青海泽多桌肉地区花岗闪长岩与暗色包体地球化学特征及成因

青海泽多桌肉地区花岗闪长岩中发育大量暗色闪长质包体。通过对花岗闪长岩(寄主岩石)与暗色包体的地球化学研究发现,花岗闪长岩(寄主岩石)的SiO_2含量为w(SiO_2)=61.61%~68.80%,A/CNK=0.91~0.99,属于偏铝质钙碱性花岗岩特征;暗色包体中发育针状磷灰石,暗色包体的SiO_2含量为w(SiO_2)=52.66%~66.99%,碱度率AR=2.08~2.26(大于1),里特曼指数σ=1.89~8.67,固结指数SI=16~24.74,属过铝质钙碱性花岗岩。稀土元素分析显示,花岗闪长岩稀土总量w(ΣREE)=117.44×10~(-6)~265.68×10~(-6);暗色包体稀土总量w(ΣREE)=184.05×10~(-6)~342.11×10~(-6),总量高于寄主岩石;暗色包体和寄主花岗岩有着相似的稀土元素配分模式,显示轻稀土富集,重稀土亏损,轻重稀土元素分馏明显的特征。微量元素分析显示,暗色包体微量元素的分布型式与寄主岩微量元素特征基本一致,大离子亲石元素K、Rb、Ba相对富集,高场强元素Nb、Ta、Zr、Hf相对亏损,反映了岩浆混合作用的特征。在花岗闪长岩中获得LA-ICP-MS锆石U-Pb年龄为202.49 Ma±0.63 Ma,属晚三叠世。表明泽多桌肉花岗闪长岩属于晚三叠世以来的造山带伸展崩塌造成岩石圈较快速减薄以及幔源岩浆底侵作用的发生,并导致地壳岩石接近熔融温度产生壳源岩浆而成岩。     

湘北华容地区小墨山花岗岩体SHRIMP U-Pb年龄及地球化学特征

小墨山岩体侵位于中元古代冷家溪群中,由两期侵入体组成,早期为粗中粒—中粒斑状黑云母二长花岗岩;末期为细粒黑(二)云母二长花岗岩。通过锆石SHRIMP U-Pb法测得岩体侵位年龄为122.5±2.1 Ma(2σ),MSWD=1.9,成岩时代为早白垩世。主元素中,SiO2变化于67.20%~75.16%,K2O含量高,且K2ONa2O,K2O/Na2O为1.16~1.72;ASI值变化于0.96~1.10之间,平均1.02,属准铝质-微过铝质、高钾钙碱性系列。岩石明显富集大离子亲石元素,亏损高场强元素,Rb/Sr=0.27~15.13;Nb/Ta=15.9~17.1,为锶和铌亏损型。ΣREE总体较高,重稀土含量相对较高,轻重稀土分馏稍弱,ΣCe/ΣY为0.49~6.18,(La/Yb)N为0.66~15.54。有较高的εNd(t),为-6.8~-8.7;T2DM相对较小(1.47~1.62 Ga)。综合研究表明,小墨山花岗岩石为壳源型富黑云母过铝花岗岩类(CPG),其成因应为下地壳物质和上地壳物质混合而成,与花岗岩底侵作用或注入地壳中的幔源岩浆有关,形成的构造背景为陆内挤压造山向非造山转换的后造山拉张环境,是在紧随侏罗纪挤压造山运动之后的构造松驰和拉张减薄条件下所形成。     

