共查询到20条相似文献,搜索用时 31 毫秒
1.
Groundwater nitrate contamination and risk assessment in an agricultural area,South Korea 总被引:2,自引:1,他引:1
Jae-Yeol Cheong Se-Yeong Hamm Jeong-Hwan Lee Kwang-Sik Lee Nam-Chil Woo 《Environmental Earth Sciences》2012,66(4):1127-1136
The nitrate of groundwater in the Gimpo agricultural area, South Korea, was characterized by means of nitrate concentration,
nitrogen-isotope analysis, and the risk assessment of nitrogen. The groundwaters belonging to Ca–(Cl + NO3) and Na–(Cl + NO3) types displayed a higher average NO3
− concentration (79.4 mg/L), exceeding the Korean drinking water standard (<44.3 mg/L NO3
−). The relationship between δ18O–NO3
− values and δ15N–NO3
− values revealed that nearly all groundwater samples with δ15N–NO3
− of +7.57 to +13.5‰ were affected by nitrate from manure/sewage as well as microbial nitrification and negligible denitrification.
The risk assessment of nitrate for groundwater in the study area was carried out using the risk-based corrective action model
since it was recognized that there is a necessity of a quantitative assessment of health hazard, as well as a simple estimation
of nitrate concentration. All the groundwaters of higher nitrate concentration than the Korean drinking water standard (<44.3 mg/L NO3
−) belonged to the domain of the hazard index <1, indicating no health hazard by nitrate in groundwater in the study area.
Further, the human exposure to the nitrate-contaminated soil was below the critical limit of non-carcinogenic risk. 相似文献
2.
Tunisian Chott’s region is one of the most productive artesian basins in Tunisia. It is located in the southwestern part of
the country, and its groundwater resources are developed for water supply and irrigation. The chemical composition of the
water is strongly influenced by the interaction with the basinal sediments and by hydrologic characteristics such as the flow
pattern and time of residence. The system is composed of an upper unconfined “Plio-Quaternary” aquifer with a varying thickness
of 20–200 m, an intermediate confined/unconfined “Complex Terminal” aquifer about 100 m in thickness and a deeper “Continental
Intercalaire” aquifer about 150 m in thickness separated by thick clay and marl layers. The dissolution of evaporites and
carbonates explains part of the contained Na+, Ca2+, Mg2+, K+, SO42− and Cl-, but other processes, such carbonate precipitation, also contributes to the water composition. The stable isotope composition
of waters establishes that the deep groundwater (depleted as compared to present corresponding local rainfall) is ancient
water recharged probably during the late Pleistocene and the early Holocene periods. The relatively recent water in the Plio-Quaternary
aquifer is composed of mixed waters resulting presumably from upward leakage from the deeper groundwater. 相似文献
3.
4.
The overexploitation of groundwater in some parts of the country induces water quality degradation. The untreated industrial effluents discharged on the surface causes severe groundwater pollution in the industrial belt of the country. This poses a problem of supply of hazard free drinking water in the rural parts of the country. There are about 80 tanneries operating in and around Dindigul town in upper Kodaganar river basin, Tamilnadu, India. The untreated effluents from the tanneries have considerably affected the quality of groundwater in this area. To assess the extent of groundwater deterioration, a detailed analysis of groundwater quality data has been carried out. The concentration of cations such as Calcium (Ca2+), Magnesium (Mg2+), Sodium (Na+) and Potassium (K+), and anions such as Bicarbonate (HCO3–), Sulphate (SO42–), Chloride (Cl–) and Nitrate (NO3–) in the groundwater have been studied. Apart from these constituents, pH, electrical conductivity (EC), total dissolved solid and total hardness (TH as CaCO3) were also studied. The correlation of these constituents with the EC has been carried out. The highest correlation is observed between EC and chloride with a correlation coefficient of 0.99. Progressive reduction in correlation coefficients for Mg2+, (Na+ + K+), Ca2+ and SO42– are observed as 0.91, 0.87, 0.86 and 0.56, respectively. It is found that the quality of groundwater in the area under investigation is deteriorated mainly due to extensive use of salt in the leather industries. 相似文献
5.
