首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
A technique for IR spectroscopic determination of the total nitrogen content N S in the form of A-and B 1-defects is suggested. It provides for the computer processing and decomposition of IR spectra into constituent bands, calculation of the total absorption band area S N and individual areas S A and S B1 and their normalization with respect to the total area of the diamond intrinsic absorption S 0, with the normalization coefficients K S , K A , and K B1 being calculated. Based on the analysis of the IR spectra of 60 octahedral diamond crystals from the Mir and Yubileinaya pipes (Sakha-Yakutiya), the empirical functions N S = 911.85 K S 0.9919 ppm (R 2 = 0.9859), N A = 1185.6 K A 1.1511 ppm (R 2 = 0.8703), and N B1 = 911.85 K S 0.9919 ? 1185.6 K A 1.1511 ppm have been defined.  相似文献   

2.
The stress regime in a Rotliegend reservoir of the Northeast German Basin   总被引:2,自引:0,他引:2  
In-situ stresses have significant impact, either positive or negative, on the short and long term behaviour of fractured reservoirs. The knowledge of the stress conditions are therefore important for planning and utilization of man-made geothermal reservoirs. The geothermal field Groß Schönebeck (40 km north of Berlin/Germany) belongs to the key sites in the northeastern German Basin. We present a stress state determination for this Lower Permian (Rotliegend) reservoir by an integrated approach of 3D structural modelling, 3D fault mapping, stress ratio definition based on frictional constraints, and slip-tendency analysis. The results indicate stress ratios of the minimum horizontal stress S hmin being equal or increasing 0.55 times the amount of the vertical stress S V (S hmin ≥ 0.55S V ) and of the maximum horizontal stress S Hmax ≤ 0.78–1.00S V in stress regimes from normal to strike slip faulting. Thus, acting stresses in the 4,100-m deep reservoir are S V  = 100 MPa, S hmin = 55 MPa and S Hmax = 78?100 MPa. Values from hydraulic fracturing support these results. Various fault sets of the reservoir are characterized in terms of their potential to conduct geothermal fluids based on their slip and dilatation tendency. This combined approach can be adopted to any other geothermal site investigation.  相似文献   

3.
In the present study, four different heuristic techniques viz. multi-layer perceptron (MLP), radial basis function (RBF), self-organizing maps (SOM), and co-active neuro-fuzzy inference system (CANFIS) with hyperbolic tangent and sigmoid transfer functions and two regression-based techniques, i.e., multiple linear regression (MLR) and sediment-rating curve (SRC), were used for suspended sediment modeling. Gamma test (GT), correlation function (CF), M test, and trail–error procedure were applied for estimation of appropriate input variables as well as training data length. The results of the GT and CF suggested the five input variables (Qt, Qt?1, Qt?2, St?1, and St?2, where Qt?1 and St?1 indicate the discharge and sediment values of one previous day) as the best combination. The optimal training data length (75% of total data) was estimated by M test and trail–error procedure for development of the applied models. The MLP with sigmoid transfer function (M-2) performed better than the all other models. The results of sensitivity analysis indicated that the present-day discharge (Qt), 1-day lag discharge (Qt?1) and 1-day lag suspended sediment (St?1) are the most influenced parameters in modeling current day suspended sediment (St).  相似文献   

4.
Rapid increases in the amounts of fullerene C60 nanoparticles (nC60) being produced and used will inevitably lead to increases in the amounts released into the aquatic environment. This will have implications for human and ecosystem health. Wastewater treatment plants are key barriers to nC60 being released into aquatic systems, but little information is available on how adsorption processes in wastewater treatment plants affect the fates of nC60. We investigated the effects of the surface properties of activated sludge on the adsorption of nC60 and related mechanisms by modeling the adsorption kinetics and equilibrium process and performing correlation analyses. The adsorption of nC60 closely followed the pseudo-second-order kinetic model (R > 0.983), the Freundlich isotherm model (R > 0.990), and the linear partitioning isotherm model (R > 0.966). Different adsorption coefficients, 1.070–4.623 for the Freundlich partitioning model and 1.788–6.148 for the linear partitioning model, were found for different types of activated sludge. The adsorption coefficients significantly positively correlated with the zeta (ζ) potential (R = 0.877) and hydrophobicity (R = 0.661) and negatively correlated with particle size (R = ?0.750). The results show that nC60 adsorption is strongly affected by the surface properties of activated sludge because changes in surface properties cause changes in the electrostatic and hydrophobic interactions that occur.  相似文献   

