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1.
Few data are available on mercury (Hg) dynamics at high-elevation mountain sites. In this project, a whole-watershed approach was used to quantify major fluxes and pools of Hg in Sagehen basin, a closed basin in the Sierra Nevada mountains in California. Over a period spanning 9 months (January-September 2009), we estimated wet deposition inputs to the watershed at 3.8 μg m−2. Dry deposition added additional Hg in the range of 0.30-2.45 μg m−2 during this time period, and was the dominant deposition process during summer time. Seasonal snowpack accounted for only half of the Hg deposited by wet deposition. We suggest that photo-induced reduction of Hg(II) in snow and subsequent volatilization was responsible for this loss. Thus, snowpacks in the Sierra Nevada mountains likely reduce the effective atmospheric mercury flux via wet deposition due to significant emission fluxes prior to snowmelt. As such, wet Hg deposition could be of lesser importance as a Hg source in snow-dominated systems. Finally, stream runoff collected at the outlet of the watershed could account for only 4% of total Hg wet deposition suggesting that a large fraction of mercury deposition was sequestered in the ecosystem, specifically in the soils.  相似文献   

2.
Atmospheric mercury deposition on snow at springtime has been reported in polar regions, potentially posing a threat to coastal and inland ecosystems receiving meltwaters. However, the post-depositional fate of Hg in snow is not well known, and no data are available on Hg partitioning in polar snow. During snowmelt, we conducted a survey of Hg concentrations, partitioning and speciation in surface snow and at depth, over sea ice and over land along a 100 km transect across Cornwallis Island, NU, Canada. Total Hg concentrations [THg] in surface snow were low (less than 20 pmol L−1) and were significantly higher in marine vs. inland environments. Particulate Hg in surface snow represented up to 90% of total Hg over sea ice and up to 59% over land. At depth, [THg] at the snow/sea ice interface (up to 300 pmol L−1) were two orders of magnitude higher than at the snow/lake ice interface (ca. 2.5 pmol L−1). Integrated snow columns, sampled over sea-ice and over land, showed that particulate Hg was mostly bound to particles ranging from 0.45 to 2.7 μm. Moreover, melting snowpacks over sea ice and over lake ice contribute to increase [THg] at the water/ice interfaces. This study indicates that, at the onset of snowmelt, most of the Hg in snow is in particulate form, particularly over sea ice. Low Hg levels in surface snow suggest that Hg deposited through early spring deposition events is partly lost to the atmosphere from the snowpack before snowmelt. The sea ice/snow interface may constitute a site for Hg accumulation, however. Further understanding of the cycling of mercury at the sea ice/snow and sea ice/seawater interfaces is thus warranted to fully understand how mercury enters the arctic food webs.  相似文献   

3.
Atmospheric mercury (Hg) is delivered to ecosystems via rain, snow, cloud/fog, and dry deposition. The importance of snow, especially snow that has passed through the forest canopy (throughfall), in delivering Hg to terrestrial ecosystems has received little attention in the literature. The snowpack is a dynamic system that links atmospheric deposition and ecosystem cycling through deposition and emission of deposited Hg. To examine the magnitude of Hg delivery via snowfall, and to illuminate processes affecting Hg flux to catchments during winter (cold season), Hg in snow in no-canopy areas and under forest canopies measured with four collection methods were compared: (1) Hg in wet precipitation as measured by the Mercury Deposition Network (MDN) for the site in Acadia National Park, Maine, USA, (2) event throughfall (collected after snowfall cessation for accumulations of >8 cm), (3) season-long throughfall collected using the same apparatus for event sampling but deployed for the entire cold season, and (4) snowpack sampling. Estimates (mean ± SE) of Hg deposition using these methods during the 91-day cold season in 2004–2005 at conifer sites showed that season-long throughfall Hg flux (1.80 μg/m2) < snowpack Hg (2.38 ± 0.68 μg/m2) < event throughfall flux (5.63 ± 0.38 μg/m2). Mercury deposition at the MDN site (0.91 μg/m2) was similar to that measured at other no-canopy sites in the area using the other methods, but was 3.4 times less than was measured under conifer canopies using the event sampling regime. This indicates that snow accumulated under the forest canopy received Hg from the overstory or exhibited less re-emission of Hg deposited in snow relative to open areas. The soil surface of field-scale plots were sprayed with a natural rain water sample that contained an Hg tracer (202Hg) just prior to the first snowfall to explore whether some snowpack Hg might be explained from soil emissions. The appearance of the 202Hg tracer in the snowpack (0–64% of the total Hg mass in the snowpack) suggests that movement of Hg from the soil into the snowpack is possible. However, as with any tracer study the 202Hg tracer may not precisely represent the reactivity and mobility of natural Hg in soils.  相似文献   

