Low-temperature thermochronology of the flanks of the southern Upper Rhine Graben

The Upper Rhine Graben (URG) is the most perceptible part of the European Cenozoic Rift System. Uplifted Variscan basement of the Black Forest and the Vosges forms the flanks of the southern part of the graben. Apatite and zircon fission-track (FT) analyses indicate a complex low-temperature thermal history of the basement that was deciphered by inverse modelling of FT parameters. The models were tested against the observed data and independent geological constraints. The zircon FT ages of 28 outcrop samples taken along an E–W trending transect across the Black Forest and the Vosges range from 136 to 312 Ma, the apatite FT ages from 20 to 83 Ma. The frequency distributions of confined track lengths are broad and often bimodal in shape indicating a complex thermal history. Cooling below 120°C in the Early Cretaceous to Palaeogene was followed by a discrete heating episode during the late Eocene and subsequent cooling to surface temperature. The modelled time–temperature (t–T) paths point to a total denudation of the flanks of URG in the range of 1.0–1.7 km for a paleogeothermal gradient of 60°C/km, and 1.3–2.2 km for a paleogeothermal gradient of 45°C/km since the late Eocene.     

Neotectonics and intraplate continental topography of the northern Alpine Foreland

Research on neotectonics and related seismicity has hitherto been mostly focused on active plate boundaries that are characterized by generally high levels of earthquake activity. Current seismic hazard estimates for intraplate domains are mainly based on probabilistic analyses of historical and instrumental earthquake catalogues. The accuracy of such hazard estimates is limited by the fact that available catalogues are restricted to a few hundred years, which, on geological time scales, is insignificant and not suitable for the assessment of tectonic processes controlling the observed earthquake activity. More reliable hazard prediction requires access to high quality data sets covering a geologically significant time span in order to obtain a better understanding of processes controlling on-going intraplate deformation.The Alpine Orogen and the intraplate sedimentary basins and rifts in its northern foreland are associated with a much higher level of neotectonic activity than hitherto assumed. Seismicity and stress indicator data, combined with geodetic and geomorphologic observations, demonstrate that deformation of the Northern Alpine foreland is still on-going and will continue in the future. This has major implications for the assessment of natural hazards and the environmental degradation potential of this densely populated area. We examine relationships between deeper lithospheric processes, neotectonics and surface processes in the northern Alpine Foreland, and their implications for tectonically induced topography.For the Environmental Tectonics Project (ENTEC), the Upper and Lower Rhine Graben (URG and LRG) and the Vienna Basin (VB) were selected as natural laboratories. The Vienna Basin developed during the middle Miocene as a sinistral pull-apart structure on top of the East Alpine nappe stack, whereas the Upper and Lower Rhine grabens are typical intracontinental rifts. The Upper Rhine Graben opened during its Late Eocene and Oligocene initial rifting phase by nearly orthogonal crustal extension, whereas its Neogene evolution was controlled by oblique extension. Seismic tomography suggests that during extension the mantle-lithosphere was partially decoupled from the upper crust at the level of the lower crust. However, whole lithospheric folding controlled the mid-Miocene to Pliocene uplift of the Vosges–Black Forest Arch, whereas thermal thinning of the mantle–lithosphere above a mantle plume contributed substantially to the past and present uplift of the Rhenish Massif. By contrast, oblique crustal extension, controlling the late Oligocene initial subsidence stage of the Lower Rhine Graben, gave way to orthogonal extension at the transition to the Neogene.The ENTEC Project integrated geological, geophysical, geomorphologic, geodetic and seismological data and developed dynamic models to quantify the societal impact of neotectonics in areas hosting major urban and industrial activity concentrations. The response of Europe's intraplate lithosphere to Late Neogene compressional stresses depends largely on its thermo-mechanical structure, which, in turn, controls vertical motions, topography evolution and related surface processes.     

