Major, trace and REE geochemistry of the Ganga River sediments: Influence of provenance and sedimentary processes

The sediments of the Ganga River from different depositional regimes in the Plain region such as the river channel, active flood-plain and the older flood-plain sediments from the inter-fluve region were analysed for major, trace and the rare earth elements (REEs). These are compared with catchment zone sediments of the river and probable source rocks in the Himalaya. The lower CIA values between 48 and 54.7 for the catchment sediments indicates that the sediments supplied to the Ganga Plain are chemically immature and subjected mostly to physical weathering due to higher erosion rates in the Himalaya. The CIA values ranging between 55 and 74, with average value of 59, 61.4 and 67 for sediments from the Plain's bed-load, active flood-plain and older flood-plain from the inter-fluve region indicates that silicate weathering of Ganga River sediments has occurred only after entering into the plains. This is likely because of higher residence time and change in the climate from cold-frigid in the Himalaya to tropical sub-humid in the plains. Therefore, the use of geochemical data on ancient system to infer climate in their source region may not always be true. Although the CIA values indicate a moderate chemical weathering in the plains, it is far from impressive. Dominance of physical weathering in the catchment region and lower degree of chemical weathering in the Plains indicate that weathering of sediments supplied by Himalayan Rivers, particularly the Ganga River may not have affected the atmospheric CO₂ to a significant level as is generally believed. Thus the net effect of the Himalaya on the CO₂ sequestration and consequent global cooling needs a re-evaluation.The plots of sediments in ternary diagram among La, Th, Sc and ratios involving Co/Th, La/Sc and Sc/Th indicate granitic to granodioritic source rocks to the sediments. The ratio plots involving relatively immobile Al₂O₃, TiO₂ and FeO along with REE plots suggest that out of the major Himalayan lithologies, gneisses and Cambro-Ordovician granites of HHCS have acted as the dominant source to the sediments.The plots of LogNa₂O/K₂O vs. LogSiO₂/Al₂O₃ and FeO/SiO₂ vs. Al₂O₃/SiO₂ diagrams show that the combination of processes including erosion, weathering, sorting and aeolian activity has together played a major role in progressively changing the chemistry from source rock to catchments bed-load to Plains bed-load, active flood-plains and the older inter-fluve sediments in the Ganga River system. The above plots demonstrate that as a result of above processes the ratios between the elements generally thought to be immobile and used in provenance studies does not always remain invariant and the linear trend line in the scatter gram between the two immobile elements show rotation around the fine grained end member.     

Geochemistry,provenance, and tectonic setting of Neoproterozoic metavolcanic and metasedimentary units,Werri area,Northern Ethiopia

Major, trace and rare earth element (REE) compositions of upper Proterozoic metavolcanic and metasedimentary rocks from the Tsaliet and Tembien Groups in the Werri district of northern Ethiopia were determined to examine their tectonic setting of eruption, provenance and source area weathering conditions. Tsaliet Group metavolcanic rocks in the Werri area have sub-alkaline chemistry characterized by low to intermediate SiO₂ contents, high Al₂O₃, low MgO and very low Cr and Ni. High field strength element (HFSE) abundances are highly variable. ∑REE abundances vary from 66.7 to 161.3 ppm, and chondrite-normalized REE patterns are moderately fractionated, with La_N/Yb_N values of between 3.1 and 9.0. Europium anomalies are variable (Eu/Eu* 0.80–1.21) but are generally positive (average Eu/Eu* 1.06). On tectonic discrimination diagrams, most samples have either volcanic-arc chemistry or fall in the overlap field with mid-oceanic ridge basalt (MORB). However, primitive mantle-normalized trace element abundances are comparable with sub-alkaline basalts from developed island arcs. ¹⁴⁷Sm/¹⁴⁴Nd ratios range from 0.1167 to 0.1269 (n = 3), yielding initial εNd_(800 Ma) of +3.8 to +4.9 and mean T_DM model age of 0.96 Ga, indicative of derivation from juvenile Neoproterozoic mantle. Metasediments from three locations (Werri1, Werri2 and Tsedia) in the Werri and Tsedia Slates have similar Al₂O₃, TiO₂ and HFSE contents but variable and low Na₂O, CaO and K₂O. Cr and Ni are slightly enriched in the Werri2 and Tsedia suites. SiO₂ is very variable, with average values of 70.75, 72.2 and 66.4 wt.% in the Werri1, Werri2 and Tsedia suites, respectively. ∑REE abundances in the metasediments (14.74–108.1) are lower than in the metavolcanics, and are slightly less fractionated, with La_N/Yb_N ratios of 0.8–5.9. Europium anomalies vary (Eu/Eu* 0.80–1.21) but are insignificant on average (Eu/Eu* 0.96). High values for the Chemical Index of Alteration (generally 70–90), and Plagioclase Index of Alteration (>75) in the Werri metasediments indicate moderate to severe chemical weathering in their source. Average major and trace element compositions of the metasediments and their REE patterns are comparable with the metavolcanics. ¹⁴⁷Sm/¹⁴⁴Nd ratios of the metasediments range from 0.1056 to 0.1398 (n = 4), with initial εNd_(800 Ma) of +3.4 to +5.0 and mean T_DM model age of 0.97 Ga, indicating derivation from juvenile Neoproterozoic crust similar to the underlying metavolcanics, with minimal (4–10%) contribution from older crust. The most sensitive tectonic setting discriminators indicate the Werri metasediments represent developed oceanic island arc sediments. The chemical similarity of the Werri metavolcanics to the nearby Adwa metavolcanics, Nakfa terrane in Eritrea, and volcanic units in central Saudi Arabia imply that juvenile Neoproterozoic Arabian Nubian Shield crust extended south at least as far as the Werri area of northern Ethiopia. The comparable geochemistry of the metasediments and their underlying lithologies attests to their derivation from this juvenile crustal material.     

