Trophic states and nutrient storage of reservoirs in Chongqing

The trophic states of 35 reservoirs were investigated in the region of Chongqing, Southwest China. The results showed that the concentrations of nutrients and chlorophyll a were high and organic pollution and transparence （SD） were low in the water body. The concentrations of total nitrogen （TN） range from 0.52 mg/L to 5.94 mg/L and those of total phosphorus （TP） range from 0.002 mg/L to 0.598 mg/L. Chemical oxygen demand （COD） ranges from 0.75 mg/L to 9.3 mg/L and SD ranges from 0.48 m to 3.2 m. There was a significant positive correlation between COD and chlorophyll a, but a significant negative correlation between SD and chlorophyll a. In terms of the integrated nutrition state index, the eutrophication states of the reservoirs were assessed. Of the investigated reservoirs, about 22 reached the grade of eutrophication. Only one reservoir was in the state of oligotropher, the rest were in the state of mestropher. Integrated nutrition state indices range from 25.4 to 74.5. The storage capacity of nutrients in the reservoirs was calculated. The stored TN, TP and COD were about 4731, 206 and 10259 t, respectively. The main pollution sources are industrial and domestic wastes. With the development of aquaculture, the contamination level increases gradually.     

Effects of climatic changes and anthropogenic activities on lake eutrophication in different ecoregions

Climatic changes and anthropogenic activities could affect nutrients?? status significantly in the different lake ecosystems. Nutrients in Lake Hulun and Lake Taihu, two largest shallow cyanobacteria-blooming lakes in northern and southern China, respectively, were at eutrophicated levels in 2009. The concentrations of total nitrogen and total phosphorus were 3.346 and 2.250?mg/L as well as 0.435 and 0.062?mg/L, respectively, in these two lakes with different causes of eutrophication. For Lake Hulun, it was the decreased amount of water as a result of the warming and drying climate that accounted for the abrupt increase of total nitrogen and total phosphorus levels through inspissation. In addition, the icebound effects, no outflows, low nutrients sequestration by the sediment and the reduction of aquatic productivity made the situation even worse. On the contrary, high population densities, the rapid development of agriculture and industry as well as urbanization have increased the nitrogen and phosphorus loads on Lake Taihu. Therefore, higher criteria of total nitrogen and total phosphorus should be applied in Lake Hulun given the difficulties in controlling climatic changes while much more rigorous standards should be established for Lake Taihu since the anthropogenic impacts on nutrient status are relatively easy to control.     

云南大理地区1989—2019年期间气候变化及对洱海水质的影响

依据1989年至2019年云南大理地区所辖12个气象站点的气候数据和洱海水质监测资料等文献,分析大理地区气候变化特征和洱海富营养化变化趋势,并总结洱海水质综合营养状态指数与降水量、气温的相互关系。结果表明,1989年至2019年期间,大理地区的年平均气温呈波动上升趋势,气候变暖明显,冬季气温升温幅度最大;年降水量总体呈波动下降趋势,秋季降水量减少最为显著。洱海水质的综合营养状态指数及单因子总氮、总磷、高锰酸盐指数等总体呈升高趋势,而水体透明度呈降低趋势;进一步可分成2个阶段,即2003年之前呈快速上升或下降变化趋势;2003年之后呈波动稳定趋势。洱海综合营养状态指数与年平均气温呈正相关,与年降水量呈负相关关系;总氮、水体透明度分别与年平均气温正相关和负相关,与年降水量则呈负相关和正相关;而总磷与冬季平均气温、高锰酸盐指数与夏季或冬季平均气温均呈正相关关系。年内变化上,洱海污染指数、综合营养状态指数在最近的2015—2019年期间呈现6—10月份明显增高,显示非汛期水质明显好于汛期状况。总之,1989—2019年期间,受大理地区气温升高、降水量减少导致入湖水量减少的影响,洱海综合营养状态指数呈升高趋势,湖泊富营养化进程加剧状况没有得到改善,洱海水环境仍然比较脆弱。     