Superposition of burial and hydrothermal events: post‐Variscan thermal evolution of the Erzgebirge,Germany

The post‐Variscan thermal history of the Erzgebirge (Germany) is the result of periods of sedimentary burial, exhumation and superimposed hydrothermal activity. The timing and degree of thermal overprint have been analysed by zircon and apatite (U–Th)/He and apatite fission track thermochronology. The present‐day surface of the Erzgebirge was exhumed to a near‐surface position after the Variscan orogeny. Thermal modelling reveals Permo‐Mesozoic burial to temperatures of up to 80–100 °C, although the sedimentary cover thins out towards the north resulting in maximum burial temperatures of less than 40 °C. This thermal pattern was locally modified by Cretaceous hydrothermal activity that reset the zircon (U–Th)/He thermochronometer along ore veins. The thermal models show no significant regional exhumation during Cenozoic times, indicating that the peneplain‐like morphology of the basement is a Late Cretaceous feature.     

Structural control of geothermal reservoirs in extensional tectonic settings: An example from the Upper Rhine Graben

In extensional tectonic settings major structural elements such as graben boundary faults are typically oriented subparallel to the maximum horizontal stress component S_Hmax. They are often structurally accompanied by transfer zones that trend subparallel to the extension direction. In the Upper Rhine Graben, such transfer faults are typically characterized by strike-slip or oblique-slip kinematics. A major re-orientation of the regional stress field by up to 90° of the Upper Rhine Graben in the Early Miocene led to the present-day normal and strike-slip faulting regimes in the North and South of the Upper Rhine Graben, respectively, and a transition zone in-between. Consequently, conditions for fault frictional failure changed significantly. Moreover, it has been observed during tracer and stimulation experiments that such transfer faults may be of major importance for the hydraulic field of geothermal reservoirs under the present stress condition, especially, when located between production and injection well.In this context we have investigated slip and dilation tendencies (T_S and T_D) of major structural elements at reservoir scale for two representative geothermal sites, Bruchsal (Germany) and Riehen (Switzerland), located close to the Eastern Main Boundary Fault of the Upper Rhine Graben. We have evaluated the quality and uncertainty range of both tendencies with respect to potential variation in S_Hmax orientation. Despite significant differences in orientation of the structures and the stress regimes, the resulting variation of T_S and T_D reveal major similarities concerning the reactivation potential of both, the graben-parallel structures and the transfer faults. The conditions of criticality for tensile failure and non-criticality for shear failure suggest that transfer faults are most likely naturally permeable structures with low stimulation potential. This is in agreement with the absence of both immediate tracer recovery and seismicity in the studied geothermal sites.     

Chemical evolution of thermal waters from limestone aquifers of the Southern Upper Rhine Valley

Thermal spas in the Upper Rhine Graben recover their waters mainly from two different limestone aquifers, Hauptrogenstein (Middle Jurassic) and Muschelkalk (Middle Triassic). The thermal waters are heated along anomalous high thermal gradients in the Tertiary rift valley. The highest well head temperature is about 40°C in Hauptrogenstein wells and 60°C in Muschelkalk wells. Mineralization (TDS) is up to 5 g/kg in Hauptrogenstein and as high as 17 g/kg in the Muschelkalk aquifer. About 300 chemical analyses from 13 wells were used in this study.Compositional relationships between major chemical components (Na/Cl, K/Cl, Mg/Cl, SO₄/Cl, Cl/Br and Na/Br) suggest that thermal water from the Hauptrogenstein originates from mixing of 3 components: (a) meteoric water, (b) fossil seawater (residual formation water) and (c) a third component that resulted from water–rock reaction.The total amount of dissolved solids and the water type from the deeper Muschelkalk aquifer depends on the depth of the aquifer at the well location. The chemical characteristics of the thermal water indicate that water composition is derived mainly from water–rock interaction.     