5.
SDO/HMI and SDO/AIA data for the 24th solar-activity cycle are analyzed using a quicker and more accurate method for resolving π ambiguities in the transverse component of the photospheric magnetic field, yielding new results and confirming some earlier results on the magnetic properties of leading and following magnetically connected spots and single spots. The minimum inclination of the field lines to the positive normal to the solar surface α min within umbrae is smaller in leading than in following spots in 78% of the spot pairs considered; the same trend is found for the mean angle 〈α〉 in 83% of the spot pairs. Positive correlations between the α min values and the 〈α〉 values in leading and following spots are also found. On average, in umbrae, the mean values of 〈B〉, the umbra area S, and the angles α min and 〈α〉 decrease with growth in the maximum magnetic field B max in both leading and following spots. The presence of a positive correlation between B max and S is confirmed, and a positive correlation between 〈B〉 and S in leading and following spots has been found. Themagnetic properties of the umbrae of magnetically connected pairs of spots are compared with the contrast of the He II 304 emission above the umbrae, C 304. Spots satisfying certain conditions display a positive correlation between C 304?L and 〈α L 〉 for the leading (L) spots, and between C 304?L /C 304?F and l L /l F , where l L (l F ) are the lengths of the field lines connecting leading (L) or following (F) spots from the corresponding spot umbrae to the apex of the field line.  相似文献   

6.
Studies of the extreme solar proton event of January 20, 2005 intensified the contest over of a long-standing problem: are solar cosmic rays arriving at the Earth accelerated by solar flares or by shocks preceding rapidly moving coronal mass ejections? Among the most important questions is the relationship between the energy spectra of the solar cosmic rays and the frequency spectra of flare microwave bursts. Some studies of previous solar-activity cycles have shown that such a relationship does exist, in particular, for protons with energies of tens of MeV. The present work analyzes this relation using data for 1987–2008. For flare events observed in the western half of the disk, there is a significant correlation between the index δ, which is equivalent to the power-law index of the integrated energy spectrum of 10–100 MeV protons detected near the Earth’s orbit, and radio burst parameters such as a ratio of peak fluxes S at two frequencies (for example, at 9 and 15 GHz) and a microwave peak frequency f m . Proton fluxes with hard (flat) energy spectra (δ ≤ 1.5) correspond to hard microwave frequency spectra (S 9/S 15 ≤ 1 and f m ≥ 15 GHz), while flares with soft radio spectra (S 9/S 15 ≥ 1.5 and f m ≤ 5 GHz) result in proton fluxes with soft (steep) energy spectra (δ ≥ 1.5–2). It is also shown that powerful high-frequency bursts with the hardest radio spectra (f m ≈ 30 GHz) can point at acceleration of significant proton fluxes in flares occurring in strong magnetic fields. These results argue that solar cosmic rays (or at least their initial impulses) are mainly accelerated in flares associated with impulsive and post-eruptive energy release, rather than in shocks driven by coronal mass ejections.  相似文献   

7.
This paper presents the first boundary equations describing the relationship between earthquake parameters (magnitude M S and macroseismic intensity I P at the observation point on the MSK-64 scale) and clastic dikes (having maximal thickness m cd , visible height h cd , and the index of manifestation intensity of dikes in the cross section I cd ). As was expected, the maximal size of dikes grows with an increase in the earthquake magnitude and macroseismic intensity. Analysis of the dependences showed that it is better to use all three parameters for estimation of the minimal threshold M S or I P from clastic dikes, and, in the absence of data on seismogenic rupture, the maximal calculated value should be used. Some limitations in application and the advantages of the equations obtained are discussed with respect to characterizing earthquakes of the pre-instrumental period.  相似文献   