沱江沉积物-水界面磷形态垂向分布及时空变化特征

水体中富营养化水平与磷元素的赋存形态密切相关。目前围绕引起富营养化关键因子之一的磷形态的垂向分布特征、各磷形态间的迁移转化行为及其影响因素取得了比较明确的研究进展。为进一步揭示不同磷形态在沉积物-水体系中迁移转化行为随时空的变化特征,本文采用磷钼蓝分光光度法对沱江流域简阳段间隙水中可溶性活性磷(SRP)、可溶性非活性磷(SUP)及总溶解性磷(TDP)进行测定;采用SMT法和改进的沉积物无机磷形态连续提取法对沉积物中总无机磷(TIP)、总磷(TP)、难提取磷(Res-P)、可交换态磷(Exc-P)、铁结合态磷(Fe-P)、铝结合态磷(Al-P)、钙结合态磷(Ca-P)进行提取,磷钼蓝分光光度法进行测定,以揭示沉积物-水体系中磷的赋存形态垂向分布行为特征,并将实验数据与十年前该地区磷的赋存形态结果进行对比,探讨磷赋存形态的变化趋势及影响因素。结果表明:间隙水中SRP、SUP和TDP的含量分别为0.004～0.36mg/L、0.080～3.19mg/L和0.056～3.28mg/L;沉积物中TP、TIP、Res-P、Exc-P、Al-P、Ca-P含量分别为1235.40～1646.94mg/kg、860.00～1318.59mg/kg、130.31～537.13mg/kg、1.35～14.10mg/kg、0.007～0.12mg/kg、743.13～1109.91mg/kg,Fe-P未检出。对比十年前后沉积物-水体系中磷赋存形态的变化可知,由于受到外源磷输入的影响,间隙水中SRP、SUP以及TDP含量虽然在-10cm以上变化不明显,但在-10cm以下明显增大,且导致沉积物中TP、TIP含量增加;偏碱性的沉积环境导致Al-P的释放,其含量明显减小;Exc-P含量的减小与其转化为稳定的Ca-P或Res-P形态有关。研究认为:随着时空的变化,沱江简阳段沉积物呈现外源磷输入和内源磷释放的综合污染。总体而言,由于输入的磷形态大部分以稳定的Ca-P和Res-P形态存在于沉积物中,使得表层间隙水中生物可直接利用的磷含量总体变化不大,该地区富营养化程度不会加重。维持沉积环境的弱碱性,有利于Al-P、Exc-P等向Ca-P的有效转换,抑制河流富营养化。     

长江口及其邻近海域孔隙水地球化学特征

对长江口沉积物有机碳、总氮、总磷、Fe、Mn、AI及孔隙水和上覆水体中营养盐、Fe、Mn的含量进行了测试,结合早期成岩模型及地球化学热力学分析,探讨了在河口环境中影响孔隙水营养盐和Fe、Mn分布的主要因素,并对沉积物-水界面营养盐扩散通量进行了估算。结果表明,孔隙水中NH4^＋、NO3^-、PO3^4、H4SiO4和Fe、Mn的含量显著高于上覆水体。早期成岩过程是控制长江口沉积物孔隙水营养盐和Fe、Mn分布的主要因素。NH^4＋剖面暗示长江口近岸和远岸海域存在两类不同的生物地球化学过程。孔隙水Fe、Mn剖面暗示在河口环境中其是有机质降解的重要电子受体。在近岸海域MnO2可能是底部NH4^＋ -N移除的重要机制。长江口孔隙水中低磷酸盐与铁及沉积物中磷的形态有关。通量计算结果显示NH4^＋、NO3^-、PO4^3-、地SiO4、Fe和Mn向上覆水体扩散的通量分别为356—3074μmol／（m2·d）、-45．3～62．6μmol／（m2·d）、-0．3～1．7μmol／（m^2·d）、323—3172μmol／（m^2·d）、3．0～10．5μmol／（m^2·d）和35．7～439．5μmol／（m^2·d）。N、P、Si界面通量对上覆水体浮游生物所需营养盐的贡献分别为0．19％～1．65％、0．13％～0．14％和1．2％～12．2％,因此在考虑长江口区域浮游生物所需营养的来源时,沉积物-水界面营养盐扩散通量可以忽略。     