4.
Heavy rainfall in June 2013 triggered flash flooding and landslides throughout the Indian Himalayan state of Uttarakhand, killing more than 6000 people. The vast majority of fatalities and destruction resulted directly from a lake outburst and debris flow disaster originating from above the village of Kedarnath on June 16 and 17. Here, we provide a systematic analysis of the contributing factors leading to the Kedarnath disaster, both in terms of hydrometeorological triggering and topographic predisposition. Topographic characteristics of the lake watershed above Kedarnath are compared with other glacial lakes across the north-western Himalayan states of Uttarakhand and Himachal Pradesh, and implications for glacier lake outburst hazard assessment in a changing climate are discussed. Our analysis suggests that the early onset of heavy monsoon rainfall (390 mm, June 10–17) immediately following a 4-week period of unusually rapid snow cover depletion and elevated streamflow was the crucial hydrometeorological factor, resulting in slope saturation and significant run-off into the small seasonal glacial lake. Between mid-May and mid-June 2013, snow-covered area above Kedarnath decreased by around 50 %. The unusual situation of the lake being dammed in a steep, unstable paraglacial environment but fed entirely from snowmelt and rainfall within a fluvial dominated watershed is important in the context of this disaster. A simple scheme enabling large-scale recognition of such an unfavourable topographic setting is introduced. In view of projected 21st century changes in monsoon timing and heavy precipitation in South Asia, more emphasis should be given to potential hydrometeorological triggering of lake outburst and debris flow disasters in the Himalaya.  相似文献   

5.
Tracing the origin of calcium in wet atmospheric deposits is important for environmental studies since it is a dominant acid neutralising cation and an essential nutrient. Here we present the first calcium isotope ratio measurements for rain and snow. Samples from northeastern and southern locations (France, Switzerland, Luxembourg, California and Japan) suggest a carbonate origin. Only at a local scale in a forested watershed (Vosges mountains, France) the Ca isotopic compositions of rainwater indicate that the rainwater becomes admixed with throughfall solution, which is a mixing product of Ca from dissolved atmospheric dust particles and leave excretions. If this proves to be widely true, the contribution of Ca from the canopy could be very important for the neutralisation of acid rain and of the corresponding soil system in forested watersheds. In such cases Ca and Sr cycles are decoupled in the lower atmosphere. In contrast to Sr isotopes, Ca isotopes can be applied to tracing processes occurring in the biosphere.  相似文献   

6.
Many lakes in northern high latitudes have undergone substantial changes in surface area over the last four decades, possibly as a result of climate warming. In the discontinuous permafrost of Yukon Flats, interior Alaska (USA), these changes have been non-uniform across adjacent watersheds, suggesting local controls on lake water budgets. Mechanisms that could explain the decreasing mass of one lake in Yukon Flats since the early 1980s, Twelvemile Lake, are identified via a scoping analysis that considers plausible changes in snowmelt mass and infiltration, permafrost distribution, and climate warming. Because predicted changes in evaporation (2  cmyr?1) are inadequate to explain the observed 17.5 cmyr?1 reduction in mass balance, other mechanisms are required. The most important potential mechanisms are found to involve: (1) changes in shallow, lateral groundwater flow to the lake possibly facilitated by vertical freeze-thaw migration of the permafrost table in gravel; (2) increased loss of lake water as downward groundwater flow through an open talik to a permeable subpermafrost flowpath; and (3) reduced snow meltwater inputs due to decreased snowpack mass and increased infiltration of snowmelt into, and subsequent evaporation from, fine-grained sediment mantling the permafrost-free lake basin.  相似文献   