东昆仑早古生代造山后花岗岩的特征——以大干沟花岗岩为例

大干沟花岗岩体位于东昆仑金水口地区,其岩石类型主要为中粗粒正长花岗岩。该花岗岩的SiO_2含量为68.68%~71.12%,平均含量为69.84%;Al_2O_3含量为14.01%~15.40%,平均含量为14.82%;K_2O/Na_2O值高,为1.19~1.64,平均为1.40;铝饱和指数A/CNK值为0.98~1.02,平均为1.00,具有准铝质-弱过铝质花岗岩的特点。岩石稀土元素总量较高,LREE元素富集,具有明显的Eu负异常,相对原始地幔明显富集U、Th,亏损Ti、P、Nb、Ta等高场强元素和Ba、Sr等大离子亲石元素,具有A型花岗岩的特征。花岗岩εNd(t)0,为-5.6~-7.3,tDM=1.54~2.27 Ga,表明其物源可能主要为中元古代物质(金水口群),LA-ICP-MS锆石εHf(t)=-2.2~2.6,显著不同于地壳岩浆的Hf同位素组成,显示有地幔物质添加。LA-ICP-MS锆石U-Pb年龄为392±2 Ma(MSWD=1.14)。结合区域构造演化和上述地球化学特征,认为大干沟岩体为早古生代造山后伸展阶段的产物,是东昆南地体与东昆北地体碰撞后地幔岩浆上涌及地壳熔融的结果。     

川西甲基卡二云母花岗岩与伟晶岩脉地球化学特征及其地质意义

对川西甲基卡地区二云母花岗岩及伟晶岩脉的岩石学特征、地球化学特征进行了分析,探讨了二云母花岗岩物质来源、构造背景及其与伟晶岩脉的成因联系。分析结果表明,甲基卡二云母花岗岩的SiO_2含量在73.93%~75.06%之间;全碱含量7.90%~8.36%,钾质含量较高,属高钾钙碱性系列岩石;Al_2O_3含量为14.24%~14.77%,A/CNK=1.14~1.24,具强过铝质S型花岗岩特征;ΣREE=31.18×10~(-6)~41.67×10~(-6),LREE/HREE=4.15~6.41,δEu=0.46~0.70;CaO/Na_2O=0.07~0.12(0.3),指示其物源可能是含砂屑物质极少的泥质岩;Al_2O_3/TiO_2=133.1~279.8,比值较高,表明甲基卡二云母花岗岩属高压低温型后碰撞强过铝质岩石。花岗伟晶岩脉SiO_2含量在72.59%~80.91%之间,全碱含量5.26%~10.60%,Al_2O_3含量11.79%~17.64%,σ=0.74~3.80,A/CNK=0.98~2.38,ΣREE=4.03×10~(-6)~8.29×10~(-6),LREE/HREE=2.61~10.40,δEu=0.18~0.68,与岩体差异明显,主、微量元素含量变化也较大。甲基卡二云母花岗岩与伟晶岩脉有密切的成因联系。岩浆不混溶作用可能是形成甲基卡含矿伟晶岩脉的关键因素,花岗质岩浆在上升过程中通过不混溶作用分离出富含挥发分的伟晶岩熔体,在运移或侵位过程中可能交代围岩矿物而使稀有金属元素进一步富集。二云母花岗岩浆和伟晶岩熔体性质的不同导致稀土元素和Th、Sr、Ti、Y、Rb、N等微量元素在两者中含量有明显差异。伟晶岩熔体在运移或就位过程中所经的路径不同和周围环境的差异导致不同位置产出的伟晶岩的元素含量有较大的变化。与二云母花岗岩相比,花岗伟晶岩的形成演化具有一定的跳跃性。     

甘肃北山大石山A型花岗岩体的地球化学特征及构造意义

甘肃北山大石山岩体主要由角闪花岗岩和二长花岗岩组成,岩石的化学成分特点为过铝质(Al_2O_3含量为 12.18%～13.37%)、富硅(SiO_2含量为74.22%～78.38%)、偏碱(Na_2O+K_2O 为7.60%～8.50%),FeO~T/MgO 值高,CaO 和 MgO 含量低(分别为0.01%～0.99%和0.05%～1.15%),富含 Y、Nb 等高场强元素(HFSE)以及 F、Sr、 Ba 和 REE(∑REE=102.3×10~(-6)～120.02×10~(-6))低。这些特点与本区的 I 型和 S 型花岗岩有明显差别,是一种典型的 A_2型花岗岩。大石山岩体 Rb-Sr 等时线年龄为273 Ma,表明北山地区在海西晚期即进入造山后拉张裂解环境。     

