西南三江甭哥金矿床磷灰石地球化学特征及地质意义

甭哥金矿床位于西南三江造山带北段的义敦弧南缘,属于与富碱侵入岩有关的金矿床。目前,对其成矿机理认识仍较为薄弱,制约了资源评价和找矿勘查进展。本文选取甭哥金矿床强矿化的正长斑岩和弱矿化的黑云辉石正长岩中的磷灰石作为研究对象,详细剖析磷灰石的地球化学特征,探讨其记录的成岩成矿信息。结果表明,磷灰石的稀土元素含量特征及配分模式显示富碱岩浆主要来自于壳幔混合的源区,黑云辉石正长岩中磷灰石的(La/Sm)N、(La/Yb)N、(Sm/Yb)N值和Sr含量呈正相关,说明长石结晶对岩浆结晶分异有重要的影响;正长斑岩中磷灰石具有高Sr/Y、Ce/Pb值,而Th/U、(Sm/Yb)N值较低,指示强烈的流体活动参与了岩浆结晶过程;磷灰石挥发分(F、Cl)含量及比值特征指示金矿成矿流体主要来自地幔源区,成矿与富碱、高氯的成矿流体有关。磷灰石Mn氧逸度计估算结果显示,甭哥富碱侵入岩具有高氧逸度特性,但两种不同岩性岩石的氧逸度具有差异性。其中,正长斑岩的logf_(O_2)值为-12～-10. 3,黑云辉石正长岩的logf_(O_2)值为-15. 5～-11. 1,磷灰石中SO_3含量及Ga含量也暗示正长斑岩的氧逸度高于黑云辉石正长岩的特征;结合磷灰石低Mn、Ga含量和高的Cl、SO_3含量,反映甭哥金矿床金的成矿是在高氧逸度条件下金氯络合物迁移、富集而沉淀的结果。因而,磷灰石的地球化学特征对金矿床成矿过程示踪和勘查评价具有重要的指示意义。     

铜陵地区中生代侵入岩LA-ICP-MS锆石U-Pb年代学及Cu-Au成矿指示意义

安徽铜陵地区是我国著名的Cu-Au多金属产地之一,金属成矿与燕山期岩浆作用关系密切.本次对铜陵地区石英(二长)闪长岩和花岗闪长岩系统地进行了LA-ICP-MS锆石年代学研究.高质量锆石U-Pb同位素206Pb/238U加权平均年龄结果表明铜陵地区中酸性侵入岩的成岩序列可能为花岗闪长岩(141Ma)→辉石(二长)闪长岩(139Ma)→石英(二长)闪长岩(135Ms,136Ma,137Ms).对比已有的高精度锆石U-Pb同位素年龄,我们认为铜陵地区岩体侵入后可能有个快速冷却的过程.铜陵地区与Cu-Au矿床有关的最主要侵入岩LA-ICP-MS锆石数据给出两组年龄:130～132Ma和138～140Ma.据高精度锆石U-Pb数据和一些矿床的Re-Os年龄,结合锆石元素地球化学资料,本文得出铜陵地区主要表现出两次成矿事件:早期成矿事件是与高Ce异常流体密切相关的铜金成矿事件(辉钼矿Re-Os年龄138～140Ma);晚期成矿事件可能与低Ce异常流体密切相关的铁硫成矿事件(黄铁矿Re-Os年龄约126Ma).     

富挥发分岩浆补给对斑岩型铜-钼矿床形成的关键作用:以西藏尼木岗讲矿床为例

西藏冈底斯带中段的岗讲斑岩铜-钼矿床发育多期次侵入体,而成矿作用主要与其中一期岩体(流纹英安斑岩)密切相关。为探究其原因,本文对岗讲斑岩铜-钼矿床中发育的各期次侵入体进行了全岩主、微量元素分析,并重点研究各期次侵入体内部新鲜斑晶(黑云母、斜长石)和副矿物(锆石、磷灰石)的化学成分和结构特征。结果表明,矿区各期次侵入岩均属于高钾钙碱性系列,具有相近的锆石饱和温度,都来自较为氧化的岩浆。此外,相比其他期次侵入岩,主成矿期的流纹英安斑岩中的磷灰石具有较高的SO_3、Cl含量,较低的F含量;黑云母含有较高的Cl含量和较低的F含量;同时,斜长石发育反环带。这些证据表明,在主成矿期岩浆就位之前,存在富S、Cl的偏基性岩浆注入了深部岩浆房,并发生岩浆混合作用,这不仅导致了主成矿期斑岩体的就位,同时还诱发流体出溶进入浅部岩浆房,并最终形成岗讲斑岩铜-钼矿床。     