7.
To evaluate watershed impacts of anthropogenic activities on terrestrial organic matter (TOM) and total mercury (THg) dynamics in large boreal lake ecosystems, we studied sediment cores retrieved in eight large lakes of Québec (Canada). Two lakes with pristine watersheds were considered as reference lakes and six lakes with watersheds affected by different types of anthropogenic activities (e.g. logging and/or mining activities) were used to illustrate the influence of land-use on TOM and Hg cycling in lakes. A Geographical Information System (GIS) approach was used to correlate the evolution of anthropogenic land-uses from 1979 to 2010 (e.g. logging and mining activities) to TOM and THg contents measured in sediment cores. In each core, THg concentrations gradually increased over the recent years. Using lignin biomarkers, we noticed that the presence of both intense logging and mining activities in the watershed does not necessarily correspond to noticeable changes in the relative amount of terrestrial organic matter (TOM) exported from the watershed to the sediments and by extension to the level of THg measured in sediments. Apparently large-scale watersheds show some “buffering” capacity to land-use disturbance.  相似文献   

8.
北极阿拉斯加春季积雪中汞的时空分布及其来源分析   总被引:1,自引:1,他引:0  
开展北极雪冰中汞分布特征及其来源的探究,不仅可以丰富冰冻圈汞生物地球化学循环的认识,而且对评估北极环境中汞的潜在暴露风险具有现实意义。在2017年4月至5月对美国阿拉斯加的积雪进行大范围样品采集,探讨了该区域积雪中汞的空间分布特征及其成因、汞的沉降后过程以及潜在来源分析。研究表明:积雪中汞的空间分布受大气汞亏损事件(AMDEs)及人为源的共同影响,毗邻北冰洋海岸(如巴罗)积雪中总汞(THg)浓度较高,接近人为源的山地表层雪中THg浓度较高。巴罗雪坑中THg浓度随深度增加呈下降趋势。积雪中主要阴阳离子与THg的相关性分析表明,阿拉斯加积雪中THg的空间分布可能主要受北冰洋海盐气溶胶以及人类活动的影响。  相似文献   

9.
A comparison of the stable-isotope signatures of spring waters, snow, snowmelt, summer (July thru September) rain, and cool season (October thru June) rain indicates that the high-intensity, short-duration summer convective storms, which contribute approximately a third of the annual precipitation to the Spring Mountains, provide only a small fraction (perhaps 10%) of the recharge to this major upland in southern Nevada, USA. Late spring snowmelt is the principal means of recharging the fractured Paleozoic-age carbonate rocks comprising the central and highest portion of the Spring Mountains. Daily discharge measurements at Peak Spring Canyon Creek during the period 1978–94 show that snowpacks were greatly enhanced during El Niño events.  相似文献   

10.
The presence of Hg in the fish of the lakes from the Cu-Zn-Au mining region of Chibougamau (Canada) represents a serious source of concern for the health of local sports and subsistence fishers. This study focuses on identifying the origin of Hg present in the sediments of lakes with mine wastes stored in tailing facilities located on their shores. In addition to C/N ratios and determination of total Hg, Methyl Hg and other metals, a series of lignin biomarkers were used to contrast the history of the mining contamination with the nature and the intensity of terrigenous organic matter (TOM) inputs from the watersheds to the sampled lakes. It appears that sediments located nearest to mine tailings are as expected most enriched in total Hg and other metals (Cu, As, Al, Fe, Pb). Nevertheless, the presence of only small amounts of refractory TOM in these contaminated sediments could explain why only a very small fraction of Hg is found as Methyl Hg. In sediments with little or no impact by mining activities, a relationship was observed between logging activities in the lake watershed and increased TOM derived from inorganic gymnosperms soils horizons and increased Hg transport to the lakes. Nevertheless, it appears that the additional TOM transported to logged lakes is refractory enough not to promote high levels of Methyl Hg. The highest fractions of Methyl Hg relative to total Hg in lake sediments of the studied area were thus observed in relatively pristine environments where least degraded TOM is brought from the watersheds.  相似文献   

