太平洋铁锰结核富集区沉积物的元素地球化学特征

尽管对大洋铁锰结核的成因的认识还未统一,但几乎一致认为结核的形成与沉积环境密切有关,结核中部分元素来自沉积物。因此,探讨铁锰结核富集区沉积物的元素地球化学特征,对研究大洋铁锰结核的形成机制具有重要的意义。近年来,作者利用我国首次大洋铁锰结核调查所取得的沉积物及某些间隙水的化学资料,通过把结核相对富集区的沉积物,与河口陆架及贫结核区(太平洋西部、南纬2—8°,     

太平洋调查区沉积物中某些金属元素的地球化学探讨

通过对大洋锰结核及其伴生沉积物研究,发现锰结核与粘土组分和有机物(或生物)有关,故笔者试图了解太平洋调查区沉积物中某些金属元素的地球化学行为。研究发现,随海水的加深,沉积物中 Ca、Sr 含量减少,其他元素含量升高,沉积物类型由钙质软泥→硅钙质软泥→红粘土。在4000—6000m 水深范围内,锰结核丰度随海水深度     

罗加湖的铁锰结核

湖泊沉积物中的铁锰结核,目前报导的还很少,对其了解也很不够。1979年笔者在罗加湖工作时首先发现了湖底沉积物中有铁锰结核,并开始对它的物理性质,化学成分进行观察测定。现将罗加湖铁锰结核的一些情况介绍如下。     

我国太平洋深海沉积研究综述

总结了我国对太平洋深海沉积物组成、分布、形成及深海沉积中宇宙尘、海洋沉积通量、铁锰结核的研究成果,指出了在全球变化研究中太平洋深海沉积的研究课题。     

雅浦海沟北部深渊和超深渊沉积物的物质组成、来源和形成过程研究

为探究雅浦海沟北部深渊、超深渊沉积物的组成、来源和形成特征,以1 cm分层对采自该海域不同深度的五根柱状沉积物样品的0~8 cm沉积层进行了扫描电子显微镜(SEM)观察和X射线能谱(EDS)分析,并且分析了这些样品的含水率,锰结核含量, Al、Ca、Fe、Mn、Ti、Mg等6种常量金属和Ba、Co、Cr、Ni、Pb、Sr、V、Cu、Zn等9种微量金属元素含量,以及总有机碳(TOC)含量等参数。结果表明,研究区域沉积物主要为深海软泥沉积,是不同年代沉积物的复杂混合,包含以盘星石为代表的颗石藻、海绵骨针、放射虫和硅藻等多种微体古生物化石以及辉石、重晶石、钛铁矿、长石等多种矿物。沉积组分主要来自生物源、火山源、陆源和海底热液,其中陆源沉积出现于海沟东侧深渊区。海沟西侧崖壁的沉积物比东侧崖壁的沉积物更容易发育锰结核。研究区域沉积物含水率较高并且颗粒较大,其含水率随深度增加呈减少趋势。研究区域超深渊站位沉积物的TOC和微体古生物化石含量均高于深渊站位,存在明显的漏斗效应。整体上海沟西侧崖壁沉积物含水率和TOC含量低于东侧崖壁的沉积物。自更新世以来,雅浦海沟北部的碳酸钙补偿深度(CCD)线从4 568 m以深变为4 435 m至4 568 m之间。研究区域的沉积环境为氧化环境,其0~8 cm沉积层的古老沉积物与现代沉积物发生了混合和再沉积作用,形成年代跨度极大。研究区域沉积物的形成受到海沟坡度、水动力环境、重力滑塌、浊流沉积、火山活动、漏斗效应等多种因素的显著影响。     

广西岩溶区土壤铁锰结核重金属富集的地质特征

广西岩溶区农田土壤重金属污染形势严峻。该地区土壤含有大量铁锰结核,其主要成分为铁和锰的氧化物,对重金属有着较强的富集作用。铁锰结核伴随着土壤形成过程而产生,也是反映土壤形成过程及成土环境变化的良好载体。研究铁锰结核中重金属的富集特征有助于了解广西岩溶区土壤中重金属元素的富集过程和富集特征。文章对广西柳江和桂平的土壤与其中的铁锰结核进行了成分分析,通过微量元素分析得到铁锰结核对Ni、Cu、Cd、Zn、Pb、Co、Ba、As、Cr等重金属元素的富集特征,通过Ti/Al2O3的比值关系推断了铁锰结核与土壤的物质来源。此外,还对铁锰结核进行了激光共聚焦显微拉曼光谱仪（Laser Microscopic Confocal Raman Spectrometer）、扫描电镜和能谱仪（SEM-EDS）分析。通过铁锰结核内部同心环带状圈层结构及其内部的元素分布周期性变化的特征,推测结核形成机制。铁锰结核的形成固定了大量重金属元素,减轻了土壤重金属污染负担;但如果铁锰结核发生了溶解则会导致Mn及受其控制的部分重金属（Co、Cu、Ni、Ba）重新释放回到土壤,加重重金属污染。     