九寨沟优势植物凋落物叶片淋溶的碳氮磷释放特征

通过对九寨沟水体中两种优势植物落叶的碳氮磷淋溶动态分析发现:初期总溶解碳氮磷释放在48 h内逐渐稳定,表明短期的淋溶过程就可以导致较大比例的元素释放;磷的短期平均可溶出比例为29.61%,表明淋溶是植物磷元素释放的重要途径;估算得出九寨沟植物叶片碳氮磷贡献总量分别可达20 577 t.a-1,2 101 t.a-1,1 402 t.a-1。研究表明九寨沟植物凋落物淋溶是水体碳氮磷的重要来源,也是影响钙华沉积的重要因素。分析凋落物养分溶出特征,可为九寨沟生态系统的健康发展提供数据支撑。      

辽河大伙房水库汇水区农业非点源污染入库模拟

利用输出系数法和SWAT模型,对大伙房水库汇水区农业非点源污染(ANSP)进行了入库模拟研究,并用2006—2009年的水文和水质监测数据对模型进行了校准和验证。研究结果表明:汇水区年均输入到水库的泥沙量、总氮和总磷负荷分别为82.65×103 t、1 873.49t和81.97t;月入库泥沙量、总氮和总磷负荷与径流量有着较强的相关性,ANSP的产生和迁移受降水、径流过程影响很大,每年7、8月份的氮、磷和泥沙流失量达到年内最大值,分别占全年流失总量的42.64%、44.42%和67.91%。水库汇水区各流域对水库氮、磷污染的贡献率由大到小依次为:浑河流域(清原段)、苏子河流域、社河流域和水库周边小流域。     

不同碳酸盐岩和土层厚度下土壤微生物数量及生物量的研究——以贵阳市花溪区为例

碳酸盐岩发育土壤的厚度变幅大,通过野外挖掘调查,在贵阳市花溪区分薄土、中土及厚土3种土层类型研究喀斯特地区不同土层厚度下微生物数量及生物量,结果表明:随着土层厚度的增加,土壤的细菌、真菌、放线菌及微生物总数逐渐增加;细菌在土壤微生物中占据了绝对优势,在石灰岩及白云岩发育土壤的各土层中分别占88.13%、85.71%、87.36%、85.00%及77.78%;石灰岩发育的土壤从薄土到厚土微生物量碳（C）、氮（N）、磷（P）的含量逐渐增加,分别增加15.15 mg·kg-1、2.82 mg·kg-1、0.18 mg·kg-1,白云岩从薄土到中土微生物量C、N、P的含量分别增加5.13 mg·kg-1、0.39 mg·kg-1、0.10 mg·kg-1;在同等厚度下石灰岩发育的土壤微生物量N、P含量明显低于白云岩发育的土壤,中土中差异最大,分别相差0.90 mg·kg-1和0.21 mg·kg-1,而石灰岩发育土壤的中土中微生物量C的含量则高于白云岩发育的土壤,高17.31 mg·kg-1;探讨相关性,pH值对微生物量C、P有显著影响（p<0.05）,全P含量对微生物量P有极显著影响（p<0.01）。      

天津围海造陆区吹填土氮磷的分布特征

天津临港经济区地处滨海, 完全是由填海造陆形成的人工陆地。土壤是港口航道清淤淤泥、近海海沙吹填围海造陆后形成的吹填土, 其性质特殊, 研究吹填土壤中氮磷空间分布对了解该区域环境状况有重要意义。研究发现:天津临港吹填土整体含氮量较低, 按土层深度分布, 平均质量分数为161.73~240.09 mg/kg;含磷量相对丰富, 平均质量分数为355.54~443.27 mg/kg;总氮变异系数较大, 总磷变异系数较小, 氮、磷质量分数主要受不同区域吹填土性质影响。吹填土中有机磷质量分数较少, 平均仅占总磷的3.83%, 吹填土中磷大多以无机磷形式存在, 其相对质量分数从大到小为:钙结合磷(Ca-P) >铁结合磷(Fe-P) >铝结合磷(Al-P) >闭蓄态磷(Oc-P) >碎屑磷(De-P) >交换态磷(Ex-P)。研究表明, 临港吹填土氮、磷质量分数水平对近海环境有潜在富营养污染威胁。     

