江南造山带东部旌德高Sr/Y花岗闪长岩的形成机制及其构造意义

旌德岩体是江南造山带东部一个典型的高Sr/Y岩体。锆石的原位U-Pb定年表明,该岩体侵位于141±1Ma。岩体由花岗闪长岩和二长花岗岩组成。全岩地球化学表明,高的碱(K2O+Na2O=6.64%~8.01%),K2O/Na2O值(变化范围在0.78~1.04),Sr(189×10-6~452×10-6)和LREE;低的HREE和HFSE含量,Eu有轻微的负异常到弱的正异常(δEu=0.81~1.18)。岩体具有高的Sr/Y值(23~66)和(La/Yb)N值(13~58),低Y(6.03×10-6~14.5×10-6)、Yb(0.36×10-6~1.17×10-6),且MgO、Cr、Ni含量较低,与中国东部中生代埃达克质岩的地球化学特征相似。岩体中黑云母为镁质黑云母,显示寄主岩为壳幔混合来源。斜长石主要为奥长石、中长石。初始87Sr/86Sr为0.7096~0.7101,εNd(t)值为-12.92~-6.28,二阶段Nd模式年龄tDM2=1.4~1.9Ga。岩体中发育有岩浆混合成因的暗色包体,指示有幔源岩浆参与。结合前人研究成果,早白垩世,先前(新元古代)发生交代的岩石圈地幔发生部分熔融,岩浆底侵到壳幔过渡带附近,导致下地壳发生部分熔融形成了旌德岩体,且发生了岩浆混合作用。江南造山带东段上发育独特的150~135 Ma的岩浆活动和成矿作用,可能与江南造山带新元古代华夏陆块与扬子陆块发生拼合形成初生地壳物质的中生代再造有关。高Sr/Y比值的旌德岩体可能代表晚侏罗世—早白垩世挤压增厚事件的结束,指示了江南造山带东部从造山增厚向伸展垮塌的转折时期的岩浆活动。     

江南造山带东段旌德岩体锆石LA-ICPMS年龄和Nd-Sr-Hf同位素地球化学

提要：旌德花岗质杂岩体位于安徽南部,由花岗闪长岩和二长花岗岩组成。本研究得到岩体中锆石U-Pb年龄为(141.0±1.0) Ma,认为该年龄代表岩体的侵位年龄。岩体全岩主量元素特征显示出中偏酸性 (SiO2＝66.01%~70.87%),富Al (Al2O3＝14.91%~16.24%),富碱 (alk = 6.64%~8.01%),K2O/Na2O变化范围在0.78~1.04,镁、铁含量较低,MgO：0.68%~1.06%,TFe2O3 (2.0%~3.34%),以及低磷 (P2O5 =0.10%~0.14%)的特点;微量元素主要富集Sr (189×10-6~452×10-6),贫Nb、Ta、P、Ti、Y、Yb,高Sr/Y比值 (23~66)和 (La/Yb)N (13~58),Eu有轻微的负异常到弱的正异常 (δEu＝0.81~1.18)。旌德岩体的地球化学特征与中国东部中生代埃达克质岩相似。ISr＝0.7096~0.7101, εNd(t)＝-6.28~-7.32,εHf(t)值变化于-6.5~-1.1,两阶段模式年龄 tDM2=1.4~1.5 Ga。较年轻的Nd同位素模式年龄、较高的εNd(t)值和εHf(t)值,以及岩体中发育有岩浆混合成因的暗色包体,指示源区可能有地幔物质的贡献。幔源岩浆底侵使下地壳发生部分熔融,并发生了岩浆混合作用,形成了旌德岩体。     

内蒙古赤峰地区蒙古营子花岗闪长岩LA-ICP-MS锆石U-Pb 年龄及成因

赤峰蒙古营子岩体位于华北板块以北的兴蒙造山带南端,岩性主要为花岗闪长岩。其SiO2含量介于56.88%~68.82%之间,Na2O含量为4.32%~4.54%,K2O含量为2.3%~3.86%,且Na2O>K2O。里特曼指数σ=2.4~3.29,Al2O3含量介于15.1%~16.8%之间,A/CNK=0.81~0.92,属于高钾钙碱性I型花岗岩。富集轻稀土元素（LREE）、亏损重稀土元素（HREE）和高场强元素（HFSE）。Sr含量为782×10-6~1230×10-6,Y和Yb平均值分别为20.1×10-6和1.77×10-6,(La/Yb)N值为19.84~22.03,δEu=0.81~1.04,Eu异常不明显。岩体总体显示出C型埃达克岩的地球化学属性,暗示岩浆可能源于加厚的下地壳部分熔融。采用LA-ICP-MS 技术测得的锆石206Pb/238U年龄为252.8±2.4Ma,表明该岩体形成于古生代末期—早中生代。结合兴蒙造山带的构造演化历史,认为蒙古营子花岗闪长岩应为西伯利亚板块和华北板块后碰撞阶段的产物,具有幔源岩浆底侵诱发地壳生长的指示意义。     

