Observations on the diagenetic behaviour of arsenic in a saline lake: Pyramid Lake,Nevada

We present, to our knowledge, the first dissolved arsenic (As) data from the pore waters of a closed-basin, saline lake, Pyramid Lake, USA. The As concentrations first decrease across the sediment-water interface to values below lake water concentrations and then rapidly increase to values as high as 5.85mol L^–1 at a depth of 15 cm. This maximum value is reached at the top of the sulfate reduction zone. The profile suggests that As is remobilized in the suboxic and anoxic zones of the sediments and is reprecipitated near the sediment-water interface under oxic conditions.     

Palaeoenvironmental Reconstructions Based on Geochemical Parameters from Annually Laminated Sediments of Sacrower See (northeastern Germany) Since the 17th Century

The history of hardwater lake Sacrower See (Brandenburg, northeastern Germany) was reconstructed back to the 17th century based on a multi-proxy study of five short sediment cores dated by varve chronology, ²¹⁰Pb and ¹³⁷Cs isotopes. We were able to distinguish three main phases: The lake was mesotrophic prior to the 1830s with an oxic hypolimnion. From the early 19th century on, δ¹³C of organic matter indicates that primary productivity starts to increase slowly. Between the 1830s and 1872, the lake went through a transition towards eutrophy. Low calcite contents in the homogeneous sediment are caused by dissolution connected to increasing primary productivity and growing importance of decomposition processes. After 1873, and accelerated since 1963, Sacrower See is characterised by growing nutrient input, and thus further increasing primary productivity. The lake is eutrophic, and decomposition of organic matter causes high oxygen consumption in the hypolimnion, which becomes regularly anoxic during thermal summer stratification. Biogenic varves are preserved in the sediment, characterised by layers of autochthonous, biochemically precipitated calcite crystals. In this study, we were able to demonstrate that Sacrower See is an example of exceptional slow increase of anthropogenically enhanced nutrient input, and of the imprint which these processes have on sediments of a hardwater lake.     

A 1500-year record of climatic and environmental change in ElkLake, Clearwater County, Minnesota II: geochemistry, mineralogy, and stableisotopes

Most of the sediment components that have accumulated in ElkLake, Clearwater County, northwestern Minnesota, over the past 1500 years areauthigenic or biogenic (CaCO₃, biogenic SiO₂, organicmatter, iron and manganese oxyhydroxides, and iron phosphate) and are deliveredto the sediment–water interface on a seasonal schedule where they are preservedas distinct annual laminae (varves). The annual biogeochemical cycles of thesecomponents are causally linked through the carbon pump, and are recapitulatedin longer-term cycles, most prominently with a periodicity of about 400 years.Organic carbon is fixed in the epilimnion by photosynthetic removal ofCO₂, which also increases the pH, triggering the precipitation ofCaCO₃. The respiration and degradation of fixed organic carbon inthe hypolimnion consumes dissolved oxygen, produces CO₂, and lowersthe pH so that the hypolimnion becomes anoxic and undersaturated with respectto CaCO₃ during the summer. Some of the CaCO₃ produced inthe epilimnion is dissolved in the anoxic, lower pH hypolimnion and sediments.The amount of CaCO₃ that is ultimately incorporated into thesediments is a function of how much is produced in the epilimnion and how muchis consumed in the hypolimnion and the sediments. Iron, manganese, andphosphate accumulate in the anoxic hypolimnion throughout the summer.Sediment-trap studies show that at fall overturn, when iron-, manganese-, andphosphate-rich bottom waters mix with carbonate- and oxygen-rich surfacewaters, precipitation of iron and manganese oxyhydroxides, iron phosphate, andmanganese carbonate begins and continues into the winter months.Detrital clastic material in the sediments of Elk Lake depositedover the last 1500 years is a minor component (<10% by weight) that ismostly wind-borne (eolian). Detailed analyses of the last 1500 years of the ElkLake sediment record show distinct cycles in eolian clastic variables (e.g.aluminum, sodium, potassium, titanium, and quartz), with a periodicity of about400 years. The 400-yr cycle in eolian clastic material does not correspond tothe 400-yr cycles in redox-sensitive authigenic components, suggesting that theclastic component is responding to external forcing (wind) whereas theauthigenic components are responding to internal forcing (productivity),although both may ultimately be forced by climate change. Variations in theoxygen and carbon isotopic composition of CaCO₃ are small but appearto reflect small variations in ground water influx that are also driven byexternal forcing.     

