Geochemical characteristics and petrogenesis of the Dashipo-Heishantuo batholith in Beijing and its geological significanceEI北大核心CSCD

The early Jurassic Dashipo-Heishantuo batholith in Beijing, which consists of the Dashipo hornblende-biotite syenite and Heishantuo granite, exposed in the western Yanshan orogenic belt, eastern North China Craton. The Dashipo syenite is magnesian potassic intermediate rock enriched in large ion lithophile elements such as Rb, Ba, Sr, Pb and LREE, and relatively depleted in high field strength elements such as Nb, Ta, U, Th, Zr, Hf as well as P and Ti, with εNd(t) values from -12.1 to -12.2 and ISr values of 0.70506-0.70464. The Heishantuo granite is magnesian peraluminous high K calc-alkaline, with an enrichment of large ion lithophile elements and radioactive elements such as Rb, Ba, Th, U and Pb, and a depletion of HREE and high field strength elements such as Nb, Ta, Zr and Hf as well as Sr, P and Ti, with εNd(t) values from -15.5 to -18.0 and ISr values of 0.70516-0.70593. The magma of the Dashipo syenite is produced by fractional crystallization of mantle-derived K-rich mafic magma under high pressure. The partial melting of the lower crust, which was heated and metasomatised by the mantle-derived magma, produced granitic magma that intruded into the unconsolidated Dashipo syenite to form the concentric batholith. The petrology and geochemistry of the Dashipo hornblende-biotite syenite indicate that the water weakening was important for the lithospheric destruction within the interior part of the North China Craton. Meanwhile, the partial melting related to the double-diffusion of energy and chemical composition between mantle-derived magma and crustal rocks was an important mechanism for the Mesozoic calc-alkaline felsic magmatism occurred in the interior of the North China Craton. ©, 2015, Science Press. All right reserved.     

浙江桐庐火山侵入杂岩的地球化学特征

The Tonglu volcano-intrusive complex belongs to a calci-alkalic rock series. The geochemistry of major and minor elements in the rocks is characteristic of the differentiation and the evolution of the calci-alkalic series. The rare-earth distribution patterns in the rocks and minerals indicate that rhyolitic, rhyodacitic and quartz ttachyandesitic magmas responsible for the volcano-intrusive complex are comagmatic. The Rb-Sr isotopic relationship in the rocks suggests that the earliest volcanic activity in western Zhejiang may commence at Middle Jurassic. The magma responsible for the Tonglu volcano-intrusive complex originated from partil melting of the lower crust. The derivation of upper mantle material was introduced upwards through deep faults, which would accelerate partial melting of the lower crust.This magma seems to have been contaminated slightly by upper crustal material during the process of upward intrusion.     

Geochemistry of the Eocene Felsic Porphyric Rocks and High-Mg Potassic Rocks along JARSZ: Implication for the Tectonic Evolution in Eastern Tibet

<正>Eocene felsic porphyric rocks and the high-Mg potassic volcanic rocks(HMPR) occur along the Jinshajiang-Ailao Shan-Red River shear zone(JARSZ) in eastern Tibet.Compared with the HMPR,which are generally believed to be sourced from an enriched mantle,the felsic porphyric rocks show similar K_2O contents,enrichment in LREE and LILE,particularly radiogenic isotope(e.g.Sr and Nd) features much similar to the former,implying generation of the felsic porphyric rocks most likely related to the HMPR,although they both have clearly different major and trace element compositions. The close relationship in spatial-temporal distribution and similar Sr-Nd characteristics between the felsic porphyric rocks and HMPR in eastern Tibet indicate that both of them were possibly formed by a similar tectonic process(event).Combining the basic dikes in southern and eastern Tibet,we suggest that the break-off of north-dipping Neo-Tethyan slab in southern Tibet during 50-40 Ma,triggered formation of high-Mg potassic magma.This led to developing felsic porphyric magma production by partial melting of underplating HMPR in the lower crust,or fractionation crystallization of the high-Mg potassic magmas.The break-off of slab in the Eocene may also have contributed to the abundant ore-forming material related to earlier subduction events,resulting in formation of the porphyric deposits along JARSZ in eastern Tibet.     

