Unravelling a long-term multi-event thermal record in the cratonic interior of southern Finland through apatite fission track thermochronology

Apatite fission track thermochronology (AFTT) has been applied to the Precambrian basement rocks of southern Finland in an attempt to detect within the long-term thermal history, thermal manifestations in the cratonic interior of tectonic events at the craton margin. The likely subtle magnitude of these manifestations means that AFTT is a useful technique for such a study due to its low temperature sensitivity. A total of 10 samples have been analysed, generating AFTT ages, length statistics and thermal models. Ages range from 313 ± 22 to 848 ± 60 Ma and mean track lengths range from 11.0 ± 1.6 to 13.3 ± 1.8 μm. The data suggests the presence of thermal overprinting of an earlier cooling event. Thermal modelling produces similar results for all samples and typically contains the following major events: (1) two phases of Late-Proterozoic cooling, (2) Late-Silurian re-heating, (3) Cenozoic cooling. The first phase of Late-Proterozoic cooling is interpreted to be due to aulacogen inversion as a result of stress propagation from the collisional tectonics of the Sveconorwegian orogeny. The second phase is discussed in relation to passive margin formation and possible asthenospheric diaper induced relief and exhumation. The Late-Silurian re-heating coincides in time with a proposed Caledonian foreland basin. The Cenozoic cooling is interpreted to represent the latest exposure resulting from North Atlantic Margin formation induced uplift and associated denudation.     

Thermal effects of Caledonian foreland basin formation,based on fission track analyses applied on basement rocks in central Sweden

Increasing evidence from fission track studies in Sweden indicate that large parts of the Fennoscandian Shield have been affected by a large-scale thermotectonic event in the Palaeozoic. In this study the results of 17 apatite fission track analyses from central Sweden are presented collected along three NW–SE transects trending from the Bothnian Sea to the Caledonides. On the Bothnian coast samples have been collected directly from the Sub-Cambrian Peneplain. The sedimentary cover protecting this surface until recently is responsible for the thermal increase detected through apatite fission track (FT) thermochronology.The apatite FT ages range between 516 ± 46 Ma (±1σ) on the Bothnian coast around sea level to 191 ± 11 Ma in the Caledonides (～500–1500 m.a.s.l.). The mean track lengths vary from 11.3 ± 2.2 μm (±1σ) in the east to 14.2 ± 2.8 μm in the west, indicating a longer stay in the PAZ in the east, versus a continuous cooling pattern in the west. This pattern in combination with other geological constraints indicates that the crystalline basement rocks near the Caledonian deformation front in the west experienced higher temperatures after the formation of the Sub-Cambrian Peneplain followed by denudation, compared with the basement rocks in the east near the Bothnian coast.The apatite FT data near the Caledonian deformation front indicates prevailing temperatures of more than 110 ± 10 °C prior to the Mid Palaeozoic, causing a resetting of the apatite fission track clock. The temperatures were progressively lower away from the deformation front. Apatite fission track analysis of samples collected from the Sub-Cambrian Peneplain along the Bothnian coast indicate maximum temperatures of 90 ± 15 °C during Late Silurian–Early Devonian time. This heating event is argued to be the result of burial beneath a developing foreland basin in front of the Caledonian orogeny. Assuming a geothermal gradient of 20 °C/km, this temperature increase can be converted to a total burial of the samples. The resulting geometry of this basin can be described as an asymmetrical basin at least 3.5 km deep in the vicinity of the Caledonian deformation front decreasing to about 2.5 km on the Bothnian coast, continuing further onto Finland. The width of this basin was in thus in the order of 600 km. Whether this was formed completely synorogenic or partly synorogenic, broadening after cessation of the orogeny, could not be revealed.The Late Palaeozoic and Mesozoic thermal evolution of this area is related to the extensional tectonics in the North Atlantic Domain.     

