The dual-beam mini-DOAS technique—measurements of volcanic gas emission,plume height and plume speed with a single instrument

The largest error in determining volcanic gas fluxes using ground based optical remote sensing instruments is typically the determination of the plume speed, and in the case of fixed scanning instruments also the plume height. We here present a newly developed technique capable of measuring plume height, plume speed and gas flux using one single instrument by simultaneously collecting scattered sunlight in two directions. The angle between the two measurement directions is fixed, removing the need for time consuming in-field calibrations. The plume height and gas flux is measured by traversing the plume and the plume speed is measured by performing a stationary measurement underneath the plume. The instrument was tested in a field campaign in May 2005 at Mt. Etna, Italy, where the measured results are compared to wind fields derived from a meso-scale meteorological model (MM5). The test and comparison show that the instrument is functioning and capable of estimating wind speed at the plume height.     

Mantle plume,large igneous province and continental breakup——Additionally discussing the Cenozoic and Mesozoic mantle plume problems in East China

Based on the former workers study results such as numerical simulation of fluid mechanics,seismic tomography of the whole earth and igneous rocks,the basic characteristics of mantle plumes are summarized in detail,namely the mantle plume,from the D″layer near the core-mantle bouundary(CMB)of 2900 km deep,is characterized by the spape of large head and thin narrow conduit,by the physical property of high temperature and low viscosity.The LIP(large igneous province)is the best exhibition when the mantle plume ascends to the surface.According to the basic characteristics of the mantle plumes and the LIP,as well as the temporal-spatial relationships between the mantle plume and continental breakup,the detailed research on petrology,geochemistry,temporal-spatial distribution,tectonic background of the Cenozoic-Mesozoic igneous rocks and gravity anomaly distribution in East China has been done.As a result,the Mesozoic igneous rocks in Southeast China should not be regarded as an example of typical LIP related to mantle plumes.for their related characteristics are not consitent with those of the typical LIPs related to mantle plumes.The Cenozoic igneous rocks in Northeast China have no the typical characteristics of mantle plumes and hotspots,so the Cenozoic volcanism in Northeast China might have no the direct relationships with the activity of mantle plumes.     

Implementation of a wetting-and-drying model in simulating the Kennebec–Androscoggin plume and the circulation in Casco Bay

A high-resolution coastal ocean model was developed to simulate the temporal/spatial variability of the Kennebec–Androscoggin (K–A) river plume and the circulation in Casco Bay. The model results agree favorably with the moored and shipboard observations of velocity, temperature, and salinity. The surface salinity gradient was used to distinguish the plume from the ambient coastal water. The calculated plume thickness suggests that the K–A plume is surface trapped. Its horizontal scales correlate well with Q ^0.25, where Q is the volume discharge of the rivers. Directional spreading is affected by the wind with the upwelling favorable wind transporting the plume water offshore. Both the wind and the tide also enhance mixing in the plume. The inclusion of a wetting-and-drying (WAD) scheme appears to enhance the mixing and entrainment processes near the estuary. The plume becomes thicker near the mouth of the estuary, the outflow velocity of the plume is weaker, and the radius of the river plume shrinks. The flow field in the model run with the WAD is noisier, not only in shallow areas of Casco Bay but also in the plume and even on the shelf. We speculate that the WAD processes can affect much larger areas than the intertidal zones, especially via a river plume that feeds into a coastal current.     

