Decoding polyphase migmatites using geochronology and phase equilibria modelling

In this study, in situ U–Pb monazite ages and Lu–Hf garnet geochronology are used to distinguish mineral parageneses developed during Devonian–Carboniferous and Cretaceous events in migmatitic paragneiss and orthogneiss from the Fosdick migmatite–granite complex in West Antarctica. SHRIMP U–Pb monazite ages define two dominant populations at 365–300 Ma (from cores of polychronic grains, dominantly from deeper structural levels in the central and western sectors of the complex) and 120–96 Ma (from rims of polychronic grains, dominantly from the central and western sectors of the complex, and from monochronic grains, mostly from shallower structural levels in the eastern sector of the complex). For five paragneisses and two orthogneisses, Lu–Hf garnet ages range from 116 to 111 Ma, c. 12–17 Ma older than published Sm–Nd garnet ages of 102–99 Ma from three of the same samples. Garnet grains in the analysed samples generally have Lu‐enriched rims relative to Lu‐depleted cores. By contrast, for three of the same samples, individual garnet grains have flat Sm concentrations consistent with high‐T diffusive resetting. Lutetium enrichment of garnet rims is interpreted to record the breakdown of a Lu‐rich accessory mineral during the final stage of garnet growth immediately prior to the metamorphic peak, and/or the preferential retention of Lu in garnet during breakdown to cordierite in the presence of melt concomitant with the initial stages of exhumation. Therefore, garnet is interpreted to be part of the Cretaceous mineral paragenesis and the Lu–Hf garnet ages are interpreted to record the timing of close‐to‐peak metamorphism for this event. For the Devonian–Carboniferous event, phase equilibria modelling of the metasedimentary protoliths to the paragneiss and a diatexite migmatite restrict the peak P–T conditions to 720–800 °C at 0.45–1.0 GPa. For the Cretaceous event, using both forward and inverse phase equilibria modelling of residual paragneiss and orthogneiss compositions, the P–T conditions after decompression are estimated to have been 850–880 °C at 0.65–0.80 GPa. These P–T conditions occurred between c. 106 and c. 96 Ma, determined from Y‐enriched rims on monazite that record the timing of garnet and biotite breakdown to cordierite in the presence of melt. The effects of this younger metamorphic event are dominant throughout the Fosdick complex.     

Geochronology in migmatites a SmNd, UPb and RbSr study from the Proterozoic Damara belt (Namibia): implications for polyphase development of migmatites in high-grade terranes

Sm–Nd (garnet), U–Pb (monazite) and Rb–Sr (biotite) ages from a composite migmatite sample (Damara orogen, Namibia) constrain the time of high‐grade regional metamorphism and the duration of regional metamorphic events. Sm–Nd garnet whole‐rock ages for a strongly restitic melanosome and an adjacent intrusive leucosome yield ages of 534±5, 528±11 and 539±8 Ma. These results provide substantial evidence for pre‐500 Ma Pan‐African regional metamorphism and melting for this segment of the orogen. Other parts of the migmatite yield younger Sm–Nd ages of 488±9 Ma for melanosome and 496±10, 492±5 and 511±16 Ma for the corresponding leucosomes. Garnet from one xenolith from the leucosomes yields an age of 497±2 Ma. Major element compostions of garnet are different in terms of absolute abundances of pyrope and spessartine components, but the flat shape of the elemental patterns suggests late‐stage retrograde equilibration. Rare earth element compositions of the garnet from the different layers are similar except for garnet from the intrusive leucosome suggesting that they grew in different environments. Monazite from the leucosomes is reversely discordant and records ²⁰⁷Pb/²³⁵U ages between 536 and 529 Ma, indicating that this monazite represents incorporated residual material from the first melting event. Monazite from the mesosome MES 2 and the melanosome MEL 3 gives ²⁰⁷Pb/²³⁵U ages of 523 and 526 Ma, and 529 and 531 Ma, respectively, which probably indicates another thermal event. Previously published ²⁰⁷Pb/²³⁵U monazite data give ages between 525 and 521 Ma for composite migmatites, and 521 and 518 Ma for monazite from neosomes. Monazite from granitic to granodioritic veins indicates another thermal event at 507–505 Ma. These ages are also recorded in ²⁰⁷Pb/²³⁵U monazite data of 508 Ma from the metasediment MET 1 from the migmatite and also in the Sm–Nd garnet ages obtained in this study. Taken together, these ages indicate that high‐grade metamorphism started at c. 535 Ma (or earlier) and was followed by thermal events at c. 520 Ma and c. 505 Ma. The latter event is probably connected with the intrusion of a large igneous body (Donkerhoek granite) for which so far only imprecise Rb–Sr whole‐rock data of 520±15 Ma are available. Rb–Sr biotite ages from the different layers of the migmatite are 488, 469 and 473 Ma. These different ages indicate late‐stage disturbance of the Rb–Sr isotopic system on the sub‐sample scale. Nevertheless, these ages are close to the youngest Sm–Nd garnet ages, indicating rapid cooling rates between 13 and 20°C Ma^?1 and fast uplift of this segment of the crust. Similar Sm–Nd garnet and U–Pb monazite ages suggest that the closure temperatures for both isotopic systems are not very different in this case and are probably similar or higher than the previously estimated peak metamorphic temperatures of 730±30°C. The preservation of restitic monazite in leucosomes indicates that dissolution of monazite in felsic water‐undersaturated peraluminous melts can be sluggish. This study shows that geochronological data from migmatites can record polymetamorphic episodes in high‐grade terranes that often contain cryptic evidence for the nature and timing of early metamorphic events.     

