Phosphorus dynamics in water and sediments in urbanized and non-urbanized rivers in Southern Brazil

Phosphorus flux models show that the removal tends to be a common feature in polluted estuarine systems whereas the release of P to the adjacent coastal area occurs in pristine environments. This study analyzes the distribution of P in water and sediments along six rivers in the south coast of Brazil. Three rivers located inside protected areas were considered non-polluted and used as a control of urbanization. The other three, situated within urbanized areas, were considered as having highly elevated concentrations of P. Results showed a different behavior of P in water and sediments located in urbanized and non-urbanized areas. The concentrations of dissolved organic (P-org) and inorganic (P-inorg) phosphorus in water, and the total phosphorus (P-tot) and polyphosphate (P-poly) in sediments where higher in the urbanized rivers compared to the non-urbanized ones. Both P of punctual origin and of diffuse origin contributed to the maintenance of elevated concentrations and disturbed the natural fluxes along the polluted rivers. The minimum and maximum concentrations in urbanized areas varied from 0.39 to 12.45 (microM) for P-org and 0.00 to 5.92 (microM) for P-inorg in water, and in sediments from 89.90 to 808.16 (microM g(-1)) for P-tot and 0.00 to 76.51 (microM g(-1)) for P-poly. In non-urbanized areas concentrations in water varied from 0.22 to 1.20 (microM) for P-inorg and 4.43 to 5.56 (microM) for P-org, and in sediments from 45.91 to 652.26 (microM g(-1)) for P-tot and 0.00 to 8.61 (microM g(-1)) for P-poly. Using a hierarchical sampling design and a simple model of variation of P (K(d) model) it was possible to demonstrate that urbanized and non-urbanized estuaries may act as sinks or sources of P. The variation of P analysis in different points along each of the six rivers showed that release and removal areas may occur within a same river independently of its urbanization.     

Retardation of organic contaminants in natural fractures in chalk

Transport of a conservative compound and two sorbing compounds through fractured chalk was studied using flow-through columns consisting of chalk cores with a single subvertical fracture. Two types of chalk matrix were compared, an oxidized white chalk with low organic carbon content (0.2%), and a gray chalk with a higher organic carbon content (1.3%). Initial rapid breakthrough followed by a delayed approach to a relative concentration of unity for the conservative compound (2,6–difluorobenzoic acid [DFBA]) was clear evidence for diffusion into the porous chalk matrix. Matrix diffusion of DFBA was apparently much greater in the gray chalk columns than in the white chalk columns. Breakthrough curves (BTCs) of the sorbing compounds (2,4,6–tri-bromophenol [TBP] and ametryn [AME]) were retarded in all cases as compared to the conservative compound. Sorption retardation was far greater in the gray chalk as compared with the white chalk, in good agreement with results from batch sorption experiments. BTCs for the conservative compound were relatively nonhysteretic for both white and gray chalk columns. In contrast, BTCs for the sorbing compounds were hysteretic in all cases, demonstrating that sorption was not at equilibrium before desorp-tion began. These experiments suggest that on a field scale, transport of contaminants through fractures in chalk and other fractured porous media will be attenuated by diffusion and sorption into the matrix.     

骆马湖营养盐收支

根据对骆马湖1998年度营养盐（氮,磷）收入和支出的研究,结果表明,入湖氮,磷量分别为15764．78t和1035．53t,其中通过河道入湖的氮磷量最大,其年入湖氮磷量分别为13598．05t和942．35t,分别占总来源量的86．3％和91．0％,氮,磷在骆马湖湖体中的滞留量和沉降量较,滞留量分别为1532．65t和221．63t,分别占总来源量的9．7％和21．4％,沉积量分别为205．47t和199．95吨,分别占总业源量的1．3％和19．3％,湖水氮,磷蓄积变化大,湖水浓度升高较快,氮磷负荷较大,年平均负荷量分别为总氮42．04％g/m^2和总磷2．76g/m,^2。     