金沙江—红河富碱侵入岩磷灰石挥发分组成特征及其地质意义

运用电子探针系统地分析了西南三江地区金沙江—红河富碱侵入岩带内8个与铜、金成矿密切相关的以及不含矿的喜山期富碱侵入岩中含水矿物磷灰石的成分。结果表明,岩体岩浆期磷灰石显示出富F而贫Cl、SO3、OH的特征,这种特点与环太平洋成矿带类似岩体磷灰石中所表现出来的有一定差异,体现了大陆环境斑岩铜金矿床岩浆挥发分的特殊性。     

安徽繁昌-铜陵中生代侵入岩的黑云母特征和成因探讨

安徽繁昌—铜陵地区属于长江中下游铁、铜、钼、金成矿带的一部分,中生代侵入岩中广泛发育黑云母。选取该区有代表性的3个岩体———板石岭黑云母石英二长岩、凤凰山花岗闪长岩、沙滩脚花岗闪长岩的黑云母单矿物样品,对其进行了电子探针成分分析I、-CP稀土元素成分分析、穆斯鲍尔谱特征分析研究。本区黑云母以三八面体类型为主,属镁质黑云母,黑云母的镁质率为0.62~0.71,表明岩体属于深源系列;铜陵2个岩体黑云母的SiO2、TiO2、Na2O含量较繁昌板石岭黑云母石英二长岩的要低,而TFeO较高。穆斯鲍尔谱表明黑云母的Fe3 /(Fe2 Fe3 )值为0.346~0.385,计算得到凤凰山花岗闪长岩的氧逸度f(O2)值为10-5.5Pa;黑云母的氧化物成分和稀土元素成分表明3个侵入体均属壳-幔混源型,但铜陵两个形成时代较早的花岗闪长岩体的幔源岩浆成分要明显多于形成时代较晚的繁昌岩体的。     

安徽铜陵中生代侵入岩地质地球化学特征再认识及成因讨论

安徽铜陵地区是我国最著名的铜多金属矿产地,岩浆岩出露广泛,岩浆作用与成矿关系密切.作者广泛收集了前人对铜陵地区中生代岩浆岩的研究资料和成果,并在此基础上进行了仔细的岩相学观察和深入的岩石学、岩石化学和微量元素及同位素地球化学研究,系统总结了该区中生代侵入岩的地质地球化学特征,并探讨了其成因机制.研究认为:①铜陵地区中酸性侵入岩形成于晚侏罗世-早白垩世(135 ～ 147Ma),岩浆活动持续时间大约为10～15Ma;岩体沿近东西向深断裂呈带状分布,浅成侵入产出,受多期不同方向和性质的断裂控制.②依据Q-A-P图解确定区内侵入岩主要为辉石闪长岩、石英(二长)闪长岩和花岗闪长岩3类中酸性闪长质岩石,均属亚碱性高钾钙碱性系列.③3类侵入岩具有相似的微量元素、稀土元素和Pb-Sr-Nd-O同位素地球化学特征,反映原始岩浆起源于富集岩石圈地幔,受到壳源物质的混染.④3类侵入岩可能是地壳深部带状岩浆房不同岩浆层中的岩浆与构造运动诱发的深断裂相沟通并随机地上升、脉动式侵位形成的;深部岩浆房中的带状岩浆层可能是由于温度梯度引起扩散对流作用进而发生一定程度的熔离分异作用所致;岩浆演化过程中存在镁铁矿物及磷灰石和锆石等矿物的结晶分异作用.⑤铜陵地区中生代岩浆活动的大地构造背景是大陆板块内部,岩浆作用与晚侏罗纪古太平洋板块的俯冲作用密切相关,但同时受区域前中生代基底构造的制约;侵入岩原始岩浆起源于挤压向拉张转换的动力学背景下的岩石圈地幔加厚之后的减压熔融并底侵下地壳岩石.     