In situ monazite (U–Th)–Pb ages from the Southern Brasília Belt,Brazil: constraints on the high‐temperature retrograde evolution of HP granulites

In the southern sector of the Southern Brasília Belt, late Neoproterozoic arc–passive margin collision resulted in juxtaposition of an arc‐derived nappe (the Socorro–Guaxupé Nappe) over a stack of passive margin‐derived nappes (the Andrelândia Nappe Complex) that lies on top of autochthonous basement of the São Francisco Craton. (U–Th)–Pb monazite ages are reported from the high‐grade nappes of the Andrelândia Nappe Complex to better constrain the high‐temperature retrograde evolution. For residual HP granulites from the uppermost Três Pontas–Varginha Nappe, (U–Th)–Pb ages of c. 662 and 655 Ma from low yttrium monazite inclusions in the rims of, or associated with garnet are interpreted to date the late‐stage close‐to‐peak prograde evolution, whereas an age of c. 648 Ma from a similar low yttrium monazite inclusion is interpreted to record post‐peak recrystallization with melt via factures in garnet. For the same nappe, ages of 640–631 Ma retrieved from higher yttrium areas or cores in monazite grains that occur both as inclusions in garnet and in the matrix are interpreted to record growth of monazite either by local breakdown of garnet (±older monazite) and mass exchange with a matrix melt reservoir along cracks or growth from residual melt in the matrix as it crystallized during high‐pressure, close‐to‐isobaric cooling close to the solidus, the temperature of which, at a given pressure, varies with bulk composition of the residual granulites. (U–Th)–Pb ages in the range 620–588 Ma from lower yttrium areas in these monazite grains and from matrix‐hosted patchy monazite are interpreted to date exhumation, as recorded by close‐to‐isothermal decompression and subsequent close‐to‐isobaric cooling. Older monazite ages in this group are interpreted to record late‐stage interaction with melt close to the solidus whereas younger monazite ages are interpreted to record recrystallization of monazite by dissolution–reprecipitation owing to ingress of alkali fluid from the Carmo da Cachoeira Nappe beneath as fluid was released by crystallization of in‐source melt at the solidus. In the underlying Carmo da Cachoeira Nappe, higher yttrium areas in monazite and one single domain monazite yield chemical ages of 619–616 Ma, which are interpreted to date growth as in‐source melt crystallized close to the solidus along the high‐pressure, close‐to‐isobaric segment of the retrograde P–T evolution. Younger (U–Th)–Pb ages of 600–595 Ma retrieved from lower yttrium areas and one single domain monazite are interpreted to record recrystallization of monazite by dissolution–reprecipitation owing to release of fluid at the solidus during exhumation of this nappe. Monazite from the Carvalhos Klippe, interpreted to be correlative with the uppermost nappe, yields a wide range of (U–Th)–Pb ages: for two zoned grains, c. 619 and c. 614 Ma from higher yttrium cores, and c. 583 and c. 595 Ma from lower yttrium rims; and, 592–580 Ma from single domain grains in one sample, and ages of c. 593 and c. 563 Ma from monazite in a second sample. Ages younger than 605 Ma are interpreted to date a fluid‐induced response to the early stages of orogenic loading associated with terrane accretion in the Ribeira Belt to the southeast. The results reported here demonstrate that ages retrieved from monazite that grew close to the solidus in residual granulites from a single tectonic unit will vary from sample to sample according to differences in the solidus temperatures. Further, we show that monazite inclusions may yield ages that are younger than the host mineral and confirm the propensity of monazite to record evidence of tectonic events that are not always registered by other high‐temperature mineral chronometers.     

Crustal response to continental collisions between the Tibet, Indian, South China and North China Blocks: geochronological constraints from the Songpan-Garzê Orogenic Belt, western China

We report SHRIMP U–Th–Pb monazite, conventional U–Pb titanite, Sm–Nd garnet and Rb–Sr muscovite and biotite ages for metamorphic rocks from the Danba Domal Metamorphic Terrane in the eastern Songpan‐Garzê Orogenic Belt (eastern Tibet Plateau). These ages are used to determine the timing of polyphase metamorphic events and the subsequent cooling history. The oldest U–Th–Pb monazite and Sm–Nd garnet ages constrain an early Barrovian metamorphism (M1) in the interval c. 204–190 Ma, coincident with extensive Indosinian granitic magmatism throughout the Songpan‐Garzê Orogenic Belt. A second, higher‐grade sillimanite‐grade metamorphic event (M2), recorded only in the northern part of the Danba terrane, was dated at c. 168–158 Ma by a combination of U–Th–Pb monazite and titanite and Sm–Nd garnet ages. It is suggested that M1 was a thermal event that affected the entire orogenic belt while M2 may represent a local thermal perturbation. Rb–Sr muscovite ages range from c. 138–100 Ma, whereas Rb–Sr biotite ages cluster at c. 34–24 Ma. These ages document regional cooling at rates of c. 2–3 °C Myr^?1 following the M1 peak for most of the terrane. However, those parts of the terrane affected by the higher‐temperature M2 event (e.g. the migmatite zone) experienced initially more rapid (c. 8 °C Myr^?1) cooling after peak M2 before joining the regional slow cooling path defined by the rest of the terrane at c. 138 Ma. Regional slow cooling between c. 138 and c. 30 Ma is thought to be the result of post‐tectonic isostatic uplift after extensive crustal thickening caused by collision of the South and North China Blocks. The clustering of biotite Rb–Sr ages marks the onset of rapid uplift across the entire terrane commencing at c. 30–20 Ma. This cooling history is shared with many other regions of the Tibet Plateau, suggesting that uplift of the Tibet Plateau (including the Songpan‐Garzê Orogenic Belt) occurred predominantly in the last c. 30 Myr as a response to the continuing northwards collision of India with Eurasia.     