Monitoring of the plume from the basaltic phreatomagmatic 2004 Grímsv?tn eruption—application of weather radar and comparison with plume models

The Grímsv?tn eruption in November 2004 belongs to a class of small- to medium-sized phreatomagmatic eruptions which are common in Iceland. The eruption lasted 6?days, but the main phase, producing most of the 0.02?km³ of magma erupted, was visible for 33?h on the C-band weather radar of the Icelandic Meteorological Office located in Keflavík, 260?km to the west of the volcano. The plume rose to 8–12?km high over sea level during 33?h. The long distance between radar and source severely reduces the accuracy of the plume height determinations, causing 3.5-km steps in recorded heights. Moreover, an apparent height overestimate of ~1.5?km in the uncorrected radar records occurs, possibly caused by wave ducting or super-refraction in the atmosphere. The stepping and the height overestimate can be partly overcome by averaging the plume heights and by applying a height adjustment based on direct aircraft measurements. Adjusted weather radar data on plume height are used to estimate the total mass erupted using empirical plume models mostly based on magmatic eruptions and to compare it with detailed in situ measurements of the mass of erupted tephra. The errors arising because of the large radar plume distance limit the applicability of the data for detailed comparisons. However, the results indicate that the models overestimate the mass erupted by a factor of three to four. This supports theoretical models indicating that high steam content of phreatomagmatic (wet) plumes enhances their height compared to dry plumes.     

Edge‐, bottom‐, and Rossby waves in a rotating stratified fluid

Abstract

It is found that in a rotating stratified fluid bounded by a single rigid wall, edge waves may occur at all frequencies less than or equal to N sin a (a is the angle of the wall from the horizontal and N the Brunt‐Vaisala frequency). These decay exponentially away from the boundary, in a distance of O(S) wavelengths, for α = O(1), or O(S ^‐1) wavelengths, for αS ≤ O(1), where S is the ratio of N to the Coriolis parameter f, taken for illustration to be large. The phase and energy both move with a component to the left, facing shallow water. The waves could, for example, appear as an internal tide at the continental rise or as baroclinic meandering of currents over a slope.

The low‐frequency limit, αS ? 1, is studied in detail. To allow for large scales of motion other rigid boundaries and variations in f are included. The edge (actually “bottom") waves then merge with topographic‐planetary waves as the wavelengths increase; the familiar depth‐independent mode is found to be possible in the sea for wavelengths exceeding about 450 km. The ß‐effect introduces modes complementary to that trapped at the bottom, which instead are isolated from it.     

Divergent distributions of prey and predator,a fishing effect?

To compare the vertical distributions of benthos and fish species of Upper Lake Constance (Bodensee), 552 benthos samples were taken with an Auerbach grab at four transects (10–250 m). An additional 54 samples (1–10 m) were collected elsewhere. Complementary data was taken from the literature. In winter, most fish feed on benthos, mainly chironomids, but in summer less than 5% do so. Formerly the bottom gill-netting aimed mainly at catchingCoregonus pidschian, but it now aims atPerca fluviatilis. Contrary to expectation, in winter the greatest abundance ofP. fluviatilis is much deeper (55 m) than that of its preferred food, i.e. chironomids (<20 m). Comparably,C. pidschian also stayed deeper than its main food source (chironomids and mollusks).Lota lota, Salvelinus profundus andS. alpinus — unlike the unwanted cyprinids — also stay or stayed deeper than the attractive chironomids. It is argued that the fish reduce their predation risk, i.e. the risk of being gillnetted in the upper 50 m, by selecting the deeper less dangerous, but also less food-abundant habitat. Balancing predation risk against food abundance may have led to survival of the deepest.     

Determination of a seismometer’s generator constant, azimuth, and orthogonality in three-dimensional space using a reference seismometer

To accurately predict the performance of a seismometer, knowledge of its key parameters is required. We present a new method that requires a single reference instrument to estimate some of the important parameters of the seismometer, such as the ratio of the generator constants, the orthogonality deviation, and the rotation in space and in the horizontal plane with regards to the reference instrument. The procedure is performed in the three-dimensional spaces where the Euler rotation theorem is applied in order to define a transformation, which is then used to transform the detection of the reference seismometer as well as the detection of the instrument under test. The estimated transformation matrix is defined as an upper triangular matrix, where its elements contain the information regarding the parameters of the tested seismometer, which are then evaluated using the Euler angles. The new method has been verified on a pair consisting of two STS-2 seismometers and on a pair consisting of one CMG-3T and one STS-2 seismometer.     

