九嶷山锡矿田矿床地质特征及矿床成因

九嶷山矿田锡矿产于复式花岗杂岩体内。锡矿以云英岩体型、蚀变花岗岩型为主,具有矿体厚度大、蚀变强、品位中等、矿石利用性能好等特点。本文阐述了区内成矿地质背景、主要矿床类型与特征以及成矿与构造、岩浆岩的关系,探讨了矿床的成因机制,认为区内锡成矿与岩浆岩多期多阶段演化分异和构造活动密切相关。     

A Preliminary Review of Metallogenic Regularity of Tin Deposits in China

China is rich in tin resources,and contains many types of tin deposits.Among the tin deposit types,the cassiterite-sulfide type,skarn type and quartz vein type occupy a large proportion of tin resources and reserves.From the aspect of exploitation and utilization,the most important types are cassiterite-sulfide type and quartz vein type.The cassiterite-sulfide type tin deposits are mainly located in Northern Guangxi and Eastern Yunnan,skarn type deposits are mainly distributed in the ore-concentration areas of South Hunan in Middle Nanling,and the quartz vein type tin deposits are mainly distributed in South China,such as Western Fujian,Middle Jiangxi,Northern Guangzhou and Southern Hunan.The most important metallogenic epoch for tin deposits is the Mesozoic era.The metallogenic geotectonic background is mainly continental environments after orogeny process,with strong tectonic changes,interlaced deep fracture and frequent magmatism.And the most distinctive feature is the well developed Mesozoic granites,which have a close relationship with tin mineralization.Based on the detailed study of the data from 873 tin deposits in China,this paper summarized the metallogenic regularity of tin deposits,classified 20 important metallogenic series of tin or tin-associated deposits,and inferred that the cassiterite-sulfide type,skarn type,quartz vein type and greisen type are the main prediction types of tin resources.Forty-four tin-mineralization belts were divided,among which,19 belts are the most important.In addition,a series of maps about tin metallogenic belts and tin metallogenic regularity were compiled,aiming to provide theoretical basis for potential estimation and prediction of tin mineral resources.     

国际锡价格百年走势及市场前景分析

锡是我国的优势矿种，研究并掌握其价格走势、市场动态，对于制定产业发展战略，安排矿山生产具有重要的现实意义。利用统计资料，在系统分析国际锡价格百年走势、资源分布情况以及锡的产量与消费量形势的基础上，对锡市场前景进行了预测，认为未来几年世界锡的消费量仍将有较大的增长潜力，国际锡价格将有回升的余地。     

会昌岩背锡矿田地球化学特征及隐伏矿床预测异常指标探讨

在岩背锡矿田,运用土壤地球化学异常寻找锡矿床,取得了显著效果,尤其是岩背锡矿床的发现和扩大,以及上湾隐伏锡矿床预测,为应用土壤地球化学异常找矿积累了经验。本文在阐述矿田土壤地球化学异常分布的基础上,着重对与矿床有关的土壤地球化学异常特征,以及隐伏锡矿床预测的异常指标进行了探讨。     

中国锡矿床时空分布特征与潜力评价

锡矿是中国传统优势矿种,但是近年来遇到了找矿潜力区不足和找矿方向不明等问题,急需进一步分析和总结其地质特征、成矿规律和资源潜力,为今后地质找矿工作提供借鉴。文中采用矿床模型综合地质信息预测方法,在各省区锡矿资源潜力预测成果的基础上,以MapGIS为平台,进行数据库汇总与综合分析研究。首先,基于全国893处锡矿产地数据的统计分析,初步总结了中国锡矿时空分布特征,岩浆岩、构造和地层等控矿因素。其次,根据锡矿床及预测区的空间分布和大地构造单元,划分了44个锡矿成矿区带。再次,将锡矿的预测类型划分为石英脉型、锡石硫化物型、夕卡岩型、云英型、伟晶岩型、火山岩型和砂矿型,并建立了主要锡矿类型的预测模型。最后,在全国范围累计圈定1 179个最小预测区,累计预测资源量1 861.13×104 t。根据锡矿区域成矿特征,将最小预测区归并为405个二级预测区,并进一步合并为109个锡矿三级预测区,其中找矿潜力大的湖南香花岭-千里山和塔山-大义山、云南个旧和薄竹山-都龙、内蒙古黄冈梁等5个三级预测区可优先部署锡矿勘查工作。预测结果还表明锡矿在500 m以浅的找矿空间里仍有很大资源潜力,因此,找矿工作应注重深浅结合,在重视老矿山深部外围找矿的同时,还应重视覆盖区和非传统锡矿类型等新领域的找矿勘查。     