Permeability profiles in granular aquifers using flowmeters in direct-push wells

Numerical hydrogeological models should ideally be based on the spatial distribution of hydraulic conductivity (K), a property rarely defined on the basis of sufficient data due to the lack of efficient characterization methods. Electromagnetic borehole flowmeter measurements during pumping in uncased wells can effectively provide a continuous vertical distribution of K in consolidated rocks. However, relatively few studies have used the flowmeter in screened wells penetrating unconsolidated aquifers, and tests conducted in gravel-packed wells have shown that flowmeter data may yield misleading results. This paper describes the practical application of flowmeter profiles in direct-push wells to measure K and delineate hydrofacies in heterogeneous unconsolidated aquifers having low-to-moderate K (10(-6) to 10(-4) m/s). The effect of direct-push well installation on K measurements in unconsolidated deposits is first assessed based on the previous work indicating that such installations minimize disturbance to the aquifer fabric. The installation and development of long-screen wells are then used in a case study validating K profiles from flowmeter tests at high-resolution intervals (15 cm) with K profiles derived from multilevel slug tests between packers at identical intervals. For 119 intervals tested in five different wells, the difference in log K values obtained from the two methods is consistently below 10%. Finally, a graphical approach to the interpretation of flowmeter profiles is proposed to delineate intervals corresponding to distinct hydrofacies, thus providing a method whereby both the scale and magnitude of K contrasts in heterogeneous unconsolidated aquifers may be represented.     

Spatial variability in beach biogeomorphology in a tropical archipelago

Beaches of tropical island coasts exhibit high levels of diversity in composition and form in comparison with their continental counterparts. To investigate the nature and origin of this diversity, individual beach morphology and sedimentology was investigated in the British Virgin Islands (BVI), a Caribbean archipelago of > 60 high volcanic and low reef islands. The islands exhibit a diversity of orientations (some facing the Atlantic and some the Caribbean), elevation and gradient, rock type and wave energy. An examination of 100 beaches in the archipelago revealed a first-order division into sand (70 beaches) and coral rubble (30 beaches). These beaches occur in seven planform types (determined by the antecedent geological framework) and are further subdivided according to shoreface type (seagrass, sandy shoreface, or reef). Mainland-attached headland-embayment beaches are the most common form of sand beach while coral rubble beaches usually occur as barriers that enclose salt ponds and wetlands. Among sand beaches, carbonate content is greatest on Atlantic-facing beaches, and coral rubble beaches are more common on Caribbean-facing beaches. Grain size characteristics on sandy beaches are highly variable and range from fine to very coarse sands while coral rubble beaches range up to boulder-sized clasts. The local source material is a primary determinant of sediment composition. The local factors such as the underlying geology, source and availability of sediments are the primary determinants of beach form, composition and texture in the BVI. Oceanographic and climatic conditions such as the prevailing easterly trade winds and waves which seasonally range in direction from east-northeast to southeast as well as beach orientation to Atlantic- or Caribbean-facing waves also contribute to the variability, but in a secondary role. © 2019 John Wiley & Sons, Ltd.     

Environmental change in Jiaozhou Bay recorded by nutrient components in sediments

Inorganic or bulk organic chemical indicators, including organic carbon (OC), total nitrogen, organic nitrogen (ON), fixed ammonium (N_fix), exchangeable ammonium, exchangeable nitrate, organic phosphorus (OP), inorganic phosphorus (IP), and biogenic silica (BSi), were examined in a 3-m core collected in Jiaozhou Bay (JZB) to decipher how the environment has changed during the preceding two centuries of increasing anthropogenic influence in this region. Concentrations of BSi, OC, and OP reveal overall increases to ca.30 cm (∼1984), then decreased toward the surface, probably reflecting a decrease in the productivity of overlying waters since 1984. Aquaculture might play an important role in the decrease of nutrient elements in the upper layers recorded in sediments. The decreased molar BSi/OC ratios upcore may be due to a change in dominance from large- to small-sized diatoms, as shown in other research. However, the shift may also be related to changes from heavily-silicified to lightly-silicified diatoms or to non-siliceous forms such as dinoflagellates. ON concentrations increased towards the surface sediment, which is most likely consistent with the increase in fertilizer application and wastewater discharge. Concentrations of IP, total P, and N_fix all decreased conspicuously upcore at 41 cm depth (∼1977), and were largely consistent with the decrease in rainfall and freshwater discharge to JZB. Our data suggest that the environment has significantly changed since the1980s. Anthropogenic activities in the watersheds may exert a substantial influence on carbon cycling processes in estuaries and potentially the coastal ocean.     

