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1.
对山东中侏罗世-早白垩世侵入岩中锆石的原位Hf同位素分析显示,形成于晚太古代(上交点年龄~2.5Ga)的继承锆石具有正的ε_(Hf)(t)值( 8~ 1),Hf同位素模式年龄集中在2.6~2.8Ga,与辽宁古生代金伯利岩中基性下地壳捕虏体中锆石Hf组成和Hf模式年龄十分一致,Hf模式年龄也与研究区变质岩和花岗岩的全岩Nd模式年龄相同,因此,这些继承锆石来自于晚太古代由岩浆底侵形成的基性下地壳。新生锆石出现在继承锆石周围或者以独立颗粒出现,其U-Pb年龄为177Ma和132~126Ma,ε_(Hf)(t)值均为负值(-23~-1)。山东中生代侵入岩的形成与富集岩石圈地幔,亏损地幔和地壳三个端员之间的相互作用有关。其中根据来源于晚太古代下地壳的侏罗纪铜石二长花岗岩限定的研究区下地壳ε_(Hf)(t)平均值为-20,根据来源于富集岩石圈地幔的早白垩纪沂南辉长岩限定的富集地幔端员的ε_(Hf)(t)为-16。部分样品锆石ε_(Hf)(t)变化非常大(-20~-1),示踪了岩浆作用过程中亏损地幔物质的参与程度的逐渐增强。这种变化是华北晚中生代岩石圈大规模减薄作用的结果。  相似文献   

2.
王芳  陈福坤  侯振辉  彭澎  翟明国 《岩石学报》2009,25(11):3057-3074
本文报道冀北崇礼-赤城地区晚古生代花岗岩类岩石的锆石U-Pb年龄和Sr-Nd-Hf同位素组成特征.它们出露在华北陆块北缘的构造单元内,侵位于中高级变质基底岩石红旗营子群中.锆石LA-ICP-MS定年结果表明,海流图花岗岩岩体记录了两期岩浆作用,即299±3Ma和254±11Ma;镇宁堡片麻状二长花岗岩和白花沟片麻状黑云母石英二长闪长岩分别形成于287±1Ma和252±3Ma.这些晚古生代花岗岩类岩石具有较低的初始~(87)Sr/~(86)Sr值(0.7062~0.7076)、低的ε_(Nd)(t)值(-18.1至-9.6)和古老的Nd亏损地幔模式年龄(2.49~1.87Ga).其锆石的ε~(Hf)(t)值变化在-13.2至-7.4之间,Hf平均地壳模式年龄值(T_(DM)~C)在2.15Ga至1.79Ga之间.锆石Hf同位素特征与全岩Nd同位素特征指示古老的华北陆块地壳物质是花岗岩浆的主要物源.在形成时代和地球化学特征上,崇礼-赤城地区晚古生代花岗岩与出露在东部丰宁-承德地区的花岗岩类岩石既有相似性,又有不同之处,可能代表华北陆块北缘不同构造背景下岩浆作用的产物.  相似文献   

3.
对青藏高原冈底斯带西部中生代花岗岩的研究依然十分有限。本文选择青藏高原冈底斯带西部狮泉河-革吉-雄巴地区的三个花岗岩基进行了锆石SHRIMP U-Pb定年和锆石Hf同位素分析,并探讨了中冈底斯带中侏罗世-早白垩世花岗岩的分布特征及其揭示的地壳基底的属性。定年结果表明,江巴岩体花岗闪长岩年龄为170±3Ma,雄巴岩体碱长花岗岩年龄为149±3Ma,它们形成于中晚侏罗世;邦巴岩体寄主岩石正长花岗岩和其中的石英二长闪长岩包体年龄分别为144±3Ma和133±3Ma,形成于早白垩世。锆石Hf同位素和地壳模式年龄结果表明,中晚侏罗世的江巴岩体(εHf(t)为-16.8~-13.4,Hf同位素地壳模式年龄为2.1~2.3Ga)与雄巴碱长花岗岩(-11.3~-6.2和1.6~2.0Ga)具有富集的Hf同位素特征,显示了新元古界的地壳基底年龄。邦巴正长花岗岩(-4~-0.8和1.2~1.5Ga)与其中的闪长质包体(-2.8~+0.6和1.2~1.4Ga)具有一致的Hf同位素特征,显示了岩浆混合作用。本文花岗岩定年与Hf同位素结果进一步揭示出中冈底斯带存在未出露地表的古元古代地壳基底。  相似文献   

