山西公海湖泊沉积物记录的大气粉尘现代过程

湖泊粉尘记录是研究区域大气粉尘演化历史的重要载体,而现代过程研究是定量提取湖泊沉积物中粉尘信号的重要基础。对山西公海湖泊沉积岩芯样品及周边不同类型的表土样品开展了粒度分析,并对岩芯样品进行粒度组分的定量分离。结果表明：全新世湖泊岩芯样品以黏粒（<2 μm）、细粉砂（2～19 μm）和粗粉砂（19～78 μm）为主,粗粉砂组分的粒度特征与湖泊沉积物中的石英颗粒、黄土样品中的粗粒组分及现代大气降尘的粒度特征相似,石英颗粒的表面微形态也具有典型风成特征。因此,公海湖泊沉积物中粒径19～78 μm的粗粉砂组分可用来代表大气粉尘的变化,这与湖泊沉积物中粗粉砂组分是大气尘暴降尘主要组分的认识一致。另外,公海湖泊冰面粉尘样品的平均粒径还具有从西北向东南递减的趋势,表现出与冬季风方向一致的特征,进一步表明公海湖泊沉积物中粗粉砂组分可以代表东亚冬季风强度的变化。因此,公海湖泊岩芯中的粗粉砂组分可用来重建全新世大气粉尘变化以及可能的东亚冬季风强度演化历史。     

Sedimentological and morphological characteristics of gypseous coastal nabkhas on Bubiyan Island,Kuwait, Arabian Gulf

Gypseous nabkhas of peculiar morphology occur on the beach berm and backshore slope along the southern coast of Bubiyan Island in northeast Kuwait. Their sediments are muddy sands and are mainly composed of gypsum with small amounts of shells, shell fragments, quartz and feldspars. Two types of gypsum are recognised: detrital grains and authigenic crystals. The authigenesis of gypsum within the nabkha detrital sediments is responsible for the significant increase in the volume of the nabkhas as well as considerable change in their morphology from a standard aerodynamic form to a whaleback shape. The genesis and diagenesis of the nabkha sediments are discussed, and future studies are recommended. The study concluded that mineral authigenesis within aeolian nabkha sediments should be seriously considered during the interpretation of their granulometrical characteristics and morphometric parameters.     

Aeolian dust in a saline playa environment, Nevada, U.S.A.

Saline playas in north-western Nevada, U.S.A., remnants of pluvial periods of the Pleistocene, represent a tremendous source of unconsolidated sediments available for aeolian transport. This study investigated the transport of aqueous-soluble solutes in dust from July 1994 through June 1996 along a transect from a barren salt-encrusted playa surface (elevation=1224 m), to a former pluvial lake beach (elevation=1228 m), to a dune-mantled upland (elevation=1248 m). The content of aqueous-soluble solutes in aeolian dust showed a significant (p≤0·05) interaction with dust trap location (playa, beach, dune) and time of collection. Dust collectors on the playa surface generally contained significantly more aqueous-soluble solutes and had greater total flux of solutes than either the beach or the dune locations. The solute content of aeolian dust was usually higher, in some cases several orders of magnitude, than that in the surface 5 cm of soil. Recent changes in playa hydrology may explain this result. Pulses of nitrate-rich dust, synchronous with spring emergence, and other nutrient additions via aeolian dust may have stimulated invasion of dune-mantled uplands by the weedSalsola paulsenii (barb-wire Russian thistle).     