Early Cretaceous Magma Mingling in Xiaocuo, Southeastern China Continental Margin: Implications for Subduction of Paleo-Pacific Plate

Magma mingling has been identified within the continental margin of southeastern China.This study focuses on the relationship between mafic and felsic igneous rocks in composite dikes and plutons in this area,and uses this relationship to examine the tectonic and geodynamic implications of the mingling of mafic and felsic magmas.Mafic magmatic enclaves(MMEs) show complex relationships with the hosting Xiaocuo granite in Fujian area,including lenticular to rounded porphyritic microgranular enclaves containing abundant felsic/mafic phenocrysts,elongate mafic enclaves,and back-veining of the felsic host granite into mafic enclaves.LA-ICP-MS zircon U-Pb analyses show crystallization of the granite and dioritic mafic magmatic enclave during ca.132 and 116 Ma.The host granite and MMEs both show zircon growth during repeated thermal events at-210 Ma and 160-180 Ma.Samples from the magma mingling zone generally contain felsic-derived zircons with well-developed growth zoning and aspect ratios of 2-3,and maficderived zircons with no obvious oscillatory zoning and with higher aspect ratios of 5-10.However,these two groups of zircons show no obvious trace element or age differences.The Hf-isotope compositions show that the host granite and MMEs have similar ε_(Hf)(t) values from negative to positive which suggest a mixed source from partial melting of the Meso-Neoproterozoic with involvement of enriched mantlederived magmas or juvenile components.The lithologies,mineral associations,and geochemical characteristics of the mafic and felsic rocks in this study area indicate that both were intruded together,suggesting Early Cretaceous mantle—crustal interactions along the southeastern China continental margin.The Early Cretaceous magma mingling is correlated to subduction of Paleo-Pacific plate.     

Guandishan Granitoids of the Paleoproterozoic Lüliang Metamorphic Complex in the Trans-North China Orogen:SHRIMP Zircon Ages,Petrogenesis and Tectonic Implications

The Paleoproterozoic Liiliang Metamorphic Complex(PLMC)is situated in the middle segment of the western margin of the Trans-North China Orogen(TNCO),North China Craton(NCC). As the most important Iithological assemblages in the southern part of the PLMC,Guandishan granitoids consist of early gneissic tonalities,granodiorites and gneissic monzogranites,and younger gneissic to massive monzogranites.Petrochemical features reveal that the early gneissic tonalities and granodiorites belong to the medium-K calc-alkaline series;the early gneissic monzogranites are transitional from high-K caic-alkaline to the shoshonite series;the younger gneissic to massive monzogranites belong to the high-k calc-alkaline series,and all rocks are characterized by right-declined REE patterns and negative Nb,Ta,Sr,P,and Ti anomalies in the primitive mantle normalized spidergrams.SHRIMP zircon U-Pb isotopic dating reveal that the early gneissic tonalities and granodiorites formed at ～2.17 Ga,the early gneissic monzogranites at ～2.06 Ga,and the younger gneissic to massive monzogranites at ～1.84 Ga.Sm-Nd isotopic data show that the early gneissic tonalities and granodiorites have εNd(t) values of +0.48 to -3.19 with Nd-depleted mantle model ages (TDM)of 2.76-2.47 Ga,and early gneissic monzogranites have εNd(t) values of -0.53 to -2.51 with TDM of 2.61-2.43 Ga,and the younger gneissic monzogranites have εNd(t) values of -6.41 to -2.78 with a TDM of 2.69-2.52 Ga.These geochemical and isotopic data indicate that the early gneissic tonalities,granodiorites,and monzogranites were derived from the partial melting of metamorphosed basaltic and pelitic rocks,respectively,in a continental arc setting.The younger gneissic to massive monzogranites were derived by partial melting of metamorphosed greywackes within the continental crust.Combined with previously regional data,we suggest that the PaleOproterOzOic granitoid magmatism in the Guandishan granitoids of the PLMC may provide the best geologicaI signature for the complete spectrum of Paleoproterozoic geodynamic processes in the Trans-North China Orogen from oceanic subduction.through collisional orogenesis,to post-orogenic extension and uplift.     