11.
中国西北高山、 高原广泛分布着冻土和积雪, 春季融雪和冻土融化是该地区重要的水文过程.基于模块化的寒区水文建模环境CRHM, 根据流域水文过程特征和观测数据约束, 选取描述不同寒区子水文过程的模块构建寒区水文模型, 并基于长期观测的两个典型寒区小流域来验证模块化的寒区水文模型.在冰沟流域, 主要模拟雪的积累/消融、 雪的升华、 融雪下渗和融雪径流过程. 结果显示: 冰沟流域积雪升华占降雪量(145.5 cm)的48%, 其中风吹雪引起的升华损失量(35 cm)占积雪升华(69 cm)的一半, 风速和辐射引起的积雪升华是该地区积雪物质平衡的重要组成; 构建的寒区水文模型可以再现春季积雪消融引起的径流过程.在左冒孔冻土流域, 主要模拟冻土下渗过程、 冻土坡面产流过程和土壤冻融对径流的影响. 结果显示: 构建的寒区水文模型可以捕捉到春季主要的冻土融化径流过程.两个流域的验证结果揭示: 模块化的建模方法在搭建模型结构的时候减少了模型的不确定性, 所以在未经率定的情况下, 具有在无资料和资料缺少地区模拟寒区水文要素和水文过程的能力.  相似文献   

12.
黑河上游冰沟流域典型积雪期水文情势   总被引:9,自引:6,他引:3  
综合研究了黑河上游祁连山冰沟流域2008年积雪期水文情势,以积雪-冻土-径流为框架详细分析了该地区积雪水文特征.采用物质平衡计算了冰沟流域雪蒸发和融水值,并分析了冻土水热变化过程和融雪径流变化特征.积雪期降水总量达到204.6 mm,雪而蒸发为140.8 mm,雪面蒸发在积雪期水文循环中占有重要的位置.3月12日融雪开始,引起3次人规模的融雪峰值;整个融雪季,冰沟流域融雪径流总嚣为3.98×106m3.冻土解冻始于4月12日左右,随着气温升高,土壤含水量变化明显.地形和风速相巨作用,造成积雪的大规模重新分布.  相似文献   

13.
Modeling snowmelt is important for water resources management and the assessment of spring snowmelt flood risk. The objective of this study was to develop a physically based module for the WetSpa model to improve the simulation of snowmelt processes. The improved model is applied, calibrated, and verified on the Hornad watershed, upstream of Margecany, Western Carpathians, Slovakia, with 10 years of observed daily precipitation and air temperature, and estimated daily potential evaporation. Daily discharge data of the gauging station at Margecany is used for model calibration and verification. The model proves to predict accurately snow accumulation and snowmelt floods, although the parameters of the snow simulation module are preset and not adjusted by model calibration. In order to show the performance of the model, two particular snow accumulation and melt periods are discussed in detail. The relevant terms of the snowpack mass and energy balances as well as the related heat and mass transport processes are discussed. The study demonstrates that accurate snowmelt prediction based on a physically energy budget approach is possible with controlling parameters that do not need any calibration.  相似文献   

14.
 Long sediment cores (>1 m) were collected from eight Precambrian Shield lakes in southern Ontario, Canada and analyzed for mercury (Hg), loss-on-ignition (LOI), and a suite of 36 other elements. Results indicated at least 100-fold variation in sediment Hg concentrations between lakes in close proximity (from 450 ppb), comparable to the variation reported for lakes across the whole of Canada. Strong areal correlations between Hg concentrations and LOI (r 2 =0.77), between Hg and other trace element concentrations (Pb, Zn, Cd, Sb, As, Br), and similarities in the vertical concentration profiles of Hg and LOI, all point to the importance of organic matter in the release, transport and redistribution of metals in watershed systems. The spatial pattern of Hg concentrations in deep, precolonial sediments (>20 cm) was found to mirror the pattern of Hg concentrations in modern surface sediments, an observation that was confirmed in a follow-up survey (r 2 =0.85;n=25 lakes), indicating that natural processes govern the unequal distribution of Hg among these lakes. Between-lake differences in surface sediment Hg concentrations normalized to organic carbon (Hg/C) were also reflected by Hg concentrations in smallmouth bass normalized to 35 cm length (R 2 =0.63;n=15 lakes). The latter relationship suggests that smallmouth bass and lake sediment indicators provide mutually supportive information regarding Hg loading to the lacustrine environment from geological sources in the watershed system. Received: 31 October 1996 · Accepted: 27 May 1997  相似文献   