High (ground) water levels and dune development in central Australia: TL dates from gypsum and quartz dunes around Lake Lewis (Napperby), Northern Territory

An episode of high lake levels prior to the last maximum glaciation has been identified at many localities in wastern Australia. Similar events have been recognized at playa lakes in central Australia, where gypsum dunes along playa margins formed during one or more episodes of high groundwater discharge, with a large influx of calcium sulphate.At Lake Lewis, exposures at two islands show similar sediment sequences: three pedogenic gypcrete layers interbedded with aeolian quartz and gypsum sand horizons form three units within gypsum dunes up to 7 m high. The lowest unit has cliffed edges buried by the upper units, indicating a significant time break. Four TL dates (coarse-grained quartz) show that this lowest unit was deposited at or before 70–80 ka. The middle unit of mixed gypsum and quartz sand capped by gypcrete represents the major phase of gypsum dune formation, and 6 TL dates range from 33 to 46 ka with overlapping error bars. These are slightly younger but statistically similar to TL dates (from 39 to 59 ka) of the shoreline gypsum dune at Lake Amadeus in the same region. The top unit of the two islands, up to 1 m thick, has not yet been well dated. One date is inconsistent with the well dated middle layer below, possibly because of incomplete bleaching, and has been rejected. The other date (17 ± 5 ka) is much younger which possibly indicates a minor and local reactivation of old gypsum sediments. At the lake margin, there are quartz dunes overlying the gypsum dunes, and a buried aeolian quartz sand layer occurs in a lake-margin terrace. These represent reactivation of the regional quartz dune field after the major gypsum dune formation. Two consistent TL dates (21 ± 4 ka and 23 ± 6 ka) indicate that regional dunes were active at about the time of the Last Glacial Maximum.     

Sediment Fluxes and Varve Formation in Sihailongwan,a Maar Lake from Northeastern China

Data derived from monthly sediment traps in Sihailongwan, a maar lake in northeastern China, yielded a detailed record of seasonal sediment fluxes. Sediment fluxes correspond to seasonal climatic variations. The diatom flux shows two distinct peaks in September and November, whereas the flux of chrysophyte stomatocysts shows a maximum in May. The blooms of diatoms may be related to the subsequent deepening of the thermocline in September and lake overturn in spring and November, and influx of nutrient-rich groundwater sometime after the onset of the summer monsoon. The fluxes of organic matter and siliciclastics show a distinct seasonal pattern. They are varying between 0.03 and 0.56 g m⁻² d⁻¹ and reach a maximum in May. Quartz in the trap samples indicates that the siliciclastic matter may originate from distant aeolian sources. Sediment trap data and thin section investigations confirm the seasonality of Lake Sihailongwan sediments. Dark-colored layer, which mainly consists of valves of Cyclotella comta, might be deposited during autumn, and then is followed by a light-colored mixed layer starting with siliciclastics deposited after ice-out. The varved sediments in the U-shaped Lake Sihailongwan represent a sensitive siliciclastic and geochemical archive of paleoenvironmental variability in this data-sparse area. Detailed investigations of varved sediments should provide decadal to annual records of seasonal sediment flux and its relation to climatic parameters. Especially the diatomaceous layer is regarded to indicate summer climatic fluctuations, while the thick siliciclastic layer could be an indictor of dust events.     

Smith Canyon dune field, Washington, U.S.A: relation to glacial outburst floods, the Mazama eruption, and Holocene paleoclimate

Sedimentary deposits from the Smith Canyon dune field, south-central Columbia Basin, Washington, U.S.A. document climatically-influenced Late Pleistocene and Holocene aeolian and fluvial deposition in a region impacted by glacial outburst floods and tephra falls. The depositional history is summarized by five environmentally distinctive and climatically sensitive sedimentary units (temporal limits estimated): Unit 1 (c. 15·5–8 ka), pedogenically altered glacial outburst flood and minor aeolian silt and clay; Unit 2 (c. 8–6·9 ka), fluvial and minor aeolian sand; Unit 3 (c. 6·9–6·8 ka), flood-induced fluvial sand with gravel-sized tephra clasts; Unit 4 (c. 6·8–3·9 ka), aeolian dune sand; Unit 5 (c. 3·9 ka to present), pedogenically altered, stabilized dune sand. Estimated age ranges are based on stratigraphic position, tephrochronology, and correlation with temporally constrained strata from elsewhere in the region.     