4.
华北克拉通东部中生代期间受到古太平洋板块俯冲并引发一系列的构造-岩浆-成矿作用,但古太平洋俯冲作用开始的具体时限仍未有定论。本文对辽西兴城地区中生代药王庙-磨盘山岩体进行了系统的岩相学研究、锆石U-Pb同位素定年、全岩地球化学和锆石原位Hf同位素测试分析,结果显示,花岗质岩石中岩浆成因锆石加权平均年龄为193~186 Ma,岩体侵位于早侏罗世;岩石组合为石英二长岩-花岗闪长岩-二长花岗岩-正长花岗岩;岩石全碱含量较高,属准铝-弱过铝质、高钾钙碱性系列,具有与Ⅰ型花岗岩类似的岩石地球化学特征;岩石相对富集轻稀土元素和大离子亲石元素K、Pb等,而相对亏损高场强元素Nb、Ta、Ti等及P元素;岩浆成因锆石εHf(t)值为-12.94~-7.39,Hf同位素二阶段模式年龄为2.05~1.69 Ga,其初始岩浆可能来源于古老地壳的部分熔融并可能有幔源物质的参与。辽西兴城地区早侏罗世花岗岩岩石组合、岩石地球化学特征和与俯冲作用有关的活动陆缘花岗岩特征类似,岩石形成于古太平洋俯冲作用导致的活动陆缘构造背景下,结合区域研究资料,认为古太平洋对华北克拉通东部的俯冲作用开始于晚三叠世—早侏罗世,而早侏罗世花岗质岩浆活动是古太平洋板块对华北克拉通俯冲作用的响应。  相似文献   

5.
对蚌埠隆起区中生代不同时期的花岗岩中6个岩体的锆石LA-MC-ICP MS原位Hf同位素的研究,据此限定它们的岩浆源区和重建华北克拉通东南部的构造格架。结果表明,中生代不同时期的花岗岩中岩浆锆石的初始Hf同位素组成(ε_(Hf)(t))可以分成两组:第一组的女山(130Ma)和西庐山花岗岩(130Ma)的ε_(Hf)(t)值分别为-18.4和-16.1;第二组的曹山(110Ma)、锥山二长花岗岩(110Ma)和蚂蚁山花岗岩(110Ma)以及淮光花岗闪长岩(130Ma)的ε_(Hf)(t)值分别为-22.3、-23.1和-21.1以及-28.1,这些岩浆锆石低的ε_(Hf)(t)值表明它们可能来源于古老的大陆下地壳。女山和西庐山岩体中早古生代—新元古代继承锆石具有低的ε_(Hf)(t)值(-2.3~-7.7)和1.52Ga~1.79Ga的Hf同位素两阶段模式年龄,表明它们的岩浆源区主要以扬子克拉通下地壳物质为主。曹山、锥山和蚂蚁山以及淮光岩体中岩浆锆石的Hf同位素两阶段模式年龄为1.89Ga~2.58Ga,结合淮光岩体中古元古代继承锆石和3400Ma捕获锆石中低的ε_(Hf)(t)值(-5.7~-6.8,-0.6、-0.9)和古老的Hf同位素两阶段模式年龄(2.44Ga~2.80Ga,3.7Ga),表明它们主要来源于华北克拉通下地壳物质的部分熔融。淮光和女山岩体中古元古代—新太古宙继承锆石中正的ε_(Hf)(t)值(0.3~6.7)以及高的ε_(Hf)(t)值(16.9~21.7)的存在,暗示形成这些古老继承锆石的初始物质中有幔源物质的涉入。蚌埠隆起区深部地壳中扬子克拉通基底物质的存在暗示扬子克拉通可能沿着郯庐断裂带向西或北西方向俯冲于华北克拉通之下。  相似文献   

