K–Ar and Ar–Ar dating of the Palaeozoic metamorphic complex from the Mid-Bosnian Schist Mts., Central Dinarides, Bosnia and Hercegovina

Summary K–Ar and Ar–Ar whole rock and mineral ages are presented for 25 samples of metamorphic rocks from the Mid-Bosnian Schist Mts., representing one of the largest allochthonous Palaeozoic terranes incorporated within the Internal Dinarides. Four main age groups can be distinguished: 1) Variscan (343Ma), 2) post-Variscan (288–238Ma), 3) Early Cretaceous (mainly 121–92Ma), and 4) Eocene (59–35Ma) ages. Apart from this, an Oligocene (31Ma) age was obtained on Alpine vein hyalophane. The radiometric dating indicates a polyphase metamorphic evolution of the Palaeozoic formations and suggests a pre-Carboniferous age of the volcano-sedimentary protoliths, an Early Carboniferous age of Variscan metamorphism and deformation, post-Variscan volcanism, an Early Cretaceous metamorphic overprint related to out-of-sequence thrusting of the Palaeozoic complex, and an Eocene and Oligocene metamorphic overprint related to the main Alpine compressional deformation and subsequent strike-slip faulting, and uplift of the metamorphic core. Accordingly, the Mid-Bosnian Schist Mts. can be correlated in its multistage geodynamic evolution with some Palaeozoic tectonostratigraphic units from the Austroalpine domain in the Eastern Alps.Deceased     

K–Ar age and geochemistry of the SW Japan Paleogene cauldron cluster: Implications for Eocene–Oligocene thermo-tectonic reactivation

Systematic K–Ar dating and geochemical analyses of Paleogene cauldrons in the Sanin Belt of SW Japan have been made to explore the relationship between the timing of their formation and the Paleogene subduction history of SW Japan documented in the Shimanto accretionary complex. We also examine the magma sources and tectonics beneath the backarc region of SW Japan at the eastern plate boundary of Eurasia.Fifty-eight new K–Ar ages and 19 previously reported radiometric age data show that the cauldrons formed during Middle Eocene to Early Oligocene time (43–30 Ma), following a period of magmatic hiatus from 52 to 43 Ma. The hiatus coincides with absence of an accretionary prism in the Shimanto Belt. Resumption of the magmatism that formed the cauldron cluster in the backarc was concurrent with voluminous influx of terrigenous detritus to the trench, as a common tectono-thermal event within a subduction system.The cauldrons are composed of medium-K calc-alkaline basalts to rhyolites and their plutonic equivalents. These rocks are characterized by lower concentrations of large ion lithophile elements (LILE) including K₂O, Ba, Rb, Th, U and Li, lower (La/Yb)_n ratios, lower initial Sr isotopic ratios (0.7037–0.7052) and higher ε_Nd(T) values (?0.5 to +3.5) relative to Late Cretaceous to Early Paleogene equivalents. There are clear trends from enriched to depleted signatures with decreasing age, from the Late Cretaceous to the Paleogene. The same isotopic shift is also confirmed in lower crust-derived xenoliths, and is interpreted as mobilization of pre-existing enriched lithospheric mantle by upwelling depleted asthenosphere.Relatively elevated geothermal gradients are presumed to have prevailed over wide areas of the backarc and forearc of the SW Japan arc-trench system during the Eocene to Oligocene. Newly identified Late Eocene low silica adakites and high-Mg andesites in the Sanin Belt and Early Eocene A-type granites in the SW Korea Peninsula probably formed due to upwelling of hot asthenosphere and subduction of a young plate.The backarc region was an extensional tectonic setting, and some Paleogene rift basins and Sanin Belt cauldrons occur in linear arrays. The Eocene–Oligocene Sanin-SE Korea continental arc lies on the NE extension of the East China Sea Basin, the initial stage of which probably formed by continental arc rifting. This rifting may have been triggered by upwelling of hot asthenosphere into the wedge space created by rollback of the subducted slab, in response to decreased convergence rate between the Pacific and Eurasian plates.     

Deep Structure and Geodynamics of the Black Sea–Caspian Region

Geotectonics - New data on the crust structure of the Black Sea?Caspian region, including the Scythian and Anatolian plate margins, the Caucasus, Black Sea and Southern Caspian structures are...     