A new electrical and mechanically detonatable shear wave source for near surface (0–30 m) seismic acquisition

We present a new, impulsive, horizontal shear source capable of performing long shot profiles in a time-efficient and repeatable manner. The new shear source is ground-coupled by eight 1/2″ (1.27 cm) × 2″ (5.08 cm) steel spikes. Blank shotshells (12-gauge) used as energy sources can be either mechanically or electrically detonated. Electrical fuses have a start time repeatability of < 50 μs. This source can be operated by a single individual, and takes only ~ 10 s between shots as opposed to ~ 30 s for six stacked hammer blows. To ensure complete safety, the shotshell holder is surrounded by a protective 6″ (15.24 cm)-thick barrel, a push-and-twist-locked breach, and a safety pin.We conducted field tests at the 17th Street Canal levee breach site in New Orleans, Louisiana (30.017° N 90.121° W) and at an instrumented test borehole at Millsaps College in Jackson, Mississippi (32.325° N 93.182° W) to compare our new source and a traditional hammer impact source. The new shear source produces a broader-band of frequencies (30–100 Hz cf. 30–60 Hz). Signal generated by the new shear source has signal-to-noise ratios equivalent to ~ 3 stacked hammer blows to the hammer impact source. Ideal source signals must be broadband in frequency, have a high SNR, be consistent, and have precise start times; all traits of the new shear source.     

Entanglement of grey seals Halichoerus grypus at a haul out site in Cornwall,UK

Entanglement in marine debris has been internationally recognised as a potential threat to marine species. Sightings records and a photo identification catalogue from a haul out site in southwest England were used to establish entanglement records for grey seals Halichoerus grypus. Between 2004 and 2008 the annual mean entanglement rates varied from 3.6% to 5%. The maximum recapture period for entangled seals compared to paired control seals was significantly less (p = 0.045) suggesting an increased mortality rate for affected seals. Of the 58 entangled cases in the catalogue, 64% had injuries that were deemed serious. Of the 15 cases where the entangling debris was visible, 14 were entangled in fisheries materials. The entanglement reported at this site could indicate a high rate of mortality and should be monitored carefully. On a more immediate level, entanglement represents a welfare issue for the affected animals.     

Assessing the footprint and volume of oil deposited in deep-sea sediments following the Deepwater Horizon oil spill

The lateral and vertical extents of Macondo oil in deep-sea sediments resulting from the 2010 Deepwater Horizon oil spill were determined using chemical forensics and geostatistical kriging of data from 2397 sediment samples from 875 cores collected in 2010/2011 and 2014. The total mass of Macondo-derived hopane on the seafloor in 2010/2011 was conservatively estimated between 2.00 and 2.26 metric tons, derived from 219,000 to 247,000 barrels of oil; or 6.9 to 7.7% of the 3.19 million barrels spilled. Macondo-derived hopane was deposited over 1030 to 1910 km² of the seafloor, mostly (> 97%) in surface (0–1 cm) and near-surface (1–3 cm) sediments, which is consistent with short-term oil deposition. Although Macondo oil was still present in surface sediments in 2014, the total mass of Macondo-derived hopane was significantly lower (~ 80 to 90%) than in 2010/2011, affirming an acute impact from the spill and not long-term deposition from natural seeps.     

Non-steady long-term uplift rates and Pleistocene marine terrace development along the Andean margin of Chile (31°S) inferred from 10Be dating

Pleistocene uplift of the Chilean coast is recorded by the formation of wave-cut platforms resulting from marine erosion during sea-level highstands. In the Altos de Talinay area (~ 31°S), we have identified a sequence of 5 wave-cut platforms. Using in situ produced ¹⁰Be exposure ages we show that these platforms were formed during interglacial periods at 6, 122, 232, 321 and 690 ka. These ages correspond to marine isotopic stages (MIS) or substages (MISS) 1, 5e, 7e, 9c and 17. Shoreline angle elevations used in conjunction with our chronology of wave-cut platform formation, illustrate that surface uplift rates vary from 103 ± 69 mm/ka between 122 and 6 ka, to 1158 ± 416 mm/ka between 321 and 232 ka. The absence of preserved platforms related to the MIS 11, 13 and 15 highstands likely reflects slow uplift rates during these times. We suggest that since 700 ka, the Altos de Talinay area was predominantly uplifted during 2 short periods following MIS 17 and MISS 9c. This episodic uplift of the Chilean coast in the Pleistocene may result from subduction related processes, such as pulses of tectonic accretion at the base of the forearc wedge.     

