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1.
Field observation showed that there are many irregular leucocratic intrusive rocks in pillow lavas in the Danfeng Group in the Xiaowangjian area, north Qinling orogenic belt. Photomicrographs indicated that the protoliths of those altered leucocratic intrusive rocks are dioritic rocks. Geochemical analyses showed that pillow lavas have a range of SiO2 from 47.35% to 51.20%, low abundance of TiO2 from 0.97% to 1.72%, and percentages of MgO (MgO#=41―49). Chondrite-normalized REE patterns of pillow lavas are even, indicative of a weak differentiation between LREE and HREE (La/YbN=1.52―0.99). N-MORB-normalized trace element abundances showed that pillow lavas are enriched in incompatible elements (e.g., K, Rb, and Ba). Leucocratic intrusive rocks in pillow lavas have a wide range of SiO2 from 53.85%―67.20%, low abundances of TiO2 from 0.51%―1.10%, and MgO (MgO#=40―51), and higher percentages of Al2O3 (13.32%―16.62%) and concentration of Sr (342-539 μg/g), ratios of Na2O/K2O (2―7) and Sr/Y (17―28). Chondrite-normalized REE patterns of leucocratic intrusive rocks showed highly differentiation between LREE and HREE (La/YbN=12.26―19.41). N-MORB-normalized trace element abundances showed that leucocratic intrusive rocks are enriched in incompatible elements (e.g., K, Rb, and Ba), and significantly depleted in HFSE (e.g., Nb, Ta, Zr and Ti), indicative of a relationship to subduction. Isotopically, leucocratic intrusive rocks have a similar εNd(t) ( 7.45― 13.14) to that of MORB ( 8.8― 9.7), which indicates that those leucocratic intrusive rocks sourced from depleted mantle most likely. SHRIMP U-Pb analyses for zircon showed that those leucocratic intrusive rocks were formed at 442±7 Ma, yielding an age of subduction in the early Paleozoic in the north Qinling orogenic belt.  相似文献   

2.
The Central Tianshan Tectonic Zone (CTTZ) is anarrow domain between an early Paleozoic southernTianshan passive continental margin and a late Paleo-zoic northern Tianshan arc zone, which is character-ized by the presence of numerous Precambrian meta-morphic basement blocks. Proterozoic granitoidgneisses and metamorphic sedimentary rocks,namely Xingxingxia and Kawabulag and Tianhugroups, are the most important lithological assem-blages in these metamorphic basement blocks, and alittle of …  相似文献   

3.
The protoliths of mafic-ultramafic plutons in the northern Dabie Mts. (NDM) (Hubei) include pyroxenite and gabbro. The zircon U-Pb dating for a gabbro suggests that emplacement of mafic magma took place in the post-collisional setting at the age of 122.9±0.6 Ma. It is difficult to obtain a reliable Sm-Nd isochron age, due to disequilibrium of the Sm-Nd isotopic system. Two hornblende40Ar/39Ar ages of 116.1±1.1 Ma and 106.6±0.8 Ma may record cooling of metamorphism in the mafic-ultramafic plutons in Hubei below 500°C. The hornblende40Ar/39Ar ages for the mafic-ultramafic rocks in Hubei are evidently 15–25 Ma younger than those for the same rocks in Anhui, indicating that there is a diversity of the cooling rates for the mafic-ultramafic rocks in Hubei and Anhui. The difference in their cooling rates may be controlled by the north-dipping normal faults in the NDM. The intense metamorphism occurring in the mafic-ultramafic rocks in Hubei may result from the Yanshanian magmatic reheating and thermal fluid action induced by the Cretaceous migmatization. The geochemical similarity of these mafic-ultramafic rocks wherever in Hubei and Anhui may be attributed to the same tectonic setting via an identical genetic mechanism.  相似文献   