Monazite as a monitor of melting,garnet growth and feldspar recrystallization in continental lower crust

Monazite is a common accessory phase in felsic granulite ribbon mylonites exposed in the Upper Deck domain of the Athabasca granulite terrane, western Canadian Shield. Field relationships, bulk rock geochemistry and phase equilibria modelling in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ system are consistent with the garnet‐rich rocks representing the residual products of ultrahigh temperature melting of biotite‐bearing paragneisses driven by intraplating of mafic magma in continental lower crust. The c. 2.64–2.61 Ga Y‐rich resorbed monazite cores included in garnet are interpreted as relicts of detrital grains deposited on the Earth's surface after c. 2.61 Ga. Yttrium‐poor monazite domains in garnet are depleted in Sm and Gd and linked to fluid‐absent melting of biotite + plagioclase + quartz ± sillimanite during a prograde loading path from ≤0.8 to ≥1.4 GPa. The c. 2.61–2.55 Ga Y‐depleted, Th‐rich monazite domains crystallized in the presence of garnet + ternary feldspar ± orthopyroxene + peraluminous melt. The c. 2.58–2.52 Ga monazite rims depleted in Th + Ca and enriched in Eu are linked to localized melt extraction synchronous with growth of high‐pressure (HP) grossular‐rich garnet at the expense of plagioclase during crustal thickening, culminating at >950 °C. Re‐heating and dextral transpressive lower crustal reactivation at c. 1.9 Ga resulted in syn‐kinematic growth of (La + Ce)‐enriched monazite and a second generation of garnet, concurrent with recrystallization of feldspar and orthopyroxene at 1.0–1.2 GPa and 600–700 °C. Monazite grains in this study are marked by positive Eu‐anomalies relative to chondrite. A direct link is implied between Y, Sm, Eu and Gd in monazite and two major phases in continental lower crust: garnet and plagioclase. Positive Eu‐anomalies in lower crustal monazite associated with modally abundant garnet appear to be directly related to Eu‐enrichment and depletions of Y, Sm and Gd that are consequences of garnet growth and plagioclase breakdown during HP melting of peraluminous bulk compositions.     

Constraints on the timing and conditions of high‐grade metamorphism,charnockite formation and fluid–rock interaction in the Trivandrum Block,southern India

Incipient charnockites have been widely used as evidence for the infiltration of CO₂‐rich fluids driving dehydration of the lower crust. Rocks exposed at Kakkod quarry in the Trivandrum Block of southern India allow for a thorough investigation of the metamorphic evolution by preserving not only orthopyroxene‐bearing charnockite patches in a host garnet–biotite felsic gneiss, but also layers of garnet–sillimanite metapelite gneiss. Thermodynamic phase equilibria modelling of all three bulk compositions indicates consistent peak‐metamorphic conditions of 830–925 °C and 6–9 kbar with retrograde evolution involving suprasolidus decompression at high temperature. These models suggest that orthopyroxene was most likely stabilized close to the metamorphic peak as a result of small compositional heterogeneities in the host garnet–biotite gneiss. There is insufficient evidence to determine whether the heterogeneities were inherited from the protolith or introduced during syn‐metamorphic fluid flow. U–Pb geochronology of monazite and zircon from all three rock types constrains the peak of metamorphism and orthopyroxene growth to have occurred between the onset of high‐grade metamorphism at c. 590 Ma and the onset of melt crystallization at c. 540 Ma. The majority of metamorphic zircon growth occurred during protracted melt crystallization between c. 540 and 510 Ma. Melt crystallization was followed by the influx of aqueous, alkali‐rich fluids likely derived from melts crystallizing at depth. This late fluid flow led to retrogression of orthopyroxene, the observed outcrop pattern and to the textural and isotopic modification of monazite grains at c. 525–490 Ma.     

A window into the Early to mid‐Cretaceous infrastructure of the Yukon‐Tanana terrane recorded in multi‐stage garnet of west‐central Yukon,Canada

Amphibolite facies metasedimentary schists within the Yukon‐Tanana terrane in the northern Canadian Cordillera reveal a two‐stage, polymetamorphic garnet growth history. In situ U‐Th‐Pb Sensitive High Resolution Ion Microprobe dating of monazite provide timing constraints for the late stages of garnet growth, deformation and subsequent decompression. Distinct textural and chemical growth zoning domains, separated by a large chemical discontinuity, reveal two stages of garnet growth characterized in part by: (i) a syn‐kinematic, inclusion‐rich stage‐1 garnet core; and (ii) an inclusion‐poor, stage‐2 garnet rim that crystallized with syn‐ to post‐kinematic staurolite and kyanite. Phase equilibria modelling of garnet molar and compositional isopleths suggest stage‐1 garnet growth initiated at ~600 °C, 8 kbar along a clockwise P–T path. Growth of the compositionally distinct, grossular‐rich, pyrope‐poor inner portion of the stage‐2 overgrowth is interpreted to have initiated at higher pressure and/or lower temperature than the stage‐1 core along a separate P–T loop, culminating at peak P–T conditions of ~650–680 °C and 9 kbar. Stage‐2 metamorphism and the waning development of a composite transposition foliation (S_T) are dated at c. 118 Ma from monazite aligned parallel to S_T, and inclusions in syn‐ to post‐S_T staurolite and kyanite. Slightly younger ages (c. 112 Ma) are obtained from Y‐rich monazite that occurs within resorbed areas of both stage‐1 and stage‐2 garnet, together with retrograde staurolite and plagioclase. The younger ages obtained from these texturally and chemically distinct grains are interpreted, with the aid of phase equilibria calculations, to date the growth of monazite from the breakdown of garnet during decompression at c. 112 Ma. Evidence for continued near‐isothermal decompression is provided by the presence of retrograde sillimanite, and cordierite after staurolite, which indicates decompression below ~4–5 kbar prior to cooling below ~550 °C. As most other parts of the Yukon‐Tanana terrane were exhumed to upper crustal levels in the Early Jurassic, these data suggest this domain represents a tectonic window revealing a much younger, high‐grade tectono‐metamorphic core (infrastructure) within the northern Cordilleran orogen. This window may be akin to extensional core complexes identified in east‐central Alaska and in the southeastern Canadian Cordillera.     