8.
This study quantifies the influence of various intrinsic soil properties including particle roundness, R, sphericity, S, 50% size by weight, D 50, coefficient of uniformity, C u, and the state property of relative density, D r, on the compression and recompression indices, C c and C r, of sands of various geologic origins at pre-crushing stress levels. Twenty-four sands exhibiting a wide range of particle shapes, gradations, and geologic origins were collected for the study. The particle shapes were determined using a computational geometry algorithm which allows characterization of a statistically large number of particles in specimens. One dimensional oedometer tests were performed on the soils. The new data was augmented with many previously published results. Through statistical analyses, simple functional relationships are developed for C c and C r. In both cases, the models utilized only R and D r since other intrinsic properties proved to have lesser direct influence on the compression indices. However, previous studies showed that the contributions of S and C u are felt through their effects on index packing void ratios and thus on D r. The accuracy of the models was confirmed by comparison of predicted and observed C c and C r values.  相似文献   

9.
Spectroscopic and photometric data for the two rapidly rotating members of the α Persei cluster He 373 and AP 225 are analyzed. Improved estimates have been obtained for the projected equatorial rotation velocities: v sin i = 164 km/s for He 323 and v sin i = 129 km/s for AP 225. Multi-band photometric mapping is used to map the spot distributions on the surfaces of the two stars. The fractional spotted areas S and mean temperature difference ΔT between the unspotted photosphere and the spots are estimated (S = 7% and ΔT = 1000 K for He 373; S = 9% and ΔT = 800 K for AP 225). The H α line profiles of both stars have variable emission components whose widths are used to deduce the presence of extended regions of emission reaching the corotation radius.  相似文献   

10.
Before starting seismic cycle of Ahar–Varzaghan 2012 event, a partial gap in the form of a pre-seismic calm sequence (seismicity rate, r = 0.46 event/year, b = 1.4) with duration of 303 days spatially has dominated over the entire seismogenic area. From April 17, 2012, to May 31, 2012, r significantly increased to 2.16, indicating strong foreshock sequence, and b value changed to 1.9, remarkably. In the last two months before the mainshock, foreshocks have partially migrated toward the earthquake fault (with a decrease in size, b = 2.0). Significantly, high rate of seismicity and low V P /V S (1.64) in the foreshocks sequence and also very high seismicity rate (17.3) and high V P /V S (1.76) in the aftershocks sequence make substantial differences between the seismic cycle and the background seismicity. Moreover, a significant E–W migration of the microseismicity was confirmed in the study area.  相似文献   

11.
The main objective of this study was to investigate the efficiency of biological treatment of azo dye-containing wastewater with a sequencing batch reactor system, followed by ultrafiltration. The performance of the system was quantified by measuring the chemical oxygen demand and azo dye concentration. The biodegradation was carried out under combined alternating anaerobic and aerobic conditions with Nylosan Yellow E2RL SGR as a model azo dye contaminant. The bioprocess revealed a maximal reduction in chemical oxygen demand and dye removal efficiency of 91 and 85%, respectively. After ultrafiltration of effluent from the biological treatment, the efficiency increased to 94% for chemical oxygen demand and to 97% for the azo dye decolourisation. Samples of activated sludge from the bioprocess were collected for microbial characterisation. Bacteria and fungi were isolated and identified by 16S rRNA gene and ITS1-5.8S rDNA-ITS2 sequence analysis, respectively. Serratia marcescens and Klebsiella oxytoca were the most common bacteria with the highest number present during the aerobic and anaerobic phases of the bioprocess. In addition, a high number of Elizabethkingia miricola, Morganella morganii, Comamonas testosteroni, Trichosporon sp. and Galactomyces sp. were detected. Taken together, our results demonstrated that the sequencing batch reactor system combined with ultrafiltration is an efficient technique for treatment of wastewater containing azo dye. Moreover, the ultrafiltration effectively removes the microbiota from the final effluent resulting in stable product water.  相似文献   