Cyclic spattering,seismic tremor,and surface fluctuation within a perched lava channel,Kīlauea Volcano

In late 2007, a perched lava channel, built up to 45 m above the preexisting surface, developed during the ongoing eruption near Pu‘u ‘Ō‘ō cone on Kīlauea Volcano’s east rift zone. The lava channel was segmented into four pools extending over a total of 1.4 km. From late October to mid-December, a cyclic behavior, consisting of steady lava level rise terminated by vigorous spattering and an abrupt drop in lava level, was commonly observed in pool 1. We use geologic observations, video, time-lapse camera images, and seismicity to characterize and understand this cyclic behavior. Spattering episodes occurred at intervals of 40–100 min during peak activity and involved small (5–10-m-high) fountains limited to the margins of the pool. Most spattering episodes had fountains which migrated downchannel. Each spattering episode was associated with a rapid lava level drop of about 1 m, which was concurrent with a conspicuous cigar-shaped tremor burst with peak frequencies of 4–5 Hz. We interpret this cyclic behavior to be gas pistoning, and this is the first documented instance of gas pistoning in lava well away from the deeper conduit. Our observations and data indicate that the gas pistoning was driven by gas accumulation beneath the visco-elastic component of the surface crust, contrary to other studies which attribute similar behavior to the periodic rise of gas slugs. The gas piston events typically had a gas mass of about 2,500 kg (similar to the explosions at Stromboli), with gas accumulation and release rates of about 1.1 and 5.7 kg s⁻¹, respectively. The time-averaged gas output rate of the gas pistoning events accounted for about 1–2% of the total gas output rate of the east rift zone eruption.     

Chemical and spectroscopic characterization of humic substances from sediment and riparian soil of a highly polluted urban river (Suquía River,Córdoba,Argentina)

The Suquia River,the largest urban river in Cordoba(Argentina),has been severely polluted for decades.Actions must be taken to restore its environmental quality by managing riparian zones for increased water-self purification.The current study aimed to characterize organic matter(OM) dynamics and humic substances(HS) spectrochemical properties along the lower-middle basin of the Suquia River.Riparian soil(0-20 cm) and sediment(0-10 cm) samples were collected from a reference location(S1)and four polluted sites(S2-S5) during a low-flow period.The contents of soil and sedimentary OM and HS fractions were analyzed by wet oxidation,as well as HS Fourier transform infrared(FT-IR) and ultraviolet-visible(UV-Vis) spectrochemical properties.The OM and HS fractions from riparian soil were high upstream of Cordoba City(S1 and S2,50.2-50.4 g/kg OM) and within a 50 km downstream location(S5,30.9 g/kg OM) owing to a surplus of fresh plant biomass-carbon(C) inputs.Highly heterogeneous sediment samples did not show any significant differences among sites(P 0.05).The lowest values of the ratio of absorbances at 465 and 665 nm(E4/E6)(1.78) and the Δ log K(0.15) coefficient(a measure of HS maturity degree) were obtained downstream of Cordoba City,for both riparian soil and sediment,indicating that HS were enriched by more condensed aromatic structures within highly degraded portions of the river.All samples exhibited similar IR spectra,implying overlapping recalcitrant-C structures at the functional group level,but with different absorbance intensity.Data from the current study constitute a baseline for understanding the chemical nature of HS from sediment and riparian soil along the Suquia River and can be used as a reference for future studies tracking OM compositional changes over time.     

Do emissions and income have a common trend? A country-specific,time-series,global analysis, 1970–2008

This paper analyzes the relation between income and emissions in the period 1970–2008, for all world countries. We consider time-series of CO₂, SO₂ and GWP100, and use Vector Autoregressive models that allow for nonstationarity and cointegration. At 5 % significance level, income and emissions are found to be driven by unrelated random walks with drift (respectively by a common random walk with drift) in about 70 % (respectively 25 %) of cases; in the remaining cases the variables are trend-stationary. Tests of Granger-causality show evidence of both directions of causality. For the case of unrelated stochastic trends, we almost never find income driving emissions, as predicted by a consumption-function interpretation. These causality results and the absence of a common trend challenge the main implications of the Environmental Kuznets Curve, namely that the dominant direction of causality should be from income to emissions, and that for increasing levels of income, emissions should tend to decrease.     

