Thermal evolution of the Tseel terrane,SW Mongolia and its relation to granitoid intrusions in the Central Asian Orogenic Belt

The timing and thermal effects of granitoid intrusions into accreted sedimentary rocks are important for understanding the growth process of continental crust. In this study, the petrology and geochronology of pelitic gneisses in the Tseel area of the Tseel terrane, SW Mongolia, are examined to understand the relationship between igneous activity and metamorphism during crustal evolution in the Central Asian Orogenic Belt (CAOB). Four mineral zones are recognized on the basis of progressive changes in the mineral assemblages in the pelitic gneisses, namely: the garnet, staurolite, sillimanite and cordierite zones. The gneisses with high metamorphic grades (i.e. sillimanite and cordierite zones) occur in the central part of the Tseel area, where granitoids are abundant. To the north and south of these granitoids, the metamorphic grade shows a gradual decrease. The composition of garnet in the pelitic gneisses varies systematically across the mineral zones, from grossular‐rich garnet in the garnet zone to zoned garnet with grossular‐rich cores and pyrope‐rich rims in the staurolite zone, and pyrope‐rich garnet in the sillimanite and cordierite zones. Thermobarometric analyses of individual garnet crystals reveal two main stages of metamorphism: (i) a high‐P and low‐T stage (as recorded by garnet in the garnet zone and garnet cores in the staurolite zone) at 520–580 °C and 4.5–7 kbar in the kyanite stability field and (ii) a low‐P and high‐T stage (garnet rims in the staurolite zone and garnet in the sillimanite and cordierite zones) at 570–680 °C and 3.0–6.0 kbar in the sillimanite stability field. The earlier high‐P metamorphism resulted in the growth of kyanite in quartz veins within the staurolite and sillimanite zones. The U–Pb zircon ages of pelitic gneisses and granitoids reveal that (i) the protolith (igneous) age of the pelitic gneisses is c. 510 Ma; (ii) the low‐P and high‐T metamorphism occurred at 377 ± 30 Ma; and (iii) this metamorphic stage was coeval with granitoid intrusion at 385 ± 7 Ma. The age of the earlier low‐T and high‐P metamorphism is not clearly recorded in the zircon, but probably corresponds to small age peaks at 450–400 Ma. The low‐P and high‐T metamorphism continued for c. 100 Ma, which is longer than the active period of a single granitoid body. These findings indicate that an elevation of geotherm and a transition from high‐P and low‐T to low‐P and high‐T metamorphism occurred, associated with continuous emplacement of several granitoids, during the crustal evolution in the Devonian CAOB.     

Progressive metamorphism of pelitic rocks from protolith to granulite facies, Dutchess County, New York, USA: constraints on the timing of fluid infiltration during regional metamorphism

A complete Barrovian sequence ranging from unmetamorphosed shales to sillimanite–K-feldspar zone metapelitic gneisses crops out in a region extending from the Hudson River in south-eastern New York state, USA, to the high-grade core of the Taconic range in western Connecticut. NNE-trending subparallel biotite, garnet, staurolite, kyanite, sillimanite and sillimanite–K-feldspar isograds have been identified, although the assignment of Barrovian zones in the high-grade rocks is complicated by the appearance of fibrolitic sillimanite at the kyanite isograd. Thermobarometric results and reaction textures are used to characterize the metamorphic history of the sequence. Pressure–temperature estimates indicate maximum metamorphic conditions of 475 °C, c. 3–4 kbar in the garnet zone to >720 °C, c. 5–6 kbar in the highest grade rocks exposed. Some samples in the kyanite zone record anomalous (low) peak conditions because garnet composition has been modified by fluid-assisted reactions. There is abundant petrographic and mineral chemical information indicating that the sequence (with the possible exception of the granulite facies zone) was infiltrated by a water-rich fluid after garnet growth was nearly completed. The truncation of fluid inclusion trails in garnet by rim growth or recrystallization, however, indicates that metamorphic reactions involving garnet continued subsequent to initial infiltration. The presence of these textures in some zones of a well-constrained Barrovian sequence allows determination of the timing of fluid infiltration relative to the P–T paths. Thermobarometric results obtained using garnet compositions at the boundary between fluid–inclusion-rich and inclusion-free regions of the garnet are interpreted to represent peak metamorphic conditions, whereas rim compositions record slightly lower pressures and temperatures. Assuming that garnet grew during a single metamorphic event, infiltration must have occurred at or slightly after the peak of metamorphism, i.e. 4–5 kbar and a temperature of c. 525–550 °C for staurolite and kyanite zone rocks.     

Timing of high-pressure metamorphism and exhumation of the eclogite type-locality (Kupplerbrunn–Prickler Halt, Saualpe, south-eastern Austria): constraints from correlations of the Sm–Nd, Lu–Hf, U–Pb and Rb–Sr isotopic systems