东昆仑祁漫塔格乌兰拜兴地区中泥盆世花岗岩年龄、地球化学特征及其地质意义

东昆仑祁漫塔格乌兰拜兴地区花岗岩体由二长花岗岩和花岗闪长岩组成,SiO_2含量为67.47%～73.63%,全碱(Na_2O+K_2O)含量为6.74%～7.89%,K_2O/Na_2O=0.59～1.30,A/CNK=0.91～1.08,属高钾钙碱性系列和钙碱性系列,准铝质-过铝质岩石。稀土元素总量平均为137.28×10~(-6),δEu值为0.37～0.89,平均为0.57,(La/Yb)_N值为6.72～19.36,平均为10.75。稀土元素球粒陨石标准化配分曲线呈负Eu异常明显的右倾型;岩体明显富集大离子亲石元素Rb、K,不相容元素U和Th,轻稀土元素和Pb;相对亏损高场强元素Nb、Ta、P、Ti,以及大离子亲石元素Ba;岩石Rb/Sr值为0.45～1.17,平均为0.72,介于上地幔值和地壳值之间; Nb/Ta值为5.36～13.90,平均为10.93,比值总体低于地幔平均值,显示壳幔混合的特点。采用锆石U-Pb定年的方法,获得乌兰拜兴花岗闪长岩的~(206)Pb/~(238)U年龄为384.1±2.4Ma,代表该岩体的形成年龄。结合岩石地球化学、构造特征和区域地质背景,认为该岩体形成于中泥盆世晚期后碰撞陆内伸展阶段,并与铁多金属矿成矿密切相关,在矿产勘查中应引起重视。     

西昆仑甜水海地体早寒武世花岗岩浆作用及其构造意义

瓦仍孜拉甫岩体和阿依里西岩体出露于西昆仑造山带的甜水海地体中。LA-ICP-MS锆石U-Pb定年表明,阿依里西岩体的花岗质斑岩的侵位年龄为(530±6)Ma,瓦仍孜拉甫岩体的黑云母二长花岗质片麻岩的侵位年龄为(515±2)Ma,都形成于早寒武世。岩石地球化学特征表明,阿依里西岩体中花岗质斑岩的SiO_2含量为67.7%~69.4%,具有较高的Mg#值(44~46),A/CNK值为0.81~0.93;K_2O含量为2.15%~3.02%,呈钙碱性至高钾钙碱性特征;其εHf(t)值为-3.3~-0.8;以轻重稀土分异较为明显,富集Cs、Rb、K、Th、Zr、Hf、Y等元素,而亏损Ba、Nb、Ta、Sr、P和Ti等元素为特点,是由幔源岩浆与壳源岩浆发生混合作用而成。瓦仍孜拉甫岩体黑云母二长花岗质片麻岩的SiO_2含量高其变化范围为75.0%~76.3%,Mg#值比较低,为18~26;A/CNK值为1.01~1.30,K_2O含量为4.31~4.98,表现为高钾钙碱性、过铝质特征,其εHf(t)值为+2.5~+4.3;属于高分异I型花岗岩,源于高钾钙碱性的安山岩和玄武质安山岩的部分熔融。根据这些地球化学特征,结合西昆仑不同地质单元中早古生代花岗岩体的分布特征、地质年代学和岩石成因特征,研究认为这2个花岗质岩体形成于岛弧环境,其为进一步深入研究西昆仑造山带早古生代的构造演化过程提供了新的地质资料。     

西藏南部岗巴—定日地区花岗岩地球化学特征及其构造环境

通过对出露于西藏南部岗巴—定日地区花岗岩体的地球化学研究表明,岩石中SiO2,Al2O3,Na2O和FeO,MgO等的含量均高,贫CaO和Fe2O3;w(SiO2)介于71.40%～73.06%,A/CNK在1.17～1.34之间,为铝和硅过饱和类型的强过铝质花岗岩。岩石的稀土元素总量(ΣREE)为56.80×10-6～89.12×10-6,(La/Yb)N=6.30～18.26,(La/Sm)N=2.62～3.40,ΣLREE/ΣHREE=2.41～4.66;稀土元素配分曲线呈右倾型,具有弱的负铕异常。Nb,Ti等高场强元素具有明显的亏损,而Rb,U,La,Nd,Hf,Eu,Y等大离子亲石元素具有明显的正异常。岩石的87Sr/86Sr初始比值较高,87Sr/86Sr为(0.738 71～0.751 12)。综合研究认为,本区花岗岩的成因为陆壳部分熔融作用形成的,属陆壳改造型强过铝质花岗岩。本区花岗岩岩浆源区岩石成分主要为砂屑岩,其次为泥质岩,是上地壳部分熔融作用的结果。岩石的微量元素标准化曲线图、岩石地R1-R2图解、Rb-(Yb+Ta)和Rb-(Nb+Yb)图解均显示本区岩体形成于同碰撞构造环境的花岗岩,具有同碰撞岩浆活动的特征,是喜马拉雅早期印度板块与冈底斯板块的俯冲碰撞导致的地壳增厚,上地壳部分熔融的产物;为形成于同碰撞构造环境的花岗岩。     