贵州关岭新铺地区铁锰结核的初步研究

本文简要叙述了关岭县新铺地区晚三叠世瓦窑组下部含锰层位及其铁锰结核产出的地质背景和宏观特征 ,并较详细地论述它的地球化学特征。认为该铁锰结核有别于现代大洋沉积的铁锰结核或铁锰结壳 ,是Mn和Fe含量中等、Mn∶Fe >1、富LREE、贫多金属的复合成因铁锰结核 ,可能是早期热水成因的铁锰沉积物经后期风化淋滤作用而成的     

海洋沉积物的锌同位素地球化学及其应用

锌同位素体系是海洋地球化学研究的新示踪剂,应用于示踪海水中锌元素的来源及其运移过程.海洋沉积物作为锌元素重要的"源"与/或"汇",其锌同位素组成的研究有助于理解海洋锌元素的地球化学循环.海洋沉积物记录了海水组成的信息,可以反演古海水锌同位素组成的变化,前提是理解沉积物与海水之间的分馏.对海水及海洋不同储库锌同位素研究进行系统总结,包括河流输入、热液体系、不同类型海洋沉积物(如富碳酸盐的沉积物、陆源硅酸盐碎屑、硅质沉积物、铁锰结核、贫氧-缺氧沉积物)的锌同位素组成,阐述了海洋沉积物锌同位素组成变化在古气候、古环境重建以及古海洋学等领域的应用以及重要性.      

锰的微生物地球化学

锰的微生物地球化学郝瑞霞彭省临（中南工业大学地质系,长沙４１００８３）关键词锰微生物地球化学循环锰的微生物地球化学是从７０年代逐渐发展起来的。目前的研究涉及到湖泊、淡水热泉、海洋表层水、深海、沉积物等不同环境中锰与微生物的相互作用,以及锰结核、锰矿物...     

北太平洋铁锰结核富集区沉积物和间隙水中重金属元素地球化学

对北太平洋28个相对富集铁锰结核的沉积物和间隙水中重金属元素(Cu、Pb、Zn、Cr、Co、Ni)地球化学研究表明:沉积物中重金属元素明显的比陆地土壤、河口、陆架及贫结核洋区的沉积物富集,并与沉积物类型密切有关;沉积物中元素的赋存状态不同,进入间隙水的途径不同;由于Cu、Co的生物作用大于Zn、Ni,使沉积物中 Cu/Zn、Co/Ni比值由钙质软泥—钙、硅软泥—硅质软泥—褐色粘土升高。     

东太平洋洋底沉积物的物质组成与物理化学特征

作者通过研究,发现东太平洋洋底沉积物主要是由<0.063mm的伊利石、蒙脱石加混层矿物、高岭石、绿泥石粘土矿物和放射虫、硅藻等组成。具有碱性、比表面积大,离子交换容量大的特点。该成果无异为东太平洋多金属结核分布区的大洋地质学的研究,提供了可贵的环境地质资料。     

Comparative study on the geochemical characteristics of rare earth elements in deep-sea sediments from different regions of the Pacific OceanSCIEI北大核心CSCD

