介形虫碳氧同位素测定样品处理方法对比研究

介形虫化石壳体被认为是反映古湖泊沉积环境的理想对象。在过去的30年,介形虫壳体的δ13C和δ18O测定已经被广泛应用到湖泊沉积古气候及古环境的重建。由于湖泊生物碳酸盐样品不同的前处理方法可能会影响到稳定同位素测试结果的重现性和辨析率以及实验室之间数据的可比性,采用有效的方法对介形虫壳体进行预处理是保证介壳稳定同位素测试的一个关键环节。在总结目前常用的湖泊生物碳酸盐稳定同位素测试样品处理方法的基础上,通过对青海湖现代和古代沉积物中介形虫的测定,讨论各种处理方法对介形虫壳体稳定同位素测试结果(δ13C和δ18O)的影响。实验表明:不同处理方法对所测介壳样品的δ13C值和δ18O值不会产生大的影响,在介壳样品的稳定同位素测试之前不需要对介壳样品进行处理。     

青海湖介壳与无机碳酸盐氧同位素组成差异的环境意义

青海湖Q14B沉积物柱芯560~415 cm(约14.0~10.5 ka B.P.)段,介壳1δ8O高于无机碳酸盐1δ8O可能反映了此时青海湖表层水温高于底层水温;介壳1δ8O与无机碳酸盐1δ8O之间的较小差值可能揭示了此时青海湖水位很浅,气候干冷;介壳1δ8O变幅大于无机碳酸盐1δ8O变幅,则可能源于此时青海湖水位大幅度波动导致的底层水温变幅超过表层,以及无机碳酸盐1δ8O测自全碳酸盐所致。在利用湖泊碳酸盐1δ8O进行气候及环境变化研究时,有必要分别测试不同种属介形虫及不同无机碳酸盐矿物的同位素值。     

湖泊化学碳酸盐与生物碳酸盐氧同位素组成差异的环境意义

湖泊生物碳酸盐形成于湖水底层,化学碳酸盐形成于湖水表层;处于湖积物同一层位的两种成因类型的碳酸盐氧同位素组成(δ18O)差异可能反映了二者形成时的环境差异,如湖泊不同深度的水温差异、碳酸盐质生物如介形类小生境水体δ18O值、两种成因碳酸盐形成的时间先后、湖泊表层水体蒸发情况等。在进行碳酸盐δ18O环境意义分析时,应分开测试生物碳酸盐和化学碳酸盐δ18O。     

泥河湾盆地东部中全新世晚期的干/冷干事件与中全新世湿润状况的结束

对取自泥河湾盆地东部化稍营镇 (114°36′E ,40°18′N)附近一剖面以泥炭为主的沉积物做了AMS 1 4 C测年、粒度、碳酸钙含量、碳酸盐中δ1 8O和δ1 3 C组分、有机质含量、TOC、C N分析以及 χlf和SIRM测量。结果表明 ,这些沉积物大致是在 5 32 0～ 3 370aB .P .堆积的 ;在 5 32 0～ 3 6 0 0aB .P .,气候仍较为湿润温暖 ;在 36 0 0～346 0aB .P .和 3 430～ 3 40 0aB .P .,有两次明显的干 冷干事件。气候的这种波动 ,可能是中全新世湿润状况的结束过程。     

撒哈拉沙漠东北部全新世气候环境与人类活动

现代极端干旱的撒哈拉沙漠东北部,在12000 aB.P.前出现了代表湿润气候记录的湖相沉积;全新世以来,在9900~2400 aB.P.形成了大面积的连续湖泊,并在9800~6450 aB.P.达到鼎盛时期。在6000 aB.P.~3600 aB.P.前,湖泊演化进入波动期,反映了该时期气候环境周期性的变动并具600年的准周期。撒哈拉沙漠东北全新世湿润时期,是该区古人类发展与进步、繁演与分化的时期;也是自然演变史上一个十分重要的时期,其中强烈的风化作用和碎屑物质积累为今日撒哈拉沙漠的形成奠定了物质基础。     