Ecosystem functioning in the German Bight under continental nutrient inputs by rivers

The functioning of the German Bight ecosystem is determined largely by nutrient fluxes in and out of the system, namely by the advection of nutrients from the central and southern North Sea, including the influence of the Rhine River; by nutrient inputs through direct continental river runoff into the German Bight (Elbe, Weser, and Ems rivers); and by atmospheric nutrient inputs originating from land. The nutrient situation in the German Bight and the entire North Sea is assessed by estimating these fluxes from available nutrient data. The advective inflowes are based also on simulated water transports. The circulation system in the North Sea is divided into a northern and a southern cell, with only little net water exchange. The nutrient inflow into the southern North Sea from the north is also small, with no effect on the continental coastal areas. For the entire North Sea, the total input of phosphorus increased by 7.7% an nitrogen by about 11.4% from 1950 to 1980. The percentage of Atlantic input of phosphorus into the entire North Sea decreased from 91% to 85%, while river input increased from 2% to 13%. In the continental coastal strip the total inputs increased by 80%. The share of river input increased to 52%, both for phosphorus (1950: 14%) and nitrogen (1950: 20%). Of the winter nutrient content of the upper 30 m of the entire North Sea 33.5% of phosphate and 16.1% of nitrate are taken up by algae until summer. About 50% of total new production is generated in the coastal areas, with 32.8% of the volume and 34.4% of the area of the North Sea. The ratio of new to regenerated production ranges from 2.8 to 12, depending on the method of derivation. In the German Bight, phosphate and nitrate concentrations increased during the last four decades. At Helgoland the five-year-medians of phosphate and nitrate increased by a factor of 1.7 and 2.5, respectively. As the nutrient inputs by river discharges are only slightly larger than advective contributions, the nutrient concentrations rose comparatively slowly. Diatoms stagnated, while flagellates increased 10-fold. Common winter values in the early 1980s resemble those during summer blooms in the early 1960’s. The German Bight ecosystem has changed drastically on all time scales under the anthropogenic nutrient inputs during the last 40 years; the plankton system is no longer in an annual quasiperiodic state.     

洪湖流域传统农业条件下营养盐输移模拟研究*

文章选择位于长江中游的洪湖流域作为研究对象,应用流域分布式水文模型SWAT,探讨传统农业条件下流域营养盐输移的规律。模拟时段选择为建国初期的1951~1960年,模拟的边界条件设置为自然地形、土壤、传统农业生产和土地利用方式,其中土壤资料包括营养盐(N和P)、有机质含量、粒径等理化参数等。根据流域汇水范围的变化,模拟分汛期与非汛期两个时间段进行。通过对模型参数率定和调试,水文模拟结果与实测值有较好的吻合程度,由此进行营养盐输出模拟。模拟结果显示,传统农业条件下流域营养盐输出,TN和TP浓度变化有明显的季节特征,体现了耕作制度对营养盐浓度的影响; 同时,该时段营养盐浓度相比较自然条件下有了很大的改变,体现了人类活动对流域营养盐输移的影响,主要是土地利用类型变化和湖泊水域面积的缩小。     

Effect of groundwater on the ecological water environment of typical inland lakes in the Inner Mongolian Plateau