Geochemistry of groundwater,Markandeya River Basin,Belgaum district,Karnataka State,India 总被引:1,自引:0,他引:1
The Markandeya River Basin stretches geographically from 15o56′ to 16o08′ N latitude and 74o37′ to 74o58′ E longitude, positioned in the midst of Belgaum district, in the northern part of Karnataka. The groundwater quality of 54 pre-monsoon samples in the Markandeya River Basin was evaluated for its suitability for drinking and irrigation purposes by estimating pH, EC, TDS, hardness and alkalinity besides major cations (Na+, K+, Ca2+, Mg2+) and anions (HCO3–, Cl–, SO42–, PO43-, F-, NO3–), boron, SAR, % Na, RSC, RSBC, chlorinity index, SSP, non-carbonate hardness, Potential Salinity, Permeability Index, Kelley’s ratio, Magnesium hazard and Index of Base Exchange. Negative Index of Base Exchange indicates the chloro-alkaline disequilibrium in the study area and the majority of water samples fall in the rock dominance field based on Gibbs’ ratio. Permeability indices of classes I and II suggest suitability of groundwater for irrigation. Based on Cl, SO4, HCO3 concentrations, water samples can be classified as normal chloride (96.3%) and normal sulfate (94.4%) and normal bicarbonate (44.4%) water types. 相似文献
6.
Environmental geochemistry and quality assessment of surface and subsurface water of Mahi River basin, western India 总被引:4,自引:3,他引:1
The hydrogeochemical study of surface and subsurface water of Mahi River basin was undertaken to assess the major ion chemistry,
solute acquisition processes and water quality in relation to domestic and irrigation uses. The analytical results show the
mildly acidic to alkaline nature of water and dominance of Na+ and Ca2+ in cationic and HCO3
− and Cl− in anionic composition. In general, alkaline-earth elements (Ca2+ + Mg2+) exceed alkalis (Na+ + K+) and weak acids (HCO3
−) dominate over strong acids (SO4
2+ + Cl−) in majority of the surface and groundwater samples. Ca2+–Mg2+–HCO3
− is the dominant hydrochemical facies both in surface and groundwater of the area. The weathering of rock-forming minerals
mainly controlled the solute acquisition process with secondary contribution from marine and anthropogenic sources. The higher
concentration of sodium and dissolved silica, high equivalent ratios of (Na+ + K+/TZ+), (Na+ + K+/Cl−) and low ratio of (Ca2+ + Mg2+)/(Na+ + K+) suggest that the chemical composition of the water is largely controlled by silicate weathering with limited contribution
from carbonate weathering and marine and anthropogenic sources. Kaolinite is the possible mineral that is in equilibrium with
the water, implying that the chemistry of river water favors kaolinite formation. Assessment of water samples for drinking
purposes suggests that the majority of the water samples are suitable for drinking. At some sites concentrations of TDS, TH,
F−, NO3
− and Fe are exceeding the desirable limit of drinking. However, these parameters are well within the maximum permissible limit
except for some cases. To assess the suitability for irrigation, parameters like SAR, RSC and %Na were calculated. In general,
both surface and groundwater is of good to suitable category for irrigation uses except at some sites where high values of
salinity, %Na and RSC restrict its uses. 相似文献
7.
The need for more agricultural or residential land has encouraged reclamation at the coastal areas of Korea since 1200 ad (approximately). The groundwaters of these reclaimed areas could be expected to reveal hydrogeochemical properties different
from those of areas directly affected by seawater intrusion. The purpose of this study, therefore, was to examine the salinization
of shallow groundwater in a coastal reclaimed area and to identify the effect of land reclamation on groundwater quality.
Major cations and anions, iodide, total organic carbon, δD, δ
18O and δ
13C were measured to assist the hydrogeochemical analysis. Chloride, δD and δ
18O data clearly show that the Na–Cl type water results from mixing of groundwater with seawater. In particular, the δD and δ
18O of Ca+Mg–Cl+NO3 type groundwaters are close to the meteoric water line, but Na–Cl type waters enriched in chloride are 18O-enriched with respect to the meteoric water line. Meanwhile, carbon isotopic data and I/Cl ratios strongly suggest that
there are various sources of salinity. The δ
13C values of Na–Cl type groundwaters are generally similar to those of Ca+Mg–Cl+NO3 type waters, which are depleted in 13C with respect to seawater. I/Cl ratios of Na–Cl type groundwater are 10–100 times higher than that of seawater. Because the
reclamation has incorporated a large amount of organic matter, it provides optimum conditions for the occurrence of redox
processes in the groundwater system. Therefore, the salinization of groundwater in the study area seems to be controlled not
only by saltwater intrusion but also by other effects, such as those caused by residual salts and organic matter in the reclaimed
sediments. 相似文献
8.
