Toxicity assessments of nanoscale zerovalent iron and its oxidation products in medaka (Oryzias latipes) fish

Iron-based nanotechnologies are increasingly used for environmental remediation; however, toxicologic impacts of iron nanoparticles on the aquatic ecosystem remain poorly understood. We treated larvae of medaka fish (Oryzias latipes) with thoroughly characterized solutions containing carboxymethyl cellulose (CMC)-stabilized nanoscale zerovalent iron (nZVI), aged nanoscale iron oxides (nFe-oxides) or ferrous ion (Fe[II]) for 12-14 days' aqueous exposure to assess the causal toxic effect(s) of iron NPs on the fish. With the CMC-nZVI solution, the dissolved oxygen level decreased, and a burst of reactive oxygen species (ROS) was generated as Fe(II) oxidized to ferric ion (Fe[III]); with the other two iron solutions, these parameters did not significantly change. CMC-nZVI and Fe(II) solutions caused acute lethally and sublethally toxic effects in medaka larvae, with nFe-oxide-containing solutions causing the least toxic effects. We discuss modes of toxic action of iron NPs and chronic toxic effects in terms of hypoxia, Fe(II) toxicity and ROS-mediated oxidative damage.     

Toxicity assessments of nanoscale zerovalent iron and its oxidation products in medaka (Oryzias latipes) fish

Iron-based nanotechnologies are increasingly used for environmental remediation; however, toxicologic impacts of iron nanoparticles on the aquatic ecosystem remain poorly understood. We treated larvae of medaka fish (Oryzias latipes) with thoroughly characterized solutions containing carboxymethyl cellulose (CMC)-stabilized nanoscale zerovalent iron (nZVI), aged nanoscale iron oxides (nFe-oxides) or ferrous ion (Fe[II]) for 12–14 days’ aqueous exposure to assess the causal toxic effect(s) of iron NPs on the fish. With the CMC-nZVI solution, the dissolved oxygen level decreased, and a burst of reactive oxygen species (ROS) was generated as Fe(II) oxidized to ferric ion (Fe[III]); with the other two iron solutions, these parameters did not significantly change. CMC-nZVI and Fe(II) solutions caused acute lethally and sublethally toxic effects in medaka larvae, with nFe-oxide-containing solutions causing the least toxic effects. We discuss modes of toxic action of iron NPs and chronic toxic effects in terms of hypoxia, Fe(II) toxicity and ROS-mediated oxidative damage.     

甜水海钻孔TS95若干地球化学指标的非线性分析与意义

应用关联维分析和R／S分析对西昆伦甜水海孔TS95的4项指标（FeO,Fe2O3,Fe2O3/FeO和有机碳）进行分析,发现它们存在明显的混沌特征和Hurst现象,4项指标的混沌吸引子分别为：FeO－2．8;Fe2O3－3．2;Fe2O／FeO－2．9;有机碳2．5,饱和嵌入维数为5到6,表明控制该地区气候环境演化的动力系统是由有限维数确定的混沌系统,构筑该系统所需变量至少3到4个,最多5到6个,这种体上与深海氧同位素比较接近,与黄土剖面一些指标差异较大,4项指标折Hurst指数（FeO－0．85;Fe2O3－0．76;Fe2O3／FeO－0．65;有机碳－0．74）显示该地区气候环境演化存在明显的持续性成分,这与早期的研究一致,很可能与青藏高原的构造抬升有关,表明除了全球性气候环境波动背景外,局域性因素,如肝藏高原构造抬升和未海地区水系变迁,都会在各种气候环境演化的替代性指标上有所反映。4项指标Hurst指数的差异可能反映FeO容易迁移,受到了流域水系变化的影响,因而有机碳和Fe2O3可能是反映这种环境演化持续性分更好的指标。     