Sm–Nd, Lu–Hf, Rb–Sr and SIMS U–Pb data are presented for meta‐gabbroic eclogites from the eclogite type‐locality ( Haüy, 1822 ) Kupplerbrunn–Prickler Halt and other areas of the Saualpe (SE Austria) and Pohorje Mountains (Slovenia). Mg‐rich eclogites derived from early gabbroic cumulates are kyanite‐ and zoisite rich, whereas eclogites with lower Mg contents contain clinozoisite ± kyanite. Calculated P–T conditions at the final stages of high‐pressure metamorphism are 2.2 ± 0.2 GPa at 630–740 °C. Kyanite‐rich eclogites did not yield geologically meaningful Sm–Nd ages due to incomplete Nd isotope equilibration, whereas Sm–Nd multifraction garnet–omphacite regression for a low‐Mg eclogite from Kupplerbrunn yields an age of 91.1 ± 1.3 Ma. The Sm–Nd age of 94.1 ± 0.8 Ma obtained from the Fe‐rich core fraction of this garnet dates the initial stages of garnet growth. Zircon that also crystallized at eclogite facies conditions gives a weighted mean U–Pb SIMS age of 88.4 ± 8.1 Ma. Lu–Hf isotope analysis of a kyanite–eclogite from Kupplerbrunn yields 88.4 ± 4.7 Ma for the garnet–omphacite pair. Two low‐Mg eclogites from the Gertrusk locality of the Saualpe yield a multimineral Sm–Nd age of 90.6 ± 1.0 Ma. A low‐Mg eclogite from the Pohorje Mountains (70 km to the SE) gives a garnet–whole‐rock Lu–Hf age of 93.3 ± 2.8 Ma. These new age data and published Sm–Nd ages of metasedimentary host rocks constrain the final stages of the eo‐Alpine high‐pressure event in the Saualpe–Pohorje part of the south‐easternmost Austroalpine nappe system suggesting that garnet growth in the high‐pressure assemblages started at c. 95–94 Ma and ceased at c. 90–88 Ma, probably at the final pressure peak. Zircon and amphibole crystallization was still possible during incipient isothermal decompression. Rapid exhumation of the high‐pressure rocks was induced by collision of the northern Apulian plate with parts of the Austroalpine microplate, following Jurassic closure of the Permo‐Triassic Meliata back‐arc basin.     

Constraining the conditions of Barrovian metamorphism in Sikkim,India: P–T–t paths of garnet crystallization in the Lesser Himalayan Belt

Garnet crystallization in metapelites from the Barrovian garnet and staurolite zones of the Lesser Himalayan Belt in Sikkim is modelled utilizing Gibbs free energy minimization, multi‐component diffusion theory and a simple nucleation and growth algorithm. The predicted mineral assemblages and garnet‐growth zoning match observations remarkably well for relatively tight, clockwise metamorphic P–T paths that are characterized by prograde gradients of ～30 °C kbar^?1 for garnet‐zone rocks and ～20 °C kbar^?1 for rocks from the staurolite zone. Estimates for peak metamorphic temperature increase up‐structure toward the Main Central Thrust. According to our calculations, garnet stopped growing at peak pressures, and protracted heating after peak pressure was absent or insignificant. Almost identical P–T paths for the samples studied and the metamorphic continuity of the Lesser Himalayan Belt support thermo‐mechanical models that favour tectonic inversion of a coherent package of Barrovian metamorphic rocks. Time‐scales associated with the metamorphism were too short for chemical diffusion to substantially modify garnet‐growth zoning in rocks from the garnet and staurolite zones. In general, the pressure of initial garnet growth decreases, and the temperature required for initial garnet growth was reached earlier, for rocks buried closer toward the MCT. Deviations from this overall trend can be explained by variations in bulk‐rock chemistry.     

U-Pb systematics of garnet: dating the growth of garnet in the late Archean Pikwitonei granulite domain at Cauchon and Natawahunan Lakes,Manitoba, Canada

This study considers the potential of using the U-Pb dating of garnet for determining quantitative P-T-t paths for the late Archean metamorphism in the Pikwitonei granulite domain. Garnets for U-Pb dating were selected mainly from samples that also provide information on pressure and temperature. The garnets used for dating were clear and free of any visible inclusions. Pb concentrations range from 63 ppb to 966 ppb and U from 136 ppb to 1143 ppb. The measured ²⁰⁶Pb/²⁰⁴Pb ratios range from 52.8 to 529.4. The ages are generally discordant with U/Pb ages that may lie above or below concordia. The discordance is caused by a recent disturbance of the U/Pb ratio in the garnets as indicated by replicate analyses on the same garnet separates that reproduce ²⁰⁷Pb/²⁰⁶Pb ages well within analytical uncertainty and in most cases within ±1.5 Ma at 2600–2750 Ma. High grade metamorphism continued over a period of at least one hundred million years, but the garnet-K-feldspar Pb-Pb ages suggest that, during this time, garnet growth has been favored during three distinct periods in the Cauchon Lake area: 2700–2687 Ma 2660–2637 Ma 2605–2591 Ma The ca. 2695 Ma garnet ages from Cauchon Lake date the time of melting and staurolite breakdown during prograde metamorphism, the ca. 2640 Ma ages date the time of extensive migmatization and the last period of metamorphic garnet growth, the ca. 2600 Ma ages date the time of crystallization of igneous garnet in late granitic intrusions. Peak metamorphism occurred around 2640 Ma followed by the intrusions of pegmatites starting at 2629 Ma. The Pb-Pb ages for garnet are similar to the U-Pb ages for zircon that date a leucocratic mobilizate (2695 Ma), a plagioclaseamphibole mobilizate (2637 Ma) and pegmatite (2598 Ma) (Heaman et al. 1986 a; Krogh et al. 1986; this study). Xenocrysts of garnet from 2600 Ma old graphic granites give minimum ages of 2984 Ma and 2741 Ma which are minima for the times of garnet growth in the source of the granites. The agreement of the zircon and garnet ages suggests that the metamorphism may have been punctuated by events that led to the development of melts or encouraged mineral growth at specific times. If so, the prograde and retrograde paths of metamorphism in the area may have contained minor excursions in pressure, temperature or fluid fugacities. In the Natawahunan Lake area some 50 km northwest of Cauchon Lake, garnet growth associated with the prograde breakdown of staurolite occurred at ca. 2744–2734 Ma. This suggests that a similar style of metamorphism may have occurred earlier in the Natawahunan Lake area than at Cauchon Lake area, or higher grades of metamorphism were reached earlier and were of longer duration associated with the somewhat greater depths in the Natawahunan Lake area. These results indicate the these garnets, which are 0.1–1 cm in diameter, have maintained closed system behavior for U and Pb at peak metamorphic conditions, i.e. temperatures up to 800° C and pressures of 7.5 kb.     

