Particle size distribution of cataclastic fault materials from Southern California: A 3-D study

The particle size distributions of fault gouge from the San Andreas, the San Gabriel, and the Lopez Canyon faults in Southern California were measured using sieving and Coulter-Counter techniques over a range of particle sizes from 2 m to 16 mm. The distributions were found to be power law (fractal) for the smaller fragments and log-normal by mass for sizes near and above the peak size. The apparent fractal dimensionD of the smaller particles in gouge samples from the San Andreas fault, the San Gabriel fault and the Lopez Canyon gouge were 2.4–3.6, 2.6–2.9 and 2.4–3.0, respectively. The averageD for the Lopez Canyon gouge was 2.7±0.2, which is in agreement with earlier studies of this gouge using planar 2-D sections. The fractal dimension of the finer fragments from all three faults is observed to be correlated with the peak fragment size, with finer gouges tending to have a largerD. A computer automaton is used to show that this observation may be explained as resulting from a fragmentation process which has a grinding limit at which particle reduction stops.     

Origin of the fumarolic fluids of Vulcano Island,Italy and implications for volcanic surveillance

Variations in D and ¹⁸O values with H₂O contents and outlet temperatures indicate that the fumaroles of La Fossa crater have discharged mixtures of magmatic water and marine hydrothermal water, since 1979. The contribution of meteoric water was low in the period 1979–1982 and very low afterwards. The ¹⁸O values of the marine-hydrothermal component of +5 to +7.2 are due to isotopic exchange with the ¹⁸O-rich silicates of the rocks under high-temperature and low-permeability conditions. The ¹⁸O value of the magmatic end-member is generally +3.5 to +4.3, although values as high as +5.5 to +6.5 were reached in the summer of 1988, when magma degassing appears to have extended into the core of the magma body. The D values of the end-member were close to -20, typical of andesitic waters. Both the isotopic values and chemical data strongly support a dry model, consisting of a central magmatic gas column and a surrounding hydrothermal envelope, in which marine hydrothermal brines move along limited fracture zones to undergo total evaporation on approaching the conduits of magmatic fluids. The vents at the eastern and western boundaries of the fumarolic field are fed by fluids whose pressure is governed by the coexistence of vapor, liquid and halite, giving rise to a high risk of phreato magmatic explosions, should magma penetrate into these wet environments. Most La Fossa eruptions were triggered by an initial hydrothermal blast and continued with a series of phreatomagmatic explosions. The fluids discharged by the Forgia Vecchia fumaroles are mixed with meteoric water, which is largely evaporated, although subordinate loss of condensed steam may be responsible for scrubbing most of the acidic gas species. The temperatures and pressures, and the risk of a sudden pressure increase, are low. A boiling hydrothermal aquifer at 230° C is present underneath the Baia di Levante beach. This area has a minor risk of hydrothermal explosions.     

Addition of magmatic volatiles into the hot spring waters of loowit canyon,Mount St. Helens,Washington, USA

Geochemical studies on cold meteoric waters, post-1980 hot spring waters, fumarole emissions from the dacite dome, and volcanic rocks at Mount St. Helens (MSH) from 1985 to 1989 show that magmatic volatiles are involved in the formation of a new hydrothermal system. Hot spring waters are enriched in ¹⁸O by as much as 2 and display enrichments in D relative to cold waters. A well-defined isotopic trend is displayed by the isotopic composition of a>400°C fumarole condensate collected from the central crater in 1980 (-33 D, +6 ¹⁸O), of condensate samples collected on the dome, and of cold meteoric and hot spring waters. The trend indicates that mixing occurs between local meteoric water and magmatic water degassing from the dacite dome. Between 30 and 70% magmatic water is present in the dome fumarole discharges and 10% magnatic water has been added to the waters of the hydrothermal system. Relations between Cl, SO₄ and HCO₃ indicate that the hot spring waters are immature volcanic waters formed by reaction of rocks with waters generated by absorption of acidic volcanic fluids. In addition, the B/Cl ratios of the spring waters are similar to the B/Cl ratios of the fumarole condensates (0.02), values of ¹³C in the HCO₃ of the hot springs (-9.5 to-13.5) are similar to the magmatic value at MSH (-10.5), and the ³He/⁴He ratio, relative to air, in a hot spring water is 5.7, suggesting a magmatic origin for this component.managed by Martin Marietta Energy Systems, Inc., under contract DE-AC05-84OR21400 with the US Department of Energy     