Guandishan Granitoids of the Paleoproterozoic Lüliang Metamorphic Complex in the Trans-North China Orogen: SHRIMP Zircon Ages, Petrogenesis and Tectonic Implications

Abstract: The Paleoproterozoic Lüliang Metamorphic Complex (PLMC) is situated in the middle segment of the western margin of the Trans-North China Orogen (TNCO), North China Craton (NCC). As the most important lithological assemblages in the southern part of the PLMC, Guandishan granitoids consist of early gneissic tonalities, granodiorites and gneissic monzogranites, and younger gneissic to massive monzogranites. Petrochemical features reveal that the early gneissic tonalities and granodiorites belong to the medium-K calc-alkaline series; the early gneissic monzogranites are transitional from high-K calc-alkaline to the shoshonite series; the younger gneissic to massive monzogranites belong to the high-k calc-alkaline series, and all rocks are characterized by right-declined REE patterns and negative Nb, Ta, Sr, P, and Ti anomalies in the primitive mantle normalized spidergrams. SHRIMP zircon U–Pb isotopic dating reveals that the early gneissic tonalities and granodiorites formed at ~2.17 Ga, the early gneissic monzogranites at ~2.06 Ga, and the younger gneissic to massive monzogranites at ~1.84 Ga. Sm–Nd isotopic data show that the early gneissic tonalities and granodiorites have εNd(t) values of +0.48 to ?3.19 with Nd-depleted mantle model ages (TDM) of 2.76–2.47 Ga, and early gneissic monzogranites have εNd(t) values of ?0.53 to ?2.51 with TDM of 2.61–2.43 Ga, and the younger gneissic monzogranites have εNd(t) values of ?6.41 to ?2.78 with a TDM of 2.69–2.52 Ga.These geochemical and isotopic data indicate that the early gneissic tonalities, granodiorites, and monzogranites were derived from the partial melting of metamorphosed basaltic and pelitic rocks, respectively, in a continental arc setting. The younger gneissic to massive monzogranites were derived by partial melting of metamorphosed greywackes within the continental crust. Combined with previously regional data, we suggest that the Paleoproterozoic granitoid magmatism in the Guandishan granitoids of the PLMC may provide the best geological signature for the complete spectrum of Paleoproterozoic geodynamic processes in the Trans-North China Orogen from oceanic subduction, through collisional orogenesis, to post-orogenic extension and uplift.     

Geochemical Characteristic of Charnockites in North Margin of North China Craton: Indicating the Significiant of the Neoarchean Tecnotic Event

The Neoarchean charnockites of North margain of North China Craton(NCC) has become a hot topic into understanding the Early Precambrian basement. Although there is a broad consensus that charnockite is usually related to granulite facies metamorphism, whether its petrogenesis and tectonics characteristics remains controversial. Inclusions within hypersthene and garnet in charnockite are used to identify the peak granulite facies mineral assemblage, with the formation of Magnesian–charnockite attributed to anatexis of the protolith associated with this granulite facies metamorphism. The distribution of major and trace elements in charnockite is very uneven, significant depleted in LILEs(eg. Cs, U, Th) and HFSEs(eg. Nb, Ta, P and Ti), riched in Sr. Raising to the coexistence of Eu–enrichment and Eu–depletion type of REE patterns that influenced by the content of plagioclase and the remnants minerals of zircon and apatite. Comparative the petrography, geochemistry and geochronology data of Magnesian–charnockite indicate that the ratios of mafic pellites and basalts involved in anatectic melting are different by the upwelling of mantle magma, also resulting in the Eu anormals characteristics. The formation of the Magnesian–charnockite is closely connected with the subduction of the NCC oceanic crust(About ～2.5 Ga). However, Ferroan–charnockite may be the formed by the crystallization differentiation of the upwelling of mantle–derived shoshonitic magma(About ～2.45 Ga), with the lower crust material addition.     

GEOCHEMICAL CHARACTERISTICS OF PLATINUM GROUP ELEMENTS IN JINCHUAN SUPER-LARGE SULFIDE COPPER-NICKEL DEPOSIT, JINCHANG CITY, GANSU PROVINCE, CHINA