近1800年来云南洱海流域气候变化与人类活动的湖泊沉积记录

对云南洱海湖泊岩芯沉积物进行了多环境指标（年代学、色素、硅藻、有机碳稳定同位素、磁化率、化学元素）的分析,建立了近１８００年来云南洱海流域气候与环境变化的序列,气候演化具有暖干、冷湿交替的组合呈些特征气候阶段如中世纪温暖期、小冰期气候特征在洱海源泊沉积记录中均有反映,洱海湖泊上沉积记录的气候暖干－冷湿交替变化规律,反映了西南委风影响下的气候演化特征,湖泊沉积记录中包含丰富的人类以的信息,磁化率,元     

Environmental changes reflected by the lake sediments of the South Hongshan Lake, Northwest Tibet

The 1.07-m long lake core with 1 cm interval cutting, which was obtained by drilling in the South Hongshan Lake of Northwest Tibet, was dated by the 210Pb and 137Cs methods, and a 150-year consecutive lake sedimentary sequence (1840─1997) with 1.4 year resolution was obtained. Some environmental proxies, such as the total organic carbon (TOC), total nitrogen (TN), ratio of TOC to TN (TOC/TN), trace chemistry elements (TCE), CaCO3, grain size, richness of ostracoda etc. showed that they are of well coincidence. These results implied that the environmental background varied from the cold-wet period in the late 19th century, to the warm-wet period from the end of the 19th century to the 1920s and to the warm-dry period since the 1920s. There were sub-variations since the 1920s: the cold-dry/warm-wet fluctuation from 1922 to 1960, the intensively warm-dry period since 1960 with a short cold-wet period in the mid-1970s to the end of the 1980s. The humid period from the mid-1970s to the end of the 1970s and the dry period beginning from the early 1980s were well documented by climatic data of the nearby weather station records while the grain size was well correlated to the annual precipitation. Compared with the records from Guliya ice core in the same area, the TOC proxy in the lake core indicating warm/cold conditions well corresponded to the ( 18O records representing temperature variations in the ice core. However, the proxies with dry/wet significance in the lake core were different from the variations of snow accumulation reflected by the ice core. It can be concluded that the chosen environmental proxies have clear environmental significance and the lake sediments can reflect climatic and environmental changes at high-resolution.     

亚热带山地垂直地带土壤的磁性特征及其环境响应

土壤中磁性矿物的形成转化对环境变化具有指示意义,定量分析土壤磁性对环境因子的响应机制是目前该领域的重要问题.本文综合相关研究及野外实地考察,采集福建南部亚热带地区戴云山垂直地带相同母质的土壤剖面进行环境磁学和漫反射光谱测试分析.结果表明：研究区土壤剖面中磁铁矿和磁赤铁矿主导其磁性变化,当海拔至1320 m以上,土壤中出现次生纤铁矿.当排除地形的影响后,相关磁学参数指示磁畴颗粒在低海拔区域以SP颗粒为主,而较高海拔区域土壤中以粗SD颗粒为主.漫反射光谱结果表明,研究区土壤中赤铁矿和针铁矿对气候梯度变化较为敏感,其中赤铁矿含量随海拔增加显示出降低趋势,并且至海拔1320 m以上赤铁矿消失而主要以针铁矿和纤铁矿为主.对比加热前后针铁矿和赤铁矿特征峰变化,并进行半定量分析认为,当年均降水量超过1900 mm且年均温低于13℃时达到赤铁矿形成的临界值,而针铁矿和纤铁矿则继续呈增加趋势.本研究论证了赤铁矿、针铁矿及纤铁矿对气候梯度具较强的敏感性,可作为研究低纬区域古环境变化的重要指标.     

The distribution of Kendall's tau for testing the significance of cross-correlation in persistent data

