One Million Years tephra record at IODP Sites U1436 and U1437: Insights into explosive volcanism from the Japan and Izu arcs

The 1 Myr tephra records of IODP (International Ocean Discovery Program) Holes U1436A and U1437B in the Izu‐Bonin fore‐ and reararc were investigated in order to assess provenance and eruptive volumes, respectively. In total, 304 tephra samples were examined and 260 primary tephra layers were identified. Tephra provenance was determined by means of major and trace element compositions of glass shards and distinguished between Japan and Izu‐Bonin arc origin of the tephra layers. A total of 33 marine tephra compositions were correlated to the Japan arc and 227 to the Izu arc. Twenty marine tephra layers were correlated between the two drilling sites. Additionally, we defined eleven correlations of marine tephra deposits to major widespread Japanese eruptions; from the 1.05 Ma Shishimuta‐Pink Tephra to the 30 ka Aira‐Tn Tephra, both from Kyushu Island. These eruptions provide independent time markers within the sediment record and six correlations were used to date tephra layers from Japan in Hole U1436A to establish an alternative age model for this hole. Furthermore, the minimum distal tephra volumes of all detected events were calculated, which enabled the comparison of the tephra volumes that derived from the Japan and the Izu‐Bonin arcs. For some of the major Japanese eruptions these are the first volume estimations that also include distal deposits. All of the Japanese tephras derived from events with eruption magnitude M_v ≥ 5.6 and three of the investigated eruptions reach magnitudes M_v ≥ 7. Volcanic events of the Izu‐Bonin arc have mostly eruption magnitudes M_v ≤ 5.     

Late cenozoic clockwise rotation of Sumatra

A clockwise rotation of Sumatra of about 20° about an axis located in or near the Sunda Strait has been inferred on the basis of the following data:(1) The portion of the Indonesian volcanic arc between the Sunda Strait and the island of Timor lies along a small circle whose center is located about 32°N, 119°E. The volcanic chain of Sumatra makes an angle of 20° with this portion of the arc.(2) The Benioff zone of Indonesia has a maximum depth of 600 km to the east of the Sunda Strait, but the maximum depth decreases to 200 km northwestward along the island of Sumatra.(3) The age of the present phase of volcanic activity in Indonesia is proportional to the maximum depth of the Benioff zone; rhyolitic tuffs of the Sunda Strait range in age from Late Miocene to Pleistocene, while ignimbrites of north Sumatra are about 70,000 years old.It is suggested that the increase in sea-floor spreading rate since 10 m.y. B.P. pushed north Sumatra and Malaya northeastward for about 500 km along the system of presently inactive faults, causing a clockwise rotation of both Sumatra and Malaya about an axis located in or near the Sunda Strait. Only when this rotation ceased did the underthrusting of north Sumatra begin, producing a shallow and short Benioff zone, and delayed volcanic activity.     

The exceptional magnitude and intensity of the Toba eruption,sumatra: An example of the use of deep-sea tephra layers as a geological tool

The eruption of Toba (75,000 years BP), Sumatra, is the largest magnitude eruption documented from the Quaternary. The eruption produced the largest-known caldera the dimensions of which are 100 × 30 km and which is surrounded by rhyolitic ignimbrite covering an area of over 20,000 km². The associated deep-sea tephra layer is found in piston cores in the north-eastern Indian Ocean covering a minimum area of 5 × 10⁶ km². We have investigated the thickness, grain size and texture of the Toba deep-sea tephra layer in order to demonstrate the use of deep-sea tephra layers as a volcanological tool. The exceptional magnitude and intensity of the Toba eruption is demonstrated by comparison of these data with the deep-sea tephra layers associated with the eruptions of the Campanian ignimbrite, Italy and of Santorini, Greece in Minoan time. The volume of ignimbrite and distal tephra fall deposit produced in the Toba eruption are comparable, a total of at least 1000 km³ of dense rhyolitic magma. In contrast the volume of dense magma produced by the Campanian and Santorini eruptions are approximately 70 and 13 km³ respectively. Thickness versus distance data on the three deep-sea tephra layers show that eruptions of smaller magnitude than Santorini are unlikely to be preserved as distinct tephra layers in most deep-sea cores. In proximal cores all three tephra layers show two distinct units: a lower coarse-grained unit and an upper fine-grained unit. We interpret the lower unit as a plinian deposit and the upper unit as a co-ignimbrite ash-fall deposit, indicating two major eruptive phases. The Toba tephra layer is coarser both in maximum and median grain size than the Campanian and Santorini layers at a given distance from source. These data are interpreted to indicate a very high cruption column, estimated to be at least 45 km. We have applied a method for estimating the duration of the Toba eruption from the style of graded-bedding in deep-sea tephra layers. Studies of two cores yield estimates of 9 and 14 days. The eruption column height and duration estimates both indicate an average volume discharge rate of approximately 10⁶ m³/sec. The Toba eruption therefore was not only of exceptional magnitude, but also of exceptional intensity.     

