大兴安岭南段锡多金属成矿系列

大兴安岭南段是我国北方最重要的锡-多金属成矿集中区.根据成矿花岗岩和成矿元素组合的不同,可分为3个成矿系列:锡(钨)成矿系列(Sn-W-Nb-Ta-Be)、锡-多金属系列(Sn-Ag-Cu-Pb-Zn)和含锡的多金属系列(Pb-Zn-Cu-Ag),3个系列的成矿时代相同(130～150Ma),均与大兴安岭南段燕山期花岗质岩浆作用有关.与锡(钨)成矿系列有关的花岗岩,主要是钾长花岗岩-花岗斑岩,具有钛铁矿系列花岗岩的特征;与含锡的多金属系列有关的花岗岩,主要是花岗闪长岩-石英二长岩类,具有I型或磁铁矿系列花岗岩的特征;而当钾长花岗岩类与花岗闪长岩-二长斑岩等构成花岗质杂岩体或定位在相近空间时,常形成锡-多金属共生组合.研究表明,锡-多金属系列是与含锡的钛铁矿系列和含多金属的磁铁矿系列两种不同花岗岩类有关的含矿热液同位叠加成矿的结果.高成熟度、富锡的锡林浩特元古宙变质岩的重融-分异演化,可能是形成大兴安岭南段锡富集的主要原因.     

A Preliminary Study on Exhalative Mineralization in Permian Basins, the Southern Segment of the Da Hinggan Mountains, China – Case Studies of the Huanggang and Dajing Deposits–

Abstract: The southern segment of the Da Hinggan Mountains is a well‐known tin–polymetallic metallogenic belt of North China with Jurassic‐Cretaceous volcanic–plutonic rocks widespread. Principally because of this, most of the deposits are regarded as epigenetic hydrothermal deposits in genetic connection with the Mesozoic magmatism. But nearly 90 % of the deposits occur in Permian strata, and show concordant stratiform mineralization with a spatial distribution constrained by sedimentary facies of the Permian strata. A close association between mineralization and Permian strata is recognizable. The Huanggang Fe‐Sn deposit was regarded as a standard skarn‐type deposit formed by magmatic hydrothermal solutions in connection with Mesozoic granites. But there are abundant fabrics indicating submarine hydrothermal exhalation both in magnetite ores and in skarns, including bedding/lamination, soft–deformation, synsedimentary brecciation, and collo‐form fabrics. The magnetite orebodies and skarn‐bodies are predominantly concordant stratiform, and extend nearly 20 km along certain stratigraphic horizon, that is, the upper section of the Lower‐Permian submarine volcanic rocks. The Mesozoic granitic rocks crosscut the magnetite and skarn zone. Instead of skarnization, they show strong greisenization associated with cassiterite‐quartz veins, distinct from the magnetite skarn‐ore with disseminated tin in the Permian rocks. The Dajing Sn‐polymetallic deposit is generally regarded as subvolcanic‐hydrothermal origin, principally because of the close spatial association between ores and some of the Mesozoic subvolcanic dikes (called rhyolitic porphyry). Detailed geological, fabric, petrographical and mineralogical study demonstrates that this very kind of subvolcanic rocks is actually a new type of exhalites (called ‘siderite‐sericite chert’ according to its mineral assemblage), formed by hydrothermal sedimentation during the evolution of the Later‐Permian lacustrine basin. There are, however, indeed some rhyolitic porphyry dikes that crosscut orebod–ies. The orebodies and their associated exhalite predate, and thus have no genetic relation, to the Mesozoic magmatic process. We thus conclude that subaqueous exhalative mineralization did occur during the basin evolution at the Permian time in the southern segment of the Da Hinggan Mountains, which is ignored and poorly understood, but might be as important as the hydrothermal mineralization connected with the Mesozoic magmatism.     