安徽铜陵矿集区石英闪长岩—花岗闪长岩成因的Sr-Nd-Hf-O同位素制约

安徽铜陵矿集区是我国长江中下游构造—岩浆—成矿带中一个重要的铜金多金属成矿区,区内广泛发育晚中生代以石英闪长岩和花岗闪长岩为主的中酸性闪长质侵入岩体,且其与成矿关系密切。关于铜陵矿集区侵入岩的成因,前人已有大量研究成果发表,但仍存有一定争议。本文在广泛收集前人研究资料和成果的基础上,选择区内铜官山石英闪长岩体和新屋里、胡村花岗闪长岩体开展全岩Sr-Nd同位素和锆石原位Hf-O同位素分析,以进一步探讨其成因机制。研究表明,石英闪长岩和花岗闪长岩的结构构造和矿物组成特征相似,全岩主量元素、微量元素和稀土元素组成特征也基本一致,均属高钾钙碱性岩石系列,并具有埃达克质岩石特征。石英闪长岩I_Sr值为0.707 2～0.709 0,ε_Nd（t）值为-13.0～-8.3,锆石ε_Hf（t）值为-23.5～-8.7,δ¹⁸O值为6.5‰～7.4‰;花岗闪长岩ISr值0.707 7～0.709 8,ε_Nd（t）值为-13.6～-8.5,锆石ε_Hf（t）值为-19.0～-7.4,δ¹⁸O值为6.7‰～8.1‰。石英闪长岩和花岗闪长岩Sr-Nd同位素组成特征和锆石Hf-O同位素组成特征亦基本一致,指示它们具有相同的成岩物质来源。结合区域地质背景和构造演化,本文认为,铜陵矿集区石英闪长岩和花岗闪长岩为富集岩石圈地幔岩浆与壳源埃达克质岩浆混合并上升侵位所形成,富集岩石圈地幔岩浆并非起源于古太平洋俯冲洋壳或俯冲洋壳析出流体交代的富集岩石圈地幔,而是新元古代华夏洋俯冲析出流体交代扬子板块岩石圈地幔所形成,壳源埃达克质岩浆为新元古代华夏板块与扬子板块碰撞之后形成的新生地壳熔融而成。铜陵矿集区晚中生代大规模岩浆作用的诱因是大陆板内构造背景下富集岩石圈地幔部分熔融岩浆上涌加热以及受古太平洋板块挤压和地壳加厚再转向拉张应力下的减压熔融。     

Petrogenesis of the Mesozoic Intrusive Rocks From the Tongling Ore Cluster Region: The Metallogenic Significance

安徽铜陵矿集区是我国最著名的铜、金、铁产地之一,成矿与岩浆作用关系密切.本次对铜陵地区中生代侵入岩进行了系统的矿物学、岩石学和元素地球化学研究.结果表明:①本区岩浆岩主要为辉石(二长)闪长岩( SiO2≤55％)、石英(二长)闪长岩(SiO255％～65％)和花岗闪长岩(SiO2≥65％)三种岩石组合,其矿物成分主要为中长石、正长石、镁质黑云母和直闪石铝直闪石系列.②辉石(二长)闪长岩组合岩石主要为碱性和橄榄玄粗岩系列.带有古老俯冲洋壳成分的富集岩石圈地幔分离结晶作用可能是辉石(二长)闪长岩组合岩石产生的最主要原因.③花岗闪长岩、石英(二长)闪长岩组合岩石主要属于亚碱性和高钾钙碱性系列,其某些地球化学特征和埃达克岩的地球化学特征一致.幔源岩浆和壳源岩浆的混合可能是石英闪长岩组合和花岗闪长岩组合岩石的主要形成机制.④早白垩世岩浆活动及其相关的铜、金成矿作用可能与古太平洋板块俯冲及其演化过程密切相关.     