An Early Palaeozoic HP/HT granulite–garnet peridotite association in the south Altyn Tagh, NW China: P–T history and U-Pb geochronology

High‐pressure kyanite‐bearing felsic granulites in the Bashiwake area of the south Altyn Tagh (SAT) subduction–collision complex enclose mafic granulites and garnet peridotite‐hosted sapphirine‐bearing metabasites. The predominant felsic granulites are garnet + quartz + ternary feldspar (now perthite) rocks containing kyanite, plagioclase, biotite, rutile, spinel, corundum, and minor zircon and apatite. The quartz‐bearing mafic granulites contain a peak pressure assemblage of garnet + clinopyroxene + ternary feldspar (now mesoperthite) + quartz + rutile. The sapphirine‐bearing metabasites occur as mafic layers in garnet peridotite. Petrographical data suggest a peak assemblage of garnet + clinopyroxene + kyanite + rutile. Early kyanite is inferred from a symplectite of sapphirine + corundum + plagioclase ± spinel, interpreted to have formed during decompression. Garnet peridotite contains an assemblage of garnet + olivine + orthopyroxene + clinopyroxene. Thermobarometry indicates that all rock types experienced peak P–T conditions of 18.5–27.3 kbar and 870–1050 °C. A medium–high pressure granulite facies overprint (780–820 °C, 9.5–12 kbar) is defined by the formation of secondary clinopyroxene ± orthopyroxene + plagioclase at the expense of garnet and early clinopyroxene in the mafic granulites, as well as by growth of spinel and plagioclase at the expense of garnet and kyanite in the felsic granulite. SHRIMP II zircon U‐Pb geochronology yields ages of 493 ± 7 Ma (mean of 11) from the felsic granulite, 497 ± 11 Ma (mean of 11) from sapphirine‐bearing metabasite and 501 ± 16 Ma (mean of 10) from garnet peridotite. Rounded zircon morphology, cathodoluminescence (CL) sector zoning, and inclusions of peak metamorphic minerals indicate these ages reflect HP/HT metamorphism. Similar ages determined for eclogites from the western segment of the SAT suggest that the same continental subduction/collision event may be responsible for HP metamorphism in both areas.     

Prograde destruction and formation of monazite and allanite during contact and regional metamorphism of pelites: petrology and geochronology

The conditions at which monazite and allanite were produced and destroyed during prograde metamorphism of pelitic rocks were determined in a Buchan and a Barrovian regional terrain and in a contact aureole, all from northern New England, USA. Pelites from the chlorite zone of each area contain monazite that has an inclusion-free core surrounded by a highly irregular, inclusion-rich rim. Textures and ²⁰⁸Pb/²³²Th dates of these monazites in the Buchan terrain, obtained by ion microprobe, suggest that they are composite grains with detrital cores and very low-grade metamorphic overgrowths. At exactly the biotite isograd in the regional terrains, composite monazite disappears from most rocks and is replaced by euhedral metamorphic allanite. At precisely the andalusite or kyanite isograd in all three areas, allanite, in turn, disappears from most rocks and is replaced by subhedral, chemically unzoned monazite neoblasts. Allanite failed to develop at the biotite isograd in pelites with lower than normal Ca and/or Al contents, and composite monazite survived at higher grades in these rocks with modified texture, chemical composition, and Th-Pb age. Pelites with elevated Ca and/or Al contents retained allanite in the andalusite or kyanite zone. The best estimate of the time of peak metamorphism at the andalusite or kyanite isograd is the mean Th-Pb age of metamorphic monazite neoblasts that have not been affected by retrograde metamorphism: 364.3Dž.5 Ma in the Buchan terrain, 352.9NJ.9 Ma in the Barrovian terrain, and 403.4LJ.9 Ma in the contact aureole. Some metamorphic monazites from the Buchan terrain have ages partially to completely reset during an episode of retrograde metamorphism at 343.1Nj.1 Ma. Interpretation of Th-Pb ages of individual composite monazite grains is complicated by the occurrence of subgrain domains of detrital material intergrown with domains of material formed or recrystallized during prograde and retrograde metamorphism.     