4.
Migmatitic gneisses of overall intermediate composition occur at Vikan i Bø, North Norway. A Pb-Pb whole-rock isochron on these Vikan Gneisses yields an age of3,460 ± 70m.y. A Rb-Sr whole-rock isochron on the same rock samples yields an age of2,300 ± 150m.y., and an initial87Sr/86Sr ratio of0.7126 ± 0.0011.The geochemical implications of the discordance of the Pb-Pb and Rb-Sr whole-rock ages are discussed, and a timetable of the geological events in the early history of Lofoten-Vestera?len is proposed.  相似文献   

5.
The Tadhak alkaline ring-complex of Permian age provides two whole rock UPb isochrons giving concordant ages in agreement within relative errors with the RbSr isochron age:235U207Pb isochron: 271 ± 32Ma(MSWD= 0.3);238U206Pb isochron: 254 ± 18Ma(MSWD= 7.8), both on 8 whole-rock samples. The existence of these isochrons indicates that in favorable conditions U (and Pb) can be immobile. This can be due either to the lack of hard oxidizing conditions and/or to the location of U, in very low concentrations, in weathering-resistant minerals. The initial ratios (206Pb/204Pb = 18.714 ± 70and207Pb/204Pb = 15.589 ± 16), corrected for their Permian age, lie in the range observed for oceanic island basalts or continental alkali basalts and indicate an origin in a similar mantle, without any significant crustal contamination. This was also suggested by the initial87Sr/86Sr ratio of 0.70457 ± 4. Moreover, these Sr and Pb isotopic characteristics belong to the field of the so-called “Dupal” anomaly and indicate that it existed already 270 Ma ago. This study shows the potential interest of isotopic investigations of within-plate alkaline ring-complexes to characterize subcontinental mantle compositions, particularly in the past.  相似文献   

6.
On the basis of the geological field investigations and isotope geochronological studies the Sm-Nd isochron age (513 Ma±40 Ma), Rb-Sr isochron age (511 Ma±8 Ma) and K-Ar age (312-317 Ma) of the Dapingzhang spilite-keratophyre formation in Yunnan Province are presented. From these geochronological data it is evidenced that this suite of volcanic rocks was formed in the Cambrian and the parent magma was derived from a depleted mantle, which was influenced by crustal contamination and/or seawater hydrothermal alteration. During the Late Carboniferous the volcanic rocks experienced relatively strong geological reworking. This study provides geochronological evidence for the occurrence of Cambrian volcanic rocks in the Sanjiang (three-river) area.  相似文献   

7.
The Abitibi Volcanic Belt in eastern Superior Province of the Canadian Shield is the largest continuous greenstone belt in the world and is a key example of late Archean crust. This belt has, in general, suffered a low intensity of metamorphism and deformation, and, as a result, the stratigraphy and geology are well established. Tholeiitic and calc-alkaline series of igneous rocks are present in this belt in about equal proportions. However, the undersaturated potassic and leucitic volcanics of the Timiskaming Group are a unique feature of this belt.SmNd systematics were determined for twelve Timiskaming volcanic rocks. These rocks show nepheline, diopside and/or olivine plus leucite in the norm and a highly fractionated REE pattern. Sm and Nd concentrations range from 25 to 160 and 45 to 300 times the chondritic abundance, respectively. The Sm and Nd isotopic data yield an isochron age of 2702±105Ma for these volcanic rocks with an initial εNd of +1.9±1.6. This age establishes the Timiskaming alkalic rock to be one of the oldest of their kind. From stratigraphic relations, 2705 Ma is an upper limit for the age and the εNd values of +1.8 to +2.2 at this age for the twelve rocks are also upper limits. Further, this small but positive εNd value for the isochron, when compared to other mantle-derived Archean rocks in the Superior Province, indicates that the Archean mantle was heterogeneous beneath the Canadian Shield and that the Timiskaming alkalic lavas were derived from a depleted mantle.  相似文献   