Geochemical anomalies of hydrothermal plume at EPR 13°N

During the DY105-12, 14cruise (R/V DAYANG YIHAO, November 2003) on East Pacific Rise (EPR) 12- 13°N, the submarine hydrothermal activity was investigated and the CTD hydrocast was carried out at EPR12°39′N-12°54′N. From the temperature anomalies and the concentrations of magnesium, chlorine, bromine in seawater samples, we discover that magnesium depletes 9.3%-22.4%, chlorine and bro- mine enrich 10.3%-28.7% and 10.7%-29.0% respectively relative to normal seawater at the stations which have chemistry anomalies, moreover temperature and chemistry anomalies are at the same layer. The depletion of magnesium in the plume may be caused by a fluid lacking of magnesium which rises after the hydrothermal fluid reaches the equilibrium with ambient seawater, the enrichment of chlorine and bromine might be the result of inputting later brine which is generated by phase separation due to hydrothermal activity. In addition, the Br/Cl ratio in the abnormal layers at the survey area is identical to that in seawater, which implies that halite dissolution (or precipitation) occurs neither when the fluid is vented nor when hydrothermal fluid entraining ambient seawater rises to form plume. From the ab- normal instance at E55 station, it is very possible that there might exist a new hydrothermal vent site.     

Structure, stratigraphy, and eruption dynamics of a young tuff ring: Hanauma Bay, O’ahu, Hawai’i

The Hanauma Bay–Koko Head complex is one of several young volcanic landforms along the Koko fissure, in southeastern O’ahu. The Hanauma Bay region of the complex comprises two nested tuff rings, inner and outer Hanauma Bay, and multiple smaller vents. The internal structure of the inner tuff ring, well exposed due to subsequent breaching by the ocean and wave erosion, indicates that it formed during a minimum of five distinct phases of deposition that produced five mappable units. Significant inward collapses generated major unconformities that separate the units exposed in the inner wall. The planes of failure are cut by narrow steep-walled, locally overhung channels and gullies, suggesting that the collapse events were each followed by short time breaks during which the deposits were eroded by rainfall runoff. Within each pyroclastic unit, there are many local slump scars and unconformities, suggesting that minor instability of the inner wall was a near-constant feature. From bedding sags and surge bed forms, it is apparent that the vent shifted at least twice during tuff ring growth. Ballistic blocks in the youngest unit indicate that the eruption overlapped in time with a separate eruption to the north, most likely to be that of the Kahauloa tuff ring 880?m away.     

National Hydrological Associations—a new network to advance science,practice and capacity

Abstract

Over the past 150 years National Hydrological Associations (NHAs) have been established in many countries. Hydrology has developed within many different contexts, as is reflected in the diverse nature of the NHAs that exist. Some NHAs have developed within a governmental context, while others owe their existence to the efforts by individual hydrologists. Their common objective is the promotion of the science and practice of hydrology, but their range of activities is very wide. On many occasions the International Association of Hydrological Sciences (IAHS) has collaborated with such Associations and has proposed that much could be gained if NHAs were to be in contact with each other, as well as with IAHS. From this arose the idea of establishing a Network of NHAs. An Agreement for the establishment of the Network was signed in Gothenburg in July 2013. Its Second General Assembly was held in Prague in July 2015.     