Geochemical evolution of the Tertiary succession of the NW shelf,Bengal basin,Bangladesh: Implications for provenance,paleoweathering and Himalayan erosion

Whole rock major, trace and rare earth element (REE) compositions of Paleogene to Neogene sedimentary rocks of the NW shelf succession (Province 1) of Bangladesh contain a record of interaction of the India and Asian plates, Himalayan tectonism, and climatic development. Analyses of 66 sandstones and mudrocks from the Tertiary succession of Bangladesh were made to examine provenance, source weathering, and the influence of paleoclimate and tectonism. The sediments display linear geochemical trends due to quartz dilution, and varying quartz–clay ratios produced by hydrodynamic sorting. Chondrite-normalized REE patterns for both sandstones and mudrocks from different groups are similar to upper continental crust, with moderate to high LREE enrichment (lithotypes within formations average La_N/Yb_N 5.31–11.41) and marked negative Eu anomalies (Eu/Eu^* 0.51–0.69). Based on geochemical criteria the succession can be divided into three parts (Jaintia; Barail–Surma; and Dupi Tila). Very high silica contents in Jaintia Tura sandstones and high Chemical Index of Alteration (CIA) indices in Kopili mudrocks (Fe-shales) suggest derivation from a deeply weathered and stable cratonic source (India). The Tura sandstones are interpreted as first-cycle quartz arenites, produced while the Indian plate drifted across equatorial regions during the Paleocene–Eocene Thermal maximum (PETM). The Barail–Surma and Dupi Tila sediments were derived from a felsic orogen (the Himalaya). The Barail–Surma sediments were mainly derived from the Trans Himalayan Batholith and associated granitoids, with significant contribution from the Lesser Himalaya. Mafic input is also evident, probably from intraoceanic arc material within the Himalaya. Barail mudrocks have uniformly high CIA values (92–95), suggesting intense steady-state weathering of their proto-Himalayan source, and warm and humid climate. In contrast, CIA values of Surma mudrocks range from 66 to 93 (average 84), suggesting non-steady state weathering related to active uplift in the Himalaya. The Dupi Tila sediments were derived from a more felsic Lesser Himalaya source, with significant contribution from the Trans-Himalaya and very little or no ophiolitic or arc material. Dupi Tila mudrocks have CIA ratios of 62–99 (average 72), also indicating non-steady state weathering in the rising Himalayan source. Geochemical compositions of the NW shelf sediments are comparable to coeval successions in the Surma basin (Province 2) of Bangladesh and the Siwaliks (India), indicating similar source. Evolution of the Indian monsoon and associated high precipitation caused intense chemical weathering of the Surma and Dupi Tila source, despite rapid uplift. The Surma Group thus bears the signature of evolution of the Asian monsoon in the Bengal basin at 21 Ma, simultaneous with the development of the East Asian monsoon. This supports proposals that both monsoon systems developed at the same time.     

Geochemistry of black shales from the Lower Cretaceous Paja Formation,Eastern Cordillera,Colombia: Source weathering,provenance, and tectonic setting

The major and trace element characteristics of black shales from the Lower Cretaceous Paja Formation of Colombia are broadly comparable with those of the average upper continental crust. Among the exceptions are marked enrichments in V, Cr, and Ni. These enrichments are associated with high organic carbon contents. CaO and Na₂O are strongly depleted, leading to high values for both the Chemical Index of Alteration (77–96) and the Plagioclase Index of Alteration (86–99), which indicates derivation from a stable, intensely weathered felsic source terrane. The REE abundances and patterns vary considerably but can be divided into three main groups according to their characteristics and stratigraphic position. Four samples from the lower part of the Paja Formation (Group 1) are characterized by LREE-enriched chondrite-normalized patterns (average La_N/Yb_N = 8.41) and significant negative Eu anomalies (average Eu/Eu¹ = 0.63). A second group of five samples (Group 2), also from the lower part, have relatively flat REE patterns (average La_N/Yb_N = 1.84) and only slightly smaller Eu anomalies (average Eu/Eu¹ = 0.69). Six samples from the middle and upper parts (Group 3) have highly fractionated patterns (average La_N/Yb_N = 15.35), resembling those of Group 1, and an identical average Eu/Eu¹ of 0.63. The fractionated REE patterns and significant negative Eu anomalies in Groups 1 and 3 are consistent with derivation from an evolved felsic source. The flatter patterns of Group 2 shale and strongly concave MREE-depleted patterns in two additional shales likely were produced during diagenesis, rather than reflecting more mafic detrital inputs. An analysis of a single sandstone suggests diagenetic modification of the REE, because its REE pattern is identical to that of the upper continental crust except for the presence of a significant positive Eu anomaly (Eu/Eu¹ = 1.15). Felsic provenance for all samples is suggested by the clustering on the Th/Sc–Zr/Sc and Gd_N/Yb_N–Eu/Eu¹ diagrams. Averages of unmodified Groups 1 and 3 REE patterns compare well with cratonic sediments from the Roraima Formation in the Guyana Shield, suggesting derivation from a continental source of similar composition. In comparison with modern sediments, the geochemical parameters (K₂O/Na₂O, La_N/Yb_N, La_N/Sm_N, Eu/Eu¹, La/Sc, La/Y, Ce/Sc) suggest the Paja Formation was deposited at a passive margin. The Paja shales thus represent highly mature sediments recycled from deeply weathered, older, sedimentary/metasedimentary rocks, possibly in the Guyana Shield, though Na-rich volcanic/granitic rocks may have contributed to some extent.     