Fluid infiltration into fault zones: Chemical,isotopic, and mechanical effects

Fluid infiltration into fault zones and their deeper-level counterparts, brittle-ductile shear zones, is examined in diverse tectonic environments. In the 2.7 Ga Abitibi greenstone belt, major tectonic discontinuities, with lateral extents of hundreds of kilometres initiated as listric normal faults accommodating rift extension and acted as sites for komatiite extrusion and locally intense metasomatism. During reverse motion on the structures, accommodating shortening of the belt, these transcrustal faults were utilised as a conduit for the ascent of trondhjemitic magmas from the base of the crust and of alkaline magmas from the asthenosphere and for the discharge of thousands of cubic kilometres of hydrothermal fluids. Such fluids were characterised by ¹⁸O=+6±2, D=–50±20, ¹³C=–4±4, and temperatures of 270 to 450°C, probably derived from devolatilisation of crustal rocks undergoing prograde metamorphism. Hydrothermal fluids were more radiogenic (⁸⁷Sr/⁸⁶Sr=0.7010 to 0.7040) and possessed higher than did contemporaneous mantle, komatiites or tholeiites, and thus carried a contribution from older sialic basement. A provinciality of⁸⁷Sr/⁸⁶Sr and ¹³C is evident, signifying that fault plumbing sampled lower crust which was heterogeneous at the scale of tens of kilometres. Mineralised faults possess enrichments of large ion lithophile (LIL), LIL elements, including K, Rb, Ba, Cs, B, and CO₂, and rare elements, such as Au, Ag, As, Sb, Se, Te, Bi, and W. Fluids were characterised by X_{CO 2}0.1, neutral to slightly acidic pH, low salinity 3 wt-%, K/Na=0.1, they carried minor CH₄, CO, and N₂, and they underwent transient effervescence of CO₂ during decompression. Clastic sediments occupy graben developed at fault flexures. The⁴⁰Ar/³⁹Ar release spectra indicate that fault rocks experienced episodic disturbance on time scales of hundreds of millions of years.At the Grenville front, translation was accommodated along two mylonite zones and an intervening boundary fault. The high-temperature (580°C) and low-temperature (430 to 490°C) mylonite zones, formed in the presence of deep-level crust-equilibrated fluids of metamorphic origin. Late brittle faults contain quartz veins precipitated from fluids with extemely negative ¹⁸O (–14 per mil) at 200 to 300°C. The water may have been derived from downward penetration into fault zones of precipitation of low¹⁸O on a mountain range induced by continental collision, with uplift accommodated at deep levels by the mylonite zones coupled with rebound on the boundary faults.Archean gneisses overlie Proterozoic sediments along thrust surfaces at Lagoa Real, Brazil; the gneisses are transected by brittle-ductile shear zones locally occupied by uranium deposits. Following deformation at 500 to 540°C, in the presence of metamorphic fluids and under conditions of low water-to-rock ratio, shear zones underwent local intense oxidation and desilication. All minerals undergo a shift of –10 per mil, indicating discharge of meteoric-water-recharged formation brines in the underlying Proterozoic sediments up through the Archean gneisses, during overthrusting; 1000 km³ of solutions passed through these structures. The shear zones and Proterozoic sediments are less radiogenic (⁸⁷Sr/⁸⁶Sr=0.720) than contemporaneous Archean gneisses (0.900), corroborating the transport of fluids and solutes through the structure from a large external reservoir.Major crustal detachment faults of Tertiary age in the Picacho Cordilleran metamorphic core complex of Arizona show an upward transition from undeformed granitic basement through mylonitic to brecciated and hydrothermally altered counterparts. The highest tectonic levels are allochthonous, oxidatively altered Miocene volcanics. This transition is accompanied by an increase of 12 per mil in ¹⁸O, from +7 to +19, and a 400°C decrease in temperature. Lower tectonic levels acted as aquifers for the expulsion of large volumes of higher-temperature reduced metamorphic fluids and/or evolved formation brines. The Miocene allochthon was influenced by a lower-temperature reservoir inducing oxidative potassic alteration; mixing occurred between cool downward-penetrating thermal waters and the hot, deeper aqueous reservoir.In general, flow regimes in these fault and shear zones follow a sequence, from conditions of high temperature and pressure with locally derived fluids at low water-to-rock ratios, during initiation of the structures, to high fluxes of reduced formation or metamorphic fluids along conduits as the structures propagate and intersect hydrothermal reservoirs. Later in the tectonic evolution and at shallower crustal levels there was incursion of oxidising fluids from near-surface reservoirs into the faults. In general, magmatism, tectonics, and fluid motion are intimately related.     