The platinum-group element geochemistry of rocks and ores from Jinchuan super-large copper-nickel sulfide deposit is systemically studied in this paper. The Cu/Pd mean ratio of Jinchuan intrusion is lower than that of original mantle magma, which indicates that these ultrabasic rocks were crystallized from magma that lost Pd in the form of melting segregation of sulfides. The PGE of the rocks show trend of partial melting, similar to that of mantle peridotite, which shows that magma formation occurs during rock-forming and ore-forming processes. The chondrite normalized PGE patterns of the rocks and ores are well related to each other, which signifies the signatures of multi-episode magmatic intrusion, melting and differentiation in the formation processes of rocks and ores. In addition, analyses about the relation between PGE and S, and study on Re-Os isotopes indicate that few contamination of the crustal substances occurred during the magmatic intrusion and the formation of deposit. However, contamination by crustal substances helps to supply part of the S for the enrichment of PGE. Meanwhile, the hydrothermal process is also advantageous for the enrichment of PGE, especially lbr Pt and Pd, due to deep melting segregation. The characteristic parameters （such as Pt/（Pt＋Pd）, （Pt＋Pd）/（Ru＋Ir＋Os）, Pd/Ir, Cu/（Ni＋Cu）, and so on.） for platinum-group elements for Jinchuan sulfide copper-nickel deposit show the same features as those for sulfide copper-nickel deposit related to basic magma, which also illustrates its original magma property representative of Mg-high tholeiite. Therefore, it is the marie （not ultramafic） magma that resulted in the formation of the superlarge sulfide copper-nickel deposit enriched in Cu and PGE. To sum up, the geochemical characteristics of platinum-group elements in rocks and ores from Jinchuan copper-nickel sulfide deposit are constrained by the continental rift tectonic environment, the parent magma features, the enriched mantel magma source, the complex metallogenesis and PGE geochemical signatures, and this would be rather significant for the study about the genetic mechanism of copper-nickel sulfide deposits.     

Granulite—facies Middle—Lower Crustal Xenoliths from Nueshan Alkali Basalt in Northeastern Anhui Province, China

Metamorphic xenoliths within the Nushan alkali basalt of northeastern Anhui (NEA),China ,are from the middle-lower crust.They could be divided into two end-members:basic and acid.Interme-diate xenoliths are scarcely found.Basic two-pyroxene granulites(pyriclasites) were formed at 720-810℃ and 7-8kb.Petrological and geochemical studies indicate that the primary magma of the protoliths of basic granulites was derived from the metasomatized upper mantle, while the pa-rental magma of the acid end-member was probably produced by partial melting of the basic rocks. The protoliths of charnockites and grey gneisses represent respectively the early and late crystallization products of the granitic magma.The Nushan granulites are much different in many aspects from the granulites exposed in the northern part of North China ,which implies the inhomogeneity regarding to the early evolution of the North China terranc.     

The Middle Devonian Bimodal Association of Volcanic Rocks in the Northern Area of East Junggar, Xinjiang

The Middle Devonian volcanic rocks in the northern area of East Junggar, located between the Ertix andUlungur rivers of northern Xinjiang, may be divided into basic and acid ones. It is evident that a compositionalgap exists between the two groups so that the volcanic rocks are not in line with a calc-alkaline series becausethe intermediate rocks are absent in the area. The fact shows that the volcanic rocks are a typical bimodal asso-ciation. The formation of the bimodal association of volcanic rocks in the area was closely related to continen-tal rifting or continental extension in the Middle Devonian. In such a tectonic setting, magmas were first pro-duced by partial melting of the mantle. Where crustal thinning was greater, the magmas ascended and eruptedon the surface directly so that the basic volcanic rocks formed, but olivine and/or partial pyroxenefractionation occurred in the magmas during their ascent through the thinning crust. On the other hand, wherecrustal thinning was less, ascending mantle-derived magmas reached the lower crust and accumulated there, re-sulting in partial melting of the lower crust and thus giving rise to the contaminated magma which was consoli-dated as acid volcanic rocks on the surface.     

Isotope Geochemistry of Erentaolegai Silver Deposit, Inner Mongolia, China

Detailed studies have been conducted on the geology and geochemistry of the deposit and granite in the mining district in the last two decades, and by comparing this deposit with other typical epithermal deposits in the world, it is clear that the Erentaolegai silver deposit is a lower-sulfidation, adularia-sericite-type epithermal silver deposit and the bulk mineralogy of this deposit is consistent with low-sulfidation epithermal mineralization. Determined by the Rb-Sr isochron method, the age of magmatic intrusives in the mining district is 120 Ma. So, it can be concluded that the local areas were marginally subjected to the movement in Late Yanshanian and produced granitic magma, and about 29% mantle material, as is calculated, was involved in magmatism. The magma experienced crystallization-differentiation, resulting in the formation of granite and quartz porphyry; the latter was the product of violent granitic magma crystallization-differentiation, so silver was enriched in later petrogenetic stages and post-petrogenetic ore fluids from which Ag was derived dominantly. Oxygen and hydrogen isotopic characteristics indicate that meteoric waters on the Earth‘ s surface played an important role in the formation of granitic magma and the deposit: ( 1 ) contributing a lot to the fundamental complex partial melting;(2) contributing a lot to magma crystallization-differentiation, and bringing silver into the magma which is eventually responsible for the formation of quartz porphyry; and (3) contributing a lot to the formation of great amounts of ore fluid. The lead isotopic characteristics show that the silver and lead have an affinity for each other.     