8.
SmNd isotopic data indicate that differential REE mobility occurred on a whole-rock scale during transitional amphibolite- to granulite-facies regional metamorphism ( 700°C, 7 kbar) in early Archaean rocks ( 3930 Ma) of the Napier Complex of Enderby Land, Antarctica. The degree of mobility is independent of metamorphic grade but correlates directly with development of tectonic fabric. Whole-rock samples with D3-M3 internal fabrics lie along an array corresponding to an age of 2410 ± 100Ma, whereas samples preserving only earlier fabrics preserve an older, albeit imprecisely defined isochron age. In contrast to a widely held belief, such changes did not require the presence of a large hydrous fluid flux. If the mechanism responsible for SmNd resetting at this locality (where TCHUR ages range from 1990 Ma to 6090 Ma) is more widespread than is currently recognised, isolated SmNd model ages, particularly in complex terrains should be treated with caution.  相似文献   

9.
A whole rock U-Th-Pb study was carried out on eight granites from a suite previously dated at 177 ± 4my(λ = 1.39 × 10?11yr?1) by Rb-Sr methods. A U-Pb isochron was not obtained owing to recent leaching of U in the outcrop. Seven samples gave a Th-Pb isochron with age 184 ± 16my(λ = 4.99 × 10?11yr?1), (20/8Pb204Pb)0 = 39.2 ± 0.2 and MSWD 0.8. The eighth sample fell off the line and was rejected on geological grounds. Dissolving 5 g aliquots of the powdered rock markedly improved the reproducibility of U analyses but analysis of the variances suggests that inhomogeneities still might exist between duplicate dissolutions. Th-Pb geochronology needs further development to bring it to the level of precision of the Rb-Sr method.  相似文献   

10.
Granulites in the Dabie Mountains are mainly ob-served in northern Dabie complex zone. Huangtuling intermediate-acid granulites and Huilanshan mafic granulites in the Luotian dome are two famous out-crops (Fig. 1)[1]. It is important to know the genesis and metamorphic age of these granulites for under-standing tectonic evolution and exhumation history of the Dabie Mountains. Previous geochemical and geo-chronological work[2―8]1) on the Huangtuling granu-lites indicates that their protoli…  相似文献   

11.
Archean komatiites, high-Mg basalts and tholeiites from the North Star Basalt and the Mount Ada Basalt formations of the Talga-Talga Subgroup, Warrawoona Group, Pilbara Block, Western Australia, define a linear correlation on the normal143Nd/144Nd vs.147Sm/144Nd isochron plot. The data give an age of 3712 ± 98 Ma and initialεNd(T) of +1.64 ± 0.40. The 3712 ± 98 Ma date is consistent with the regional stratigraphic sequence and available age data and the SmNd linear array may be interpreted as an isochron giving the eruption age of the Talga-Talga Subgroup. An alternative interpretation is that the isochron represents a mixing line giving a pre-volcanism age for the Subgroup. Consideration of geochemical and isotopic data indicates that the true eruptive age of the Talga-Talga Subgroup is possibly closer to about 3500 Ma. Regardless of the age interpretation, the new Nd isotopic data support an existence of ancient LREE-depleted reservoirs in the early Archean mantle, and further suggest that source regions for the Pilbara volcanic rocks were isotopically heterogeneous, withεNd(T) values ranging from at least 0 to +4.0.  相似文献   

12.
Integrated zircon U-Pb dating and whole rock geochemical analyses have been carried out for two typical S-and I-type granitoids in the north Qinling. Zircon dating by SIMS of the Piaochi S-type grani- toids yields an emplacement age of 495±6 Ma. The granitoids show whole-rock εNd(t)=-8.2--8.8, zircon εHf(t)=-6―-39. The Huichizi I-type granitoids have emplacement ages of 421±27 Ma and 434±7 Ma es- tablished by LA-ICP-MS and SIMS methods, respectively. Their whole-rock εNd(t)=-0.9-0.9 and zircon εHf(t)=-11-8....  相似文献   

13.
From geology and geochemistry studies on four typical large-superlarge nonmetal deposits in eastern Zhejiang Province, it is concluded that nonmetal mineralization is an in situ reduction process in which SiO2 and Fe2O3 are lost, and Al2O3 and K2O are enriched. Moreover, incompatible elements are depleted in zeolite but enriched in alunite. Rb-Sr isotopic age of zeolite and K-Ar isotopic age or micro-area40Ar-39Ar isochron age of alunite are coincident with their geological data. respectively. Comparison studies of various chronology methods indicate that K-Ar and Rb-Sr methods are effective for zeolite and alunite, but should be carefully used for pyrophyllite, dekite and illite. From isotopic ages of ore and wall rocks of zeolite and alunite, it could be deduced that the age difference of metallogenism and volcanism is about 10–20 Ma.  相似文献   