Tracing the sources of nitrate in karstic groundwater in Zunyi,Southwest China: a combined nitrogen isotope and water chemistry approach 总被引:1,自引:0,他引:1
Si-Liang Li Cong-Qiang Liu Yun-Chao Lang Zhi-Qi Zhao Zhi-Hua Zhou 《Environmental Earth Sciences》2010,60(7):1415-1423
Nitrate (NO3
−) is major pollutant in groundwater worldwide. Karst aquifers are particularly vulnerable to nitrate contamination from anthropogenic
sources due to the rapid movement of water in their conduit networks. In this study, the isotopic compositions (δ15N–NO3
−, δ15N–NH4
+) and chemical compositions(e.g., NO3
−, NH4
+, NO2
−, K+) were measured in groundwater in the Zunyi area of Southwest China during summer and winter to identify the primary sources
of contamination and characterize the processes affecting nitrate in the groundwater. It was found that nitrate was the dominant
species of nitrogen in most of the water samples. In addition, the δ15N–NO3
− values of water samples collected in summer were lower than those collected in winter, suggesting that the groundwater received
a significant contribution of NO3
− from agricultural fertilizer during the summer. Furthermore, the spatial variation in the concentration of nitrate and the
δ15N–NO3
− value indicated that some of the urban groundwater was contaminated with pollution from point sources. In addition, the distribution
of δ15N–NO3
− values and the relationship between ions in the groundwater indicated that synthetic and organic fertilizers (cattle manure)
were the two primary sources of nitrate in the study area, except in a few cases where the water had been contaminated by
urban anthropogenic inputs. Finally, the temporal and spatial variation of the water chemistry and isotopic data indicated
that denitrification has no significant effect on the nitrogen isotopic values in Zunyi groundwater. 相似文献
9.
Manish Kumar Bhawna Sharma AL. Ramanathan M. Someshwar Rao Bhishm Kumar 《Environmental Geology》2009,56(6):1171-1181
Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards
high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from
the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space
and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na+/Cl−, SO4
2−/Cl−, Mg2+/Ca2+ and Ca2+/(HCO3
− + SO4
2−) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined
landfill sites and drains is the prime cause of NO3
− contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level
fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater
and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater
salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution
inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect
to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening
and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable
for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and
recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined
drains. 相似文献
10.
L. Valenzuela-Vásquez J. Ramírez-Hernández J. Reyes-López A. Sol-Uribe O. Lázaro-Mancilla 《Environmental Geology》2006,51(1):17-27
Anomalous high fluoride concentration up to 7.59 mg/dm3 is found in groundwater from “La Victoria” area. This water is used to supply drinking water to Hermosillo City, Sonora. Geochemistry of groundwater, relationship between physicochemical parameters, hydrogeology and geologic setting were correlated to define the origin and the geochemical mechanisms of groundwater fluorine enrichment. High fluoride concentration is associated with high bicarbonates, pH and temperature, and it decreases toward the west and south of the area. Fluoride is in negative correlation to calcium concentration. Sodium sulphate facies of regional deep water flow are related to high fluoride concentration. High electric resistivity rocks associated with granites from the Sierra Bachoco basement might be the deep source of fluoride. Outcropping of Sierra Bachoco in the west causes upward regional flow. Groundwater of longer residence time can be pumped there. The anomalous area is restricted to “La Victoria” because calcareous paleozoic rocks outcrop to the south. 相似文献
11.
A crystallographic and m?ssbauer spectroscopy study of Fe 总被引:1,自引:0,他引:1
The crystal chemistry of garnet solid solutions on the Fe
3
2+
Al2Si3O12-Fe
3
2+
Fe
2
3+
Si3O12 (almandine-“skiagite”) and Ca3Fe
2
3+
Si3O12-Fe
3
2+
Fe
2
3+
Si3O12 (andradite-“skiagite”) joins have been investigated by single-crystal X-ray structure refinements and M?ssbauer spectroscopy.
Together, these two solid solution series encompass the complete range in Fe3+/ΣFe from 0.0 to 1.0. All garnets are isotropic and were re0fined in the Ia
d space group.