Thoughts on the Jiaodong Gold Province of China:Towards a Tectonic Model

The Jiaodong gold province is situated in the eastern Sino-Korean Platform within the so-calledJiaoliao Uplift. The basement rocks are Archaean and Proterozoic metamorphic rocks. Mesozoic sedimentary andvolcanic cover occur within extensional basins. Intrusive rocks are dominated by Mesozoic granitoid, with interme-diate-acid and basic dyke swarms. The structures form an E-W-trending anticlinorium in the basement complex, andlarge-scale NE-SW-and NNE-SSW-trending fault zones of Mesozoic age. The gold mineralization is associated withthe Mesozoic faults and related secondary fractures in the granites or granite-basement contacts. The mineralizationtypes are quartz-vein type and wall-rock alteration type. Wall-rock alteration is very well developed around the orezones. Alteration minerals include quartz, sericite (and fuchsite), pyrite, calcite, chlorite, hematite, rutile and graph-ite. The ore assemblage is uniform in all deposits, including pyrite, chalcopyrite, galena, sphalerite, arsenopyrite,pyrrhotite, gold, electrum, hessite, petzite, magnetite, molybdenite, tetrahedrite and wolframite. Mesozoic collisionand subduction between the South China and North China continental blocks contributed to formation of the Meso-zoic granitoid intrusions. The granitic magma is considered to be derived from partial melting of the crust throughunderplating processes. Gold was remobilised from basement rocks and deposited in fracture zones by the high-temperature fluids associated with these processes.     

The Evolution of Alpine Ultramafic Rocks and Partial Melting of the Upper Mantle

Ultramafic rocks of Tibet and Xinjiang are the products of partial melting of the upper mantle. The evolution of their mineral composition is marked by two parallel evolutionary series: one is the progressive increase of the 100 Mg/(Mg+Fe~(2+) ratio of silicate minerals in order of lherzolite→harzburgite→dunite, i.e. the increase in magnesium; the other is the increase of the 100 Cr/(Cr+Al) ratio of accessory chrome spinel in the same order, i. e. the increase in Chromium. The above-mentioned evolutionary trends are contrary to that of magmatic differentiation. The evolution of fabrics of ultramafic rocks is characterized by progressive variation in order of protogranular texture→melted residual texture, symplectic texture and clastophyritic texture→equigranular mosaic texture and tabular mosaic texture. Experiments of partial melting of lherzolite have convincingly shown that the evolution of Alpine ultramafic rocks resulted from the partial melting of pyrolite. Various subtypes of them represent different degrees of partial melting. The vertical zoning marked by more basic rocks in the upper part and more acid rocks in the lower actually belongs to the fusion zoning of pyrolite.     

Geochemical Characteristics and Metallogenesis of the Qingkuangshan Ni‐Cu‐PGE Mineralized Mafic‐Ultramafic Intrusion in Huili County,Sichuan Province,SW China

The Qingkuangshan Ni-Cu-PGE deposit, located in the Xiaoguanhe region of Huili County, Sichuan Province, is one of several Ni-Cu-PGE deposits in the Emeishan Large Igneous Province (ELIP). The ore-bearing intrusion is a mafic-ultramafic body. This paper reports major elements, trace elements and platinum-group elements in different types of rocks and sulfide-mineralized samples in the intrusion. These data are used to evaluate the source mantle characteristics, the degree of mantle partial melting, the composition of parental magma and the ore-forming processes. The results show that Qingkuangshan intrusion is part of the ELIP. The rocks have trace element ratios similar to the coeval Emeishan basalts. The primitive mantle-normalized patterns of Ni-Cu-PGE have positive slopes, and the ratios of Pd/Ir are lower than 22. The PGE compositions of sulfide ores and associated rocks are characterized by Ru depletion. The PGE contents in bulk sulfides are slightly depleted relative to Ni and Cu, which is similar to the Yangliuping Ni-Cu-PGE deposit. The composition of the parental magma for the intrusion is estimated to contain about 14.65 wt% MgO, 48.66 wt% SiO2 and 15.48 wt% FeOt, and the degree of mantle partial melting is estimated to be about 20%. In comparison with other typical Ni-Cu-PGE deposits in the ELIP, the Qingkuangshan Ni-Cu-PGE deposit has lower PGE contents than the Jinbaoshan PGE deposit, but has higher PGE contents than the Limahe and Baimazhai Ni-Cu deposit, and has similar PGE contents to the Yangliuping Ni-Cu-PGE deposit. The moderate PGE depletions in the bulk sulfide of the Qingkuanghan deposit suggest that the parental magma of the host intrusion may have undergone minor sulfide segregation at depth. The mixing calculations suggests that an average of 10% crustal contamination in the magma, which may have been the main cause of sulfide saturation in the magma. We propose that sulfide segregation from a moderately PGE depleted magma took place prior to magma emplacement at Qingkuangshan, that small amounts of immiscible sulfide droplets and olivine and chromite crystals were suspended in the ascending magma, and that the suspended materials settled down when the magma passed trough the Qingkuangshan conduit. The Qingkuangshan sulfide-bearing intrusion is interpreted to a feeder of Emeishan flood basalts in the region.     