Water quality and presence of pesticides in a tropical coastal wetland in southern Mexico

The water quality of the Pozuelos-Murillo lagoon system in southern Mexico was evaluated during three periods between March and October 2002, with particular emphasis on the detection of organochlorine and organophosphorous pesticide residues in water and sediments. Physicochemical and microbiological parameters of water were also measured and integrated in a water quality index (WQI). Multivariate analysis was used to regionalise the lagoon system as a function of the behaviour of all measured parameters. Solid phase micro-extraction followed by gas chromatography (SPME-GC) was used for pesticide analysis. The concentration of phosphorous was found to be higher than that of nitrogenous compounds. This, besides a deficiency in dissolved oxygen and a high organic matter concentration (as COD), reflects eutrophication processes in some areas of the system. Measured levels of faecal coliforms and oils and greases were above the limits established by Mexican law and comparable to the concentrations reported for other highly polluted systems in Mexico. Residues of DDD (2.0 microg L(-1)) in water and DDE (247 ng g(-1)) and endosulfan I (814 ng g(-1)) sediments were detected by SPME-GC. The spatial distribution of these contaminants implies major potential risks because the most polluted sites were found to be those with the highest fishing activity. Although in general the WQI is on acceptable levels (65-80%), some contamination problems are evident.     

Short-term changes in global cloud cover and in cosmic radiation

Galactic cosmic rays (GCR) have been suggested as a possible contributory mechanism to cloud formation. If these are significant then, in addition to the similarity between long-term (years) changes in GCR and cloud cover, there should also be a similarity over shorter (days) time scales. This paper reports an analysis of changes in global cloud cover and GCR recorded at 3 hourly intervals over 22 years. There is a significant correlation between short-term changes in low cloud cover over northern and southern hemispheres, consistent with about 3% of the variation arising from common factors. However, GCR is not a major factor responsible for cloud cover changes. There is an association between short-term changes in low cloud cover and galactic cosmic radiation over a period of several days. This could arise if approximately 3% of the variations in cloud cover resulted from GCR.     

Estimation of particulate organic carbon flux in relation to photosynthetic production in a shallow coastal area in the Seto Inland Sea

Sediment trap experiments were carried out three times from 1999 to 2000, in the western part of the Seto Inland Sea (Suo-Sound), Japan. We investigated both the particulate flux and the composition of chemical substances in the sediment trap samples. Based on the results, we discuss the origin of particulate organic carbon (POC) collected by the sediment traps in a coastal area. Moreover, we purposed to estimate the flux of the portion of the POC that is derived from phytoplankton photosynthesis. The fluxes of POC varied between 677 and 3424 mgC m(-2) d(-1). Significant positive correlations between POC and aluminum (Al) fluxes suggested that these components show almost the same behaviour. The mean value of the Al flux was about eight times higher than that of Al burial rates on the sediment surface. Therefore, it seems that the POC flux observed with the sediment traps was considerably overestimated. Moreover, judging from the fact that Al is a typical terriginous element, it seems that most of the POC collected in the sediment traps derived from the re-suspended surface sediment or sediment transported laterally from shallow flanks such as intertidal mudflats. The fluxes of chlorophyll a (Chl a) were independent of the POC fluxes, and a relatively consistent correlation was found between Chl a abundance in the water column and the Chl a flux. Moreover, surface sediment Chl a content was approximately 100 times lower than that of suspended matter. Therefore, resuspension and terriginous contributions to Chl a collected in sediment traps are likely to be negligible. The POC content in the trap samples varied between 22.4 and 70.7 mg g(-1) dry weight. The variations of POC contents were positively correlated with the Chl a contents: POC(mg g(-1))=76.5 x Chl a(mg g(-1)) + 26.0 (r=0.95, p<0.01, n=9). This result shows that POC contents strongly corresponded with phytoplankton and their debris. It was also considered that the fraction of POC derived from phytoplankton primary production could be estimated as Chl a content times a certain factor. In this study, we estimated the flux of the portion of the POC originating from phytoplankton production by multiplying the Chl a fluxes by 76.5 (the mean POC:Chl a ratio in the trap samples). These values varied between 308 and 758 mgC m(-2) d(-1), and accounted for 35.1+/-21.2% of total POC flux. Although the amount of POC that originates from phytoplankton photosynthesis was a small portion of total POC flux, it seems to be a large portion of potential primary production in the water column.     

