Evaluating crude oil chemical dispersion efficacy in a flow-through wave tank under regular non-breaking wave and breaking wave conditions

Testing dispersant effectiveness under conditions similar to that of the open environment is required for improvements in operational procedures and the formulation of regulatory guidelines. To this end, a novel wave tank facility was fabricated to study the dispersion of crude oil under regular non-breaking and irregular breaking wave conditions. This wave tank facility was designed for operation in a flow-through mode to simulate both wave- and current-driven hydrodynamic conditions. We report here an evaluation of the effectiveness of chemical dispersants (Corexit^® EC9500A and SPC 1000^™) on two crude oils (Medium South American [MESA] and Alaska North Slope [ANS]) under two different wave conditions (regular non-breaking and plunging breaking waves) in this wave tank. The dispersant effectiveness was assessed by measuring the water column oil concentration and dispersed oil droplet size distribution. In the absence of dispersants, nearly 8-19% of the test crude oils were dispersed and diluted under regular wave and breaking wave conditions. In the presence of dispersants, about 21-36% of the crude oils were dispersed and diluted under regular waves, and 42-62% under breaking waves. Consistently, physical dispersion under regular waves produced large oil droplets (volumetric mean diameter or VMD ? 300 μm), whereas chemical dispersion under breaking waves created small droplets (VMD ? 50 μm). The data can provide useful information for developing better operational guidelines for dispersant use and improved predictive models on dispersant effectiveness in the field.     

Investigation and Remediation of Petroleum Product Releases from Residential Storage Tanks

Releases of petroleum products from leaking residential storage tanks are a growing problem in the stale of New Jersey. Approximately two releases per day have been reported to the New Jersey Department of Environmental Protection. Product releases may cause aquifers to become contaminated, may affect surface water, or cause vapor problems inside households. As of 1992, there arc no federal or state regulations pertaining to the maintenance and monitoring of residential petroleum storage tanks. Regulations are essential for protecting drinking water supplies. The regulations must address installation procedures, lank materials, monitoring, and tank location.     

Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.     

Risk assessment for optimal freshwater inflow in response to sustainability indicators in semi-arid coastal bay

Coastal zones are the primary interface for the exchange of natural and man-made materials between terrestrial and coastal ecosystems. While continuous industrial development and population growth in the coastal region promote unprecedented economic prosperity, water resource management in bay and estuary areas turns out to be a crucial challenge. Therefore, local, state, and federal water planning groups are attempting to manage the supply of freshwater inflow based on sustainability goals, especially for semi-arid coastal regions like South Texas. Surface and ground water management practices in this semi-arid coastal region are implemented to ensure an ever-lasting water supply on one hand and to maintain ecosystem integrity in the bay and estuary system on the other hand. The aim of this study is to apply a stochastic compromise programming model to identify a compromise solution under uncertainty in terms of two competing objectives: minimizing freshwater release from a coastal reservoir and maximizing fishery harvest in its associated bay—Corpus Christi Bay, South Texas. The global criterion method used in the solution procedure seeks to select a compromise solution that possesses the shortest distance from a positive ideal solution (PIS) and the farthest distance from a negative ideal solution (NIS). Solutions were found using three distance-based functions in conjunction with stochastic constraints reflecting the risk levels involved in decision-making. Results indicate that current flows in the mouth of the Nueces River are not sufficient to maintain the salinity level and to satisfy harvest requirements in the Corpus Christi Bay if water supply goal in the city has higher priority. Therefore, a sustainable management plan of exploring the structure of demand and supply is highly desirable in this fast growing urban region.     