Geochemistry, Nd Isotopic Characteristics of Metamorphic Complexes in Northern Hebei： Implications for Crustal Accretion

The middle segment of the northern margin of the North China Craton （NCC） consists mainly of metamorphosed Archean Dantazi Complex, Paleoproterozoic Hongqiyingzi Complex and unmetamorphosed gabbro-anorthosite-meta-alkaline granite, as well as metamorphosed Late Paleozoic mafic to granitoid rocks in the Damiao-Changshaoying area. The -2.49 Ga Dantazi Complex comprises dioritic-trondhjemitic-granodoritic-monzogranitic gneisses metamorphosed in amphibolite to granulite facies. Petrochemical characteristics reveal that most of the rocks belong to a medium- to high-potassium calc-alkaline series, and display Mg^# less than 40, right-declined REE patterns with no to obviously positive Eu anomalies, evidently negative Th, Nb, Ta and Ti anomalies in primitive mantlenormalized spider diagrams, εNd（t）=＋0.65 to -0.03, and depleted mantle model ages TDM=2.78-2.71 Ga. Study in petrogenesis indicates that the rocks were formed from magmatic mixing between mafic magma from the depleted mantle and granitoid magma from partial melting of recycled crustal mafic rocks in a continental margin setting. The 2.44-2.41 Ga Hongqiyingzi Complex is dominated by metamorphic mafic-granodioritic-monzogranitic gneisses, displaying similar petrochemical features to the Dantazi Complex, namely medium to high potassium calc-alkaline series, and the mafic rocks show evident change in LILEs, negative Th, Nb, Ta, Zr anomalies and positive P anomalies. And the other granitiod samples also exhibit negative Th, Nb, Ta, P and Ti anomalies. All rocks in the Hongqiyingzi Complex show right-declined REE patterns without Eu anomaly. The metamorphic mafic rocks with εNd（t） = -1.64 may not be an identical magmatic evolution series with granitoids that have εNd（t） values of ＋3.19 to ＋1.94 and TDM ages of 2.55-2.52 Ga. These granitic rocks originated from hybrid between mafic magma from the depleted mantle and magma from partial melting of juvenile crustal mafic rocks in an island arc setting. All the -311 Ma Late Paleozoic metamorphic mafic rocks and related granitic rocks show a medium-potassium calc-alkaline magmatic evolution series, characterized by high Mg^#, obviously negative Th, Nb, Ta anomalies and positive Sr anomalies, from no to strongly negative Ti anomalies and flat REE patterns with εNd（t） = ＋8.42, implying that the maflc magma was derived from the depleted mantle. However the other granitic rocks are characterized by right-declined REE patterns with no to evidently positive Eu anomalies, significantly low εNd（t） = -13.37 to -14.04, and TDM=1.97-1.96 Ga, revealing that the granitoid magma was derived from hybrid between maflc magma that came from -311 Ma depleted mantle and granitoid magma from Archean to Early Paleoproterozoic ancient crustal recycling. The geochemistry and Nd isotopic characteristics as well as the above geological and geochronological results indicate that the middle segment of the northern margin of the NCC mainly experienced four crustal growth episodes from Archean to Late Paleozoic, which were dominated by three continental marginal arc accretions （-2.49, -2.44 and 311 Ma）, except the 1.76-1.68 Ga episode related to post-collisional extension, revealing that the crustal accretion of this segment was chiefly generated from arc accretion and amalgamation to the NCC continental block.     