Compositions of three tephra layers from the byrd station ice core, antarctica

Volcanic glass shards from three tephra layers at 788, 1457, 1711 m depth in the 2164-m Byrd Station ice core from the West Antarctic Ice Sheet were analysed by electron microprobe. Glass shards within each tephra layer are homogeneous and have peralkaline trachyte compositions. Mt. Takahe, 450 km north-northwest of the drill site is considered the most likely eruptive source, although Toney Mountain, 460 km to the north is also a possible source. Tephra layers in ice cores from the West Antarctic ice sheet may offer a valuable tool for stratigraphic correlation.     

Composition of widespread volcanic glass in deep-sea sediments of the Southern Pacific Ocean: an Antarctic source inferred

Widespread Plio-Pleistocene (2.43-0.06 Ma) tephra zones recognised in deep-sea cores from high latitudes (>60°) in the Southern Pacific Ocean were thought to have originated from calc-alkaline rhyolitic eruptions in New Zealand, some 5000 km distant. Electron microprobe analyses of the glasses reveal a wide diversity of alkalic felsic compositions, as well as minor components of basic and intermediate glasses, incompatible with a New Zealand Neogene source but similar to contemporaneous eruptives from the Antarctic region. Most tephra zones are trachytic; seven zones are peralkaline rhyolite. The rhyolitic zones represent a deep-sea record of widespread silicic eruptions from continental Antarctica, possibly Marie Byrd Land. The extent of these rhyolitic zones suggest a greater frequency of large explosive eruptions in Antarctica than previously documented. The coarse grain size of some of the shards (up to 3 mm), their great distance from the closest sources (>1600 km for some cores), and the presence of nonvolcanic ice-rafted debris indicate some of the glasses, especially the more basic compositions, may have been ice-rafted, contrary to previous suggestions of a fallout origin.     

The roseau ash: Deep-sea tephra deposits from a major eruption on Dominica, lesser antilles arc

Two extensive marine tephra layers recovered by piston coring in the western equatorial Atlantic and eastern Caribbean have been correlated by electron microprobe analyses of glass shards and mineral phases to the Pleistocene Roseau tuff on Dominica in the Lesser Antilles arc. Tephra deposition and transport to the deep sea was primarily controlled by two processes related to two different styles of eruptive activity: a plinian airfall phase and a pyroclastic flow phase. A plinian phase produced a relatively thin (1–8 cm) airfall ash layer in the western Atlantic, covering an area of 3.0 × 10⁵ km² with a volume of 13 km³ (tephra). The majority of the airfall tephra was transported by antitrade winds at altitudes of 6–17 km. Aeolian fractionation of crystals and glass occurred during transport resulting in an airfall deposit enriched in crystals relative to the source. Mass balance calculation based on crystal/glass fractionation indicates an additional 12 km³ of airfall tephra was deposited outside the observed fall-out envelope as dispersed ash.Discharge of pyroclastic flows into the sea along the west coast of Dominica initiated subaqueous pyroclastic debris flows which descended the steep western submarine flanks of the island. 30 km³ of tephra were deposited by this process on the floor of the Grenada Basin up to 250 km from source. The Roseau event represents the largest explosive eruption in the Lesser Antilles in the last 200,000 years and illustrates the complexity of primary volcanogenic sedimentation associated with a major explosive eruption within an island arc environment.     