Assessment of chemical dispersant effectiveness in a wave tank under regular non-breaking and breaking wave conditions

Current chemical dispersant effectiveness tests for product selection are commonly performed with bench-scale testing apparatus. However, for the assessment of oil dispersant effectiveness under real sea state conditions, test protocols are required to have hydrodynamic conditions closer to the natural environment, including transport and dilution effects. To achieve this goal, Fisheries and Oceans Canada and the US Environmental Protection Agency (EPA) designed and constructed a wave tank system to study chemical dispersant effectiveness under controlled mixing energy conditions (regular non-breaking, spilling breaking, and plunging breaking waves). Quantification of oil dispersant effectiveness was based on observed changes in dispersed oil concentrations and oil-droplet size distribution. The study results quantitatively demonstrated that total dispersed oil concentration and breakup kinetics of oil droplets in the water column were strongly dependent on the presence of chemical dispersants and the influence of breaking waves. These data on the effectiveness of dispersants as a function of sea state will have significant implications in the drafting of future operational guidelines for dispersant use at sea.     

A three-dimensional discontinuous Galerkin model applied to the baroclinic simulation of Corpus Christi Bay

In this work, we present results of a numerical study of Corpus Christi Bay, Texas and surrounding regions and compare simulated model results to recorded data. The validation data for the year 2000 include the water elevation, velocity, and salinity at selected locations. The baroclinic computations were performed using the University of Texas Bays and Estuaries 3D (UTBEST3D) simulator based on a discontinuous Galerkin finite element method for unstructured prismatic meshes. We also detail some recent advances in the modeling capabilities of UTBEST3D, such as a novel turbulence scheme and the support for local vertical discretization on parts of the computational domain. All runs were conducted on parallel clusters; an evaluation of parallel performance of UTBEST3D is included.     

Large-scale dispersant leaching and effectiveness experiments with oils on calm water

The use of dispersants to treat oil spills in calm seas is discouraged because there is insufficient ‘mixing energy’ to cause immediate dispersion of the oil. However, dispersants might be applied while the seas are calm, in the expectation that they would work later when sea states increase. The present study examined the persistence of dispersants in treated oil slicks on calm water in a large outdoor wave tank. Test slicks, pre-mixed with dispersant, were allowed to stand on static and flowing water for up to six days, after which their dispersibility was tested by exposing them to breaking waves. Results showed that thicker slicks exposed to calm water for up to six days dispersed completely with the addition of breaking waves. Thinner slicks and slicks exposed to water movement became less dispersible within two days. The loss of dispersibility was caused by dispersant loss rather than by oil weathering.     

Effectiveness and toxicity of an oil dispersant in large outdoor salt water tanks

Use of the dispersant, Oilsperse 43, increased the dispersion of Venezuelan Guanipa crude oil. The resulting mixture was more homogeneous and the oil slick less viscous than in the oil tank. The dispersant appeared to retard formation of the familiar “crust” on the surface. A weathered crude oil plus dispersant mixture with an oil concentration of 250 μg/l was lethal to over 50% of the test organisms, green sea urchins, within 4 days. No mortalities occurred among urchins exposed to the crude oil treatment.     

Droplet breakup in subsurface oil releases – Part 1: Experimental study of droplet breakup and effectiveness of dispersant injection

Size distribution of oil droplets formed in deep water oil and gas blowouts have strong impact on the fate of the oil in the environment. However, very limited data on droplet distributions from subsurface releases exist. The objective of this study has been to establish a laboratory facility to study droplet size versus release conditions (rates and nozzle diameters), oil properties and injection of dispersants (injection techniques and dispersant types). This paper presents this facility (6 m high, 3 m wide, containing 40 m³ of sea water) and introductory data. Injection of dispersant lowers the interfacial tension between oil and water and cause a significant reduction in droplet size. Most of this data show a good fit to existing Weber scaling equations. Some interesting deviations due to dispersant treatment are further analyzed and used to develop modified algorithms for predicting droplet sizes in a second paper (Johansen et al., 2013).     

Development of a unified oil droplet size distribution model with application to surface breaking waves and subsea blowout releases considering dispersant effects

An oil droplet size model was developed for a variety of turbulent conditions based on non-dimensional analysis of disruptive and restorative forces, which is applicable to oil droplet formation under both surface breaking-wave and subsurface-blowout conditions, with or without dispersant application. This new model was calibrated and successfully validated with droplet size data obtained from controlled laboratory studies of dispersant-treated and non-treated oil in subsea dispersant tank tests and field surveys, including the Deep Spill experimental release and the Deepwater Horizon blowout oil spill. This model is an advancement over prior models, as it explicitly addresses the effects of the dispersed phase viscosity, resulting from dispersant application and constrains the maximum stable droplet size based on Rayleigh-Taylor instability that is invoked for a release from a large aperture.     