Sedimentological and geochemical records of past trophic state and hypolimnetic anoxia in large,hard-water Lake Bourget,French Alps

Sedimentological, geochemical and particle-size analyses were used to reconstruct the evolution of both trophic state and hypolimnetic anoxia in Lake Bourget (French Alps) during the last century. Radionuclide dating (²¹⁰Pb, ¹³⁷Cs and ²⁴¹Am) confirmed the annual rhythm of laminations in the upper sediment profile. In Lake Bourget, biochemical varves are triplets composed of a diatom layer (spring lamina), a bio-precipitated calcite-rich layer (spring/summer lamina), and a layer rich in organic matter and detrital particles (winter lamina). The onset of eutrophication and the first appearance of an anoxic facies occurred simultaneously and were dated by laminae counting to AD 1943±1 year. Persistent anoxic conditions began in AD 1960. Eutrophication is characterised by drastic increases in the flux of biogenic silica (mostly diatoms), lacustrine organic matter, and larger calcite crystals (15–30 μm). The increase of organic matter also represents a marker of the onset of anoxic conditions in the hypolimnion. Our results show that eutrophication was the main factor controlling anoxia in the hypolimnion. This eutrophication was caused mostly by the inflow of untreated sewage effluents, and to a lesser extent, by input of fertilizer-derived phosphorus during floods of the Rhone River and run-off from the lake catchment. The Rhone River, however, can also be a source of re-oxygenation via underflows that originate during flood events. Oxygenation of the hypolimnion is also controlled by low winter temperatures, which enable turnover of the lake. Thus, global warming, associated with a forecasted reduction in precipitation, might reduce the efficiency of hypolimnetic re-oxygenation in Lake Bourget.     

Sedimentological evidence for environmental changes since 34,000 years BP from Lago di Mezzano, central Italy

Sediment cores recovered from Lago di Mezzano, central Italy, were petrographically and geochemically (dry densitity, total organic carbon) investigated. A floating chronology was established with sedimentation rates derived from varve thickness measurements, and this chronology was both supported and extrapolated with calibrated AMS-14C-datings. The profile has a length of 29.7 m and comprises a total of 34,000 years.Late Pleistocene sediments consist of minerogenic-organic mud with few benthic diatoms and an organic carbon content of 2%, thus suggesting a high allochthonous input. The onset of the Late Glacial at 14,580 cal BP is documented by a lithologic change to more organic-dominated sedimentation. The Younger Dryas cold event is recorded between 12,650 and 11,400 cal BP and exhibits higher dry densities and minerogenic input. These dates agree with records from other lacustrine archives in Europe and the Greenland ice cores.The early Holocene comprises a laminated organic diatom gyttja deposited at a time of climatic amelioration and increased primary productivity. The establishment of an anoxic hypolimnion enhanced the varve and organic matter preservation. Since 3700 varve years BP the sedimentation pattern has been strongly influenced by human impact, as documented by the increase in minerogenic sediments and turbidites as well as higher sedimention rates. The onset of this influence coincides with a Bronze Age settlement at the lake shore.     

Historical loading record of sulfur in an Adirondack Lake

A model for the distribution of sulfur in the sediments of a lake in the Adirondack Mountains, New York, is developed to gain insight into the timing and magnitude of anthropogenic increases in sulfur loading. Surficial sulfur concentrations are about 3500 µg g^–1, increase to 6000–7000 µg g^–1 at a depth of about 6 cm, and then decrease downcore to background levels of about 2500 µg g^–1. Sulfate concentrations are about 60–80 µM in the overlying water and decrease rapidly below the sediment-water interface. This reflects assimilatory reduction and/or dissimilatory reduction of sulfate and incorporation into the inorganic and/or organic solid-phase fractions of the sediment. A mathematical model is constructed assuming sulfur is incorporated into sediments by burial of detrital organic matter and by diffusion of sulfate from the overlying water with subsequent fixation in the sediment. Several historical scenarios of atmospheric sulfate loading rates were examined as model boundary conditions. Model results are compared with observed sedimentary sulfur profiles. The observed sediment sulfur profiles are best described using model boundary conditions showing increases in lake water sulfate concentrations since about 1940. Assuming as much as a decade of retention of sulfate within the terrestrial portion of the ecosystem, this suggests that significant increases in sulfate deposition rates began sometime after 1930 in this relatively remote area.     