内蒙古红岭铅锌多金属矿床地质特征

红岭(浩布高)铅锌多金属矿床位于我国大兴安岭南段主峰黄岗-甘珠尔庙成矿带的东北端。该地区成矿地质条件优越,是我国重点矿产勘查区之一。前人对红岭铅锌矿的矿床成因、成矿规律做了大量研究,但对基础地质特征研究不够深入,特别是对矿区主要赋矿围岩的岩石类型、矿区蚀变-矿化的类型及空间分布规律等方面的研究相对薄弱,制约了研究区矿床成因研究及勘察找矿的进展。本文通过详细的野外地质观察、室内岩矿相鉴定及扫描电镜/能谱(SEM/EDS)研究发现,矿区内出露的二叠纪地层除大理岩外,其余均为火山岩和火山碎屑岩,未见正常碎屑岩,与已有勘查资料认识不同,且在片理化二叠系晶屑凝灰岩中发现了由黄铜矿和闪锌矿组成的压力影,表明该区二叠系中可能发育同生的铜、锌矿化。矿区内除矽卡岩型矿化外还存在角砾岩型、热液脉型、碳酸盐交代型等多种矿化类型,为该区找矿提供了新思路。     

Geo–tectonic Position of Tin Polymetallic Mineralization Zone in the Southern Da Hinggan Mountains Area, Inner Mongolia, China: An Introduction to This Special Issue

Abstract: As a part of the main activities of Japan‐China technical cooperation project, a test survey area, approximately 5,000 km², was established for the implement of its geological and geochemical research program. A major mineralization zone called Huanggang–Ganzhuermiao–Wulanhaote Sn‐Cu polymetallic mineralization zone is recognized in the southern Da Hinggan Mountains area. The southern half of this zone is known as the sole Sn‐mineralization zone in North China. The survey area lies in this prominent zone. As the most of the papers presented in this issue have concerns to the geology and mineralization in this survey area, this report was prepared to introduce geo‐tectonic situation of the Sn‐Cu polymetallic mineralization zone in the Inner Mongolia orogenic belt. The belt is divided into four tectonic facies (from NW to SE); I: Wuliyasitai volcano‐plutonic zone, II: Hegenshan ophiolite mélange zone, III: Sunitezuoqi volcano‐plutonic zone, IV: Wenduermiao ophiolite mélange zone. The subject Sn‐Cu polymetallic mineralization zone is situated in the southeastern part of the Sunitezuoqi magmatic zone. About this Sunitezuoqi magmatic zone, three geo‐tectonic characteristics are pointed out. In late Carboniferous to early Permian period, subduction of Hegenshan oceanic crust occurred, which accelerated volcano‐plutonic activities and brought about basic to intermediate volcanic rocks of tholeiitic to calc‐alkaline series represented by Dashizhai Group in the Sunitezuoqi magmatic zone. Late Jurassic to early Cretaceous acidic rocks representing the most culminated volcanism and plutonism in Mesozoic era in the Da Hinggan Moutains area are distributed very extensively in and around the Sn‐Cu polymetallic mineralization zone. The Proterozoic metamorphic basement rocks called Xilinhaote complex are distributed close to the mineralized area in the Sunitezuoqi magmatic zone. Although the real mineralization was known associated with Mesozoic acidic to intermediate volcano‐plutonic activities, it is thought that the lower Permian Dashizhai volcanic rocks and pre‐Cambrian basement rocks might have played certain significant role in the process respectively of extraction of elements and formation of the magma favorable for such mineralization in the Sunitezuoqi magmatic zone. It would be necessary to give further considerations to these three geological units in relation to the Sn‐Cu polymetallic mineralization.     