Water-rock interactions in fault gouge

Measurements were made of the amounts of D,¹⁸O, and H₂O⁺ in fault gouge collected over a depth of 400 m in the San Andreas fault of California. The amounts and isotopic compositions of the pore fluids, also analyzed, suggest that formation waters from adjacent Franciscan rocks have migrated into the gouge and mixed with local meteoric water. Thus the gouge is an open system permeable to fluid flow. This permeability has important implications concerning heat flow along the fault zone.Analyses of the fault gouge itself give information on the amounts, timing, and conditions of formation of the clay minerals.Stable-isotope analyses of materials from fault zones are good indicators of water-rock interactions that bear importantly on processes taking place in seismically active regions.     

Isotopic ratio and concentration of sulfur in the undersaturated alkaline magmas of Vulture Volcano (Italy)

Both the ³⁴ value and the total S content of products from Vulture Volcano, Italy are mainly controlled by the separation of S gases, predominantly SO₂, from high f _O2magmas containing S predominantly as SO _2- ⁴ . The addition of evaporites to such magmas appears to be a relatively uncommon and limited phenomenon. The total S content of the most primitive product of Vulture Volcano (5600 mg/kg) is very high. The high ³⁴S value of 4 indicates an origin through the partial melting of a mantle containing high S, enriched in ³⁴S of unknown origin.     

On the propagation of finite Love Waves

Summary The problem of the propagation of finite Love Waves in a heterogeneous elastic half space lying over a homogeneous elastic half space, using the quasilinear stress-strain relation due toS. Ferhst [4] is considered in detail. The variations of the parameter in the layer assumed to be of the form 1= 0e ^z, 0e ^z where is a constant andz is distance measured from the surface into the layer.     

Abiogenic hydrocarbons in commercial gases from the Songliao Basin, China

This paper discusses the kinetic fractionation, composition and distribution characteristics of carbon and hydrogen isotopes for various alkane gases formed in different environments, by different mecha- nisms and from different sources in nature. It is demonstrated that the biodegradation or thermode- gradation of complex high-molecule sedimentary organic material can form microbial gas or thermogenic gas. The δ 13C1 value ranges from -110‰ to -50‰ for microbial gases but from -50‰ to -35‰ (even heavier) f...     

Fractal analysis of long-range paleoclimatic data: Oxygen isotope record of pacific core V28-239

R/S analysis of the oxygen isotope curve of Pacific core V28-239 yields a fractal dimension of 1.22. This value is considered to characterize global climatic change over the last 2 million years as expressed by changing O¹⁸ ratios and confirms that climatic variations are characterized by long-term persistence. The fractal dimension of 1.22 compares favorably with the approximate fractal dimension of 1.26 for annual precipitation records for nine major cities in the United States. Although the precipitation and oxygen isotope data are measured in different physical units and recorded at different time scales, fractal analysis allows for a mathematical comparison of the two phenomena. Additionally, since the fractal dimensions of the oxygen isotope and precipitation records are similar, it is implied that such fractal dimensions are characteristic of climate change over the spectral range of 10 to 10⁶ years. Given this temperature curves based on fractal parameters of long-term O¹⁸ data could be constructed which would allow examination of characteristics of temperature variation over tens and hundreds of years. Such studies may allow the establishment of limits on natural temperature variation and document the persistence of temperature trends through time. If these trends and limits can be resolved, long-range climatic prediction is feasible.     