黄旗海岩芯烧失量分析与冰后期环境演变

重建闭流型湖泊的水位及环境变化,可以为研究冰后期及全新世以来的气候变化及季风环流演变提供不可或缺的关键信息。对HQH4岩芯烧失量与川蔓藻化石种子的研究结果显示,黄旗海湖区在全新世到来之前的气候寒冷,湖面冰封期较长,夏季温度较低,致使湖泊的有机生产率和自生碳酸盐产量比全新世低很多。黄旗海从全新世早期起进入了稳定的湖泊发展阶段后有机生产率显著上升,自生碳酸盐产量同步大幅度增长。在10 200~6 800 a BP期间,烧失量出现显著波动,很大程度上反映了气候发生暖湿-冷干-暖湿-冷湿的变化。在6 800~3 800 a BP期间,烧失量较高而且波动较小,反映了中全新世黄旗海以稳定的温暖湿润气候为主,湖水水位变化不大,有机质和碳酸盐生产力较高。从3 800 a BP起,气候逐渐变凉,间有多次冷暖干湿的剧烈变化,水位波动频繁。     

黄旗海沉积岩芯烧失量变化曲线:冰后期环境演变的有效代用指标

重建黄旗海水位、水化学和湖泊生物学变化历史可为研究我国夏季风边缘区冰后期气候变化提供重要环境记录。对该湖中央HQH4岩芯研究结果显示,末次冰期晚期沉积物中湖泊自生有机质烧失量和自生碳酸盐烧失量的平均值分别仅为全新世沉积物的1/13和1/5,造成这种结果的主导因素是夏季气温在全新世初显著升高和黄旗海从此进入稳定的湖泊环境。晚全新世自生碳酸盐烧失量平均值比早、中全新世低14%,其最大值也明显低于早、中全新世,这种情况很可能是因为晚全新世夏季温度略低于早、中全新世所致。自生有机质和碳酸盐烧失量是快速、经济地获取闭流型半咸水湖泊冰后期环境变化的有效代用指标。     

青藏高原兹格塘错沉积物介形虫壳体同位素

兹格塘错是位于藏北高原腹地的封闭型湖泊,其变化过程可直接反映区域气候变化。对一支深727 cm沉积岩芯中介形虫进行了壳体同位素分析,发现介形虫壳体氧同位素变化主要取决于壳体形成时的湖水氧同位素组成和湖水温度的变化;封闭湖泊湖水的氧同位素组成主要取决于降水和蒸发比值的变化。兹格塘错介形虫壳体碳、氧同位素变化特征表明两者可能受控于不同的环境因子。介形虫壳体同位素记录反映了全新世气候环境变化的整体特征,同时对晚第四纪特征气候事件都有明确记录,包括8.2 ka冷事件、Roman暖期、中世纪暖期以及小冰期等,在响应全球气候变化的过程中又记录了区域间的差异响应。     

黄土高原东缘晚全新世高精度高分辨率石笋古环境记录

基于山西武乡太行龙洞一支石笋5个230Th年龄和190个氧同位素数据重建4 400~150 a B.P.高分辨率δ18O序列。石笋δ18O值逐渐增加,除最近约600 a外,在千年尺度长期趋势变化上与中国南部其它洞穴记录相一致,表明晚全新世亚洲夏季风强度持续减弱响应于同一驱动机制。一次显著的气候突变事件发生在2 550~2 000 aB.P.,与史料记载的干旱期大致相对应。功率谱分析揭示出106 a周期,与树轮Δ14C太阳活动周期大体一致,说明百年尺度上太阳活动与东亚季风变化有一定关联性。     