松潘－甘孜南部玛孜措石英闪长岩的地球 化学特征、同位素年龄及其构造意义

玛孜措石英闪长岩体位于松潘 甘孜地体南部的甘孜地体内,地处鲜水河断裂带西南侧。岩体具高钾（3.53%~3.86%）、富钙（4.91%~6.07%）、贫铝（14.60%~15.24%）,铝饱和指数（A/CNK=0.80~0.89）偏低的特征,岩石稀土总量较低,轻稀土中度富集,δEu介于0.46~0.53之间,Eu中度亏损,岩石（87Sr/86Sr）i比值介于0.707407~0.707640,表明岩浆起源于壳 幔混熔或下地壳物质的部分熔融,属下地壳重熔的I型高钾钙碱性花岗岩系列。在微量元素构造环境判别图上,样品都落在岛弧区,反映了石英闪长岩具有与岛弧型花岗岩相似的地球化学性质。岩体具较高的Rb（60.1×10-6~85.9×10-6）、Cs（4.01×10-6~19.62×10-6）含量和K2O/Na2O比值（1.31~1.82）,反映源区可能与黑云母的脱水熔融有关。玛孜措石英闪长岩锆石SHRIMP U Pb年龄为221±2.0 Ma（MSWD=1.4）,显示岩体侵位时代为晚三叠世;而全岩Rb Sr等时线年龄为207.0±2.0 Ma（R=0.9979）,显示岩体就位时代为晚三叠世晚期。玛孜措岩体形成于晚三叠世弧后构造环境,是幔源岩浆的底侵作用导致壳-幔混熔的产物。     

南岭大东山花岗岩的形成时代与成因——SHRIMP锆石 U-Pb年龄、元素和Sr-Nd-Hf同位素地球化学

中国东南部南岭地区广泛出露以弱过铝质黑云母二长花岗岩和黑云母钾长花岗岩为主的燕山早期花岗质岩石,其成因有待进一步研究。大东山岩体岩性主要为黑云母二长花岗岩和黑云母钾长花岗岩,两个样品的SHRIMP锆石U-Pb 年龄为165±2 Ma 和159±2 Ma,与区域南岭系列的黑云母花岗岩的主要形成时代一致。花岗岩样品以高硅（SiO2 > 72%）、高钾（K2O/Na2O > 1.6）、富碱（K2O + Na2O = 7.36% ~ 9.31%）和弱过铝质（集中于ASI = 1.00 ~ 1.11）为特征。微量和稀土元素组成上,岩体富Rb, Th 和LREE,贫Ba, Nb, Sr, P 和Ti, Eu 负异常显著（δEu = 0.06 ~ 0.34）。多数样品的Zr,Ce, Nb 和Y 含量总和小于350×10-6,10 000 × Ga/Al 值低于典型的A 型花岗岩。同位素组成上,样品具有高I sr（ 0.7123 ~ 0.7193）和低εN（d t）（-9.3~ -11.5）的特点,两阶段Nd 模式年龄为1.70~1.89 Ga ;与全岩εNd（t）不同,岩浆锆石的εHf（t）具有较大的变化范围（-3.5~ -11.8）。矿物学及地球化学结果表明大东山是一个高分异的I 型花岗岩岩体。岩体岩浆很可能是由元古代火成岩石部分熔融形成,并伴随有少量年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生混合、结晶分异作用。     