Onshore–offshore structure and hydrocarbon potential of the South Yellow Sea

Recent high-resolution airborne gravity data taken over the South Yellow Sea and its western onshore–offshore transition zone, combined with ground gravity data taken over the onshore area (Subei Basin), China, show that the South Basin of the South Yellow Sea and the Subei Basin correspond to the same gravity low anomaly. Magnetic data also support our interpretations. Both areas have similar strata, structures and hydrocarbon potential, and form a large Cenozoic terrestrial sedimentary basin controlled by the Tanlu Fault. Cenozoic terrestrial strata are well developed in the South Basin of the South Yellow Sea, and thick Meso–Paleozoic marine strata are preserved in the Central uplift area. Future hydrocarbon exploration in the South Yellow Sea should focus on the Cenozoic continental sequence, especially the Paleogene in the South Basin, as well as the Meso–Paleozoic marine rocks in the Central uplift area. The western part of the middle depression and middle and western parts of the north depression in the South Basin of the South Yellow Sea have the greatest potential for hydrocarbon accumulation.     

Structure and Composition of the Holocene–Pleistocene Sediments in the Northern Barents Sea

Lithology and Mineral Resources - Signs of extensive migration of gas-bearing fluids from the sedimentary cover into the water column were identified in the northern Barents Sea during Cruises 25...     

Geochemistry and petrogenesis of the Late Mesozoic–Early Cenozoic volcanic rocks of the Okhotsk and Japan marginal seas

The results of ICP-MS trace-element (LILE, HFSE, REE) study of the Late Mesozoic–Early Cenozoic volcanic rocks of the Okhotsk and Japan seas and geochronological K-Ar dating of the Eocene volcanic rocks are presented. Specifics of volcanism developed on submarine rises of these seas was characterized for the first time, and magma sources and geodynamic settings of the volcanic complexes predating the formation of the deep-water basins were determined. It is established that the Late Mesozoic magmas were formed in a subduction setting from spinel peridotites of suprasubduction mantle wedge, which was metasomatically reworked by aqueous fluids that were released by dehydration of sedimentary layer of subducting oceanic plate. This follows from the elevated concentrations of H₂O, alkalis, potassium, LILE and LREE, and lowered HFSE (including Ta-Nb minimum) and HREE contents, at lowered Sm/Yb, Nb/Ta, Nb/Y and elevated La/Nb, Ba/La, and Zr/Y ratios. Eocene adakite-like volcanic rocks were identified for the first time in the Sea of Okhotsk. They vary from andesitic to more felsic compositions with elevated MgO (>4%) and elevated La/Yb (>14) and Sr/Y (50–60) ratios. Identification of adakite-like volcanic rocks serves as evidence in support of the transform continental-margin (or plate sliding) setting, which is characterized by breaking apart of subduction slab and formation of slab “windows” acting as pathways for the transfer of asthenospheric mantle into continental lithosphere. New geochemical data on the Late Mesozoic–Early Cenozoic volcanic rocks of the Okhotsk and Japan seas and analysis of literature data were used to distinguish two geodynamic settings within these seas: subduction and transform margin. Similar settings operated at that time in the adjacent continental- margin volcanic belts (Akinin and Miller, 2011; Martynov and Khanchuk, 2013; et al.).     

The Stages of Formation of the Main Batholite Belt,Northeast Russia: U–Th–Pb SIMS and Ar–Ar Geochronological Data

Doklady Earth Sciences - The original and published geochronological data and the geological position of different granitoid complexes of the Main (Kolyma) Batholith Belt of Northeast Asia have...     

Lower–Middle Jurassic foraminiferal and ostracode biostratigraphy of the Barents Sea shelf

The Barents Sea shelf is an attractive target as a prospective large petroleum province. Further development of geological and geophysical exploration in the area requires high-resolution biostratigraphic constraints and update stratigraphic charts. The zonal succession of Lower and Middle Jurassic assemblages of foraminifers and ostracodes of the Barents Sea fits well the division for northern Siberia based on correlated independent Jurassic and Cretaceous zonal scales on all main microfossil groups, of which some scales were suggested as the Boreal Zonal Standard. The stratigraphic range of the Barents Sea microfossil assemblages has been updated through correlation with their counterparts from northern Siberia constrained by ammonite and bivalve data. Joint analysis of foraminiferal and ostracode biostratigraphy and lithostratigraphy of the sections allowed a revision to the stratigraphic position and extent of lithological and seismic units. The discovered similarity in the Lower and Middle Jurassic lithostratigraphy in the sections of the Barents Sea shelf and northern Siberia, along with their almost identical microfossil taxonomy, prompts similarity in the Early and Middle Jurassic deposition and geological histories of the two areas.     

Structural–Geodynamic Systems of the Basement of the Black Sea–Caspian Sea Region: Evolution in the Late Paleozoic‒Cenozoic

Geotectonics - Structural-cartographic geological and geophysical materials were analyzed in order to construct a series of models of structural–geodynamic systems of the basement of the...     