An Overview on the Composition and Age of Upper Crust of Proto-Tethyan Lajishan Intra-oceanic Arc, NE Tibet Plateau

Identification and anatomy of oceanic arcs within ancient orogenic belt are significant for better understanding the tectonic framework and closure process of paleo-ocean basin. This article summarizes the geological, geochemical, and geochronological characteristics of upper crust of Proto-Tethyan Lajishan intra-oceanic arc and provides new data to constrain the subduction evolution of the South Qilian Ocean. The intra-oceanic arc volcanic rocks, including intermediate–mafic lava, breccia, tuff, and minor felsic rocks, are distributed along southern part of the Lajishan ophiolite belt. Geochemical and isotopic compositions indicate that the intermediate–mafic lava were originated from depleted mantle contaminated by sediment melts or hydrous fluids, whereas the felsic rocks were likely generated by partial melting of juvenile mafic crust in intra-oceanic arc setting. Zircons from felsic rocks yield consistent and concordant ages ranging from 506 to 523 Ma, suggesting these volcanic rocks represent the relicts of upper crust of the Cambrian intra-oceanic arc. Combined with the Cambrian forearc ophiolite and accretionary complex, we suggest that the Cambrian intra-oceanic arc in the Lajishan ophiolite belt is belonging to the intra-oceanic arc system which was generated by south-directed subduction in the South Qilian Ocean at a relatively short interval between approximately 530 and 480 Ma.     

Petrogenesis and Geodynamic Implications of Early Cretaceous (~130 Ma) Magmatism in the Baingoin Batholith, Central Tibet: Products of Subducting Slab Rollback

The Baingoin batholith is one of the largest granitic plutons in the North Lhasa terrane. Its petrogenesis and tectonic setting have been studied for decades, but remain controversial. Here we report data on geochronology, geochemistry and isotopes of Early Cretaceous granitoids within the Baingoin batholith, which provide more evidence to uncover its petrogenesis and regional geodynamic processes. The Early Cretaceous magmatism yields ages of 134.4–132.0 Ma and can be divided into I-type, S-type and highly fractionated granites. The I- and S-type granites exhibit medium SiO2, high K2O/Na2O with negative εNd(t) and εHf(t) values, whereas, the albite granites have very high SiO2 (79.04%–80.40%), very low K2O/N2O, negative εNd(t) and a large variation in εHf(t). Our new data indicate that these granitoids are derived from unbalanced melting in a heterogeneous source area. The granodiorites involved had a hybrid origin from partial melting of basalt-derived and Al-rich rocks in the crust, the porphyritic monzogranites being derived from partial melting of pelitic rocks. The albite granites crystallized from residual melt separated from K-rich magma within the ‘mush’ process and underwent fractionation of K-feldspar. We believe that the Early Cretaceous magmatism formed in an extensional setting produced by the initial and continuous rollback of a northward-subducting slab of the NTO.     

Geochemical and Petrological Studies on the Early Carboniferous Sidingheishan Mafic–Ultramafic Iintrusion in the Southern Margin of the Central Asian Orogenic Belt, NW China

The Sidingheishan mafic-ultramafic intrusion is located in the eastern part of the Northern Tianshan Mountain, along the southern margin of the Central Asian Orogenic Belt in northern Xinjiang autonomous region of China. The Sidingheishan intrusion is mainly composed of wehrlite, olivine websterite, olivine gabbro, gabbro and hornblende gabbro. At least two pulses of magma were involved in the formation of the intrusion. The first pulse of magma produced an olivine-free unit and the second pulse produced an olivine-bearing unit. The magmas intruded the Devonian granites and granodiorites.An age of 351.4±5.8 Ma(Early Carboniferous) for the Sidingheishan intrusion has been determined by U-Pb SHRIMP analysis of zircon grains separated from the olivine gabbro unit. A U-Pb age of 359.2±6.4 Ma from the gabbro unit has been obtained by LA-ICP-MS. Olivine of the Sidingheishan intrusion reaches 82.52 mole% Fo and 1414 ppm Ni. On the basis of olivine-liquid equilibria, it has been calculated that the MgO and FeO included in the parental magma of a wehrlite sample were approximately10.43 wt% and 13.14 wt%, respectively. The Sidingheishan intrusive rocks are characterized by moderate enrichments in Th and Sm, slight enrichments in light REE, and depletions in Nb, Ta, Zr and Hf. The ε_(Nd)(t) values in the rock units vary from +6.70 to +9.64, and initial ~(87)Sr/~(86)Sr ratios range between 0.7035 and0.7042. Initial ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb and ~(208)Pb/~(204)Pb values fall in the ranges of 17.23-17.91,15.45-15.54 and 37.54-38.09 respectively. These characteristics are collectively similar to the Heishan intrusion and the Early Carboniferous subduction related volcanic rocks in the Santanghu Basin, North Tianshan and Beishan area. The low(La/Gd)_(PM) values between 0.26 and 1.77 indicate that the magma of the Sidingheishan intrusion was most likely derived from a depleted spinel-peridotite mantle.(Th/Nb)_(PM)ratios from 0.59 to 20.25 indicate contamination of the parental magma in the upper crust.Crystallization modeling methods suggest that the parental magma of the Sidingheishan intrusion was generated by flush melting of the asthenosphere and subsequently there was about 10 vol%contamination from a granitic melt. This was followed by about 5 vol% assimilation of upper crustal rocks. Thus, the high-Mg basaltic parental magma of Sidingheishan intrusion is interpreted to have formed from partial melting of the asthenosphere during the break-off of a subducted slab.     