Abstract

Kendall's tau (τ) has been widely used as a distribution-free measure of cross-correlation between two variables. It has been previously shown that persistence in the two involved variables results in the inflation of the variance of τ. In this paper, the full null distribution of Kendall's τ for persistent data with multivariate Gaussian dependence is derived, and an approximation to the full distribution is proposed. The effect of the deviation from the multivariate Gaussian dependence model on the distribution of τ is also investigated. As a demonstration, the temporal consistency and field significance of the cross-correlation between the North Hemisphere (NH) temperature time series in the period 1850–1995 and a set of 784 NH tree-ring width (TRW) proxies in addition to 105 NH tree-ring maximum latewood density (MXD) proxies are studied. When persistence is ignored, the original Mann-Kendall test gives temporally inconsistent results between the early half (1850–1922) and the late half (1923–1995) of the record. These temporal inconsistencies are largely eliminated when persistence is accounted for, indicating the spuriousness of a large portion of the identified cross-correlations. Furthermore, the use of the modified test in combination with a field significance test that is robust to spatial correlation indicates the absence of field significant cross-correlation in both halves of the record. These results have serious implications for the use of tree-ring data as temperature proxies, and emphasize the importance of utilizing the correct distribution of Kendall's τ in order to avoid the overestimation of the significance of cross-correlation between data that exhibit significant persistence.

Citation Hamed, K. H. (2011) The distribution of Kendall's tau for testing the significance of cross-correlation in persistent data. Hydrol. Sci. J. 56(5), 841–853.     

湖泊沉积有机碳同位素与环境变化的研究进展

湖泊沉积有机质稳定碳同位素（δ^13Corg)在区域气候与环境变化方面的应用近年来发展迅速,成果令人瞩目,保存在各类湖泊岩芯中的δ^13Corg记录揭示了晚更新世以来大气CO2浓度的变化、湖泊水位波动、湖区生态与植被的变迁以及气温变化等重要环境信息,由于造成δ^13Corg值变化的影响因素较多,确定个湖与环境变化有关的主导因素时常有赖于其它证据的帮助,诸如地球化学、古湖沼学、孢粉学、分子同位素地层学等等,前人通过研究来自不同类型湖泊、具不同曲线形态特征的δ^13Corg记录,提出了多种环境解释模型,本文对此作了归纳和评述。鉴别和澄清湖泊沉积有机质的源物质以及有机物源随环境变化而发生过的变化,是研究δ^13Corg记录环境意义至关重要的基础性工作,由于有机质含量、碳氮比值、氢指数、生物残留物鉴别等常能提供有关有关湖泊有机质来源、产率、成岩作用等方面的有用信息,这方面的研究结果应该尽可能一并提供,以利于恰当地应用现有的环境解释模型,或者建立个湖新模型,单体生物标志化合物鉴别通常也能为区分湖积有机质中陆生、水生、细菌生等不同碳的来源提供有用信息,特定化合物同位素分析技术近年来成功地应用于建立单体生物标志化合物碳同位素地层学,为湖积有机碳同位素在生态环境演变研究方面的应用提供了思路,我国许多湖泊的湖底沉积岩芯尚未钻取,那些对过去全球变化研究有价值的δ^13Corg记录有待我们去获取和研究。     

巢湖柱状沉积物中甘油二烷基甘油四醚脂(GDGTs)的组成特征

甘油二烷基甘油四醚脂(GDGTs)是目前生物地球化学研究的热点之一.与GDGTs有关的指标已成功地应用在海洋环境中有关来源判识和古环境古气候重建的研究,但是在湖泊环境中的应用目前还比较有限.通过开展巢湖柱状沉积物中GDGTs的组成测定,为GDGTs类脂分子标志物在湖泊系统中的应用提供依据.研究表明由柱状沉积物中支链GDGTs参数计算得到的量化结果与巢湖周围流域的环境温度、pH等历史记录能较好地吻合;柱状沉积物中类异戊二烯类GDGTs来源的不确定性可能是造成TEX_(86)指标的量化结果和实际的水体温度出现较大偏差的重要原因.另外,沉积物中GDGTs指标和TOC、C/N、δ~(13)C_(org)、δ~(15)N等传统湖泊总体有机质参数以及其它分子标志物指标相比,具有高分辨性和抗干扰等特点.因此,湖泊中GDGTs有望成为湖泊古气候和古环境重建的重要指标.     