Experimental and numerical evaluation of the effectiveness of a stiff wave barrier in the soil

This paper discusses the design, the installation, and the experimental and numerical evaluation of the effectiveness of a stiff wave barrier in the soil as a mitigation measure for railway induced vibrations. A full scale in situ experiment has been conducted at a site in El Realengo (Spain), where a barrier consisting of overlapping jet grout columns has been installed along a railway track. This barrier is stiff compared to the soil and has a depth of 7.5 m, a width of 1 m, and a length of 55 m. Geophysical tests have been performed prior to the installation of the barrier for the determination of the dynamic soil characteristics. Extensive measurements have been carried out before and after installation of the barrier, including free field vibrations during train passages, transfer functions between the track and the free field, and the track receptance. Measurements have also been performed at a reference section adjacent to the test section in order to verify the effect of changing train, track, and soil conditions over time. The in situ measurements show that the barrier is very effective: during train passages, a reduction of vibration levels by 5 dB is already obtained from 8 Hz upwards, while a peak reduction of about 12 dB is observed near 30 Hz immediately behind the barrier. The performance decreases further away from the jet grouting wall, but remains significant. The experimental results are also compared to numerical simulations based on a coupled finite element–boundary element methodology. A reasonable agreement between experiments and predictions is found, largely confirming the initially predicted reduction. This in situ test hence serves as a ‘proof of concept׳, demonstrating that stiff wave barriers are capable of significantly reducing vibration levels, provided that they are properly designed.     

Pliocene climate change of the Southwest Pacific and the impact of ocean gateways

The transition from the early Pliocene “Warmhouse” towards the present “Icehouse” climate and the role of Gateway dynamics are intensively debated. Both, the constrictions of the Central American Seaway and the Indonesian Gateway affected ocean circulation and climate during the Pliocene epoch. Here, we use combined δ¹⁸O and Mg/Ca ratios of planktonic foraminifera (marine protozoa) from surface and subsurface levels to reconstruct the thermal structure and changes in salinities from the Southwest Pacific Deep Sea Drilling Project (DSDP) Site 590B from 6.5 to 2.5 Ma. Our data suggest a gradual cooling of ~ 2 °C and freshening of the sea surface during ~ 4.6–4 Ma with an increased meridional temperature gradient between the West Pacific Warm Pool and the Southwest Pacific when the closing of the Central American Seaway reached a critical threshold. After ~ 3.5 Ma, the restricted Indonesian Gateway might have amplified the East Australian Current, allowing enhanced heat transport towards the Southwest Pacific with reduced meridional temperature gradients when the global climate gradually cooled. At the same time our data suggest a cooling and freshening of Subantarctic Mode Water (SAMW) or/and an increased northward flow of SAMW towards Site 590B, possibly a first step towards the present Antarctic Frontal System.     

Spatiotemporal patterns of fault slip rates across the Central Sierra Nevada frontal fault zone