Metamorphic petrology and zircon geochronology of high-grade rocks from the central Mozambique Belt of Tanzania: crustal recycling of Archean and Palaeoproterozoic material during the Pan-African orogeny

New data on the metamorphic petrology and zircon geochronology of high‐grade rocks in the central Mozambique Belt (MB) of Tanzania show that this part of the orogen consists of Archean and Palaeoproterozoic material that was structurally reworked during the Pan‐African event. The metamorphic rocks are characterized by a clockwise P–T path, followed by strong decompression, and the time of peak granulite facies metamorphism is similar to other granulite terranes in Tanzania. The predominant rock types are mafic to intermediate granulites, migmatites, granitoid orthogneisses and kyanite/sillimanite‐bearing metapelites. The meta‐granitoid rocks are of calc‐alkaline composition, range in age from late Archean to Neoproterozoic, and their protoliths were probably derived from magmatic arcs during collisional processes. Mafic to intermediate granulites consist of the mineral assemblage garnet–clinopyroxene–plagioclase–quartz–biotite–amphibole ± K‐feldspar ± orthopyroxene ± oxides. Metapelites are composed of garnet‐biotite‐plagioclase ± K‐feldspar ± kyanite/sillimanite ± oxides. Estimated values for peak granulite facies metamorphism are 12–13 kbar and 750–800 °C. Pressures of 5–8 kbar and temperatures of 550–700 °C characterize subsequent retrogression to amphibolite facies conditions. Evidence for a clockwise P–T path is provided by late growth of sillimanite after kyanite in metapelites. Zircon ages indicate that most of the central part of the MB in Tanzania consists of reworked ancient crust as shown by Archean (c. 2970–2500 Ma) and Palaeoproterozoic (c. 2124–1837 Ma) protolith ages. Metamorphic zircon from metapelites and granitoid orthogneisses yielded ages of c. 640 Ma which are considered to date peak regional granulite facies metamorphism during the Pan‐African orogenic event. However, the available zircon ages for the entire MB in East Africa and Madagascar also document that peak metamorphic conditions were reached at different times in different places. Large parts of the MB in central Tanzania consist of Archean and Palaeoproterozoic material that was reworked during the Pan‐African event and that may have been part of the Tanzania Craton and Usagaran domain farther to the west.     

Integrated garnet and zircon–titanite geochronology constrains the evolution of ultra‐high–pressure terranes: An example from the Sulu orogen

Dating ultra‐high–pressure (UHP) metamorphic rocks provides important timing constraints on deep subduction zone processes. Eclogites, deeply subducted rocks now exposed at the surface, undergo a wide range of metamorphic conditions (i.e. deep subduction and exhumation) and their mineralogy can preserve a detailed record of chronologic information of these dynamic processes. Here, we present an approach that integrates multiple radiogenic isotope systems in the same sample to provide a more complete timeline for the subduction–collision–exhumation processes, based on eclogites from the Dabie–Sulu orogenic belt in eastern China, one of the largest UHP terranes on Earth. In this study, we integrate garnet Lu–Hf and Sm–Nd ages with zircon and titanite U–Pb ages for three eclogite samples from the Sulu UHP terrane. We combine this age information with Zr‐in‐rutile temperature estimates, and relate these multiple chronometers to different P–T conditions. Two types of rutile, one present as inclusions in garnet and the other in the matrix, record the temperatures of UHP conditions and a hotter stage, subsequent to the peak pressure (‘hot exhumation') respectively. Garnet Lu–Hf ages (c. 238–235 Ma) record the initial prograde growth of garnet, while coupled Sm–Nd ages (c. 219–213 Ma) reflect cooling following hot exhumation. The maximum duration of UHP conditions is constrained by the age difference of these two systems in garnet (c. 235–220 Ma). Complementary zircon and titanite U–Pb ages of c. 235–230 Ma and c. 216–206 Ma provide further constraints on the timing of prograde metamorphism and the ‘cold exhumation' respectively. We demonstrate that timing of various metamorphic stages can thus be determined by employing complementary chronometers from the same samples. These age results, combined with published data from adjacent areas, show lateral diachroneity in the Dabie–Sulu orogeny. Three sub‐blocks are thus defined by progressively younger garnet ages: western Dabie (243–238 Ma), eastern Dabie–northern Sulu (238–235 Ma) and southern Sulu terranes (225–220 Ma), which possibly correlate to different crustal slices in the recently proposed subduction channel model. These observed lateral chronologic variations in a large UHP terrane can possibly be extended to other suture zones.     

Delamerian‐aged metamorphism in the southern Curnamona Province,Australia: implications for the evolution of the Mesoproterozoic Olarian Orogeny

Monazite electron microprobe U–Th–Pb and garnet Sm–Nd isotopic data from metapelitic assemblages in the Willyama Supergroup in the southern Curnamona Province, south‐central Australia, indicate that the terrain underwent regional greenschist to amphibolite‐grade metamorphism during the c. 500 Ma Delamerian Orogeny. The Delamerian‐aged mineral assemblages include prograde garnet–staurolite and kyanite‐bearing associations that overprint andalusite‐ and sillimanite‐bearing assemblages that are interpreted to have developed during the c. 1600 Ma Olarian Orogeny. Importantly, the development of secondary kyanite‐bearing assemblages in the southern Curnamona Province has been used previously to suggest that the Olarian Orogeny followed an anticlockwise P–T evolution. If such assemblages are the product of c. 500 Ma metamorphism, then the anticlockwise P–T path is an apparent path, due to the overprint of a distinct metamorphic cycle c. 1100 Ma later. Making such distinctions is therefore extremely important when using the textural and metamorphic evolution of polycyclic terrains to model the thermal behaviour of the crust during orogeny. This study highlights the utility of in situ geochronology, linking age data to petrologically important phases and assemblages.     