Provenance of the Greater Himalayan sequence: Evidence from mafic granulites and amphibolites in NW Bhutan

Mafic granulites and amphibolites in the Masang Kang area of NW Bhutan Himalaya have been investigated for their geochemical and isotopic characteristics in order to determine their protolith history. Bulk-rock major and trace element geochemistry indicate that the rocks were originally tholeiitic and alkali basalts with minor ultramafics. U–Pb zircon SIMS data suggest an age of 1742 ± 39 Ma for mafic magmatism. The age-corrected ε_Nd(1742) values of the rocks are highly variable, ranging from high positive (+ 8.4) to negative (? 3.3). The positive value suggests a primitive magma source, similar to that of rift-related tholeiites. We suggest that the rocks of the Masang Kang suite were produced during a major late Paleoproterozoic thermal event that caused the mobilization and enrichment of the sub-continental lithospheric mantle beneath the north Indian margin. The geochemical signature of these rift-related metabasic rocks may have been produced during an earlier episode of oceanic underplating or subduction from which the fluid required to mobilize and enrich the overlying sub-lithospheric mantle may have been derived. Though their occurrence is rare, Paleoproterozoic igneous rocks within the Greater Himalayan Sequence (GHS), in addition to sources identified throughout the LHS, may have contributed to the detrital zircon population that form the 1.7–1.9 Ga peak in the age spectra of the Lesser Himalayan Sequence (LHS). In addition, the coeval Paleoproterozoic magmatism in both LHS and GHS suggests that the two lithotectonic units may have belonged to the same continental plate at that time period.     

Central Himalayan crystallines as the primary source for the sandstone–mudstone suites of the Siwalik Group: New geochemical evidence

Geochemistry of the Sub-Himalayan foreland basin Siwalik sediments has been used for interpreting the nature of the source rocks. This study has shown that the compositional changes are a function of stratigraphic height, demonstrated by the upward increase of P₂O₅, Na₂O, CaO, MgO and SiO₂ content from Lower to the Upper Siwalik rocks. On the other hand, K₂O, Fe₂O₃, TiO₂ and Al₂O₃ show decrease with the increasing stratigraphic height. These trends are a clear reflection of time-controlled changes in the source lithology. Ratios such as Eu/Eu*, (La/Lu)_cn, La/Sc, Th/Sc, La/Co, and Cr/Th suggest a prominent felsic source area for the Siwalik sediments. Chondrite-normalized REE pattern with LREE enrichment and moderately flat HREE pattern with sharp negative Eu anomaly are attributed to a felsic source. Contrary to the existing belief, this study has ruled out any contribution from the mafic sources and highlighted the compositional similarities of Siwalik sediments with the crustal proxies like PAAS, NASC and UCC. The geochemical data point to a significant role played by the Precambrian and early Paleozoic granitic rocks of the Himalayan tectogene in shaping the composition of the foreland sediments. The variable CIA values and marked depletion in Na, Mg and Ca exhibited by the Lower, Middle and Upper Siwalik sediments reflect variable climatic zones and variations in the rate of tectonic uplift of the source area. Our results demonstrate that in the Lower Siwalik and part of the Middle Siwalik, Higher Himalayan Crystalline sequence (HHCS) was the primary source area with minor contributions by the meta-sedimentary succession of the Lesser Himalaya. Later, during the deposition of the upper part of the Middle Siwalik and Upper Siwalik, the source terrain switched positions. These two prominent source terrains supplied sediments in steadily changing proportion through time.     