Patterns in fault slip rates through time and space are examined across the transition from the Sierra Nevada to the Eastern California Shear Zone–Walker Lane belt. At each of four sites along the eastern Sierra Nevada frontal fault zone between 38 and 39° N latitude, geomorphic markers, such as glacial moraines and outwash terraces, are displaced by a suite of range-front normal faults. Using geomorphic mapping, surveying, and ¹⁰Be surface exposure dating, mean fault slip rates are defined, and by utilizing markers of different ages (generally, ~ 20 ka and ~ 150 ka), rates through time and interactions among multiple faults are examined over 10⁴–10⁵ year timescales.At each site for which data are available for the last ~ 150 ky, mean slip rates across the Sierra Nevada frontal fault zone have probably not varied by more than a factor of two over time spans equal to half of the total time interval (~ 20 ky and ~ 150 ky timescales): 0.3 ± 0.1 mm year^? 1 (mode and 95% CI) at both Buckeye Creek in the Bridgeport basin and Sonora Junction; and 0.4 + 0.3/?0.1 mm year^? 1 along the West Fork of the Carson River at Woodfords. Data permit rates that are relatively constant over the time scales examined. In contrast, slip rates are highly variable in space over the last ~ 20 ky. Slip rates decrease by a factor of 3–5 northward over a distance of ~ 20 km between the northern Mono Basin (1.3 + 0.6/?0.3 mm year^? 1 at Lundy Canyon site) to the Bridgeport Basin (0.3 ± 0.1 mm year^? 1). The 3-fold decrease in the slip rate on the Sierra Nevada frontal fault zone northward from Mono Basin is indicative of a change in the character of faulting north of the Mina Deflection as extension is transferred eastward onto normal faults between the Sierra Nevada and Walker Lane belt.A compilation of regional deformation rates reveals that the spatial pattern of extension rates changes along strike of the Eastern California Shear Zone-Walker Lane belt. South of the Mina Deflection, extension is accommodated within a diffuse zone of normal and oblique faults, with extension rates increasing northward on the Fish Lake Valley fault. Where faults of the Eastern California Shear Zone terminate northward into the Mina Deflection, extension rates increase northward along the Sierra Nevada frontal fault zone to ~ 0.7 mm year^? 1 in northern Mono Basin. This spatial pattern suggests that extension is transferred from more easterly fault systems, e.g., Fish Lake Valley fault, and localized on the Sierra Nevada frontal fault zone as the Eastern California Shear Zone–Walker Lane belt faulting is transferred through the Mina Deflection.     

Contrasting punctuated zircon growth in two syn-erupted rhyolite magmas from Tarawera volcano: Insights to crystal diversity in magmatic systems

Two mineralogically and chemically distinct rhyolite magmas (T1 and T3) were syn-erupted from the same conduit system during the 21.9 ka basalt intrusion-triggered Okareka eruption from Tarawera volcano, New Zealand. High spatial resolution U–Th disequilibrium dating of zircon crystals at the ~ 3–5 μm scale reveals a protracted yet discontinuous zircon crystallization history within the magmatic system. Both magma types contain zircon whose interiors predate the eruption by up to 200 ka. The dominant age peak in the T1 magma is ~ 30 ka with subordinate peaks at ~ 45, ~ 75, and ~ 100 ka, whereas the T3 magma has a dominant zircon interior age peak at ~ 90 ka with smaller modes at ~ 35 and ~ 150 ka. These patterns are consistent with isolated pockets of crystallization throughout the evolution of the system. Crystal rim analyses yield ages ranging from within error of the eruption age to at least ~ 90 ka prior to eruption, highlighting that zircon crystallization frequently stalled long before the eruption. Continuous depth profiling from crystal rims inward demonstrates protracted growth histories for individual crystals (up to ~ 100 ka) that were punctuated by asynchronous hiatuses of up to 30 ka in duration. Disparate zircon growth histories can result from localized thermal perturbations caused by mafic intrusions into a silicic reservoir. The crystal age heterogeneity at hand-sample scale requires considerable crystal transport and mixing. We propose that crystal mixing was achieved through buoyancy instabilities caused by mafic magma flow through crystal mush. A terminal pre-eruptive rejuvenation event was capable of mobilizing voluminous melts that erupted, but was too short (< 10²–10³ years) to result in extensive zircon growth. The contrasting, punctuated zircon histories argue against closed-system fractional crystallization models for silicic magmatism that require protracted cooling times following a mostly liquid starting condition.     