12.
This paper presents the numerical simulation of pile installation and the subsequent increase in the pile capacity over time (or setup) after installation that was performed using the finite element software Abaqus. In the first part, pile installation and the following load tests were simulated numerically using the volumetric cavity expansion concept. The anisotropic modified Cam-Clay and Dracker–Prager models were adopted in the FE model to describe the behavior of the clayey and sandy soils, respectively. The proposed FE model proposed was successfully validated through simulating two full-scale instrumented driven pile case studies. In the second part, over 100 different actual properties of individual soil layers distracted from literature were used in the finite element analysis to conduct parametric study and to evaluate the effect of different soil properties on the pile setup behavior. The setup factor A was targeted here to describe the pile setup as a function of time after the end of driving. The selected soil properties in this study to evaluate the setup factor A include: soil plasticity index (PI), undrained shear strength (S u ), vertical coefficient of consolidation (C v ), sensitivity ratio (S r ), and over-consolidation ratio (OCR). The predicted setup factor showed direct proportion with the PI and S r and inverse relation with S u , C v and OCR. These soil properties were selected as independent variables, and nonlinear multivariable regression analysis was performed using Gauss–Newton algorithm to develop appropriate regression models for A. Best models were selected among all based on level of errors of prediction, which were validated with additional nineteen different site information available in the literature. The results indicated that the developed model is able to predict the setup behavior for individual cohesive soil layers, especially for values of setup factor greater than 0.10, which is the most expectable case in nature.  相似文献   

13.
The classical aquitard-drainage model COMPAC has been modified to simulate the compaction process of a heterogeneous aquitard consisting of multiple sub-units (Multi-COMPAC). By coupling Multi-COMPAC with the parameter estimation code PEST++, the vertical hydraulic conductivity (K v) and elastic (S ske) and inelastic (S skp) skeletal specific-storage values of each sub-unit can be estimated using observed long-term multi-extensometer and groundwater level data. The approach was first tested through a synthetic case with known parameters. Results of the synthetic case revealed that it was possible to accurately estimate the three parameters for each sub-unit. Next, the methodology was applied to a field site located in Changzhou city, China. Based on the detailed stratigraphic information and extensometer data, the aquitard of interest was subdivided into three sub-units. Parameters K v, S ske and S skp of each sub-unit were estimated simultaneously and then were compared with laboratory results and with bulk values and geologic data from previous studies, demonstrating the reliability of parameter estimates. Estimated S skp values ranged within the magnitude of 10?4 m?1, while K v ranged over 10?10–10?8 m/s, suggesting moderately high heterogeneity of the aquitard. However, the elastic deformation of the third sub-unit, consisting of soft plastic silty clay, is masked by delayed drainage, and the inverse procedure leads to large uncertainty in the S ske estimate for this sub-unit.  相似文献   

14.
To investigate inhomogeneous and porous structures in nature, the concept of fractal dimension was established. This paper briefly introduces the definition and measurement methods of fractal dimension. Three different methods including mercury injection capillary pressure (MICP), nuclear magnetic resonance (NMR), and nitrogen adsorption (BET) were applied to determine the fractal dimensions of the pore space of eight carbonate rock samples taken from West Tushka area, Egypt. In the case of fractal behavior, the capillary pressure P c and cumulative fraction V c resulting from MICP are linearly related with a slope of D-3 in a double logarithmic plot with D being the value of fractal dimension. For NMR, the cumulative intensity fraction V c and relaxation time T 2 show a linear relation with a slope of 3-D in a double logarithmic plot. Fractal dimension can also be determined by the specific surface area S por derived from nitrogen adsorption measurements and the effective hydraulic radius. The fractal dimension D shows a linear relation with the logarithm of S por . The fractal dimension is also used in models of permeability prediction. To consider a more comprehensive data set, another 34 carbonate samples taken from the same study area were integrated in the discussion on BET method and permeability prediction. Most of the 42 rock samples show a good agreement between measured permeability and predicted permeability if the mean surface fractal dimension for each facies is used.  相似文献   

