柴达木盆地自然伽玛曲线在古气候及沉积环境研究中的应用

应用自然伽玛测井（GR）曲线反演古气候和古环境的方法在国际上逐渐得到重视并取得了进展，柴达木盆地第四纪应用其反演2.85Ma B.P来的古气候变化也取得了成功。本文以柴达木盆地侏罗系冷科1井和雨33井自然伽玛曲线并结合孢粉等地质资料进行了古气候与沉积环境分析，证明GR曲线是有价值的古气候研究参数。GR值的大小及古气候的干湿变化和沉积水体的深浅变化均有内在联系，GR曲线振幅与频率的变化快慢反映出沉积环境动荡与稳定的相对特征，据此对两口井的沉积环境演变作了具体分析。结合古气候与沉积环境综合分析，GR曲线的异常波动还具有特殊的指相意义。GR值增大-古气候加湿-沉积水体加深的同步表现特征是一般性规律，构造-古地理背景的变动可改变这一对应关系，因而提供了研究古地理演变的信息，进一步丰富了GR曲线研究的地质涵义。说明在侏罗纪古气候和古环境研究上，GR曲线是一有价值的参考指标。     

沧东—南皮凹陷孔店期古盐度与古环境演化

内陆封闭湖泊的盐度与湖平面具有同步反向变化的特点,通过古盐度研究可推测沉积时期的古气候状况。通过Sr/Ba、Th/U含量比值及C、O同位素的含量变化分析,对沧东—南皮凹陷孔店期各层序古盐度的变化进行系统研究,结合孢粉及岩性组合,推断该区孔店期的水体性质及各层序间古环境的演化。综合认为孔店期整体水体性质为半咸—微咸水,水体深度呈浅→深→浅的变化规律,古气候变化特征为半干旱→湿润→半干旱→干旱气候。     

大庆油田徐22井青山口组/姚家组微体生物及其古气候响应

对大庆油田徐22井青山口组/姚家组界线上下约12.20 m长的岩心做了详细采样、描述,进行了孢粉、介形类化石的处理、鉴定和分析,以恢复界线上下的古环境和古气候。研究表明,采样段底部沉积期主要出现一种相对深水还原的沉积环境,介形类、水源和陆源生物均比较繁盛,孢粉Cyathidites类型占优势,显示出一种相对温暖湿润的气候;向上岩层颜色变浅,粒度有所加粗,化石含量迅速减少,反映出沉积水体急剧变浅,气候变得比较干热,生物受到打击,在1 612.90 m界线处介形类化石完全消失,孢粉含量也急剧减少;再向上岩性明显变粗,并出现红层,反映当时湖水变得很浅,可能为三角洲淤积相,气候更加干热,并有波动,化石很少见。因此可以看出在界线上下热带、湿润-半湿润气候的大背景下,水体由深而平静变得浅而动荡,气候由相对温暖湿润变得相对干热,生物出现由繁盛到衰退的变化过程。     

古环境、古气候分析对P-T之交灭绝事件的启示——以豫西济源孙家沟组为例

二叠纪—三叠纪之交,海洋和陆地均经历了地球历史上最严重的生物危机,大灭绝事件前后沉积环境的恢复及古气候的重建是生物大灭绝事件研究的基础。济源盆地位于华北板块南缘,二叠纪—三叠纪陆相地层发育完整且接触清晰,是研究华北板块二叠纪—三叠纪之交古气候和沉积环境演化的良好区域。以豫西济源大峪镇剖面孙家沟组为研究对象,综合运用岩石学、沉积学、古生物学和地球化学方法对研究区进行了系统研究。结果表明：济源孙家沟组从下部曲流河环境逐渐过渡为滨湖环境。孙家沟组下、中段地化数据表明当时的年降水量较低,古温度与化学风化强度较高,反映了干旱—半干旱为主的气候特征,可能为全球性巨型季风影响的结果,并由此导致了“济源动物群”的消失和微生物成因沉积构造（MISS）的发育。中段沉积期末期气候向湿润转变,到上段顶部干旱气候再次占据主导地位并持续至早三叠世。整体上,孙家沟组沉积期呈湿润—干旱—半湿润—干旱的气候变化,干旱炎热的气候可能是研究区陆地生态环境遭到破坏的重要原因,环境的退化加剧了陆相生物灭绝;根据岩性特征、古气候、古环境、MISS等,综合推测P-T之交灭绝事件发生在孙家沟组沉积期早期。     