青海省阳康地区晚奥陶世花岗岩地球化学特征及其地质意义

青海省阳康地区花岗岩岩石组合为细粒石英闪长岩、黑云母花岗闪长岩。通过对岩石地球化学分析发现,SiO_2含量为54.36%～70.16%,Al_2O_3含量为13.08%～17.01%,K_2O含量为1.57%～3.91%,Na_2O含量为2.37%～3.75%,CaO含量为1.91%～8.09%,里特曼指数σ为1.5～2.61,属偏铝质-过铝质钙碱性花岗岩;稀土总量(∑REE)为121.7×10~(-6)～458×10~(-6),LREE/HREE值为6.81～14.72,表现为轻稀土富集型,δEu值为0.46～1.16,Eu亏损明显,δCe略亏损;富集大离子亲石元素(Rb、Ba、K)和轻稀土元素(La、Ce、Nd),亏损重稀土元素(Yb、Lu)和高场强元素(Nb、Ta),具有明显的Eu和Sr、P、Ti的亏损。在石英闪长岩和花岗闪长岩中分别获得LA-ICP-MS锆石U-Pb年龄分别为(455.5±1.1)Ma和444Ma,形成时代为晚奥陶世。通过构造环境分析,认为阳康地区花岗岩是由挤压向拉伸环境转换的张驰阶段的岩浆侵位,属同造山花岗岩。     

伊犁盆地南缘琼博拉二长花岗岩锆石年代学及形成动力学机制

西天山造山带内琼博拉地区的长条状岩体位于伊犁盆地南缘,由二长花岗岩组成。为厘定该二长花岗岩的形成机制,本文对该二长花岗岩进行了详细的锆石U-Pb年代学、主量元素、微量元素以及Sr-Nd-Pb同位素研究。LA-ICP-MS锆石年代学研究揭示出琼博拉地区二长花岗岩成岩年龄为(330.5±2.2)Ma、(339.7±2.2)Ma、(351.2±3.0)Ma,为早中石炭世花岗岩,比伊犁盆地511矿床含矿砂体的U-Pb同位素等时线年龄(308±26Ma)老,表明该二长花岗岩体可能是该含矿砂体的一部分物质来源。岩石主量元素、微量元素和Sr-Nd-Pb同位素测试结果揭示该二长花岗岩具有以下特征:(1)SiO_2(70.15%~73.38%)含量高,碱质(K_2O+Na_2O含量为6.32%~7.88%)含量较高,A/CNK(0.82~1.03)较高,表明二长花岗岩为准铝质岩石,属于高钾钙碱性系列;(2)LREE(50.19×10~(-6)~87.92×10~(-6))相对富集,HREE(9.44×10~(-6)~12.08×10~(-6))相对亏损,无明显Eu异常(δEu为0.71~0.97);(3)富集Rb、Th、K、Pb和Sr等大离子亲石元素,相对亏损Nb、Ta、Zr、P和Ti等高场强元素;(4)初始锶同位素比值为0.7050~0.7082,143Nd/144Nd值为0.512217~0.512254,ε_(Nd)(t)为0.3~1.0,Nd模式年龄为1010~1098 Ma。二长花岗岩的Sr、Nd、Pb同位素组成表明该岩石是由幔源玄武质岩浆与地壳重熔形成的硅铝质岩浆混染形成。结合区域构造演化,本文认为二长花岗岩形成于板块的同碰撞构造环境。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。