A multi-scale approach to study the lithospheric structure of the southern Upper Rhine Graben: from seismic tomography through reflection seismics to surface geology

This paper integrates the results of different techniques—local and regional travel time tomography, reflection seismics, and surface geology. With this integration of different techniques, working on different scales, it is possible to derive a comprehensive picture of the present-day structures in the lithosphere of the Upper Rhine Graben. It is shown that the stucture of the lithosphere is dominated by structures related to the Variscan orogeny. Late stage strike-slip reactivation of the internal faults of the Rhine Graben is observed in the field. This reactivation is of dominant influence on the geomorphology in the southern end of the Upper Rhine Graben.     

Geochemical modelling of fluid–rock interactions in the context of the Soultz-sous-Forêts geothermal system

The development of the Enhanced Geothermal System (EGS) at Soultz-sous-Forêts (France) has given to scientists an interesting opportunity for the application of geochemical modelling of water–rock interactions, combining theoretical studies with field and experimental data. The main results of four successive and complementary studies are summarized: geochemical modelling of fluid–rock interactions with prediction of dissolution/precipitation of minerals, feed-back effects on the mineralogy and petrography of the rock (major role of silicates in the geological past and of carbonates in the near future of the exploitation), experimental control of the dynamics of silicates under thermal gradient and relation between the evolution of the petrophysics of the rocks and the heat and mass transfers. The thermal cycle of the fluid, between 200 °C and 65 °C in the geothermal loop, may be responsible for dissolution/precipitation of minerals which modify the porosity and permeability of the granite, as it happened in the geological past, in relation with hydrothermal circulations in the Rhine Graben.     

A 40Ar/39Ar laser probe study of micas from the Sesia Zone, Italian Alps: implications for metamorphic and deformation histories

Two samples from the Eclogite Micaschist Complex (EMC) and the Seconda Zona Diorito–Kinzigitica (IIDK) of the Sesia Zone have been studied using a high-spatial resolution laser probe ⁴⁰Ar/³⁹Ar technique with the aim of investigating the complexities of argon behaviour in metamorphic rocks and comparing their thermal histories. Data from a single large phengite grain from the EMC show a range of ages from mid-Jurassic to Upper Cretaceous. These ‘apparent age’ variations are spatially related to both location within the grain and to intragrain microstructure. Modelling of the data shows that the profile formed by the diffusion of an excess argon component into the grain, parallel to the mica cleavage. Profile asymmetry is explained by temporal variations in microstructural development enabling excess argon to enter the grain at different times in different places. The temperatures of the initiation of deformation and the possible time-scales for the deformation can be calculated as a function of cooling rate. All estimates suggest deformation at greenschist facies, in accord with the observed retrograde mineral assemblage. Absolute temperature estimates for deformation vary by less than 22 °C for different cooling rates of 10 and 30 °C Ma^?1 but vary by 80 °C with different estimates of diffusion parameters. The duration of deformation was for at least 2 Ma at 10 °C Ma^?1 or 0.7 Ma at 30 °C Ma^?1. Biotites from the IIDK sample record a Permian to Upper Cretaceous age range that correlates with grain size, the smallest grain sizes yielding the youngest ages. This relationship is best explained by a partial resetting of biotites during an Alpine thermal event initiated not more than 70 Ma ago. Modelling of these data suggest that the sample never exceeded 300 °C during the Alpine. The profoundly different thermal histories of the two units—the EMC recrystallized at 550 °C whilst the IIDK remained below 300 °C—suggests that they may not have been juxtaposed until much later than the eclogite facies metamorphism.     