豫西宜阳地区晚二叠世晚期—早三叠世沉积记录及其对古气候变化的响应

晚二叠世-早三叠世宜阳地区位于东特提斯低纬度地区的华北板块南缘,发育一套连续且沉积特征显著的陆相碎屑 岩相沉积,是研究陆相晚二叠世-早三叠世古环境与古气候变化的理想地层。本文在前人研究与野外实测的基础上,采用 岩石学、沉积学、古生物学方法综合分析研究区的沉积记录,识别出宜阳地区在该时期由陆源近海的滨湖沉积环境向河流 沉积环境过渡的古环境,重建了晚二叠世晚期-早三叠世宜阳地区的古地理面貌。沉积特征显示,此期整体气候条件为炎 热-半干旱,并且在长兴期末期与奥伦尼克期早期出现了极端干旱气候,可能是受到当时全球性巨型季风环流的影响。这 一时期的古气候与古环境的变化可能对二叠纪末陆地大灭绝事件起到了推动作用,并抑制了早三叠世生物复苏的进展。     

柴达木盆地自然伽玛曲线与古里雅冰芯记录的末次间冰期以来气候环境变化过程的对比

采用柴达木盆地达参1井自然伽玛(GR)曲线进行古气候反演,分析了GR曲线记录的末次间冰期以来的环境变迁过程. 表明GR曲线忠实地记录了构造运动及气候变化的影响,与古里雅冰芯、格陵兰冰芯所记录的气候事件均能较好对应. 表明柴达木盆地同时包含了高原隆升和全球性气候变化的信息,是反映古气候变化良好的信息载体之一, 是反映内陆干旱盆地环境与气候变化良好的代用指标.     

豫西宜阳地区晚二叠世晚期—早三叠世沉积记录及其对古气候变化的响应

晚二叠世—早三叠世宜阳地区位于东特提斯低纬度地区的华北板块南缘，发育一套连续且沉积特征显著的陆相碎屑 岩相沉积，是研究陆相晚二叠世—早三叠世古环境与古气候变化的理想地层。本文在前人研究与野外实测的基础上，采用 岩石学、沉积学、古生物学方法综合分析研究区的沉积记录，识别出宜阳地区在该时期由陆源近海的滨湖沉积环境向河流 沉积环境过渡的古环境，重建了晚二叠世晚期—早三叠世宜阳地区的古地理面貌。沉积特征显示，此期整体气候条件为炎 热—半干旱，并且在长兴期末期与奥伦尼克期早期出现了极端干旱气候，可能是受到当时全球性巨型季风环流的影响。这 一时期的古气候与古环境的变化可能对二叠纪末陆地大灭绝事件起到了推动作用，并抑制了早三叠世生物复苏的进展。     

黑龙江省柳树河盆地始新统八虎力组油页岩元素地球化学特征及沉积环境

黑龙江省柳树河盆地始新统八虎力组发育多层油页岩。通过对油页岩样品元素地球化学分析测试,研究了其常量元素、微量元素和稀土元素特征,分析了油页岩沉积环境。研究结果表明,常量元素以富Al₂O₃、Fe和CaO,贫SiO₂、MgO、Na₂O和K₂O为特征,微量元素总体上表现出不同程度的亏损特征,稀土元素总量平均为140.7×10^-6,表现出轻稀土元素轻度富集特征。稀土元素具有较为一致的变化趋势,表明油页岩沉积时物源和沉积环境较为稳定。Mn/Ti值表明油页岩组成物质的搬运距离随着时间变化经历了远→近→远的变化,反映水体深度经历了深→浅→深的变化。Sr/Cu值和Rb/Sr值表明油页岩沉积时为相对炎热干旱的环境。Sr/Ba值反映当时为炎热干旱气候条件下的过渡相咸水湖泊沉积环境。V/(V+Ni)值、δEu和有机碳含量表明油页岩沉积时处于缺氧的还原沉积环境中。总体上,柳树河盆地油页岩发育于炎热干旱气候、咸水、缺氧条件下的湖泊沉积环境中。     

