Heavy metal contamination in the vicinity of the Daduk Au–Ag–Pb–Zn mine in Korea

The heavy metal contamination and seasonal variation of the metals in soils, plants and waters in the vicinity of an abandoned metalliferous mine in Korea were studied. Elevated levels of Cd, Cu, Pb and Zn were found in tailings with averages of 8.57, 481, 4,450 and 753 mg/kg, respectively. These metals are continuously dispersed downstream and downslope from the tailings by clastic movement through wind and water. Thus, significant levels of the elements in waters and sediments were found up to 3.3 km downstream from the mining site, especially for Cd and Zn. Enriched concentrations of heavy metals were also found in various plants grown in the vicinity of the mining area, and the metal concentrations in plants increased with those in soils. In a study of seasonal variation on the heavy metals in paddy fields, relatively high concentrations of heavy metals were found in rice leaves and stalks grown under oxidizing conditions rather than a reducing environment (P<0.05).     

Hydrogen incorporation in enstatite in the system MgO–SiO2–H2O–NaCl

The incorporation of hydrogen in enstatite in a hydrous system containing various amounts of NaCl was investigated at 25 kbar. The hydrogen content in enstatite shows a clear negative correlation to the NaCl-concentration in the system. The most favourable explanation is the reduction of water fugacity due to dilution. Other reasons for the limited hydrogen incorporation at high NaCl levels, such as a significant influence of Na⁺ on the defect chemistry or an exchange between OH^- and Cl⁻in enstatite, appear much less important. A partition coefficient D _Na ^En/Fluid = 0.0013 could be determined, demonstrating that Na is less incompatible in enstatite than H. The new results support the idea that dissolved components have to be considered when the total hydrogen storage capacity in nominally anhydrous minerals is estimated, especially in geological settings with high levels of halogens, such as subduction zones.     

Low-Nitrogen Diamond Growth in the Fe–C–S System

Doklady Earth Sciences - The first results on diamond growth in the Fe–С–S system with 1 wt % S (relative to Fe) at 6 GPa and 1450°C have been reported. The diamonds obtained...     

Radiolarian paleobiogeography in the late Albian–Santonian

Radiolarian paleobiogeography for the late Albian–Santonian is proposed for the first time. The paleobiogeographic differentiation is found to be different for the Albian, Cenomanian, Turonian, and Coniacian–Santonian. The Tethyan and Boreal superrealms can be recognized for the Albian–Santonian. For the Albian–Santonian, the Tethyan Superrealm can be subdivided into realms: Atlantic-Mediterranean, Carpathian-Caucasian, and Tropical-Pacific. The boundaries of these realms changed throughout geological time. The Boreal Superrealm recognized for the Albian so far cannot be subdivided into realms, whereas in the Cenomanian it included the East European and Western Siberian realms without a clear definition of the boundaries and the Boreal-Pacific (in the North Pacific). The Boreal Superrealm is subdivided in the Turonian into two realms (European-Western Siberian and Boreal-Pacific), and in the Coniacian–Santonian, it is subdivided into three realms (European, Western Siberian, and Boreal-Pacific). The Austral Superrealm can be recognized only for the Albian and Cenomanian, and because of the lack of data, it cannot be delineated for the Turonian and Coniacian–Santonian.     

Silica Distribution in the System Quartz–Water–Vapor Depending on the Temperature Gradient