Relating zircon and monazite domains to garnet growth zones: age and duration of granulite facies metamorphism in the Val Malenco lower crust

Zircon from a lower crustal metapelitic granulite (Val Malenco, N‐Italy) display inherited cores, and three metamorphic overgrowths with ages of 281 ± 2, 269 ± 3 and 258 ± 4 Ma. Using mineral inclusions in zircon and garnet and their rare earth element characteristics it is possible to relate the ages to distinct stages of granulite facies metamorphism. The first zircon overgrowth formed during prograde fluid‐absent partial melting of muscovite and biotite apparently caused by the intrusion of a Permian gabbro complex. The second metamorphic zircon grew after formation of peak garnet, during cooling from 850 °C to c. 700 °C. It crystallized from partial melts that were depleted in heavy rare earth elements because of previous, extensive garnet crystallization. A second stage of partial melting is documented in new growth of garnet and produced the third metamorphic zircon. The ages obtained indicate that the granulite facies metamorphism lasted for about 20 Myr and was related to two phases of partial melting producing strongly restitic metapelites. Monazite records three metamorphic stages at 279 ± 5, 270 ± 5 and 257 ± 4 Ma, indicating that formation ages can be obtained in monazite that underwent even granulite facies conditions. However, monazite displays less clear relationships between growth zones and mineral inclusions than zircon, hampering the correlation of age to metamorphism. To overcome this problem garnet–monazite trace element partitioning was determined for the first time, which can be used in future studies to relate monazite formation to garnet growth.     

Geochronology of high-pressure mafic granulite dykes in SW Sweden: tracking the P–T–t path of metamorphism using Hf isotopes in zircon and baddeleyite

Although the U–Pb zircon chronometer has been widely used for dating metamorphism in moderate‐ to high‐grade rocks, it is generally difficult to link the U–Pb age of zircon to specific metamorphic reactions. In this study, the initial Hf isotopic composition of secondary zircon is compared with the evolution of Hf isotopic composition of the bulk sample, back‐projected from the measured value through time. This approach may enhance the interpretation of radiometric ages performed on metamorphic mineral assemblages. Here, U–Pb, Sm–Nd and Lu–Hf geochronology and thermobarometry have been integrated and applied to two metamorphosed diabase dykes in the Sveconorwegian orogen, SW Sweden. The dykes are located ～5 km east of the NNE‐trending Göta Älv deformation zone in the Idefjorden terrane, and trend parallel to this zone. The Lunden dyke is recrystallized into a coronitic, granulite facies assemblage. U–Pb isotopic analyses of baddeleyite in this dyke indicate an emplacement age of c. 1300 Ma. Thermobarometric techniques applied to garnet and omphacitic clinopyroxene coronas indicate high‐pressure metamorphism at ～15 kbar and ～740 °C. The growth of polycrystalline zircon at the expense of baddeleyite occurred at 1046 ± 6 Ma. The identical Hf isotopic composition of polycrystalline zircon and baddeleyite shows that the baddeleyite‐to‐zircon transition took place before Hf equilibration among the other metamorphic minerals and, hence the c. 1046 Ma age of polycrystalline zircon sets an upper age limit of metamorphism of this sample. The Haregården dyke is recrystallized into a granoblastic transitional upper amphibolite to granulite facies assemblage. The estimated P–T conditions are ～10 kbar and ～700 °C. Analyses of small (～30 μm), clear and round zircon in this sample yield a Concordia U–Pb age of 1026 ± 4 Ma, which is indistinguishable from the Lu‐Hf and Sm‐Nd mineral isochron ages of 1027 ± 9 and 1022 ± 34 Ma, respectively. This type of secondary zircon plots at the lower end of the Lu‐Hf isochron and indicates simultaneous growth with garnet at c. 1026 Ma, a time when Hf isotopic equilibrium among minerals must have been reached.     

New Lu–Hf and Sm–Nd geochronology constrains the subduction of oceanic crust during the Carboniferous–Permian in the Dabie orogen

Eclogites from the Huwan shear zone in the western Dabie were investigated in terms of their P–T evolution, geochemistry, and combined Lu–Hf and Sm–Nd geochronology. Trace element and isotope data suggest a normal mid-ocean ridge rather than an intraplate or ocean island setting for the protoliths of the eclogites. Electron microprobe analyses of representative garnets show typical prograde zoning profiles. Estimated peak metamorphic temperatures of 540–590 °C most likely did not exceed the closure temperature of the Lu–Hf and Sm–Nd systems. The consistent Lu–Hf and Sm–Nd ages, therefore, most likely reflect garnet growth and are interpreted to reflect high-pressure eclogite-facies metamorphism due to the occurrence of omphacite inclusions from core to rim in garnets and the spherical geometry effect despite the well-preserved prograde zoning in the garnets. The high-pressure mineral assemblage of the eclogite yielded a statistically robust Lu–Hf age of 260.0 ± 1.0 Ma (2σ, 10 points, MSWD = 1.0) and a Sm–Nd age of 260.4 ± 2.0 Ma (2σ, 9 points, MSWD = 1.4), which are younger than the Carboniferous zircon U–Pb ages of ca. 310 Ma. The new Lu–Hf and Sm–Nd data, in combination with published geochronological data, define two distinct Carboniferous and Permian population ages for the oceanic-type eclogites from the Huwan shear zone, which may require that these rocks experienced two episodes of high-pressure metamorphism within less than 50 Myr.     