14.
Rhyolites occur as a subordinate component of the basalt-dominated Eastern Snake River Plain volcanic field. The basalt-dominated volcanic field spatially overlaps and post-dates voluminous late Miocene to Pliocene rhyolites of the Yellowstone–Snake River Plain hotspot track. In some areas the basalt lavas are intruded, interlayered or overlain by ~15 km3 of cryptodomes, domes and flows of high-silica rhyolite. These post-hotspot rhyolites have distinctive A-type geochemical signatures including high whole-rock FeOtot/(FeOtot+MgO), high Rb/Sr, low Sr (0.5–10 ppm) and are either aphyric, or contain an anhydrous phenocryst assemblage of sodic sanidine ± plagioclase + quartz > fayalite + ferroaugite > magnetite > ilmenite + accessory zircon + apatite + chevkinite. Nd- and Sr-isotopic compositions overlap with coeval olivine tholeiites (ɛNd = −4 to −6; 87Sr/86Sri = 0.7080–0.7102) and contrast markedly with isotopically evolved Archean country rocks. In at least two cases, the rhyolite lavas occur as cogenetic parts of compositionally zoned (~55–75% SiO2) shield volcanoes. Both consist dominantly of intermediate composition lavas and have cumulative volumes of several 10’s of km3 each. They exhibit two distinct, systematic and continuous types of compositional trends: (1) At Cedar Butte (0.4 Ma) the volcanic rocks are characterized by prominent curvilinear patterns of whole-rock chemical covariation. Whole-rock compositions correlate systematically with changes in phenocryst compositions and assemblages. (2) At Unnamed Butte (1.4 Ma) the lavas are dominated by linear patterns of whole-rock chemical covariation, disequilibrium phenocryst assemblages, and magmatic enclaves. Intermediate compositions in this group resulted from variable amounts of mixing and hybridization of olivine tholeiite and rhyolite parent magmas. Interestingly, models of rhyolite genesis that involve large degrees of melting of Archean crust or previously consolidated mafic or silicic Tertiary intrusions do not produce observed ranges of Nd- and Sr-isotopes, extreme depletions in Sr-concentration, and cogenetic spectra of intermediate rock compositions for both groups. Instead, least-squares mass-balance, energy-constrained assimilation and fractional crystallization modeling, and mineral thermobarometry can explain rhyolite production by 77% low-pressure fractional crystallization of a basaltic trachyandesite parent magma (~55% SiO2), accompanied by minor (0.03–7%) assimilation of Archean upper crust. We present a physical model that links the rhyolites and parental intermediate magmas to primitive olivine tholeiite by fractional crystallization. Assimilation, recharge, mixing and fractional melting occur to limited degrees, but are not essential parts of the rhyolite formation process. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. This paper constitutes part of a special issue dedicated to Bill Bonnichsen on the petrogenesis and volcanology of anorogenic rhyolites.  相似文献   

15.
The Yushugou terrane of deepcrustal granulite facies in southern Tianshan consists of two parts, granulite and metaperidotite. The whole terrane is a metamorphism of (high-pressure) grunulite facies, and typical mineral associations are: Gt-Cpx-P1-Tit-Ilm (±Qz) (silica-saturated and oversaturated mafic rocks), Gt-Ky (pseudomorph)-P1-Ru-Ilm± Qz (metapelitic rocks) and Spi-Opx-Cpx-01 (meta-ultramafic rocks). The peak-stage P-T conditions are 795— 964°, 0.97—1.42 GPa, which are obtained with mineral chemistry, assemblage analyses and P-T estimation. The Sm-Nd isochron age of peak-stage metamorphic minerals is (315 ± 3.62) Ma. All of these indicate that the terrane is a deep-crustal body, which subducts to the depth of 40—50 km in the middle late-Paleozoic, undergoing metamorphism of (high-pressure) granulite facies, and exhumed again to the surface by tectonic uplifting. Project supported hy the National Natural Science Foundation of China (Grant No. 49472135).  相似文献   