Nanoscale porosity in SAFOD core samples (San Andreas Fault)

With transmission electron microscopy (TEM) we observed nanometer-sized pores in four ultracataclastic and fractured core samples recovered from different depths of the main bore hole of the San Andreas Fault Observatory at Depth (SAFOD). Cutting of foils with a focused ion beam technique (FIB) allowed identifying porosity down to the nm scale. Between 40 and 50% of all pores could be identified as in-situ pores without any damage related to sample preparation. The total porosity estimated from TEM micrographs (1–5%) is comparable to the connected fault rock porosity (2.8–6.7%) estimated by pressure-induced injection of mercury. Permeability estimates for cataclastic fault rocks are 10^? 21–10^? 19 m² and 10^? 17 m² for the fractured fault rock. Porosity and permeability are independent of sample depth. TEM images reveal that the porosity is intimately linked to fault rock composition and associated with deformation. The TEM-estimated porosity of the samples increases with increasing clay content. The highest porosity was estimated in the vicinity of an active fault trace. The largest pores with an equivalent radius > 200 nm occur around large quartz and feldspar grains or grain-fragments while the smallest pores (equivalent radius < 50 nm) are typically observed in the extremely fine-grained matrix (grain size < 1 μm). Based on pore morphology we distinguish different pore types varying with fault rock fabric and alteration. The pores were probably filled with formation water and/or hydrothermal fluids at elevated pore fluid pressure, preventing pore collapse. The pore geometry derived from TEM observations and BET (Brunauer, Emmett and Teller) gas adsorption/desorption hysteresis curves indicates pore blocking effects in the fine-grained matrix. Observations of isolated pores in TEM micrographs and high pore body to pore throat ratios inferred from mercury injection suggest elevated pore fluid pressure in the low permeability cataclasites, reducing shear strength of the fault.     

Isotopic evidence for meteoric-hydrothermal alteration of plutonic igneous rocks in the Yakutat Bay and Skagway areas,Alaska

Oxygen and hydrogen isotope ratios were measured on coexisting minerals from quartz diorites and quartz monzonites from a section across the Coast Range batholith in the Skagway area, Alaska, including a variety of outlying plutons west of the batholith in the Yakutat Bay-Mt. St. Elias region (latitudes 59–60°N). The extremely low and variable δ¹⁸Oand δD results indicate widespread meteoric-hydrothermal alternaiton of the Coast Range batholith, and to a lesser extent, of the Yakutat Bay plutons as well. In the Yakutat Bay area, the plutons with K—Ar ages younger than 50 m.y. have widely varying δD values of ?72 to ?148, compared to δD = ?69to?90 for all but one sample in the 50–225 m.y. age grouping (one biotite has δD = ?109). This suggests that the major meteoric-hydrothermal episodes in this area occurred during the Eocene and Miocene. This involved relatively small meteoric water/rock ratios(<0.1), as none of the δ¹⁸O values show any clear-cut evidence of alteration (δ¹⁸O_quartz= 7.4 ?11.8; δ¹⁸O_feldspar= 5.7?10.0). However, in the section across the Coast Range batholith, 85% of the plutonic rocks have very low δD values of ?100 to ?167, and the δ¹⁸O values are extremely variable δ¹⁸O_feldspar= + 10.3to?4.0 and Δ¹⁸O_{quartz-feldspar}= 0.4?10.5. These data indicate that a major portion of the batholith, particularly the quartz monzonite-rich eastern part, but also including many of the quartz diorite plutons as well, interacted with meteoric-hydrothermal convective systems that involved water/rock ratios of about 0.3–1.4. The quart diorite plutons are most depleted in¹⁸O near their northeast contacts against the younger quartz monzonite intrusions. The primary igneous δ¹⁸O values of the quartz diorites were apparently higher than those of the quartz monzonites; they are also unusually high in¹⁸O compared to most other analyzed quartz diorites, suggesting derivation from, exchange with, or assimilation of high-¹⁸O metasediments or altered volcanic rocks. These data and conclusions are very similar to those reached previously on a similar isotopic study of the Coast Range batholith in British Columbia, 700 km to the southeast at latitudes 54–55°N, except that in the Skagway area an even greater proportion of the batholith was apparently depleted in deuterium. This implies that deep (?5km?) circulation of meteoric groundwaters is probably a characteristic of the later stages of emplacement of the Cordilleran batholiths of western North America, suggesting that the eastern sections of these batholiths in particular were emplaced at relatively shallow depths.     