15.
The sound velocity (V P) of liquid Fe–10 wt% Ni and Fe–10 wt% Ni–4 wt% C up to 6.6 GPa was studied using the ultrasonic pulse-echo method combined with synchrotron X-ray techniques. The obtained V P of liquid Fe–Ni is insensitive to temperature, whereas that of liquid Fe–Ni–C tends to decrease with increasing temperature. The V P values of both liquid Fe–Ni and Fe–Ni–C increase with pressure. Alloying with 10 wt% of Ni slightly reduces the V P of liquid Fe, whereas alloying with C is likely to increase the V P. However, a difference in V P between liquid Fe–Ni and Fe–Ni–C becomes to be smaller at higher temperature. By fitting the measured V P data with the Murnaghan equation of state, the adiabatic bulk modulus (K S0) and its pressure derivative (K S ) were obtained to be K S0 = 103 GPa and K S  = 5.7 for liquid Fe–Ni and K S0 = 110 GPa and K S  = 7.6 for liquid Fe–Ni–C. The calculated density of liquid Fe–Ni–C using the obtained elastic parameters was consistent with the density values measured directly using the X-ray computed tomography technique. In the relation between the density (ρ) and sound velocity (V P) at 5 GPa (the lunar core condition), it was found that the effect of alloying Fe with Ni was that ρ increased mildly and V P decreased, whereas the effect of C dissolution was to decrease ρ but increase V P. In contrast, alloying with S significantly reduces both ρ and V P. Therefore, the effects of light elements (C and S) and Ni on the ρ and V P of liquid Fe are quite different under the lunar core conditions, providing a clue to constrain the light element in the lunar core by comparing with lunar seismic data.  相似文献   

16.
The rock mass failure process can be divided into several distinct deformation stages: the compaction stage, elastic stage, stable failure stage, accelerated failure stage, and post-peak stage. Although each stage has been well studied, the relationship among the stages has not been established. Here, we establish two models which are the Strain model Q and Energy density model S by using the renormalization group theory and investigate the mechanical relationship between the volume dilatant point and peak stress point on the rock stress-strain curve. Our models show that the strain ratio (ε f /ε c ) and energy ratio (E f /E c ) at the volume dilatant point and peak stress point are solely functions of the shape parameter m. To verify our models, we further studied the failure process of rock specimens through several uniaxial compression experiments and found that the relationship between ε f /ε c or E f /E c and m shares a notably similar pattern to that from our theoretical model. However, the ε f /ε c and E f /E c values in our experiments are slightly smaller than those predicted by the models. In brief, we demonstrate that our models can be used to predict the failure process of the laboratory-scale hard brittle rock samples.  相似文献   

17.
In this study, Illumina sequencing was used for the identification of bulking and foaming bacteria in industrial wastewater treatment plants. The reliable identification of bulking and foaming bacteria represents the first step in developing effective and specific control strategies to avoid disturbances in activated sludge systems. Illumina sequencing revealed 432 16S rRNA operational taxonomic units, representing phylotypes and including 21 bulking and foaming bacteria in the two investigated industrial wastewater treatment plants. Foaming represents the most severe problem in the cascade biology system. Up to 22.5% of all sequencing reads are bulking and foaming bacteria, including Chryseobacterium, Candidatus Microthrix parvicella and Gordonia sp. as the dominant bulking and foaming bacteria which are known for foam formation. Moreover, Illumina sequencing revealed an increase in Candidatus Microthrix parvicella and Gordonia sp. reads from activated sludge to foam and scum samples, indicating a preferred flotation and/or growth advantages in the foam and scum layers. Analyses of the taxonomic assignment and distribution showed that the phylum Actinobacteria is the most dominant phylum, underlining the key role of Actinobacteria in bulking and foaming. Multivariate data analysis was applied, revealing that the dominant bulking and foaming bacteria are positively correlated with the sludge age and influent flow and negatively correlated with the dissolved oxygen level and the temperature. In terms of developing a specific control strategy, the positive linear relationships to the fatty acid and surfactant sludge loadings are highlighted and the removal of lipid compounds from the wastewater influent could avoid an overgrowth of bulking and foaming bacteria.  相似文献   