6.
目前对于华北克拉通东部晚中生代花岗质岩石的成因仍存在地幔柱、加厚/拆沉下地壳部分熔融、俯冲板片脱水导致地壳熔融等不同认识。辽西兴城地区晚中生代花岗质岩石主要由二长花岗岩、石英闪长岩、花岗斑岩和石英正长岩组成,岩浆成因锆石U-Pb同位素定年结果显示岩浆活动主要发生于晚侏罗世(156Ma)、早白垩世早期(139Ma)、早白垩世中期(130~125Ma)。岩石地球化学测试分析结果显示岩石属于高钾钙碱性系列且具有富集K、Pb等大离子亲石元素而相对亏损Nb、Ta、Ti等高场强元素等活动陆缘岩浆岩特点,表明辽西地区晚中生代岩浆活动的发生与俯冲作用有关。晚侏罗世-早白垩世早期(156~139Ma)花岗质岩石地球化学特征与I型花岗岩类似,同时具有富集的Hf同位素组成(εHf(t)=-22.70~-18.66)和古老的Hf同位素二阶段模式年龄(tDM2=2387~2767Ma),其初始岩浆可能来源于古老中上地壳的部分熔融;形成于130Ma的花岗质岩石同样具有与I型花岗岩相类似的岩石地球化学特征,但其Hf同位素组成突变为亏损(εHf(t)=+3.64~+6.22、tDM1=537~969Ma),其初始岩浆起源于新元古代新生地壳物质的部分熔融并混入少量亏损地幔物质组分;形成于125Ma的花岗质岩石为碱性A型花岗岩,岩石地球化学特征与其他岩石有所不同,具有负的εHf(t)值(-17.30~-11.56)和相对古老的Hf同位素二阶段年龄(tDM2=1917~2278Ma),初始岩浆可能起源于较为古老的中下地壳部分熔融并有幔源物质的参与。华北克拉通东部形成于160~139Ma的花岗质岩石具有I型、高钾钙碱性、与埃达克质岩石类似的高Sr/Y、低Y含量特征和富集的Hf同位素组成,而形成于130~120Ma的花岗质岩石具有A型、碱性、与典型岛弧岩浆岩类似的岩石地球化学特征和相对亏损的Hf同位素组成,同时晚中生代岩浆活动具有向洋年轻化的特点,表明华北克拉通东部156~139Ma期间可能受到古太平洋板块的持续俯冲作用,而139~130Ma古太平洋俯冲板片开始回撤,130~125Ma进入古太平洋俯冲板片持续回撤导致的强烈区域伸展作用阶段。古太平洋俯冲板片脱水交代岩石圈地幔并形成幔源岩浆,幔源岩浆不断底侵作用于古老/新生地壳使其发生部分熔融为花岗质岩石提供岩浆来源。  相似文献   

7.
华北克拉通五台群LA-ICP-MS锆石U-Pb年龄和Hf同位素特征   总被引:2,自引:0,他引:2  
通过对五台群石咀亚群金刚库组4个典型样品的LA-ICP-MS锆石U-Pb年龄和Hf同位素研究,对五台群的形成时代及华北克拉通新太古代—古元古代期间的地壳演化进行了探讨。锆石U-Pb同位素测定结果表明,侵入金刚库组中的片麻状花岗岩锆石的U-Pb年龄为2548Ma,因此五台群的上限年龄约为2.5Ga;金刚库组黑云母石英片岩和片麻状石英闪长岩的原岩锆石U-Pb年龄分别为2663Ma和2636Ma,因此五台群的下限年龄约为2.7Ga。五台群的地质年龄为2.5~2.7Ga,属于新太古代。锆石Hf同位素研究结果表明,黑云母石英片岩和片麻状石英闪长岩的二阶段Hf模式年龄(tDM2)均为2.8Ga左右,指示2.8Ga左右是五台山区乃至整个华北克拉通地壳生长的重要时期;片麻状花岗岩tDM2平均为2.57Ga,与锆石结晶年龄非常接近,表明2.5Ga左右也是华北克拉通地壳的主要增生期。地壳的增长是幕式的,2.8Ga和2.5Ga都是华北克拉通地壳生长时期。  相似文献   

8.
对山东中侏罗世-早白垩世侵入岩中锆石的原位Hf同位素分析显示,形成于新太古代(上交点年龄~2.5 Ga)的继承锆石具有正的εHf(t)值(+8~+1),Hf同位素模式年龄集中在2.6~2.8 Ga,与辽宁古生代金伯利岩中基性下地壳捕虏体中锆石Hf组成和Hf模式年龄十分一致,Hf模式年龄也与研究区变质岩和花岗岩的全岩Nd模式年龄相同.  相似文献   

9.
满洲里南部中生代花岗岩的锆石U--Pb年龄及Hf同位素特征   总被引:4,自引:0,他引:4  
满洲里南部地区花岗岩主要由碱长花岗岩、正长花岗岩、二长花岗岩及花岗斑岩组成。采用LA--ICP--MS技术,对满洲里南部花岗岩进行的锆石U--Pb年龄测定表明,该区中生代花岗岩浆活动分为3期:中—晚三叠世(208~239 Ma)、早侏罗世(179~185 Ma)和晚侏罗世—早白垩世(137~151 Ma),与整个大兴安岭中生代花岗岩的年代学格架基本一致,与东部的张广才岭—小兴安岭地区中生代岩浆活动时代也可以对比。锆石LA--MC--ICP--MS Hf同位素研究显示,本区中生代花岗岩的锆石εHf(t)多数为+0.7~+9.5,二阶段模式年龄为0.6~1.2 Ga,表明花岗岩浆主要源于中—新元古代增生的地壳物质。结合额尔古纳地块其他花岗岩的锆石Hf同位素资料,认为额尔古纳地块在中—新元古代时期曾发生一次重要的地壳增生事件,与兴安地块的地壳增生时间为新元古代—显生宙的特点不同。  相似文献   