粘土矿物在气候环境变化研究中的应用进展

在古环境和古气候的重建中,粘土矿物和碳-氧同位素、孢粉、树轮、冰芯等代用指标一样具有同等重要的地位。在没有地质构造运动影响时,气候是影响粘土矿物形成的主要因素,沉积物中的粘土矿物可用来分析古气候和古环境。粘土矿物及其组合可以独立或作为主要指标反映气候和环境变化,并已应用于高分辨率的晚第四纪地层的气候环境研究中。粘土矿物在很短的时间内也会发生明显地变化,不仅可以反映千年-百年尺度的气候环境变化,而且也可以反映几十年尺度的古气候环境变化过程。粘土矿物与其它指标对同一气候环境响应的相位差有待深入研究。不同的半定量分析方法测量出的同一剖面中粘土矿物的含量变化趋势和特征具有一致性。     

南海东北部中生界岩石学特征及沉积环境

南海东北部潮汕坳陷发现中—晚侏罗世到白垩纪的海相中生代地层，由泥岩、砂岩、放射虫硅质岩夹鲕粒灰岩及火山岩构成。岩石组合及沉积特征反映出，从中-晚侏罗世到白垩纪沉积水深经历了由浅到深，然后又转为陆地的一个完整旋回，沉积环境则经历了由滨浅海相到深海相，又到滨海过渡相和陆相河湖体系的演变过程，在深海相与滨海陆地过渡相之间存在一个明显的环境突变，为沉积环境缺失所致。与深海相放射虫硅质岩相伴，则夹有玄武岩（细碧岩）层。沉积反应的气候条件从中-晚侏罗世-早白垩世的温暖湿润气候环境过渡到晚白垩世的炎热干旱气候环境。这套海相中生代地层的存在对解释南海北部中生代大地构造演化以及古特提斯洋和太平洋的关系具有重要意义。     

Morphotectonic study of Hispaniola

Geomorphological analysis; aerial photographs; and geomorphologic, geological, geophysical, topographical, and field studies show that the morphology of Hispaniola can be linked to lateral variations in the geometry and tectonism of the Caribbean-North American Plate Boundary Zone. Three main categories of the relief were established: territorial units (1 megablock, 2 macroblocks, 14 mesoblocks, 209 blocks, 401 microblocks, and 527 nanoblocks), morphostructural alignments (4 first-, 1 second-, 12 third-, and 30 fourth-rank), and 16 knots between morphostructural alignments (second-to fourth-rank). The main seismic activity is concentrated on the first-and second-rank lineaments, and some important epicenters are located in the vicinity of the lineament intersections. The origin of the earthquakes in the vicinity of such knots can be explained by the forcing/pushing of macroblocks northeastward. The existence of earthquakes along the main lineaments may be explained by tension or compression in a restraining bend zone. From the current study, it appears that earthquake occurrence in Hispaniola is related with the stress concentrations in the vicinity of morphotectonic zones. A seismotectonic interpretation of Hispaniola is shown where three zones exist, each of them with a different active level and dimensions. The text was submitted by the authors in English.     

阴极发光在翡翠研究中的应用

通过对多个翡翠及其他玉石标本进行阴极发光实验,观察不同品种的翡翠、处理翡翠制品以及翡翠的相似玉石品种在阴极发光镜下的荧光颜色、发光强度、环带特点、颗粒形态和裂隙状况等的不同特征,来有效鉴别翡翠、处理翡翠及翡翠的相似品。同时依据不同类型翡翠在阴极发光下的特征,对翡翠的品质、颜色等的划分提供依据。     

土壤地质单位的建立与研究--以浙江省为例

土壤地质单位是地学工作者根据地质资料、结合成土特征提出的一种新型土壤分类方法,其实质就是在充分考虑气候、生物、地形、时间等成土因素的同时,抓住母岩-母质-土壤三者之间的成生联系,找出成土母岩岩性、矿物成分、结构构造、地球化学特征对土壤结构、质地、厚度、微量营养元素的制约关系,为农业区划和农业种植结构调整提供科学的依据.笔者据浙江省农业地质背景调查项目实践,在从地学角度对浙江省成土母质进行分类的基础上,结合土壤亚类建立了土壤地质单位,并提出研究内容和研究方法.     