滇西南云岭锡矿床地质特征与花岗岩锆石U-Pb年代学

滇西南是中国重要的锡矿带之一,前人研究主要集中在白垩纪和新生代花岗岩中的锡矿床,而对印支期花岗岩中的锡矿关注较少.云岭锡矿位于保山地块的东缘,矿体主要以脉状产在黑云母二长花岗岩中,发育云英岩化和电气石化蚀变.矿石矿物为锡石,脉石矿物为石英、白云母、电气石、萤石、方解石,以及黄铁矿、毒砂、黄铜矿、闪锌矿等硫化物.根据矿物...     

Placer Tin Ores from Mt. Cer,West Serbia,and Their Potential Exploitation during the Bronze Age

Tin is a rare metal that is essential for making bronze, the defining technology of the Bronze Age. The source(s) of tin for Aegean bronze is undetermined but several small Bronze Age tin mines have been documented in the circum‐Aegean region. The discovery of Bronze Age archaeological sites in West Serbia near a tin placer deposit on the flanks of Mt. Cer led to an investigation of this site as a potential additional Bronze Age tin mine in the region. Geochemical prospecting of stream sediments flowing from Mt. Cer allowed for categorization of streams based on relative tin grade. Tin grade is highest in the Milinska River, a likely combination of a broad catchment area with multiple ore‐bearing tributaries, and a topographic profile that favors the accumulation of placer deposits. A survey of cornfields along the southern pluton margin discovered archaeological sites spanning the Neolithic to the Iron Age. Unlike older and younger sites, those of the Bronze Age were found only along the Milinska and Cernica Rivers where placer tin grades are highest, but appear to be absent where tin is scarce or absent. This suggests that these sites were associated with the exploitation of the tin ore.     

中国锡矿成矿规律概要

我国锡矿资源丰富,矿床类型比较齐全。在锡矿资源储量中占有较大比重的主要是锡石—硫化物型、矽卡岩型和石英脉型;从开采和利用角度来说,最为重要的是锡石—硫化物型和石英脉型。锡石—硫化物型主要集中在桂北、滇东等地,矽卡岩型集中分布在南岭中段湘南等矿集区、石英脉型则主要集中在华南地区的闽西、赣中、粤北、湘南等地;成矿时代以中生代最为重要;成矿大地构造背景以造山运动之后的大陆环境为主,构造变动剧烈,深大断裂纵横交错,岩浆活动频繁,特别是与锡成矿作用关系密切的中生代花岗岩类非常发育,最具特色。本次在对全国873处锡矿矿产地资料进行系统梳理的基础上,深入总结了全国锡矿的成矿规律,厘定出20个以锡为主或锡较为重要的矿床成矿系列,认为锡石—硫化物型、矽卡岩(—云英岩型)、石英脉型和岩体型4类锡矿类型,应该作为重点预测类型,并划分出44个成锡带,提出了19个重要工作部署区,并编制了中国成锡带图、中国锡矿成矿规律图等系列图件,为潜力评价预测工作提供了理论依据。     