Mercury in the ecosystem of Admiralty Bay,King George Island,Antarctica: Occurrence and trophic distribution

Mercury (Hg) can reach the environment through natural and human-related sources, threatening ecosystems all over the planet due to its well known deleterious effects. Therefore, Antarctic trophic webs, despite being relatively isolated, are not exempt of its influence. To evaluate Hg concentrations in an Antarctic ecosystem, different tissues from 2 species of invertebrates, 2 of fish, 8 of birds, 4 of pinnipeds and at least 5 of vegetation were investigated (n = 176). For animals, values ranged from 0.018 to 48.7 μg g^? 1 dw (whole Antarctic krill and Antarctic Fur Seal liver). They were generally correlated to trophic position (assessed by δ¹⁵N and δ¹³C) but also to cephalopods and myctophids consumption. For vegetation, values ranged from 0.014 to 0.227 μg g^? 1 dw (Colobanthus quitensis and an unidentified lichen), with lichens presenting significantly higher values than mosses, likely due to year-round exposure and absorption of animal derived organic matter, as hypothesized by literature.     

Bioindicator role of tintinnid (Protozoa: Ciliophora) for water quality monitoring in Kalpakkam,Tamil Nadu,south east coast of India

The feasibility of a potential bioindicator based on functional groups of microzooplankton tintinnids for bioassessments of water quality status was studied during southwest monsoon (June to September) along the coastal waters of Kalpakkam, India during 2012–2015. The work highlights the following features (1) tintinnid community composed of 28 species belonging to 11 genera and 9 families, revealed significant differences among the four study sites (2) maximum numerical abundance (2224 ± 90 ind. l^? 1) and species diversity (H′ = 2.66) of tintinnid were recorded towards Bay of Bengal whereas minimum abundance (720 ± 35 ind. l^? 1) and diversity (H′ = 1.74) were encountered in the backwater sites, (3) multivariate analyses [RELATE, Biota-environment (BIOENV) and canonical analysis of principal coordinates (CAP)] reveal that chl a, nitrate and phosphate were the potential causative factors for tintinnid distribution. Based on the results, we suggest that tintinnids may be used as a potential bioindicator of water quality status in marine ecosystem.     

Baseline survey of sediments and marine organisms in Liaohe Estuary: Heavy metals,polychlorinated biphenyls and organochlorine pesticides

A geographically extensive investigation was carried out to analyze the concentrations of heavy metals, PCBs and OCPs in the sediments and marine organisms collected from the Liaohe Estuary. In order to determine the spatial distribution and potential ecological risk of heavy metals, the surface sediments were collected from 44 sites in the Liaohe Estuary. The results showed that the heavy metal contents in the sediments were observed in the following order: Cr (11.2–84.8 mg/kg) > Cu (1.7–47.9 mg/kg) > Pb (4.3–28.3 mg/kg) > As (1.61–12.77 mg/kg) > Cd (0.06–0.47 mg/kg) > Hg (0.005–0.113 mg/kg). In comparison with the concentrations of heavy metals and POPs in other regions, the concentrations of As, Pb and DDTs in the Liaohe Estuary were generally low, and other pollutant concentrations were inconsistent with those reported in other regions. The contamination factor (CF), the pollution load index (PLI), the geoaccumulation index and the potential ecological risk index were used to analyze the pollution situation, which showed that the heavy metal pollution in Liaohe Estuary is mainly dominated by Cd and Hg. The concentrations of the four heavy metals varied significantly in the three kinds of tested organisms (fish, mollusk and crustacean), indicating the different accumulative abilities of the species. The results obtained in this study provide useful information background information for further ecology investigation and management in this region.     

Decoupled warming and monsoon precipitation in East Asia over the last deglaciation