岩体强度的各向异性研究

本文运用断裂力学理论推导了含节理岩体的初裂强度公式,定量地讨论了节理方向、长度对岩石强度的影响,阐明了节理岩体强度各向异性的实质。通过证实,本文所建立的公式具有很强的适用性和较高的可靠性,可用于实际的工程岩体稳定性评价。     

High-pressure structural study of muscovite

The compressibility and structural variations of two 2M₁ muscovites having compositions (Na_0.07K_0.90 Ba_0.01□_0.02)(Al_1.84Ti_0.04Fe_0.07Mg_0.04)(Si_3.02Al_0.98) O₁₀ (OH)₂ (7 mole % paragonite) and (Na_0.37K_0.60□_0.03)(Al_1.84Ti_0.02 Fe_0.10Mg_0.06)(Si_3.03Al_0.97) O₁₀(OH)₂ (37 mole % paragonite) were determined at pressures between 1 bar and 35 kbar, by single-crystal X-ray diffraction using a Merrill-Bassett diamond anvil cell. Isothermal bulk moduli, setting K′ = 4, were 490 and 540 (± 30) kbar for the Na-poor and Na-rich samples respectively. Both samples show highly anisotropic compressibility patterns, with β _a ∶β _b ∶β _c = 1∶1.15∶3.95 for the Na-poor sample and β _a ∶β _b ∶β _c = 1∶1.19∶3.46 for the Na-rich one. HP structural refinements showed that the different compressibility was largely due to the partial substitution of Na for K in the interlayer region. Moreover, the different compressibility of the tetrahedral and octahedral layers, observed in both micas, increased the a rotation of the tetrahedral layer by about 2° in 28 kbar, as also indicated by the evolution of interlayer cation bond lengths. This increases the repulsion of oxygens of the basal layers and between the high-charged cations of the tetrahedral layer. As a consequence, phengitic substitution, reducing α rotation, would increase the baric stability of mica. Comparison between the HP structures of muscovite and phlogopite indicated the lower compressibility of the latter, mainly due to the greater compressibility of the dioctahedral layer with respect to that of the trioctahedral layer. The HT and HP behaviour of di- and trioctahedral micas showed an anisotropy in the compressional pattern which was markedly greater than that observed in the dilatation pattern. This unexpected result was explained by the different evolution with P and T of alkaliO bond lengths. By combining HP and HT data, a tentative equation of state of muscovite is proposed.     

Experimental study of stick-slip behaviour

Simple axi-symmetric uni-axial compression tests have been realized on dry loose samples of glass beads (diameters d: d=0.2 ± 0.05 mm, 0.75 ± 0.1 mm, or 3 mm) and on Hostun sand under small lateral confinement, σ₃<60 kPa, using different sample sizes. The experiments with the two smallest spheres (d=0.2 and 0.75 mm) exhibit stick-slips, which are characterized by (i) a rapid release Δq of the deviatoric stress q and by (ii) the strain Δε₁ separating two events. The samples which exhibit stick-slip also present a weakening of strength q(ε₁) as the rate of deformation dε₁/dt is increased. No stick-slip is generated during the first part of the q−ε₁ curve, i.e. when q grows fast with ε₁. Four different parameters helped us determine the statistics of Δq and Δε: the lateral pressure σ₃′, the rate of deformation dε₁/dt, the sample height H, and the diameter D. The statistics do not depend on rate history. They look like exponentials in small samples and/or in (large sample+fast dε₁/dt), and they look like Poissonian or Gaussian in (Large sample+small dε₁/dt). This change in statistics is attributed to a varying of triggering process starting from a single random event in small samples to multiple random events. We have interpreted this change of statistics as due to some finite size effect so that the representative elementary volume shall contain at least (200)³ grains. Localization of deformation is visible at the end of compression but cannot be detected from stick-slip statistics nor from q vs ε curve. Copyright © 2004 John Wiley & Sons, Ltd.     