Clay slides in the Målselv valley, northern Norway: Characteristics, occurrence, and triggering mechanisms

The distribution of a large number of clay slides in the Målselv valley, northern Norway, is analysed and put into context with the stratigraphic organization of the valley-fill sediments. About 32% of the landslides larger than 10⁴ m³ occur close to the valley margins, where mud is either exposed or at shallow depth. About 57% of the landslides occur mid-valley, where relatively thin (< 15 m) coarse-grained deltaic sediments overlay fine-grained marine and glaciomarine sediments, and about 11% of the landslides occur in front of ice-contact deposits. The slide-prone areas are all characterized by the occurrence of heterogeneous sediments (interbedded clay, silt and sand), in addition to the presence of steep slopes eroded by rivers. The heterogeneous nature of the sediments probably enhanced groundwater drainage and leaching of salts from the clay, increasing sensitivity. Thus, the distribution and organization of the valley-fill sediments and groundwater drainage probably controlled the position of the slide scars and sliding planes. Since deglaciation of the valley (11,500 BP–present), isostatic rebound has enhanced fluvial incision and the creation of steep slopes due to a fall in relative sea level of up to 80 m.Arcuate-shaped, ‘bottleneck’ landslide scars ranging from c. 10⁴ to 10⁷ m³ in size is the dominant morphological signature of the slides, typical for quick clay slides or earth flows involving fluid mud. Their most common triggering mechanism is probably erosion at the toe slopes by the river Målselv or its tributaries. River erosion close to the valley margin, where glaciomarine and marine sediments are present, seems to give the most severe slides. The overall valley-fill organization controls the distribution of clay slides, which may apply to other fjord valleys having similar sediment distribution.     

Weathering characteristics of arctic islands in northern Norway

The arctic islands of the Lofoten-Vesterålen archipelago in northern Norway have a wide distribution of weathered land surfaces commonly located above 250 m with several apparent similarities. In order to investigate the characteristics of (deep) weathering in this region, northern Langøya and Hadseløya were chosen for in-depth analyses. Eight weathering profiles were excavated from various surfaces, and the stratigraphies were logged in detail. Material was collected throughout the weathering horizons, and all samples were subsequently analysed for clay mineralogy (< 63 μm fraction) and grain size distribution. The sampling strategy was complemented by samples from additional saprolites and other landforms such as moraines and rock glaciers. The XRD results indicate that the presence of secondary minerals, such as gibbsite (Al(OH)₃) and kaolinite (Al₂Si₂O₅(OH)₄), are very common throughout the profiles. Gibbsite is an extreme end product of silicate weathering and usually associated with a warmer and more humid climate, as found in Scandinavia during the Tertiary. The grain size analyses (< 63 μm) show that the finer silt fractions (< 8 μm) tend to be high in the profiles (20–40%), with significant amounts of clay (5–15%) demonstrating that the regolith itself is susceptible to frost sorting mechanisms.¹⁰Be exposure dates from in situ quartz knobs on tors and boulders of local origin suggest > 40,000 years of subaerial conditions. Considering the steady surface erosion, this figure should be viewed as an absolute minimum age estimate. Mapping of the superficial sediments and geomorphological features of the study areas has revealed several common morphological features, which indicate dominance of glacial and periglacial processes in the areas lying below the lower boundary of blockfields (c. 250 m). The weathering mantles are not a periglacial end product, but rather a relict tertiary landform that were modulated by permafrost processes as well as biological processes at later stages. The regolith cover constrain the vertical extension of warm-based Quaternary ice sheets challenging the notion of a parabolic ice mass consuming every mountain top of Lofoten and Vesterålen.     

