桂东北大宁岩体锆石SHRIMP年代学和地球化学研究

大宁岩体位于扬子板块与华夏板块结合带,岩性组合为二长闪长岩-花岗闪长岩-二长花岗岩-钾长花岗岩.岩体中广泛存在壳幔混合包体.本文利用锆石sHRIMPU-Pb法,获得大宁岩体成岩年龄上限为(419.1±6.4)Ma(MSWD=1.03),属加里东晚期.岩体的地球化学研究显示,大宁岩体属弱过铝高钾钙碱性岩石,富大离子亲石元素和轻稀土,显Nb、Ba、Sr、Eu组合异常.岩石具有较高的I_(Sr)值(0.7112～0.7196),较低的εNd(t)值(-6.77～-7.53)和T_(DM)值(1.40～1.71Ga).结合邻区加里东花岗岩壳幔混合特征,本文认为,大宁岩体为幔源岩浆底侵诱发的下地壳变砂屑岩部分熔融形成,形成过程中有显著的幔源组分加入.     

北祁连西段小柳沟矿区花岗质岩石锆石U-Pb年代学、地球化学及成因研究

甘肃小柳沟钨钼(铜)矿是一个与花岗岩类有关的斑岩-矽卡岩-石英脉型矿床,小柳沟矿区内花岗质岩石类型主要为二长花岗岩和花岗闪长岩。本文对该岩体进行年代学、地球化学研究以约束其形成时代和岩石成因。LA-ICP-MS锆石UPb测年分别获得二长花岗岩与花岗闪长岩谐和年龄为454.0±2.0Ma和417.7±1.7Ma,属于加里东期岩浆活动的产物,并经历了海西期和燕山期岩浆热事件的改造。地球化学数据显示,小柳沟花岗质岩石具有高硅、富碱的特征,属于过铝质高钾钙碱性系列,富集Rb、Th、U、K、Pb,亏损Ba、Sr、Ti、P,具有明显Eu负异常,尤其是二长花岗岩显示强烈的铕负异常(δEu为0.08～0.19),属于高分异I型花岗岩。锆石Hf同位素分析结果显示,二长花岗岩εHf(t)为-4.45～4.04,t DM2=1176～1714Ma,花岗闪长岩εHf(t)为-4.18～4.43,t DM2=1124～1670Ma,二者可能是由壳幔混合作用形成,其壳源源区很可能来源于古元古代-中元古代古老地壳岩石,花岗闪长岩的源区相对较深,北大河岩群与朱龙关群可能是小柳沟钨矿的初始矿源层。综合研究表明,小柳沟钨钼矿床与二长花岗岩在时间、空间及成因上有密切关系。结合区域构造演化,认为小柳沟二长花岗岩应形成于俯冲背景下的活动大陆边缘环境,花岗闪长岩形成于碰撞造山环境。     

西昆仑阿卡阿孜山杂岩体的特征和成因

阿卡阿孜山杂岩体位于西昆仑昆南地体南侧,被新藏公路横切出一条南北长约2 km的剖面。在剖面范围内可见二长闪长岩、石英二长闪长岩、花岗闪长岩、二长花岗岩、正长花岗岩和碱长花岗岩等多种岩石类型出露。通过详细研究岩体的野外地质特征、地球化学和同位素地球化学特征发现：岩体中出现不平衡矿物组合;镁铁质微粒包体中可见石英和长石捕虏晶;各岩石样品的痕量元素配分型式呈现相似性;岩体的Sr、Nd、Pb同位素体系同时具有地幔和下地壳的贡献等,认为岩体形成于壳幔岩浆混合作用,幔源岩浆底侵作用可能是混合作用的直接原因。由此推测,幔源岩浆底侵作用是西昆仑地区印支晚期岩浆活动的重要诱发机制。     

闽南沿海地区变质变形侵入岩时序划分及其地质意义

根据接触关系,结合同位素测年资料、岩石变形变质特征及原岩的岩石学、矿物学等特征,将闽南沿海地区变质变形侵入岩划分为早侏罗世东山序列(石英闪长岩—花岗闪长岩—二长花岗岩—正长花岗岩)、晚侏罗世古美山序列(花岗闪长岩—二长花岗岩—正长花岗岩)(145.4 Ma,LA-ICPMS锆石U-Pb)及早白垩世早期漳浦序列(石英闪长岩—花岗闪长岩—二长花岗岩—正长花岗岩)(121.5～139.4 Ma,锆石U-Pb)。并据侵入岩产状、岩石学、矿物学、岩石化学及地球化学等特征,分析各序列花岗岩的成因及形成时的构造环境,认为早侏罗世东山序列岩浆来源为壳-幔混合源(I型),形成于构造体制由挤压转向拉张转换期大陆上隆(碰撞后隆升)的构造环境(PAG);晚侏罗世古美山序列岩浆来源为幔-壳混合源(I-S型),属与板块碰撞(俯冲作用)有关的同碰撞花岗岩(ACG);早白垩世早期漳浦序列岩浆来源为壳-幔混合源(I-S型),属构造体制由挤压向拉张转化时期幔-壳源型花岗岩(KCG)。该区变质变形花岗岩序次的厘定及其成因、形成环境的研究为长乐—南澳断裂带中生代构造演化提供了依据,并为东南沿海地区寻找与中生代岩浆作用有关的钨、锡、铜、钼等矿产提供找矿理论依据。     