The timing of migmatization in the northern Arabian–Nubian Shield: Evidence for a juvenile sedimentary component in collision‐related batholiths

Collision‐related granitoid batholiths, like those of the Hercynian and Himalayan orogens, are mostly fed by magma derived from metasedimentary sources. However, in the late Neoproterozoic calcalkaline (CA) batholiths of the Arabian–Nubian Shield (ANS), which constitutes the northern half of the East African orogen, any sedimentary contribution is obscured by the juvenile character of the crust and the scarcity of migmatites. Here, we use paired in situ LASS‐ICP‐MS measurements of U–Th–Pb isotope ratios and REE contents of monazite and xenotime and SHRIMP‐RG analyses of separated zircon to demonstrate direct linkage between migmatites and granites in the northernmost ANS. Our results indicate a single prolonged period of monazite growth at 640–600 Ma, in metapelites, migmatites and peraluminous granites of three metamorphic suites: Abu‐Barqa (SW Jordan), Roded (S Israel) and Taba–Nuweiba (Sinai, Egypt). The distribution of monazite dates and age zoning in single monazite grains in migmatites suggest that peak thermal conditions, involving partial melting, prevailed for c. 10 Ma, from 620 to 610 Ma. REE abundances in monazite are well correlated with age, recording garnet growth and garnet breakdown in association with the prograde and retrograde stages of the melting reactions, respectively. Xenotime dates cluster at 600–580 Ma, recording retrogression to greenschist facies conditions as garnet continued to destabilize. Phase equilibrium modelling and mineral thermobarometry yield P–T conditions of ~650–680°C and 5–7 kbar, consistent with either water‐fluxed or muscovite‐breakdown melting. The expected melt production is 8–10 vol.%, allowing a melt connectivity network to form leading to melt segregation and extraction. U–Pb ages of zircon rims from leucosomes indicate crystallization of melt at 610 ± 10 Ma, coinciding with the emplacement of a vast volume of CA granites throughout the northern ANS, which were previously considered post‐collisional. Similar monazite ages (c. 620 Ma) retrieved from the amphibolite facies Elat schist indicate that migmatites are the result of widespread regional rather than local contact metamorphism, representing the climax of the East African orogenesis.     

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.     

High to ultrahigh temperature contact metamorphism and dry partial melting of the Tasiuyak paragneiss,Northern Labrador

Contact aureoles of the anorthositic to granitic plutons of the Mesoproterozoic Nain Plutonic Suite (NPS), Labrador, are particularly well developed in the Palaeoproterozoic granulite facies, metasedimentary, Tasiuyak gneiss. Granulite facies regional metamorphism (M_R), c. 1860 Ma, led to biotite dehydration melting of the paragneiss and melt migration, leaving behind biotite‐poor, garnet–sillimanite‐bearing quartzofeldspathic rocks. Subsequently, Tasiuyak gneiss within a c. 1320 Ma contact aureole of the NPS was statically subjected to lower pressure, but higher temperature conditions (M_C), leading to a second partial melting event, and the generation of complex mineral assemblages and microstructures, which were controlled to a large extent by the textures of the M_R assemblage. This control is clearly seen in scanning electron microscopic images of thin sections and is further supported by phase equilibria modelling. Samples collected within the contact aureole near Anaktalik Brook, west of Nain, Labrador, mainly consist of spinel–cordierite and orthopyroxene–cordierite (or plagioclase) pseudomorphs after M_R sillimanite and garnet, respectively, within a quartzofeldspathic matrix. In addition, some samples contain fine‐grained intergrowths of K‐feldspar–quartz–cordierite–orthopyroxene inferred to be pseudomorphs after osumulite. Microstructural evidence of the former melt includes (i) coarse‐grained K‐feldspar–quartz–cordierite–orthopyroxene domains that locally cut the rock fabric and are inferred to represent neosome; (ii) very fine‐ to medium‐grained cordierite–quartz intergrowths interpreted to have formed by a reaction involving dissolution of biotite and feldspar in melt; and (iii) fine‐scale interstitial pools or micro‐cracks filled by feldspar interpreted to have crystallized from melt. Ultrahigh temperature (UHT) conditions during contact metamorphism are supported by (i) solidus temperatures >900 °C estimated for all samples, coupled with extensive textural evidence for contact‐related partial melting; (ii) the inferred (former) presence of osumilite; and (iii) titanium‐in‐quartz thermometry indicating temperatures within error of 900 °C. The UHT environment in which these unusual textures and minerals were developed was likely a consequence of the superposition of more than one contact metamorphic event upon the already relatively anhydrous Tasiuyak gneiss.     

Zoned (Cretaceous and Cenozoic) garnet and the timing of high grade metamorphism, Southern Alps, New Zealand