锡的地球化学性质与华南晚白垩世锡矿成因

锡在地质过程中表现出亲氧、亲硫和亲铁三重特性。在地幔岩浆过程中,锡是一种中等不相容的金属元素。锡成矿主要与酸性岩浆活动有关,其地球化学性质决定了其成矿主要受源区性质、氧逸度以及挥发分含量、岩浆结晶分异等因素控制。高度结晶分异可使锡在岩浆中进一步富集,是锡成矿相关花岗岩的普遍特征;锡为变价元素,岩浆体系氧逸度影响源区中锡的迁移能力和分离结晶过程中锡的元素行为,还原性岩浆体系有利于锡富集成矿。富含F、Cl和B等挥发组分对锡元素的迁移和富集起积极的作用。全球锡矿床分布与俯冲带关系密切,特提斯和环太平洋构造域是主要蕴藏区。重要的锡成矿事件表现出区域性和阶段性的特征。结合锡的地球化学特性以及锡矿分布特征,我们认为最有利锡成矿的动力学机制是俯冲板片后撤机制。俯冲板片后撤引发深部软流圈地幔上涌,导致强烈的壳幔相互作用,形成低氧逸度、富F、Cl和B等花岗岩,有利于锡成矿。对于华南晚白垩世锡成矿事件,新特提斯洋俯冲板片发生后撤是其成矿地球动力学背景。     

华南与花岗岩有关大规模钨锡成矿作用的时空分布、成矿模式及找矿方向

华南是我国重要的钨锡成矿区。本文围绕华南与花岗岩有关的大规模钨锡成矿作用,系统收集了区内130余个主要矿床的地质和同位素年代学资料,初步总结了与花岗岩有关大规模钨锡矿床的主要类型和时空分布特征。统计结果表明,矽卡岩型和石英脉型是华南最重要的钨成矿类型,而矽卡岩型和锡石硫化物型(或碳酸盐岩交代型)是华南最主要的锡成矿类型。华南与花岗岩有关钨锡成矿作用具有多时代特点,但大规模成矿均集中于燕山期。以南岭和赣北成矿带为主要代表的钨成矿作用主要集中爆发于晚侏罗世至早白垩世早期(160～120Ma),而右江盆地晚白垩世(110～80 Ma,峰期为90～80 Ma)和南岭成矿带晚侏罗世(160～150 Ma)锡矿床则共同构成了华南最主要的锡成矿作用。多种不同矿化或金属类型在同一矿床或矿田尺度上组合产出是华南与花岗岩有关钨锡矿床的重要特征之一,对指导找矿具有重要意义。对此,文章结合华南地区近年来的一些重要成矿机制研究成果和找矿勘查进展,分别以瑶岗仙、川口、茅坪、柿竹园、大厂和个旧等矿床或矿田为例,论述了华南与花岗岩有关大规模钨锡成矿作用的几种成矿模式和找矿方向。此外,本文在钨、锡成矿花岗岩的岩石学、地...     

新疆贝勒库都克锡矿带含锡花岗岩地质特征

本文根据矿物、岩石、微量元素、稀土元素及同位素的研究,重点讨论了我国近年新发现的北方地区第一条独立锡矿带的海西期含锡和非含锡花岗岩的地质特征,确定了该区花岗岩的成因类型及其与锡矿化的关系,认定该区伴随海西运动出现I型、S型和A型三种花岗岩。与锡矿化有关的属S型和A型花岗岩,它们是在早期(造山期)I型和S型花岗岩的基础上进一步演化而隶属造山晚期—造山期后的产物。在上述研究的基础上,总结了该区含矿花岗岩与无矿花岗岩的综合判别标志,为该区及邻区同类锡矿的找寻与研究提供了依据。     

内蒙大井锡多金属矿床矿石的物质成分及特征

大井锡多金属矿床是华北地区较大的锡矿床，深入研究该矿床地质、地球化学特征及成矿规律，对我国北方找锡矿工作具有参考对比意义，通过对大井锡矿床的矿物组成、物质成分及矿石结构构造特征的研究，探讨了成矿温度和成矿深度，进而指出该矿床属于次火岩有关的热液矿床。     

Determination of the Tin Stable Isotopic Composition in Tin‐bearing Metals and Minerals by MC‐ICP‐MS