Chronology of the Tungsten Deposits in Southern Jiangxi Province,and Episodes and Zonation of the Regional W‐Sn Mineralization – Evidence from High‐precision Zircon U‐Pb,Molybdenite Re‐Os and Muscovite Ar‐Ar Ages

Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP (sensitive high-resolution ion microprobe) zircon U-Pb, zircon LA-ICPMS (laser-ablation–inductively coupled plasma mass spectroscopy) U-Pb, molybdenite Re-Os isochron and muscovite Ar-Ar methods in southern Jiangxi Province and its adjacent areas. Based on these, the purpose of this paper is to study the petrogenetic and metallogenic ages and their time gap for different genetic types of W-Sn deposits, and thus to research their numerous episodes, zonal arrangement and their geodynamic background. The result shows that the large-scale W-Sn mineralization in southern Jiangxi Province occurred in the middle to late Jurassic (170–150 Ma), the skarn W-Sn-polymetallic deposits formed much earlier (170–161 Ma), and all of the wolframite – quartz vein type, greisen type, altered granite type and fractured zone type tungsten deposits formed in the late Jurassic (160–150 Ma). In one ore field or ore district, greisen type tungsten deposits formed earlier than quartz vein type ones hosted in the endo- or exo-contact zone; and quartz vein type hosted in the endocontact zone formed earlier than that of exocontact zone. There is no significant time difference between tungsten-tin mineralization and its intimately associated parent granite emplacement (1–6 Ma). They all formed in the same rock-forming and ore-forming system and under the same geodynamic setting. Regionally, rock-forming and ore-forming processes of the W-Sn deposits in the Nanling region (include southern Jiangxi Province, southern Hunan Province, northern Guangdong Province and eastern Guangxi Zhuang Autonomous Region) exhibit numerous episodes. The mineralization in the Nanling region mainly occurred at (240–210) Ma, (170–150) Ma and (130–90) Ma. The tungsten-tin deposits in this region are centered by the largest scale in southern Jiangxi Province and southern Hunan Province, and become small in the east, west, south and north directions. This displays a zonal arrangement and temporal and spatial distribution regularity. Integrated with the latest research results, it is concluded that the W-Sn mineralization in southern Jiangxi Province and its adjacent areas corresponds to the second large-scale mineralization in South China. The Indosinian W-Sn mineralization formed under the extensional tectonic regime between collisional compressional stages, while the Yanshanian large-scale petrogenetic and metallogenic processes occurred in the Jurassic intraplate extensional geodynamic setting of lithosphere extension.     

大兴安岭中南段典型银锡多金属矿床成矿条件与找矿潜力

大兴安岭中南段银锡多金属成矿带位于中亚造山带东部,近年来找矿成果丰硕。在对边家大院、拜仁达坝-维拉斯托、双尖子山3个银锡多金属矿床的成矿特征进行系统分析的基础上,探讨本区银锡多金属矿成矿条件与找矿潜力。结果显示,本区银锡多金属成矿与花岗质岩浆侵入密切相关,成岩与成矿具多期多阶段特征,主要发生于早白垩世,峰值为130~150 Ma。成矿岩体多具高硅、低镁、富碱的特征,形成于蒙古-鄂霍茨克洋和古太平洋两大构造体系叠加影响的伸展背景。银锡多金属成矿受地层-构造-岩浆岩三位一体联合控制,成矿条件优越,找矿潜力较大。在边家大院矿床西区的深部和外围以及北大山、磨盘山岩体的周边,有找寻锡多金属矿床的潜力。借鉴大兴安岭北段的找矿经验,应注重在本区中生代火山岩中找寻银铅锌多金属矿床。     

Magmatic‐Hydrothermal Mineralization Sequence in Xinlu Ore Field,Guangxi, South China: Constraints from Zircon U‐Pb,Molybdenite Re‐Os,and Muscovite Ar‐Ar Dating