Relationships between major and trace elements during weathering processes in a sedimentary context: Implications for the nature of source rocks in Douala,Littoral Cameroon

In Douala (Littoral Cameroon), the Cretaceous to Quaternary formation composed of marine to continental sediments are covered by ferrallitic soils. These sediments and soils have high contents of SiO₂ (≥70.0 wt%), intermediate contents of Al₂O₃ (11.6–28.4 wt%), Fe₂O₃ (0.00–20.5 wt%) and TiO₂ (0.04–4.08 wt%), while K₂O (≤0.18 wt%), Na₂O (≤0.04 wt%), MgO (≤0.14 wt%) and CaO (≤0.02 wt%) are very low to extremely low. Apart from silica, major oxides and trace elements (REE included) are more concentrated in the fine fraction (<62.5 μm) whose proportions of phyllosilicates and heavy minerals are significant. The close co-associations between Zr, Hf, Th and ∑REE in this fraction suggest that REE distribution is controlled by monazite and zircon. CIA values indicate intense weathering. Weathering products are characterized by the association Al₂O₃ and Ga in kaolinite; the strong correlation between Fe₂O₃ and V in hematite and goethite; the affinity of TiO₂ with HFSE (Hf, Nb, Th, Y and Zr) in heavy minerals. The ICV values suggest mature sediments. The PCI indicates a well-drained environment whereas U/Th and V/Cr ratios imply oxic conditions. La/Sc, La/Co, Th/Cr, Th/Sc and Eu/Eu* elemental ratios suggest a source with felsic components. Discrimination diagrams are consistent with the felsic source. The REE patterns of some High-K granite and granodiorite of the Congo Craton resemble those of the samples, indicating that they derive from similar source rocks.     

Petrological and geochemical characteristics of Zhaibei granites in Nanling region,Southeast China: Implications for REE mineralization

Mineralization with ion adsorption rare earth elements (REEs) in the weathering profile of granitoid rocks from Nanling region of Southeast China is an important REE resource, especially for heavy REE (HREE) and Y. However, the Jurassic granites in Zhaibei which host the ion adsorption light REE (LREE) ores are rare. It is of peraluminous and high K calc-alkaline composition, which has similar geochemical features of high K₂O + Na₂O and Zr + Nb + Ce + Y contents and Ga/Al ratio to A-type granite. Based on the chemical discrimination criteria of Eby [Geology 20 (1992) 641], the Zhaibei granite belongs to A1-type and has similar source to ocean island basalts. The rock is enriched in LREE and contains abundant REE minerals including LREE-phosphates and halides. Minor LREE was also determined in the feldspar and biotite, which shows negligible and negative Eu anomalies, respectively. This indicates that the Zhaibei granite was generated by extreme differentiation of basaltic parent magmas. In contrast, granites associated with ion adsorption HREE ores contain amounts of HREE minerals, and show similar geochemical characteristics with fractionated felsic granites. Note that most Jurassic granitoids in the Nanling region contain no REE minerals and cannot produce REE mineralization. They belong to unfractionated M-, I- and S-type granites. Therefore, accumulation of REE in the weathering profile is controlled by primary REE mineral compositions in the granitoids. Intense fractional crystallization plays a role on REE enrichment in the Nanling granitoid rocks.     

Oligocene HP metamorphism and anatexis of the Higher Himalayan Crystalline Sequence in Yadong region,east-central Himalaya

The Higher Himalayan Crystalline Sequence (HHCS) provides an excellent natural laboratory to study continental subduction, crustal melting and tectonic evolution of orogenic belt generated through the collision of India with Eurasia. Our petrological study and phase equilibrium modeling reveal that the pelitic migmatites in the HHCS of Yadong region, east-central Himalaya, preserve an early mineral assemblage garnet, kyanite, biotite, quartz, plagioclase, K-feldspar, rutile and ilmenite, and a late sillimanite- and/or cordierite-bearing assemblage, and underwent the high pressure (HP) and high temperature (HT) granulite-facies metamorphism and associated partial melting under P–T conditions of ca. 12 kbar and 825–845 °C, followed by nearly isothermal decompression and isobaric cooling. The anatexis of the migmatites occurred dominantly through dehydration-melting of both muscovite and biotite during the prograde metamorphism. The melt produced in the peak metamorphic conditions is about 20 to 30 vol.% of the rocks, and a significant amount of melt has been extracted from the source leading to the formation of Himalayan leucogranites. The zircon U–Pb dating data shows that the migmatites probably witnessed a prolonged melting episode that began at ca. 30 Ma and lasted to ca. 20 Ma. These results show that the thickening lower crust of the Himalayan orogen experienced long-lived and continued HP and HT metamorphism and pervasive anatexis, supporting the models on channel flow.     