Our understanding of the continental climate development in East Asia is mainly based on loess–paleosol sequences and summer monsoon precipitation reconstructions based on oxygen isotopes (δ¹⁸O) of stalagmites from several Chinese caves. Based on these records, it is thought that East Asian Summer Monsoon (EASM) precipitation generally follows Northern Hemisphere (NH) summer insolation. However, not much is known about the magnitude and timing of deglacial warming on the East Asian continent. In this study we reconstruct continental air temperatures for central China covering the last 34,000 yr, based on the distribution of fossil branched tetraether membrane lipids of soil bacteria in a loess–paleosol sequence from the Mangshan loess plateau. The results indicate that air temperature varied in phase with NH summer insolation, and that the onset of deglacial warming at ~ 19 kyr BP is parallel in timing with other continental records from e.g. Antarctica, southern Africa and South-America. The air temperature increased from ~ 15 °C at the onset of the warming to a maximum of ~ 27 °C in the early Holocene (~ 12 kyr BP), in agreement with the temperature increase inferred from e.g. pollen and phytolith data, and permafrost limits in central China.Comparison of the tetraether membrane lipid-derived temperature record with loess–paleosol proxy records and stalagmite δ¹⁸O records shows that the strengthening of EASM precipitation lagged that of deglacial warming by ca. 3 kyr. Moreover, intense soil formation in the loess deposits, caused by substantial increases in summer monsoon precipitation, only started around 12 kyr BP (ca. 7 kyr lag). Our results thus show that the intensification of EASM precipitation unambiguously lagged deglacial warming and NH summer insolation, and may contribute to a better understanding of the mechanisms controlling ice age terminations.     

Systematic tapping of independent magma chambers during the 1 Ma Kidnappers supereruption

The 1.0 Ma Kidnappers supereruption (~ 1200 km³ DRE) from Mangakino volcanic centre, Taupo Volcanic Zone, New Zealand, produced a large phreatomagmatic fall deposit followed by an exceptionally widespread ignimbrite. Detailed sampling and analysis of glass shards and mineral phases have been undertaken through a proximal 4.0 m section of the fall deposit, representing the first two-thirds of erupted extra-caldera material. Major and trace element chemistries of glass shards define three distinct populations (types A, B and C), which systematically change in proportion through the fall deposit and are inferred to represent three magma types. Type B glass and biotite first appear at the same level (~ 0.95 m above base) in the fall deposit suggesting later tapping of a biotite-bearing magma. Plagioclase and Fe–Ti oxide compositions show bimodal distributions, which are linked to types A and B glass compositions. Temperature and pressure (T–P) estimates from hornblende and Fe–Ti oxide equilibria from each magma type are similar and therefore the three magma bodies were adjacent, not vertically stacked, in the crust. Most hornblende model T–P estimates range from 770 to 840 °C and 90 to 170 MPa corresponding to storage depths of ~ 4.0–6.5 km. Hornblende model T–P estimates coupled with in situ trace element fingerprinting imply that the magma bodies were individually well mixed, and not stratified. Compositional gaps between the three glass compositional types imply that no mixing between these magmas occurred. We interpret these data, coupled with the systematic changes in shard compositional proportions through the fall deposit, to reflect that three independent melt-dominant bodies of magma contributed large (A, ~ 270 km³), medium (B, ~ 90 km³) and small (C, ~ 40 km³) volumes (as reflected in the fall deposits) and were systematically tapped during the eruption. We propose that the systematic evacuation of the three independent magma bodies implies that there was tectonic triggering and linkage of eruptions. Our results show that supereruptions can be generated by near simultaneous multiple eruptions from independent magma chambers rather than the evacuation of a large single unitary magma chamber.     

A coastal three-dimensional water quality model of nitrogen in Jiaozhou Bay linking field experiments with modelling

With anthropogenic changes, the structure and quantity of nitrogen nutrients have changed in coastal ocean, which has dramatically influenced the water quality. Water quality modeling can contribute to the necessary scientific grounding of coastal management. In this paper, some of the dynamic functions and parameters of nitrogen were calibrated based on coastal field experiments covering the dynamic nitrogen processes in Jiaozhou Bay (JZB), including phytoplankton growth, respiration, and mortality; particulate nitrogen degradation; and dissolved organic nitrogen remineralization. The results of the field experiments and box model simulations showed good agreement (RSD = 20% ± 2% and SI = 0.77 ± 0.04). A three-dimensional water quality model of nitrogen (3DWQMN) in JZB was improved and the dynamic parameters were updated according to field experiments. The 3DWQMN was validated based on observed data from 2012 to 2013, with good agreement (RSD = 27 ± 4%, SI = 0.68 ± 0.06, and K = 0.48 ± 0.04), which testifies to the model's credibility.     