Single and multiple dislocation models of extended earthquake sources

Summary A short review of simple theoretical models for extended earthquake sources visualized as single and multiple dislocations is presented. Formulas for the duration of the radiation t _i ^s from the starting point of the destruction up to the region forming the amplitude maxima of body waves are given. A method for determining some basic parameters of extended earthquake sources (length and depth of the dislocation, azimuth of the first dislocation and the angles between every two consecutive dislocations) from the seismogram data for t_i ^s is presented. The procedure is applied to yield some practical results.     

Strong Potential Magnetic Field Influence on Slightly Differentially Rotating Spherical Shell

An electrically conducting viscous fluid-filled spherical shell is permeated by an axisymmetric strong potential magnetic field with large Elssaser number ² 1. We describe analytically the steady flow driven by a slightly faster rotation of the conducting inner boundary of the shell. The main flow is controlled by Ekman-Hartmann boundary layers with a small thickness /, where ² is the Ekman number. Asymptotics based on small ^–1 1 reveal the nature of a free shear layer O((/)^1/2) and a super-rotation that allows a part of the fluid to rotate faster than the inner sphere. The free shear is following an imposed field line that is tangent to the inner or outer sphere. Meridional flux is concentrated in the shear and boundary layers. Fluid tends to rotate with the inner sphere and to expel azimuthal magnetic field from an -region restricted by the free shear in the spherical shell. For an imposed axial uniform magnetic field, this -region is outside the cylinder tangent to the inner sphere and rotates with the outer sphere. Weak differential rotation O(/) is inside the cylinder, while almost all difference in rotation rates between spheres is accommodated in the thin O((/)^1/2) free shear. For an imposed dipole magnet, the region has a shape of a lobe touching the outer equator. Inside a super-rotation exists; this is the common case for such when the source of the imposed field is inside.     

The derivatives of the lunar disturbing potential harmonics with respect to euler's angles

Summary The derivatives of the harmonicsP _n ^(k) (sin _O)cos kT_O andP _n ^(k) (sin _O)sin kT_O, occurring in the development of the lunar disturbing potential, are derived upto n=4 and for k== 0, 1, ..., n. The equatorial co-ordinates _OT_O are referred to the Moon's mass centre; the procedure for the solar disturbing potential is formally identical.     

Ore fluid of the Tieluping silver deposit of Henan Province and its illustration of the tectonic model for collisional petrogenesis,metallogenesis and fluidization

The Tieluping silver deposit, located in the NE-trending faults within the metamorphic basement of the Xiong'er Mountain, is a typical altered fracture type deposit. Its ore-forming process includes three stages with temperatures concentrated at 373°C, 223°C and 165°C respectively. With δD=90‰,\(\delta ^{13} C_{CO_2 } \)=2.0‰ and δ{si18}O=8094‰, the early stage fluid was generated from reworking and metamorphism of the carbonate rich formation; the late one, with δD=?70‰,\(\delta ^{13} C_{CO_2 } \)=-1.2‰, δ¹⁸O=1.89‰, was meteoric hydrothermal solution; and the middle. δD=?109‰,\(\delta ^{13} C_{CO_2 } \)=0.1‰, δ¹⁸O=1.79‰, might be a hybrid mixed by reworking-metamorphic fluid and meteoric hydrothermal solution. Crystallized rapidly in the condition of fluid-boiling and fluid-mixing, the middle stage minerals have far more fluid inclusions with higher content of ions, higher ratios of H₂O/CO₂ and KN/MC. Consequently, they have much more ore elements such as gold compared with those of the early and late stages. It was the northward intracontinental subduction along the Machaoying fault during the Mesozoic collision between the South China and North China paleocontinents that intrigued large-scale fluidization and magmatism and led to the appearance of more than 10 large and medium hydrothermal deposits, including the Tieluping silver deposit. The study on ore-forming fluidization of the Tieluping silver deposit proves the CPMF model.     