Small excess volumes of mixing are observed in andradite-“skiagite” solid solutions (W
v
=1.0±0.2 cm3 mol-1) and along the almandine-“skiagite” join (W
v
=-0.77±0.17cm3 mol-1). The octahedral (Al, Fe3+)-O bond lengths show a much greater variation across the almandine-skiagite join compared to the andradite-skiagite garnets.
The dodecahedral (X)-O bond lengths show the opposite behaviour. In andradite-“skiagite” solid solutions, the octahedral site
passes from being flattened to elongated parallel to the 3 axis of symmetry with increasing “skiagite” content. A perfect
octahedron occurs in a composition of ≈35 mol% “skiagite”. The occupancy of the neighboring dodecahedral sites has the greatest
effect on octahedral distortion and vice versa. The M?ssbauer hyperfine parameters of Fe2+remain constant in both solid solutions. The hyperfine parameters of Fe3+ (at room temperature: centre shift=0.32–0.40 mm/sec, quadrupole splitting (QS)≈0.21–0.55 mm/ sec) indicate that all Fe3+ is in octahedral coordination. The Fe3+ parameters are nearly constant in almandine-“skiagite” solid solutions, but vary significantly across the andradite-“skiagite”
join. The structural unit that contributes to the electric field gradient of the octahedral site is different from that of
the coordinating oxygen polyhedron, probably involving the neighboring dodeca-hedral sites. 相似文献
12.
M. A. Halim R. K. Majumder S. A. Nessa K. Oda Y. Hiroshiro B. B. Saha S. M. Hassain Sk. A. Latif M. A. Islam K. Jinno 《Environmental Geology》2009,58(1):73-84
An integrated study has been carried out to elucidate the distribution and occurrence of arsenic in selected groundwater samples
in the area of Sherajdikhan, Bangladesh. Arsenic and other parameters (T, pH, EC, Na+, K+, Ca2+, Mg2+, Cl−, NO3
−, SO4
2−, HCO3
−, PO4
3−, Fe, Mn and DOC) have been measured in groundwater samples collected from shallow/deep tube wells at different depths. Hydrogeochemical
data suggest that the groundwaters are generally Ca–Mg–HCO3 and Mg–Ca–HCO3 types with bicarbonate (HCO3
−) as the dominant anion, though the other type of water has also been observed. Dissolved arsenic in groundwater ranged from
0.006 to 0.461 mg/l, with 69% groundwater samples exceeded the Bangladesh limit for safe drinking water (0.05 mg/l). Correlation
and principal component analysis have been performed to find out possible relationships among the examined parameters in groundwater.
Low concentrations of NO3
− and SO4
2−, and high concentrations of DOC, HCO3
− and PO4
3− indicate the reducing condition of subsurface aquifer where sediments are deposited with abundant organic matter. Distinct
relationship of As with Fe and Mn, and strong correlation with DOC suggests that the biodegradation of organic matter along
with reductive dissolution of Fe–Mn oxyhydroxides has being considered the dominant process to release As in the aquifers
studied herein. 相似文献
13.
Hydrogeochemical processes in the groundwater environment of Heihe River Basin,northwest China 总被引:5,自引:0,他引:5
Zhu Gaofeng Su Yonghong Huang Chunlin Feng Qi Liu Zhiguang 《Environmental Earth Sciences》2010,60(1):139-153
The Heihe River Basin is a typical arid inland river basin for examining stress on groundwater resources in northwest China.
The basin is composed of large volumes of unconsolidated Quaternary sediments of widely differing grain size, and during the
past half century, rapid socio-economic development has created an increased demand for groundwater resources. Understanding
the hydrogeochemical processes of groundwater and water quality is important for sustainable development and effective management
of groundwater resources in the Heihe River basin. To this end, a total of 30 representative groundwater samples were collected
from different wells to monitor the water chemistry of various ions and its quality for irrigation. Chemical analysis shows
that water presents a large spatial variability of chemical facies (SO4
2−–HCO3−, SO4
2−–Cl−, and Cl−–SO4
2−) as groundwater flow from recharge area to discharge area. The ionic ratio indicates positive correlation between the flowing
pairs of parameters: Cl− and Na+(r = 0.95), SO4
2− and Na+ (r = 0.84), HCO3
− and Mg2+(r = 0.86), and SO4
2− and Ca2+ (r = 0.91). Dissolution of minerals, such as halite, gypsum, dolomite, silicate, and Mirabilite (Na2SO4·10H2O) in the sediments results in the Cl−, SO4
2−, HCO3
−, Na+, Ca2+ and Mg2+ content in the groundwater. Other reactions, such as evaporation, ion exchange, and deposition also influence the water composition.