Estimation of drift limits for different seismic damage states of RC frame staging in elevated water tanks using Park and Ang damage index

Damage to elevated water tanks in past earthquakes can be attributed to the poor performance of their supporting frame staging. In order to ascertain the performance of these elevated water tanks, it is crucial to categorize the damage in quantifiable damage states. Among various parameters to quantify the damage states, the top drift of frame staging can be conveniently correlated to the different damage levels. In literature, drift limits corresponding to different damage states of the frame staging of the elevated water tank are not available. In the present study, drift limits for RC frame staging in elevated water tanks corresponding to different seismic damage states have been proposed. Various damage states of the elevated water tank have been determined using the Park and Ang damage index. The Park and Ang damage index utilizes results of both pushover analysis and incremental dynamic analysis. Twelve models of elevated water tanks have been developed considering variation in staging height and tank capacity. Incremental dynamic analysis has been performed using the suite of twelve actual earthquake ground motions. Based on the regression analysis between damage indexes and drift, limiting drift values for each damage state are proposed.     

Oil viscosity limitation on dispersibility of crude oil under simulated at-sea conditions in a large wave tank

This study determined the limiting oil viscosity for chemical dispersion of oil spills under simulated sea conditions in the large outdoor wave tank at the US National Oil Spill Response Test Facility in New Jersey. Dispersant effectiveness tests were completed using crude oils with viscosities ranging from 67 to 40,100 cP at test temperature. Tests produced an effectiveness-viscosity curve with three phases when oil was treated with Corexit 9500 at a dispersant-to-oil ratio of 1:20. The oil viscosity that limited chemical dispersion under simulated at-sea conditions was in the range of 18,690 cP to 33,400 cP. Visual observations and measurements of oil concentrations and droplet size distributions in the water under treated and control slicks correlated well with direct measurements of effectiveness. The dispersant effectiveness versus oil viscosity relationship under simulated at sea conditions at Ohmsett was most similar to those from similar tests made using the Institut Francais du Pétrole and Exxon Dispersant Effectiveness (EXDET) test methods.     

On the validation of a coupled water and energy balance model at small catchment scales

Catchment runoff is the most widely used catchment scale measurement in modelling studies, and we have a reasonable degree of confidence in its accuracy. The advent of satellites gives access to a new suite of measurements taken over a defined spatial range. These measurements, principally reflected or emitted radiation, provide hydrologists with new possibilities for quantifying the state of a catchment. Surface temperatures can be readily measured by a satellite on a scale comparable to the size of a small catchment.

In this paper we show that satellite sensed temperatures can provide an important measure of catchment status, which can complement runoff measurements in water balance studies. A one-dimensional model, which couples the land surface energy balance with the soil and surface water balance is tested by comparison with runoff and with remotely sensed surface temperature measurements. Simulations have been run over four years for two small catchments which have a fairly homogeneous vegetation, one being forest and its neighbour pasture. Satellite “surface” temperatures have been interpreted in terms of the energy balance, and used as a test of modelling accuracy. An “effective” surface temperature is calculated as a weighted mean of temperatures of the separate soil and leaf surfaces. This modelled “effective” temperature correlates well with Landsat TM surface temperatures.

When pasture replaces forest, the model predicts a reduction in evapotranspiration of around 30%, a three-fold increase in runoff, and an increase in mean soil moisture status. The change to pasture also results in a rise in mean effective surface temperature of about 4°C, and an increase in summer diurnal temperature range from 10 to 22°C. The winter diurnal temperature range is similar for both vegetation systems.

Inclusion of soil moisture variability in thermal properties results in an increase in mean daily maximum temperature of about 2°C in summer and winter, without much change in daily minima. The daily mean temperature is not significantly affected.     