湘东北早白垩世桃花山—小墨山花岗岩体岩石地球化学特征及成因

出露于湖南东北部华容县附近的桃花山—小墨山岩体侵位于中元古代冷家溪群。通过锆石LA-ICP-MS U-Pb法测得两岩体侵位时代分别为129 ± 1 Ma和117 ± 1 Ma。桃花山主体岩性为（片麻状）二云母二长花岗岩,SiO2 = 71.75%~73.81%,K2O/Na2O = 0.84~1.11,属弱过铝质高钾钙碱性系列;岩石明显富集大离子亲石元素,亏损高场强元素;Eu为中等负异常,ΣREE较高,Rb/Sr = 0.9~2.7,（La/Yb）N = 26.92~86.02;高ISr（0.714~0.723）,低εNd（-9.76~-10.6）, 高t2DM （1.72~1.79 Ga）。小墨山黑云母二长花岗岩SiO2 = 69.64%~72.73%,K2O/Na2O = 0.62~0.7,准铝质至弱过铝质,Rb/Sr = 0.26~0.88,（La/Yb）N =11.97~12.67;低ISr（ 0.707~0.709）,高εNd（-6.38~-6.73）,低t2DM （1.43~1.46 Ga）。综合分析表明,桃花山二云母二长花岗岩为壳源含白云母过铝花岗岩类（GPG）,源岩为华南古元古代基底;小墨山黑云母二长花岗岩类似含堇青石及富黑云母过铝花岗岩类（CPG）,源岩为低成熟度的变杂砂岩。桃花山、小墨山岩体形成于华南早白垩世伸展背景下的局部挤压增厚环境。江南断裂晚燕山期的逆冲推覆构造造成了华容地区的小范围地壳增厚,并为桃花山源岩的“湿”深熔作用提供了流体聚集通道;小墨山花岗岩的形成则与幔源岩浆的底侵有关,热的幔源岩浆不仅为地壳的部分熔融提供了热量,而且与熔融的壳源岩浆发生了混合作用。     

北秦岭西段早古生代埃达克岩地球化学特征及岩石成因

唐藏石英闪长岩体出露于北秦岭造山带西段,侵入于丹凤群火山沉积岩系之中,主要矿物组成为斜长石、角闪石、石英、钾长石、黑云母等,形成时代为454Ma。该岩体SiO2= 62.02％～64.26％;Al2O3=16.55%～17.45%,MgO=1.71%～2.09%, Sr = (1069～1296)×10-6（>400 ×10-6）,Y = (11.6～13.81)×10-6 （<18×10-6）,Yb = (0.96～1.14)×10-6（<1.9 ×10-6）,Sr/Y=80.98～108.19（>40）,稀土总量（∑REE=217.88×10-6～355.07×10-6）较高,LREE强烈富集,重稀土亏损,Eu负异常不明显（LREE/HREE=17.72~25.82;LaN/ YbN=44.56～53.85;δEu＝0.82～1.0）,显示出典型埃达克岩的岩石地球化学特点。在以原始地幔标准化的微量元素分布图中,大离子亲石元素（LILE）K、Th、Rb、Ba、Sr等富集,高场强元素(HFSE)Ta、Nb、Y、Yb等较相邻元素相对亏损,微量元素曲线分布形式及稀土元素配分模式与典型地区埃达克岩分布形式一致。研究表明,该岩体Na2O＝4.99%～6.91%, Na2O-2＞K2O,Mg#＝0.59～0.63, A/CNK=0.82～1.01,σ=4.24～2.24,为富钠偏铝质高镁埃达克岩。唐藏埃达克岩体岩浆源于早古生代秦岭商丹洋向北俯冲消减洋壳板片的部分熔融,岩浆在上升过程中与地幔楔发生反应。北秦岭早古生代埃达克岩的确定为探讨秦岭早古生代构造演化提供了新的证据。     

新疆东昆仑木孜塔格地区碎石沟花岗岩锆石 U-Pb年龄、岩石地球化学特征及地质意义

碎石沟花岗岩体位于东昆仑造山带西段木孜塔格地区,是该地区几个主要花岗岩体之一。为了查明该岩体的成因类型、物质来源及形成时代,并在此基础上进一步探讨木孜塔格地区的区域构造演化过程及东昆仑造山带地球动力学背景,对该岩体进行了详细的岩石学、地球化学及锆石U- Pb年代学研究。岩石学特征表明,碎石沟花岗岩主要由灰白色中细粒二长花岗岩组成,在岩体边部可见少量灰白色花岗闪长岩。岩石地球化学研究表明,该岩体具有高硅（SiO2=67.54 %~71.56 %）、高碱（Na2O=3.08%~4.50%、K2O=3.05%~4.20%）、富铝的特点（Al2O3=14.26%~16.58%）,属于准铝质—弱过铝质高钾钙碱性系列;稀土元素含量较高（126.31×10-6~160.13×10-6）,总体表现出轻稀土富集,重稀土亏损的右倾式配分模式,具有Eu的弱负异常（δEu=0.68~0.85）;微量元素相对富集Rb、Th、K等大离子亲石元素,亏损Nb、Ta、Hf、Sr等高场强元素,显示出 I 型花岗岩的特征。本次研究获得碎石沟岩体二长花岗岩的锆石U- Pb年龄为208.0±1.1 Ma（MSWD=1.0）,属于晚三叠世岩浆活动产物。结合区域构造演化特征,碎石沟花岗岩来源于下地壳物质部分熔融,并且在形成过程中存在幔源岩浆底侵及壳幔岩浆混合作用,其构造背景为后碰撞环境。     

