Late Paleozoic retrograded eclogites from within the northern margin of the North China Craton: Evidence for subduction of the Paleo-Asian ocean

Retrograded eclogites from the central part of the northern margin of the North China Craton, Hebei Province, China occur as separate tectonic lenses or boundins within garnet–biotite–plagioclase gneisses of the Paleoproterozoic Hongqiyingzi Complex characterized by amphibolite facies paragneisses. The petrographic features and mineralogical compositions represent three main metamorphic stages: (1) the peak eclogite facies stage (P > 1.40–1.50 GPa, T = 680–730 °C), (2) the granulite facies stage and (3) the amphibolite facies stage (P = 0.67–0.81 GPa, T = 530–610 °C) formed during decompression. The major and trace element and Sm–Nd isotopic data suggest that most of the retrograded eclogite samples had protoliths of tholeiitic oceanic crust with geochemical characteristics of mid-ocean ridge basalt (MORB) or island arc tholeiite (IAT) environment, and were contaminated by crustal components during subsequent subduction. Zircon SHRIMP isotopic dating of two different textural varieties of retrograded eclogite defines a weighted mean age of 325 Ma, which is interpreted as the peak metamorphic age of the eclogites and reflects the occurrence of eclogite facies metamorphism related to subduction of Paleo-Asian Oceanic crust beneath the North China Craton during the Late Paleozoic. Finally, we show that the retrograded eclogite from Hebei Province is not related to the Baimashi retrograded eclogite at the northern foot of the Heng Mountains, approximately, 300 km to the southwest.     

Archean Granitoids at the Contact of Eastern Ghat Granulite Belt and Singhbhum-Orissa Craton, in Bhuban-Rengali Sector, Orissa, India

The small granite plutons occurring at the contact of the Singhbhum-Orissa Iron Ore craton (IOC) to the north and the Eastern Ghat Granulite Belt (EGGB) to the south in eastern Indian shield are characterised by the presence of enclaves of the granulites of EGGB and the greenschist facies rocks of IOC. These granites also bear the imprints of later cataclastic deformation which is present at the contact of the IOC and the EGGB. In situ Pb-Pb zircon dating of these granites gives minimum age of their formation 2.80 Ga. A whole-rock three point Rb-Sr isochron age of this rock is found to be 2.90 Ga. Therefore, the true age of formation of these granites will be around 2.90–2.80 Ga. These granitic rocks also contain xenocrystic zircon components of 3.50 Ga and show a later metasomatic or metamorphic effect 2.48 Ga obtained from the analyses on overgrowths developed on 2.80 Ga old zircon cores. The presence of granulitic enclaves within these contact zone granite indicates that the granulite facies metamorphism of the EGGB is 2.80 Ga or still older in age. The cataclastic deformations observed at the contact zone of the two adjacent cratons is definitely younger than 2.80 Ga and possibly related to 2.48 Ga event observed from the overgrowths. As 2.80 Ga granite plutons of small dimensions are also observed at the western margin of the IOC; it can be concluded that a geologic event occurred 2.80 Ga over the IOC when small granite bodies evolved at the marginal part of this craton after its stabilisation at 3.09 Ga.     

Holocene activity of the Scilla Fault, Southern Calabria: Insights from coastal morphological and structural investigations

Integration of on-land and offshore geomorphological and structural investigations coupled to extensive radiometric dating of co-seismically uplifted Holocene beaches allows characterization of the geometry, kinematics and seismotectonics of the Scilla Fault, which borders the eastern side of the Messina Strait in Calabria, Southern Italy. This region has been struck by destructive historical earthquakes, but knowledge of geologically-based source parameters for active faults is relatively poor, particularly for those running mostly offshore, as the Scilla Fault does. The  30 km-long normal fault may be divided into three segments of  10 km individual length, with the central and southern segments split in at least two strands. The central and northern segments are submerged, and in this area marine geophysical data indicate a youthful morphology and locally evidence for active faulting. The on-land strand of the western segment displaces marine terraces of the last interglacial (124 to 83 ka), but seismic reflection profiles suggest a full Quaternary activity. Structural data collected on bedrock faults exposed along the on-land segment provide evidence for normal slip and  NW-SE extension, which is consistent with focal mechanisms of large earthquakes and GPS velocity fields in the region. Detailed mapping of raised Holocene marine deposits exposed at the coastline straddling of the northern and central segments supplies evidence for two co-seismic displacements at  1.9 and  3.5 ka, and a possible previous event at  5 ka. Co-seismic displacements show a consistent site value and pattern of along-strike variation, suggestive of characteristic-type behaviour for the fault. The  1.5–2.0 m average co-seismic slips during these events document M_e  6.9–7.0 earthquakes with  1.6–1.7 ka recurrence time. Because hanging-wall subsidence cannot be included into slip magnitude computation, these slips reflect footwall uplift, and represent minimum average estimates. The palaeoseismological record based on the palaeo-shorelines suggests that the last rupture on the Scilla Fault during the February 6, 1783 M_w = 5.9–6.3 earthquake was at the expected time but it may have not entirely released the loaded stress since the last great event at  1.9 ka. Comparison of the estimated co-seismic extension rate based on the Holocene shoreline record with available GPS velocities indicates that the Scilla Fault accounts for at least  15–20% of the contemporary geodetic extension across the Messina Strait.     