Relatively short-term correlation among deformation,degassing, and seismicity: a case study from Concepción volcano,Nicaragua

Concepción is a frequently active composite volcano in Nicaragua, and is located on Ometepe Island, within Lake Nicaragua. Significant eruptive activity took place at this volcano between March and May 2010, consisting of ash and gas explosions (VEI 1–2). We compare geodetic baseline changes observed with global positioning system (GPS), sulfur dioxide flux (SO₂), and seismic amplitude (SAM) data collected at Concepción during April – June, 2010, and February – April, 2011. Time series analysis reveals a remarkable correlation among the data sets during 2010, when the volcano was erupting. In contrast, the volcano was at its background level of activity in 2011 and the statistical correlation among the time series is not significant for this period. We explain the emergence of correlation among the time series during eruptive activity through modeling of the GPS data with emplacement of a magma column in an open conduit. In the model, magma rose in the conduit, between May 5 and 14, 2010, from a shallow reservoir located at ～ 1.8 km depth. Later, between May 24 and 31, 2010, the top of the magma column descended to almost 600 m depth, corresponding to the cessation of eruptive activity. Thus, cross-correlation and an integrated analysis of these geophysical time series on a timescale of days helps to reveal the dynamics of the magma plumbing system operating below Concepción volcano.     

Widespread inflation and drainage of a pāhoehoe flow field: the Nesjahraun, Tingvellir, Iceland

This study describes the emplacement of the Nesjahraun, a basaltic lava flow that entered the lake Tingvallavatn, SW Iceland. High-resolution remotely sensed data were combined with fieldwork to map the flow field. Onshore, the Nesjahraun exhibits a variety of textures related to the widespread inflation and collapse of a pāhoehoe flow field. Its emplacement is interpreted as follows: Initially, the eruption produced sheet pāhoehoe. In the central part of the flow field, the lava has a platy-ridged surface, which is similar to some other lava flows in Iceland and on Mars. Here, the texture is interpreted to have formed by unsteady inflation of the brittle crust of stationary sheet pāhoehoe, causing it to break into separate plates. The ridges of broken pāhoehoe slabs formed as the plates of crust moved vertically past each other in a process similar to the formation of shatter rings. Upstream, fresh lava overflowed repeatedly from channels and tubes, covering the surface with shelly pāhoehoe. Formation of a 250-m-wide open channel through the flow field allowed the inflated central part of the flow to drain rapidly. This phase produced ‘a‘ā lava, which eroded the channel walls, carrying broken pāhoehoe slabs, lava balls and detaching large (>200 m long) rafts of compound shelly pāhoehoe lava. Much of this channelized lava flowed into the lake, leaving a network of drained channels and tubes in the upstream part of the flow. As in other locations, the platy-ridged texture is associated with a low underlying slope and high eruption rate. Here, its formation was possibly enhanced by lateral confinement, hindered entry into the lake and an elevated vent location. We suggest that formation of this type of platy-ridged lava, where the plates are smooth and the ridges are slabs of broken pāhoehoe, can occur without significant horizontal transport, as the surface crust is broken into plates in situ. This reconstruction of the emplacement of the Nesjahraun also demonstrates that high-resolution aerial survey data are extremely useful in the mapping and measurement of lithofacies distributions in large flow fields, but that fieldwork is still necessary to obtain the detailed textural information necessary to interpret them.     

Comparison of LLR,MLP, Elman,NNARX and ANFIS Models—with a case study in solar radiation estimation

Despite the widespread application of nonlinear mathematical models, comparative studies of different models are still a huge task for modellers. This is because a large number of trial and error processes are needed to develop each model, so the workload will be multiplied into an unmanageable level if many types of models are involved. This study presents an efficient approach by using the Gamma test (GT) to select the input variables and the training data length, so that the trial and error workload can be greatly reduced. The methodology is tested in estimating solar radiation at the Brue catchment, UK. Several nonlinear models have been developed efficiently with the aid of the GT, including local linear regression, multi-layer perceptron (MLP), Elman neural network, neural network auto-regressive model with exogenous inputs (NNARX) and adaptive neuro-fuzzy inference system (ANFIS). This work is only feasible within the time and resources constraint, due to the GT in reducing huge workload of the trial and error process.     