18.
Sludge samples taken from different sources and times may have different characteristics that could affect dewatering performance. In this study, 20 sludge samples from five wastewater treatment plants and different seasons in 1 year were characterized. Pearson correlation analysis indicated that solid content (SC), total suspended solid (TSS), polysaccharides and proteins contents had positive correlations with the capillary suction time (CST), whereas volatile suspended–solid/total suspended solid (VSS/TSS) exhibited negative correlations with CST. Moreover, no correlations between CST and specific resistance to filtration were found among these different sludge samples. The principal component analysis confirmed that only two group variables could represent most of the sludge characteristic parameters. The first set of variables represents the particulate nature of the biotic factors (SC, VSS/TSS, SCOD, TSS, polysaccharides and proteins), and the second set is the pH. CST could not be a reasonable indicator of dewaterability in sludge deep dewatering by Fe2+/S2O8 2?-phosphogypsum composite conditioning. Furthermore, the results of diaphragm filter press dewatering showed that initial SC and VSS/TSS were the most dominant sludge characteristics affecting the solid content of dewatered cake (R p = 0.610, p = 0.016; R p = ?0.838, p = 0.000, respectively) with Fe2+/S2O8 2?-phosphogypsum composite conditioning. Results from this study suggest that dewatering performance is predictable by sludge characteristics parameters for Fe2+/S2O8 2?-phosphogypsum conditioning.  相似文献   

19.
Theoretical analysis, calculations, and comparison with the results of observations in Lake Baikal, Lake Tanganyika, and the World Ocean are performed for the vertical stability E and the Brunt-Väisäla frequency N in the form of N 2 with regard to all components (at the constant temperature T and the salinity S, the common adiabatic form at T, S Const). The adiabatic stability E ad and the Väisäla frequency N in the form of N ad 2 are always positive; at a change from the inverse to the direct temperature stratification, they have deep minimums reaching 10?16 m?1 and 10?15 s?2 and less; the minimums have the form of a special point, a reversal point of the first kind called a “cusp.” The reality of these reversal points is confirmed by the analysis of the investigation procedure, comparison with the results of previous theoretical (Sherstyankin, et al., 2007), and experimental (observations in Baikal, Shimaraev et al., 1994) works. The features of vertical profiles of E ad , E andN ad 2 , N 2, as well as the layers where the Brunt-Väisäla frequency is less than the inertial frequency, are studied. The analysis with regard to all components of the stability E ad and the Brunt-Väisäla frequency N makes a great contribution to understanding of mixing processes in theoretical and experimental investigations; it is valid in all reservoirs of the Earth with inverse and direct temperature stratification, including Lake Baikal, Lake Tanganyika, and the World Ocean.  相似文献   

20.
New bio-adsorbent carbon materials were synthesized from the leaves and veins of Mucuna pruriens and Manihot esculenta plants, which are locally available in abundance. The synthesized carbons were activated using 0.01N HNO3. Surface area of the activated carbons from M. pruriens and M. esculenta plants was found to be quite high, i.e., 918 and 865 m2/g, respectively. Scanning electron microscopy analysis of the carbons reflects complex disorganized surface structures of different open pore sizes, shapes and dimensions. These properties of the newly synthesized activated carbons led to the development of a sand-supported carbon column, for its possible use in the removal of coliform bacteria and Escherichia coli (E. Coli) from raw water samples. The removal percentage of E. coli was found to be 100% with both the types of carbon adsorbents, as confirmed from the McCardy most probable number table. Similarly, the removal percentage of coliform bacteria was found to be 99 and 98.7% by M. pruriens and M. esculenta carbon columns, respectively. These activated carbons synthesized from locally available plants possess the characteristics of good low-cost adsorbents which can be easily used for the removal of bacteria from water by adsorption method.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号