Holocene climate forcings and lacustrine regime shifts in the Indian summer monsoon realm

Extreme climate events have been identified both in meteorological and long-term proxy records from the Indian summer monsoon (ISM) realm. However, the potential of palaeoclimate data for understanding mechanisms triggering climate extremes over long time scales has not been fully exploited. A distinction between proxies indicating climate change, environment, and ecosystem shift is crucial for enabling a comparison with forcing mechanisms (e.g. El-Niño Southern Oscillation). In this study we decouple these factors using data analysis techniques [multiplex recurrence network (MRN) and principal component analyses (PCA)] on multiproxy data from two lakes located in different climate regions – Lonar Lake (ISM dominated) and the high-altitude Tso Moriri Lake (ISM and westerlies influenced). Our results indicate that (i) MRN analysis, an indicator of changing environmental conditions, is associated with droughts in regions with a single climate driver but provides ambiguous results in regions with multiple climate/environmental drivers; (ii) the lacustrine ecosystem was ‘less sensitive’ to forcings during the early Holocene wetter periods; (iii) archives in climate zones with a single climate driver were most sensitive to regime shifts; (iv) data analyses are successful in identifying the timing of onset of climate change, and distinguishing between extrinsic and intrinsic (lacustrine) regime shifts by comparison with forcing mechanisms. Our results enable development of conceptual models to explain links between forcings and regional climate change that can be tested in climate models to provide an improved understanding of the ISM dynamics and their impact on ecosystems. © 2020 John Wiley & Sons, Ltd.     

Reconstructing the iron cycle from the horizontal distribution of metals in the sediment of Baldeggersee

In Baldeggersee, the distributions of solid phase Fe, Mn, V, Cr, As and Mo were determined in different sediment strata, deposited under various deep-water oxygen conditions. Iron concentrations are correlated with water depth when an anoxic sediment is in contact with an oxic water column. Benthic redox gradients trigger iron transport towards the deepest site (geochemical focusing) and loss of iron from the shallower parts through the outflow. Fe cycling in the lake is inhibited by oxygen penetration into the sediment. Vanadium and arsenic can be used as tracers for the internal Fe cycle. Their distribution patterns are highly correlated with iron. In case of a stable oxycline in the deep water, Mo is enriched in the sediment and correlates with Mn. The horizontal distribution patterns of Fe, V, As and the correlation of Fe and Mn with trace metals are promising proxy indicators for the reconstruction of deep-water oxygen conditions during deposition.     

Evaluating proxies for estimating subaerial beach volume change across increasing time scales and various morphologies

Proxies, such as changes in beach profiles and shoreline positions, are commonly used in management and research for estimating changes in subaerial beach volume; however, the accuracy of these proxies across increasing time scales and complex morphologies is unclear. Volume changes associated with along‐beach morphologic variability may not be captured well by changes in profiles, while volume changes associated with across‐beach morphologic variability may not be captured well by measuring shoreline change. This study assesses the impacts of morphologic variations, associated with beach cusps and nourishment material, on volume change estimates from profiles and shoreline change at 0.5 to 3.5 year time periods. Results indicate that profiles spaced ≥ 150 m apart and the shoreline‐change proxy will likely estimate volume change inaccurately over periods ≤ 1 year at beaches that are consistently eroding or accreting and contain cusps. However, over longer time periods (1–3.5 years), estimates of volume change from both proxies improved at those types of beaches. Volume changes at the edges of nourishment areas are not captured well by profiles. When the nourishment material is graded to a ramped morphology, which minimizes across‐beach morphologic variability, the shoreline‐change proxy does accurately estimate volume changes. Both proxies estimate volume changes inaccurately at beaches where volume changes oscillate between erosion and accretion on both short and long time scales because the magnitude of small‐scale changes in volume from the formation and erosion of morphologic features, such as cusps and berms, will always be similar to the longer‐term net volume change. This study suggests that decadal records of shoreline change, which are commonly developed using aerial photography, can be used to help identify the best proxy for estimating volume change; however, recent anthropogenic modifications that impact patterns of beach sedimentation, including nourishment, terminal groins, and inlet‐channel dredging, makes decadal records less useful. Copyright © 2013 John Wiley & Sons, Ltd.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

Coprecipitation of metal ions into calcite: an estimation of partition coefficients based on field investigation