青海湖碳酸盐氧同位素环境记录再认识

青海湖是我国内陆最大的闭流型水体,地处东亚季风和西风的交汇影响区,对区域降水的改变等气候变化反应敏感,其水位变化历史是研究区域季风环境演变极其宝贵和重要的环境档案。青海湖Q14B孔岩芯介壳δ18Oc变化曲线自1991年发表以来,受到国内外同行的广泛关注和继续探讨。依据近年来青海湖气候与环境演变研究的最新研究结果和个人对闭流型湖泊同位素地球化学的认识,对介壳δ18Oc变化曲线进行了重新判读并得出以下结论:14.5~10.5 ka B.P.,青海湖区气候已逐渐从干冷向温湿过渡,季风降水逐渐增加;10.8~10.5 ka B.P.,青海湖处于碳酸盐滩湖环境,湖水深度从几米演变到接近干涸;10.5~9.5 kaB.P.,季风降水增加;9.5~8 ka B.P,湖水位从此前的接近干涸演变到此间的2~8 m,δ18Oc值跌落到一个较低的位置;8~3.5ka B.P,气候条件相对稳定,湖水不断蒸发引起重同位素的富集;3.5~0ka B.P,湖水处于同位素稳定阶段。研究结果还显示,δ18Oc值的短期波动与湖泊水位短期变化关系密切且明显,即水位高低分别对应δ18Oc的低值与高值。δ18Oc值的长期变化与湖泊水位长期变化关系不明显,水位较浅时,二者几乎无关联;水位较深时,水位的长期缓慢下降自然会导致δ18Oc逐渐攀升,而水位的长期缓慢上升也可以伴随δ18Oc逐渐攀升。     

Ostracode stratigraphy and paleoecology from surficial sediments of Lake Tanganyika, Africa

We report here on the first detailed ostracode stratigraphic record to be obtained from late Holocene sediments of Lake Tanganyika. We analyzed four cores, three from the northern lake region and a fourth from a more southern lake locality, that collectively record ostracode assemblages under a variety of disturbance regimes. These cores provide a stratigraphic record of ostracode abundance and diversity, as well as depositional changes over time periods of decades to millennia. We have investigated the fossil ostracodes in these cores by looking at temporal changes of species diversity and population structure for the species present. All four cores provided distinct patterns of ostracode diversity and abundance. BUR-1, a northern lake core obtained close to the Ruisizi River delta, yielded a sparse ostracode record. Karonge #3, another northern core from a site that is closely adjacent to a river delta with high sediment loading, yielded almost no ostracodes. The third core 86-DG-14, taken from a somewhat less disturbed area of the lake, suggests that there have been recent changes in ostracode populations. Through most of the lower portion of this core, ostracode abundance is low and species richness is relatively constant. Above 7 cm there is a marked increase in ostracode abundance and a corresponding decrease in species richness, probably signaling the onset of a major community disturbance, perhaps due to human activities. The southernmost core, 86-DG-32, is from a site that is well removed from influent rivers. Ostracode abundance varies erratically throughout the core, whereas species richness is relatively constant and high throughout the core. The temporal variation evident in ostracode community makeup both within and between the studied cores may be a result of naturally patchy distributions among ostracodes, coupled with local extinctions and recolonizations, or it may reflect inadequate sampling of these high diversity assemblages. In either case, these cores illustrate the potential to obtain high resolution ostracode records from the rich, endemic fauna of Lake Tanganyika that can be used to address questions about the history of community structure and human impacts in this lake.     

Oxygen isotopic composition and its application to the study of tracing oceanographical process in Bering Sea and Chukchi Sea

In this paper, the 18 O distribution of surface water from the central sea areas of the Bering Sea and the Chukchi Sea was studied. The δ 18 O value of surface water from the Bering Sea is averagely -0.5‰; the δ 18 O contents of the Chukchi Sea are distributionally lower in northeast and higher in southwest; the δ 18 O value at the margin of Canadian Basin is -2.8‰, and averagely -0.8‰ in the southern area of the Chukchi Sea. The δ 18 O vertical distribution in some deep water stations from the Chukchi Sea and the Bering Sea is also studied. In the southern margin of Canadian Basin, the δ 18 O value is -2‰ -3‰ for surface layer and rises to 0 at 100 m depth layer. In the Bering Sea, the δ 18 O is about -0.5‰ for surface layer and increases to 0 at the depth of 300 m. The NO tracer can reflect obviously three water masses vertically distributed in the central Bering Sea: the upper Bering water mass, the middle Bering water mass and the deep Pacific water mass. The distributive ranges of NO and temperature for the various water masses are T<7℃, NO>780 μmol/dm 3 and T≥7℃, NO>650 μmol/dm 3 for upper Bering water mass, T<4℃, 550相似文献   