Re-Os isotope systematics of sediments of the Brahmaputra River system

Re-Os analyses were performed on suspended loads and coarser grained bank sediments of the Brahmaputra River system. Re and Os concentrations of these sediments vary from 7 to 1154 ppt and from 3 to 173 ppt, respectively. ¹⁸⁷Os/¹⁸⁸Os ratios range from 0.178 to 6.8, and thus vary from nearly mantle to very radiogenic crustal values. Nevertheless, most of the sediments have ¹⁸⁷Os/¹⁸⁸Os ratios less than 1.5, and nearly all of the samples of the Brahmaputra main channel have ratios less than 1.2. Thus, as previously suggested, the Brahmaputra is much less radiogenic than the Ganga. The Siang River, the northern extension of the Brahmaputra, is quite radiogenic in Os despite receiving sediments from the Tsangpo River, which flows along a suture zone with ultramafic outcrops. The Brahmaputra main channel has a fairly constant ¹⁸⁷Os/¹⁸⁸Os ratio even though its tributaries contribute sediments with very heterogeneous Os isotopic compositions. These data, along with the corresponding Nd isotopic compositions, suggest that about 60-90% of the sediment in the Brahmaputra system is derived from Himalayan formations (Higher Himalaya and Lesser Himalaya) whereas 10-40% comes from ophiolite-bearing sequences, perhaps eastern equivalents of those of the Transhimalayan Plutonic Belt. Os data also confirm previously published Sr and Nd results, indicating that about half of the sediments delivered to the Brahmaputra are supplied by the Siang River, while the Himalayan and the eastern tributaries account for 40 and 10%, respectively.The lower ¹⁸⁷Os/¹⁸⁸Os of the Brahmaputra River compared to that of the Ganga is due to two factors. One is the more limited presence of the Lesser Himalaya and hence the lower black shale content of the eastern Himalaya. The other is the non-radiogenic Os supplied by the eastern and southern tributaries, reflecting the presence of mantle-derived lithologies in this region. Despite the lower sediment supply from these tributaries, they contribute greatly to the Os budget of the Brahmaputra River. This study indicates that the Brahmaputra River has little effect on the present-day seawater Os budget. However, reconsideration of this budget suggests that the Ganga, which provides the most radiogenic Os of major rivers studied to date, may have significant impact on the marine Os isotopic composition. The Indo-Asian collision cannot be excluded as an important cause of the increase in the marine ¹⁸⁷Os/¹⁸⁸Os over the past 16 million years until the contributions of all of the rivers draining the Himalayan Tibetan Plateau are known.     

Sources of stream sediments in the granulite terrain of the Walawe Ganga Basin,Sri Lanka,indicated by rare earth element geochemistry

Thirty-eight samples of stream sediments draining high-grade metamorphic rocks in the Walawe Ganga (river) Basin, Sri Lanka, were analysed for their REE contents, together with samples of metamorphic suites from the source region. The metamorphic rocks are enriched in light REE (LREE) compared to heavy REE (HREE) and are characterised by high La/Lu ratios and negative Eu anomalies. The chondrite-normalised patterns for these granulite-grade rocks are similar to that of the average post-Archaean upper crust, but they are slightly enriched with La and Ce. The REE contents of the <63-μm fraction of the stream sediments are similar to the probable source rocks, but the other grain size fractions show more enriched patterns. The <63-μm stream sediments fraction contains lower total REE, more pronouncd negative Eu anomalies, higher Eu_N/Sm_N and lower La _N/Lu_N ratios relative to other fractions. The lower La _N/Lu_N ratio is related to the depletion of heavy minerals in the <63-μm fraction. The 63–125-μm and 125–177-μm grain size fractions of sediments are particularly enriched in LREE (average ΣLREE=2990 μg/g and 3410 μg/g, respectively). The total HREE contents are surprisingly uniform in all size fractions. However, the REE contents in the Walawe Ganga sediments are not comparable with those of the granulite-grade rocks from the source region of the sediments. The enrichment of REE is accounted for by the presence of REE containing accessory mineral phases such as zircon, monazite, apatite and garnet. These minerals are derived from an unknown source, presumably from scattered bodies of granitic pegmatites.     

Geochemistry and behavior of REE in stream sediments close to an old Sn-W mine,Ribeira, Northeast Portugal

The abandoned Sn-W Ribeira mine, northeast of Portugal, contained quartz veins with cassiterite, wolframite, scheelite, pyrite, arsenopyrite, sphalerite, chalcopyrite, manganocolumbite, bismuthinite, native bismuth, phosphates and carbonates. The exploration took place on the northern slope of the Viveiros stream, which is an affluent of the Sabor River. The waste-rock dumps and tailings were deposited on the hillside, close to the mine and are nowadays exposed to significant weathering and erosion, as they are not vegetated. The eroded material is transported by the Viveiros stream toward the Sabor River. A seasonal stream drains the tailings. The stream sediments samples were collected along the Viveiros stream, in the seasonal stream, in a seasonal spring at the bottom of the tailings, in the Sabor River and in other streams not affected by mine workings, following the mine influence along the Viveiros stream and in the Sabor River (1.2 km away from the mine workings). The data show that the degree of pollution increases along the Viveiros stream, especially in winter. The highest degree of pollution is for As, In, W, Sn and Bi. The sediments from the drainage of the main tailings are particularly polluted during winter, by Bi, In and Sn. The sedimentary precipitate from the spring is polluted in Cu, As, In, Sn, Ta, W, Bi, Zn, Nb, Ag, Sb and Ta. The sediments from the Sabor River are significantly polluted by As, Ag, In, Sn, W and Bi. The sediments from the regional streams, Viveiros stream and Sabor River have similar REE (NASC normalized) patterns (ΣREE = 131.7–185.9 mg/kg, La_N/Lu_N = 1.23–1.42 and Eu/Eu* = 1.02), while those from the seasonal stream, crossing the main tailings, are enriched in REE (ΣREE = 250.3–283.6 mg/kg, La_N/Lu_N = 1.6–2.09 and Eu/Eu* = 0.96). The general decrease in La_N/Lu_N values with increase in total Fe₂O₃ can be explained by the partitioning of HREE to the solid Fe-oxides phase. The sedimentary precipitate and coatings, which are mainly formed by Fe-oxy-hydroxides, but also contain jarosite, are impoverished in all REE. The impoverishment can be explained by the release of REE from the surface of the Fe-oxy-hydroxides, which occurs due to a local lowering of pH, caused by jarosite dissolution. During successive alternate cycles of wet and dry conditions, takes place the formation of Fe-oxy-hydroxides and jarosite in the sedimentary precipitate and coatings. The subsequent dissolution of jarosite releases acidity, thus promoting de-sorption of REE from the Fe-oxy-hydroxides mineral phases.     