土壤坑蚀性实验研究

对采自内蒙东胜、河北张家口、山西离石和湖北通城、秭归等不同自然地理环境区的９２个土壤样，分别进行了其各项物理、化学特性的测定，和崩解、溅蚀、贯入试验，发现不同土类的试验结果与其理化性状之间存在规律性，它们是土壤抗蚀性的反映。文中还对不同土壤的抗蚀性大小进行了讨论。     

Laghi di Monticchio (Southern Italy,Region Basilicata): genesis of sediments—a geochemical study

The sedimentation record of Lago Grande di Monticchio (LGM) is one of the most prominent paleoclimatic archives in the non-glaciated areas of Europe. However, the modern lake system has never been the subject of intense limnological studies. On the basis of hydrochemical water profiles, detailed investigations of sediment short cores and in situ pore water profiles from the littoral to the profundal zone, we elucidate spatial variations of sediment genesis within the lake basin and the importance of various depth sections for the lake’s internal nutrient cycling. Sediments from the smaller meromictic Lago Piccolo di Montichio are discussed as a reference. Our study demonstrates: (i) distinctly higher sediment accumulation for the centre of the lake basin by focussing of the settling particle flux; (ii) decline of carbonate from the littoral to the profundal zones; (iii) non-synchronous change of calcite net-accumulation for various water depths; (iv) exceptionally high cation release from sediments covering the steeply inclining sector of the lake basin; (v) relatively constant dissolved silica concentrations in the pore waters (SiO₂ ∼42 mg/l) independent of water depth and sediment composition; (vi) influx of oxygen-bearing groundwater into the anoxic hypolimnion after heavy rainfall and the associated precipitation of Fe-oxihydroxides; (vii) higher release of NH₄ by anaerobic degradation of organic matter at a water depth of 23 m than for sediments at a maximum water depth of 32 m, whereby the latter reflects the importance of seasonal sediment re-oxidation for anaerobic degradation of organic debris; (viii) although seasonal re-oxidation of sediments from various water depths is quite different, Oxygen Index values of LGM sediments fall in a small range, which reflects rapid microbial consumption of seasonally re-generated easily bio-degradable organic molecules.     

Stratigraphy of the mid-Holocene black bands in Lakes Michigan and Huron: Evidence for possible basin-wide anoxia

The post-glacial history of the Great Lakes has involved several changes in lake levels throughout the latest Pleistocene and Holocene, resulting from the changing position of the retreating Laurentide ice sheet, outlet incision and isostatic rebound. The final lowering of lake levels occurred at approximately 7600 ¹⁴C yr BP, after which lake levels began to rise again to the Nipissing highstand at approximately 4700 ¹⁴C yr BP. During this time of rising lake levels, black bands of iron sulfide were being formed in the sediments of all five of the Great Lakes. These bands signify suboxic to anoxic conditions, at least within the sediments and possibly at the sediment-water interface, during the middle Holocene warm interval. During this interval, the climate was warmer and drier than present, possibly resulting in the occasional absence of seasonal turnover in the lakes. We examined a series of piston cores from northern Lakes Michigan and Huron and found that the black bands are correlatable among cores taken from within the same basin. The observation that the banding can be correlated suggests a basin-wide cause, near-bottom or sub-bottom anoxia in the northern Michigan and northern Huron sediments during the mid-Holocene warm period. The sedimentary and geochemical processes in the Great Lakes during the middle Holocene warm interval are good indicators of possible future scenarios for the lakes as a result of global warming, as 21^st-century temperatures are predicted to reach similar levels due to increased concentrations of greenhouse gases.     

Holocene Lake Level Fluctuations Recorded in the Sediment Compositionof Lake Juusa,Southeastern Estonia

The main aim of this study was to reconstruct the history of water level fluctuations of a small dimictic lake during the Holocene based on the lithological and geochemical composition of sediments. We studied lithological and geochemical parameters in sediment cores extracted along a transect through Lake Juusa in southeastern Estonia. Analysis revealed that LOI₅₅₀ and CaCO₃ content in the accumulated sediment are dependent on water depth. At depths greater than 3 m, the relationship between organic carbon and CaCO₃ is inverse, whereas no relationship exists at shallower depths. Lake-level changes are well depicted on the grain-size distribution profiles and macrofossil composition. An increase in the >‰315μm fraction appeared during the initial phases of water level fluctuations, followed by an increase in the 100–315μm fraction. The >‰36μm fraction dominated the silt fraction. Higher OC/N ratios in shallow water sediments reflect the dominance of macrophytes vegetation.     