15.
新疆阿尔泰山区克兰河上游水文过程对气候变暖的响应   总被引:17,自引:7,他引:10  
额尔齐斯河支流克兰河上游发源于西风带水汽影响的阿尔泰山南坡,主要由融雪径流补给,年内积雪融水可占年径流量的45%.年最大月径流一般出现在6月份,融雪季节4~6月径流量占65%.流域自20世纪60年代开始明显升温,年平均温度从50年代的1.4℃上升到90年代的5.2℃;年降水总量也呈增加趋势,尤其是冬季和初春增加最多.随着气候变暖,河流年内水文过程发生了很大的变化,主要表现在最大月径流由6月提前到5月,月径流总量增加约15%,4~6月融雪径流量也由占年流量的60%增加到近70%.在多年变化趋势上,气温上升主要发生在冬季,降水也以冬季增加明显,而夏季降水呈下降趋势;水文过程主要表现在5月径流呈增加趋势,而6月径流为下降趋势;夏季径流减少而春季径流增加明显.冬春季积雪增加和气温上升,导致融雪洪水增多且洪峰流量增大,使洪水灾害破坏性加大.近些年来气候变暖引起的年内水文过程变化,已经对河流下游的城市供水和农牧业生产产生了影响.  相似文献   

16.
To test the usefulness of the He method for the detection of buried U ore, a lake-water survey of the Key Lake area was carried out during March 1977 and repeated in June 1977. A set of 87 lake-water samples from 37 sites in eight different lakes were collected from the same sites in each survey. These samples were analyzed for He, Rn, O2, Eh, pH, conductivity, alkalinity, and U.In the lakes the highest He concentrations, of nearly four times atmospheric equilibrium concentrations, were obtained during the winter survey. This was under the ice in two bottom lake samples where the sandy overburden extends for some 50 m directly to the ore zone. Radon and U values at these sites were also anomalous, but the highest values of Rn and U were obtained in a shallow lake about 2 km south of the ore zone where concentrations of radioactive boulders occur.The average net He and Rn contents dropped from 21 standard nanolitres/litre (nl/l) and 25 picocuries/litre (pCi/l) in the winter under the ice to 3 nl/l and 8 pCi/l in the summer, respectively. Average U and conductivity dropped from 2.3 ppb and 15 μmho/cm to 1.5 ppb and 11 μmho/cm, respectively, in the same suites of samples. The drop in the ionic species probably reflects the effect of snow and ice meltwater dilution and the much larger drop in the dissolved He and Rn reflects the combined effects of meltwater dilution, wind turbulence over ice-free lakes, and change in thermal gradients.The He results must be viewed with guarded optimism until a detailed investigation is completed to ascertain what fraction of the detected He is from the ore, what fraction from basement He that may have found its way into the lakes via the fracture zone in which the ore is located, and what effect drilling has had on the He flow into the lakes from the ore zone.  相似文献   

17.
Waters from high‐altitude alpine lakes are mainly recharged by meteoric water. Because of seasonal variations in precipitation and temperature and relatively short hydraulic residence times, most high‐altitude lakes have lake water isotopic compositions (δ18Olake) that fluctuate due to seasonality in water balance processes. Input from snowmelt, in particular, has a significant role in determining lake water δ18O. Here we compare two high‐resolution δ18Odiatom records from lake sediments in the Swedish Scandes with instrumental data from the last century obtained from nearby meteorological stations. The time period AD 1900–1990 is characterised by an increase in winter precipitation and high winter/summer precipitation ratios and this is recorded in δ18Odiatom as decreasing trends. Lowest δ18Odiatom values and highest amount of winter precipitation are found around AD 1990 when the winter North Atlantic Oscillation index was above +2. We conclude that for the last 150 a the main factor affecting the δ18Odiatom signal in these sub‐Arctic high‐altitude lakes with short residence times has been changes in amount of winter precipitation and that δ18Odiatom derived from high‐altitude lakes in the Swedish Scandes can be used as a winter precipitation proxy. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