Thermobaric structure of the Himalayan Metamorphic Belt in Kaghan Valley,Pakistan

The thermobaric structure of the Himalayan Metamorphic Belt (HMB) has been constructed along the Kaghan Valley transect, Pakistan. The HMB in this valley represents mainly the Lesser Himalayan Sequence (LHS) and Higher Himalayan Crystallines (HHC). Mineral parageneses of 474 samples, from an approximately, 80-km traverse from southwest to northeast, were examined. Microprobe analyses were carried out to quantify the mineral composition. To determine the pressure–temperature (P–T) conditions, 65 thin sections (7 pelites from LHS and 25 pelites, 9 mafic rocks/amphibolites and 19 eclogites from HHC) were selected. Based on field observations and mineral paragenesis, low-grade to high-grade metapelites, show Barrovian-type progressive metamorphic sequence, with chlorite, biotite, garnet and staurolite zones in LHS and staurolite, kyanite and sillimanite zones in HHC. By using well-calibrated geothermobarometers, P–T conditions for pelitic and mafic rocks are estimated. P–T estimates for pelitic rocks from the garnet zone indicate a condition of 534 ± 17 °C at 7.6 ± 1.2 kbar. P–T estimates for rocks from the staurolite and kyanite zones indicate average conditions of 526 ± 17 °C at 9.4 ± 1.2 kbar and 657 ± 54 °C at 10 ± 1.6 kbar, respectively. P–T conditions for mafic rocks (amphibolites) and eclogites from HHC are estimated as 645 ± 54 °C at 10.3 ± 2 kbar and 746 ± 59 °C at 15.5 ± 2.1 kbar, respectively. The coesite-bearing ultrahigh-pressure (UHP) eclogites record a peak P–T condition of 757–786 °C at 28.6 ± 0.4 kbar and retrograde P–T conditions of 825 ± 59 °C at 18.1 ± 1.7 kbar.These results suggest that HMB show a gradual increase in metamorphic grade from southwest to northeast. The P–T conditions from Pelitic and adjacent mafic rocks having identical peak conditions in the same metamorphic zone, while the structural middle in HHC reached the highest P–T condition upto the UHP grade.     

Central Himalayan crystallines as the primary source for the sandstone–mudstone suites of the Siwalik Group: New geochemical evidence

Geochemistry of the Sub-Himalayan foreland basin Siwalik sediments has been used for interpreting the nature of the source rocks. This study has shown that the compositional changes are a function of stratigraphic height, demonstrated by the upward increase of P₂O₅, Na₂O, CaO, MgO and SiO₂ content from Lower to the Upper Siwalik rocks. On the other hand, K₂O, Fe₂O₃, TiO₂ and Al₂O₃ show decrease with the increasing stratigraphic height. These trends are a clear reflection of time-controlled changes in the source lithology. Ratios such as Eu/Eu*, (La/Lu)_cn, La/Sc, Th/Sc, La/Co, and Cr/Th suggest a prominent felsic source area for the Siwalik sediments. Chondrite-normalized REE pattern with LREE enrichment and moderately flat HREE pattern with sharp negative Eu anomaly are attributed to a felsic source. Contrary to the existing belief, this study has ruled out any contribution from the mafic sources and highlighted the compositional similarities of Siwalik sediments with the crustal proxies like PAAS, NASC and UCC. The geochemical data point to a significant role played by the Precambrian and early Paleozoic granitic rocks of the Himalayan tectogene in shaping the composition of the foreland sediments. The variable CIA values and marked depletion in Na, Mg and Ca exhibited by the Lower, Middle and Upper Siwalik sediments reflect variable climatic zones and variations in the rate of tectonic uplift of the source area. Our results demonstrate that in the Lower Siwalik and part of the Middle Siwalik, Higher Himalayan Crystalline sequence (HHCS) was the primary source area with minor contributions by the meta-sedimentary succession of the Lesser Himalaya. Later, during the deposition of the upper part of the Middle Siwalik and Upper Siwalik, the source terrain switched positions. These two prominent source terrains supplied sediments in steadily changing proportion through time.     