Joint Inversion of Body-Wave Arrival Times and Surface-Wave Dispersion for Three-Dimensional Seismic Structure Around SAFOD

We incorporate body-wave arrival time and surface-wave dispersion data into a joint inversion for three-dimensional P-wave and S-wave velocity structure of the crust surrounding the site of the San Andreas Fault Observatory at Depth. The contributions of the two data types to the inversion are controlled by the relative weighting of the respective equations. We find that the trade-off between fitting the two data types, controlled by the weighting, defines a clear optimal solution. Varying the weighting away from the optimal point leads to sharp increases in misfit for one data type with only modest reduction in misfit for the other data type. All the acceptable solutions yield structures with similar primary features, but the smaller-scale features change substantially. When there is a lower relative weight on the surface-wave data, it appears that the solution over-fits the body-wave data, leading to a relatively rough V _s model, whereas for the optimal weighting, we obtain a relatively smooth model that is able to fit both the body-wave and surface-wave observations adequately.     

Oxygen isotopic evidence for meteoric water interaction with the Captains Bay pluton,Aleutian Islands

Low¹⁸O/¹⁶O values have been found in rocks from the Captains Bay pluton and surrounding country rocks on Unalaska Island in the Aleutian Islands. The pluton is surrounded by a metamorphic aureole in which the country rocks have been domed, faulted and chaotically fractured. Samples with lower¹⁸O/¹⁶O values (δ¹⁸O = ?4.1 to +2.7‰, SMOW) commonly have interstitial micrographic intergrowths of quartz and turbid potassium feldspar. These facts suggest extensive interaction of circulating meteoric waters with the pluton. Unalaska Island must have been subaerially exposed at or shortly after the time of intrusion of the pluton. The pervasive low-grade metamorphism of the “early series” volcanic rocks of all of the Aleutian Islands might be a result of the interaction of intrusive bodies with meteoric waters rather than the consequence of ridge subduction.     

Environmental isotopes as indicators for ground water recharge to fractured granite

To assess the contribution of accumulated winter precipitation and glacial meltwater to the recharge of deep ground water flow systems in fracture crystalline rocks, measurements of environmental isotope ratios, hydrochemical composition, and in situ parameters of ground water were performed in a deep tunnel. The measurements demonstrate the significance of these ground water recharge components for deep ground water flow systems in fractured granites of a high alpine catchment in the Central Alps, Switzerland. Hydrochemical and in situ parameters, as well as delta(18)O in ground water samples collected in the tunnel, show only small temporal variations. The precipitation record of delta(18)O shows seasonal variations of approximately 14% and a decrease of 0.23% +/- 0.03% per 100 m elevation gain. delta(2)H and delta(18)O in precipitation are well correlated and plot close to the meteoric water line, as well as delta(2)H and delta(18)O in ground water samples, reflecting the meteoric origin of the latter. The depletion of 18O in ground water compared to 18O content in precipitation during the ground water recharge period indicates significant contributions from accumulated depleted winter precipitation to ground water recharge. The hydrochemical composition of the encountered ground water, Na-Ca-HCO3-SO4(-F), reflects an evolution of the ground water along the flowpath through the granite body. Observed tritium concentrations in ground water range from 2.6 to 16.6 TU, with the lowest values associated with a local negative temperature anomaly and anomalous depleted 18O in ground water. This demonstrates the effect of local ground water recharge from meltwater of submodern glacial ice. Such localized recharge from glaciated areas occurs along preferential flowpaths within the granite body that are mainly controlled by observed hydraulic active shear fractures and cataclastic faults.