Tephra layers in the Byrd Station ice core and the Dome C ice core, Antarctica and their climatic importance

Volcanic glass shards from tephra layers in the Byrd Station ice core were chemically analyzed by electron microprobe. Tephra in seven layers have similar peralkaline trachyte compositions. The tephra are believed to originate from Mt. Takahe, on the basis of their chemical similarity to analyzed rocks from Mt. Takahe and because dated rock samples from the volcano are younger than 250,000 years old. Glass shards from 726 m deep in the Dome C ice core, which is 2400 km from Byrd Station, are composed of peralkaline trachyte and may have also been derived from Mt. Takahe. The tephra could have resulted from eruptions which were triggered by increased ice loading during the late Wisconsin glaciation. Preliminary grain size data suggest the eruptions were only minor and they were unlikely to have instantaneously altered global climate as have explosive eruptions in the tropics. Nevertheless, the effect of this localized volcanic activity upon the Antarctic energy budget warrants further investigation.     

Crustal heat transfer in the Taupo Volcanic Zone (New Zealand): comparison with other volcanic arcs and explanatory heat source models

The Taupo Volcanic Zone (TVZ) is a 200-km-long volcanic arc segment which developed ≤2 Ma ago within the continental crust of the North Island of New Zealand and lies at the southern end of the much larger Tonga-Kermadec arc system. The total crustal heat transfer of the TVZ is at present c. 2600 MW/100 km, most of the heat being transferred by convective geothermal systems. The rate of transfer is anomalously high in comparison to that of other active arcs, and arguably the highest world wide for such a setting. Heat transfer of other active arcs appear to vary almost linearly with subduction speed (about 150 MW/100 km for 10 mm/yr). The mass rate of common type arc extrusions (basalts, andesites, dacites) also increases almost linearly with subduction speed. This allows separation of the TVZ heat transfer into a “normal” component, associated with extrusions and intrusions of andesites and dacites (about 600 MW/100 km), and an “anomalous” component of about 2000 MW/100 km, related to extrusions and intrusions of rhyolitic melts whose generation is not directly controlled by subduction processes.Rhyolitic melts in the TVZ are partial melts of dominantly crustal origin. Comparison with other arcs indicates that the long-term extrusion rate of TVZ rhyolites (about 400 kg/s per 100 km) is also the highest world wide for this setting. The occurrence of voluminous Quaternary rhyolitic pyroclastics is a rare phenomenon and appears to be associated with a few arc segments (TVZ, Sumatra, Kyushu) that undergo significant crustal deformation.Various models have been proposed to explain the phenomenon of the anomalously high heat transfer within the TVZ. Models which require only heat transfer from plumes and subcrustal melts, either ponded at the crust/mantle boundary or intruding a spreading crust, are not suitable because the associated heat transfer at the contact is too low by a factor 2 to explain the required transfer rate of about 0.8 W/m² representing the “anomalous” crustal heat component of the TVZ. Heat generation by focussed plastic deformation within the ductile lithosphere is an alternative mechanism to explain “endogenous crustal heating” which yields heating rates that are also too low by a factor of two, although important parameters (average yield strength of lithosphere and opening rate of the TVZ) are not well known. A further search for a suitable combination of heat source models is required.     

Permian to recent volcanism in northern sumatra,indonesia: a preliminary study of its distribution,chemistry, and peculiarities