Taconic Orogeny in Pennsylvania: A 15 –20 m.y. Apennine-style Ordovician event viewed from its Martic hinterland

In Pennsylvania, the Taconic Orogeny lasted from 461 to 443 Ma as Cambro-Ordovician slope deposits were deformed into mountains edging the Laurentian craton at the same time that materials from an adjacent deep-water basin were being transported 50 –70 km across a carbonate platform into foreland basins. This paper focuses on shelf-edge hinterland features, mostly the Martic Zone as a folded, stack of imbricate thrust sheets of slope materials that corresponds to Vermont's Taconic Mountains and Southern Quebec's zone of Taconic allochthons. Work of the last century is summarized, corrected, and combined with a new 450 Ma radiometric date and fluid inclusion data from the Pequea Mine within the Martic Zone. These and abundant new graptolite and conodont dates in the foreland paint a revised Pennsylvania picture differing from the northern Taconic areas. Differences are: (1) transport of very large allochthonous masses of deep-water material, the Dauphin Formation, far across the carbonate platform, and (2) deformation migrating progressively across that platform during a 15 –20 m.y. period, incorporating it and its foreland cover into alpine-scale, recumbent folds and thrusts. The scenario has many analogies to Italy's modern Apennine Mountains minus the Latian volcanics.     

Quantitative evaluation of the biostratigraphic distribution of acanthomorphic acritarchs in the Ediacaran Doushantuo Formation in the Yangtze Gorges area, South China

Doushantuo acanthomorphic acritarchs are large morphologically complex organic-walled microfossils broadly constrained between the 635 Ma Nantuo glaciation and the 551 Ma Miaohe Biota. They are potential biostratigraphic tools for subdivision and correlation of the Ediacaran System in South China. However, major variations in sedimentary facies and stratigraphic thickness present challenges in understanding the spatial and temporal distribution of these acritarchs. Further, the distribution of acritarchs in the Doushantuo Formation is associated with the presence of early diagenetic chert and phosphate, implying a certain degree of preservational bias and/or environmental control. The purpose of this paper is to document the stratigraphic distribution of Doushantuo acritarchs and to quantitatively evaluate their biostratigraphic significance and possible taphonomic–environmental biases, based on high-resolution paleontological data from six sections over 100 km in the Yangtze Gorges area, South China.A total of 1082 acritarch fossils were recorded from 84 chert horizons in the six sections of the study area. These chert horizons are not uniformly distributed throughout the Doushantuo Formation, thus the presence/absence of early diagenetic chert does play a role in controlling the distribution of acritarchs. The sampled chert horizons can be grouped into two stratigraphic intervals in the lower and upper Doushantuo Formation, respectively, based on regional stratigraphic correlation. Quantitative analysis shows that the two intervals are distinct taxonomically and largely independent of taphonomic or facies controls. Thus, the two intervals can be regarded as assemblage biozones. The lower biozone (biozone 1) is numerically dominated by Tianzhushania spinosa (n = 587; 68.3%) and Meghystrichosphaeridium magnificum (n = 74; 8.6%), whereas the upper biozone (biozone 2) is dominated by Ericiasphaera rigida (n = 104; 47.1%) and Tianzhushania spinosa (n = 34; 14.1%). The three most common genera, Meghystrichosphaeridium, Tianzhushania, and Ericiasphaera, have been identified in all sections. Correspondence analysis (CA), detrended correspondence analysis (DCA), discriminant analysis (DA), and pairwise comparisons of samples (Spearman rank coefficient and Jaccard–Chao index), all consistently support biostratigraphic zonations. Thus, the distribution of the Doushantuo acanthomorphs is primarily controlled by biostratigraphic position of samples, with facies and taphonomic differences playing a secondary role. Our case study suggests that acanthomorphic acritarchs can offer a viable tool for regional correlation of the Ediacaran System.     