Careful measurements of temperature on the surface of autoclaves indicate that small temperature gradients (TG) occur in the standard electric furnaces. These gradients can affect the results of long-lasting (up to 775 days) experiments in the system quartz–water–vapor at 300°C. From the bottom of the autoclave to its top, the temperature decreased in the upper parts of the electric furnaces and increased in their lower parts (TG =–0.08 and 0.15°C/cm, respectively). In the upper parts of the electric furnaces, the concentration of dissolved silica (m) was close to the quartz solubility (10 mmol/kg), and no other changes took place, which is consistent with the currently conventionally admitted notion that quartz is stable under these conditions. In the lower parts of the electric furnaces, m decreased to 0.03 mmol/kg, and opal was precipitated on the walls of the capsules above the solution (the opal was transformed into secondary quartz with time). These data suggest that no equilibrium silica distribution between liquid and vapor water phases was reached. We have suggested and analyzed as wide as possible circle of hypotheses conceivably able to explain this unequilibrated state. The most realistic explanation of the phenomenon seems to be that distillation is initiated by preferable evaporation of the solution in its thin (<100 nm) layer at the meniscus edge. A mathematic model of the process is suggested. The model is consistent with experimental data. The phenomenon in question can be detected in various experimental and technological systems and hampers the attainment of complete equilibrium. In natural systems, this phenomenon can lead to the migration of cavities partly filled with solution at an inversion of the geothermal gradient (beneath sills and lava flows).     

Gas–oil fluids in the formation of travertines in the Baikal rift zone

Active participation of gas–oil fluids in the processes of mineral formation and petrogenesis in travertines of the Arshan and Garga hot springs is substantiated. The parageneses of the products of pyrolytic decomposition and oxidation of the gas–oil components of hydrothermal fluids (amorphous bitumen, graphite-like CM, and graphite) with different genetic groups of minerals crystallized in a wide range of P–T conditions were established. Travertines of the Baikal rift zone were formed from multicomponent hydrous–gas–oil fluids by the following basic mechanisms of mineral formation: chemogenic, biogenic, cavitation, fluid pyrometamorphism, and pyrolysis.     

Anoxia in the Domanik basin of the Timan–Pechora region

Analysis of the carbon isotopic composition in aryl carotenoid derivatives, including isorenieratene, in bitumen from domanikoid rocks of the sections cropping out along the Chut River revealed that they contain anomalously heavy carbon, which is determined by the formation of these compounds from green sulfur bacteria of the family Chlorobiaceae. These bacteria use the peculiar process of carbon fixing as HCO₃^? in the reversed tricarboxilic acid cycle. The fact of hydrosulfuric contamination of the photic water layer in the Domanik basin is confirmed by the plurality of data. Anoxity in shelf water of the middle Frasnian Timan–Pechora basin is evident from lithological features such as, for example, lamination of some rocks and mass death of the fauna.     

Phlogopite Formation in the Orthopyroxene–Garnet System in the Presence of H2O–KCl Fluid in Application to the Processes of Mantle Metasomatism

Doklady Earth Sciences - The results of experimental studies are presented for reactions in the orthopyroxene–garnet–phlogopite system in the presence of H2O–KCl fluid at...     

Activity of the Seyfert galaxy NGC 4151 in the near-IR in 1994–2011

We present the results of our infrared J H K L photometry of the Seyfert galaxy NGC 4151 during its active period in 1995–2011. The variable IR source was still in its active state in 2011, though its observed luminosity had almost halved compared to the maximum of 1995–1996. If the “cool” component of the galaxy’s variable source is a dust shell heated with the central “hot” source, its optical depth at 1.25 µm varied from 0.3 to almost 1.0, its temperature from 700 to 950 K, its size from 20 to 40 pc, and its mass from 2 to 40M _⊙ during our observations. A component with a period of 317 ± 5 days can be revealed in the flux variations observed in 1994–2011.     

Deformation style in the Munsiari Thrust Zone: a study in the Madlakia–Munsiari–Dhapa section in north-eastern Kumaun Himalaya