Sumatra has been a ‘volcanic arc’, above an NE-dipping subduction zone, since at least the Late Permian. The principal volcanic episodes in Sumatra N of the Equator have been in the Late Permian, Late Mesozoic, Palaeogene, Miocene and Quaternary.Late Permian volcanic rocks, of limited extent, are altered porphyritic basic lavas interstratified with limestones and phyllites.Late Mesozoic volcanic rocks, widely distributed along and W of the major transcurrent.Sumatra Fault System (SFS), which axially bisects Sumatra, include ophiolite-related spilites, andesites and basalts. PossiblePalaeogene volcanic rocks include an altered basalt pile with associated dyke-swarm in the extreme NW, intruded by an Early Miocene (19 my) dioritic stock; and variable pyroxene rich basic lavas and agglomerates ranging from alkali basaltic to absarokitic in the extreme SW.Miocene volcanic rocks, widely distributed (especially W of the SFS), and cropping out extensively along the W coast, include calc-alkaline to high-K calc-alkaline basalts, andesites and dacites.Quaternary volcanoes (3 active, 14 dormant or extinct) are irregularly distributed both along and across the arc; thus they lie fore-arc of the SFS near the Equator but well back-arc farther north. The largest concentration of centres, around Lake Toba, includes the >2000 km³ Pleistocene rhyolitic Toba Tuffs. Quaternary volcanics are mainly calc-alkaline andesites, dacites and rhyolites with few basalts; they seem less variable, but on the whole more acid, than the Tertiary. The Quaternary volcanism is anomalous in relation to both southern Sumatra and adjacent Java/Bali: in southern Sumatra, volcanoes are regularly spaced along and successively less active away from the SFS, but neither rule holds in northern Sumatra. Depths to the subduction zone below major calc-alkaline volcanoes in Java/Bali are 160–210 km, but little over 100 km in northern Sumatra, which also lacks the regular K₂O-depth correlations seen in Java. These anomalies may arise because Sumatra — being underlain by continental crust — is more akin to destructive continental margins than typical island-arcs such as E Java or Bali, and because the Sumatran subduction zone has a peculiar structure due to the oblique approach of the subducting plate. A further anomaly — an E-W belt of small centres along the back-arc coast — may relate to an incipient S-dipping subduction zone N of Sumatra and not the main NE-dipping zone to its W. Correlation of the Tertiary volcanism with the present tectonic regime is hazardous, but the extensive W coastal volcanism (which includes rather alkaline lavas) is particularly anomalous in relation to the shallow depth (<100 km) of the present subduction zone. The various outcrops may owe their present locations to extensive fault movements (especially along the SFS), to the peculiar structure of the fore-arc (suggested by equally anomalous Sn- and W-bearing granitic batholiths also along the W coast), or they may not be subduction-related at all.     

Englacial tephrostratigraphy of Erebus volcano,Antarctica

A tephrostratigraphy for Erebus volcano is presented, including tephra composition, stratigraphy, and eruption mechanism. Tephra from Erebus were collected from glacial ice and firn. Scanning electron microscope images of the ash morphologies help determine their eruption mechanisms The tephra resulted mainly from phreatomagmatic eruptions with fewer from Strombolian eruptions. Tephra having mixed phreatomagmatic–Strombolian origins are common. Two tephra deposited on the East Antarctic ice sheet, ~ 200 km from Erebus, resulted from Plinian and phreatomagmatic eruptions. Glass droplets in some tephra indicate that these shards were produced in both phreatomagmatic and Strombolian eruptions. A budding ash morphology results from small spheres quenched during the process of hydrodynamically splitting off from a parent melt globule. Clustered and rare single xenocrystic analcime crystals, undifferentiated zeolites, and clay are likely accidental clasts entrained from a hydrothermal system present prior to eruption. The phonolite compositions of glass shards confirm Erebus volcano as the eruptive source. The glasses show subtle trends in composition, which correlate with stratigraphic position. Trace element analyses of bulk tephra samples show slight differences that reflect varying feldspar contents.     

Geochemical evidence for sundering of the West Mariana arc in miocene ash from the Parece Vela Basin

Glass and mineral fragments from discrete volcanic ash layers were sampled from DSDP/IPOD Site 450 in the Parece Vela Basin, Philippine Sea and analyzed by electron microprobe. The ashes are interpreted as eruptive products of the adjacent West Mariana arc system between 25 and 14 Ma B.P., and have compositions between basaltic andesite and rhyolite, and rarely, boninite. ‘Continuous’ chemical trends appear to reflect mixing of mafic and silicic magmas. ‘Discontinuous’ trends between these end-members are relatively few, and are consistent with ‘liquid lines’ produced by fractional crystallization. Andesitic tephra become progressively richer in MgO and CaO through the middle Miocene, while boninite appears towards the end of the sequence, between 14 and 15 Ma B.P. Coeval rhyolitic glasses become richer in K₂O and Na₂O, with maximum concentrations at about 15 Ma B.P. Chronologic changes in fractionation type and composition of parent magmas are interpreted to reflect the subaerial volcanic evolution of the West Mariana arc. The appearance of boninite is believed to signal early stages of arc sundering, and corresponds temporally with regional uplift of the sea floor above the carbonate compensation depth, precursor to a new pulse of back-arc spreading.     