Total organic carbon transport by the Alaknanda River,Garhwal Himalayas,India

Transport and fate of organic carbon by the fluvial system play a significant role in the global biogeochemical cycle of carbon. Previous studies show that the transportation of modern organic carbon from the Himalayan River system accounts for 10–20% of the total global flux to the oceans. Till date, no study has been published which dealt with the transport of organic carbon in the headwaters of the Ganga River. The Alaknanda River is a headwater stream of the Ganga, which flows in the Western Himalayas of India. Water and freshly deposited channel sediment samples were collected during the months of March 2014 and August 2014 and analysed for dissolved organic carbon (DOC), particulate organic carbon (POC) and channel organic carbon (COC). The observed variability of organic carbon concentration was correlated with factors such as discharge, physiography and suspended sediment concentration (SSC). The results show that seasonal erosivity in the basin influences its DOC concentration and physiography, thus acting as a key parameter which controls transportation, oxidation and residence time of the organic matter. The allochthonous input of sediments from the erosional activities is the major source of organic carbon. At Devprayag, Alaknanda contributes 66% of the total DOC flux carried by the Ganga River. The comparison with the previously published values indicate that due to differences in physiography and chemical weathering rate, the Ganga River transports organic carbon mainly as a dissolved load in its upstream and predominantly as POC down the Himalayan foothills.     

Evidence for structural discordance in the inverted metamorphic sequence of Sikkim Himalaya: Towards resolving the Main Central Thrust controversy

Inverted metamorphism in the Himalayas is closely associated with the Main Central Thrust (MCT). In the western Himalayas, the Main Central Thrust conventionally separates high grade metamorphic rocks of the Higher Himalayan Crystalline Sequence (HHCS) from unmetamorphosed rocks of the Inner sedimentary Belt. In the eastern Himalayas, the Inner sedimentary Belt is absent, and the HHCS and meta-sedimentary Lesser Himalayan Sequence (LHS) apparently form a continuous Barrovian metamorphic sequence, leading to confusion about the precise location of the MCT. In this study, it is demonstrated that migmatitic gneisses of the sillimanite zone in the higher structural levels of the HHCS are multiply deformed, with two phases of penetrative fabric formation (S_1HHCS and S_2HHCS) followed by third folding event associated with a spaced, NW-SE trending, north-east dipping foliation (S_3HHCS). The underlying LHS schists (kyanite zone and lower) are also multiply deformed, with the bedding S₀ being isoclinally folded (F_1LHS), and subsequently refolded (F_2LHS and F_3LHS). The contact zone between the HHCS and LHS is characterized by ductile, top-to-the southwest shearing and stabilization of a pervasive foliation that is consistently oriented NW-SE and dips northeast. This foliation is parallel to the S_3HHCS foliation in the HHCS, and the S_2LHS in the LHS. Early lineations in the HHCS and LHS also show different dispersions across the contact shear zone, implying that pre-thrusting orientations of the two units were distinct. The contact shear zone is therefore interpreted to be a plane of structural discordance, shows a shear sense consistent with thrust movement and is associated with mineral growth during Barrovian metamorphism. It may well be considered to represent the MCT in this region.     

Temporal and compositional differences between subsolidus and anatectic migmatite leucosomes from the Quetico metasedimentary belt, Canada

Abstract Migmatites in the Quetico Metasedimentary Belt contain two types of leucosome: (1) Layer-parallel leucosomes that grew during deformation and prograde metamorphism. These are enriched in SiO₂, Sr, and Eu, but depleted in TiO₂, Fe₂O₃, MgO, Cs, Rb, REE, Sc, Th, Zr, and Hf relative to the Quetico metasediments. (2) Discordant leucosomes that formed after the regional folding events when metamorphic temperatures were at their peak. These are enriched in Rb, Ba, Sr and Eu, but display a wide range of LREE, Th, Zr, and Hf contents relative to the Quetico metasediments.
Layer-parallel leucosomes formed by a subsolidus process termed tectonic segregation. This stress-induced mass transfer process began when the Quetico sediments were deformed during burial, and continued whilst the rocks were both stressed and heterogeneous. Subsolidus leucosome compositions are consistent with the mobilization of quartz and feldspar from the host rocks by pressure solution. The discordant leucosomes formed by partial melting of the Quetico metasediments, possibly during uplift of the belt. The range of composition displayed by the anatectic leucosomes arises from crystal fractionation during leucosome emplacement. Some anatectic leucosomes preserve primary melt compositions and have smooth REE patterns, but those with negative Eu anomalies represent fractionated melts, and others with positive Eu anomalies represent accumulations of feldspar plus trapped melt.     