The Xinlu Sn‐polymetallic ore field is located in the western Nanling Polymetallic Belt in northeastern Guangxi, South China, where a number of typical skarn‐, hydrothermal vein‐type tin deposits have developed. There are two types of Sn deposits: skarn‐type and sulfide‐quartz vein‐type. The tin mineralizations mainly occur on the south side of the Guposhan granitic complex pluton and within its outer contact zone. To constrain the Sn mineralization age and further understand its genetic links to the Guposhan granitic complex, a series of geochronological works has been conducted at the Liuheao deposit of the ore field using high‐precision zircon SHRIMP U‐Pb, molybdenite Re‐Os, and muscovite Ar‐Ar dating methods. The results show that the biotite‐monzogranite, which is part of the Xinlu intrusive unit of the Guposhan complex pluton, has a SHRIMP U‐Pb zircon age of 161.0 ± 1.5 Ma. The skarn‐type ore has a ⁴⁰Ar‐³⁹Ar muscovite plateau age of 160 ± 2 Ma (same as its isochron age), and the sulfide‐quartz vein‐type ore yields an Re‐Os molybdenite isochron age of 154.4 ± 3.5 Ma. The magmatic‐hydrothermal geochronological sequence demonstrated that the hydrothermal mineralization took place immediately following the emplacement of the monzogranite, with the skarn metasomatic mineralization stage predating the sulfide mineralization stage. Geochronologically, we have compared this ore field with 26 typical Sn deposits distributed along the Nanling Polymetallic Belt, leading to the suggestion of the magmatic‐metallogenic processes in the Xinlu ore field (ca. 161–154 Ma) as a component of the Early Yanshanian large‐scale Sn‐polymetallic mineralization event (peaked at 160–150 Ma) in the Nanling Range of South China. Petrogenesis of Sn‐producing granite and Sn‐polymetallic mineralization were probably caused by crust–mantle interaction as a result of significant lithospheric extension and thinning in South China in the Late Jurassic.     

大兴安岭中南段铜多金属矿床成矿系统

在区域地质背景分析和典型矿床研究的基础上,通过对大兴安岭中南段铜多金属矿床成矿地质特征的分析,阐明了该区铜多金属矿床的空间分布、容矿围岩、与成矿有关岩体和成矿时代,运用区域成矿学研究方法将该区铜多金属成矿初步划分为燕山期斑岩热液、印支—燕山期动力热液和晚华力西—燕山期热水喷流沉积叠加后期热液3个成矿系统。研究表明,本区应重视在侏罗世—白垩世火山岩区寻找大型铜多金属矿床,加强在已知矽卡岩型或热液脉型矿床的深部和外围寻找斑岩型矿床。     

沉积喷流型矿化的岩石学证据——以大兴安岭南段黄岗和大井矿床为例

沉积喷流型矿床往往有各种喷流岩（热水沉积岩）的共生，正确识别这些喷流岩经常能为认识矿床的成因提供关键证据。大兴安岭南段是我国北方著名的锡－多金属成矿区，燕山期火山－侵入岩广泛出露，因此认为区内矿床大都是与燕山期岩浆活动有关的热液矿床。但是，区内近90％的矿床却产在二叠纪地层中，显示了与二叠纪沉积地层的密切联系。本文以其中的黄岗铁－锡矿床和大井锡－多金属矿床为例，对与矿石密切共生的热水沉积岩开展了系统的地质学、岩相学、矿物学和组构学研究，并结合必要的地球化学数据，证明大兴安岭南段在二叠纪沉积盆地演化过程中可能普经有重要的水下热液沉积喷流成矿作用发生，尽管历来被人们所忽视，但其重要性可能并不亚于燕山期的岩浆热液成矿作用。黄岗矿床的层状矽卡岩与二叠纪海底火山活动关系密切，是一种很具特色的喷流岩；而被误认为是燕山期流纹斑岩的大井矿床菱铁织云硅质岩可能是一种产在陆相断陷盆地、与锡铜铅锌银多金属矿化有关的新类型热水沉积岩。显然，与热水沉积喷流矿床紧密共生的热水沉积岩是认识该类矿床至为重要的岩石学证据之一。     