The Variscan tectonic inheritance of the Upper Rhine Graben: evidence of reactivations in the Lias,Late Eocene–Oligocene up to the recent

Processing of gravity and magnetic maps shows that the basement of the Upper Rhine Graben area is characterized by a series of NE–SW trending discontinuities and elongated structures, identified in outcrops in the Vosges, Black Forest, and the Odenwald Mountains. They form a 40 km wide, N30–40° striking, sinistral wrench-zone that, in the Visean, shifted the Variscan and pre-Variscan structures by at least 43 km to the NE. Wrenching was associated with emplacement of several generations of plutonic bodies emplaced in the time range 340–325 Ma. The sub-vertical, NE–SW trending discontinuities in the basement acted as zones of weakness, susceptible to reactivation by subsequent tectonism. The first reactivation, marked by mineralizations and palaeomagnetic overprinting along NE–SW faults of the Vosges Mountains, results from the Liassic NW–SE extension contemporaneous with the break-up of Pangea. The major reactivation occurred during the Late Eocene N–S compression and the Early-Middle Oligocene E–W extension. The NE–SW striking basement discontinuities were successively reactivated as sinistral strike-slip faults, and as oblique normal faults. Elongated depocenters appear to form in association with reactivated Variscan wrench faults. Some of the recent earthquakes are located on NE–SW striking Variscan fault zones, and show sinistral strike-slip focal mechanisms with the same direction, suggesting also present reactivation.     

The northern Upper Rhine Graben: basin geometry and early syn-rift tectono-sedimentary evolution

A large-scale transfer zone subdivides the northern parts of the Upper Rhine Graben into a northern and a southern sub-basin. These sub-basins display the geometry of asymmetric half-grabens with opposing tilt directions. The transfer zone connects the western master fault of the northern half-graben with the eastern master fault of the southern half-graben. In the northern Upper Rhine Graben early syn-rift sedimentation (Late Priabonian to Late Rupelian) was controlled by the tectonically induced subsidence of these half-grabens (autogenetic), as well as by regional third-order sea level variations (allogenetic). Within the graben, lateral changes in subsidence rates (in dip and strike direction of fault blocks) controlled the development of accommodation space and thus, sediment thickness and facies. Furthermore, a low-displacement segment along the western border fault acted as a sediment entry point. Tectonics controlled the distribution of early syn-rift deposits and the palaeogeography of the northern Upper Rhine Graben.     

Main characteristics of the deep geothermal brine (5 km) at Soultz-sous-Forêts (France) determined using geochemical and tracer test data

Three deep wells (5000 m) have been drilled into a fractured granite basement at Soultz-sous-Forêts, within the Tertiary Rhine Graben, in order to develop a heat exchanger and produce electricity after the creation of an EGS reservoir. Very few analyses representative of the deep geothermal fluids are available because of frequent contamination by drilling fluids or injected waters. These indicate similar chemical and isotopic compositions (NaCl fluids) and high salinities (about 100 g/l) suggesting a common sedimentary origin and identical water–rock interaction processes at equilibrium temperatures close to 230 °C in a sedimentary rather than a granite reservoir. The latter would be situated closer to the Graben centre where the Triassic Buntsandstein formation is deepest and hottest. Tracer tests conducted after 2000 show that the deep native geothermal brine is omnipresent in the fluids discharged during the production and circulation tests. Its natural convective flux was estimated at 1–1.2 m³/h.     

Hydrogeology and geochemistry in the Curuksu (Denizli) hydrothermal field, western Turkey

 Curuksu is a low temperature hydrothermal system located within the upper sector of the B. Menderes Graben. The hydrologic structure of the Curuksu hydrothermal system is largely controlled by major graben faults where it is characterized by the presence of two thermal reservoirs. One is formed by Paleozoic quartzite, schist and marble units, and the second consists of Pliocene limestone-travertine units. The thermal conditions in the Curuksu region indicate that the regional tectonics and resulting local stress field control low temperatures activity. Temperatures of 30 springs emerging in the study area range between 15 and 55  °C. These springs are classified as cold fresh, warm mineral and thermal waters. Pamukkale, Karahayıt and Honaz springs are steam condensate waters, whereas Curuksu springs are commonly steam-heated waters with respect to the major anion concentrations. The reservoir temperatures have been estimated from chemical compositions by utilizing simultaneously, geothermometers and mixing models. According to these thermometric methods, the most probable subsurface temperature is in the range of 62–90  °C. However, the mixing models suggest a temperature level of 80  °C for the parent water. The system has low total dissolved solid (TDS) of ∼1000–1500 mg/l, which indicate that these waters undergo conductive cooling within the reservoir. Received: 9 September 1999 · Accepted: 14 February 2000     