Geochemistry, strontium isotope data, and potassium-argon ages of the andesite-rhyolite association in the Padang area, West Sumatra

Quaternary volcanoes in the Padang area on the west coast of Sumatra have produced two-pyroxene, calc-alkaline andesite and volumetrically subordinate rhyolitic and andesitic ash-flow tuffs. A sequence of andesite (pre-caldera), rhyolitic tuff and andesitic tuff, in decreasing order of age, is related to Maninjau caldera. Andesite compositions range from 55.0 to 61.2% SiO₂ and from 1.13 to 2.05% K₂O. Six K-Ar whole-rock age determinations on andesites show a range of 0.27 ± 0.12 to 0.83 ± 0.42 m.y.; a single determination on the rhyolitic ashflow tuff gave 0.28 ± 0.12 m.y.Eight ⁵⁷Sr/²⁶Sr ratios on andesites and rhyolite tuff west of the Semangko fault zone are in the range 0.7056 – 0.7066. These ratios are higher than those elsewhere in the Sunda arc but are comparable to the Taupo volcanic zone of New Zealand and calc-alkaline volcanics of continental margins. An ⁸⁷Sr/⁸⁶Sr ratio of 0.7048 on G. Sirabungan east of the Semangko fault is similar to an earlier determination on nearby G. Marapi (0.7047), and agrees with ⁸⁷Sr/⁸⁶Sr ratios in the rest of the Sunda arc. The reason for this distribution of ⁸⁷Sr/⁸⁶Sr ratios is unknown.The high ⁸⁷Sr/⁸⁶Sr ratios are tentatively regarded to reflect a crustal source for the andesites, while moderately fractionated REE patterns with pronounced negative Eu anomalies suggest a residue enriched in plagioclase with hornblende and/or pyroxenes. Generation of associated andesite and rhyolite could have been caused by hydrous fractional melting of andesite or volcanogenic sediments under adiabatic decompression.     

TEPHRA RECORD FROM QUANYANG PEAT OF THE CHANGBAISHAN MILLENNIUM ERUPTION

Tephra, usually produced by explosive eruptions, is deposited rapidly, hence, it can serve as a distinctive and widespread synchronous marker horizon correlating terrestrial, marine and ice core records. The tephra from Changbaishan Millennium eruption, a widely distributed tephra, is an important marker bed across the Japan Sea, Japan Islands and even in the Greenland ice cores 9000km away from volcanic vent. In this study, a discrete tephra was identified in the Quanyang peat~45km northeast to the Changbaishan volcano. Radiocarbon ¹⁴ C dating on the plant remains constrains an age of 886-1013calAD(95.4%)to the tephra layer, which can correspond to the Millennium eruption of Changbaishan in time. In addition, there was no similar volcanic eruption in the surrounding areas except Changbaishan at the same time. This tephra shows rhyolitic glass shards major element compositions similar to those rhyolitic tephra from Millennium eruption. This study illustrates that tephra from Millennium eruption has been transported to Quanyang peat~45km northwest to the Changbaishan volcano. Additionally, the diameter of the pumice lapilli is up to 0.3cm, implying that the tephra must be transported more distal away from Quanyang peat and formed a widely distributed isochronic layer. Glass geochemistry of the Quanyang tephra, different from the distal tephra recorded at Sihailongwan, Japan, and Greenland ice, shows a close affinity to the pyroclastic flow deposits of the Millennium eruption while not from fall deposits. This may indicate that distribution of the Millennium eruption of Changbaishanin in different directions may be controlled by different stages of eruption. This layer with well-defined annual results can be used to optimize the chronological framework of the corresponding sedimentary environment, thus facilitating more accurate discussion of corresponding environmental changes, which can achieve the contrast of the ancient climate records in the whole Northeast China-Japan and arctic regions.     