安徽铜陵凤凰山燕山期中酸性侵入岩地球化学特征及其与金属成矿关系

安徽铜陵凤凰山铜矿是铜陵矿集区内最典型的矽卡岩型铜矿床之一,也是凤凰山矿田内规模最大的铜矿床。矿区内新屋里岩体属于高钾钙碱性系列,主要岩性为石英二长闪长岩和花岗闪长岩。岩石地球化学特征表明凤凰山中酸性侵入岩岩浆属于壳幔混合型,原始岩浆来源于上地幔碱性玄武岩区并有地壳物质混染,在岩浆不断演化过程中有外来物质的加入,成岩过程以混合作用为主。凤凰山铜矿体分布于岩体与大理岩的内矽卡岩带上,岩体中铜含量较高。铜矿体是岩浆期后热液交代碳酸盐地层形成的。矿体的空间分布受构造变形-岩浆侵入高温高压作用的双重控制。矿化经历了从高温矽卡岩阶段到中低温热液阶段的多期次复合成矿作用。     

安徽沿江地区燕山期含铜岩体稀土、微量地球化学特征

安徽沿江地区位于长江中下游岩浆成矿带中段,其中众多矿床的形成与燕山期岩浆密切相关.对安徽沿江地区(铜陵、安庆和庐纵)燕山期中酸性舍铜岩体地球化学研究表明:舍铜岩体稀土特征总体表现为右倾型,LREE富集,HREE亏损但表现为平缓的曲线,无明显的Eu异常,XREE含量变化范围在85.84×10-6～446.26×10-6,(La/Yb)N值为7.87至63.8,具有高Th,Sr;低Cr,Ni;La/Nb(平均值为3.4),Nb/U(平均值为5.24)和Nb/Pb(平均值为1.47)等特征,结合同住素特征,为壳幔混熔的物源区.研究还表明,本区燕山期含铜岩体可能来自于底侵的幔源碱性玄武岩浆同化混染古老地壳物质同时结晶分异的产物.其中岩体中的铜能否参与成矿关键取决于是否发生热液蚀变交代作用.     

Petrogenesis and metallogenic implications of Late Mesozoic intrusive rocks in the Tongling region,eastern China: a case study and perspective review

ABSTRACT

Large-scale Cu–Au mineralization is associated with Late Mesozoic intrusive rocks in the Tongling region of eastern China, which mainly comprise pyroxene monzodiorite, quartz monzodiorite, and granodiorite. To constrain the petrogenesis of the intrusive rocks and Cu–Au mineralization, detailed analyses of the geochronology, apatite in situ geochemistry, whole-rock geochemistry, and zircon Hf isotopic compositions were performed. Magmatic zircons from pyroxene monzodiorites, quartz monzodiorites, and granodiorites yield U–Pb ages of 136–149 Ma, 136–146 Ma, and 138–152 Ma, respectively, indicating that their formation ages are contemporaneous. Quartz monzodiorites and granodiorites (SiO₂ = 57.9–69.5 wt.%) are highly potassic calc-alkaline rocks with adakitic affinity and have low MgO and Y contents, low zircon ε_Hf(t) values (?11.7 to ?39.0), high apatite Cl contents (>0.2 wt.%), and log fO₂ values (?23.2 to ?8.23), indicating that they may have formed when metasomatized mantle-derived magmas mixed with slab-derived magmas before undergoing crustal assimilation and fractional crystallization. Pyroxene monzodiorites (SiO₂ = 48.4–53.0 wt.%) are shoshonitic and record high MgO, P₂O₅, and Y contents, high zircon ε_Hf(t) values (1.55 to ?7.87), high oxygen fugacity, low Nb and Ta contents, and low apatite Cl contents (mainly <0.2 wt.%), suggesting that they were primarily derived from a metasomatized lithospheric mantle-derived magma that experienced the assimilation of lower crustal materials. The results indicate that the intrusive rocks and associated large-scale Cu–Au mineralization of the Tongling region resulted from the partial melting of the subducted oceanic slab in an oxidizing environment.     