太平洋深海沉积物中富集稀土元素(REY,包括钇),被认为是富有潜力的新型稀土资源。(含)沸石粘土、深海粘土和多金属软泥是主要的富含REY的沉积物类型,其中(含)沸石粘土和深海粘土在中、西北太平洋海盆大面积分布,而多金属软泥则多分布于靠近东太平洋洋脊热液活动的深海盆地中。目前关于中、西北太平洋海盆的深海粘土和(含)沸石粘土已有较多的研究,但关于多金属软泥中REY的研究较少。不同区域、不同类型深海沉积物中的稀土元素赋存状态有何差异?影响稀土富集的机制又是什么目前尚不清楚,也就进一步影响了对深海沉积物稀土资源的勘查和开发工作。本文分析对比了太平洋不同区域不同类型深海沉积物的地球化学特征及矿物学特征。结果表明,总体上,中、西北太平洋海盆深海沉积物中,尤其是(含)沸石粘土中的REY含量明显高于东太平洋海盆多金属软泥REY含量,其REY的富集主要与磷酸盐有关。超常富集REY(∑REY>2000×10^(-6))的沉积物中的CaO/P_(2)O_(5)比值趋向于一致(~1.4),几乎接近于磷灰石CaO/P2O5比值(~1.3),因此REY主要赋存载体为磷灰石,该区沉积物中REY的富集可能受到磷酸盐化的影响;东太平洋海盆多金属软泥明显受到热液影响,铁和锰的含量明显增加,但其∑REY含量集中于500×10^(-6)~800×10^(-6),不随铁和锰的增加而变化,REY的富集仍与磷酸盐关系密切,而与铁锰物质和铝硅酸盐关系不大。中、西北太平洋海盆富稀土的深海沉积物形成时处于较强的氧化环境,同时又有充足的含磷物质补给,才造成REY在该区沉积物中的超常富集;而东太平洋海盆多金属软泥虽然处于氧化环境,但缺少足够的磷补给,所以其∑REY含量通常低于中、西北太平洋海盆沸石粘土中∑REY含量。     

深海沉积物分类与命名的关键技术和方案

对地质研究的对象进行科学合理的分类,是地学研究的重要内容之一.为建立科学合理、量化统一、操作简便的深海沉积物分类与命名方案,详细分析国内外深海沉积物分类与命名现状,深刻了解海洋沉积物组成与分布,深入研究深海沉积物的水深、平均粒径和粘土含量3项参数指标,通过分析涂片鉴定粘土、钙质生物、硅质生物这三者的含量、粒度和化学分析之间的差异,建立钙质生物、硅质生物与CaCO₃、生物SiO₂的量化关系,完成沉降法和激光法粒度分析资料的对比和校正,分析深海沉积物分类与命名的兼容性和可比性.在上述研究成果基础上,自主创新提出深海沉积物分类与命名方案及其关键技术.深海沉积物类型简分法把深海沉积物分为深海粘土、钙质软泥、硅质软泥、粘土-硅质-钙质软泥4类,它能满足一般性海洋地质调查要求,达到基本了解深海沉积物类型的目的,在兼容世界深海沉积物类型现状的同时,充分考虑到混合沉积物的存在.深海沉积物类型细分法在简分法基础上细分了16种沉积物,使分类与命名更加详细和全面,满足海洋地质详细调查研究的要求.深海沉积物分类与命名方案与浅海沉积物分类与命名比较,在图形、类型指标、种类数量、冠字冠名法、混合沉积物表示法、可操作性等方面具有可比性,使浅海到深海的沉积物分类与命名呈渐变和有机联系.      

Paleoceanographic Setting and Preservation of Buried Manganese Deposits in DSDP/ODP Cores

Abstract. The occurrence, lithology, and stratigraphic setting of buried manganese deposits and associated host sediments in cores obtained on Legs 123–210 of the Ocean Drilling Program (ODP) are examined in order to establish the formative environment and conditions of preservation. Fossil manganese nodule and crusts are found to have formed or deposited throughout the period from 100 Ma to the present, with an additional example of formation near 137 Ma, suggesting that the deep-sea environment has been oxic and suitable for the formation of manganese nodules and crusts since the Cretaceous. Many manganese nodules and crusts occur on horizons corresponding to hiatuses in sedimentation or periods of slow sedimentation, consistent with the environment in which modern nodules form (sedimentation rate less than 10 m/m.y.). Sediments overlying the fossil nodules and crusts are oozes or biogenic sediments with sedimentation rates of 1–18 m/m.y. Low total organic carbon (<0.1 wt%) in the overlying sediments and high sulfate content (>25 mM) in interstitial water around the manganese horizon suggest that no strong reduction occurred within the overlying sediments. Coverage by biogenic sediments containing only small amounts of organic matter is therefore considered important for the preservation of manganese nodules and crusts. Manganese carbonate occurs sporadically as nodules, concretions or thin layers in various host sediments, including clay, calcareous ooze and siliceous ooze with sedimentation rates of 6–125 m/m.y. Hiatuses are rare around the host sediments of manganese carbonate. Higher total organic carbon (0.2–1.8 wt%) in the host sediments and lower sulfate content (0–25 mM) in interstitial water around the manganese carbonate horizon suggest that reduction in association with decomposition of organic matter would have proceeded in the host sediments.     