This study uses MC‐ICP‐MS for the precise analysis of the stable tin isotopic composition in ore minerals of tin (cassiterite, stannite), tin metal and tin bronze. The ultimate goal is to determine the provenance of tin in ancient metal objects. We document the isotope compositions of reference materials and compare the precision of different isotope ratios and the accuracy of different procedures of mass fractionation correction. These data represent a base with which isotopic data of future studies can be directly compared. The isotopic composition of cassiterite and stannite can be determined after reduction to tin metal and bronze, respectively. Both metals readily dissolve in HCl, but while the solutions of tin metal can be directly measured, the bronze solutions must be purified with an anion exchanger. The correction of the mass bias is best performed with an internal Sb standard and an empirical regression method. A series of Sn isotope determinations on commercially available mono‐element Sn solutions as well as reference bronze materials and tin minerals show fractionations ranging from about ?0.09‰ to 0.05‰/amu. The combined analytical uncertainty (2s) was determined by replicate dissolutions of reference materials of bronze (BAM 211, IARM‐91D) and averages at about 0.005‰/amu.     

^40Ar-^39Ar Isotopic Dating of the Xianghualing Sn-polymetallic Orefield in Southern Hunan, China and Its Geological Implications

The Xianghualing Sn-polymetallic orefield in Hunan Province, southern China, is a large-size tin orefield. Although numerous studies have been undertaken on this orefield, its genesis, mineralization age, and tectonic setting are still controversial, mainly because of the lack of reliable geochronological data on tin mineralization. The 40Ar/39Ar stepwise heating dating method was first employed on muscovite from different deposits in this orefield. The muscovite sample from the Xianghualing Sn-polymetallic deposit defines a plateau age of 154.4±1.1 Ma and an isochron age of 151.9±3.0 Ma; muscovite from the Xianghuapu W-polymetallic deposit yields a plateau age of 161.3±1.1 Ma and an isochron age of 160.0±3.2 Ma; muscovite from the Jianfengling greisen-type Sn-polymetallic deposit gives a plateau age of 158.7±1.2 Ma and an isochron age of 160.3±3.2 Ma. The tungsten-tin mineralization ages in the Xianghualing area are therefore restricted within 150-160 Ma. The tungsten -tin mineralization in Xianghualing occurred at the same time as the regional tin-tungsten mineralization including the Furong tin orefield, Shizhuyuan tungsten-tin polymetallic deposit and Yaogangxian tungsten-polymetallic deposit. Thus, the large-scale tungsten-tin metallogenesis in South China occurring at 160-150 Ma. probably is closely related to asthenospheric upwelling and crust-mantle interaction under a geodynamic setting of crustal extension and lithosphere thinning during the transformation of tectonic regimes during the Mid-Late Jurassic.     

滇西南与花岗岩有关的锡矿床时空分布与成矿作用

滇西锡矿带与全球著名的东南亚锡矿带具有相似的成矿地质背景,其成矿规律与资源潜力一直是研究热点。本文在前人已有研究的基础上,探讨了滇西南锡矿时空分布规律与成矿作用。滇西南锡矿主要分布在腾冲地体、保山地体与昌宁-孟连造山带。已有的年代学数据显示腾冲地体发育三期锡成矿事件,分别为125～120Ma,75～68 Ma,52～47 Ma。本文在保山地体识别出晚新生代(约32～24 Ma)和晚白垩世(约75 Ma)两期锡成矿作用,进一步厘定了昌宁-孟连造山带东部三叠纪临沧花岗岩体中锡成矿时代为三叠纪(约235～220 Ma)。提出滇西南与三叠纪花岗岩有关的锡成矿作用发生于古特提斯洋闭合后碰撞环境,与早白垩世花岗岩有关的锡矿形成于中特提斯洋闭合后碰撞环境,与晚白垩世—古近纪花岗岩有关的锡成矿作用与新特提斯洋俯冲和板片回撤有关,而保山地体晚新生代锡矿则可能与新生代隐伏的新生代花岗岩有关,其侵位可能与走滑断裂活动诱发的软流圈上涌和地壳熔融有关。滇西南含锡花岗岩多为复式花岗岩体中晚阶段的高分异花岗岩(如二云母花岗岩或白云母花岗岩)。保山地体三叠纪花岗岩中的锡矿成矿时代显著晚于赋矿围岩,应注重加强成矿期花岗...     