Changes in Zn speciation during soil formation from Zn-rich limestones

In order to better understand the long-term speciation and fractionation of Zn in soils, we investigated three soils naturally enriched in Zn (237–864 mg/kg Zn) from the weathering of Zn-rich limestones (40–207 mg/kg Zn) using extended X-ray absorption fine structure (EXAFS) spectroscopy and sequential extractions. The analysis of bulk EXAFS spectra by linear combination fitting (LCF) indicated that Zn in the oolitic limestones was mainly present as Zn-containing calcite (at site Dornach), Zn-containing goethite (Gurnigel) and Zn-containing goethite and sphalerite (Liestal). Correspondingly, extraction of the powdered rocks with 1 M NH₄-acetate at pH 6.0 mobilized only minor fractions of Zn from the Gurnigel and Liestal limestones (<30%), but most Zn from the Dornach rock (81%). In the Dornach soil, part of the Zn released from the dissolving limestone was subsequently incorporated into pedogenic hydroxy-interlayered vermiculite (Zn-HIV, 30%) and Zn-containing kaolinite (30%) and adsorbed or complexed by soil organic and inorganic components (40%). The Gurnigel and Liestal soils contained substantial amounts of Zn-containing goethite (50%) stemming from the parent rock, smaller amounts (20%) of Zn-containing kaolinite (and possibly Zn-HIV), as well as adsorbed or complexed Zn-species (30%). In the soil from Liestal, sphalerite was only found in trace amounts, indicating its dissolution during soil formation. In sequential extractions, large percentages of Zn (55–85%) were extracted in recalcitrant extraction steps, confirming that Zn-HIV, Zn-containing kaolinite and Zn-containing goethite are highly resistant to weathering. These Zn-bearing phases thus represent long-term hosts for Zn in soils over thousands of years. The capability of these phases to immobilize Zn in heavily contaminated soils may however be limited by their uptake capacity (especially HIV and kaolinite) or their abundance in soil.     

Probing fault zone heterogeneity on the Nojima fault: Constraints from zircon fission-track analysis of borehole samples

Fission-track (FT) thermochronologic analysis was performed on zircon separates from rocks in and around the Nojima fault, which was activated during the 1995 Kobe earthquake. Samples were collected from the University Group 500 m (UG-500) borehole and nearby outcrops. FT lengths in zircons from localities > 25 m away from the fault plane as well as one 0.1 m away from the fault in the footwall are characterized by concordant mean values of  10–11 μm and unimodal distributions with negative skewness, which showed no signs of appreciable reduction in FT length. In contrast, those adjacent (< 3 m) to the fault at depths on the hanging wall side showed significantly reduced mean track lengths of  6–8 μm and distributions having a peak around 6–7 μm with rather positive skewness. The former pattern is interpreted to reflect cooling through the zircon partial annealing zone (ZPAZ), without later, partial thermal overprints. The latter indicates substantial track shortening due probably to secondary heating by a thermal event(s) that locally perturbed the geothermal structure. Modeled zircon FT length and age data of partially annealed samples from the UG-500 borehole revealed a cooling episode in the ZPAZ that started at  4 Ma within  3 m from the fault plane, whereas those from the Geological Survey of Japan 750 m borehole record cooling started at  31–38 Ma within  25 m from the fault. On the basis of one-dimensional heat conduction modeling as well as the consistency between the degree of FT annealing and the degree of deformation/alteration of borehole rocks, these cooling ages in both boreholes are interpreted as consequences of ancient thermal overprints by heat transfer or dispersion via fluids in the fault zone. Together with the zircon FT data of a pseudotachylyte layer recently analyzed, it is suggested that the present Nojima fault system was reactivated in the Middle Quaternary from an ancient fault initiated at  56 Ma at mid-crustal depths. Also shown is a temporal/spatial variation in terms of the thermal anomalies recorded in the fault rocks, implying heterogeneity of hot fluid flows in the fault zone.     