Garnet growth during crustal thickening in the Cascades Crystalline Core,Washington, USA

Garnet Sm–Nd and zircon U–Pb ages, and pressure–temperature–time paths elucidate Late Cretaceous crustal thickening which occurred within magmatic arc rocks of the Insular Superterrane. Voluminous tonalitic magma of the Mount Stuart batholith intruded at <3 kbar into upper crustal sedimentary rocks between 96 and 91 Ma, with initial intrusion prior to garnet growth in the metasedimentary rocks. Arc plutonism then shifted northward as crustal thickening commenced. Initial garnet growth, locally with kyanite and staurolite replacing andalusite, at c. 91 Ma was directly associated with intrusion of granodiorite to tonalite sheets at 7 kbar, north of the Mount Stuart batholith, within the Nason Ridge Migmatitic Gneiss. Subsequent heating and garnet growth, which postdates emplacement of large plutons, occurred between 88 and 86 Ma. This late garnet growth occurred at pressures of 6–8 kbar. The history of garnet growth and intrusion indicates that initial garnet zone and higher temperature metamorphism was restricted to contact aureoles. However, later widespread garnet growth at higher pressure probably resulted from heating as the orogenic wedge approached thermal equilibrium after crustal thickening. We conclude that metasedimentary rocks outside narrow contact aureoles remained at temperatures significantly below those of garnet growth and that the growth of garnet lasted <6 Myr. Heating to temperatures that stabilized garnet after pluton emplacement is compatible with intrusion of arc plutons into an accretionary wedge (Chiwaukum Schist) which was tectonically thickened and/or overthrust causing loading and thermal relaxation.     

The effect of allanite inclusions on U–Pb step-leaching ages and Sm–Nd isotope systematics of garnet from the Ogcheon metamorphic belt,South Korea

The Ogcheon metamorphic belt consists primarily of metasedimentary and metavolcanic rocks that have experienced polyphase tectonometamorphism since the Neoproterozoic. Peak metamorphism reaching up to lower-amphibolite facies produced ubiquitous garnet porphyroblasts in pelitic and mafic schists. To determine the timing of their formation, step-leaching experiments were undertaken for five garnet fractions separated from pelitic and quartz-hornblende-garnet schists. The U–Pb ages from three samples are identical within 2σ errors, ranging from 291 ± 41 Ma to 276 ± 29 Ma. The quasi-linearity of leachates in ²³⁸U–²⁰⁶Pb and ²⁰⁸Pb–²⁰⁶Pb diagrams suggests that U and Pb are released from a single mineral phase and that minor chemical fractionation between U and Pb may have occurred during the leaching experiment. Deviations of residues and bulk garnet fractions from the linear trend are attributed to partial dissolution of refractory inclusions of detrital zircon. Th/U ratios of leachates are in the range of 3.4–12, much higher than those of pure garnet, and suggest the contribution of allanite. Negative relationships in the Sm–Nd isochron diagram and similar ¹⁴⁷Sm/¹⁴⁴Nd ratios between whole rock and garnet corroborate the influence of light rare earth element (LREE)-rich allanite on the Sm–Nd isotopic system. Simple mass-balance calculations indicate that only a trace amount (0.35 modal%) of allanite inclusions should govern the U–Th–Pb systematics of garnet. Petrographic evidence together with the consistency in U–Pb ages suggests that allanite is a product of prograde metamorphism. Thus, peak metamorphism responsible for the growth of allanite-bearing garnet porphyroblasts in the Ogcheon metamorphic belt is best estimated to be Early Permian.     

Geochronology in migmatites a SmNd, UPb and RbSr study from the Proterozoic Damara belt (Namibia): implications for polyphase development of migmatites in high-grade terranes