Localization of temperature anomalies in the Upper Rhine Graben: insights from geophysics and neotectonic activity

The European Cenozoic Rift System hosts major temperature anomalies in Central Europe. In its central segment, the Upper Rhine Graben (URG), temperatures range from 75°C to nearly 150°C at a depth of 2000 m. Different hypotheses have been suggested to explain the localization of these anomalies. Our review and comprehensive interpretation of gravimetric and magnetic data, as well as neotectonic activity patterns, suggests that low-density, mostly magnetic and fractured granitic basement is systematically associated with major temperature anomalies. Further analyses provide insight into different heat transport processes contributing to the localization of these anomalies. Magnetic and gravity anomalies are known to represent lithological variations associated with the pre-Permian. We show their spatial relationship with positive temperature anomalies in the URG. Correlation between magnetics and temperature reveal a mean contribution of heat production to the temperature anomaly of about 10–15°C. A slightly higher mean value is obtained from correlation between gravity and temperature, which may be attributed to effects resulting from fracture porosity. The spatial relationship between temperature anomalies and neotectonic patterns indicates compressional shear and uplift regime for the major anomalies of the central segment of the URG. This is in agreement with different numerical models indicating free convection on fracture zones linked to faults. Our findings show that about 15–25% of the temperature anomaly can be attributed to variation in heat production. Hydrothermal circulation convection along faults, activated by the tectonic context, may explain the remaining 75–85% of the temperature anomalies.     

Palaeotemperatures and Diagenetic Phases of the Upper Triassic Oil-bearing Sandstones in the Eastern Part of the Ordos Basin

The maximum palaeotemperature of oil-bearing sandstones in the UpperTriassic in the eastern Ordos basin has been determined by using many methods including thevitrinite reflectance, fluid inclusion, apatite fission track, illite crystallinity, chlorite polytypeand diagenetic change of authigenic minerals. The thermal gradient in the Late Mesozoic wasabout 2.9-3.0℃/100m. The Upper Triassic was in a mature stage of organic matter andhydrocarbon began to be generated and migrated during this period. The palaeotemperatures ofoil-bearing sandstones were in the range of 88-110℃; those for the generation and migrationof oil ranged from 112 to 122℃. The thickness of the denuded strata overlying the UpperTriassic was 2465-2750m. The present burial depth of oil-bearing sandstones is generally from400 to 1200m. At a depth of ca. 1900m, the temperature may reach 140℃. Below this depth,organic matter was supermature and mainly generated gas.     

Major palaeohydrographic changes in Alpine foreland during the Pliocene - Pleistocene

The changing palaeogeographical pattern of Alpine deposits across the European forelands can be traced by identifying mineral assemblages and establishing the chronology of Pliocene-Pleistocene deposits in Alpine foreland. In the late Miocene, the upper courses of the Rhine and the Aar flowed east from the Swiss molasse plain towards the Danube. In the early Pliocene (Brunssumian, 5-3.2 Ma), these same rivers headed north wards towards the Rhine Graben of Alsace. In the early Reuverian, these streams were captured south of the Rhine Graben by the Doubs. They ceased their northward flow and headed west to feed the Bresse Graben. This phase is dated to the Lower and Middle Reuverian (3.2-2.6 Ma). From the Upper Reuverian (2.6 Ma) to the present day, the Rhine has adapted approximately its present course towards the North Sea, south to north along the Rhine Graben and across the Rhine Schist Massif to feed the Dutch Grabens. This changing pattern of capture and alteration of the hydrographic system of the upper reaches of the Rhine and the Aar can be explained by local tectonic movements.     