Constraining models of the tectonic setting of the giant Olympic Dam iron oxide–copper–gold deposit, South Australia, using deep seismic reflection data

In the Gawler Craton, the completeness of cover concealing the crystalline basement in the region of the giant Olympic Dam Cu–Au deposit has impeded any sufficient understanding of the crustal architecture and tectonic setting of its IOCG mineral-system. To circumvent this problem, deep seismic reflection data were recently acquired from  250 line-km of two intersecting traverses, centered on the Olympic Dam deposit. The data were recorded to 18 s TWT ( 55 km). The crust consists of Neoproterozoic cover, in places more than 5 km thick, over crystalline basement with the Moho at depths of 13–14 s TWT ( 40–42 km). The Olympic Dam deposit lies on the boundary between two distinct pieces of crust, one interpreted as the Archean–Paleoproterozoic core to the craton, the other as a Meso–Neoproterozoic mobile belt. The host to the deposit, a member of the  1590 Ma Hiltaba Suite of granites, is situated above a zone of reduced impedance contrast in the lower crust, which we interpret to be source-region for its  1000 °C magma. The crystalline basement is dominated by thrusts. This contrasts with widely held models for the tectonic setting of Olympic Dam, which predict extension associated with heat from the mantle producing the high temperatures required to generate the Hiltaba Suite granites implicated in mineralization. We use the seismic data to test four hypotheses for this heat-source: mantle underplating, a mantle-plume, lithospheric extension, and radioactive heating in the lower crust. We reject the first three hypotheses. The data cannot be used to reject or confirm the fourth hypothesis.     

Structural and stratigraphical constraints on the kinematics history of the Southern Tan–Lu Fault Zone during the Mesozoic Anhui Province, China

The Tan–Lu Fault Zone (TLFZ) extends in a NNE–SSW direction for more than 2000 km in Eastern China. It has been considered either as a major sinistral strike-slip fault, as a suture zone or as a normal fault. We have conducted a structural analysis of the southern segment of this fault zone (STLFZ) in the Anhui Province. The ages (Triassic to Palaeocene) of the formations affected by the faults have been re-appraised taking into account recent stratigraphical studies to better constraint the ages of the successive stages of the kinematics of the STLFZ. Subsequently, the kinematics of the faults is presented in terms of strain/stress fields by inversion of the striated fault set data. Finally, the data are discussed in the light of the results obtained by previous workers.We propose the following history of the STLFZ kinematics during the Mesozoic. At the time of collision, a  NNE orientated Tan–Lu margin probably connected two margins located north of the Dabie and Sulu collision belts. During the Middle–Late Triassic, the SCB has been obliquely subducted below the NCB along this margin which has acted as a compressional transfer zone between the Dabie and Sulu continental subduction zones. The STLFZ has been initiated during the Early Jurassic and has acted as a sinistral transform fault during the Jurassic, following which the NCB/SCB collision stopped. A  NW-trending extension related to metamorphic domes was active during the basal Early Cretaceous ( 135–130 Ma); it has been followed by a NW–SE compression and a NE–SW tension during the middle–late Early Cretaceous ( 127 to  105 Ma, possibly  95 Ma); at that time the TLFZ was a sinistral transcurrent fault within the eastern part of the Asian continent. During the Late Cretaceous–Palaeocene, the STLFZ was a normal fault zone under a WNW–ESE tension.     

The age and petrology of the Chimbadzi Hill Intrusion, NW Zimbabwe: first evidence for early Paleoproterozoic magmatism in Zimbabwe

The mafic-ultramafic Chimbadzi Hill intrusion in the NW of the Zimbabwe craton is a dyke with inward-dipping margins comprising magnetite peridotite, troctolite and magnetite melatroctolite. The magnetite peridotite is composed of about equal amounts of V- and Ti-bearing magnetite and olivine (Fo₆₀). The troctolite is composed of about 50% olivine (Fo_50-54), 40% plagioclase (An_53-58), 7% clinopyroxene and minor apatite and magnetite with ilmenite lamellae. Geochemical trends suggest that the Chimbadzi Hill Intrusion formed by fractional crystallisation from a single initial magma. However, the more primitive magnetite peridotite overlies the more evolved troctolite in the intrusion. This ‘apparent’ inverted stratigraphy may be due to emptying of a fractionated magma chamber from the top, or to floor subsidence during intrusion.U–Pb dating on baddeleyite reveals that the age of the Chimbadzi Hill Intrusion is 2262 ± 2 Ma. This age does not correspond to any known tectono-thermal event in the Zimbabwe Craton or adjacent metamorphic belts. It is 300 Ma younger than the late Archean Great Dyke, and 230 Ma older than other Paleoproterozoic events in and around the craton. Therefore, it may represent a so far undocumented very early Proterozoic igneous event in the Zimbabwe Craton. The intrusion represents a vanadium resource for Zimbabwe, with titanium potentially being mined as by-product.     