Effects of dispersed oil on mangroves synthesis of a seven-year study

The results of a long-term program to determine the effects of oil and dispersant on red mangroves and black mangroves are presented. Laboratory experiments were conducted to determine the effects of three oils and dispersant on juvenile red mangroves and black mangroves. A field experiment was conducted to determine the effects of a crude oil and dispersant on a mature mangrove forest in Panama. Our studies indicate that exposure of mangrove seedlings to oil and dispersant in the laboratory resulted in changes of growth, respiration, and transpiration, and led to uptake of petroleum hydrocarbons. Exposure of a mature red mangrove forest to oil and dispersant resulted in many of the same effects observed in the laboratory and at other oil spill sites. These effects were greatly reduced at the site treated with oil and dispersant when compared to the site treated with whole oil.     

Inhibition of Fertilization and Larval Metamorphosis of the Coral Acropora millepora (Ehrenberg, 1834) by Petroleum Products

Accidental oil spills from ships or rigs and inputs of effluent such as production formation water (PFW) are key perceived threats to tropical biota from industry activities. Scleractinian corals are an important functional component of tropical reefs and the abundance, diversity and resilience of coral communities can be used as an indicator of ecosystem health. In this paper, we report the effects of petroleum products, including water accommodated fractions (WAF) of crude oil, PFW and dispersant (Corexit 9527), on fertilization and larval metamorphosis of the widespread scleractinian coral, Acropora millepora (Ehrenberg, 1834) in laboratory-based assays. At 20% v/v PFW fertilization was inhibited by 25%. This concentration was equivalent 0.0721 mg l⁻¹ total hydrocarbon (THC). In contrast, larval metamorphosis was more sensitive to this effluent, with 98% metamorphosis inhibited at the same concentration. Crude oil WAF did not inhibit fertilization of gametes until dispersant was introduced. Dispersed oil was slightly more toxic to fertilization than dispersant alone, suggesting toxicity to that event may be additive. The minimum concentration of dispersed oil which inhibited fertilization was 0.0325 mg l⁻¹ THC. Larval metamorphosis was more sensitive than fertilization to crude oil. Although crude oil and dispersant inhibited larval metamorphosis individually, this toxicity was magnified when larvae were exposed to combinations of both. Crude oil inhibited metamorphosis at 0.0824 mg l⁻¹ THC and at 0.0325 mg l⁻¹ THC when dispersed in 10% v/v (dispersant/oil). Management of petroleum-related risks to spawning corals should consider not only the occurrence of the annual coral spawning event, but also the subsequent 1–3-week period during which most larval metamorphosis and recruitment occur.     

Water balance approach under extreme arid conditions — A case study of Tabalah Basin,Saudi Arabia

Quantification of water balance components, under arid conditions, is essential to the development of water management policies. This study demonstrates the application of the mass water balance approach for the assessment of water resources in a typical watershed located in the southwestern region of Saudi Arabia. The water balance approach was used, on an event basis, to express the amount of precipitation for 13 storms over a three year period, as a percentage of other hydrological components such as runoff, evaporation, and recharge. The study indicated that 63 per cent of precipitation is lost through evaporation from the water surface during flooding, and from the upper layers of the soil surface immediately after storms. Another 32 per cent is stored in the form of soil moisture in the unsaturated layers below the effective evaporation depth. Only 3 per cent of the precipitation was transformed into surface runoff; however, 75 per cent of this contributes towards groundwater recharge. This study has illustrated that the mass water balance approach can be used, with reasonable accuracy, to quantify the components of the hydrological processes under arid conditions, where a reliable data base is available. This, in turn, will help in the development of appropriate water management policies for arid regions.     