The Main Central Thrust demarcates the boundary between the Lesser Himalaya and the Higher Himalaya in the Himalayan orogen. Several definitions of the Main Central Thrust have been proposed since it was originally described as the southern boundary of the crystalline rocks (the Main Central Thrust mass) in the Kumaun-Garhwal Himalaya. The long-held contention that the Munsiari Thrust represents the Main Central Thrust has been negated by recent isotopic studies. One way to define the Main Central Thrust is that it is a ductile shear zone that is delimited by the Munsiari Thrust (MCT-I) in south and the Vaikrita Thrust (MCT-II) in north. The alternative proposition that the Vaikrita Thrust represents the Main Central Thrust is fraught with practical limitations in many parts of the Himalaya, including the study area. In the metamorphic rocks bounded between the Vaikrita Thrust and the Munsiari Thrust, the isoclinal folds of the earliest phase are routinely ascribed to the pre-Himalayan orogeny, whereas all subsequent folding phases are attributed to the Himalayan orogeny. This article elucidates the structural characteristics of the kilometre-thick Munsiari Thrust Zone and revisits the issue of pre-Himalayan orogenic signatures in the thrust zone. With the help of high-resolution field mapping and the analyses of mesoscopic scale structures, we demonstrate that the Munsiari Thrust is a typical fault zone that is made up of a fault core and two damage zones. The fault core traces the boundary between the quartzite and the biotite-gneiss. The damage zones consist of the low-grade metasedimentary rocks in the footwall and the gneiss-migmatite in the hanging wall. The entire fault zone shares an essentially common history of progressive ductile shearing. Successively developed mesoscopic folds trace various stages of progressive ductile shearing in the damage zones. Two recognizable stages of the shearing are represented by the early isoclinal folds and the late kink folds. As the strain during progressive deformation achieved the levels that were too high for accommodation by ductile flow, it was released by development of a tectonic dislocation along a mechanically weak boundary, the Munsiari Thrust. The isoclinal folds and the Munsiari Thrust were developed at different stages of a common progressive deformation during the Himalayan orogeny. Contrary to the popular notion of consistency with respect to orientation, the stretching lineations show large directional variability due to distortion during the late folding.     

Kysylga gold–silver deposit in the terrigenous sequences of the Verkhoyansk–Kolyma mesozoides

The paper reports the mineralogical and geochemical features of the Kysylga gold deposit located in the hornfelsed Norian sedimentary rocks and classified with low-sulfide gold–quartz type of deposits typical of the Verkhoyansk–Kolyma metallogenic province. Detailed typomorphic study of the major minerals (quartz, arsenopyrite, and gold) of the ore veins shows that the deposit is assigned to the gold–silver type. Mineralogical and geochemical data substantiate this conclusion.     

Changes in Phytoplankton Biomass in the Western Scheldt Estuary During the Period 1978–2006

We investigated whether climate change results in long-term changes in phytoplankton biomass and phenology in a turbid eutrophic coastal plain estuary. Changes in annual mean chlorophyll a (chla) concentrations were studied for the period 1978–2006 in the eutrophic and turbid macro-tidal Western Scheldt estuary. Three stations were investigated: WS1, at the mouth of the estuary; station WS6, halfway up the estuary; and station WS11, near the Dutch–Belgian border near the upstream end of the estuary. No significant long-term changes in yearly averaged chla concentrations were observed in WS1 and WS6, but in WS11 the phytoplankton biomass decreased considerably. This is most likely due to an increase in grazing pressure as a result of an improvement in the dissolved oxygen concentrations. Spectral analyses revealed a possible periodicity of 7 years in the mean chla which was related to periodicity in river discharge. We also observed strong phenological responses in the timing of the spring/summer bloom which were related to a well-documented increase in the temperature in the estuary. The fulcrum, the center of gravity or the day at which 50% of the cumulative chla was reached during the year, advanced by 1–2 days/year. A similar trend was observed for the month in which the maximum bloom was observed, with the exception of station WS1. All stations showed an earlier initiation of the bloom, whereas the day at which the phytoplankton bloom was terminated also moved forward in time excepted for WS11. As a result, the bloom length decreased at station WS1, remained the same at station WS6, and increased at WS11. This complicated pattern in bloom phenology demonstrates the complex nature of ecosystem functioning in estuaries.     

