浙江长兴煤山二叠-三叠系界线层牙形石序列及其全球对比

在详细研究全球二叠－三叠系界线层候选剖面───中国浙江长兴煤山剖面Ｐ／Ｔ界线层牙形石动物群序列基础上，自下而上识别出４个牙形石带：（１）ＣｌａｒｋｉｎａｃｈａｎｇｘｉｎｇｅｎｓｉｓＣｌａｒｋｉｎａｄｅｆｌｅｃｔａ带；（２）Ｉｓａｒｃｉｃｅｌｌａｐａｒｖａ带；（３）Ｉｓａｒｃｉｃｅｌｌａｉｓａｒｃｉｃａ带；（４）ＣｌａｒｋｉｎａｃａｒｉｎａｔａＣｌａｒｋｉｎａｐｌａｎａｔａ带，并在第一带中划分出３个动物群，从下向上是：ＣｌａｒｋｉｎａｃｈａｎｇｚｉｎｇｅｎｓｉｓＣｌａｒｋｉｎａｄｅｆｌｅｃｔａ－Ｃｌａｒｋｉｎａｓｕｂｃａｒｉｎａｔａ动物群，Ｈｉｎｄｅｏｄｕｓｌａｔｉｄｅｎｔａｔｕｓ－Ｃｌａｒｋｉｎａｍｅｉｓｈａｎｅｎｓｉｓｓｐ．ｎｏｖ．动物群和Ｈｉｎｄｅｏｄｕｓｔｙｐｉｃａｌｉｓ动物群，煤山剖面二叠、三叠系界线层牙形石序列的建立、完善，对确立该剖面在全球二叠、三在系界线高精度对比中的标准地位具重要意义。     

二叠-三叠纪之交牙形石生态新模式

通过对浙江长兴煤山剖面二叠－三叠系界线层沉积相分析及牙形石演化规律研究,提出了该时期Ｃｌａｒｋｉｎａ（Ｎｅｏｇｏｎｄｏｌｅｌａ）,Ｈｉｎｄｅｏｄｕｓ两类重要牙形石属的生态新模式．（１）Ｃｌａｒｋｉｎａ是一种底栖自由游泳生物,可出现于远岸浅海至盆地相较深水环境;（２）Ｈｉｎｄｅｏｄｕｓ是一种洋面浮游型生物,死亡之后可沉于海底的滨、浅海至深水盆地各种环境之中,并可渡过二叠－三叠纪之交海底缺氧事件这一难关,在早三叠世得到发展;因此,Ｈｉｎｄｅｏｄｕｓ可作为全球二叠－三叠系界线划分对比的可靠证据．     

华南二叠－三叠系的事件地层与生物地层界线

华南二叠－三叠系界线研究应严格区分事件地层界线与生物地层界线。“界线粘土”层的底界即为事件地层界线。生物地层界线定义不能与“混生层”或“过渡层”的概念连在一起。长兴煤山忠心大队剖面是最好的二叠－三叠系全球界线层型剖面点（ＧＳＳＰ）。二叠－三叠系生物地层界线定义为ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,其位置就在长兴剖面界线层（混生层）２的内部,比事件地层界线高１５ｃｍ。ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,即为长兴阶的顶界。     

华南二叠－三叠系的事件地层与生物地层界线

华南二叠－三叠系界线研究应严格区分事件地层界线与生物地层界线。“界线粘土”层的底界即为事件地层界线。生物地层界线定义不能与“混生层”或“过渡层”的概念连在一起。长兴煤山忠心大队剖面是最好的二叠－三叠系全球界线层型剖面点（ＧＳＳＰ）。二叠－三叠系生物地层界线定义为ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,其位置就在长兴剖面界线层（混生层）２的内部,比事件地层界线高１５ｃｍ。ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,即为长兴阶的顶界。     

浙江长兴煤山二叠-三叠系混生层1中微球粒的发现及其意义

<正> 浙江长兴煤山是中国南部上二叠统长兴阶和二叠、三叠系界线层型剖面(共A,B,C,D,E,Z六条剖面)的所在地。孙亦因等(1984)在D剖面的界线粘土及其上覆的灰黑色泥岩中发现铱异常,提出了二叠、三叠纪交替时可能发生了一次地外来的陨击事件。然而,人们更关心的似乎是作为铱异常物质来源最可靠证据的宇宙尘或微玻陨石是否也存     

浙江长兴煤山二叠—三叠系界线年龄测定

本文报道了用高灵敏度高分辨率离子探针,测定的浙江长兴煤山二叠—三叠系临界层位,斑脱岩中锆石的U-Pb年龄,结果为351.3±3.4Ma(2σ)。这是国际上首次直接从界线层位准确测定的二叠—三叠系界线的同位素年龄。长兴煤山二叠—三叠系界线剖面是迄今所发现的地层剖面连续,所含化石门类众多,数量丰富,且在临界层位夹有火山岩层的少有剖面之一,它不仅对国际显生宙地质年表的研究具有重要意义,而且也具有作为二叠—三叠系界线层型剖面的优越条件。     

陇南中─下三叠统磁性地层划分

根据古地磁测试资料尝试对甘肃南部宕昌县岷江剖面的中－下三叠统浊积岩系进行了磁性地层划分，认为该套地层应属二叠－三叠纪混合极性超时期间的产物，研究区当时的古纬度约为２０°Ｎ。     

浙江长兴地区二叠纪与三叠纪之交牙形石动物群及地层意义

本文把采自华南浙江长兴煤山二叠系与三叠系界线剖面的牙形石动物群从老至新分为三个带:1.Gondolella subcarinata-G·wangi组合带;2.G.changxingensis-G.deflecta组合带;3.Anchignathodus parvus带。将煤山剖面的二叠系与三叠系界线划在2、3组合带之间。并初步探讨了长兴地区长兴期至早格里斯巴赫期的牙形石分异度与沉积环境变迁。     

库车再生前陆逆冲带造山运动时间的厘定

库车再生前陆逆冲带自晚二叠世－三叠纪的前陆盆地演化阶段之后,侏罗纪－早第三纪进入了断陷盆地的伸展夷平阶段。始新世末印藏碰撞的远距离构造效应（郭令智等,１９９２）,至中新世碰撞的应力才传递到南天山古生代碰撞造山带,使晚二叠世－三叠纪曾经存在的Ａ型俯冲带再生活动,开始形成库车再生前陆逆冲带和前陆盆地（Ｌｕ等,１９９４）。库车再生前陆逆冲带分为７个构造带：①北部边缘冲断带;②东风背斜带;③北部背斜带;④拜城－阳霞向斜带;⑤南部背斜带;⑥西南雁列背斜带;⑦南缘剪切伸展构造带。对造山运动时间特征的认识是地…     

我国二叠—三叠系界线和事件研究的新进展

本文主要介绍了近几年来我国南方和北方海、陆相二叠—三叠纪地层及生物群研究的新进展。前者包括长兴阶的详细划分对比;混生生物群和岩相、地球化学的最新研究成果;界线粘土层中铱异常的发现及界线附近碳、氧同位素的变化等。后者包括甘肃地区晚二叠世甘肃兽和安哥拉植物群的发现;新疆二齿兽与水龙兽混生及北方广大地区二叠—三叠系孢粉系列的建立和对比等。提出浙江长兴煤山和四川华蓥邻水及广元上寺三条剖面可作为海相二叠—三叠系界线层型的候选剖面,新疆吉木萨尔大龙口剖面作为陆相二叠—三叠系界线层型候选剖面,高铱含量表明此时曾发生过重大事件。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.