New (garnet Sm–Nd and Lu–Hf) and existing (Rb–Sr, ⁴⁰Ar/³⁹Ar, U–Pb and Sm–Nd) ages and data on deformational fabrics and mineral compositions show for the first time that the garnet growth and ductile deformation in the Alpine Schist belt and Southern Alps orogen, New Zealand are diachronous and partly Cenozoic in age. The dominant metamorphic isograds in the Alpine Schist formed during crustal thickening at a previously unsuspected time, at c. 86 Ma, immediately prior to the opening of the Tasman Sea at c. 84–82 Ma. Obvious changes in the textures and compositional zoning patterns of garnet are not always reliable indicators of polymetamorphism, and fabric elements can be highly diachronous. A detailed timing history for the growth of a single garnet is recorded by a Sm–Nd garnet–whole rock age of 97.8 ± 8.1 Ma for the inmost garnet core (zone 1), Lu–Hf ages of 86.2 ± 0.2 Ma and 86.3 ± 0.2 Ma for overgrowth zones 2 and 3, a step‐leach Sm–Nd age of 12 ± 37 Ma for zone 4, and growth of the garnet rim (zone 5) over the Alpine Fault mylonite foliation during the modern phase of oblique collision that began at c. 5–6 Ma. Plate convergence along the New Zealand portion of the Gondwana margin continued after c. 105 Ma, almost certainly culminating in the oblique collision of a large oceanic plateau (Hikurangi Plateau). The metamorphism of the Alpine Schist at c. 86 Ma is evidence of that hit. The mid‐ to late‐Cretaceous extension that is widespread elsewhere in the New Zealand region is attributed to upper plate extension and slab roll‐back. The effects of the collision with the Hikurangi Plateau may have contributed to the changing plate motions in the region leading up to the opening of the Tasman Sea at c. 82 Ma.     

Triassic to Early Jurassic (c. 200 Ma) UHP metamorphism in the Central Rhodopes: evidence from U–Pb–Th dating of monazite in diamond‐bearing gneiss from Chepelare (Bulgaria)

Evidence for ultrahigh‐pressure metamorphism (UHPM) in the Rhodope metamorphic complex comes from occurrence of diamond in pelitic gneisses, variably overprinted by granulite facies metamorphism, known from several areas of the Rhodopes. However, tectonic setting and timing of UHPM are not interpreted unanimously. Linking age to a metamorphic stage is a prerequisite for reconstruction of these processes. Here, we use monazite in diamond‐bearing gneiss from Chepelare (Bulgaria) to date the diamond‐forming UHPM event in the Central Rhodopes. The diamond‐bearing gneiss comes from a strongly deformed, lithologically heterogeneous zone (Chepelare Mélange) sandwiched between two migmatized orthogneiss units, known as Arda‐I and Arda‐II. Diamond, identified by Raman micro‐spectroscopy, shows the characteristic band mostly centred between 1332 and 1330 cm^?1. The microdiamond occurs as single grains or polyphase diamond + carbonate inclusions, rarely with CO₂. Thermodynamic modelling shows that garnet was stable at UHP conditions of 3.5–4.6 GPa and 700–800 °C, in the stability field of diamond, and was re‐equilibrated at granulite facies/partial melting conditions of 0.8–1.2 GPa and 750–800 °C. The texture of monazite shows older central parts and extensive younger domains which formed due to metasomatic replacement in solid residue and/or overgrowth in melt domains. The monazite core compositions, with distinctly lower Y, Th and U contents, suggest its formation in equilibrium with garnet. The U–Th–Pb dating of monazite using electron microprobe analysis yielded a c. 200 Ma age for the older cores with low Th, Y, U and high La/Nd ratio, and a c. 160 Ma age for the dominant younger monazite enriched in Th, Y, U and HREE. The older age of c. 200 Ma is interpreted as the timing of UHPM, whereas the younger age of c. 160 Ma as granulite facies/partial melting overprint. Our results suggest that UHPM occurred in Late Triassic to Early Jurassic time, in the framework of collision and subduction of continental crust after the closure of Paleotethys.     

Constraints from monazite and xenotime growth modelling in the MnCKFMASH‐PYCe system on the P–T path of a metapelite from Shillong‐Meghalaya Plateau: implications for the Indian shield assembly

The Palaeo‐Mesoproterozoic metapelite granulites from northern Garo Hills, western Shillong‐Meghalaya Gneissic Complex (SMGC), northeast India, consist of resorbed garnet, cordierite and K‐feldspar porphyroblasts in a matrix comprising shape‐preferred aggregates of biotite±sillimanite+quartz that define the penetrative gneissic fabric. An earlier assemblage including biotite and sillimanite occurs as inclusions within the garnet and cordierite porphyroblasts. Staurolite within cordierite in samples without matrix sillimanite is interpreted to have formed by a reaction between the sillimanite inclusion and the host cordierite during retrogression. Accessory monazite occurs as inclusions within garnet as well as in the matrix, whereas accessory xenotime occurs only in the matrix. The monazite inclusions in garnet contain higher Ca, and lower Y and Th/U than the matrix monazite outside resorbed garnet rims. On the other hand, matrix monazite away from garnet contains low Ca and Y, and shows very high Th/U ratios. The low Th/U ratios (<10) of the Y‐poor garnet‐hosted monazite indicate subsolidus formation during an early stage of prograde metamorphism. A calculated P–T pseudosection in the MnCKFMASH‐PYCe system indicates that the garnet‐hosted monazite formed at <3 kbar/600 °C (Stage A). These P–T estimates extend backward the previously inferred prograde P–T path from peak anatectic conditions of 7–8 kbar/850 °C based on major mineral equilibria. Furthermore, the calculated P–T pseudosections indicate that cordierite–staurolite equilibrated at ~5.5 kbar/630 °C during retrograde metamorphism. Thus, the P–T path was counterclockwise. The Y‐rich matrix monazite outside garnet rims formed between ~3.2 kbar/650 °C and ~5 kbar/775 °C (Stage B) during prograde metamorphism. If the effect of bulk composition change due to open system behaviour during anatexis is considered, the P–T conditions may be lower for Stage A (<2 kbar/525 °C) and Stage B (~3 kbar/600 °C to ~3.5 kbar/660 °C). Prograde garnet growth occurred over the entire temperature range (550–850 °C), and Stage‐B monazite was perhaps initially entrapped in garnet. During post‐peak cooling, the Stage‐B monazite grains were released in the matrix by garnet dissolution. Furthermore, new matrix monazite (low Y and very high Th/U ≤80, ~8 kbar/850–800 °C, Stage C), some monazite outside garnet rims (high Y and intermediate Th/U ≤30, ~8 kbar/800–785 °C, Stage D), and matrix xenotime (<785 °C) formed through post‐peak crystallization of melt. Regardless of textural setting, all monazite populations show identical chemical ages (1630–1578 Ma, ±43 Ma). The lithological association (metapelite and mafic granulites), and metamorphic age and P–T path of the northern Garo Hills metapelites and those from the southern domain of the Central Indian Tectonic Zone (CITZ) are similar. The SMGC was initially aligned with the southern parts of CITZ and Chotanagpur Gneissic Complex of central/eastern India in an ENE direction, but was displaced ~350 km northward by sinistral movement along the north‐trending Eastern Indian Tectonic Zone in Neoproterozoic. The southern CITZ metapelites supposedly originated in a back‐arc associated with subducting oceanic lithosphere below the Southern Indian Block at c. 1.6 Ga during the initial stage of Indian shield assembly. It is inferred that the SMGC metapelites may also have originated contemporaneously with the southern CITZ metapelites in a similar back‐arc setting.     