大兴安岭中南段区域成矿规律初步研究

大兴安岭中南段是我国北方重要的铜多金属成矿集中区。文章对大兴安岭中南段的区域成矿地质背景、矿床时空分布规律、矿床分布与构造一岩浆活动及地层的关系、矿床类型等进行了系统的总结。将区内铜多金属矿床划分为5个成矿系列,对每一个成矿系列的成矿特征进行了简要归纳。最后,探讨了大兴安岭中南段的区域成矿作用。     

大兴安岭南段锡的成矿作用：以黄岗-甘珠尔庙地区为例

大兴安岭南段是我国重要的锡多金属成矿集中区,为促进区域锡多金属找矿突破,以在黄岗-甘珠尔庙地区多年的野外调查研究工作为基础,运用年代学测试、化学分析及地质模型等方法,分析了区域锡的成矿作用。认为二叠统基底地层及锡林郭勒杂岩是成矿物质的初始来源,经历的变质过程具有进一步富集的作用,大部分锡矿均遭受了多期次的火山-岩浆活动,最终决定锡多金属成矿的是燕山期酸性岩浆-热液成矿作用。同时成矿作用还受到控岩控矿构造、围岩性质、氧化-还原条件、开放-封闭环境的制约,认为在氧化性花岗岩浆侵入钙质地层条件下成矿作用以铁锡为主;还原性岩浆在侵入具开放性特征的围岩时,成矿作用以花岗岩外带围岩中的热液型脉状锡矿为主,而在侵入具封闭性特征的围岩时,成矿作用以花岗岩内带岩浆凸起部位的花岗岩型锡矿为主。因此,建议将主攻矿种由铅锌调整为锡银,部署重砂及化探方法圈定异常,针对硫化矿体部署电法,针对隐伏岩体部署磁法与重力,还可部署烃、汞、氧气测量等非常规化探方法预测隐伏岩体。     

云南水头山铅锌矿床闪锌矿Rb-Sr定年及其地质意义

水头山铅锌矿床位于保山地块南端芦子园矿集区,区内以发育矽卡岩型和热液脉型两类铅锌矿化为特点.为查明铅锌多金属成矿作用过程,本文对水头山热液脉型铅锌矿床主成矿阶段的闪锌矿开展了Rb-Sr同位素组成测定,获得闪锌矿的Rb-Sr等时线年龄为135.8±4.2Ma(MSWD=1.70,n=6),结合区内其他矿床的成矿年龄,认为...     

冈底斯复合造山带铜钼金多金属成矿作用与成矿系列

2001年以前西藏冈底斯斑岩铜钼多金属成矿带未列入国家重要成矿区带,而随后的成矿、找矿理论认识和方法创新,致使该带找矿取得历史性重大突破,新发现与评价了驱龙、甲玛、朱诺、雄村、努日、冲江、邦浦、蒙亚啊、洞中松多、查个勒等一系列大型-超大型矿床,仅探明的铜资源量就超过5 600万吨,形成了我国规模最大的世界级铜多金属勘查开发基地;新发现的矿床主要分布在南部拉萨地体及弧背断隆带,空间上的分布表现出东西成带、北东成行、交汇成矿、近等间距分布的规律性;同位素资料展示5期斑岩成矿作用(213 Ma、173~165 Ma、~45 Ma、~30 Ma、17~13 Ma)、5期矽卡岩成矿作用(~112 Ma、~77 Ma、67~55 Ma、~41~37 Ma、~23~16 Ma)及2期浅成低温热液成矿作用(~126 Ma、~65~55 Ma);伴随着新特提斯洋的形成、俯冲、消减及印-亚陆陆碰撞,冈底斯带经历了增生造山、碰撞造山、陆内造山及均衡造山四大造山作用过程,揭示了含矿岩浆来源于不同时期俯冲的玄武质洋壳——以幔源物质为主、或以古老地壳为主、或以新生下地壳为主的部分熔融,形成了与不同造山作用相关的斑岩型-矽卡岩型-浅成低温热液型-岩浆热液脉型-热泉型等单一类型、或斑岩-矽卡岩-浅成低温热液型等多种类型复合的一系列Cu-Mo-W-Ag-Sn-Au多金属矿床;复合造山过程中不同造山作用的叠加,使矿床展现出同源多位、同位多因、深源浅成、多因复成的成矿特征,并据此划分出晚三叠世与大陆弧岩浆有关的斑岩Cu-Au、中侏罗世与岛弧岩浆作用有关的斑岩Cu-Au、早白垩世与中酸性岩浆有关的矽卡岩-浅成低温热液型Fe-Ag-Pb-Zn(-Sn)、晚白垩世与中酸性侵入岩有关的Fe-Cu多金属、古新世-始新世与中酸性侵入岩有关的Fe-Cu多金属、古新世与陆相(次)火山岩有关的Ag-Sn-Au多金属、渐新世斑岩-矽卡岩型Cu-W-Mo(-Au)、中新世斑岩-矽卡岩-浅成低温热液型Cu-Mo-Au-Pb-Zn-Ag、新生代热泉型Au-S-Cs矿床及盐类矿床等9大成矿系列;最后指出该带有待今后进一步深入研究与探索的科学问题,并预测朱诺矿集区仍有发现大-超大型斑岩铜矿床的潜力,将会成为冈底斯成矿带未来找矿最能取得重大突破的地区,为该带下一步的勘查工作部署与评价指明了方向.      