Monitoring the Spatiotemporal Evolution of Sea Ice in the Bohai Sea in the 2009–2010 Winter Combining MODIS and Meteorological Data

The spatiotemporal evolution of sea ice of Bohai Sea in the 2009–2010 winter was studied by time-series remote sensing data, and real-time meteorological data in combination with cumulative freezing degree days (CFDD). Sea ice acreage was determined using a ratio-threshold segmentation together with visual interpretation of daily MODIS 250 m imagery. We found the sea ice acreage soared to 31,849 km² on January 23, covering 40.8% of the Bohai Sea. But on February 12, it reached 26,700 km² in Liaodong Bay only, covering almost 90.0% of Liaodong Bay. The rapid formation and expansion of sea ice was caused by continuous cold snaps superimposed on a background of anomalously cold weather. CFDD calculated from surrounding cities highly correlated with sea ice acreage in Liaodong Bay (R ² = 0.72) suggesting CFDD is one of the significant controlling factors. Sea ice expansion showed 7 days lag with respect to the lowest temperature from surrounding coastal cities, and it mainly occurred close to land, along the coastline, and gradually expanded from the shore outwards.     

White mica K–Ar geochronology of Sanbagawa eclogites from Southwest Japan: implications for deformation-controlled K–Ar closure temperature

White mica (phengite and paragonite) K–Ar ages of eclogite-facies Sanbagawa metamorphic rocks (15 eclogitic rocks and eight associated pelitic schists) from four different localities yielded ages of 84–89 Ma (Seba, central Shikoku), 78–80 Ma (Nishi-Iratsu, central Shikoku), 123 and 136 Ma (Gongen, central Shikoku), and 82–88 Ma (Kotsu/Bizan, eastern Shikoku). With the exception of a quartz-rich kyanite-bearing eclogite from Gongen, white mica ages overlap with the previously known range of phengite K–Ar ages of pelitic schists of the Sanbagawa metamorphic belt and can be distinguished from those of the Shimanto metamorphic belt. The similarity of K–Ar ages between the eclogites and surrounding pelitic schists supports a geological setting wherein the eclogites experienced intense ductile deformation with pelitic schists during exhumation. In contrast, phengite extracted from the Gongen eclogite, which is less overprinted by a ductile shear deformation during exhumation, yielded significantly older ages. Given that the Gongen eclogite is enclosed by the Higashi-Akaishi meta-peridotite body, these K–Ar ages are attributed to excess ⁴⁰Ar gained during an interaction between the eclogite and host meta-peridotite with mantle-derived noble gas (very high ⁴⁰Ar/³⁶Ar ratio) at eclogite-facies depth. Fluid exchange between deep-subducted sediments and mantle material might have enhanced the gain of mantle-derived extreme ⁴⁰Ar in the meta-sediment. Although dynamic recrystallization of white mica can reset the Ar isotope system, limited-argon-depletion due to lesser degrees of ductile shear deformation of the Gongen eclogite might have prevented complete release of the trapped excess argon from phengites. This observation supports a model of deformation-controlled K–Ar closure temperature.     

U–Pb–Hf zircon study of two mylonitic granite complexes in the Talas-Fergana fault zone,Kyrgyzstan, and Ar–Ar age of deformations along the fault

A 2000 km long dextral Talas-Fergana strike–slip fault separates eastern terranes in the Kyrgyz Tien Shan from western terranes. The aim of this study was to constrain an age of dextral shearing in the central part of the fault utilizing Ar–Ar dating of micas. We also carried out a U–Pb–Hf zircon study of two different deformed granitoid complexes in the fault zone from which the micas for Ar dating were separated. Two samples of the oldest deformed Neoproterozoic granitoids in the area of study yielded U–Pb zircon SHRIMP ages 728 ± 11 Ma and 778 ± 11 Ma, characteristic for the Cryogenian Bolshoi Naryn Formation, and zircon grains analyzed for their Lu–Hf isotopic compositions yielded εHf(t) values from −11.43 to −16.73, and their calculated tHfc ages varied from 2.42 to 2.71 Ga. Thus varying Cryogenian ages and noticeable heterogeneity of Meso- to Paleoproterozoic crustal sources was established for mylonitic granites of the Bolshoi Naryn Formation. Two samples of mylonitized pegmatoidal granites of the Kyrgysh Complex yielded identical ²⁰⁶Pb/²³⁸U ages of 279 ± 5 Ma corresponding to the main peak of Late-Paleozoic post-collisional magmatism in the Tien Shan (Seltmann et al., 2011), and zircon grains analyzed for their Lu–Hf isotopic compositions yielded εHf(t) values from −11.43 to −16.73, and calculated tHfc ages from 2.42 to 2.71 Ga indicating derivation from a Paleoproterozoic crustal source. Microstructural studies showed that ductile/brittle deformation of pegmatoidal granites of the Kyrgysh Complex occurred at temperatures of 300–400 °C and caused resetting of the K–Ar isotope system of primary muscovite. Deformation of mylonitized granites of the Bolshoi Naryn Formation occurred under high temperature conditions and resulted in protracted growth and recrystallization of micas. The oldest Ar–Ar muscovite age of 241 Ma with a well defined plateau from a pegmatoidal granite of the Kyrgysh Complex is considered as a “minimum” age of dextral motions along this section of the fault in the Triassic while younger ages varying from 227 Ma to 199 Ma with typical staircase patterns indicate protracted growth and recrystallization of micas during ductile deformations which continued until the end of the Triassic.     