Sm–Nd (garnet), U–Pb (monazite) and Rb–Sr (biotite) ages from a composite migmatite sample (Damara orogen, Namibia) constrain the time of high‐grade regional metamorphism and the duration of regional metamorphic events. Sm–Nd garnet whole‐rock ages for a strongly restitic melanosome and an adjacent intrusive leucosome yield ages of 534±5, 528±11 and 539±8 Ma. These results provide substantial evidence for pre‐500 Ma Pan‐African regional metamorphism and melting for this segment of the orogen. Other parts of the migmatite yield younger Sm–Nd ages of 488±9 Ma for melanosome and 496±10, 492±5 and 511±16 Ma for the corresponding leucosomes. Garnet from one xenolith from the leucosomes yields an age of 497±2 Ma. Major element compostions of garnet are different in terms of absolute abundances of pyrope and spessartine components, but the flat shape of the elemental patterns suggests late‐stage retrograde equilibration. Rare earth element compositions of the garnet from the different layers are similar except for garnet from the intrusive leucosome suggesting that they grew in different environments. Monazite from the leucosomes is reversely discordant and records ²⁰⁷Pb/²³⁵U ages between 536 and 529 Ma, indicating that this monazite represents incorporated residual material from the first melting event. Monazite from the mesosome MES 2 and the melanosome MEL 3 gives ²⁰⁷Pb/²³⁵U ages of 523 and 526 Ma, and 529 and 531 Ma, respectively, which probably indicates another thermal event. Previously published ²⁰⁷Pb/²³⁵U monazite data give ages between 525 and 521 Ma for composite migmatites, and 521 and 518 Ma for monazite from neosomes. Monazite from granitic to granodioritic veins indicates another thermal event at 507–505 Ma. These ages are also recorded in ²⁰⁷Pb/²³⁵U monazite data of 508 Ma from the metasediment MET 1 from the migmatite and also in the Sm–Nd garnet ages obtained in this study. Taken together, these ages indicate that high‐grade metamorphism started at c. 535 Ma (or earlier) and was followed by thermal events at c. 520 Ma and c. 505 Ma. The latter event is probably connected with the intrusion of a large igneous body (Donkerhoek granite) for which so far only imprecise Rb–Sr whole‐rock data of 520±15 Ma are available. Rb–Sr biotite ages from the different layers of the migmatite are 488, 469 and 473 Ma. These different ages indicate late‐stage disturbance of the Rb–Sr isotopic system on the sub‐sample scale. Nevertheless, these ages are close to the youngest Sm–Nd garnet ages, indicating rapid cooling rates between 13 and 20°C Ma^?1 and fast uplift of this segment of the crust. Similar Sm–Nd garnet and U–Pb monazite ages suggest that the closure temperatures for both isotopic systems are not very different in this case and are probably similar or higher than the previously estimated peak metamorphic temperatures of 730±30°C. The preservation of restitic monazite in leucosomes indicates that dissolution of monazite in felsic water‐undersaturated peraluminous melts can be sluggish. This study shows that geochronological data from migmatites can record polymetamorphic episodes in high‐grade terranes that often contain cryptic evidence for the nature and timing of early metamorphic events.     

Bulk chemical control on metamorphic monazite growth in pelitic schists and implications for U–Pb age data

Several petrographic studies have linked accessory monazite growth in pelitic schist to metamorphic reactions involving major rock‐forming minerals, but little attention has been paid to the control that bulk composition might have on these reactions. In this study we use chemographic projections and pseudosections to argue that discrepant monazite ages from the Mount Barren Group of the Albany–Fraser Orogen, Western Australia, reflect differing bulk compositions. A new Sensitive High‐mass Resolution Ion Microprobe (SHRIMP) U–Pb monazite age of 1027 ± 8 Ma for pelitic schist from the Mount Barren Group contrasts markedly with previously published SHRIMP U–Pb monazite and xenotime ages of c. 1200 Ma for the same area. All dated samples experienced identical metamorphic conditions, but preserve different mineral assemblages due to variable bulk composition. Monazite grains dated at c. 1200 Ma are from relatively magnesian rocks dominated by biotite, kyanite and/or staurolite, whilst c. 1027 Ma grains are from a ferroan rock dominated by garnet and staurolite. The latter monazite population is likely to have grown when staurolite was produced at the expense of garnet and chlorite, but this reaction was not intersected by more magnesian compositions, which are instead dominated by monazite that grew during an earlier, greenschist facies metamorphic event. These results imply that monazite ages from pelitic schist can vary depending on the bulk composition of the host rock. Samples containing both garnet and staurolite are the most likely to yield monazite ages that approximate the timing of peak metamorphism in amphibolite facies terranes. Samples too magnesian to ever grow garnet, or too iron‐rich to undergo garnet breakdown, are likely to yield older monazite, and the age difference can be significant in terranes with a polymetamorphic history.     

Pseudosection modelling and garnet Lu–Hf geochronology of HP amphibole schists constrain the closure of an ocean basin between the northern and southern Lhasa blocks,central Tibet

The P–T–t path of high‐P metamorphic rocks in subduction zones may reveal valuable information regarding the tectonic processes along convergent plate boundaries. Herein, we present a detailed petrological, pseudosection modelling and radiometric dating study of several amphibole schists of oceanic affinity from the Lhasa Block, Tibet. The amphibole schists experienced an overall clockwise P–T path that was marked by post‐P_max heating–decompression and subsequent isothermal decompression following the attainment of peak high‐P and low‐T conditions (~490°C and 1.6 GPa). Pseudosection modelling shows that the amphibole schists underwent water‐unsaturated conditions during prograde metamorphism, and the stability field of the assemblage extends to lower temperatures and higher pressures within the water‐unsaturated condition relative to water‐saturated model along the prograde path. The high‐P amphibole schists were highly reduced during retrograde metamorphism. Precise evaluation of the ferric iron conditions determined from the different compositions of epidote inclusions in garnet and matrix epidote is crucial for a true P–T estimate by garnet isopleth thermobarometry. Lu–Hf isotope analyses on garnet size separates from a garnet‐bearing amphibole schist yield four two‐point garnet–whole‐rock isochron ages from 228.2 ± 1.2 Ma to 224.3 ± 1.2 Ma. These Lu–Hf dates are interpreted to constrain the period of garnet growth and approximate the timing of prograde metamorphism because of the low peak metamorphic temperature of the rock and the well‐preserved Mn/Lu growth zoning in garnet. The majority of zircon U–Pb dates provide no constraints on the timing of metamorphism; however, two concordant U–Pb dates of 222.4 ± 3.9 Ma and 223.3 ± 4.2 Ma were obtained from narrow and uncommon metamorphic rims. Coexistence of zircon and sphene in the samples implies that the metamorphic zircon growth was likely assisted by retrogression of rutile to sphene during exhumation. The near coincident radiometric dates of zircon U–Pb and garnet Lu–Hf indicate rapid burial and exhumation of the amphibole schists, suggesting a closure time of c. 224–223 Ma for the fossil ocean basin between the northern and southern Lhasa blocks.     