To explore the causes of the ecological environment deterioration of lakes in the Inner Mongolia Plateau, this study took a typical inland lake Daihai as an example, and investigated the groundwater recharge in the process of lake shrinkage and eutrophication. Using the radon isotope (²²²Rn) as the main means of investigation, the ²²²Rn mass balance equation was established to evaluate the groundwater recharge in Daihai. The spatial variability of ²²²Rn activity in lake water and groundwater, the contribution of groundwater recharge to lake water balance and its effect on nitrogen and phosphorus pollution in lake water were discussed. The analysis showed that, mainly controlled by the fault structure, the activity of ²²²Rn in groundwater north and south of Daihai is higher than that in the east and west, and the difference in lithology and hydraulic gradient may also be the influencing factors of this phenomenon. The ²²²Rn activity of the middle and southeast of the underlying lake is greater, indicating that the ²²²Rn flux of groundwater inflow is higher, and the runoff intensity is greater, which is the main groundwater recharge area for the lake. The estimated groundwater recharge in 2021 was 3 017×10⁴ m³, which was 57% of the total recharge to the lake, or 1.6 times and 8.1 times that of precipitation and surface runoff. The TN and TP contents in Daihai have been rising continuously, and the average TN and TP concentrations in the lake water in 2021 were 4.21 mg·L^?1 and 0.12 mg·L^?1, respectively. The TN and TP contents entering the lake with groundwater recharge were 6.8 times and 8.7 times above those of runoff, accounting for 87% and 90% of the total input, respectively. The calculation results showed that groundwater is not only the main source of recharge for Daihai, but also the main source of exogenous nutrients. In recent years, the pressurized exploitation of groundwater in the basin is beneficial in increasing the groundwater recharge to the lake, reducing the water balance difference of the lake, and slowing down the shrinking degree of the lake surface. However, under the action of high evaporation, nitrogen and phosphorus brought by groundwater recharge would become more concentrated in the lake, leading to a continuous increase in the content of nutrients and degree of eutrophication. Therefore, the impact of changes in regional groundwater quantity and quality on Daihai is an important issue that needs further assessment.     

中国北方某湖泊底泥污染分析及重金属潜在生态风险评价

以中国北方某湖泊(以下称A湖)为例,开展了底泥中氮磷污染及重金属生态风险评价研究,探讨多种评价方法的相关性,并分析底泥中氮磷元素向上覆水迁移造成水体富营养化的风险.选取A湖中心区域的10个底泥监测点位数据,对其总氮、总磷及重金属(Pb、Cr、As、Cd、Ni)含量进行分析,并采用有机污染指数法评价总氮污染,单因子指数法...     

黄河干流潼关断面非点源污染负荷估算

基于平均浓度法原理,根据黄河中游降雨径流特点,将年内过程分为汛期和非汛期两个阶段,同时将高含沙水流中的污染负荷分为水体中的溶解态污染负荷、泥沙吸附态负荷两部分,提出了多沙河流非点源污染负荷估算模型;根据黄河干流潼关断面1950-2006年实测水沙资料,结合水体、泥沙污染物浓度测定试验,分别计算了潼关断面2006年以及丰水年(P=25%)、平水年(P=50%)、枯水年(P=75%)3种不同代表年型下的非点源污染负荷.结果表明:黄河干流潼关断面年污染负荷以汛期为主,汛期污染负荷以非点源为主;非点源污染负荷中,硝酸盐氮、氨氮以溶解态为主,总磷以吸附态为主;潼关断面非点源污染负荷占全年负荷比例:丰水年时,硝酸盐氮占63.09%,氨氮占61.32%,总氮占87.17%、总磷占89.83%;枯水年时,硝酸盐氮占26.92%,氨氮占24.62%,总氮占67.60%、总磷占71.73%.2006年,硝酸盐氮、氨氮、总氮和总磷非点源污染负荷占全年比例依次为:17%、14%、15%和41%.     

利用矿物方解石进行水体除磷实验研究

为探索解决水体富营养化问题的新方法,利用矿物方解石对含磷溶液进行了除磷实验。实验结果表明,方解石晶芽可以促进磷的沉淀,降低溶液磷浓度;其降磷效果与溶液初始磷浓度有关,初始磷浓度为1.2mg/L,除磷率为12.68%,初始磷浓度为3mg/L,除磷率为69.94%,初始磷浓度为5mg/L,除磷率为88.48%;同样,实验温度升高,可使方解石降磷效果明显提高。经透射电子显微镜测试,除磷沉淀物没有明显的晶质体特征。     