Space–time variability of the Plata plume inferred from ocean color

Satellite ocean color and surface salinity data are used to characterize the space–time variability of the Río de la Plata plume. River outflow and satellite wind data are also used to assess their combined effect on the plume spreading over the Southwestern South Atlantic continental shelf. Over the continental shelf satellite-derived surface chlorophyll-a (CSAT) estimated by the OC4v4 SeaWiFS retrieval algorithm is a good indicator of surface salinity. The log (CSAT) distribution over the shelf presents three distinct modes, each associated to: Subantarctic Shelf Water, Subtropical Shelf Water and Plata Plume water. The log (CSAT) 0.4–0.8 range is associated with a sharp surface salinity transition across the offshore edge of the Plata plume from 28.5 to 32.5. Waters of surface salinity <31, derived from mixtures of Plata waters with continental shelf waters, are associated to log (CSAT)>0.5. In austral winter CSAT maxima extend northeastward from the Plata estuary beyond 30°S. In summer the high CSAT waters along the southern Brazil shelf retreat to 32°S and extend south of the estuary to about 37.5°S, only exceeding this latitude during extraordinary events. The seasonal CSAT variations northeast of the estuary are primarily controlled by reversals of the along-shore wind stress and surface currents. Along-shore wind stress and CSAT variations in the inner and mid-shelves are in phase north of the estuary and 180° out of phase south of the estuary. At interannual time scales northernmost Plata plume penetrations in winter (∼1200 km from the estuary) are associated with more intense and persistent northeastward wind stress, which in the period 2000–2003, prevailed over the shelf south of 26°S. In contrast, in winter 1999, 2004 and 2005, characterized by weaker northeastward wind stress, the plume only reached between 650 and 900 km. Intense southwestward plume extensions beyond 38°S are dominated by interannual time scales and appear to be related to the magnitude of the river outflow. The plume response to large river outflow fluctuations observed at interannual time scales is moderate, except offshore from the estuary mouth, where outflow variations lead CSAT variations by about 2 months.     

Modons and monopoles on a γ-plane

Abstract

The gamma plane approximation introduced in this study corresponds to a nonlinear horizontal shallow flow in a plane where, in addition to the familiar linear variation of f (i.e., β), there is a quadratic variation with latitude. Such a plane may have some application to the mesoscale oceanic flow in the immediate vicinity of the North Pole because at the pole the linear gradient (β) vanishes so that the quadratic variation (γ) is the dominant gradient. It is also applicable to the flow near the center of a rotating (laboratory) tank.

Exact analytical solutions analogous to the stationary barotropic mid-latitude modons (Stern, 1975) are constructed. First, it is shown that, for a modon situated slightly off the pole (i.e., both β and γ are present) the condition of stationarity (in a resting ocean) takes the form β ∫∫ &Psi; dxdy — 2γ ∫∫ y&Psi; dxdy = 0, where &Psi; is the streamfunction and x and y are Cartesian coordinates pointing eastward and northward, respectively. Secondly, it is shown that due to the presence of γ, the cyclonic cell situated to the north increases in size and engulfs the southern anticyclone which decreases in size. Namely, as the pole is approached the engulfing cyclone grows whereas the anticyclone shrinks. Ultimately, when the center of the modon (whose diameter is R) reaches a critical distance from the pole (0.1227 R) the anticyclone diminishes to merely a point. Modons that are closer than this critical distance to the pole cannot contain an anticyclone. Far away from the pole our solution reduces to the familiar mid-latitude β-plane modon as should be the case.

In contrast to these dramatic effects of γ on modons, the migration of monopoles (i.e., isolated cyclones or anticyclones) is almost unaffected by γ even though γ is of the same order of (or larger than) β. This results from the fact that the γ-induced perturbations are symmetrical (with respect to north and south) whereas those due to β are asymmetrical. It is shown that, as in other eddies, self-propulsion is primarily caused by asymmetrical perturbations so that disturbances due to γ have almost no influence on the migration.