A thermochemical study of monohydrocalcite

The thermodynamic properties of monohydrocalcite, CaCO₃ · H₂O, have been obtained using a well-characterized natural specimen. Equilibration of the solid with water at 25°C under 0.97 atm CO₂ led to an activity product [Ca²⁺][CO₃^2?] = 10^?7.60±0.03 and a free energy of formation ΔG_f^o = ?325,430 ± 270 calmol^?. The enthalpy of solution of monohydrocalcite in 0.1 N HCl at 25°C led to a standard enthalpy of formation ΔH_f^o = ?358,100 ± 280 cal mol^?1. Estimates of the variation of ΔG_f with temperature and pressure showed monohydrocalcite to be metastable with respect to calcite and aragonite.     

A thermochemical study of vaterite

Vaterite is shown to be unstable with respect to calcite at 25°C by measurements of the enthalpies of solution in 0·1 N HCl under 0·97 atm CO₂ and the solubilities in water under 0·97 atm CO₂ of the two polymorphs. For a pure, synthetic vaterite ΔH (tr) = ?1036 ±16 cal mol^?1 and ΔG(tr) = ?790 ± 25 cal mol^?1 for the transition to calcite. For other vaterites aged longer during preparation ΔH(tr) is smaller and shows a linear relationship with the X-ray line broadening which extrapolates to ΔH(tr) = ?545 ± 30 cal mo^?1 for zero broadening. The use of X-ray line broadening as a measure of crystal imperfection and stability is discussed for various synthetic and natural vaterites.     

土体各向异性研究进展

综合论述了土体各向异性在土体本构理论发展的不同阶段的研究进展：详细介绍了国内外在各向异性研究中所采用的试验手段、研究方法、理论成果和应用情况：对具代表意义的重要成果作了比较详细的描述和分析。分析了原生各向异性和应力各向异性的区别与联系，认为土体材料的颗粒结构性是各向异性产生的根本原因，复杂的应力状态是各向异性产生的客观条件：强调了各向异性，尤其是应力各向异性在土体本构理论研究中的重要性，对以后各向异性研究方法提出自己的观点。     

Thermochemical study of natural montmorillonite

The paper reports results of an experimental thermochemical study (in a heat-flux Tian-Calvet microcalorimeter) of montmorillonite from (I) the Taganskoe and (II) Askanskoe deposits and (III) from the caldera of Uzon volcano, Kamchatka. The enthalpy of formation Δ _f H _el ⁰ (298.15 K) of dehydrated hydroxyl-bearing montmorillonite was determined by melt solution calorimetry: ?5677.6 ± 7.6 kJ/mol for Na_0.3Ca_0.1(Mg_0.4Al_1.6)[Si_3.9Al_0.1O₁₀](OH)₂ (I), ?5614.3 ± 7.0 kJ/mol for Na_0.4K_0.1(Ca_0.1Mg_0.3Al_1.5Fe _0.1 ³⁺ )[Si_3.9Al_0.1O₁₀](OH)₂ (II), ?5719 ± 11 kJ/mol for K_0.1Ca_0.2Mg_0.2(Mg_0.6Al_1.3Fe _0.1 ³⁺ ) [Si_3.7Al_0.3O10](OH)₂ (III), and ?6454 ± 11 kJ/mol for water-bearing montmorillonite (I) Na_0.3Ca_0.1(Mg_0.4Al_1.6)[Si_3.9Al_0.1O₁₀](OH)₂ · 2.6H₂O. The paper reports estimated enthalpy of formation for the smectite end members of the theoretical composition of K-, Na-, Mg-, and Ca-montmorillonite and experimental data on the enthalpy of dehydration (14 ± 2 kJ per mole of H₂O) and dehydroxylation (166 ± 10 kJ per mole of H₂O) for Na-montmorillonite.