Special points in 11-year variations in the latitudinal characteristics of sunspot activity

It has been indicated that special moments (turning points), when certain characteristics of the latitudinal (equatorward) drift of the sunspot drift zone suddenly change, exist in each 11-year solar cycle. The moment when a sunspot formation low-latitude boundary minimum (T2), coordinated in time with the end of a polar magnetic field polarity reversal, exists has a special place among these points. A conclusion has been drawn that it is impossible to reconstruct polarity reversal moments in the past based on information about turning points T2. The average velocities of the latitudinal drift of the minimal, average, and maximal sunspot group latitudes have been calculated. It has been indicated that the closeness of the relationship between the first two velocities and the maximal activity amplitudes in the cycles differ substantially for the first (before point T2) and second (after point T2) cycle parts. The corresponding values of the correlation coefficients increase substantially in the second cycle (after point T2). It has been established that a relationship exists between some velocities calculated in these cycles and the activity amplitudes at maximums of the next cycles. A model for predicting future cycle maximums has been constructed based on this conclusion. The probable average annual Wolf number at a maximum of cycle 24 has been determined (W(24) = 93).     

Multiphysics modeling of CO2 sequestration in a faulted saline formation in Italy

The present work describes the results of a modeling study addressing the geological sequestration of carbon dioxide (CO₂) in an offshore multi-compartment reservoir located in Italy. The study is part of a large scale project aimed at implementing carbon capture and storage (CCS) technology in a power plant in Italy within the framework of the European Energy Programme for Recovery (EEPR). The processes modeled include multiphase flow and geomechanical effects occurring in the storage formation and the sealing layers, along with near wellbore effects, fault/thrust reactivation and land surface stability, for a CO₂ injection rate of 1 × 10⁶ ton/a. Based on an accurate reproduction of the three-dimensional geological setting of the selected structure, two scenarios are discussed depending on a different distribution of the petrophysical properties of the formation used for injection, namely porosity and permeability. The numerical results help clarify the importance of: (i) facies models at the reservoir scale, properly conditioned on wellbore logs, in assessing the CO₂ storage capacity; (ii) coupled wellbore-reservoir flow in allocating injection fluxes among permeable levels; and (iii) geomechanical processes, especially shear failure, in constraining the sustainable pressure buildup of a faulted reservoir.     

Diurnal variation in the effect of the weekend in global seismic activity

The influence of the earthquake probability diurnal variation on specific features in the weekend effect in global seismic activity is revealed. The dependence of the global earthquake number on the local time and its possible relation to a quiet solar diurnal variation (Sq) in the geomagnetic field have been considered in detail. It has been indicated that a stable diurnal effect, which has a maximum near midnight and a minimum near local noon, exists in the global seismicity of the Earth. The diurnal variation amplitude changes insignificantly during days of week and substantially decreases (by a factor of almost 3) on Saturday and Sunday. The weekend effect is not revealed during “local nights.” Since the daily effect of a quiet solar diurnal variation (Sq) should not depend on days of week, we arrive at the conclusion that the diurnal variation in global seismicity evidently contains the anthropogenic activity product. The Sunday effect in the earthquake number decreases over the course of time and is most probably real but weak and not stationary since weekly variations occur against a background (or under the action) of stronger variations, i.e., an increase in the earthquake number and diurnal variations.     