Constraints from Moho geometry and crustal thickness on the geodynamic origin of the Vrancea Seismogenic Zone (Romania)

Reprocessing of industry deep seismic reflection data (Ramnicu Sarat and Braila profiles) from the SE Carpathian foreland of Romania provides important new constraints on geodynamic models for the origin of the intermediate depth Vrancea Seismogenic Zone (VSZ). Mantle (70–200 km) earthquakes of the VSZ are characterized by high magnitudes (greater than 6.5), frequent occurrence rates (approximately 25 years), and confinement in a very narrow (30 × 70 × 200 km³) near vertical zone atypical for a Wadati–Benioff plane, located in front of the orogen. These two deep (20 s) seismic reflection profiles (70 km length across the foreland) reveal (1) a high-amplitude, gently east-dipping reflection across most of the section from what we interpret to be the Moho at  15 s (40–42 km) on the Ramnicu Sarat line to  16 s (47–48 km) on the Braila line, (2) a thick sedimentary cover increasing in thickness from east (1 s;  800 m) to west (7.5 s; 14 km), (3) an eastward increase in crustal thickness from 38 km (near VSZ) to  45 km, (4) seismic and topographic evidence for a newly imaged, possibly seismically active basement fault with a surface offset of 30 m observed on the Ramnicu Sarat line, (5) a lack of notable west-dipping structures in the crust and across the Moho, and (6) variable displacements on Peceneaga–Camena Fault of  5 km at Moho and  200 m at the basement–sedimentary cover contact.These observations appear to argue against recent models for west-dipping subduction of oceanic lithosphere at or in the vicinity of the Vrancea Seismogenic Zone given the lack of west-dipping fabrics in the lower crust and across the crust–mantle boundary. Consequently, one possible explanation for the geodynamic origin of VSZ could be partial delamination of the continental lithosphere in an intra-plate setting along a sub-horizontal lithospheric interface in the Carpathian hinterland that likely involves remnant lithospheric coupling between the crust and uppermost mantle in the foreland.     

SHRIMP zircon U–Pb geochronological and whole-rock geochemical evidence for an early Neoproterozoic Sibaoan magmatic arc along the southeastern margin of the Yangtze Block

It has been generally accepted that the South China Block was formed through amalgamation of the Yangtze and Cathaysia Blocks during the Proterozoic Sibaoan orogenesis, but the timing and kinematics of the Sibao orogeny are still not well constrained. We report here SHRIMP U–Pb zircon geochronological and geochemical data for the Taohong and Xiqiu tonalite–granodiorite stocks from northeastern Zhejiang, southeastern margin of the Yangtze Block. Our data demonstrate that these rocks, dated at 913 ± 15 Ma and 905 ± 14 Ma, are typical amphibole-rich calc-alkaline granitoids formed in an active continental margin. Combined with previously reported isotopic dates for the  1.0 Ga ophiolites and  0.97 Ga adakitic rocks from northeastern Jiangxi, the timing of the Sibao orogenesis is thus believed to be between  1.0 and  0.9 Ga in its eastern segment. It is noted that the Sibao orogeny in South China is in general contemporaneous with some other early Neoproterozoic (1.0–0.9 Ga) orogenic belts such as the Eastern Ghats Belt of India and the Rayner Province in East Antarctica, indicating that the assembly of Rodinia was not finally completed until  0.9 Ga.     

The evolution of a tropical rainforest/grassland mosaic in southeastern Brazil since 28,000 C yr BP based on carbon isotopes and pollen records

The lack of paleoecological records from the montane Atlantic Rainforest of coastal Brazil, a hotspot of biological diversity, has been a major obstacle to our understanding of the vegetational changes since the last glacial cycle. We present carbon isotope and pollen records to assess the impact of the glaciation on the native vegetation of the Serra do Mar rainforest in São Paulo, Brazil. From ca. 28,000 to  22,000 ¹⁴C yr BP, a subtropical forest with conifer trees is indicative of cool and humid conditions. In agreement carbon isotopic data on soil organic matter suggest the presence of C₃ plants and perhaps C₄ plants from  28,000 to  19,000 ¹⁴C yr BP. The significant increase in the sedimentation rate and algal spores from  19,450 to  19,000 ¹⁴C yr BP indicates increasing humidity, associated to an erosion process between  19,000 and  15,600 ¹⁴C yr BP. From  15,600 ¹⁴C yr BP to present there is a substantial increase in arboreal elements and herbs, indicating more humid and warmer climate. From  19,000 to  1000 ¹⁴C yr BP, δ¹³C values indicated the predominance of C₃ plants. These results are in agreement with studies in speleothems of caves, which suggest humid conditions during the last glacial maximum.     