The suitability of the groundwater for irrigation was assessed based on the US Salinity Laboratory salinity classification
and the Wilcox diagram. The results show that most of the groundwater samples are suitable for irrigation uses barring a few
locations in the dessert region in the northern sub-basin. 相似文献
14.
Seasonal variation of groundwater quality in a part of Guntur District, Andhra Pradesh, India 总被引:3,自引:0,他引:3
N. Subba Rao 《Environmental Geology》2006,49(3):413-429
The area in Guntur district, Andhra Pradesh, India, is selected to discuss the impact of seasonal variation of groundwater
quality on irrigation and human health, where the agriculture is the main livelihood of rural people and the groundwater is
the main source for irrigation and drinking. Granite gneisses associated with schists and charnockites of the Precambrian
Eastern Ghats underlie the area. Groundwater samples collected seasonally, pre- and post-monsoons, during three years from
forty wells in the area were analyzed for pH, EC, TDS, TA, TH, Ca2+, Mg2+, Na+, K+, CO32−, HCO3−, Cl−, SO42−, NO3−and F−. The chemical relationships in Piper’s diagram, Chebotarev’s genetic classification and Gibbs’s diagram suggest that the
groundwaters mainly belong to non-carbonate alkali type and Cl− group, and are controlled by evaporation-dominance, respectively, due to the influence of semi-arid climate, gentle slope,
sluggish drainage conditions, greater water–rock interaction, and anthropogenic activities. A comparison of the groundwater
quality in relation to drinking water quality standards proves that most of the water samples are not suitable for drinking,
especially in post-monsoon period. US Salinity Laboratory’s and Wilcox’s diagrams, and %Na+ used for evaluating the water quality for irrigation suggest that the majority of the groundwater samples are not good for
irrigation in post-monsoon compared to that in pre-monsoon. These conditions are caused due to leaching of salts from the
overlying materials by infiltrating recharge waters. A management plan is suggested for sustainable development of the area. 相似文献
15.
An integrated geological, geoelectrical and hydrochemical investigation of shallow groundwater occurrence in the Ibadan area,
southwestern Nigeria, is presented. The primary objective was to characterise the groundwater in a typical low-latitude environment
underlain by Precambrian crystalline basement complex rocks. The dominant rocks comprise suites of gneisses and quartzites.
Chemical analyses of the groundwater show that the mean concentration of the cations is in the order Na>Ca>Mg>K while that
for the anions is Cl>HCO3>NO3>SO4. Statistical analyses, using the product-moment coefficient of correlation, indicate positive correlations between the following
pairs of parameters: TDS and conductivity (r=0.96); Na++Mg2+ and Cl– (r=0.95); Na++K+ and Ca2+ (r=0.43); Na++K+ and HCO3
– (r=0.17); Ca2+ and Mg2+ (r=0.74); Ca2+ and HCO3
– (r=0.33); Ca2++Mg2+ and HCO3
– (r=0.31) and pH and HCO3
– (r=0.54). A very weak negative correlation was recorded between pH and Cl–, with r=–0.003. Five groundwater groups have been identified, namely, (1) the Na-Cl, Na-Ca-Cl, Na-Ca-(Mg)-Cl; (2) the Ca-(Mg)-Na-HCO3-Cl, Na-Ca-HCO3-Cl, and Ca-HCO3-Cl; (3) the Ca-(Mg)-Na-HCO3, Ca-Na-HCO3; (4) Ca-Na-Cl-(SO4)-HCO3 and (5) the Ca-(Mg)-Na-SO4-HCO3. The different groups reflect the diversity of bedrock types and consequently also of the products of weathering. Most of
the water sampled is unfit for drinking on account of the high NO3
– content. It can, however, be used for irrigation purposes as the sodium hazard is low while the salinity hazard ranges from
low to medium. Resistivity soundings indicate the presence of a thick weathering profile, which could be up to 60 m. Such
sites should be the target for any long-term and sustainable groundwater development in the area.