Incremental growth of a large volume,chemically zoned magma body: a study of the tephra sequence beneath the Rainier Mesa ash flow sheet of the Timber Mountain Tuff

The Rainier Mesa ash-flow is a large (1200 km³), 11.6 My old, chemically zoned unit that ranges in composition from 55 to 76% SiO₂ — one of the largest chemical ranges ever observed in a large volume ash-flow sheet. Two chemical trends occur in this sheet, a low silica (55–66% SiO₂) and a high silica (>66% SiO₂) trend. Ninety per cent of the Rainier Mesa sheet occurs in the high silica trend. Immediately beneath the Rainier Mesa sheet is a thick tephra sequence. The chemical variation of this sequence is nearly equivalent to the high silica portion of the Rainier Mesa ash-flow sheet (about 66–78% SiO₂). Throughout the tephra sequence numerous small ash-flow layers occur, and each ash-flow layer is chemically zoned from more evolved at the base to less evolved at the top. This is consistent with having been erupted from a zoned magma body. The lowest silica tephra units are at the base of the sequence and the highest silica units are at the top — that is, the large-scale chemical trend of the entire sequence is opposite to that of the individual ash-flow layers. These ash-flow layers are of very small volume. The tephra sequence provides a unique record of the incremental development of the zoned, high silica portion of the Rainier Mesa magma body.     

Geochemistry of quaternary volcanism in the Sunda-Banda arc, Indonesia, and three-component genesis of island-arc basaltic magmas

Volcanic rocks of the Sunda and Banda arcs range from tholeiitic through calcalkaline and shoshonitic to leucititic, the widest compositional span of mafic magmatism known from an active arc setting.Mafic rocks in our data set, which includes 315 new analyses of volcanic rocks from twelve Quaternary volcanoes, including Batu Tara in the previously geochemically unknown Flores-Lembata arc sector, are generally similar to those from other island arcs: most contain <1.3 wt. % TiO₂ and 16–22 wt. % Al₂O₃, and have characteristically high K/Nb and La/Nb values. Abundances of P, Ba, Rb, Sr, La, Ce, Nd, Zr and Nb increase sympathetically with increasing K₂O contents of mafic rocks but those of Na, Ti, Y and Sc vary little throughout the geochemical continuum from low-K tholeiitic to high-K leucititic rocks.Excluding Sumatra and Wetar, which possess mainly dacitic and rhyolitic volcanics, the Sunda-Banda arc is divisible into four geochemical arc sectors with boundaries that correlate with major changes in regional tectonic setting and geological history. From west to east, the West Java, Bali and Flores arc sectors each comprise volcanoes which become progressively more K-rich eastwards, culminating in the leucitite volcanoes Muriah, Soromundi and Sangenges, and Batu Tara, respectively. In the most easterly Banda sector, the volcanics vary from high- to low-K eastwards around the arc.Correlations between geochemistry and ⁸⁷Sr/⁸⁶Sr values show separate trends for each of the four arc sectors, believed to be the result of involvement of at least three geochemically and isotopically distinct components in the source regions of the arc magmatism.A dominant source component with a low K content and a low ⁸⁷Sr/⁸⁶Sr value, and common to all sectors, is probably peridotitic mantle. A second component, with low K content but high ⁸⁷Sr/⁸⁶Sr value, appears to be crustal material. This component is most apparent in the Banda sector, in keeping with that sector's tectonic setting close to Precambrian Australian continental crust, but it is also present to lesser extents in the West Java and Flores sectors.However, the most marked geochemical and isotopic variations shown by the arc volcanics are primarily due to the involvement of a third component, which is rich in K-group elements but has relatively low ⁸⁷Sr/⁸⁶Sr values. This component appears to be mantle-derived and is least overprinted by crustal material in the Bali sector volcanics where the Pb, Be, U-Th and O isotope characteristics of the rocks support the suggestion that their genesis has not involved incorporation of recently subducted, continent-derived sialic material.The high, regionally persistent, Th/U value (about 4.3) of the Sunda subarc mantle, obtained from U-Th isotopic data, suggests a close association could exist between the K-rich component and the southern hemisphere ‘DUPAL’ mantle isotopic anomaly.     