Geochemistry of orthogneisses and metasedimentary rocks across a proposed terrane boundary in the Central Domain of Borborema Province,NE Brazil: Geodynamic implications

The Borborema Province, northeastern Brazil, occupies a central position in pre-drift reconstructions of western Gondwana, making an understanding of its geological evolution crucial for Neoproterozoic reconstructions. In recent years, it has been proposed that the Borborema Province grew by accretion of distinct tectonic terranes. In order to test this hypothesis, we compare here the geochemistry of orthogneisses and metasedimentary rocks across a proposed terrane boundary in the Central Domain of the province. Orthogneiss samples show smooth trends in Harker diagrams and similar rare earth element (REE) patterns, characterized by sharp decreases from La to Sm (chondrite-normalized La/Sm = 3–6) and flat heavy REE profiles (chondrite-normalized Tb/Yb = 1.5–2.5), with small or no Eu anomalies. In primitive mantle-normalized multi-element diagrams, all samples show parallel patterns characterized by sharp negative anomalies of U, Ta, Nb, P and Ti. The metasedimentary samples show little scatter of the major elements in Harker diagrams, suggesting that their chemistry was little affected by post-depositional diagenesis and metamorphism. They have indistinguishable chondrite-normalized REE patterns, characterized by light REE enrichment, flat heavy REE (normalized Tb/Y = 1–2) and small or no negative Eu anomalies, and similar ratios of immobile trace elements (e.g., Th/Sc, Zr/Sc). The geochemistry of the metasedimentary samples is comparable in many ways to those of the orthogneisses, suggesting that these may have been an important source of the precursor sedimentary rocks. These data do not support the terrane accretion hypothesis, rather suggesting the existence of a continuous basement that became available for erosion during intraplate continental extension in the late Neoproterozoic. Comparisons of the studied sequences with those present in the Northern Domain suggest that most, if not all of the Neoproterozoic geodynamic evolution of Borborema Province, occurred in an intracontinental setting.     

Geochemical features of the Matomb alluvial rutile from the Neoproterozoic Pan-African belt,Southern Cameroon

The Matomb region constitutes an important deposit of detrital rutile. The rutile grains are essentially coarse (> 3 mm), tabular and elongated, due to the short sorting of highly weathered detritus. This study reports the major, trace, and rare-earth element distribution in the bulk and rutile concentrated fractions. The bulk sediments contain minor TiO₂ concentrations (1–2 wt%), high SiO₂ contents (∼77–95 wt%) and variable contents in Al₂O₃, Fe₂O₃, Zr, Y, Ba, Nb, Cr, V, and Zn. The total REE content is low to moderate (86–372 ppm) marked by high LREE-enrichment (LREE/HREE ∼5–25.72) and negative Eu anomalies (Eu/Eu^* ∼0.51–0.69). The chemical index of alteration (CIA) shows that the source rocks are highly weathered, characteristic of humid tropical zone with the development of ferrallitic soils. In the concentrated fractions, TiO₂ abundances exceed 94 wt%. Trace elements with high contents include V, Nb, Cr, Sn, and W. These data associated with several binary diagrams show that rutile is the main carrier of Ti, V, Nb, Cr, Sn, and W in the alluvia. The REE content is very low (1–9 ppm) in spite of the LREE-abundance (LREE/HREE ∼4–40). The rutile concentrated fractions exhibit anomalies in Ce (Ce/Ce^* ∼0.58 to 0.83; ∼1.41–2.50) and Eu (Eu/Eu^* ∼0.42; 1.20–1.64). The high (La/Sm)_N, (La/Yb)_N and (Gd/Yb)_N ratios indicate high REE fractionation.     

Deconvolving the pre-Himalayan Indian margin-Tales of crustal growth and destruction

The metamorphic core of the Himalaya is composed of Indian cratonic rocks with two distinct crustal affinities that are defined by radiogenic isotopic geochemistry and detrital zircon age spectra. One is derived predominantly from the Paleoproterozoic and Archean rocks of the Indian cratonic interior and is either represented as metamorphosed sedimentary rocks of the Lesser Himalayan Sequence(LHS) or as slices of the distal cratonic margin. The other is the Greater Himalayan Sequence(GHS) whose provenance is less clear and has an enigmatic affinity. Here we present new detrital zircon Hf analyses from LHS and GHS samples spanning over 1000 km along the orogen that respectively show a striking similarity in age spectra and Hf isotope ratios. Within the GHS, the zircon age populations at 2800-2500 Ma,1800 Ma, 1000 Ma and 500 Ma can be ascribed to various Gondwanan source regions; however, a pervasive and dominant Tonianage population(～860-800 Ma) with a variably enriched radiogenic Hf isotope signature(eHf = 10 to-20) has not been identified from Gondwana or peripheral accreted terranes. We suggest this detrital zircon age population was derived from a crustal province that was subsequently removed by tectonic erosion. Substantial geologic evidence exists from previous studies across the Himalaya supporting the Cambro-Ordovician Kurgiakh Orogeny. We propose the tectonic removal of Tonian lithosphere occurred prior to or during this Cambro-Ordovician episode of orogenesis in a similar scenario as is seen in the modern Andean and Indonesian orogenies, wherein tectonic processes have removed significant portions of the continental lithosphere in a relatively short amount of time. This model described herein of the pre-Himalayan northern margin of Greater India highlights the paucity of the geologic record associated with the growth of continental crust. Although the continental crust is the archive of Earth history, it is vital to recognize the ways in which preservation bias and destruction of continental crust informs geologic models.