Optical dating of Holocene sediments from a variety of geomorphic settings using single grains of quartz

This paper presents an improved method for the optical dating of Holocene sediments from a variety of geomorphic settings. We have measured the equivalent dose (D_e) in individual grains of quartz, using green laser light for optical stimulation, and have simulated the D_e distributions for multiple-grain ‘synthetic’ aliquots using the single-grain data. For 12 samples of known (independent) age, we show that application of a ‘minimum age model’ to the single-grain and ‘small’ (10-grain) aliquot D_e data provides the most accurate estimate of the burial dose for nine of the samples examined (3 aeolian, 5 fluvial, and 1 marine). The weighted mean D_e (as obtained using the ‘central age model’) gives rise to burial age overestimates of up to a factor of 10 for these nine samples, whether single grains, small aliquots, or ‘large’ (100-grain) aliquots are used. For the other three samples (two aeolian and one fluvial), application of either the minimum age model or the central age model to the single-grain, small aliquot, and large aliquot D_e data yields burial ages in accord with the independent age control. We infer that these three samples were well bleached at the time of deposition. These results show that heterogeneous bleaching of the optical dating signal is commonplace in nature, and that aeolian transport offers no guarantee that the sample will be well bleached at the time of deposition. We also show that grains sensitive to infrared (IR) stimulation can give rise to low D_e values, which will result in significant underestimation of the burial dose and, hence, of the age of deposition. We demonstrate that use of a modified single-aliquot regenerative-dose protocol incorporating IR stimulation prior to green light stimulation deals effectively with contamination by IR-sensitive grains. We conclude that application of the modified protocol to single grains or small aliquots of quartz, using the lowest D_e population to estimate the burial dose, is the best means of obtaining reliable ages for Holocene sediments from a wide range of depositional environments.     

Changes in the ionic composition of a saline lake,Mar Chiquita,Province of Córdoba,Argentina

Mar Chiquita is the largest water-body in Argentina according to area. This ranges from 2,000 km² in dry periods to 5,000 km² in humid ones. Its very high salinity ranged this century from 200 to 300 g/L, but an increase in the average rainfall in the basin since 1973 has led to a rise in lake level and the dilution of its waters to 78 g/L in 1978 and about 30 g/L in the late 1980s. Ionic strength decreased from 6.61 in 1970 to 0.541 in 1986. The composition of the water also changed, with increases in the proportions of sulphate, calcium and magnesium concentrations. The most important processes taking place in solution are calcite and gypsum equilibrium, formation of clay minerals, and sulphate reduction in the interstitial waters of the bottom sediments. The thermodynamic state of the solutions for different years has been obtained. Results show that the solution shifted from gypsum oversaturation in 1970 to gypsum equilibrium in 1978, and to gypsum undersaturation since 1982. A geochemical simulation of the composition of the solution from its origin from mean tributary composition, following a modified Hardie-Eugster model, has been developed using PHRQPITZ. The results agree with empirical observations.     

青海苏干湖表层沉积物粒度分布模式 与大气粉尘记录

位于干旱区柴达木盆地具有年纹层的苏干湖是以地下水补给为主的内陆封闭湖泊, 其表层沉积物粒度具有多组分峰态分布特征, Weibull 函数的拟合结果发现, 其粒度分布全部具 有4 个基本组分: 超细粒组分, 众数粒径在1 μm 上下; 细粒组分, 众数粒径在5~10 μm; 粗粒组分, 众数粒径在50~100 μm; 砂组分, 众数粒径在500 $m 左右。粒度主峰出现在细 粒组分或者粗粒组分。直接来自大气粉尘的冬季湖泊冰面样品及当地尘暴样品的Weibull 函数粒度拟合也显现出了相似的分布模式, 冰面样品的粒度主峰位于众数粒径在15~20 μmm 的 细粒组分, 砂组分(众数粒径452.9μm) 的出现指示出砂粒在冬半年沿冰面而进入湖泊中心。 尘暴降尘样品在尘暴季节(5 月份) 和非尘暴季节(11 月份) 的粒度分布普遍具有3 个组分, 缺少砂组分, 强沙尘暴事件样品则由4 个组分组成, 粒度主峰均位于众数粒径在100~200 μm 的粗粒组分。结果显示, 苏干湖湖泊沉积能够较好记录当地大气粉尘, 砂组分与湖泊周边干旱地表经历的近地面强沙尘活动有关, 粗粒组分记录了区域性的尘暴事件, 细粒组分主要反映 流域径流状况, 超细粒组分代表干旱区的大气背景粉尘和气溶胶。研究表明, 苏干湖内陆湖 泊沉积客观记录了区域大气粉尘和尘暴事件, 具有重建干旱区大气粉尘变化历史的潜在优势。     