Rb–Sr and Sm–Nd study of granite–charnockite association in the Pudukkottai region and the link between metamorphism and magmatism in the Madurai Block

Pudukkottai region in the northeastern part of the Madurai Block exposes the garnetiferous pink granite that intruded the biotite gneiss. Charnockite patches are associated with both the rock types. Rb–Sr biotite and Sm–Nd whole-rock isochron ages indicate a regional uplift and cooling at ～550 Ma. The initial Nd isotope ratios (\(\varepsilon _{\text {Nd}}^{\mathrm {t}}=-20\) to ?22) and Nd depleted-mantle model ages (T_DM = 2.25 to 2.79 Ga) indicate a common crustal source for the pink-granite and associated charnockite, while the biotite gneiss and the charnockite within it represent an older crustal source (\(\varepsilon _{\text {Nd}}^{\mathrm {t}}= -29\) and T_DM = > 3.2 Ga). The Rb–Sr whole-rock data and initial Sr–Nd isotope ratios also help demonstrate the partial but systematic equilibration of Sr isotope and Rb/Sr ratios during metamorphic mineral-reactions resulting in an ‘apparent whole-rock isochron’. The available geochronological results from the Madurai Block indicate four major periods of magmatism and metamorphism: Neoarchaean–Paleoproterozoic, Mesoproterozoic, mid-Neoproterozoic and late-Neoproterozoic. We suggest that the high-grade and ultrahigh-temperature metamorphism was preceded by magmatism which ‘prepared’ the residual crust to sustain the high P–T conditions. There also appears to be cyclicity in the tectono-magmatic events and an evolutionary model for the Madurai Block should account for the cyclicity in the preserved records.     

Application of the region–time–length algorithm to study of earthquake precursors in the Thailand–Laos–Myanmar borders

In order to examine the precursory seismic quiescence of upcoming hazardous earthquakes, the seismicity data available in the vicinity of the Thailand–Laos–Myanmar borders was analyzed using the Region–Time–Length (RTL) algorithm based statistical technique. The utilized earthquake data were obtained from the International Seismological Centre. Thereafter, the homogeneity and completeness of the catalogue were improved. After performing iterative tests with different values of the \(r_{0}\) and \(t_{0}\) parameters, those of \(r_{0}\) = 120 km and \(t_{0}\) = 2 yr yielded reasonable estimates of the anomalous RTL scores, in both temporal variation and spatial distribution, of a few years prior to five out of eight strong-to-major recognized earthquakes. Statistical evaluation of both the correlation coefficient and stochastic process for the RTL were checked and revealed that the RTL score obtained here excluded artificial or random phenomena. Therefore, the prospective earthquake sources mentioned here should be recognized and effective mitigation plans should be provided.     

Sediment-hosted Zn–Pb–Cu deposits in the Central African Copperbelt

Stratabound epigenetic sulphide Zn–Pb–Cu ore deposits of the Central African Copperbelt in the Democratic Republic of Congo and Zambia are mostly hosted in deformed shallow marine platform carbonates and associated sedimentary rocks of the Neoproterozoic Katanga Supergroup. Economic orebodies, that also contain variable amounts of minor Cd, Co, Ge, Ag, Re, As, Mo, Ga, and V, occur mainly as irregular pipe-like bodies associated with collapse breccias and faults as well as lenticular bodies subparallel to bedding. Kipushi and Kabwe in the Democratic Republic of the Congo and Zambia, respectively, are the major examples of carbonate-hosted Zn–Pb–Cu mined deposits with important by-products of Ge, Cd, Ag and V in the Lufilian Arc, a major metallogenic province famous for its world-class sediment-hosted stratiform Cu–Co deposits. The carbonate-hosted deposits range in age from Neoproterozoic to early Palaeozoic (680 to 450 Ma). The formation of the relatively older Neoproterozoic deposits is probably related to early collision events during the Lufilian Orogeny, whereas the younger Palaeozoic deposits may be related to post-collisional processes of ore formation. Fluid inclusion and stable isotope data indicate that hydrothermal metal-bearing fluids evolved from formation brines during basin evolution and later tectonogenesis. Ore fluid migration occurred mainly along major thrust zones and other structural discontinuities such as karsts, breccias and faults within the Katangan cover rocks, resulting in ore deposition within favourable structures and reactive carbonates of the Katangan Supergroup.     