内蒙古维拉斯托锡多金属矿流体包裹体特征

大兴安岭锡矿带是中国北方唯一成型的锡多金属成矿带。新近发现的内蒙古维拉斯托锡多金属矿床位于大兴安岭南段,隶属中亚造山带东段的兴蒙造山带。该矿床为一典型的大型斑岩型热液脉型锡多金属矿床,矿区内锡矿化主要赋存于石英斑岩体顶部及其上部的石英脉中。矿床成矿阶段包括石英斑岩体内的滴状锡锌矿化阶段、石英斑岩体上部石英脉中的辉钼矿矿化阶段、石英锡石黑钨矿阶段和石英多金属硫化物阶段。流体包裹体研究结果显示：流体包裹体类型主要为气液两相包裹体,尤其是富液相包裹体,其次为含子矿物的三相包裹体。斑岩体内矿化阶段流体包裹体均一温度为324~333 ℃,盐度为6.5%~7.5% NaCleqv,密度为0.73~0.74 g/cm3;石英脉型矿化阶段包裹体均一温度为201~324 ℃,盐度为3.4%~9.9% NaCleqv,密度为0.73~0.92 g/cm3。包裹体显微测温分析结果显示该矿区成矿流体具有中高温、低盐度、中密度的特征。激光拉曼光谱分析表明,气液两相包裹体液相成分主要为H2O,气相成分主要有H2O、CO2和CH4。氢氧同位素研究结果表明该矿床石英斑岩体上部石英脉矿化阶段的成矿流体为岩浆水和大气降水混合来源,以岩浆水为主。岩浆流体与大气降水的混合以及流体演化中的降温过程是该矿床矿石沉淀的主要机制。     

大兴安岭地区铜钼矿床成矿区带背景及找矿前景分析

本文根据区域构造背景和已知铜钼矿床的分布规律,将大兴安岭地区划分为西拉木伦河钼多金属、大兴安岭南段铜钼、大兴安岭北段铜钼和额尔古纳铜钼4个成矿带.归纳了研究区铜钼矿床的成因类型,主要有斑岩型、热液脉型、矽卡岩型等,并就各成因类型进行了典型矿床的举例.对研究区铜钼矿床的时空分布特征进行了总结,并按照典型矿床形成时间的先后...     