16.
Geochemical and Pb-Sr-Nd isotopic compositions of five Indosinian granitoid intrusions from the western Qinling belt provide insights into basement nature and tectonic affinity. The results show that the western Qinling granitoids incline towards basic in their bulk chemical composition. The granitoids belong to high-K to shoshonitic series with K2O/Na2O=1.04-1.86 and are dominantly metaluminous with A/CNK=0.90-1.05 (most samples have A/CNK of <1.0). They have similar trace elemental compo- sitional patterns. In Sr-Nd isotopic compositions, they display some extent heterogeneity with Isr=0.70682-0.70845, εNd(t)=?4.85 to ?9.17 and TDM=1.26-1.66 Ga. They are characterized by high ra- diogenic Pb isotopic compositions. Their initial Pb isotopic ratios are 206Pb/204Pb=17.996-18.468, 207Pb/204Pb=15.565-15.677 and 208Pb/204Pb=38.082-38.587. Geochemical and Sr-Nd isotopic composi- tions reveal that magma for the granitoids was derived from partial melting of high-K (Rb) basaltic rocks, which might be formed in 900-1400 Ma. It is suggested that a large amount of the Proterozoic high-K (Rb) basaltic rocks, which underlie the Phanerozoic sedimentary cover, constitute the crustal basement of the western Qinling belt. Pb-Sr-Nd isotopic compositional comparison between the east- ern Qinling and the western Qinling Indosinian granitoids indicates that the crustal basement of the western Qinling is distinct from that of the eastern Qinling. The Baoji-Chengdu railway close to south-north orientation can be taken as an approximate boundary between both basements. The Pb-Nd isotopic compositional characteristics of the western Qinling granitoids suggest that the basement of the western Qinling belt has an affinity with the Yangtze block.  相似文献   

17.
Petrographic and chemical evidence suggests that boulders from a conglomeratic unit in the Isua supracrustal succession were derived by the erosion of an acid volcanogenic sediment. Six samples of the boulders and surrounding matrix yield a Rb-Sr whole rock isochron with a slope corresponding to an age of 3860 ± 240 m.y. (2 sigma error), but consideration of the initial87Sr/86Sr ratio constrains the possible age of formation of 3710 ± 900 m.y. This is in general agreement with a published Pb/Pb age of 3760 ± 70 m.y. on Isua banded ironstones.Pb isotope compositions as well as highly fractionated, heavy element depleted, rare earth element abundance patterns for the boulders suggest that their igneous precursors were derived from a source region with a similar geochemical history to that of some components of the 3700–3800 m.y. old Ami?tsoq gneisses, involving fractionation of garnet during their evolution.A Pb/Pb whole-rock isochron for Ami?tsoq gneisses from Isua yields an age of 3800 ± 120 m.y. (2σ), in good agreement with previously published Rb-Sr age data on the same rocks. The rock leads are highly unradiogenic and demonstrate substantial U depletion at least 3800 ± 120 m.y. ago. A two-stage model for the U-Pb system yields an average238U/204Pb (μ1) value of 9.3 ± 0.2 for the source region, which is significantly different from the published value of 9.9 ± 0.1 for the Isua iron formation. This indicates the existence of U-Pb heterogeneities between the source regions of plutonic and supracrustal rocks by about 3700–3800 m.y. ago. Attempts to apply U-Pb whole-rock dating to the Ami?tsoq gneisses were unsuccessful because of geologically recent U loss, possibly due to groundwater leaching.A Rb-Sr whole-rock isochron on a suite of Ami?tsoq gneiss samples from a different locality in the Isua region has yielded an age of 3780 ± 130 m.y.In contrast to the Godthaab area, there is no geochronological evidence at Isua for major rock-producing or tectonothermal events after about 3700 m.y. ago. The entire gneiss-supracrustal system developed within the approximate interval 3900–3700 m.y. ago.  相似文献   