Textural attributes, mineralogy and provenance of sand dune fields in the greater Al Ain area, United Arab Emirates

Sand dunes and interdune sediments around Al Ain city have markedly high carbonate contents which increase towards Jabal Hafit mountain and the Arabian Gulf coast. The dunes are composed predominantly of well-sorted fine sands, consisting of unstrained quartz and carbonate grains together with minor proportions of chert and feldspars. Scanning electron microscope (SEM) examination reveals that quartz grains display various mechanically- and chemically-formed surface textures. The heavy minerals are dominated by opaques and pyroxenes with minor tourmaline, garnet, rutile, epidote, monazite, zircon, hornblende and staurolite.Interdune sediments consist of fine and very fine, poorly- to extremely poorly-sorted sands together with small concentrations of gravel, silt and clay. The light sand fractions compositionally resemble those of dunes but contain, in addition, gypsum, anhydrite, halite and celestite. Percentages of pyroxenes are higher whereas those of zircon, tourmaline and rutile are lower than in dunes. X-ray diffractometry reveals that the clay fractions consist solely of palygorskite. Generally, interdune sediments are much less mature texturally and mineralogically than dune sands; the maturity of both types of sediments decreases toward the NE of the study area.Sand dunes in the various districts of the greater Al Ain area are genetically related. Also, there is a partial genetic relationship between the dunes and interdune sediments; both are mainly multicyclic. Their major parts were brought mainly by the dominant north-west (El Shamal) winds from older dune fields in other localities in U.A.E., Qatar and El-Rub El-Khali. Local contributions to the dune fields from Jabal Hafit mountain, the Oman Mountains and the calcareous coast of the Arabian Gulf were, in cases, significant. Also, authigenesis by groundwater under highly evaporitic conditions played a major role in the formation of interdune sediments through the genesis of the clay and some nonclay minerals.     

Characteristics of the Gobi desert and their significance for dust emissions in the Ala Shan Plateau (Central Asia): An experimental study

Using intact samples of Gobi surfaces, we conducted wind tunnel experiments and related analyses to describe the surface characteristics of Gobi deserts and their significance for dust emissions in the Ala Shan Plateau, an area of Central Asia with high dust emissions. Under relatively high wind velocities (22 m s⁻¹), the total sediment transport approached 700 g m⁻², with the fine fractions (<50 μm in diameter) accounting for up to 26 g m⁻². In consecutive experiments, the emission rates decreased greatly due to depletion of erodible particles. In the Ala Shan Plateau, coverage by gravels varied, and aeolian sediment transport increased with increasing gravel cover (to about 30%); above that level, transport decreased. Because gravel cover was less than 30% in most areas, the gravel may not play important role in dust emissions in this region. Although the Gobi surfaces are covered by gravel, high clay contents that may restrain sediment transport. In the Ala Shan Plateau, dust emissions therefore appear to be controlled mainly by the availability of fine particles, which is in turn controlled by their deposition by ephemeral streams, by their creation via physical, salt, and chemical weathering, and by other processes such as aeolian abrasion.     