10.
西天山那拉提地区发育强烈的古生代花岗岩浆活动,依据野外地质特征和形成时代,将该区花岗岩分为早古生代—晚泥盆世花岗岩和石炭纪花岗岩两类。前者变形较强,发育弱的片麻理构造,岩石类型主体为闪长岩-石英闪长岩-花岗闪长岩-二长花岗岩,LA-ICPMS锆石U-Pb定年揭示其形成时代为366~485Ma,εHf(t)和t2DM的研究揭示花岗岩主要有3种来源:一是t2DM介于1.2~1.6Ga的中元古代地壳源区;二是t2DM介于0.7~1.6Ga的中新元古代地壳混合源区;三是t2DM与岩石形成年龄接近或略大的以亏损地幔新生地壳为主的地壳源区。后者变形很弱,LA-ICPMS锆石U-Pb定年揭示其形成时代为320~352Ma。晚泥盆世—石炭纪花岗岩主要源区亦有3种:一是t2DM介于1.0~1.7Ga的中新元古代混合源区;二是t2DM约为0.4Ga左右的早古生代新生地壳源区;三是早石炭世早期与岩浆形成年龄一致的亏损地幔和古老地壳混合源区。那拉提早石炭世花岗闪长岩当εHf(t)为最高的正值时(14.21),其t2DM与岩石形成年龄一致,表明在349Ma时存在一次地幔物质的加入。综合西天山地区区域地质演化和花岗岩的野外地质特征、时代格架、锆石Hf同位素揭示的源区特征,认为那拉提地区现划分的古元古代地层中存在0.7~0.8Ga、1.6~1.8Ga中新元古代增生地壳。石炭纪花岗岩为碰撞后大陆伸展作用的产物,早石炭世大规模地幔物质的加入代表了大陆伸展作用的强烈发育期。  相似文献   

11.
Police, politics, and the right to the city   总被引:1,自引:0,他引:1  
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.  相似文献   

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Average concentrations of Pb, Zn, Cu, and other metals, as well as S and As, were calculated for the Aue granitic cupola, the contact aureole of which hosts the large vein-type uranium deposit of Schlema-Alberoda and the Schneeberg uranium-base metal deposit (Erzgebirge, Germany). The cupola was exposed by mine workings and boreholes, which provided an opportunity to evaluate variations in the abundances of metals in the granites over a vertical interval of more than 2.5 km and estimate their losses in the upper oxidized part of the investigated volume of the cupola (coefficient of iron oxidation, KO Fe, increases in the granites from bottom to top from 7 to 70%) compared with the lower unaltered and unoxidized part (with a KO Fe plateau at about 5%). The average concentrations of metals in the upper part of the cupola are lower than those in the lower part by a factor of 2.5 for Pb, 1.56 for Zn, 1.45 for Cu, 1.3 for Co, etc. A similar decrease in the abundances of ore elements along the vertical section associating with the relative epigenetic alteration and oxidation of the granite was previously described by us for U and Th and for the components of high-temperature ores, W, Sn, and Mo. The removal of ore elements from the granite was accompanied by a decrease in the bulk contents of sulfur and arsenic by a factor of 1.35 and 1.65, respectively. The leaching of trace metals from the granites of the upper part of the Aue cupola was followed by their partial redeposition above the cupola in the ore veins of the Schlema and Schneeberg deposits. Original Russian Text ? Vikt. L. Barsukov, N.T. Sokolova, O.M. Ivanitskii, 2006, published in Geokhimiya, 2006, No. 9, pp. 967–982.  相似文献   