18.
One of the most intriguing episodes in the Quaternary evolution of the Grand Canyon of the Colorado River, Arizona, was the development of vast lakes that are thought to have backed up behind lava erupted into the gorge. Stratigraphic evidence for these deep lava-dammed lakes is expectedly sparse. Possible lacustrine deposits at six areas in the eastern canyon yielded no compelling evidence for sediment deposited in a deep lake. At two of the sites the sediment was associated with late Quaternary spring-fed pools and marshes. Water-lain silt and sand at lower Havasu Creek was deposited 3000 cal yr ago. The deposit contains an ostracode assemblage similar to that living in the modern travertine-dammed pools adjacent to the outcrop. The second deposit, at Lees Ferry, formed in a spring-fed marsh 43,000 cal yr ago, as determined by 14C and amino acid geochronology. It contains abundant ostracode and mollusk fossils, the richest assemblages reported from the Grand Canyon to date. Our interpretation of these sediments as spring-fed deposits, and their relative youth, provides an alternative to the conventional view that deposits like these were formed in deep lava-dammed lakes that filled the Grand Canyon.  相似文献   

19.
Changes in vegetation were tracked from a well-dated sediment core from a boreal lake, Lake 239, at ~200-year resolution over the Holocene. This presently oligotrophic lake is located ~100-km east from the present-day parkland-forest ecotone in northwestern Ontario. Near-shore sediment core transects from Lake 239 have previously shown this lake was at least 8-m lower than present in the mid-Holocene, or ~58% less lake volume in comparison to today. Large shifts were expected in the terrestrial vegetation if the low lake levels were related to climate. The core from Lake 239 shows increases in the relative abundance and concentration of pollen such as Cupressaceae and Ambrosia, indicating a more open boreal forest between ~4500–8000 cal yr BP. Pollen-based inferences of average, summer and winter temperatures suggest that temperatures were on average up to 1–2 °C warmer than today, with winter temperatures up to 4 °C warmer. The pollen inferences also suggest enhanced precipitation, likely in the summer, but with an overall increase in evaporation and evapotranspiration resulting in reduced effective moisture. To assess regional climate changes, pollen-based reconstructions of temperature and precipitation were developed and synthesized from sediment cores from eight previously published lakes, from which pollen sites were available to both the west and east of Lake 239, spanning present-day prairie lakes to forested lakes up to 300 km east of the prairie-boreal ecotone. All sites show shifts in pollen assemblages that indicate a warm mid-Holocene period; prairie sites west of the Experimental Lakes Area (ELA) show mid-Holocene decreases in precipitation relative to today, whereas sites near or east of ELA show consistent increases in precipitation, but with increased temperatures and enhanced evaporation during the mid-Holocene.  相似文献   

20.
Major Ion Geochemistry of Nam Co Lake and its Sources, Tibetan Plateau   总被引:4,自引:0,他引:4  
The major cations and anions from lake water samples and its sources, including glacier snow, precipitation, stream, and swamp water in the Nam Co basin, central Tibetan Plateau, were studied. The concentrations of the major ions varied significantly in the five environmental matrices. Generally, the mean concentrations of most ions are in the order of lake water > swamp water > stream water > precipitation > snow. Rock weathering is the dominant process controlling the chemical compositions of the stream and swamp waters, with carbonate weathering being the primary source of the dissolved ions. The Nam Co lake water is characterized by high Na+ concentration and extremely low Ca2+ concentration relative to other ions, resulting from evapoconcentration and chemical precipitation within the lake. Comparison with the water chemistry of other lakes over the Tibetan Plateau indicated that Nam Co is located in a transition area between non-saline lakes and highly saline lakes. The relatively low concentration of total dissolved solids is possibly due to the abundant inflow of glacial meltwater and relatively high annual precipitation.  相似文献   

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