18.
The Dongco ophiolite occurred in the middle-western segment of the Bangong-Nujiang suture zone. The thickness of the ophiolite suite is more than 5 km, which is composed, from bottom to top, of the mantle peridotite, mafic-ultramafic cumulates, basic sills (dykes) and basic lava and tectoni- cally emplaced in Jurassic strata (Mugagongru Group). The Dongco cumulates consist of dunite- troctolite-olivine-gabbro, being a part of DTG series of mafic-ultramafic cumulates. The basic lavas are characterized by being rich in alkali (Na2O K2O), TiO2, P2O5 and a LREE-rich type pattern dip- ping right with [La/Yb]=6.94―16.6 as well as a trace elements spider-diagram with normal anomaly of Th, Nb, Ta, Hf. Therefore, the Dongco basic lavas belong to ocean-island basalt (OIB) and dis- tinctly differ from mid-ocean ridge basalt (MORB) and island-arc basalt (IAB) formed in the plate convergence margin. The basic lavas have higher 87Sr/86Sr (0.704363―0.705007), lower 143Nd/144Nd (0.512708―0.512887) and εNd(t ) from 2.7― 5.8, indicating that they derive from a two-components mixing mantle source of depleted mantle (DM) and enriched mantle (EMI). From above it is ready to see that the Dongco ophiolite forms in oceanic island (OIB) where the mantle source is replaced by a large amount of enriched material, therefore it distinctly differs from these ophiolites formed in island-arc and mid-oecan ridge. Newly obtained SHRIMP U-Pb dating for zircon of the cumulate troctolite is 132 ± 3 Ma and whole-rock dating of ~(39)Ar/~(40)Ar for the basalt is 173.4 ± 2.7 Ma and 140.9 ± 2.8 Ma, indicating that the Dongco ophiolite formed at Early Cretaceous and the middle-western segment of the Bangong-Nujiang oceanic basin was still in the developing and evolving period at Early Cretaceous.  相似文献   

19.
Sm-Nd data for ten greenstone belt volcanics from Rhodesia define an age of2.64 ± 0.14AE, which is in agreement with other geochronological data and with observed field relationships. This age and the initial143Nd/144Nd ratio of0.50919 ± 0.00018 yield a time-integrated Sm/Nd ratio of0.302 ± 0.009 in the mantle source region, similar to that in chondrites. Sm/Nd ratios of some lavas are0.31 and imply that a small fraction of their source was removed prior to or as part of the main melting event.The utility of the Sm-Nd system for dating altered Archaean volcanic rocks is amply demonstrated by these data.  相似文献   

20.
The ~ 14 km diameter Jänisjärvi impact structure is located in Svecofennian Proterozoic terrain in the southeastern part of the Baltic shield, Karelia, Russia. Previous radioisotopic dating attempts gave K/Ar and 40Ar/39Ar ages of 700 ± 5 Ma and 698 ± 22 Ma, respectively, with both results being difficult to interpret. Recent paleomagnetic results have challenged these ages and proposed instead ages of either 500 Ma or 850–900 Ma. In order to better constrain the age of the Jänisjärvi impact structure, we present new 40Ar/39Ar data for the Jänisjärvi impact melt rock. We obtained five concordant isochron ages that yield a combined isochron age of 682 ± 4 Ma (2σ) with a MSWD of 1.2, P = 0.14, and 40Ar/36Ar intercept of 475 ± 3. We suggest that this date indicates the age of the impact and therefore can be used in conjunction with existing paleomagnetic results to define the position of the Baltica paleocontinent at that time. Argon isotopic results imply that melt homogenization was achieved at the hundred-micrometer scale certainly, because of the low-silica content of the molten target rock that allows fast 40Ar? diffusion in the melt. However, the large range of F(40Ar?inherited) (4.1% to 11.0%) observed for seven grains shows that complete isotopic homogenization was not reached at the centimeter and perhaps the millimeter scale. The F(40Ar?inherited) results are also in good agreement with previous Rb and Sr isotopic data.  相似文献   

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