Polymetamorphism, zircon growth and retention of early assemblages through the dynamic evolution of a continental arc in Fiordland, New Zealand

The Marguerite Amphibolite and associated rocks in northern Fiordland, New Zealand, contain evidence for retention of Carboniferous metamorphic assemblages through Cretaceous collision of an arc, emplacement of large volumes of mafic magma, high‐P metamorphism and then extensional exhumation. The amphibolite occurs as five dismembered aluminous meta‐gabbroic xenoliths up to 2 km wide that are enclosed within meta‐leucotonalite of the Lake Hankinson Complex. A first metamorphic event (M1) is manifest in the amphibolite as a pervasively lineated pargasite–anorthite–kyanite or corundum ± rutile assemblage, and as diffusion‐zoned garnet in pelitic schist xenoliths within the amphibolite. Thin zones of metasomatically Al‐enriched leucotonalite directly at the margins of each amphibolite xenolith indicate element redistribution during M1 and equilibration at 6.6 ± 0.8 kbar and 618 ± 25 °C. A second phase of recrystallization (M2) formed patchy and static margarite ± kyanite–staurolite–chlorite–plagioclase–epidote assemblages in the amphibolite, pseudomorphs of coronas in gabbronorite, and thin high‐grossular garnet rims in the pelitic schists. Conditions of M2, 8.8 ± 0.6 kbar and 643 ± 27 °C, are recorded from the rims of garnet in the pelitic schists. Cathodoluminescence imaging and simultaneous acquisition of U‐Th‐Pb isotopes and trace elements by depth‐profiling zircon grains from one pelitic schist reveals four stages of growth, two of which are metamorphic. The first metamorphic stage, dated as 340.2 ± 2.2 Ma, is correlated with M1 on the basis that the unusual zircon trace element compositions indicate growth from a metasomatic fluid derived from the surrounding amphibolite during penetrative deformation. A second phase of zircon overgrowth coupled with crosscutting relationships date M2 to between 119 and 117 Ma. The Early Carboniferous event has not previously been recognized in northern Fiordland, whereas the latter event, which has been identified in Early Cretaceous batholiths, their xenoliths, and rocks directly at batholith margins, is here shown to have also affected the country rock. However, the effects of M2 are fragmentary due to limited element mobility, lack of deformation, distance from a heat source and short residence time in the lower crust during peak P and T. It is possible that many parts of the Fiordland continental arc achieved high‐P conditions in the Early Cretaceous but retain earlier metamorphic or igneous assemblages.     

Separate or shared metamorphic histories of eclogites and surrounding rocks? An example from the Bohemian Massif

Eclogite boudins occur within an orthogneiss sheet enclosed in a Barrovian metapelite‐dominated volcano‐sedimentary sequence within the Velké Vrbno unit, NE Bohemian Massif. A metamorphic and lithological break defines the base of the eclogite‐bearing orthogneiss nappe, with a structurally lower sequence without eclogite exposed in a tectonic window. The typical assemblage of the structurally upper metapelites is garnet–staurolite–kyanite–biotite–plagioclase–muscovite–quartz–ilmenite ± rutile ± silli‐manite and prograde‐zoned garnet includes chloritoid–chlorite–paragonite–margarite, staurolite–chlorite–paragonite–margarite and kyanite–chlorite–rutile. In pseudosection modelling in the system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (NCKFMASH) using THERMOCALC, the prograde path crosses the discontinuous reaction chloritoid + margarite = chlorite + garnet + staurolite + paragonite (with muscovite + quartz + H₂O) at 9.5 kbar and 570 °C and the metamorphic peak is reached at 11 kbar and 640 °C. Decompression through about 7 kbar is indicated by sillimanite and biotite growing at the expense of garnet. In the tectonic window, the structurally lower metapelites (garnet–staurolite–biotite–muscovite–quartz ± plagioclase ± sillimanite ± kyanite) and amphibolites (garnet–amphibole–plagioclase ± epidote) indicate a metamorphic peak of 10 kbar at 620 °C and 11 kbar and 610–660 °C, respectively, that is consistent with the other metapelites. The eclogites are composed of garnet, omphacite relicts (jadeite = 33%) within plagioclase–clinopyroxene symplectites, epidote and late amphibole–plagioclase domains. Garnet commonly includes rutile–quartz–epidote ± clinopyroxene (jadeite = 43%) ± magnetite ± amphibole and its growth zoning is compatible in the pseudosection with burial under H₂O‐undersaturated conditions to 18 kbar and 680 °C. Plagioclase + amphibole replaces garnet within foliated boudin margins and results in the assemblage epidote–amphibole–plagioclase indicating that decompression occurred under decreasing temperature into garnet‐free epidote–amphibolite facies conditions. The prograde path of eclogites and metapelites up to the metamorphic peak cannot be shared, being along different geothermal gradients, of about 11 and 17 °C km^?1, respectively, to metamorphic pressure peaks that are 6–7 kbar apart. The eclogite–orthogneiss sheet docked with metapelites at about 11 kbar and 650 °C, and from this depth the exhumation of the pile is shared.