Ecology of the bottom fauna and bioaccumulation of trace metals along the Lena River–Laptev Sea transect

The first data on ecology and trace metal (As, Cd, Cr, Cu, Fe, Mn, Ni, Pb) bioaccumulation by macrozoobenthic organisms in area along the 130°E meridional transect from shallow water near the Lena River’s delta till the 78°N are presented. At the newly discovered methane seeps in the shallow Laptev Sea areas (72 m depth), a higher total abundance and biomass compared with background stations were recorded. In carbonate shells and soft tissues of Bivalvia Portlandia arctica and Astarte borealis, the high concentrations of Mn, Fe, Pb, Ni and Co were detected that varied in dependence from sampling site. In the dominating taxa of brittle stars (Ophiuroidea), there were found no significant differences between majority of trace metal content in organisms inhabiting the seeps area and background ones. An elevated content of some metals was detected in the Asteroidea bodies that may be attributed to its trophic behavior (deposit feeder).     

Mesozoic–Cenozoic Structure of the Black Sea–Caucasus–Caspian Region and Its Relationships with the Upper Mantle Structure

Geotectonics - Abstract—Mesozoic‒Cenozoic tectonic zoning and its evolution are characterized by analysis of geological data on the Black Sea–Caucasus–Caspian region. The...     

Major ion composition and carbonate equilibrium in the sediment pore water of the Razdol’naya River estuary of Amur Bay,the Sea of Japan

The complex study of the river water and pore solutions from the bottom sediments in the lower reaches of the Razdol’naya River was conducted in February 2010. The major ion composition of the waters indicates the submarine origin of the near-bottom and pore waters in the lower reaches of the Razdol’naya River in the winter. The river estuary extends upstream for more than 20 km. It was established that the studied sediments are reduced oozes containing pyrite, hydrotroilite, and iron monosulfide, which is direct evidence for sulfate-reduction in the sediments. The diagenesis of organic matter is the main reason for the considerable decrease in the amount of sulfates and the increase in the alkalinity of the sediment pore water. The sedimentary pore water sampled from the deep river pits is characterized by excess alkalinity that cannot be explained by sulfate-reduction and methane genesis. It was suggested that the chemical weathering of silicate minerals and the bacterial mineralization of salts of organic acids could result in the excess alkalinity of the sediment pore water.     

Stratigraphy of the Okhotsk–Chukotka Belt in the Headwaters of the Malyi Anyui River (the Vicinity of Kupol Deposit): U–Pb and 40Ar/39Ar Age Data

Doklady Earth Sciences - U–Pb and 40Ar/39Ar age data obtained for volcanic rocks of the Okhotsk–Chukotka Belt in the headwaters of the Malyi Anyui River (the vicinity of Kupol deposit)...     

The 40Ar/39Ar and Rb–Sr chronology of the Precambrian Aksu blueschists in western China

Three metapelite samples from the Aksu blueschist terrane, Xinjiang, China, were dated by the ⁴⁰Ar/³⁹Ar method on separated phengite grains, obtaining plateau ages in the range of 741−757 Ma. In contrast, the measured Rb and Sr isotope data for the three samples yielded isochron ages ranging from 630 Ma to 900 Ma, suggesting large heterogeneity in the blueschist protolith and suppression of diffusional exchange owing to the low-temperature metamorphic conditions. Because the protolith of Aksu blueschist is composed of oceanic materials that formed ⁴⁰Ar-free phengite during HP and UHP metamorphism and the apparent ⁴⁰Ar/³⁹Ar plateaus ages in this study are similar to previous K–Ar and Rb–Sr ages, the existence of excess argon in these rocks is considered to be insignificant. As a result, the ⁴⁰Ar/³⁹Ar plateau ages in this study (ca. 750 Ma) likely represent the approximate time for peak metamorphism, given the low peak metamorphic temperatures for the Aksu blueschist terrane (300−400 °C). This strongly implies that modern style, cold subduction tectonics operated along the margin of the Aksu terrane no later than 750 Ma, in Neoproterozoic time.     