Trace elements(and their isotopes) in carbonates are commonly used to reconstruct paleoenvironment and paleoclimate.Understanding the processes and mechanisms of element incorporation into carbonates is thus crucial for using such geochemical parameters as paleoclimate proxies.In contrast to laboratory-based experimental results,the partitioning of trace metals between solid and solution phases in natural carbonate precipitation systems has rarely been reported.In this study,we investigated the partition coefficients of metal ions between solid and solution in the channel of the natural Baishuitai travertine system,Yunnan,China.Our results show that the partition coefficients of Li~+,Na~+,Mg~(2+),Sr~(2+) and Ba~(2+)are 1,that of Ni~(2+) is approximately 1,and those of Co~(2+),Mn~(2+),Zn~(2+) and Cu~(2+) are 1,consistent with the results found in previous experimental studies.Although the substitution for Ca~(2+) is likely the main uptake process of these metals into calcite,depending on their ionic radius and charge,trace elements may also be incorporated by adsorption or physical entrapment.Our study shows that unlike laboratory experiments performed under specific conditions,the partitioning of metals between two phases in the natural travertine system could be controlled by several,even multiple,environmental factors(e.g.,carbonate deposition rate,temperature,and pH),which should be taken into account when using trace metals(and their isotopes) in carbonate archives as a paleoclimate proxy.     

Ocean tidal effects on Earth rotation

Tidal forces due to the tide-raising potential deform the solid and fluid regions of the Earth, causing the Earth's inertia tensor to change, and hence causing the Earth's rate of rotation and length-of-day to change. Because both the tide-raising potential and the solid Earth's elastic response to the tidal forces caused by this potential are well-known, accurate models for the effects of the elastic solid body tides on the Earth's rotation are available. However, models for the effect of the ocean tides on the Earth's rotation are more problematic because of the need to model the dynamic response of the oceans to the tidal forces. Hydrodynamic ocean tide models that have recently become available are evaluated here for their ability to account for long-period ocean tidal signals in length-of-day observations. Of the models tested here, the older altimetric data-constrained model of Kantha et al. (1998) is shown to still do the best job of accounting for ocean tidal effects in length-of-day, particularly at the fortnightly tidal frequency. The model currently recommended by the IERS is shown to do the worst job.     

Effect of hydrogen on the melting temperature of FeS at high pressure: Implications for the core of Ganymede

We have carried out in situ X-ray diffraction experiments on the FeS–H system up to 16.5 GPa and 1723 K using a Kawai-type multianvil high-pressure apparatus employing synchrotron X-ray radiation. Hydrogen was supplied to FeS from the thermal decomposition of LiAlH₄, and FeSH_x was formed at high pressures and temperatures. The melting temperature and phase relationships of FeSH_x were determined based on in situ powder X-ray diffraction data. The melting temperature of FeSH_x was reduced by 150–250 K comparing with that of pure FeS. The hydrogen concentration in FeSH_x was determined to be x = 0.2–0.4 just before melting occurred between 3.0 and 16.5 GPa. It is considered that sulfur is the major light element in the core of Ganymede, one of the Galilean satellites of Jupiter. Although the interior of Ganymede is differentiated today, the silicate rock and the iron alloy mixed with H₂O, and the iron alloy could react with H₂O (as ice or water) or the hydrous silicate before the differentiation occurred in an early period, resulting in a formation of iron hydride. Therefore, Ganymede's core may be composed of an Fe–S–H system. According to our results, hydrogen dissolved in Ganymede's core lowers the melting temperature of the core composition, and so today, the core could have solid FeSH_x inner core and liquid FeH_x–FeSH_x outer core and the present core temperature is considered to be relatively low.     

中国湖泊古生态研究进展

湖泊古生态学是古湖沼学的一个主要分支学科,主要通过沉积记录中的各种生物化石指标分析,重建不同时空尺度的湖泊生态系统演化过程,回答生态学、全球变化和环境管理应用方面的议题.本文回顾了国内外湖泊古生态研究的发展历程,在介绍湖泊古生态系列指标和研究基本原理基础上,着重评述了过去20 a来我国湖泊古生态研究取得的主要进展和成果,包括:(1)建立了基于多种生物和生物标记化合物指标进行古气候环境要素(温度、盐度、水体总磷等)定量重建的系列转换函数模型;(2)重点揭示了不同地质历史时期和近百年来湖泊生态环境演变的规律,及其对自然和人为驱动的响应特征与机理;(3)利用古生态记录诊断了湖泊生态系统突变模式与早期信号特征,定量揭示了湖泊生物群落演替与生态系统弹性损失的关系.上述成果为湖泊环境管理和治理提供了重要依据.本文最后对我国湖泊古生态研究进行了展望,提出了今后研究的重点方向.     