江西省鄱阳湖地区饮用水健康风险评价

按照美国环境保护局风险评价模型,对江西省鄱阳湖地区24个县市的饮用水中As、Cd、Hg、Pb、F、氨氮和酚进行了健康风险评价。研究结果表明,通过饮水途径所致健康风险中,As在彭泽县所引起的致癌风险最大(29.1×10-6.a-1),Cd在鄱阳县的致癌风险最大(7.94×10-7.a-1),但均低于国际辐射防护委员会(ICRP)推荐的通过饮水途径最大可接受风险水平(5×10-5.a-1);通过饮水途径引起的非致癌健康风险中,酚的风险最大,出现在鄱阳县(4.99×10-9.a-1),远低于ICRP推荐的最大可接受风险水平。最后将致癌风险和非致癌风险相加得出鄱阳湖24个县市的整体健康风险,结果显示研究区的总风险水平介于10-6~10-11.a-1,基本处于可接受的水平。高风险区主要为彭泽县、南昌市、南昌县、湖口县,这些地区的饮用水环境健康问题应引起更多的关注。     

水体富营养化状态对城市河道底泥吸附/释放P的影响——以江苏省苏州市河道试验研究为例

以苏州古城区内的河道为研究对象,采用静态培养的方式,研究了上覆水体不同富营养化程度对底泥中P释放/吸附的影响。研究结果表明：截断外源污染后,苏州河道底泥对水体中营养盐P呈现吸收状态;随着上覆水体磷酸盐浓度的增大,单位面积底泥累积吸收的磷酸盐就越多;上覆水与底泥比值越大,底泥对P的吸附率有减小的趋势。     

水体富营养化状态对城市河道底泥吸附/释放P的影响 ——以江苏省苏州市河道试验研究为例

以苏州古城区内的河道为研究对象,采用静态培养的方式,研究了上覆水体不同富营养化程度对底泥中P释放/吸附的影响。研究结果表明：截断外源污染后,苏州河道底泥对水体中营养盐P呈现吸收状态;随着上覆水体磷酸盐浓度的增大,单位面积底泥累积吸收的磷酸盐就越多;上覆水与底泥比值越大,底泥对P的吸附率有减小的趋势。     

仙桃地区关键带生态演化与碳埋藏

仙桃地区湖群不断萎缩,水体富营养化水平和湿地沉积物重金属含量持续升高,江汉湖群生态系统日益脆弱,加强对该地区生态环境演化研究、分析人类活动和富营养化对湖泊生态系统的影响、探究该地区不同沉积环境的碳埋藏规律等显得尤为重要.在对江汉平原重点地区(仙桃彭场镇幅和脉旺咀幅)第四纪地质调查的基础上,选取研究区大型渔场、小型鱼塘、沟滩、湖泊、水稻田、泄洪道、旱地、汉水阶地8种不同沉积环境的16个关键带点位,分别测定了其表层及浅层钻孔沉积物的色素、TOC(total organic carbon,总有机碳)与TN(total nitrogen,总氮).表层沉积物TOC含量反映了研究区南部多湖泊区域有机碳埋藏量较高,而北部冲、洪积成因环境相对较低,与色素、TN所指示的人类活动强度和富营养化水平相吻合.湿地浅层钻孔沉积物碳埋藏速率变化整体表现为升高趋势,与色素所指示的湖泊富营养化的趋势相吻合;不同沉积环境碳埋藏速率差异较大,最高为大型渔场77.71 g·m-2·a-1、最低为汉水阶地3.61 g·m-2·a-1.研究结果表明,受到人类活动影响,湖相沉积物中碳埋藏量相对较高,湖泊碳汇功能不断增强,这对江汉平原关键带碳循环研究具有重要意义.      

水体叶绿素二维生态动力学模型研究

针对边界曲折复杂的河川型水库,以质量平衡方程为基础,以各生态变量的生态动力过程为核心,并结合水库的二维水动力学模型,建立了曲线坐标系下的水体叶绿素二维生态动力学模型,该模型结合水动力学条件,考虑了富营养化过程中的生物、化学和物理变化,给出了更为详细的富营养化信息,适用于计算区域复杂的水体。结合隔河岩水库的实测数据,用矩阵追赶法给出了模型的数值解,从而得到水库中总氮、总磷和叶绿素a的分布。经验证,模型的计算结果与实测值吻合较好。