15.
Mercury contamination in aquatic environments is of worldwide concern because of its high biomagnification factor in food chains and long-range transport. The rivers, estuary and the bay along the northwestern Bohai Sea coast, northeastern China have been heavily contaminated by Hg due to long-term Zn smelting and chlor-alkali production. This work investigated the distributions of total Hg (THg) and monomethylmercury (MMHg) in the water, sediment and hydrophytes from this area. Concentrations of THg in sediment (0.5–64 mg kg−1) and water (39–2700 ng L−1) were elevated by 1–3 orders of magnitude compared to background concentrations, which induced high concentrations of MMHg in these media. The highest concentration of MMHg in sediment reached 35 μg kg−1, which was comparable to that in the Hg mining area, Wanshan, China, and the highest MMHg concentration of 3.0 ng L−1 in the water sample exceeded the MMHg Chinese drinking water guideline of 1.0 ng L−1. Concentrations of THg in a sediment profile from Jinzhou Bay were found to be consistent with annual Hg emission flux from a local Zn smelter (r = 0.74, p < 0.01), indicating that Hg contamination was mainly caused by Zn smelting locally. For some freshwater hydrophytes, concentrations of THg and MMHg ranged from 5.2 to 100 μg kg−1 and 0.15 to 12 μg kg−1, respectively. Compared to sediment, concentrations of THg in hydrophytes were 2–3 orders of magnitude lower but MMHg was comparable or higher, indicating that the bioaccumulation in plants was distinct for the two Hg species studied. The data suggest that a significant load of Hg has been released into the northwestern coastal region of the Bohai Sea.  相似文献   

16.
The behavior of trace elements under conditions of partial melting of granitoid rocks has been studied. The element’s partition coefficients between minerals and the melt Dimin/melt depends, in the first place, on the composition of the primary melt. In biotite the HREE Di are a little below 1, while those of LREE, especially Di for Ce, are 1–3 orders of magnitude less. This leads to an efficient differentiation of REEs in anatexic melts especially when biotite is the main mineral phase of restite. On the contrary, there are feldspars, the Di of which cannot provide such a magnitude of differentiation. Unlike garnets and pyroxenes, whose stability in restite permits enrichment of anatexic melts produced in migmatization zones with Nb, Ti, and Cr, the presence of biotite in restite causes depletion of melts with those elements as well as with Rb. Feldspars, under conditions of their fractional crystallization or during differentiation of an anatexic melt, deplete the latter with Sr, Ba, and Rb, but enrich it with Nb, Ti, Cr, Y, Zr, and V.  相似文献   

17.
The dielectric constants and dielectric loss values of 4 Ca-containing minerals were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: vesuvianitel κ′ a=9.93 tan δ=0.006 κ′ c=9.79 tan δ=0.005 vesuvianitel κ′ a=10.02 tan δ=0.002 κ′ c=9.85 tan δ=0.003 zoisite1 κ′ a =10.49 tan δ=0.0006 κ′ b =15.31 tan δ=0.0008 κ′ c=9.51 tan δ=0.0008 zoisite2 κ′ a =10.55 tan δ=0.0011 κ′ b =15.45 tan δ=0.0013 κ′ c=9.39 tan δ=0.0008 epidote κ′ 11= 9.52 tan δ=0.0008 κ′ 22=17.1 tan δ=0.0009 κ′ 33= 9.37 tan δ=0.0006 fluorapatite1 κ′ a =10.48 tan δ=0.0008 κ′ c = 8.72 tan δ=0.0114 fluorapatite2 κ′ a =10.40 tan δ=0.0010 κ′ c=8.26 tan δ=0.0178 The deviation (δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of oxide polarizabilities according to α D (mineral)=∑ α D (oxides) for vesuvianite is ~ 0.5%. The large deviations of epidote and zoisite from the additivity rule with Δ=+ 10.1 and + 11.7%, respectively, are attributed to “rattling” Ca ions. The combined effects of both a large F thermal parameter and possible F-ion conductivity in fluorapatite are believed to be responsible for Δ=+2–3%. Although variation of oxygen polarizability with oxygen molar volume (Vo) is believed to affect the total polarizabilities, the variation of Vo in these Ca minerals is too small to observe the effect.  相似文献   

18.
The 1988 good rainy season in the Sudan raised the hopes that desertification/land degradation and shortage of food so markedly observed in Western Sudan have been elevated. This was particularly so as large quantities of grains were produced in the mechanized rain-fed agricultural schemes in the clay plains of Eastern Sudan. But the field work carried by the author in the Umm Ruwaba district of Kordofan region in July/August 1989 shows that, although there has been some improvement in the crop production situation, desertification/land degradation and shortage of food produced locally are still prevailing in the district. The people are still living below the poverty line, but they are able to cope because of remittances from members of the families working abroad and because of donations of food by some world organizations.  相似文献   

19.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

20.
Yuriy Sokolov 《GeoJournal》1992,26(4):497-502
The discovery of a new continent that was later called America by Christopher Columbus some five hundred years ago, has in one way or another, influenced people the World over. The extraordinary significance of this event for mankind is displayed by the dimension of the consequences and the variety of reactions among nations and communities of the “Old World”.  相似文献   

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