Isotope geochemistry and origin of calc-alkaline lavas from a caledonian continental margin volcanic arc

Analyses for major and trace elements, including REE, and Sr, Nd and Pb isotopes are reported from a suite of Siluro-Devonian lavas from Fife, Scotland. The rocks form part of a major calc-alkaline igneous province developed on the Scottish continental margin above a WNW-dipping subduction zone. Within the small area (ca. 15 km²) considered, rock types range from primitive basalts and andesites (high Mg, Ni and Cr) to lavas more typical of modern calc-alkaline suites with less than 30 ppm Ni and Cr. There is a marked silica gap between these rocks (< 62%) and the rare rhyolites (> 74%), yet the latter can be generated by fractional crystallization from the more mafic lavas. In contrast, variation in incompatible element concentrations and ratios in the mafic lavas can not be generated by fractional crystallization processes. Increasing SiO₂ is accompanied by increasing Rb, K, Pb, U and Ba relative to Sr and high field strength elements, increasing LREE enrichment and increasing _Sr calculated at 410 Ma, and by decreasing HREE, Eu/Eu*, Sm/Nd and _Nd (410). _Nd and _Sr are roughly anticorrelated and have more radiogenic compositions than the mantle array, in common with data reported elsewhere from this part of the arc. The correlation extrapolates up to cross the mantle array within the composition field of the contemporary MORB source, and extrapolates down towards the probable compositional range of Lower Palaeozoic greywackes, which may form the uppermost 8 km of the crust, or may be supplied to the source by subduction. One sample, however, lies within the mantle array, and closely resembles lavas from northwestern parts of the arc, where a mantle source with mild time-integrated Rb/Sr and LREE enrichment has been inferred. The lavas have relatively high initial ²⁰⁷Pb/²⁰⁴Pb for their ²⁰⁶Pb/²⁰⁴Pb, a feature which has been interpreted elsewhere as the result of incorporation of a sediment component into arc magmas. The systematic changes with increasing SiO₂ in isotopic and chemical parameters can be explained by mixing of a greywacke-derived component with depleted mantle. The various possible mixing mechanisms are discussed, and it is considered most likely that mixing occurred in the mantle source through greywacke subduction. The bulk of the Rb, K, Ba and Pb in the lavas is probably recycled from the crust, whereas less than some 40% of the Sr and Nd is recycled. The calc-alkaline chemical trends are solely a function of mixing with the sediment component.     

The Bag Tephra, a widespread tephrochronological marker in Middle Europe: chemical and mineralogical investigations

 The Bag Tephra is a widespread tephra layer interbedded in Quaternary loess deposits along the Danubian valley of Hungary and Slovakia. Its age is poorly defined between 788 and 380 ka B.P. The glass and mineral composition – micropumice clasts of phono-tephrite and blocky shards of tephri-phonolite associated with two kinds of clinopyroxene, fassaitic diopside, and salite – is very distinctive. This tephra could be used as a chronological marker, as soon as its age is refined. The probable origin is the middle Italian volcanic area. Received: 3 November 1998 / Accepted: 18 January 1999     

Explosive silicic volcanism in Iceland and the Jan Mayen area during the last 6 Ma: sources and timing of major eruptions