Holocene paleoclimatic evidence and sedimentation rates from a core in southwestern Lake Michigan

Preliminary results of a multidisciplinary study of cores in southwestern Lake Michigan suggest that the materials in these cores can be interpreted in terms of both isostatically and climatically induced changes in lake level. Ostracodes and mollusks are well preserved in the Holocene sediments, and they provide paleolimnologic and paleoclimatic data, as well as biogenic carbonate for stable-isotope studies and radiocarbon dating. Pollen and diatom preservation in the cores is poor, which prevents comparison with regional vegetation records. New accelerator-mass spectrometer ¹⁴C ages, from both carbon and carbonate fractions, provide basin-wide correlations and appear to resolve the longstanding problem of anomalously old ages that result from detrital organic matter in Great Lakes sediments.Several cores contain a distinct unconformity associated with the abrupt fall in lake level that occurred about 10.3 ka when the isostatically depressed North Bay outlet was uncovered by the retreating Laurentide Ice Sheet. Below the unconformity, ostracode assemblages imply deep, cold water with very low total dissolved solids (TDS), and bivalves have ¹⁸O (PDB) values as light as — 10 per mil. Samples from just above the unconformity contain littoral to sublittoral ostracode species that imply warmer, higher-TDS (though still dilute) water than that inferred below the unconformity. Above this zone, another interval with ¹⁸O values more negative than — 10 occurs. The isotopic data suggest that two influxes of cold, isotopically light meltwater from Laurentide ice entered the lake, one shortly before 10.3 ka and the other about 9 ka. These influxes were separated by a period during which the lake was warmer, shallower, but still very low in dissolved solids. One or both of the meltwater influxes may be related to discharge from Lake Agassiz into the Great Lakes.Sedimentation rates appear to have been constant from about 10 ka to 5 ka. Bivalve shells formed between about 8 and 5 ka have ¹⁸O values that range from-2.3 to-3.3 per mil and appear to decrease toward the end of the interval. The ostracode assemblages and the stable isotopes suggest changes that are climatically controlled, including fluctuating water levels and increasing dissolved solids, although the water remained relatively dilute (TDS < 300 mg/l).A dramatic decrease in sedimentation rates occurred at about 5 ka, about the time of the peak of the Nippissing high lake stage. This decrease in sedimentation rate may be associated with a large increase in effective wave base as the lake approached its present size and fetch. A dramatic reduction in ostracode and mollusk abundances during the late Holocene is probably due to this decrease in sedimentation rates, which would result in increased carbonate dissolution. Ostracode productivity may also have declined due to a reduction in bottom-water oxygen caused by increased epilimnion algal productivity.Woods Hole Oceanographic Institute Contribution No. 7492     

Ostracode δ18O and δ13C evidence of Holocene environmental changes in the sediments of two Minnesota lakes

Stable oxygen and carbon isotope geochemistry of ostracode valves, abundance and assemblages of ostracode species, and sedimentological parameters from cores taken in Williams and Shingobee Lakes in north-central Minnesota show changes in climatic and hydrologic history during the Holocene. Isotopic records are consistent with the following scenario:Before 9800 yr B.P. the two lakes were connected. Increasing evaporation through the jack/red pine period (9800-7700 yr B.P.) led to lower lake levels, leaving small separated basins. The prairie period (7700-4000 yr B.P.) reflects high aridity, and lake levels reached low stands shortly before 6500 yr B.P. Low lake levels are associated with groundwater discharge between 6500 and 6000 yr B.P. The hardwood period (4000-3200 yr B.P.) corresponds to long cold winters and warm to cool summers with lower evaporation rates and slower sedimentation. During the white pine period (<3200 yr B.P.) evaporation increased and/or precipitation shifted to the summer months.These changes can be related to shifting atmospheric circulation patterns. Zonal flow was probably dominant during the early Holocene until the end of the prairie period (c. 4000 yr B.P.). During the hardwood period a combination of zonal and meridional flow patterns caused long and cold winters and wetter summers. During the white pine period wintners were shorter and the meridional flow pattern more significant. Today meridional flow dominates the circulation pattern.This is the 6th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.     