Geochronological and geochemical studies of adakites from Tethyan Belt,Western Pakistan: A clue to geodynamics and Cu-Au mineralization

ABSTRACT

Large porphyry Cu-Au deposits are associated with Early Miocene intrusive rocks in Tethyan belt, discovered along Chagai magmatic arc in Western Pakistan, adjacent to Southeast Iran. Two types of rocks were discriminated as granodiorite and monzodiorite from Saindak area. The granodiorites are associated with regional large Cu-Au mineralization, while the monzodiorites are mostly ore-barren. LA-ICP-MS U-Pb dating yielded weighted mean ²⁰⁶Pb/²³⁸U ages of 22.16–24.2 Ma for granodiorites and ca. 22.6 Ma for a monzodiorite. These intrusive rocks in the Saindak area are all calc-alkaline rocks, with enriched LILEs and depleted HFSEs, and without Eu negative anomalies. The felsic granodiorites are characterized by high Sr contents and Sr/Y ratios, with intermediate to high (La/Yb)_N ratios that identify them as typical high-silica adakites. In contrast, the basaltic-andesitic monzodiorites are just normal arc-related rocks, showing less fractionated REE patterns than the granodiorites, with systematically lower LREE and higher MREE and HREE. Low K₂O/Na₂O ratios and decoupled Sr/Y-(La/Yb)_N ratios indicate the characteristics of slab-derived adakites for the granodiorites, most likely originated through partial melting of the subducted Neotethys oceanic crust beneath Eurasian continent followed by subsequent mantle interaction. The almost simultaneously melting of subcontinental lithospheric mantle induced by dehydration of Neotethys plate gave rise to the formation of the barren monzodiorites. These intrusive rocks in the Saindak area are characterized by similar Sr-Nd-Pb isotopes with high ⁸⁷Sr/⁸⁶Sr_i ratios, slightly negative εNd(t) values and radiogenic Pb isotopes, plotting in the field between the MORB and EM-II mantle endmembers or the Average Cadomian Lower Crust, suggesting subducting sediments or old continental crustal materials have contributed into the compositions of these rocks by source enrichment or crustal contamination. The slab-melting derived adakite is favourable for regional massive Cu-Au mineralization in the Saindak area.     

安徽铜陵焦冲矿田侵入岩锆石U-Pb定年、Hf同位素特征及成因

安徽铜陵矿集区出露的侵入岩可划分为高钾钙碱性和橄榄安粗岩系列,作为铜陵7大矿田之一的焦冲地区是否也存在两个系列侵入岩?它们的时代及成因与整个铜陵地区的侵入岩是否相同?这些问题目前仍不清楚。本文选择铜陵焦冲矿田的侵入岩开展了岩相学、岩石地球化学、LA-ICPMS锆石U-Pb定年及原位Hf同位素地球化学研究。结果表明,焦冲矿田也存在高钾钙碱性系列和橄榄安粗岩系列侵入岩,前者的主要岩石类型为石英二长闪长岩、花岗闪长岩,后者为辉石二长闪长岩。LA-ICPMS锆石U-Pb定年结果显示,高钾钙碱性系列侵入岩年代与铜陵地区其他矿区同类岩石年代相同,约为142 Ma;而橄榄安粗岩系列侵入岩年代比铜陵地区其他矿区同类岩石年轻,约为136 Ma。总体上看,铜陵地区两个系列侵入岩具有多期次侵位的特征。焦冲高钾钙碱性系列侵入岩含有较多的老的继承性锆石,说明本区古老地壳卷入了岩浆形成过程。结合铜陵地区侵入岩的特征和焦冲矿田侵入岩岩石地球化学研究结果,笔者认为,焦冲矿田两个系列侵入岩成因与铜陵地区侵入岩相似,即橄榄安粗岩系列侵入岩是来自莫霍面附近深部位岩浆房富碱基性岩浆结晶分异后的产物,而高钾钙碱性系列侵入岩是深位岩浆房分异后的岩浆与浅位岩浆房长英质岩浆混合后的产物。     

Petrogenesis and metallogeny of the Dongguashan Cu-Au deposit in the Tongling ore-cluster region,the Lower Yangtze River Metallogenic Belt: Constraints from geochemistry and geochronology