Effects of temperature and wave conditions on chemical dispersion efficacy of heavy fuel oil in an experimental flow-through wave tank

The effectiveness of chemical dispersants (Corexit 9500 and SPC 1000) on heavy fuel oil (IFO180 as test oil) has been evaluated under different wave conditions in a flow-through wave tank. The dispersant effectiveness was determined by measuring oil concentrations and droplet size distributions. An analysis of covariance (ANCOVA) model indicated that wave type and temperature significantly (p < 0.05) affected the dynamic dispersant effectiveness (DDE). At higher temperatures (16 °C), the test IFO180 was effectively dispersed under breaking waves with a DDE of 90% and 50% for Corexit 9500 and SPC 1000, respectively. The dispersion was ineffective under breaking waves at lower temperature (10 °C), and under regular wave conditions at all temperatures (10-17 °C), with DDE < 15%. Effective chemical dispersion was associated with formation of smaller droplets (with volumetric mean diameters or VMD ? 200 μm), whereas ineffective dispersion produced large oil droplets (with VMD ? 400 μm).     

Review of behaviour of oil in freezing environments

The current knowledge of the physical fate and behaviour of crude oil and petroleum products spilled in Arctic situations is reviewed. The fate and final deposition of oil in marine conditions is presented as based on the extant literature.

Spreading models were evaluated for oil on ice, under ice, in snow, in brash ice, and between blocks of ice. Models of oil transport under sheet and broken ice were considered, both for sea and river conditions. The ability of ice sheets to trap oil is discussed in relation to oil storage capacity. The effects of oil on a growing ice sheet were examined, both in terms of ice formation and the thermal effects of oil inclusions in ice. The migration of oil through ice was reviewed, focussing primarily on the movement through brine channels. The effects of oil on the surface of ice were considered, with emphasis on the effects of surface pools on ice melt. Similar consideration was given to the effects of oil on snow on the surface of ice.

The few quantitative studies of oil in open and dynamic ice conditions are reviewed. Observations of intentional small-scale spills in leads and ice fields are reviewed and compared with observations from real spills. The conditions under which “oil pumping” from leads occurs were quantified. The most common ultimate fate of oil in an ice field is to be released onto the water surface.     

考虑桩土作用的储罐模拟地震振动台试验

为研究考虑桩土相互作用的储液罐的动力响应及长周期地震波对储液晃动、储罐提离的影响,根据量纲分析法设计了桩-土-储罐模型进行了振动台试验。试验中采用4条基岩波、4条地表波进行振动台试验。试验显示基岩波与地表波输入时,体系变化规律基本一致,其结果表明:土体地表加速度被放大,且输入加速度峰值增加,地表加速度放大倍数减小;一般地震波时,随着输入加速度峰值的增加,储液晃动波高大致呈线性增加。长周期地震波下则为非线性增加,且晃动波较大。此外,液体产生的晃动波高与储罐类型相关。细高型储罐产生的波高稍大;储罐提离高度随着输入加速度峰值的增加呈非线性增长。长周期地震波激励下,储罐提离高度小于一般地震波时的提离高度。细高型储罐在长短周期地震波激励下,提离高度较为接近,而一般储罐在两种地震波激励下,提离高度相差较大。细高型储罐提离高度大于一般储罐的提离高度。建议在储罐设计时考虑长周期地震波的影响。     

Effects of Olestra on Organic and Solids Removal in Septic Tanks

A field study was conducted to examine the fate and potential effects of olestra, a non-caloric fat replacer, in septic tanks. The study compared the performance of parallel septic tanks, which were led domestic waste water with liquid and solid forms of olestra, against a control tank receiving waste water without olestra. Results showed that 36 g/d of olestra dosed to the tanks (a three-fold exaggeration of expected loadings) had no adverse effect on system operation (based on visual observations and sludge accumulation) or performance (based on removal of organic content and solids) over a six-month period. Removal efficiencies for total suspended solids (TSS), carbonaceous biochemical oxygen demand (CBOD), and chemical oxygen demand (COD) were not significantly different (p<0.05) in the olestra tanks when compared to the control tank. In addition, a relatively small amount of the total olestra added (3 to 6%) was recovered in the septic tank effluents over the course of the study. Accumulation of tank solids was not affected as measured sludge levels in the tank at the middle and end of the study showed no difference between the olestra dosed tanks and the control tank.