Recent anthropogenic impact in ancient Lake Ohrid (Macedonia/Albania): a palaeolimnological approach

Ancient lakes, which are important centres of biodiversity and endemism, are threatened by a wide variety of human impacts. To assess environmental impact on ancient Lake Ohrid we have taken short sediment cores from two contrasting site locations, comprising a site of urban pollution and an apparently pristine area. Recent impacts on water quality and ecology were assessed using sediment, geochemical, ostracode, and diatom data derived from analysis of two ²¹⁰Pb-dated sediment cores spanning the period from 1918 to 2009. According to the index of geoaccumulation, sediments were often moderately contaminated with As. Fe and Ni concentrations often exceeded reported maximum limits above which harmful effects on sediment-dwelling organisms are expected. Productivity in the (pristine) south-eastern part of Lake Ohrid (Sveti Naum) is generally lower than in the north, probably due to the strong influence of spring discharge. Low ostracode and diatom concentrations, low abundance of the epilimnetic diatom Cyclotella ocellata, and low values of TOC and TIC indicate a lower productivity from the early 1920s to the late 1980s. Since the mid 1970s, increased relative abundance of C. ocellata and increasing diatom concentration indicate increasing productivity in the south-eastern part. Rising numbers of ostracode valves and higher TIC and TOC contents in both sediment cores indicate an increase in productivity during the late 1980s. A slight increase in productivity near Sveti Naum continued from the early 1990s until 2009, witnessed by rising TC, TIC, and TOC content and a generally high number of ostracode valves and ostracode diversity. The area near the City of Struga (site of urban pollution) is also characterized by rising TOC and TIC contents and, furthermore, by increasing Cu, Fe, Pb, and Zn concentrations since the early 1990s. The recent reduction in the number of ostracode valves and ostracode diversity is probably caused by a higher heavy metal load into the lake. This suggests that living conditions for the endemic species in Lake Ohrid have become less favourable in the northern part of the lake, which might threaten the unique flora and fauna of Lake Ohrid.     

极地冰雪氢氧同位素指标及其指示意义

本文综述了水汽来源状况、降水季节变化、火山喷发、太阳活动等气候环境因素对极地冰雪中同位素含量的可能影响及其程度 ,以及降水区域不均衡性、降水年际不均衡性、逆温层和同位素在冰雪中的扩散迁移作用等几种不稳定因素可能对冰雪同位素分析造成的干扰 ;在此基础上 ,综述了极地冰雪中δ1 8O、δD和其差值d(d =δD - 8δ1 8O)与局部或全球气温之间的一些线性关系 (包括全球尺度 ,格陵兰地区 ,南极地区等 )及它们在空间分布上的变化规律     

Holocene climate reconstructions from tandem trace-element and stable-isotope composition of ostracodes from Coldwater Lake, North Dakota, U.S.A.

The geochemistry of ostracode shells and bulk carbonates in a 19-meter sediment core documents at century-scale resolution the evolution of water chemistry in Coldwater Lake, North Dakota, providing a continuous paleohydrologic record of Holocene climate change in the northern Great Plains. A combination of ¹⁸O, ¹³C, Mg/Ca and Sr/Ca in ostracode calcite aided by Sr/Ca in bulk carbonates are used to constrain the paleoclimatic reconstructions. A fresh-water phase in the early Holocene, indicated by the absence of Candona rawsoni and low concentrations of Sr/Ca in bulk carbonate, was followed by a sharp increase in salinity between 10800 and 8900 yr B.P. The climate was predominately dry during the late part of the early Holocene and most of the middle Holocene (8900–5000 yr B.P.), when the lake was very sensitive and recorded a series of dry and wet oscillations. Maximum salinity occurred around 5500 yr B.P. and was followed by a gradual decrease between 5000 and 2400 yr B.P. From 2400 yr B.P. the ¹⁸O, Mg/Ca, and Sr/Ca in the ostracodes indicate generally wet conditions interrupted by a series of lesser salinity and temperature oscillations lasting until 600 yr B.P. Ostracode geochemistry indicates that a warm and dry climate returned at about the time of the Little Ice Age (600–150 yr B.P.). Ostracode ¹³C shows a ong-term increasing trend during the Holocene, which suggests that lake productivity and atmospheric CO₂ exchange made greater contributions to the hypolimnetic carbon pool as the lake became shallower with time.     