从地洼学说谈浙江地区锡的找矿方向

在大地构造上,浙江地区锡矿(化)主要形成于中、新生代以来的地洼阶段。以江山-绍兴深断裂为界,可以划分为浙东洼陷和浙西洼隆。从地质条件、矿床成因、岩石类型和物质组分等特征,将浙江锡矿(化)划分为斑岩型、矽卡岩型、云英岩型、锡石-石英脉型,锡石-石硫化物型和砂矿型六种类型。亲石型锡矿建造主要分布于陈蔡—龙泉地穹内;亲铁型和亲硫型锡矿建造主要分布于富阳—开化地洼陷带。从锡矿(化)受控于构造、沉积建造的特点,结合锡的赋存状态,提出乌岙—洋滨一带是浙江找锡最有利的部位。     

南岭中段花岗岩中榍石对锡成矿能力的指示意义

榍石是钙碱性花岗岩中常见的副矿物,因Ti4+与Sn4+具有相近的晶体化学性质,榍石可以有不同含量的Sn,因此,榍石是研究含锡花岗岩(特别是氧化型花岗岩)的有用矿物之一.本文选择南岭地区中段3个含锡花岗岩(骑田岭、花山、姑婆山)和3个尚未发现重要锡矿化的花岗岩(连阳、大东山、九峰)中的榍石进行了系统的矿物学研究.在这些花...     

云南大屯锡粗精矿工艺矿物学研究

以云南大屯选矿厂锡粗精矿为研究对象,采用化学分析、X射线衍射分析及光学显微镜分析等手段对该粗精矿的化学组成、矿物组成、矿物嵌布粒度特征等进行了详细的研究。结果表明,锡粗精矿中有价元素锡的品位为13.80%,锡矿物主要以锡石形式产出。锡粗精矿中TFe含量为30.78%,主要以褐铁矿、磁黄铁矿的形式存在,磁黄铁矿是导致粗精矿含硫高的主要原因。锡粗精矿中主要的脉石矿物有白云石、透闪石、电气石、石英、白云母、萤石等,且脉石矿物与锡石均有不同程度的毗邻连生、包裹共生关系。本次工艺矿物学研究认为,大屯选矿厂锡粗精矿宜采用浮选预先脱硫,除去其中的硫化物,再对浮选尾矿采用重选工艺提高锡品位和回收率。该研究结果可以为大屯选矿厂工艺流程改造和合理开发利用锡资源提供科学依据。     

柿竹园矿床大理岩型锡矿石工艺矿物学研究

大理岩型锡矿石产于燕山早、中期千里山花岗岩与中、上泥盆统灰岩的外接触带。矿石呈细脉、网脉浸染状,锡矿物有:锡石、黄锡矿,富钛尼日利亚石、尼日利亚石和木锡矿,脉石矿物绿帘石、石榴石、电气石、萤石、方解石及磁黄铁矿等亦含锡,锡主要呈锡的浊立矿物存在,占总锡量的89.78％,其中锡石锡占总锡量的80.01％,其次有呈类质同象形式存在的锡,在绿帘石、石榴石、电气石等矿物中以Sn~(4+)取代Fe~(3+),这类锡占总量的8.33％。工艺矿物学研究表明,该类锡矿石以“贫”、“细”、“杂”为特征。锡不仅十分分散,而且品位偏低,矿石矿物组合及镶嵌关系复杂、相互包裹,紧密连生;锡矿物粒度微细,粒径一般为0.2～0.01mm,部分为<0.0l～0.002mm,是一种难选的锡矿石类型。通过锡的回收试验,采用选冶联合工艺流程,预测锡的最佳回收率可达50％以上。     

广西钟山县珊瑚钨锡矿区及其外围找矿远景展望

简要阐述了珊瑚钨-锡矿区地质概况和成矿规律.根据该矿区及外围历年地质勘查及科研成果、矿山开采和生产勘探实际情况以及对珊瑚矿床成矿规律的研究,以我国华南钨-锡矿床成矿理论作指导,进行矿区深部及外围钨、锡资源二轮找矿远景预测,提出了四个钨、锡成矿预测区和一个成矿远景区的展望.