Mesozoic plutons of the Yidun Arc, SW China: U/Pb geochronology and Hf isotopic signature

The Yidun Arc is a Triassic volcanic arc located between the Songpan Garzê Fold Belt and the Qiangtang Block, southwest China. To constrain the age of a number of the major granitic plutons from the Yidun Arc, laser ablation ICP-MS U/Pb analysis of zircon was conducted. Hafnium isotope data was also acquired through laser-ablation multicollector ICPMS analysis of zircon, with the aim of gaining insight into the age and nature of the source region of the plutons. Three age groups have been identified from seven granite samples: Early–Middle Triassic ( 245 to 229 Ma), Late Triassic ( 219 to 216 Ma) and Cretaceous ( 105 to 95 Ma). Hafnium analysis shows the Triassic granites to have negative and variable ε_Hf values and Mesoproterozoic ( 1.6 Ga) depleted-mantle model ages, which is interpreted to reflect derivation from an isotopically heterogeneous, largely crustal source. The Cretaceous granite shows higher and less variable ε_Hf values and slightly younger model ages ( 1.3 Ga), and is interpreted to be derived from melting of a more homogeneous crustal source. A depleted-mantle model age of  1.5 Ga is calculated from the pooled Triassic and Cretaceous samples. The source region for these magmas may be tentatively correlated with Mesoproterozoic material of the Yangtze Craton, which has been suggested to underlie the Yidun Arc; however, further work is necessary to demonstrate this suggestion.     

15,000-yr pollen record of vegetation change in the high altitude tropical Andes at Laguna Verde Alta, Venezuela

Pollen analysis of sediments from a high-altitude (4215 m), Neotropical (9°N) Andean lake was conducted in order to reconstruct local and regional vegetation dynamics since deglaciation. Although deglaciation commenced 15,500 cal yr B.P., the area around the Laguna Verde Alta (LVA) remained a periglacial desert, practically unvegetated, until about 11,000 cal yr B.P. At this time, a lycopod assemblage bearing no modern analog colonized the superpáramo. Although this community persisted until 6000 cal yr B.P., it began to decline somewhat earlier, in synchrony with cooling following the Holocene thermal maximum of the Northern Hemisphere. At this time, the pioneer assemblage was replaced by a low-diversity superpáramo community that became established 9000 cal yr B.P. This replacement coincides with regional declines in temperature and/or available moisture. Modern, more diverse superpáramo assemblages were not established until 4600 cal yr B.P., and were accompanied by a dramatic decline in Alnus, probably the result of factors associated with climate, humans, or both. Pollen influx from upper Andean forests is remarkably higher than expected during the Late Glacial and early to middle Holocene, especially between 14,000 and 12,600 cal yr B.P., when unparalleled high values are recorded. We propose that intensification of upslope orographic winds transported lower elevation forest pollen to the superpáramo, causing the apparent increase in tree pollen at high altitude. The association between increased forest pollen and summer insolation at this time suggests a causal link; however, further work is needed to clarify this relationship.     

Guidelines for assessing the petroleum potential of coaly source rocks using Rock-Eval pyrolysis

Coaly source rocks are sufficiently different from marine and lacustrine source rocks in their organic matter characteristics to warrant separate guidelines for their assessment using Rock-Eval pyrolysis. The rank threshold for oil generation is indicated by the increase in BI (S1/TOC) at Rank(S_r)9–10 (T_max 420–430 °C, R_o 0.55–0.6%), and the threshold for oil expulsion is indicated by the peak in QI ([S1+S2]/TOC) at Rank(S_r)11–12.5 (T_max 430–440 °C, R_o 0.65–0.85%). The pronounced rank-related increase in HI (S2/TOC) prior to oil expulsion renders the use of immature samples inappropriate for source rock characterisation. A more realistic indication of the petroleum generative potential and oil expulsion efficiency of coaly source rocks can be gained from samples near the onset of expulsion. Alternatively, effective HI′ values (i.e. HIs near the onset of expulsion) can be estimated by translating the measured HIs of immature samples along the maturation pathway defined by the New Zealand (or other defined) Coal Band. Coaly source rocks comprise a continuum of coaly lithologies, including coals, shaly coals and coaly mudstones. Determination of the total genetic potential of coaly source rock sequences is best made using lithology-based samples near the onset of expulsion.     