SHRIMP U–Pb and Ar–Ar geochronology of major porphyry and skarn Cu deposits in the Balkhash Metallogenic Belt,Central Asia,and geological implications

The Balkhash Metallogenic Belt (BMB) in Kazakhstan, Central Asia, with the occurrence of the super-large Kounrad and Aktogai, the large Borly porphyry Cu–Mo deposits, and the large Sayak skarn polymetallic ore-field, is one of the central regions of the Paleozoic Central Asian metallogenic domain and orogenic belt. In this study, newly obtained SHRIMP zircon U–Pb ages of nine samples and ⁴⁰Ar/³⁹Ar ages of six mineral samples (inclding hornblende, biotite and K-feldspar) give more detailed constraints on the timing of the granitic intrusions and their metallogeny. Porphyritic monzonite granite and tonalite porphyry from the Kounrad deposit yield U–Pb zircon SHRIMP ages of 327.3 ± 2.1 Ma and 308.7 ± 2.2 Ma, respectively. Quartz diorite and porphyritic granodiorite from the Aktogai deposit yield U–Pb SHRIMP ages of 335.7 ± 1.3 Ma and 327.5 ± 1.9 Ma, respectively. Porphyritic granodiorite and granodiorite from the Borly deposit yield U–Pb SHRIMP ages of 316.3 ± 0.8 Ma and 305 ± 3 Ma, respectively. Diorite, granodiorite, and monzonite from the Sayak ore-field yield U–Pb SHRIMP ages of 335 ± 2 Ma, 308 ± 10 Ma, and 297 ± 3 Ma, respectively. Hornblende, biotite, and K-feldspar from the Aktogai deposit yield ⁴⁰Ar/³⁹Ar cooling ages of 310.6 Ma, 271.5 Ma, and 274.9 Ma, respectively. Hornblende, biotite, and K-feldspar from the Sayak ore-field yield ⁴⁰Ar/³⁹Ar cooling ages of 287.3 ± 2.8 Ma, 307.9 ± 1.8 Ma, and 249.8 ± 1.6 Ma, respectively. The new ages constrain the timing of Late Paleozoic felsic magmatism to ∼336 to ∼297 Ma. Skarn mineralization in the Sayak ore-field formed at ∼335 and ∼308 Ma. Porphyry Cu–Mo mineralization in the Kounrad deposit and the Aktogai deposit formed at ∼327 Ma, and in the Borly deposit at ∼316 Ma. The Late Paleozoic regional cooling in the temperature range of ∼600 °C to ∼150 °C occurred from ∼307 to ∼257 Ma.     

Is the lycopane/n-C31 ratio an effective proxy of palaeoxicity of bottom water for the Japan Sea? – Unusual distribution of lycopane in the surface sediment from the Japan Sea collected by the MD179 cruise

The lycopane/n-C₃₁ ratio has been proposed as a proxy of palaeoxicity of bottom water. To assess its applicability in the Japan Sea, the piston core samples of MD179-3312, which contains several dark layers that are known to deposited when the bottom water had low oxygen contents, were geochemically analyzed. The TL2 and TL3 layers, deposited during the last glacial maximum when the Japan Sea was stratified, did not show a high lycopane/n-C₃₁ ratio. In contrast, the TL1 layer, which was deposited when the Japan Sea stagnated temporarily but the surface ocean became increasingly productive, had a high lycopane/n-C₃₁ ratio. Furthermore, the depth profile of lycopane/n-C₃₁ ratio is similar to that of n-C₃₇ alkadiene, a compound potentially related to alkenones. Accordingly, we concluded that the lycopane/n-C₃₁ ratio is not a useful proxy to assess palaeoxicity of the bottom water, but reflects the productivity of some phytoplankton in the Japan Sea. This study was supported by MH21, Research Consortium for Methane Hydrate Resources in Japan.     

Lithology,Biostratigraphy, and Geochronology of the Late Pleistocene–Holocene Sediments on the Coast of Onega Bay of the White Sea

Doklady Earth Sciences - This paper reports on the lithological, micropaleontological, and chronometric data (radiocarbon dating) for one of the areas of the White Sea coast. The sedimentary...