新疆东准噶尔黄羊山碱性花岗岩体的锆石U-Pb年龄和岩石成因

新疆东准噶尔卡拉麦里构造带分布有多种类型花岗岩,主要包括花岗闪长岩、二长花岗岩、碱长花岗岩和碱性花岗岩.对其中最大的碱性花岗岩体(黄羊山岩体)进行定年和地球化学组成研究,结果显示,岩体的年龄约为305 Ma,岩石富含钠质角闪石(钠闪石、钠铁闪石)和少量霓石,具低铝、富碱、贫钙镁及低铁的主量元素特征,其微量元素明显富集Rb、Th等大离子亲石元素和Zr、Hf等高场强元素而强烈亏损元素Ba、Sr、Eu,稀土元素配分模式呈典型的平坦‘V'字型.这些矿物学和地球化学组成特征表明黄羊山碱性花岗岩属于典型的A型花岗岩.认为幔源岩浆高度分异、麻粒岩相残留岩及I型英云闪长质-花岗闪长质岩石部分熔融等A型花岗岩成岩模式不能解释黄羊山碱性花岗岩的成因.根据岩石的εNd(t)= 5.9～ 6.5,比当时洋壳的εNd(t)值低3～4个ε单位,认为形成该岩体的岩浆可能来源于花岗闪长质岩浆的分异结晶,而花岗闪长质岩浆则主要是玄武质洋壳和少量大洋沉积物(约5%)部分熔融的产物.     

黑龙江太平岭早侏罗世花岗岩成因及壳幔混合作用

位于黑龙江省牡丹江一带的太平岭是兴蒙造山带的重要组成部分,在该区广泛分布大量花岗岩。这些花岗岩的SHRIMP锆石U-Pb年龄介于179～204 Ma之间,表明形成于早侏罗世,而非以往认为的晚三叠世。岩体的岩性以花岗闪长岩为主,其中普遍含有细粒闪长质包体,而二长花岗岩-正长花岗岩中偶见细粒闪长质包体。岩石学、岩相学和地球化学研究表明这些花岗岩为壳幔岩浆混合成因。太平岭早侏罗世花岗岩具有比较均一的Sr、Nd、Pb同位素成分,εNd(t)值介于-3.2～+2.3之间,(87Sr/86Sr)i值主要集中在0.704～0.706之间,进一步表明岩石的源区与幔源物质有密切的联系。花岗岩显示火山弧花岗岩的特点,代表了以挤压为主的构造环境,表明岩石可能与古太平洋板块俯冲作用有关。     

江西大湖塘矿区九岭花岗闪长岩的成因及其构造意义

江南造山带东段发育了一系列新元古代花岗岩类侵入体,其中以江西九岭岩体最为显著。锆石U-Pb定年结果表明九岭岩体形成于819Ma。富云母暗色包体在九岭花岗闪长岩体内部广泛出现,典型的岩浆结构及针状磷灰石表明包体为岩浆成因。花岗闪长岩及暗色包体的Mg~#(42~50)均大于玄武质岩石熔融实验结果(大多数40)。暗色包体具有更高的MgO、CaO、Fe_2O_3~T、TiO2及更高的Ni、Co、Sc、V。全岩Sm-Nd同位素结果显示暗色包体的ε_(Nd)(t)为-3.4~-2.1,花岗闪长岩ε_(Nd)(t)为-4.0~-3.5。花岗闪长岩锆石的ε_(Hf)(t)为(-1.4~6.4),多数为正值。Nd-Hf同位素分析表明双桥山群很可能是花岗闪长岩的源区。暗色岩浆包体的普遍发育暗示九岭岩体形成于壳幔岩浆混合过程,除双桥山群外,地幔也贡献了一定的物质。暗色富云包体不是岩石熔融的残渣,而是幔源基性岩浆与富钾下地壳相互作用的产物。结合区域上变质岩、地层学、基性岩研究结果,我们认为扬子板块与华夏板块碰撞的时间很可能在825Ma左右,九岭岩体形成于造山带碰撞挤压向伸展转变的过渡阶段,是壳幔岩浆混合的产物。     