川西龙门山彭灌杂岩地球化学特征:岩石成因与构造意义

对位于扬子地块西缘龙门山逆冲推覆构造带中的彭灌杂岩进行了岩石地球化学研究,重点讨论了岩石成因、成岩物质来源及其构造意义。彭灌杂岩为一新元古代侵入的杂岩体,主要由中酸性侵入岩组成,其地球化学特征表现为SiO2含量变化范围较大(57.70%~71.90%),Na2O>K2O(K2O/Na2O=0.31~0.85),里特曼指数δ=1.33~2.28,A/CNK=0.93~1.08,彭灌杂岩主体属于准铝质到弱过铝质的钙碱性花岗岩类;稀土总量不高(∑REE=76.25×10-6~139.80×10-6),轻重稀土分异程度差别较大(LaN/YbN=3.86~35.23),弱负到正Eu异常(δEu=0.70~1.86);富集大离子亲石元素(LILE)Rb、Sr、Ba、K等,亏损高场强元素(HFSE)Nb、Ta、P和Y。与正常壳源钙碱性花岗岩相比,彭灌杂岩显示出更高的Mg#值(多数>45)和Sr/Y比值(多数20.03~111.34)。通过与其毗邻的埃达克质雪隆包杂岩的比较,表明彭灌杂岩可能是底侵的幔源岩浆与下地壳熔融产物混合的结果。结合其它研究成果,认为扬子西缘新元古代大面积分布的岩浆岩形成于俯冲汇聚和火山弧构造环境。     

福建金山花岗质复式岩体的元素和同位素地球化学及其成因研究

金山复式岩体位于福建南部华安县和南靖县交界地区,为一燕山晚期的花岗质复式大岩基,由早白垩世早期的华安洋竹径单元（锆石U-Pb年龄为140.3±1.2Ma）和早白垩世晚期的南靖龙山单元（锆石U-Pb年龄为105.1±0.8Ma）组成。复式岩体东部的洋竹径单元主体岩性为中粒钾长花岗岩,在中心部位发育部分黑云母花岗岩,地球化学特征上,该单元岩石总体为弱过铝质（A/NKC值变化于1.00~1.05）,富硅,碱含量中等（K2O+Na2O介于8.30%~8.84%）,碱铝指数（AKI值）变化于0.80~0.90,富钾（K2O含量变化于4.59%~5.58%,K2O/Na2O比值介于1.18~1.95）,富轻稀土和大离子亲石元素（如Rh、Th等）,贫Ba、Sr、Ti、P,Rb/Sr比值高,具中到强的铕负异常。复式岩体西部的龙山单元主体岩性为黑云母二长花岗岩,与洋竹径单元相比,其硅、碱含量及Rb/Sr比值均相对偏低,轻重稀土比值更高,而铕负异常相对不明显。复式岩体各单元岩石的Ga/Al比值以及Zr、Nb、Ce、Y等高场强元素含量较之典型的A型花岗岩均偏低,综合地质地球化学资料指示该复式岩体应属高钾钙碱性I型花岗岩。洋竹径单元黑云母花岗岩和钾长花岗岩具有一致的Nd同位素组成,Nd(t)值分别为-1.13和-1.16~-1.94,表明它们具有相同的岩浆源区,二者应为同源岩浆经分异演化的产物。龙山单元的成岩年龄晚于洋竹径单元,Nd(t)值略低（＝-2.22）,其岩石学和元素地球化学特征与洋竹径单元存在较明显的差别,相关的元素演变趋势表明龙山单元不可能为洋竹径单元岩浆分异演化的产物,而应具独立的岩浆起源。金山复式岩体极可能是在弧后伸展背景下,由于持续的幔源岩浆底侵作用导致早期底侵物质（初生地壳）与古老基底地壳混合的地壳原岩叠次熔融复合的产物。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an     

PROSPECTING EXPLORATION

正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of