Provenance of sediments deposited at paleolake San Felipe,western Sonora Desert: Implications to regimes of summer and winter precipitation during last 50 cal kyr BP

Rare earth element, major and trace element and mineralogy in the sediments representing last 50 cal kyr BP from the summer precipitation fed paleolake San Felipe identify the different association of minerals and selective transportation of different grain size fractions and relate them to the variation in pluvial discharge into the basin as well as aeolian activities in the western Sonora Desert. Period of lower pluvial discharge during 14–48 cal kyr BP is contemporary to the regime of dominant winter storms in the region. Transportation of coarser quartz and plagioclase during 40–48 cal kyr BP and dominant finer fractions during 14–40 cal kyr BP possibly mirror the variation in the frequency of winter storms. During 3–14 cal kyr BP, higher catchment erosion (sedimentation increased 4–12 times) and transportation of REE bearing heavy minerals into the basin indicate higher pluvial discharge. We relate this period to a regime of dominant summer precipitation associated with the North American Monsoon and tropical cyclones. Geochemical and mineralogical signatures of the sediments deposited during ca. 8, 12–13 and >48 cal kyr BP suggest selective mobilization of quartz and plagioclase from the surrounding sand dunes by the aeolian processes.     

Calibration of the MDCO dust collector and of four versions of the inverted frisbee dust deposition sampler

Wind tunnel experiments were conducted to determine the efficiency of sediment samplers designed to measure the deposition of aeolian dust. Efficiency was ascertained relative to a water surface, which was considered the best alternative for simulating a perfectly absorbent surface. Two types of samplers were studied: the Marble Dust Collector (MDCO) and the inverted frisbee sampler. Four versions of the latter catcher were tested: an empty frisbee, an empty frisbee surrounded by an aerodynamic flow deflector ring, a frisbee filled with glass marbles, and a frisbee filled with glass marbles and surrounded by a flow deflector ring. Efficiency was ascertained for five wind velocities (range: 1–5 m s^− 1) and eight grain size classes (range: 10–89 μm). The efficiency of dust deposition catchers diminishes rapidly as the wind speed increases. It also diminishes as the particles caught become coarser. Adding a flow deflector ring to a catcher substantially improves the catcher's efficiency, by up to 100% in some cases. The addition of glass marbles to a catcher, on the other hand, does not seem to increase the efficiency, at least not at wind velocities inferior to the deflation threshold. For higher velocities the marbles protect the settled particles from resuspension, keeping them in the catcher. The following five parameters determine the accumulation of aeolian dust in a catcher: the horizontal dust flux, the weight of the particles, atmospheric turbulence, resuspension, and the dust shadow effect created by the catcher. The final accumulation flux depends on the combination of these parameters. The catchers tested in this study belong to the best catchers currently in use in earth science and have been the subject of various aerodynamic studies to improve their efficiency. Nevertheless the catching efficiency remains low, in the order of 20–40% for wind speeds above 2 m s^− 1. Other catchers suffer from the same low efficiencies. There is, thus, evidence to believe that dust deposition rates published in the aeolian literature and obtained by collecting the sediment in a catcher largely underestimate the true deposition. The errors are considerable, of the order of 100% and more. A reconsideration of the literature data on aeolian dust deposition measured by catchers is, therefore, required.     