The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

湖泊水体微生物四醚膜脂化合物研究进展

来源于微生物膜脂的甘油二烷基甘油四醚类(GDGTs)化合物是近年来被广泛用于古环境定量重建研究的化合物之一,究其原因在于此类化合物对环境响应敏感,特别是温度与pH值等,据此而建立的一系列GDGTs指标有效定量重建海洋、湖泊、泥炭以及土壤等不同沉积载体的环境信息.目前已在全球范围广泛开展湖泊沉积物GDGTs的研究工作,相继建立的全球以及不同区域尺度的湖泊沉积物GDGTs校正方程,已被用于湖泊古环境的定量重建研究,有效记载古湖泊环境变迁信息.相较之下,基于湖泊水体GDGTs的调查工作则起步较晚,但越来越多的研究显示,不同类型湖泊水体普遍贡献GDGTs,然而究竟此类水生来源GDGTs是否与陆源以及湖泊沉积物GDGTs具有类似的分布,以及他们对环境因素的响应如何,这都为湖泊古温度定量重建研究带来不确定性.基于此,本文总结这10年来湖泊水体GDGTs研究工作的进展,首先阐述湖泊水体不同来源(古菌以及细菌)GDGTs的分布情况,研究发现水体不同层位GDGTs浓度以及各组分之间存在差异,并且水深在不同湖泊对GDGTs浓度以及各组分相对比例的影响存在差异.此外还总结湖泊水体中古菌来源isoGDGTs以及细菌来源brGDGTs的生物来源,并进一步分析环境因素对不同深度水体GDGTs分布的影响,虽然温度依然是影响水体中GDGTs分布的首要因素之一,然而湖泊水深、温度以及水体中溶解氧浓度等因素存在着一定的耦合关系,这些因素往往协同作用于水体GDGTs,因此会为评估环境因素对水体GDGTs的影响带来难度.     

Review of Abiotic Degradation of Chlorinated Solvents by Reactive Iron Minerals in Aquifers

Abiotic degradation of chlorinated solvents by reactive iron minerals such as iron sulfides, magnetite, green rust, and other Fe(II)‐containing minerals has been observed in both laboratory and field studies. These reactive iron minerals form under iron‐ and sulfate‐reducing conditions which are commonly found in permeable reactive barriers (PRBs), enhanced reductive dechlorination (ERD) treatment locations, landfills, and aquifers that are chemically reducing. The objective of this review is to synthesize current understanding of abiotic degradation of chlorinated solvents by reactive iron minerals, with special focus on how abiotic processes relate to groundwater remediation. Degradation of chlorinated solvents by reactive minerals can proceed through reductive elimination, hydrogenolysis, dehydrohalogenation, and hydrolysis reactions. Degradation products of abiotic reactions depend on degradation pathways and parent compounds. Some degradation products (e.g., acetylene) have the potential to serve as a signature product for demonstrating abiotic reactions. Laboratory and field studies show that various minerals have a range of reactivity toward chlorinated solvents. A general trend of mineral reactivity for degradation of chlorinated solvents can be approximated as follows: disordered FeS > FeS > Fe(0) > FeS₂ > sorbed Fe²⁺ > green rust = magnetite > biotite = vermiculite. Reaction kinetics are also influenced by factors such as pH, natural organic matter (NOM), coexisting metal ions, and sulfide concentration in the system. In practice, abiotic reactions can be engineered to stimulate reactive mineral formation for groundwater remediation. Under appropriate site geochemical conditions, abiotic reactions can occur naturally, and can be incorporated into remedial strategies such as monitored natural attenuation.