Experimental Study of the Influence of Hydrous Minerals on the Melting Behaviour of Rocks at High Temperatures and Pressures

The experimental study on the melting of potassic basalt and eclogite with about 2% waterat 800-1300℃ and 1.0-3.5 GPa shows that the solidi of both rocks are significantly lower thanthose obtained from the previous experiments of the same type of rocks under dry conditions,and the former which is enriched in potassium has a lower melting point than the latter. It is con-sistent with the previous study. The melting temperature of eclogite increases with pressure,whereas potassic basalt has similar properties only at 1.5—2.5 GPa and>3.0 GPa, and at 2.5—3.0 GPa the melting temperature decreases with pressure. This can be explained as follows: (1)eclogite only has one hydrous mineral amphibole and the dehydous temperature is lower than thewet solidus of the rock. (2) Amphibole exists in potassic basalt at the pressures lower than 2.5GPa and phlogopite exists at pressures higher than 2.5 GPa, and the special compositions of bothminerals determine that amphibole has a dehydration temperature higher than or close to that ofthe wet solidus of the rocks, while phlogopite has a dehydration temperature lower than that ofthe wet solidus. On the other hand the features of the continuous solidus in the experiment ofhydrous eclogite were produced by the fact that the dehydration temperature of its amphibolelower than or close to the melting temperature of the hydrous conditions. So the melting tempera-ture lowers at higher pressures. Therefore, the composition of the rocks in the lithosphere and thetypes of hydrous minerals and their stable P-T conditions are the important factors controllingthe solidi of rocks. It can quite well explain the partial melting of rocks and the origin of the lowvelocity zone in the deep lithosphere.     

LA-ICP-MS U-Pb Zircon Dating for Felsic Granulite, Huangtuling Area, North Dabieshan: Constraints on Timing of Its Protolith and Granulite-Facies Metamorphism, and Thermal Events in Its Provenance

Information about the protolith of the Huangtuling granulite in North Dabieshan has been unavailable. The complex evolution history of the rock and its host basement must be further discussed. LA-ICP-MS U-Pb dating was conducted on three textural domains in zircon from a high-temperature, high-pressure felsic granulite in the Huangtuling area, North Dabieshan, Central China. The metamorphic growth-derived detrital zircon domain yields a 207Pb/206Pb age in the range of (2 493±54) -(2 500±180) Ma. The magmatic genesis-derived detrital zircon domain gives a 207Pb/206Pb age ranging from 2 628 Ma to 2 690 Ma, with an oldest 206Pb/238U age of (2 790±150) Ma. The metamorphic overgrowth or metamorphic recrystallization zircon domain yields a dicsordia with an upper intercept age of (2 044.7±29.3) Ma. Compositions of the mineral assemblage, major element geochemistry, and especially the complex interior texture of the zircon suggest that the prololith of the felsic granulite is of sedimentary origin. Results show that the protolith material of the granulite came from a provenance with a complex thermal history, i.e. ～2.8 Ga magmatism and ～2.5 Ga metamorphism, and was deposited in a basin not earlier than 2.5 Ga. The high-temperature and high-pressure granulite-facies metamorphic age was precisely constrained at (2.04±0.03) Ga, which indicates the granulite in Huangtuling area should be a relict of a Paleoproterozoic UHT (ultrahigh temperature) metamorphosed slab.