A critical review of the potential impacts of marine seismic surveys on fish & invertebrates

Marine seismic surveys produce high intensity, low-frequency impulsive sounds at regular intervals, with most sound produced between 10 and 300 Hz. Offshore seismic surveys have long been considered to be disruptive to fisheries, but there are few ecological studies that target commercially important species, particularly invertebrates. This review aims to summarise scientific studies investigating the impacts of low-frequency sound on marine fish and invertebrates, as well as to critically evaluate how such studies may apply to field populations exposed to seismic operations. We focus on marine seismic surveys due to their associated unique sound properties (i.e. acute, low-frequency, mobile source locations), as well as fish and invertebrates due to the commercial value of many species in these groups. The main challenges of seismic impact research are the translation of laboratory results to field populations over a range of sound exposure scenarios and the lack of sound exposure standardisation which hinders the identification of response thresholds. An integrated multidisciplinary approach to manipulative and in situ studies is the most effective way to establish impact thresholds in the context of realistic exposure levels, but if that is not practical the limitations of each approach must be carefully considered.     

Investigating Bermuda's pollution history through stable isotope analyses of modern and museum-held gorgonian corals

For centuries, Bermuda has been challenged with wastewater management for the protection of human and environmental health. By quantifying the δ¹⁵N of the common sea fan Gorgonia ventalina sampled from 30 sites throughout Bermuda we show that sewage-derived nitrogen is detectable on nearshore coral reefs and declines across the lagoon to the outer rim. We also sampled gorgonians from two museum collections representing a 50y time-series (1958–2008). These samples revealed an increase in δ¹⁵N of > 4.0‰ until the mid-1970s, after which δ¹⁵N values slowly declined by ~ 2.0‰. A δ¹⁵N chronology from a gorgonian skeleton exhibited a similar decline over the last 30–40 years of approximately 0.6‰. We conclude that policies have been effective in reducing sewage impacts to Bermudian reefs. However, significant sources of sewage pollution persist and are likely have a strong impact on harbor and nearshore coral communities and human health.     

Velocity dispersion in fractured rocks in a wide frequency range

Experimental measurements of fracture-induced seismic waves velocity variations at frequencies ~ 1 kHz, ~ 40 kHz and ~ 1 MHz were performed directly in the field at the rocky outcrop and in the laboratory on specific rock samples collected from the outcrops. The peridotite–lherzolite outcrop appeared macroscopically uniform and contained three systems of visible parallel sub-vertical fractures. This rock has substantial bulk density and higher than average value of seismic wave velocity. The presence of fracture systems gives rise to its velocity anisotropy. The seismic waves passing through the rock fractures are subject to velocity dispersion and frequency dependent attenuation. Our data, obtained from field and laboratory measurements, were compared with theoretical model predictions. In this model we successfully used displacement discontinuity approach. For the velocity dispersion evaluation we used multi-frequency measurements. The a priori observation of orientations and densities of fracture sets allowed evaluation of their stiffness. Our approach revealed that the first arrivals of seismic waves can be used for evaluation of P-wave group velocities, the specific case, in which we expect anomalous velocity dispersion. Our observations contribute to the issue of up-scaling of well-log derived velocities in fractured rock to the scale of standard seismic exploration frequencies.     

Mugil curema as a PAH bioavailability monitor for Atlantic west sub-tropical estuaries

This work aimed to evaluate the use of Mugil curema as a biomonitor for polycyclic aromatic hydrocarbon (PAH) bioavailability. Fish biliary metabolites from low-contaminated (Cananéia) and contaminated (Santos) Brazilian estuaries were analysed using a high-performance liquid chromatography apparatus coupled to fluorescence detectors connected in a series. In the Cananéia and Santos estuaries, total metabolite levels ranged from 0.85 to 34.4 μg g^? 1 of bile and from 4.06 to 528 μg g^? 1 of bile, respectively. Metabolite levels were not influenced by feeding status or sexual hormones (p < 0.05), thus suggesting that M. curema is a good biomonitor for PAH bioavailability. In estuarine regions, it is possible to sample both the male and female genders of this species in any reproductive period.