Bacterial community and some physico-chemical characteristics in a subtropical mangrove environment in Bahrain

A study of bacterial communities and some physico-chemical parameters of a subtropical mangrove habitat in the Arabian Gulf (Bahrain) was carried out in 1993-1994. Six stations at different parts of the tidal channel were selected for sampling. The mangrove habitat was found to harbor diverse bacterial communities, included among them anoxygenic phototrophs (AP), oxygenic phototrophs (OP), organotrophs (OT), total coliforms (TC), faecal coliforms (FC) and haloalkaliphiles (HA). Spatial and temporal variations in bacterial communities and environmental parameters were found. Each of the OT, AP, TC, and FC were dominant in the innermost stations (S1&S2) and gradually decreased seaward. The HA community on the other hand, was dominant at the seaward stations (S5&S6) and was most likely to have originated from the sea through the tidal flows. Both AP and OT were considered as part of the mangrove native flora, whereas TC and FC were alien and believed to have been introduced through partially treated sewage released at the upstream of the tidal channel. Closely monitoring of the mangrove water revealed succession pattern in bacterial communities. The AP community was predominant from November 1993 to March 1994, succeeded by dominance of OP from June 1994 to October 1994. Both bacterial blooms gave water a pinkish, purple, or green color, respectively. Although OT prevailed during Transitional period between AP and OP eutrophication, it remained comparatively constant (not less than 2 x 10(5)cfu/ml) through other periods. Frequent eutrophication phenomena of OP, which took place in summer and autumn, coincided with increases in water temperature, chlorophyll a, and nutrients (NO(3)(-) and PO(4)(-)). On the other hand, OT and AP were negatively correlated with temperature, salinity and chlorophyll a, but no specific pattern was observed in relation to NO(3)(-) and PO(4)(-). In comparison with seawater, nutrients such as NO(3)(-) and PO(4)(-) were consistently higher in the mangrove habitat. Partially treated sewage and farm drainage canals are proposed to form additional sources of nutrients. Although, the mangrove habitat has been demonstrated to possess self-cleaning properties, data obtained suggest that anthropogenic pollution has a deleterious effect.     

Effects in cosmic rays in March 1991

Using the spectrographic global survey method, variations in the rigidity spectrum and anisotropy of galactic cosmic rays (March 1991) have been studied using data from ground-based observations of cosmic rays (CR) at the worldwide network of stations. Variations in geomagnetic cutoff rigidity (GCR) have been calculated. The paper also presents latitudinal GCR variations at certain moments of the considered period for different geomagnetic field disturbance levels. Calculation results of GCR variations have been compared with those of effect of the westward current flowing with a strength proportional to the latitude cosine along parallels on the sphere, for different radii of the current ring in the dipole field.     

Variation in transparent exopolymer particles in relation to biological and chemical factors in two contrasting lake districts

In inland waters, transparent exopolymer particles (TEP) can affect carbon export and sequestration in sediments with consequences for lake C budgets. We measured TEP concentration in 32 lakes from two contrasting lake districts covering wide ranges in biological and chemical characteristics. North temperate lakes, located in a wet region, have low to moderate ionic strength and low to high dissolved organic carbon with corresponding variation in color (light absorbance). Mediterranean lakes located in a semiarid region were characterized by high ionic strength and high concentrations of dissolved organic carbon but low color. TEP concentrations were large relative to the living portion of the particulate organic carbon pool in both Mediterranean (36%) and north temperate (33%) lakes. TEP concentrations ranged from 36 to 1,462 μg [as Gum Xanthan equivalents (GX eq)] L⁻¹ in north temperate lakes. In the Mediterranean lakes, concentrations were higher that previously reported for other systems and ranged from 66 to 9,038 μg GX eq L⁻¹. TEP concentration was positive and significantly related to chlorophyll a (chl a) in north temperate lakes and in the entire data set. Although a significant and positive relationship between TEP and chl a was also detected in the Mediterranean lakes, bacterial abundance was most strongly related to TEP. In contrast with the positive influence of phytoplankton and bacteria on TEP, there were weaker relationships between TEP and the chemical variables tested. We observed a significant and positive relationship between pH and TEP (for all lakes) but this relationship was indirectly driven by a co-variation of pH with phytoplankton biomass based on multiple regression analysis. For the Mediterranean lakes, the negative (but not significant) trends between TEP and both conductivity and divalent cations suggest thresholds above which TEP will likely be destabilized. Under these conditions, TEP may flocculate or disperse in the water column.     