Synchronous peak Barrovian metamorphism driven by syn-orogenic magmatism and fluid flow in southern Connecticut, USA

Recent work in Barrovian metamorphic terranes has found that rocks experience peak metamorphic temperatures across several grades at similar times. This result is inconsistent with most geodynamic models of crustal over‐thickening and conductive heating, wherein rocks which reach different metamorphic grades generally reach peak temperatures at different times. Instead, the presence of additional sources of heat and/or focusing mechanisms for heat transport, such as magmatic intrusions and/or advection by metamorphic fluids, may have contributed to the contemporaneous development of several different metamorphic zones. Here, we test the hypothesis of temporally focussed heating for the Wepawaug Schist, a Barrovian terrane in Connecticut, USA, using Sm–Nd ages of prograde garnet growth and U–Pb zircon crystallization ages of associated igneous rocks. Peak temperature in the biotite–garnet zone was dated (via Sm–Nd on garnet) at 378.9 ± 1.6 Ma (2σ), whereas peak temperature in the highest grade staurolite–kyanite zone was dated (via Sm–Nd on garnet rims) at 379.9 ± 6.8 Ma (2σ). These garnet ages suggest that peak metamorphism was pene‐contemporaneous (within error) across these metamorphic grades. Ion microprobe U–Pb ages for zircon from igneous rocks hosted by the metapelites also indicate a period of syn‐metamorphic peak igneous activity at 380.6 ± 4.7 Ma (2σ), indistinguishable from the peak ages recorded by garnet. A 388.6 ± 2.1 Ma (2σ) garnet core age from the staurolite–kyanite zone indicates an earlier episode of growth (coincident with ages from texturally early zircon and a previously published monazite age) along the prograde regional metamorphic T–t path. The timing of peak metamorphism and igneous activity, as well as the occurrence of extensive syn‐metamorphic quartz vein systems and pegmatites, best supports the hypothesis that advective heating driven by magmas and fluids focussed major mineral growth into two distinct episodes: the first at c. 389 Ma, and the second, corresponding to the regionally synchronous peak metamorphism, at c. 380 Ma.     

Monazite behaviour during isothermal decompression in pelitic granulites: a case study from Dinggye,Tibetan Himalaya

Monazite is a key accessory mineral for metamorphic geochronology, but interpretation of its complex chemical and age zoning acquired during high-temperature metamorphism and anatexis remains a challenge. We investigate the petrology, pressure–temperature and timing of metamorphism in pelitic and psammitic granulites that contain monazite from the Greater Himalayan Crystalline Complex (GHC) in Dinggye, southern Tibet. These rocks underwent isothermal decompression from pressure of >10 kbar to ~5 kbar at temperatures of 750–830 °C, and recorded three metamorphic stages at kyanite (M₁), sillimanite (M₂) and cordierite-spinel grade (M₃). Monazite and zircon crystals were dated by microbeam techniques either as grain separates or in thin sections. U–Th–Pb ages are linked to specific conditions of mineral growth on the basis of zoning patterns, trace element signatures, index mineral inclusions (melt inclusions, sillimanite and K-feldspar) in dated domains and textural relationships with co-existing minerals. The results show that inherited domains (500–400 Ma) are preserved in monazite even at granulite-facies conditions. Few monazites or zircon yield ages related to the M₁-stage (~30–29 Ma), possibly corresponding to prograde melting by muscovite dehydration. During the early stage of isothermal decompression, inherited or prograde monazites in most samples were dissolved in the melt produced by biotite dehydration-melting. Most monazite grains crystallized from melt toward the end of decompression (M₃-stage, 21–19 Ma) and are chemically related to garnet breakdown reactions. Another peak of monazite growth occurred at final melt crystallization (~15 Ma), and these monazite grains are unzoned and are homogeneous in composition. In a regional context, our pressure–temperature–time data constrains peak high-pressure metamorphism within the GHC to ~30–29 Ma in Dinggye Himalaya. Our results are in line with a melt-assisted exhumation of the GHC rocks.     