西太暖池区生物组分对海底表层沉积物物理力学性质的影响

西太平洋暖池区是指位于热带西太平洋及印度洋东部海表温度常年在28 ℃以上的海域,是全球海表温度最高的深海区,构造环境与沉积环境复杂,沉积物中的生物组分含量差异较大,生物组分会对深海沉积物物理力学性质产生显著影响,但目前对沉积物中生物组分含量和沉积物物理力学性质之间的相关性关系尚不明确。本文对西太平洋暖池区核心部位的表层沉积物样品进行现场物理力学性质测试和室内涂片鉴定,研究深海表层沉积物的物理力学性质与生物组分之间的关系。结果表明:研究区表层沉积物含水率范围为61.1%~435.1%,天然密度范围为1.04~1.76 g/cm³,贯入阻力范围为0~100 kPa,十字板剪切强度范围为0~8.6 kPa,整体具有高含水率、低密度、低强度等典型的深海沉积物物理力学性质特点。西加洛林海脊、海山等CCD以浅的区域为钙质生物组分>50%的钙质沉积区;西加洛林海槽西南部及其周边的深水沟槽地区一般为硅质生物组分>50%的硅质沉积;西加洛林海盆内部则主要为黏土沉积区。随钙质生物组分减少和硅质生物组分增多,表层沉积物类型分别为钙质沉积物、黏土沉积物和硅质沉积物,天然含水率变高,天然密度、贯入阻力和十字板剪切强度降低,表明深海表层沉积物的物理力学性质与生物组分含量密切相关:贯入阻力、十字板剪切强度、天然密度与钙质生物组分含量呈正相关,与硅质生物组分含量呈负相关;而天然含水率正好相反,与钙质生物组分含量呈负相关,与硅质生物组分含量呈正相关。本文建立了深海沉积物中生物组分与物理力学性质之间的相关关系,提出了沉积物生物组分含量与物理力学性质之间的拟合公式,可以为深海沉积物工程性质的评价提供参考。     

尼罗河与长江三角洲晚更新世末期硬土层特征及其成因对比研究

作者根据多年来在尼罗河与长江三角洲工作中所获大量实测资料，探讨两个三角洲晚更新世末期硬土层沉积特征、时空分布及其成因；剖析干旱性气候和湿冷性气候对三角洲硬土层成因的影响；指出两个三角洲晚更新世末期的硬土层主要为洪水泛滥堆积物，但在枯水期受到了风的改造。     

Quaternary iron-manganese deposits and associated pelagic sediments (radiolarian clay and chert, gypsiferous mud) from the Tyrrhenian Sea

Various types of pelagic sediments occur on a dolomitic basement located at some 1000 m depth on the eastern slope of the Tyrrhenian Sea, i.e. in the most internal, collapsed and presently submerged portion of southern Apennines. The deposits include laminated limonites, muds with manganosiderite nodules, radiolarian clays, opal chert, gypsiferous muds, lutites with calcareous plankton, and all are of Quaternary age. They are interpreted as products of the interactions between submarine hydrothermal activity and deep-sea sediments, and represent the first documented case of submarine hydrothermal sediments not directly connected to active ridges or volcanic buildings and deposits. The iron-rich sediments are very similar to many other reported examples of submarine thermal activity. The radiolarian clay displays very abundant and almost exclusively radiolarian tests, and no calcareous fossils, but shows numerous dissolution traces of carbonate skeletons. It has been interpreted as deriving from a primary bloom of siliceous plankton followed by an extensive leaching of the calcareous tests on the seafloor. The radiolarian chert shows a very early and yet unknown Opal-A cement. The immediate source of the cement is biogenous silica, whereas the ultimate source is the bloom of siliceous plankton triggered by the hydrothermal and volcanic activity. The gypsum muds are the result of a hydrothermal chemical remobilization of the Messinian sulphate beds which overlie the dolomitic basement.     