Rainfall interception in three contrasting lowland rain forest types in Central Kalimantan, Indonesia

Rainfall interception was quantified and modeled for a Lowland Evergreen Rain Forest (LERF) and two Heath Forests (HF) of contrasting stature during a one-year period at a remote site in Central Kalimantan, Indonesia. Throughfall was measured using a roving gauge approach using 18–20 gauges per forest type. Throughfall was 82.8% of incident rainfall in the LERF vs. 89.1% in tall HF and 76.7% in stunted HF. Corresponding stemflow fractions were 0.8%, 1.3% and 2.0% of rainfall, respectively. Interception losses derived for the LERF (16.4%) and the tall HF (9.6%) were close to findings obtained for similar forest types elsewhere but the high interception loss for the stunted HF (21.3%) was unexpected. On the basis of canopy structural characteristics and wet canopy evaporation modeling it is concluded that throughfall in the stunted HF was underestimated and that the specific nature of the HF required a more intensive sampling arrangement. Throughfall sampling schemes in tropical forests, associated errors and hydrological implications are discussed.     

The role of the stratosphere in Iberian Peninsula rainfall: A preliminary approach in February

This paper attempts to establish a connection between stratospheric anomalies in the North Pole and rainfall on the Iberian Peninsula through the occurrence of major midwinter warmings (MMWs) and cold events (CEs), taking February as a preliminary approach. We define the MMWs as the warmings which break down the polar vortex, whereas the CEs are the episodes in which the polar vortex remains cold and undisturbed. Both anomalies lead to a wind anomaly around the north polar stratosphere, which is connected with a shortly lagged tropospheric anomaly through a stratosphere–troposphere coupling in winter. A T-mode principal component analysis (PCA) was used as an objective pattern classification method for identifying the main daily surface-level pressure (SLP) patterns for February for the 1961–1990 reference period. Subsequently, those February months with an MMW or a CE influence in the troposphere are identified in the whole study period (1958–2000) by means of the Arctic Oscillation Index (AOI). Thus, performing the same analysis for the selected February months, new principal patterns for detecting changes in surface circulation structure and morphology are obtained. The results show a significant decrease in the westerlies and a southward shift of the storm tracks in Western Europe some weeks after an MMW occurrence, leading to an increase in precipitation in western Iberia and a slight decrease on the eastern Mediterranean fringe. The results are quite the opposite under a CE influence: the westerlies are strengthened and shifted northwards due to the displacement of the Atlantic anticyclone towards Central Europe; dry conditions are established throughout Iberia, except for the Mediterranean fringe, where precipitation shows a considerable increase due to the greater frequency of the northeasterly winds. Finally, an 11-year sunspot cycle–quasi-biennial oscillation (QBO) modulation might be demonstrated in Iberian rainfall in February through the occurrence of these stratospheric anomalies.     

Screening of Emerging Volatile Organic Contaminants in Shallow Groundwater in East China

In order to collect baseline information on the environmental occurrence of volatile organic compounds (VOCs) in groundwater in East China, shallow groundwater samples were collected from five alluvial plains in East China in 2008 to 2009. All samples were analyzed for 54 VOCs representing a wide variety of uses and origins. Sampling sites were mainly selected in the areas to be susceptible to contamination from human activities in terms of previous hydrogeological survey. The data of all samples showed a variety of different hydrogeological systems with potential sources of VOCs, with 36 of the 54 VOCs being found. The most frequently detected compounds include naphthalene (56.9%), chloroform (16.9%), 1,2‐dichloroethane (16.2%), 1,2‐dichloropropane (13.1%), and 1,2,3‐trichlorobenzene (12.3%). The concentrations of methylene chloride, 1,2‐dichloroethane, carbon tetrachloride, trichloroethene, 1,2‐dichloropropane, and tetrachloroethene exceeded the relating drinking water standards. Future work will be needed to identify those factors that are most important in determining the occurrence and concentrations of VOCs in groundwater in China.     

龙感湖水生植被

于１９９３年９月对龙感湖水生植被及环境进行了调查研究。龙感湖有水生植物２６科３８属５０种,依据优势种群划分９个群丛,其分布面积２８３．５ｋｍ＾２,占全湖总面积的８９．７％,植被现有年生产力达２１４７７３０ｔ,对渔业生产和生态环境具有十分重要的意义。建议对该湖植被应合理开发利用,如果围网养鱼得到广泛地发展,渔业生产潜力每年可达４１８１．８ｔ。