Neoproterozoic evolution and Cambrian reworking of ultrahigh temperature granulites in the Eastern Ghats Province,India

The time‐scales and P–T conditions recorded by granulite facies metamorphic rocks permit inferences about the geodynamic regime in which they formed. Two compositionally heterogeneous cordierite–spinel‐bearing granulites from Vizianagaram, Eastern Ghats Province (EGP), India, were investigated to provide P–T–time constraints using petrography, phase equilibrium modelling, U–Pb geochronology, the rare earth element composition of zircon and monazite, and Ti‐in‐zircon thermometry. These ultrahigh temperature (UHT) granulites preserve discrete compositional layering in which different inferred peak assemblages are developed, including layers bearing garnet–sillimanite–spinel, and others bearing orthopyroxene–sillimanite–spinel. These mineral associations cannot be reproduced by phase equilibrium modelling of whole‐rock compositions, indicating that the samples became domainal on a scale less than that of a thin section, even at UHT conditions. Calculation of the P–T stability fields for six compositional domains within which the main rock‐forming minerals are considered to have attained equilibrium suggests peak metamorphic conditions of ~6.8–8.3 kbar at ~1,000°C. In most of these domains, the subsequent evolution resulted in the growth of cordierite and final crystallization of melt at an elevated (residual) H₂O‐undersaturated solidus, consistent with <1 kbar of decompression. Concordant U–Pb ages obtained by SHRIMP from zircon (spread 1,050–800 Ma) and monazite (spread 950–800 Ma) demonstrate that crystallization of these minerals occurred during an interval of c. 250 Ma. By combining LA‐ICP‐MS U–Pb zircon ages with Ti‐in‐zircon temperatures from the same analysis sites, we show that the crust may have remained above 900°C for a minimum of c. 120 Ma between c. 1,000 and c. 880 Ma. Overall, the results suggest that, in the interval 1,050 to 800 Ma, the evolution of the Vizianagaram granulites culminated with UHT conditions from c. 1,000 Ma to c. 880 Ma, associated with minor decompression, before further zircon crystallization at c. 880–800 Ma during cooling to the solidus. However, these rocks are adjacent to the Paderu–Anantagiri–Salur crustal block to the NW that experienced counterclockwise P–T–t paths, and records similar UHT peak metamorphic conditions (7–8 kbar, ~950°C) followed by near‐isobaric cooling, and has a similar chronology during the Neoproterozoic. The limited decompression inferred at Vizianagaram may be explained by partial exhumation due to thrusting of this crustal block over the adjacent Paderu–Anantagiri–Salur crustal block. The residual granulites in both blocks have high concentrations of heat‐producing elements and likely remained hot at mid‐crustal depths throughout a period of relative tectonic quiescence in the interval 800–550 Ma. During the Cambrian Period, the EGP was located in the hinterland of the Denman–Pinjarra–Prydz orogen. A later concordant population of zircon dated at 511 ± 6 Ma records crystallization at temperatures of ~810°C. This age may record a low‐degree of melting due to limited influx of fluid into hot, weak crust in response to convergence of the Crohn craton with a composite orogenic hinterland comprising the Rayner terrane, EGP, and cratonic India.     

Polymetamorphism in garnet micaschists of the Saualpe Eclogite Unit (Eastern Alps,Austria), resolved by automated SEM methods and EMP–Th–U–Pb monazite dating

Polymetamorphic garnet micaschists from the Austroalpine Saualpe Eclogite Unit (Kärnten, Austria, Eastern Alps) display complex microstructural and mineral–chemical relationships. Automated scanning electron microscopy routines with energy dispersive X‐ray (EDX) spectral mapping were applied for monazite detection and garnet mineral–chemical characterization. When the Fe, Mg, Mn and Ca element wt% compositions are used as generic labels for garnet EDX spectra, complex zonations and porphyroblast generations can be resolved in complete thin sections for selective electron‐microprobe analyses. Two garnet porphyroblast generations and diverse monazite age populations have been revealed in low‐Ca and high‐Al‐metapelites. Garnet 1 has decreasing Mn, constant Ca and significantly increasing Mg from cores to rims. Geothermobarometry of garnet 1 assemblages signals a crystallization along a M1 prograde metamorphism at ~650 °C/6–8 kbar. Sporadic monazite 1 crystallization started at c. 320 Ma. Subsequent pervasive 300–250 Ma high‐Y and high‐Gd monazite 1 formation during decompression coincided with the intrusion of Permian and Early Triassic pegmatites. Monazite 1 crystallized along the margin of garnet 1. Coronas of apatite and allanite around the large 320–250 Ma monazite signal a retrogressive stage. These microstructures suggest a Carboniferous‐to‐Early‐Permian age for the prograde M1 event with garnet 1. Such a M1 event at an intermediate‐P/T gradient has not yet been described from the Saualpe, and preceded a Permo‐Triassic low‐P stage. The M2 event with garnet 2 postdates the corona formation around Permian monazite. Garnet 2 displays first increasing X_Ca at decreasing X_Mg, then increasing X_Ca and X_Mg, and finally decreasing X_Ca with increasing X_Mg, always at high Ca and Mg, and low Mn. This records a P–T evolution which passed through eclogite facies conditions and reached maximum temperatures at ~750 °C/14 kbar during decompression‐heating. A monazite 2 population (94–86 Ma) with lower Y and Gd contents crystallized at decreasing pressure during the Cretaceous (Eo‐Alpine) metamorphism M2 at a high‐P/T gradient. The Saualpe Eclogite Unit underwent two distinct clockwise metamorphic cycles at different P–T conditions, related to continental collisions under different thermal regimes. This led to a characteristic distribution pattern of monazite ages in this unit which is different from other Austroalpine basement areas.     