Evolution of radiolarians in the late Albian–Campanian

The dynamics of radiolarian evolution in the late Albian–Campanian is analyzed, and several stages are recognized. The first stage (late Albian–middle Cenomanian), related to the MCE regional anoxic event, showed low evolutionary tempos and hence lacked structural change in radiolarian communities. The second stage (late Cenomanian–early Turonian), corresponding to ОАЕ 2, which was a global anoxic event, is characterized by a decrease in the number of genera, while many genera showed increased diversification of species composition. At this stage, a considerable number of genera became extinct and appeared, suggesting an increased rate of the radiolarian evolution. The third stage (middle Turonian–early Coniacian), including the beginning of ОАЕ 3, is characterized by a stabilized number of genera. The fourth stage (late Coniacian–Santonian) completely encompasses ОАЕ 3 except for its very beginning. At this stage, the radiolarian communities underwent a significant structural change, while their rate of evolution increased considerably. Nevertheless, during the ОАЕ 3 stage, a distinct trend toward a decrease in generic diversity continued from the late Cenomanian to the middle Turonian. The fifth stage (Campanian) is characterized by quite significant changes in the assemblage composition, while the trend toward a gradual decrease in the number of genera steadily continued. At this stage, which coincided with a considerable cooling, twice as many genera became extinct as during ОАЕ 2. The analysis of the dynamics of radiolarian evolution showed that the anoxic MCE, ОАЕ 2, and ОАЕ 3 events did not result in degradation of radiolarian assemblages. This suggests that this group has significant stratigraphic potential. In general, the evolution of radiolarians in the Late Cretaceous was gradual. By the end of the Campanian, nearly half of the generic diversity was composed of genera which appeared at the beginning of the Cretaceous and earlier.     

On the miscibility gap in monazite–xenotime systems

The regular solid solution model has been applied to solid solubility in the monazite–xenotime systems and is verified against the available experimental data for LaPO₄–YPO₄ and CePO₄–YPO₄ systems. The model is then used to predict the miscibility gaps in a number of other monazite–xenotime systems. The implications for prospective two-phase monazite–xenotime fiber coatings for applications in ceramic matrix composites (CMCs) are discussed.

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Metallogeny of the northeastern Gangdese Pb–Zn–Ag–Fe–Mo–W polymetallic belt in the Lhasa terrane,southern Tibet

The northeastern Gangdese Pb–Zn–Ag–Fe–Mo–W polymetallic belt (NGPB), characterized by skarn and porphyry deposits, is one of the most important metallogenic belts in the Himalaya–Tibetan continental orogenic system. This belt extends for nearly four hundred kilometers along the Luobadui–Milashan Fault in the central Lhasa subterrane, and contains more than 10 large ore deposits with high potential for development. Three major types of mineralization system have been identified: skarn Fe systems, skarn/breccia Pb–Zn–Ag systems, and porphyry/skarn Mo–Cu–W systems. In this study, we conducted a whole-rock geochemical, U–Pb zircon geochronological, and in situ zircon Hf isotopic study of ore-forming rocks in the NGPB, specifically the Jiangga, Jiaduopule, and Rema skarn Fe deposits, and the Yaguila Pb–Zn–Ag deposit. Although some of these deposits (porphyry Mo systems) formed during the post-collisional stage (21–14 Ma), the majority (these three systems) developed during the main (‘soft collision’) stage of the India–Asia continental collision (65–50 Ma). The skarn Fe deposits are commonly associated with granodiorites, monzogranites, and granites, and formed between 65 and 50 Ma. The ore-forming intrusions of the Pb–Zn–Ag deposits are characterized by granite, quartz porphyry, and granite porphyry, which developed in the interval of 65–55 Ma. The ore-forming porphyries in the Sharang Mo deposit, formed at 53 Ma. The rocks from Fe deposits are metaluminous, and have relatively lower SiO₂, and higher CaO, MgO, FeO contents than the intrusions associated with Mo and Pb–Zn–Ag mineralization, while the Pb–Zn–Ag deposits are peraluminous, and have high SiO₂ and high total alkali concentrations. They all exhibit moderately fractionated REE patterns characterized by lower contents of heavy REE relative to light REE, and they are enriched in large-ion lithophile elements and relatively depleted in high-field-strength elements. Ore-forming granites from Fe deposits display ⁸⁷Sr/⁸⁶Sr_(i) = 0.7054–0.7074 and ε_Nd(t) = − 4.7 to + 1.3, whereas rocks from the Yaguila Pb–Zn–Ag deposit have ⁸⁷Sr/⁸⁶Sr_(i) = 0.7266–0.7281 and ε_Nd(t) = − 13.5 to − 13.3. In situ Lu–Hf isotopic analyses of zircons from Fe deposits show that ε_Hf(t) values range from − 7.3 to + 6.6, with T_DM(Hf)^C model ages of 712 to 1589 Ma, and Yaguila Pb–Zn–Ag deposit has ε_Hf(t) values from − 13.9 to − 1.3 with T_DM(Hf)^C model ages of 1216 to 2016 Ma. Combined with existing data from the Sharang Mo deposit, we conclude that the ore-forming intrusions associated with the skarn Fe and porphyry Mo deposits were derived from partial melting of metasomatized lithospheric mantle and rejuvenated lower crust beneath the central Lhasa subterrane, respectively. Melting of the ancient continental material was critical for the development of the Pb–Zn–Ag system. Therefore, it is likely that the source rocks play an important role in determining the metal endowment of intrusions formed during the initial stage of the India–Asia continental collision.     