Ultrahigh temperature deformation microstructures in felsic granulites of the Napier Complex, Antarctica

Detailed electron microscope and microstructural analysis of two ultrahigh temperature felsic granulites from Tonagh Island, Napier Complex, Antarctica show deformation microstructures produced at  1000 °C at 8–10 kbar. High temperature orthopyroxene (Al 7 wt.% and  11 wt.%), exhibits crystallographic preferred orientation (CPO) and frequent subgrain boundaries which point to dislocation creep as the dominating deformation mechanism within opx. Two different main slip systems are observed: in opx bands with exclusively opx grains containing subgrain boundaries with traces parallel to [010] and a strong coupling of low angle misorientations (2.5°–5°) with rotation axes parallel to [010] the dominating slip system is (100)[001]. Isolated opx grains and grain clusters of 2–5 grains embedded in a qtz–fsp matrix show an additional slip system of (010)[001]. The latter slip system is harder to activate. We suggest that differences in the activation of these slip systems is a result of higher differential stresses imposed onto the isolated opx grains and grain clusters. In contrast to opx, large qtz grains (up to 200 μm) show random crystallographic orientation. This together with their elongate and cuspate shape and the lack of systematic in the rotation axes associated with the subgrain boundaries is consistent with diffusion creep as the primary deformation mechanism in quartz.Our first time detailed microstructural observations of ultrahigh temperature and medium to high pressure granulites and their interpretation in terms of active deformation mechanisms give some insight into the type of rheology that can be expect at lower crustal conditions. If qtz is the mineral phase governing the rock rheology, Newtonian flow behaviour is expected and only low differential stress can be supported. However, if the stress supporting mineral phase is opx, the flow law resulting from dislocation creep will govern the rheology of the rock unit; hence, an exponential relationship between stress and strain rate is to be expected.     

Cretaceous and Cenozoic cooling history across the ultrahigh pressure Tongbai–Dabie belt, central China, from apatite fission-track thermochronology

The crystalline terrane of the Tongbai–Dabie region, central China, comprising the Earth's largest ultrahigh-pressure (UHP) exposure was formed during Triassic collision between the Sino–Korean and Yangtze cratons. New apatite fission-track (AFT) data presented here from the UHP terrane, extends over a significantly greater area than reported in previous studies, and includes the (eastern) Dabie, the Hong'an (northwestern Dabie) and Tongbai regions. The new data yield ages ranging from 44 ± 3 to 142 ± 36 Ma and mean track lengths between 10 and 14.4 μm. Thermal history models based on the AFT data taken together with published ⁴⁰Ar/³⁹Ar, K–Ar, apatite and zircon (U–Th)/He and U–Pb data, exhibit a three-stage cooling pattern that is similar across the study region, commencing with an Early Cretaceous rapid cooling event, followed by a period of relative thermal stability during which rocks remained at temperatures within the AFT partial annealing zone (60–110 °C) and ending with a possible renewed phase of accelerated cooling during Pliocene to Recent time. The first cooling phase followed large-scale transtensional deformation between 140 and 110 Ma and is related to Early Cretaceous eastward tectonic escape and Pacific back arc extension. Between this phase and the subsequent slow cooling phase, a transition period from 120 to 80 Ma (to 70 to 45 Ma along the Tan–Lu fault) was characterised by a relatively low cooling rate (3–5 °C/Ma). This transition is likely related to a tectonic response associated with the mid-Cretaceous subduction of the Izanagi–Pacific plate as well as lithospheric extension and thinning in eastern Asia. The present regional AFT age pattern is therefore basically controlled by the Early Cretaceous rapid cooling event, but finally shaped through active Cenozoic faulting. Following the transition phase the subsequent slow cooling phase pattern implies a net reduction in horizontal compressional stress corresponding to increased extension rates along the continental margin due to the decrease in plate convergence. Modelling of the AFT data suggests a possible Pliocene–Recent cooling episode, which may be supported by increased rates of sedimentation observed in adjacent basins. This cooling phase may be interpreted as a response to the far-field effects of the frontal India–Eurasia collision to the west. Approximate estimates suggest that the total amount of post 120 Ma denudation across the UHP orogen ranged from 2.4 to 13.2 km for different tectonic blocks and ranged from 0.8 to 9.7 km during the Cretaceous to between 1.7 and 3.8 km during the Cenozoic.     

Archean greenstone-tonalite duality: Thermochemical mantle convection models or plate tectonics in the early Earth global dynamics?