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: VII. Carbonate isotope geochemistry as a record of riverine runoff

Evaporation dominates the removal of water from Lake Tanganyika, and therefore the oxygen isotope composition of lake water has become very positive in comparison to the waters entering the lake. The surface water in Lake Tanganyika has remained relatively unchanged over the last 30 years with a seasonal range of +3.2 to +3.5 VSMOW. Water from small rivers entering the lake seems to have a ¹⁸O value between –3.5 and –4.0, based on scattered measurements. The two largest catchments emptying into the lake deliver water that has a ¹⁸O value between these two extremes. This large contrast is the basis of a model presented here that attempts to reconstruct the history of runoff intensity based on the ¹⁸O of carbonate shells from Lake Tanganyika cores. In order to use biogenic carbonates to monitor changes in the ¹⁸O of mixing-zone water, however, the oxygen isotope fractionation between water and shell carbonate must be well understood. The relatively invariant environmental conditions of the lake allow us to constrain the fractionation of both oxygen and carbon isotope ratios. Although molluskan aragonitic shell ¹⁸O values are in agreement with published mineral-water fractionations, ostracode calcite is 1.2 more positive than that of inorganic calcite precipitated under similar conditions. Ostracode shell ¹⁸O data from two cores from central Lake Tanganyika suggest that runoff decreased in the first half of this millennium and has increased in the last century. This conclusion is poorly constrained, however, and much more work needs to be done on stable isotope variation in both the waters and carbonates of Lake Tanganyika. We also compared the ¹³C of shells against predicted values based solely on the ¹³C of lake water dissolved inorganic carbon (DIC). The ostracode Mecynocypria opaca is the only ostracode or mollusk that falls within the predicted range. This suggests that M. opaca has potential for reconstructing the carbon isotope ratio of DIC in Lake Tanganyika, and may be a useful tool in the study of the history of the lakes productivity and carbon cycle.     

A 6000 year water level history of Europe Lake, Wisconsin, USA

Europe Lake occupies a small, closed, basin that would have been an embayment in Lake Michigan during the high water level events in the larger lake. Cores recovered from the lake reveal late Holocene water level fluctuations in the basin that are inferred from changes in taxa and abundance of molluscs, ostracodes, magnetic susceptibility, organic carbon, and oxygen isotopes.Non-glacial, Holocene lacustrine/paludal sedimentation in this portion of the Europe Lake basin started after 6600 RCYBP and was probably initiated by a rise in the water table of the deep bedrock aquifer, during the Nipissing transgression in Lake Michigan. Isotopically light ground water from this source was probably a major contributor during this phase to the negative ¹⁸O spikes in Valvata tricarinata and Amnicola limosa.The start of stable lacustrine conditions is marked by maximum diversity of ostracode and mollusc taxa and a shift toward much more positive ¹⁸O values. The Europe Lake basin at this time became an embayment of Lake Michigan. This event was probably coeval with the peak of the Nipissing transgression, when the water plane reached an altitude of about 183 m.The isolation of Europe Lake from Lake Michigan started at about 2390 RCYBP and is probably due to a drop in water level in Lake Michigan and/or to isostatic uplift of the Door Peninsula. Since isolation from Lake Michigan, water levels in Europe lake have been controlled primarily by fluctuations in local precipitation, evaporation and ground water discharge.