Trends in heat-related mortality in the United States, 1975–2004

This study addresses the long-term trends in heat-related mortality across 29 US metropolitan areas from 1975 to 2004 to discern the spatial patterns and temporal trends in heat vulnerability. Mortality data have been standardized to account for population trends, and seasonal and interannual variability. On days when a city experienced an “oppressive” air mass, mean anomalous mortality was calculated, along with the likelihood that oppressive days led to a mortality response at least one standard deviation above the baseline value. Results show a general decline in heat-related mortality from the 1970s to 1990s, after which the decline seems to have abated. The likelihood of oppressive days leading to significant increases in mortality has shown less of a decline. The number of oppressive days has stayed the same or increased at most metropolitan areas. With US homes near saturation in terms of air-conditioning availability, an aging population is still significantly vulnerable to heat events.     

The Thakkhola–Mustang graben in Nepal and the late Cenozoic extension in the Higher Himalayas

The Thakkhola–Mustang graben is located at the northern side of the Dhaulagiri and Annapurna ranges in North Central Nepal. The structural pattern is mainly characterised by the N020–040° Thakkhola Fault system responsible for the development of the half-graben. A detailed study of the substrate and the sedimentary fill in several outcrops indicates polyphased faulting:-pre-sedimentation faulting (Miocene), with a mainly NNW–SSE to N–S compressional stress expressed in the substratum by N020–040° and N180–N010° sinistral and N130–140° dextral conjugate strike-slip faults;-syn-sedimentation faulting (Pliocene–Pleistocene), characterised by a W–E to WNW–ESE extensional stress and tectonic subsidence of the half-graben during the Tetang period (Pliocene probably), followed by a doming of the Tetang deposits and a short period of erosion (cf. Pliocene planation surface and unconformity between the Tetang and Thakkhola Formations); the Thakkhola period (Pleistocene) is characterized by a W–E to WNW–ESE extensional stress and a major subsidence of the half graben;-post-sedimentation recurrent extensional faulting and N–S and NE–SW normal faults in the late Quaternary terrace formations.Geodynamic interpretation of the faulting is discussed in relation to the following:

• 1.the geographic situation of the Thakkhola–Mustang half-graben in the southern part of Tibet and its setting in the Tethyan series above the South Tibetan Detachment System (STDS);
• 2.the geodynamic conditions of the convergence between India and Eurasia and the dextral east–west shearing between the High Himalayas and south Tibet;
• 3.the possible relations between the sinistral Thakkhola and the dextral Karakorum strike-slip faults in a N–S compressional stress regime during the Miocene.