Received: 15 April 1998 · Accepted: 4 July 1998 相似文献
16.
Isotopic and geochemical characteristics of groundwater in the Senegal River delta aquifer: implication of recharge and flow regime 总被引:3,自引:3,他引:0
Moctar Diaw Serigne Faye Willibald Stichler Piotr Maloszewski 《Environmental Earth Sciences》2012,66(4):1011-1020
Groundwater and surface water samples were collected to improve understanding of the Senegal River Lower Valley and Delta
system, which is prone to salinization. Inorganic ion concentrations and environmental isotopes (18O, 2H and 3H) in groundwater, river, lake and precipitation were investigated to gain insight into the functioning of the system with
regard to recharge sources and process, groundwater renewability, hydraulic interconnection and geochemical evolution. The
geochemical characteristics of the system display mainly cation (Ca2+ and/or Na+) bicarbonated waters, which evolve to chloride water type; this occurs during groundwater flow in the less mineralized part
of the aquifer. In contrast, saline intrusion and secondary brines together with halite dissolution are likely to contaminate
the groundwater to Na–Cl type. Halite, gypsum and calcite dissolution determine the major ion (Na+, Cl−, Ca2+, Mg2+, SO4
2− and HCO3
−) chemistry, but other processes such as evaporation, salt deposition, ion exchange and reverse exchange reactions also control
the groundwater chemistry. Both surface water and groundwater in the system show an evaporation effect, but high evaporated
signatures in the groundwater may be due to direct evaporation from the ground, infiltration of evaporated water or enriched
rainwater in this region. The stable isotopes also reveal two types of groundwater in this system, which geomorphologically
are distributed in the sand dunes (depleted isotopes) and in the flood plain (enriched isotopes). Consideration of the 3H content reinforces this grouping and suggests two mechanisms of recharge: contribution of enriched surface water in recharging
the flood plain groundwater and, in the sand dunes area where water table is at depth between 8 and 13 m, slow recharge process
characterized the submodern to mixed water. 相似文献
17.
Hydrogeological conditions and quality of ground waters in northern Banat,Pannonian basin 总被引:1,自引:0,他引:1
Geological relationships, hydrogeology and chemical composition of ground water in northern Banat were studied through the
period 2000–2004 using the available background data from published and unpublished sources. Northern Banat is the extreme
northeastern part of the Republic of Serbia and a geotectonic part of the vast Pannonian depression. The source of domestic
and industrial water supply is only groundwater from artesian and subartesian aquifers of Lower Pleistocene (Q11) and Upper Pleistocene (Pl32) sand deposits. The ground water, “peculiar” in chemical composition, is the only source of drinking water in the arid area.
A notable variation in the chemical composition of artesian waters within the same geotectonic unit (Pannonian basin), abstracted
for municipal water supplies of Kikinda, Novi Knezevac and Djala, has attracted attention of these authors. Our paper attempts
to interpret the variation in the chemical composition of ground water and the cause of the variation by the interaction of
ground water and rocks forming the aquifers on the case example of the water supply sources for the three mentioned towns.
With respect to the depth and lithology of the aquifers, we interpret the varied chemical compositions of waters in the mentioned
sources as a consequence of natural factors (geological environment), geological relationships and hydrogeological conditions. 相似文献
18.
Tahir Rafique Shahid Naseem Muhammad I. Bhanger Tanzil H. Usmani 《Environmental Geology》2008,56(2):317-326
Groundwater samples were collected from various localities of Mithi sub-district of the Thar Desert of Pakistan and analysed
for fluoride ion along with other chemical parameters. The area is mainly covered by sand dunes and kaolin/granite at variable
depths. Results showed that collected water samples were severely contaminated by the presence of fluoride ion and most of
the samples have higher concentration than prescribed WHO standards (1.5 mg/l) for drinking water. Fluoride ion concentrations
ranged between 0.09 and 11.63 mg/l with mean and median values of 3.64 and 3.44 mg/l, respectively, in this area whereas,
distribution pattern showed high concentrations in the vicinity of Islamkot and Mithi towns. The content of F− has also been correlated with other major ions found in the groundwater of the study area. The positive correlation of F− with Na+ and HCO3
− showed that the water with high Na+ and HCO3
− stabilizes F− ions in the groundwater of the Thar Desert. The pH versus F− plots signifies high fluoride concentration at higher pH values, implying that alkaline environment favours the replacement
of exchangeable OH− with F− in the groundwater of Mithi area. The saturation indices (SI) of fluorite (CaF2) and calcite (CaCO3) in the groundwater samples showed that most of the samples are oversaturated with respect to calcite whereas majority of
samples have been found under saturated with respect to fluorite. The log TDS and Na/Na+Ca ratio reflected supremacy of weathering
of rocks, which promotes the availability of fluoride ions in the groundwater. Piper diagram has been used to classify the
hydrofacies. In the cation triangle, all samples are Na-type, while the anion triangle reflects major dominance of Cl-type
with a minor influence of HCO3
− and SO4
−. 相似文献
19.