吉林南部晚三叠世蚂蚁河岩体的成因:锆石U-Pb年代学和地球化学证据

蚂蚁河岩体主要由辉长闪长岩-花岗闪长岩-二长花岗岩构成。辉长闪长岩和二长花岗岩中的锆石呈自形晶,发育细微振荡生长环带,显示高的Th/U值(0.14～2.56),表明了锆石的岩浆成因。锆石LA-ICP-MSU-Pb定年结果表明,辉长闪长岩中锆石206Pb/238U年龄集中于219～227Ma,其加权平均年龄为(224±4)Ma(n=8);二长花岗岩中锆石年龄为217～241Ma,206Pb/238U加权平均年龄为(226±3)Ma(n=19)。岩石地球化学分析结果表明,蚂蚁河岩体具有双峰式岩石组合特征,辉长闪长岩具有较低的SiO2,较高的TiO2、MgO和CaO,以及富集大离子亲石元素(LILEs)和轻稀土元素(LREEs),亏损高场强元素(HFSEs)特征,其87Sr/86Sr初始值和εNd(t)值分别为0.7037和3.45～3.82。上述特征暗示岩浆起源于亏损岩石圈地幔;相反,花岗闪长岩和二长花岗岩具有较高的SiO2,较低的TiO2、MgO和CaO,以及强烈富集Rb、Th、U,亏损Nb、Ta、P、Ti、Ba、Sr的地球化学属性,其87Sr/86Sr初始值和εNd(t)值分别为0.7053～0.7058和-0.73～-3.40,暗示了岩浆的壳源成因。蚂蚁河岩体双峰式岩石组合的存在反映了伸展的构造背景,结合区域构造研究成果,其成因应与扬子和华北克拉通之间俯冲碰撞后的伸展环境有关,华北克拉通东部中生代岩石圈减薄或破坏始于晚三叠世,减薄或破坏空间范围应包括吉南地区。     

甘肃北山柳园地区花岗岩类的年代学、地球化学特征及构造意义

北山柳园地区分布大量的花岗岩类岩石,岩石类型有花岗闪长岩、二长花岗岩、钾长花岗岩和斑状花岗岩。锆石SHRIMP U—Pb 定年分析结果为:花岗闪长岩的侵位年代为423±8Ma 辉铜山以东(HT-)钾长花岗岩和二长花岗岩的侵位分别为436±9Ma 和397±7Ma。该区花岗质岩石都具有大离子亲石元素和轻稀土元素相对富集,K、Ni、Ta、P 和 Ti 负异常的特征,属于准铝质到过铝质的高 K 花岗岩。花岗闪长岩无 Sr 和 Eu负异常的特征,ε_(Nd)(t)=-2.5～-0.8,其岩浆源于岩石圈地幔或是软流圈与岩石圈地幔相混合的岩浆熔融,并受到了含有火山弧组分的年轻地壳的混染。钾长花岗岩和二长花岗岩具有 Sr 和 Eu 负异常的特征,ε_(Nd)(t)值分别为 1.4、-4.0～-2.0和-2.7～-0.3。HT-钾长花岗岩岩浆主要源于由于岩石圈地幔岩浆作用而导致上覆年轻地壳物质的部分熔融;花牛山附近(HN-)钾长花岗岩岩浆主要源于软流圈地幔部分熔融,可能受到了部分年轻地壳物质的混染;二长花岗岩岩浆主要源于年轻地壳的部分熔融。柳园地区4类花岗岩类岩石都是后碰撞构造背景下的岩浆产物,岩浆形成可能与俯冲板片断离有关。     

桂东南富钾岩浆岩岩的Nd同位素组成：华南中生代地幔物质上涌事件

广西东南部罗容杂岩体由辉长岩－闪长岩－二长岩－正长岩组成，马山由碱性辉长岩－正长岩－花岗闪长岩－花岗岩组成。它们富K、富大离子亲石元素（LIL），无Nb、Ta负异常等特征表明它们是形成于板内环境的钾玄质侵入岩。罗容杂岩体的各种岩石和马山的基性岩的εNd(T)稍低，为－0．6，此岩石单元是由幔源岩浆加热地壳使之熔融的壳源岩浆形成的，并伴有幔源岩浆的混合或交换。此二杂岩体形成于拉张构造环境。地幔物质上涌导致了中生代华南地壳张裂以及华南大规模花岗岩和相关矿床的形成。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.