Tertiary tectonics of the Dannemarie Basin, upper Rhine graben, and regional implications

Recently released seismic reflection data, together with previous seismic and well data, are used to describe the development of the Dannemarie basin, in the SW end of the Upper Rhine Graben. The Dannemarie Basin was formed during the main rifting phase of the Upper Rhine Graben as an asymmetrical graben trending NE–SW. Post-rift tectonism shifted the depocenter southward and changed the overall shape of the basin. Miocene Jura compression did not result in the formation of folds, as in the adjacent Mulhouse Horst. Strike slip faulting was dominant in the post-rift period and new faults were created, most notably the north trending and transpressional Belfort Fault. The boundary of the Dannemarie Basin with the Vosges Mountains is part of a restraining bend, which may account for the uplift of the southernmost part of the Vosges Mountains.     

Chemical and isotopic investigations into the origin of clay minerals from the Galapagos hydrothermal mounds field

A dark green authigenic nontronite is the major component of the Galapagos hydrothermal mounds field sediments. Oxygen isotopic compositions of the chemically purified, <0.2-μm fraction of the nontronitic clays indicate formation temperatures of 25° to 47°C, in contrast with measured in situ mounds temperatures of up to 15°C. Assuming an authigenic origin, the Fe-rich montmorillonite that dominates in the noncarbonate clay fraction of the surrounding pelagic ooze has isotopic formation temperatures of 27° to 39°C, compared with measured in situ temperatures of ca. 3.5° to 6.5°C. The higher isotopic formation temperatures calculated for the hydrothermal nontronite suggest either complex patterns of fluid circulation and nontronite precipitation presently within the mounds or a higher thermal history associated with rapid and episodic periods of deposition during the Holocene-Pleistocene. The apparent high isotopic temperature of the Fe-rich montmorillonite may reflect: (1) formation under hydrothermal conditions at spreading centers with subsequent dispersal by bottom currents, (2) a detrital origin of the mineral, or (3) a mixture of authigenic Fe-montmorillonite and detrital Al-montmorillonite in this region.     

Further evidence for a Jurassic mineralizing event in central Europe: K–Ar dating of hydrothermal alteration and fluid inclusion systematics in wall rocks of the Käfersteige fluorite vein deposit in the northern Black Forest, Germany

The hydrothermal fluorite vein deposit of `Käfersteige' ranks among the biggest in central Europe. It is located along the suture zone that separates the Moldanubian and Saxothuringian units in the northern Black Forest, and is hosted in Bunter sandstone and underlying granitic basement. K–Ar ages of authigenic illite from the wall rocks give a Jurassic formation age of around 145?Ma for the deposit. Age data scatter down to 80?Ma in illite from the clay gouge and indicate a younger Cretaceous-Tertiary hydrothermal overprint. The pyrophyllite component in authigenic illite from wall rocks and the re-equilibration of illite suggest a formation temperature around 200?°C. Secondary fluid inclusions in quartz from the wall rocks define a syn-mineralization fluid episode involving Ca–Mg–K–Na–Cl-rich brines (about 27 wt% NaCl_eq) with a T _h of about 125?°C, and a post-mineralization Na–Cl-rich fluid overprint with a T _h of about 100?°C. Both generations of fluid inclusions relate to the final event of each cycle, while authigenic illite composition and re-equilibration of illite in the clay gouge may document initial temperatures of formation. The Upper Jurassic fluid system can be traced all over western Europe. It is probably an expression of continent-wide rifting and concomitant regional fluid circulation in connection with major tectonic disturbances, magmatism and abnormal heat flow during the opening of the North Atlantic ocean. The younger barren fluid overprint could be related to the onset of the Alpine orogeny.