中国锡矿成矿规律概要

我国锡矿资源丰富,矿床类型比较齐全。在锡矿资源储量中占有较大比重的主要是锡石—硫化物型、矽卡岩型和石英脉型;从开采和利用角度来说,最为重要的是锡石—硫化物型和石英脉型。锡石—硫化物型主要集中在桂北、滇东等地,矽卡岩型集中分布在南岭中段湘南等矿集区、石英脉型则主要集中在华南地区的闽西、赣中、粤北、湘南等地;成矿时代以中生代最为重要;成矿大地构造背景以造山运动之后的大陆环境为主,构造变动剧烈,深大断裂纵横交错,岩浆活动频繁,特别是与锡成矿作用关系密切的中生代花岗岩类非常发育,最具特色。本次在对全国873处锡矿矿产地资料进行系统梳理的基础上,深入总结了全国锡矿的成矿规律,厘定出20个以锡为主或锡较为重要的矿床成矿系列,认为锡石—硫化物型、矽卡岩(—云英岩型)、石英脉型和岩体型4类锡矿类型,应该作为重点预测类型,并划分出44个成锡带,提出了19个重要工作部署区,并编制了中国成锡带图、中国锡矿成矿规律图等系列图件,为潜力评价预测工作提供了理论依据。     

Sn, B and Pb-Zn Skarn, Vein and Disseminated Deposits in the East Sikhote–Alin, Russia

Abstract: Sn, B and Pb-Zn skarn, vein and disseminated deposits occur in the eastern part of Sikhote-Alin fold system associated with the late Cretaceous-earliest Paleogene volcano-plutonic complexes, which are products of a continental margin-type subduction along the East Sikhote-Alin belt. There are two metallogenic zones where the ore deposits are concentrated. The Taukha metallogenic zone combining B and Pb-Zn skarn, vein and disseminated deposits occurs on the main volcanic chain along the Japan Sea coast. Late Cretaceous-earliest Paleogene calc-alkaline plutonic and volcanic rocks of magnetite series predominate here. Volcanic rocks overlie on the lower Cretaceous Taukha terrane which consists of abundant olistostromes with numerous olistoliths of Triassic limestones. During the middle-late Cretaceous time, an ignimbrite erupted and formed a huge borosilicate skarn deposit. A later subduction related volcanism of the late Cretaceous-earliest Paleogene stage (70–55 Ma) was predominated by andesites and rhyodacites. Many Pb-Zn skarn and vein deposits were formed. Sulfur isotope compositions of galena in the B and Pb-Zn deposits of the Taukha metallogenic zone vary from –1. 3 to +2. 0%, averaging 0% in the δ³⁴S.     

大兴安岭南段锡多金属矿床成矿规律与矿床模型

大兴安岭南段是我国北方最重要的锡矿带,本文对其时空分布和成矿规律进行了系统总结,并提出了大兴安岭南段锡多金属矿深部动力学模型和矿床模型,旨在推动区域进一步锡银找矿工作。研究表明,锡多金属矿形成于伸展构造环境,具有明显的成群分布特点,空间上夹持在二连—贺根山、黄岗—甘珠尔庙和西拉木伦深大断裂带之间,矿化时代集中在150~130 Ma之间,但在个别大中型矿床中表现出多期成矿的特征。尽管锡矿化规模巨大,但目前揭露的高分异含矿花岗岩体并不多见,成矿作用可能与该区高的成矿元素背景值有关,但同时矿体下部可能存在隐伏高分异岩体。锡多金属成矿系统以锡铅锌银为主,鲜有共生或伴生钨矿化,不同阶段或类型矿化是深部岩浆房多期次出溶的不同或相同性质流体共同作用的结果,同时成矿流体与围岩的反应也会影响流体的组成和演化。岩浆流体出溶、地层活化萃取、地幔物质、大气降水、热卤水和变质热液共同参与了成矿作用,尤其是深部镁铁质岩浆底侵及脱气不仅为成矿提供了热源,同时也可能提供了大量的成矿元素和挥发组分。在成矿过程中,流体温压的下降、不同来源流体混合、超临界流体不混溶作用、流体多次沸腾和水岩反应等是金属元素超常富集的主要机制。     