A study on hydrochemical characteristics of surface and sub-surface water in and around Perumal Lake,Cuddalore district,Tamil Nadu,South India 总被引:4,自引:4,他引:0
M. V. Prasanna S. Chidambaram T. V. Gireesh T. V. Jabir Ali 《Environmental Earth Sciences》2011,63(1):31-47
Hydrogeochemical investigations are carried out in and around Perumal Lake, Cuddalore district, South India in order to assess
its suitability in relation to domestic and agricultural uses. The water samples (surface water = 16; groundwater = 12) were
analyzed for various physicochemical attributes like pH, electrical conductivity (EC), sodium (Na+), potassium (K+), calcium (Ca2+), magnesium (Mg2+), chloride (Cl−), bicarbonate (HCO3
−), sulfate (SO4
2−), phosphate (PO4), silica (H4SiO4) and total dissolved solids (TDS). Major hydrochemical facies were identified using Piper trilinear diagram. Hydrogeochemical
processes controlling the water chemistry are water–rock interaction rather than evaporation and precipitation. Interpretation
of isotopic signatures reveals that groundwater samples recharged by meteoric water with few water–rock interactions. A comparison
of water quality in relation to drinking water quality standard proves that the surface water samples are suitable for drinking
purpose, whereas groundwater in some areas exceeds the permissible limit. Various determinants such as sodium absorption ratio
(SAR), percent sodium (Na%), residual sodium carbonate (RSC) and permeability index (PI) revealed that most of the samples
are suitable for irrigation. 相似文献
20.
A. H. M. Selim Reza Jiin-Shuh Jean Ming-Kuo Lee Shang-De Luo Jochen Bundschuh Hong-Chun Li Huai-Jen Yang Chia-Chuan Liu 《Environmental Earth Sciences》2011,63(5):955-967
Two boreholes and ten piezometers in the Ganges flood plain were drilled and installed for collecting As-rich sediments and
groundwater. Groundwater samples from the Ganges flood plain were collected for the analysis of cations (Ca2+, Mg2+, K+, Na+), anions (Cl−, NO3
−, SO4
2−), total organic carbon (TOC), and trace elements (As, Mn, Fe, Sr, Se, Ni, Co, Cu, Mo, Sb, Pb). X-ray powder diffraction was
performed to characterize the major mineral contents of aquifer sediments and X-ray fluorescence (XRF) to analyze the major
chemical composition of alluvial sediments. Results of XRF analysis clearly show that fine-grained sediments contain higher
amounts of trace element because of their high surface area for adsorption. Relative fluorescence index (15–38 QSU) of humic
substance in groundwater was measured using spectrofluorometer, the results revealed that groundwater in the Ganges flood
plain contains less organic matter (OM). Arsenic concentration in water ranges from 2.8 to 170 μg/L (mean 50 μg/L) in the
Ganges flood plain. Arsenic content in sediments ranges from 2.1 to 14 mg/kg (mean 4.58 mg/kg) in the flood plains. TOC ranges
from 0.49 to 3.53 g/kg (mean 1.64 g/kg) in the Ganges flood plain. Arsenic is positively correlated with TOC (R
2 = 0.55) in sediments of this plain. Humic substances were extracted from the sediments from the Ganges flood plain. Fourier
transform infrared analysis of the sediments revealed that the plain contains less humic substances. The source of organic
carbon was assigned from δ13C values obtained using elemental analysis-isotope ratio mass spectrometry (EA-IRMS); the values (−10 to −29.44‰) strongly
support the hypothesis that the OM of the Ganges flood plain is of terrestrial origin. 相似文献