Fifty-three major explosive eruptions on Iceland and Jan Mayen island were identified in 0–6-Ma-old sediments of the North Atlantic and Arctic oceans by the age and the chemical composition of silicic tephra. The depositional age of the tephra was estimated using the continuous record in sediment of paleomagnetic reversals for the last 6 Ma and paleoclimatic proxies (δ¹⁸O, ice-rafted debris) for the last 1 Ma. Major element and normative compositions of glasses were used to assign the sources of the tephra to the rift and off-rift volcanic zones in Iceland, and to the Jan Mayen volcanic system. The tholeiitic central volcanoes along the Iceland rift zones were steadily active with the longest interruption in activity recorded between 4 and 4.9 Ma. They were the source of at least 26 eruptions of dominant rhyolitic magma composition, including the late Pleistocene explosive eruption of Krafla volcano of the Eastern Rift Zone at about 201 ka. The central volcanoes along the off-rift volcanic zones in Iceland were the source of at least 19 eruptions of dominant alkali rhyolitic composition, with three distinct episodes recorded at 4.6–5.3, 3.5–3.6, and 0–1.8 Ma. The longest and last episode recorded 11 Pleistocene major events including the two explosive eruptions of Tindfjallajökull volcano (Thórsmörk, ca. 54.5 ka) and Katla volcano (Sólheimar, ca. 11.9 ka) of the Southeastern Transgressive Zone. Eight major explosive eruptions from the Jan Mayen volcanic system are recorded in terms of the distinctive grain-size, mineralogy and chemistry of the tephra. The tephra contain K-rich glasses (K₂O/SiO₂>0.06) ranging from trachytic to alkali rhyolitic composition. Their normative trends (Ab–Q–Or) and their depleted concentrations of Ba, Eu and heavy-REE reflect fractional crystallisation of K-feldspar, biotite and hornblende. In contrast, their enrichment in highly incompatible and water-mobile trace elements such as Rb, Th, Nb and Ta most likely reflect crustal contamination. One late Pleistocene tephra from Jan Mayen was recorded in the marine sequence. Its age, estimated between 617 and 620 ka, and its composition support a common source with the Borga pumice formation at Sør Jan in the south of the island.     

Chemical and optical studies of glass shards in Pleistocene and Pliocene ash layers from DSDP site 192, Northwest Pacific Ocean

Thirty-four ash layers of Pleistocene and Pliocene age from DSDP Site 192, northwestern Pacific Ocean, have been subjected to detailed chemical and optical study to evaluate: (1) the chemical and optical variability in glass shards from deep-sea ash layers, and (2) secondary changes brought about by prolonged exposure to seawater. Glass shards from approximately half of the ash layers studied were found to have uniform compositions which approach the precision of the microprobe chemical analyses, whereas the remainder are compositionally diverse (e.g., SiO₂, variations of 5–15% among shards from the same ash layer) and appear to be the eruptive products of compositionally zoned magma chambers. Optical studies of glass shards confirm the absence of devitrification or the formation of pervasive secondary alteration products. By contrast, chemical studies suggest that the glass shards have experienced progressive hydration with possible minor ion exchange of K, Mg, Ca and Si. The hydration occurs rapidly and leads to a rather uniform water content of 4.5–5% after several hundred thousands of years exposure to seawater. Step-wise heating dehydration experiments, optical effects, and published'oxygen isotope studies indicate that the water of hydration is incorporated uniformly within the glass. Systematic chemical differences between electron microprobe analyses of glass shard interiors and corresponding bulk chemical study by atomic absorption lead us to postulate that glass shard margins have undergone a minor chemical exchange with major cations in seawater. They have gained 0.10–0.20 wt. % K₂0, MgO, and CaO while losing a corresponding amount of Si₂O. Although the glass shards from DSDP Site 192 are hydrated and may have experienced subtle, surficial ion exchange, we stress that they are the most chemically representative samples available of magmas that were explosively erupted from volcanic arcs.     

Optical luminescence dating of a loess section containing a critical tephra marker horizon,SW North Island of New Zealand

A new IRSL dataset is presented for the age and setting of a critical Late Glacial Maximum tephra isochron marker. The rhyolitic tephra, known as the Kawakawa Tephra, occurs as a 14 cm thick layer within a 5.9 m thick loess section overlying alluvial gravels in the Rangitikei River valley, SW North Island of New Zealand. Ages range from 21 at the base to 5 ka near the top of the loess and bracket an age of 17.0 ± 2.2 for the tephra. The new IRSL ages are in agreement with published and unpublished luminescence ages from other localities of loess, sand and ash above and below the tephra and of the tephra itself, that indicate an age of ca. 19 ka for the Kawakawa Tephra. This age is considerably younger than the generally accepted ¹⁴C 27.1 ka cal yrs BP age of the Kawakawa Tephra and highlights an unresolved discrepancy between the two dating systems.