge rates of 26 million(M)m³/year. The model constructed in this study helps decision makers and planners in selecting optimum management schemes suitable for such arid and semi-arid regions.     

Hydrogeochemical transport modeling of the infiltration of tertiary treated wastewater in a dune area, Belgium

Managed artificial recharge (MAR) is a well-established practice for augmentation of depleted groundwater resources or for environmental benefit. At the St-André MAR site in the Belgian dune area, groundwater resources are optimised through re-use of highly treated wastewater by means of infiltration ponds. The very high quality of the infiltration water sets this system apart from other MAR systems. The low total dissolved solid (TDS) content in the infiltration water (less than 50 mg/L) compared to the dune aquifer (500 mg/L) triggers a number of reactions, increasing the TDS through soil-aquifer passage. Multi-component reactive transport modelling was applied to analyse the geochemical processes that occur. Carbonate dissolution is the main process increasing the TDS of the infiltration water. Oxic aquifer conditions prevail between the infiltration ponds and the extraction wells. This is driven by the high flow velocities, leaving no time to consume O₂ between the ponds and extraction wells. Cation exchange is important when infiltration water is replaced by native dune water or when significant changes in infiltration-water quality occur. The seasonal variation of O₂ and temperature in the infiltration water are the main drivers for seasonal changes in the concentration of all major ions.     

人工补给对含水层水质的影响

为了研究人工补给对含水层水质的影响问题,通过反向地球化学模拟方法对大庆西部地下水水质演化规律进行了分析。结果表明,地下水化学成分主要受含水层矿物相的溶解-沉淀作用、阳离子交换吸附作用以及氧化还原作用的影响,并确定方解石、白云石、盐岩、萤石、石膏、赤铁矿、菱铁矿、软锰矿、二氧化碳、阳离子交换剂等为影响地下水化学成分的控制性（矿）物相。在此基础上,采用正向地球化学模拟方法,以大庆市西水源地下水人工补给为例,模拟了地表水进入到地下后与含水层中原有的地下水以及含水层介质发生的水-岩相互作用。模拟结果表明,注入水与含水层中的水混合后,使地下水的矿化度有所降低,且混合水中地表水所占比例越大,地下水的矿化度越低;注入水与含水层中的地下水混合后,不会导致地下水水质的突变和水质级别的降低,还可在一定程度上改善含水层水质。     

Percolation pond as a method of managed aquifer recharge in a coastal saline aquifer: A case study on the criteria for site selection and its impacts

Percolation ponds have become very popular methods of managed aquifer recharge due to their low cost, ease of construction and the participation and assistance of community. The objective of this study is to assess the feasibility of a percolation pond in a saline aquifer, north of Chennai, Tamil Nadu, India, to improve the storage and quality of groundwater. Electrical resistivity and ground penetrating radar methods were used to understand the subsurface conditions of the area. From these investigations, a suitable location was chosen and a percolation pond was constructed. The quality and quantity of groundwater of the nearby area has improved due to the recharge from the pond. This study indicated that a simple excavation without providing support for the slope and paving of the bunds helped to improve the groundwater quality. This method can be easily adoptable by farmers who can have a small pond within their farm to collect and store the rainwater. The cost of water recharged from this pond works out to be about 0.225 Re/l. Cleaning the pond by scrapping the accumulated sediments needs to be done once a year. Due to the small dimension and high saline groundwater, considerable improvement in quality at greater depths could not be achieved. However, ponds of larger size with recharge shafts can directly recharge the aquifer and help to improve the quality of water at greater depths.     

Hydrogeological investigation of groundwater artificial recharge by treated wastewater in semi-arid regions: Korba aquifer (Cap-Bon Tunisia)

Korba aquifer is one of the most typical examples of overexploited coastal aquifer in the Mediterranean countries. In fact, from 1985, a considerable piezometric level drop, water salinization, and seawater intrusion were registered in the aquifer. In December 2008, Tunisian authorities initiated a general plan to groundwater management in order to augment groundwater resources, restore the piezometric levels, and improve water quality. The plan consists of artificial recharge of groundwater used treated wastewater through three infiltration basins. During the first 4 years (from December 2008 to December 2012), 1.41 Mm³ of treated wastewater was injected to the Korba aquifer. This study presents a hydrogeological assessment of groundwater evolution during the recharge processes. In this study, 32 piezometric and chemical surveys of 70 piezometers and observed wells are used to present hydrogeological investigation and water quality evolution of wastewater reuse through artificial recharge in Korba coastal aquifer. The piezometric evolution maps are used to specify the positive effect in groundwater level that exceeding 1.5 m in some regions. The interpretation of salinity evolution maps are used to indicate the improving of groundwater quality.     

Pollution vulnerability of the Quaternary aquifer near Cairo, Egypt, as indicated by isotopes and hydrochemistry

The present study was conducted to delineate the pollution vulnerability of the Quaternary aquifer in two areas, Imbaba and Shobra El-Khima, near Cairo, Egypt. Environmental isotopes combined with hydrochemistry were used for this purpose. The groundwater in the Imbaba area (average total dissolved solids about 900 mg/L; sodium/chloride, sulfate, and bicarbonate water types) is more mineralized than groundwater in the Shobra El-Khima area (average total dissolved solids 500 mg/L; calcium and sodium/bicarbonate water type). A high nitrate content and significant mineralization in the groundwater are probably due to contamination of recharge to the aquifer by irrigation drainage, deteriorated sewage networks, and septic tanks. The deuterium and oxygen-18 compositions of the groundwater are depleted compared to Nile River water, which is the main source of aquifer recharge. This less isotopically enriched water probably represents older Nile water recharge that flooded the region before construction of the Aswan High Dam in 1963, or it is a mixture of a young water and originally deposited paleowater that was in deeper horizons at a time of cooler and more humid climate. Intensive pumping has moved the paleowater higher in the aquifer. Groundwater in the Shobra El-Khima area has higher residence time, based on the tritium concentration, than groundwater in the Imbaba area. The percentage of the isotopically depleted water equals 75% in the Shobra El-Khima and 35% in Imbaba, and the thickness of the clay cap above the aquifer is 38 m in Shobra El-Khima and 20 m in Imbaba. These factors are indicative of the rate of recharge to the aquifer and were used to evaluate the pollution vulnerability in the two areas. Electronic Publication