青藏高原北部可可西里库赛湖年纹层微区分析及形成机理

湖泊年纹层是进行高分辨率古气候环境研究的重要载体之一,其形成机理的研究能够为高分辨率古气候环境信息的提取提供重要的依据。本文以青藏高原北部可可西里库赛湖沉积的年纹层为研究对象,通过纹层薄片显微镜观察,以及纹层的扫描电镜、X衍射和同步辐射X射线荧光等微区分析,对库赛湖沉积年纹层的形态、沉积和成分特征进行了研究,以探讨库赛湖年纹层形成过程和机理。结果表明:年纹层层偶由深浅相间的微层组成,深色层主要由灰褐色—黑褐色的粗颗粒物质组成,磨圆中等、分选性差,矿物以石英、长石、白云母、黏土矿物等为主,其中石英含量占73%左右,且具有明显的风力搬运特征;浅色层呈灰白色,矿物颗粒较细,除石英、长石、白云母、黏土外,还有自生的文石,同时浅色层中含有大量的枝角类碎片和半月形介形类生物壳体。研究认为,库赛湖冬季温度低、风力强劲,风的机械搬运作用使大量的陆源物质在冰面堆积,等到春季湖泊开封,冰面上粗颗粒物质沉积到湖底形成库赛湖年纹层的深色层(粗颗粒层);夏季温度升高,冰雪融化,降水增加,河流搬运的陆源粗颗粒物质由于重力作用先在湖泊边缘沉积,而黏土矿物等细颗粒物质则在湖泊中心沉积,同时夏季湖水温度升高,蒸发作用加强,生物活动增强,湖泊自身的生物、化学作用加强,从而形成以细碎屑矿物、生物残体、自生碳酸盐沉积为主的浅色层(细颗粒层)。因此,库赛湖的年纹层层偶是由冬季冰面风成物质形成的粗颗粒深色层(冰融化后,风成物质沉降至湖底堆积)和夏季沉积的细颗粒浅色层两者交替而形成的。     

Geochemistry of ferromanganese nodule–sediment pairs from Central Indian Ocean Basin

Fourteen ferromanganese nodule–sediment pairs from different sedimentary environments such as siliceous ooze (11), calcareous ooze (two) and red clay (one) from Central Indian Ocean Basin (CIOB) were analysed for major, trace and rare earth elements (REE) to understand the possible elemental relationship between them. Nodules from siliceous and calcareous ooze are diagenetic to early diagenetic whereas, nodule from red clay is of hydrogenetic origin. Si, Al and Ba are enriched in the sediments compared to associated nodules; K and Na are almost in the similar range in nodule–sediment pairs and Mn, Fe, Ti, Mg, P, Ni, Cu, Mo, Zn, Co, Pb, Sr, V, Y, Li and REEs are all enriched in nodules compared to associated sediments (siliceous and calcareous). Major portion of Si, Al and K in both nodules and sediments appear to be of terrigenous nature. The elements which are highly enriched in the nodules compared to associated sediments from both siliceous and calcareous ooze are Mo – (307, 273), Ni – (71, 125), Mn – (64, 87), Cu – (43, 80), Co – (23, 75), Pb – (15, 24), Zn – (9, 11) and V – (8, 19) respectively. These high enrichment ratios of elements could be due to effective diagenetic supply of metals from the underlying sediment to the nodule. Enrichment ratios of transition metals and REEs in the nodule to sediment are higher in CIOB compared to Pacific and Atlantic Ocean. Nodule from red clay, exhibit very small enrichment ratio of four with Mn and Ce while, Al, Fe, Ti, Ca, Na, K, Mg, P, Zn, Co, V, Y and REE are all enriched in red clay compared to associated nodule. This is probably due to presence of abundant smectite, fish teeth, micronodules and phillipsite in the red clay. The strong positive correlation (r ? 0.8) of Mn with Ni, Cu, Zn and Mo and a convex pattern of shale-normalized REE pattern with positive Ce-anomaly of siliceous ooze could be due to presence of abundant manganese micronodules. None of the major trace and REE exhibits any type of inter-elemental relationship between nodule and sediment pairs. Therefore, it may not be appropriate to correlate elemental behaviour between these pairs.     

Upper quaternary laminated sapropelic sediments from the continental slope of Baja California

Core MD02-2508 retrieved from the plateau of the continental slope off Baja California recovered a 40-m-thick section of sapropel (up to 15% C_org), calcareous clay, and diatom ooze with the age of 120 ka at the core bottom. The section is subdivided into three units: Unit I (Holocene) consists of the laminated sapropel; Unit II comprising oxygen isotope stages (MIS) 2, 3, and 4 is represented by homogeneous calcareous clay with interbeds of slightly siliceous sapropelic mud; and Unit III (MIS-5) is composed of laminated sapropelic diatom ooze. Laminated intervals are characterized by the intercalation of two lamina types: (1) dark-colored organic-rich laminae containing multi-species “oceanic” diatom assemblages, as well as radiolarians, coccoliths, planktonic and benthic foraminifera; (2) lighter-colored laminae consisting of diatom ooze with the neritic colonial diatom assemblages commonly composed of one to three species of a single genera. The dark laminae are assumed to be generated within a high productivity zone over the slope, whereas light ones likely represent diatom mats produced by short-term boisterous phytoplankton blooms, possibly in the coastal upwelling.