Origin of the sedimentary deposits of the Naracoorte Caves, South Australia

The origin of the sediments located in the Naracoorte Caves (South Australia) was investigated via the analysis of strontium isotope ratios (⁸⁷Sr/⁸⁶Sr), elemental geochemistry, and mineralogy. Sedimentary deposits located in Robertson, Wet, Blanche and several other chambers in Victoria Cave are all variable mixes of fine sand and coarse silts, which display similar and consistent strontium isotope ratios (0.717–0.725). This suggests that over the 400 ka time frame that these deposits span there has been minimal variation in the source of the clastic sediments. Increased strontium concentrations for these cave sediments correspond with increasing silt content, yet there is no correlation between ⁸⁷Sr/⁸⁶Sr ratios and silt content. This implies that the silt-sized component of the sediments is the main contributor of strontium to the cave sediments. Comparisons of ⁸⁷Sr/⁸⁶Sr with regional surficial deposits show a significant correlation between the cave sediments (avg: 0.7228; n = 27), the fine silt lunettes of the Bool Lagoon area (avg: 0.7224; n = 4), the sandy A horizons of the Coonawarra Red Brown Earths (RBEs; avg: 0.726; n = 5), and Holocene age podsolic sand deposits (0.723). These data suggest that there has been substantial flux from this group of deposits to the caves, as would be expected considering prevailing winds. This relationship is further supported by a strong correlation between many trace elements, including Ti, Zr, Ce, and Y; however, variations in clay mineralogy suggest that the fine silt-dominated lunettes and Padthaway RBEs were not significant contributors to the cave deposits. Hence, the detritus entering the caves was more than likely from areas proximal to the cave entrance and was dominated by medium grain-sized materials. Major regional deposits, including the coarser-grained, calcite-rich Bridgewater Formation sands, basalts from the lower SE, Padthaway Horst granites, Gambier limestone, and metamorphics from the Adelaide geosyncline show minimal correlation in ⁸⁷Sr/⁸⁶Sr ratios, elemental geochemistry, and mineralogy with the cave sediments, and are discounted as significant sources. In comparison, ⁸⁷Sr/⁸⁶Sr ratios for the Coorong silty sands (0.717–0.724), Lower Murray sands (0.727–0.730), and the medium size silt component of the Murray–Darling River system (0.71–0.72), compare favourably with the cave sediments. This relationship is further supported by similarities in elemental chemistry and mineralogy. Thus, much of the strontium-rich silt that is now located in the Naracoorte Cave sediments likely originated from the Murray–Darling basin. Over time, this material has been transported to the SE of South Australia, where it mixed with the medium sand component of the regressive dune ridge sequence, locally derived organic matter, limestone fragments, and fossil material to produce the unique deposits that we see evident in many of the chambers of the Naracoorte Cave system today.     

The PM10and PM2·5 dust generation potential of soils/sediments in the Southern Aral Sea Basin, Uzbekistan

The objective of this study was to assess the contribution of the major soil/sediment surfaces in the Southern Aral Sea Basin to the dust generation potential of this region. Eight crusts and soils/sediments from seven sites, representative of these surfaces, were sampled in the field and their major characteristics (particle size distribution, organic carbon content, carbonate content, salt content and composition) that are related to dust generation, were determined. The PM₁₀ and PM_2·5 dust generation potential of the materials was determined in the laboratory using the Lubbock Dust Generation, Analysis and Sampling System (LDGASS). The highest amount of PM₁₀ dust (579·3 mg.m⁻³) was generated from the Takyr crust material. The lowest by one Solonchak salt crust material (39·6 mg.m⁻³). Salt crusts from the desiccated Aral Sea bottom generated intermediate amounts of dust.The experimental results indicate that the Takyrs and Takyr-like soils, that occupy over 1 million ha in the Southern Aral Sea Basin, constitute the surfaces with the highest potential for being the source for the severe dust storms of the area. Second to the Takyr soils, the Solonchaks and Solonchak-like soils, also with an extent of over 1 million ha, contribute highly saline dust. To these must be added a large, as yet uncharted, proportion of the approximately 4 million ha of exposed sea bed, that exhibit Solonchak-like characteristics.     