The metamorphic evolution of metapelitic granulites from Radok Lake, northern Prince Charles Mountains, east Antarctica; evidence for an anticlockwise P–T path

Mineral textures in metapelitic granulites from the northern Prince Charles Mountains, coupled with thermodynamic modelling in the K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) model system, point to pressure increasing with increasing temperature on the prograde metamorphic path, followed by retrograde cooling (i.e. an anticlockwise P–T path). Textural evidence for the increasing temperature part of the path is given by the breakdown of garnet and biotite to form orthopyroxene and cordierite in sillimanite‐absent rocks, and through the break‐down of biotite and sillimanite to form spinel, cordierite and garnet in more aluminous assemblages. This is equated to the advective addition of heat from the regional emplacement of granitic and charnockitic magmas dated at c. 980 Ma. A subsequent increase in pressure, inferred from the break‐down of spinel and quartz to sillimanite, cordierite and garnet in aluminous rocks, is attributed to crustal thickening related to upright folding dated at 940–910 Ma. The terrane attained peak metamorphic temperatures of c. 880 °C at pressures of c. 6.0–6.5 kbar during this event. Subsequent cooling is inferred from the localised breakdown of cordierite and garnet to form biotite and sillimanite that developed in the latter stages of the same event. The textural observations described are interpreted via the application of P–T and P–T–X pseudosections. The latter show that most rock compositions preserve only fragments of the overall P–T path; a result of different rock compositions undergoing mineral assemblage changes, or changes in mineral modal abundance, on different sections of the P–T path. The results also suggest that partial melting during granulite facies metamorphism, coupled with melt loss and dehydration, initiated a switch from pervasive ductile, to discrete ductile/brittle deformation, during retrograde cooling.     

Timing of high-pressure metamorphism and exhumation of the eclogite type-locality (Kupplerbrunn–Prickler Halt, Saualpe, south-eastern Austria): constraints from correlations of the Sm–Nd, Lu–Hf, U–Pb and Rb–Sr isotopic systems

Sm–Nd, Lu–Hf, Rb–Sr and SIMS U–Pb data are presented for meta‐gabbroic eclogites from the eclogite type‐locality ( Haüy, 1822 ) Kupplerbrunn–Prickler Halt and other areas of the Saualpe (SE Austria) and Pohorje Mountains (Slovenia). Mg‐rich eclogites derived from early gabbroic cumulates are kyanite‐ and zoisite rich, whereas eclogites with lower Mg contents contain clinozoisite ± kyanite. Calculated P–T conditions at the final stages of high‐pressure metamorphism are 2.2 ± 0.2 GPa at 630–740 °C. Kyanite‐rich eclogites did not yield geologically meaningful Sm–Nd ages due to incomplete Nd isotope equilibration, whereas Sm–Nd multifraction garnet–omphacite regression for a low‐Mg eclogite from Kupplerbrunn yields an age of 91.1 ± 1.3 Ma. The Sm–Nd age of 94.1 ± 0.8 Ma obtained from the Fe‐rich core fraction of this garnet dates the initial stages of garnet growth. Zircon that also crystallized at eclogite facies conditions gives a weighted mean U–Pb SIMS age of 88.4 ± 8.1 Ma. Lu–Hf isotope analysis of a kyanite–eclogite from Kupplerbrunn yields 88.4 ± 4.7 Ma for the garnet–omphacite pair. Two low‐Mg eclogites from the Gertrusk locality of the Saualpe yield a multimineral Sm–Nd age of 90.6 ± 1.0 Ma. A low‐Mg eclogite from the Pohorje Mountains (70 km to the SE) gives a garnet–whole‐rock Lu–Hf age of 93.3 ± 2.8 Ma. These new age data and published Sm–Nd ages of metasedimentary host rocks constrain the final stages of the eo‐Alpine high‐pressure event in the Saualpe–Pohorje part of the south‐easternmost Austroalpine nappe system suggesting that garnet growth in the high‐pressure assemblages started at c. 95–94 Ma and ceased at c. 90–88 Ma, probably at the final pressure peak. Zircon and amphibole crystallization was still possible during incipient isothermal decompression. Rapid exhumation of the high‐pressure rocks was induced by collision of the northern Apulian plate with parts of the Austroalpine microplate, following Jurassic closure of the Permo‐Triassic Meliata back‐arc basin.     

Modification of the Sm–Nd isotopic system in garnet induced by retrogressive fluids

Garnet, as a major constitutive mineral of eclogite, is important for Sm–Nd dating of eclogite due to its high Sm/Nd ratio and its stability during retrogression. However, a comprehensive study of the petrography, mineral chemistry, garnet water content, and Sm–Nd isotopic composition of eclogites from the Bixiling massif, Central Dabie Zone (CDZ), reveals significant modification of the Sm–Nd isotopic system in garnet as a result of retrogression. This problem constitutes a challenge for Sm–Nd dating of the Bixiling eclogites, with the Sm–Nd isochron ages of 218 ± 4 to 210 ± 9 Ma reported in the literature being younger than 226 ± 3 Ma, which is the generally accepted peak metamorphic age of the CDZ. Petrographic analysis reveals heterogeneity in colour within single fractured garnet grains. There are light‐pink garnet (Grt‐P) and red garnet (Grt‐R) types that possess distinct chemical compositions. Compared to Grt‐P, Grt‐R has higher Fe and andradrite contents but lower Al and grossular contents. Grt‐P also has lower water contents (15–35 ppm) than Grt‐R (34–65 ppm), which, together with the spatial association between Grt‐R and fractures, suggests that the colour change is related to fluid alteration. Grt‐P is an ultra‐high‐pressure (UHP) mineral, and Grt‐R is the product of the interaction between Grt‐P and a fluid during retrogression. Moreover, Grt‐R features lower Sm and Nd contents but higher Sm/Nd ratios than Grt‐P. The Sm–Nd isochrons defined by UHP minerals (Grt‐P+Omp+Rt or Grt‐P+Cpx+WR) from three eclogite samples yield consistent ages of 226.0 ± 3.8 Ma, 225.0 ± 3.9 Ma and 226.2 ± 6.9 Ma, which are identical to the peak metamorphic age of 226 ± 3 Ma for the CDZ. The retrogressed garnet (i.e., Grt‐R), omphacite and rutile, together define a pseudoisochron with younger ages of 218.9 ± 5.9 to 202.8 ± 4.8 Ma, which are geologically meaningless. The increase in the Sm/Nd ratio with constant or lower ¹⁴³Nd/¹⁴⁴Nd ratios during the transformation of Grt‐P to Grt‐R was probably the cause of these younger ages.