浆液过渡态流体在矽卡岩型钨矿成矿过程中的作用——以湖南柿竹园钨锡多金属矿为例

湖南杮竹园是世界著名的大型矽卡岩型锡钨多金属矿床,产于千里山碱长花岗岩岩体南部接触带。矽卡岩中广泛发育网脉状碱交代脉和少量花岗岩脉、云英岩脉等各类脉体。碱交代脉主体由钾长石、萤石、少量石英、磁铁矿、黑钨矿、白钨矿及花岗岩构成,以往被统称为"云英岩脉"。其中早阶段碱交代脉中央发育花岗岩,边部为钾长石-萤石-黑钨矿,脉体两侧发育石榴子石透辉石矽卡岩化,对应矽卡岩阶段。晚阶段碱交代脉主要成分为钾长石、萤石,脉体及两侧出现大量阳起石、绿帘石、磁铁矿、白钨矿及辉钼矿、辉铋矿、自然铋等,对应退变质氧化物阶段。空间上,碱交代脉分布于矽卡岩和矽卡岩化大理岩中,不进入岩体。自花岗岩体→岩脉→碱交代脉→矽卡岩,Ca O、Ti O2、成矿元素W、Bi、Mo、Cu、Pb、Zn以及Sr、Ba等元素含量增高,显示出成矿元素向热液中富集,且岩浆和矽卡岩受到碳酸盐岩围岩的影响。碱交代脉的组构显示出其形成于富含成矿物质和挥发份流体的岩浆,其中广泛发育熔融包裹体和熔流包裹体,显示其浆液过渡态流体的成因性质。从岩浆晚期分异演化→热液阶段是连续演化的过程,块状云英岩和矽卡岩阶段,岩浆并未完全固结,成矿作用自岩浆固结之前已经开始。总结了杮竹园矿床成矿模型:碱长花岗岩岩浆演化晚期分异出的高度富含挥发份的熔浆,在岩体顶部聚集,部分形成似伟晶岩(壳)和块状云英岩以及条带状硅灰石符山石矽卡岩。进一步聚集以及矽卡岩化产生大量CO2引起大规模隐爆,富含挥发份的岩浆或浆液过渡态流体沿隐爆形成的碎裂裂隙进入碳酸盐岩围岩,与碳酸盐岩不断发生反应,在脉体边部形成钾长石化以及大范围的石榴子石透辉石矽卡岩化。至退变质氧化物阶段,随着岩浆冷凝和温度、压力的降低,地下水大范围参与,成矿流体逐渐转变为热液性质,形成大量阳起石、磁铁矿、白钨矿及钼、铋硫化物。硫化物阶段,大量的大气降水参与成矿,温度、盐度进一步降低,在矽卡岩及其外侧的碳酸盐岩中形成铅锌硫化物矿石。     

湘南黄沙坪多金属矿床花岗质岩浆性质及演化对成矿差异的约束

黄沙坪矿床是湘南地区最大的铅锌矿床,除铅、锌外,可供开采利用的矿种还包括钨、锡、钼、铜、铁、硫等。矿区内岩浆作用复杂、成矿元素多样、矿化类型丰富,是研究湘南地区斑岩-矽卡岩-热液脉型Cu多金属与矽卡岩W-Sn多金属复合成矿作用的理想对象。为查明矿区Cu多金属与W多金属复合成矿机理,本文在已有研究的基础上,从岩石学、矿物学及元素地球化学等方面分别对区内石英斑岩和花岗斑岩这两类成矿岩体开展了系统研究。结果表明,两类岩体具有相似的源区特征,但在源区性质及其演化过程方面仍存在差异:石英斑岩侵位深度更浅,具有相对较高的氧逸度和较低的形成温度;而花岗斑岩则侵位相对更深,具有更高的形成温度和极高的分异演化程度、更低的氧逸度。这些地球化学特征差异可能是制约石英斑岩成铜矿而花岗斑岩成钨矿的重要原因。