Mantle convection and plate tectonics are one system, because oceanic plates are cold upper thermal boundary layers of the convection cells. As a corollary, Phanerozoic-style of plate tectonics or more likely a different version of it (i.e. a larger number of slowly moving plates, or similar number of faster plates) is expected to have operated in the hotter, vigorously convecting early Earth. Despite the recent advances in understanding the origin of Archean greenstone–granitoid terranes, the question regarding the operation of plate tectonics in the early Earth remains still controversial. Numerical model outputs for the Archean Earth range from predominantly shallow to flat subduction between 4.0 and 2.5 Ga and well-established steep subduction since 2.5 Ga [Abbott, D., Drury, R., Smith, W.H.F., 1994. Flat to steep transition in subduction style. Geology 22, 937–940], to no plate tectonics but rather foundering of 1000 km sectors of basaltic crust, then “resurfaced” by upper asthenospheric mantle basaltic melts that generate the observed duality of basalts and tonalities [van Thienen, P., van den Berg, A.P., Vlaar, N.J., 2004a. Production and recycling of oceanic crust in the early earth. Tectonophysics 386, 41–65; van Thienen, P., Van den Berg, A.P., Vlaar, N.J., 2004b. On the formation of continental silicic melts in thermochemical mantle convection models: implications for early Earth. Tectonophysics 394, 111–124]. These model outputs can be tested against the geological record. Greenstone belt volcanics are composites of komatiite–basalt plateau sequences erupted from deep mantle plumes and bimodal basalt–dacite sequences having the geochemical signatures of convergent margins; i.e. horizontally imbricated plateau and island arc crust. Greenstone belts from 3.8 to 2.5 Ga include volcanic types reported from Cenozoic convergent margins including: boninites; arc picrites; and the association of adakites–Mg andesites- and Nb-enriched basalts.Archean cratons were intruded by voluminous norites from the Neoarchean through Proterozoic; norites are accounted for by melting of subduction metasomatized Archean continental lithospheric mantle (CLM). Deep CLM defines Archean cratons; it extends to  350 km, includes the diamond facies, and xenoliths signify a composition of the buoyant, refractory, residue of plume melting, a natural consequence of imbricated plateau-arc crust. Voluminous tonalites of Archean greenstone–granitoid terranes show a secular trend of increasing Mg#, Cr, Ni consistent with slab melts hybridizing with thicker mantle wedge as subduction angle steepens. Strike-slip faults of 1000 km scale; diachronous accretion of distinct tectonostratigraphic terranes; and broad Cordilleran-type orogens featuring multiple sutures, and oceanward migration of arcs, in the Archean Superior and Yilgarn cratons, are in common with the Altaid and Phanerozoic Cordilleran orogens. There is increasing geological evidence of the supercontinent cycle operating back to  2.7 Ga: Kenorland or Ur  2.7–2.4 Ga; Columbia  1.6–1.4 Ga; Rodinia  1100–750 Ma; and Pangea  230 Ma. High-resolution seismic reflection profiling of Archean terranes reveals a prevalence of low angle structures, and evidence for paleo-subduction zones. Collectively, the geological–geochemical–seismic records endorse the operation of plate tectonics since the early Archean.     

A late Quaternary paleotemperature record from Hanging Lake, northern Yukon Territory, eastern Beringia

The late Quaternary paleoclimate of eastern Beringia has primarily been studied by drawing qualitative inferences from vegetation shifts. To quantitatively reconstruct summer temperatures, we analyzed lake sediments for fossil chironomids, and additionally we analyzed the sediments for fossil pollen and organic carbon content. A comparison with the δ¹⁸O record from Greenland indicates that the general climatic development of the region throughout the last glaciation–Holocene transition differed from that of the North Atlantic region. Between  17 and 15 ka, mean July air temperature was on average 5°C colder than modern, albeit a period of near-modern temperature at  16.5 ka. Total pollen accumulation rates ranged between  180 and 1200 grains cm^− 2 yr^− 1. At  15 ka, approximately coeval with the Bølling interstadial, temperatures again reached modern values. At  14 ka, nearly 1000 yr after warming began, Betula pollen percentages increased substantially and mark the transition to shrub-dominated pollen contributors. Chironomid-based inferences suggest no evidence of the Younger Dryas stade and only subtle evidence of an early Holocene thermal maximum, as temperatures from  15 ka to the late Holocene were relatively stable. The most recognizable climatic oscillation of the Holocene occurred from  4.5 to 2 ka.