Morphological and speleothemic development in Brujas Cave (Southern Andean Range, Argentine): palaeoenvironmental significance

Brujas Cave, in the Southern Andean Range, is a well-known endokarstic site in Argentina. However, the origin and evolution of this cave system are poorly known. Based on morphological cave features as well as characteristics of cave deposits, we propose a meteogene drawdown cave genesis, including a change from phreatic to vadose conditions related to the high rate of fluvial downcutting in the area. During the vadose period, various cave-related deposits, including authogenic calcite and gypsum speleothems, allogenic volcanic ash and external tufas were deposited. Gypsum crusts are the oldest cave deposits identified (90.2–64.3 ky BP). Their origin, deduced from isotopic characteristics (∂³⁴S=9.6‰), is related to the oxidation of pyrite contained in the Jurassic limestone bedrock as well as the dissolution of overlying Jurassic–Triassic evaporite formations. Gypsum crust deposition is associated with evaporation of water flowing and seeping into the cave during arid environmental conditions. Calcite deposits precipitated from flowing water under equilibrium conditions represent the main speleothem growth period (67.6–34 ky BP in age). Their stable isotope values (∂¹³C=−3‰ to −5‰ and ∂¹⁸O=−9‰ to −11‰) may indicate slightly humid and warm conditions related to the regional Minchin lacustrine phase and global oxygen isotope stage 3. Following this stage, a seismic event is evidenced by accumulations of broken stalactites. Seepage calcite speleothems covering cave walls were deposited under disequilibrium conditions by evaporation, probably during Holocene time. Finally, another more recent gypsum deposition period represented by gypsum balls has been differentiated. Micromorphological as well as isotopic (∂³⁴S=5.6‰) data indicate that these gypsum forms are related to cyclic processes (solution–deposition) from water seeping into the cave under arid conditions. In addition, intense volcanic activity in the area during Holocene time is deduced from allogenic volcanic ash and lapilli located mainly at the entrance cave. At present, limited hydrological activity is observed in the cave and small tufa deposits at karstic discharge points are evidenced. We conclude that the geomorphological evolution of Brujas Cave was controlled by climatic changes (wet and dry stages) under semiarid environmental conditions in a very active tectonic and volcanic setting during Late Quaternary time.     

Cleaning of lake sediment samples for diatom oxygen isotope analysis

Detrital grain contamination in a diatom sample can considerably influence the δ¹⁸O_diatom signal. In order to obtain a meaningful signal, pure samples must be used. This can be achieved via a series of cleaning stages including organic and carbonate material removal, sieving, differential settling and heavy liquid separation. The method described here works best for sediments with >20% diatom content. Based on testing various clean-up methods, we propose a sequence of four clean-up stages to produce pure diatom samples from a range of lake sediments types starting with a few grams of sediment. The diatom content and the oxygen isotope composition of the samples at each stage were measured in order to assess the effect of differential amounts of contamination. Results show that a four stage clean-up is necessary to produce clean diatom samples and that contamination by silt and clay causes lower δ¹⁸O values.     

Production of polysaccharide slime by microbial mats in the hypersaline environment of a Western Australian solar saltfield

Of the many microorganisms present in the hypersline environment of the saltfield studied, the cyanobacteriumSynechococcus was found to be the major producer of polysaccharide slime. When dissolved in the brine, this slime caused elevated brine viscosities which impaired the quality of the salt crystallised from such brine.Synechococcus was present in benthic microbial mats throughout the 6 concentrating ponds of the saltfield, but it dominated in the ponds where brine density was above 1.10 g cm^–3, corresponding to the saturation density of gypsum (CaSO₄·2H₂O). At such density,Synechococcus was always associated with copious amounts of slime. At lower density, the nature of the substratum over which the mat was growing affected the slime content and productivity of the mat, presumably relatively to its ability to supply nutrients to the mat. Under laboratory conditions, the addition of gypsum stimulated the growth ofSynechococcus in the presence of excess phosphate (>15 mg L^–1 PO₄-P). Slime production however was not stimulated by high salinity, addition of (CaSO₄·2H₂O), NaSO₄ or nitrate deficiency. Only as cultures entered a stationary phase of growth did slime production increase. It was concluded that a nutrient limitation was probably responsible for the activation of extracellular polysaccharide production, possibly as a means of disposing of excess photosynthetically fixed carbon.