The Dongguashan Cu-Au deposit located in the eastern portion of the Tongling mining district, the Lower Yangtze River Metallogenic Belt (LYRB), Eastern China is a typical one associated with the Qingshanjiao quartz monzodiorite, including porphyry, skarn, and stratabound ores. In order to constrain the petrogenesis of the intrusive rocks and associated Cu-Au mineralization, detailed analyses of the zircon geochronology and geochemistry, whole-rock geochemistry and Sr-Nd-Pb isotopes, and zircon Lu-Hf isotopes were performed. Magmatic zircons from quartz monzodiorite yield U-Pb ages of 136–138 Ma, revealing their formation ages of early Cretaceous. Geochemical characteristics of the quartz monzodiorites (SiO₂ = 63.6–66.2 wt%, high Sr, low Y and Yb concentrations) discriminate their adakitic affinity. They are enriched in LILE and LREE, depleted in HFSE and HREE, and has no or slightly negative Eu anomalies. These geochemical characteristics indicate that the monzodiorites may be primarily derived from the magma mixing of mantle- and LCC-derived melts. The relatively low ε_Nd(t) values (−11.7 to −10.7) and high (⁸⁷Sr/⁸⁶Sr)_i ratios (0.7075 to 0.7078) may be plausibly interpreted by contamination of enriched mantle materials and/or continental crust. The high radiogenic Pb isotopes with (²⁰⁶Pb/²⁰⁴Pb)_i = 17.98–18.09, (²⁰⁷Pb/²⁰⁴Pb)_i = 15.51–15.53, and (²⁰⁸Pb/²⁰⁴Pb)_i = 38.18–38.26 plot in the field of MORB, near the intersection of EM-1 and EM-2, and are considerably different from those of the upper and lower continental crust and the Dabie adakites, which exclude major contamination from the continental crust. Ti-in-zircon temperatures and calculated Ce⁴⁺/Ce³⁺ values fall within the field between MH and FMQ. The results indicate that the intrusive rocks and associated large-scale Cu-Au mineralization in the Dongguashan deposit are resulted from the magma mixing of mantle- and LCC-derived melts. in a lower magma temperature, yet higher fO₂ and water content environment.     

铜陵地区中酸性侵入岩年代学研究

本文选择了铜陵地区主要岩石类型的代表性岩体中黑云母为测定对象，准确地测定了侵入岩的４０Ａｒ／３９Ａｒ同位素年龄。测定结果表明，区内侵入岩的年龄均小于１４０Ｍａ，属燕山晚期的产物，后期热事件为成矿时代，晚于岩浆侵入时代，在此基础上，分析了ＫＡｒ法、ＲｂＳｒ法同位素年龄产生偏差的原因     

Geochronology of Intermediate-Acid Intrusive Rocks from Tongling, Anhui

1. Introduction Tongling district is situated in the southern part of the middle-lower reaches of the Yangtze River, Anhui province, China (Fig.1). It is one of the most important metal base in China, being rich copper material resources, also named "ancient copper capital of China". Many geologists have been working in petrology, tectonics and ore-deposits in the area for many years. Studies show none of the ore-deposits is not bound up with the intermediate-acid intrusion in the area (Ma…     

安徽铜陵地区中生代侵入岩成因及成矿意义

安徽铜陵矿集区是我国最著名的铜、金、铁产地之一,成矿与岩浆作用关系密切.本次对铜陵地区中生代侵入岩进行了系统的矿物学、岩石学和元素地球化学研究.结果表明:①本区岩浆岩主要为辉石(二长)闪长岩( SiO2≤55％)、石英(二长)闪长岩(SiO255％～65％)和花岗闪长岩(SiO2≥65％)三种岩石组合,其矿物成分主要为...     

新疆阿尔金地区长沙沟一带奥陶纪侵入岩及其演化特征

新疆阿尔金地区长沙沟一带发育的侵入岩岩石类型包括辉石岩、辉长岩、辉绿辉长岩、石英闪长岩和石英二长闪长岩。野外地质特征和LA-ICP-MS锆石U-Pb测年结果显示就位时代均为奥陶纪。其中基性超基性侵入岩具有幔源型特征;中酸性侵入岩显示I型和地S型双重特征,其岩浆主要来源于上地幔,在岩浆上侵过程中同化混染了部分壳源物质,使其具有壳幔混合源的岩浆性质。基性超基性侵入岩形成于超大陆裂解构造环境,系与大陆裂谷或深大断裂有关的深成岩浆作用的产物,中酸性侵入岩是汇聚阶段的产物。