Carbon cycling in Lake Erie during cultural eutrophication over the last century inferred from the stable carbon isotope composition of sediments

A ~106-cm sediment core from the eastern basin of Lake Erie was examined to investigate biogeochemical processes in this large lake during its cultural eutrophication over the last century. We measured stable carbon isotopes of total organic carbon and calcium carbonate (δ¹³C_TOC and d¹³ \textC_{\textCaCO 3} \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} ) as well as the concentrations of total organic carbon (TOC) and calcium carbonate (CaCO₃). δ¹³C_TOC and TOC show a strong positive correlation throughout the core and record changes in phytoplankton productivity and nutrient loading. CaCO₃ and TOC concentrations display a negative correlation throughout the core, suggesting that CaCO₃ concentrations are controlled primarily by decomposition of TOC in the hypolimnion and the sediments, although temperature and invasive mussels are also potential controlling factors. d¹³ \textC_{\textCaCO 3} \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} values show a positive correlation with δ¹³C_TOC between 1909 and 1969, indicating phytoplankton productivity was the primary control for d¹³ \textC_{\textCaCO 3} \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} values during eutrophication. However, a negative correlation between d¹³ \textC_{\textCaCO 3} \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} and δ¹³C_TOC from 1970 to 2002 suggests that these two proxies tracked different aspects of the carbon cycle in the lake in more recent times. The cause for the negative correlation is not yet known, but it is perhaps associated with temperature variations and seasonal differences in productivity.     

Historical changes in sediments of Pyramid Lake,Nevada, USA: consequences of changes in the water balance of a terminal desert lake

Sediment cores from the shallow and deep basins of Pyramid Lake, Nevada, revealed variations in composition with depth reflecting changes in lake level, river inflow, and lake productivity. Recent sediments from the period of historical record indicate: (1) CaCO₃ and organic content of sediment in the shallow basin decrease at lower lake level, (2) CaCO₃ content of deep basin sediments increases when lake level decreases rapidly, and (3) the inorganic P content of sediments increases with decreasing lake volume. Variations in sediment composition also indicate several periods for which productivity in Pyramid Lake may have been elevated over the past 1000 years. Our data provide strong evidence for increased productivity during the first half of the 20th Century, although the typical pattern for cultural eutrophication was not observed. The organic content of sediments also suggests periods of increased productivity in the lake prior to the discovery and development of the region by white settlers. Indeed, a broad peak in organic fractions during the 1800's originates as an increase starting around 1600. However, periods of changing organic content of sediments also correspond to periods when inflow to the lake was probably at extremes (e.g. drought or flood) indicating that fluctuations in river inflow may be an important factor affecting sediment composition in Pyramid Lake.     

Anthropogenic impacts recorded in recent sediments from Otisco Lake,New York,USA

Geochemical analysis of ²¹⁰Pb-dated sediment cores from Otisco Lake (New York) combined with analysis of recent land cover change in the watershed revealed the history of land use change, lake management, and industrial pollution since European settlement in the northeastern US. Clearance of forestland for agriculture characterized the early settlement era that was marked in the Otisco Lake sediments by a decline in organic carbon (OC) and OC:N ratios, which indicate a change in the sources of organic matter to the lake. Agricultural land use reached its greatest areal extent in the Otisco watershed around 1900, followed by field abandonment and reforestation over the last century. In the 1920s sediment accumulation rates began to increase coincident with residential development along the lake shore. Nitrogen and organic carbon, which are transported from the watershed, show increased fluxes to the lake in response to this change. Deposition of inorganic carbon increased markedly over a short period from the 1940s to the 1980s, which is consistent with enhanced mobilization of watershed calcium by increased acidic deposition, followed by alkalinization of the lake waters and calcite precipitation. An increase in copper content in the sediments reflects application, since 1942, of the algicide copper sulfate to the lake waters to control algal blooms. This CuSO₄ marker confirmed the accuracy of the ²¹⁰Pb chronology. Atmospheric mercury (Hg) fluxes to the lake were affected by increased sediment transport from the watershed. The maximum Hg peak in the sediment record, however, was dated to the early 1970s and coincides with maximum Hg emissions to the atmosphere in the Great Lakes region.     

Recently induced anoxia leading to the preservation of seasonal laminae in two NE-German lakes

The recent sediments of two lakes in the NE German lowland became seasonally laminated at different times. Anoxic bottom conditions resulted from a surplus of organic matter (OM), in the early stage indicated by irregularly laminated sediments comprising abundant iron-sulfide framboids. Their diagenetic formation predates the preservation of biochemical calcite varves. In the larger, deeper Lake Tiefer See near Klocksin, anoxia developed stepwise. A first anoxic pulse was contemporary with inflow narrowing by railway-dam construction and accumulation of OM. It was favored by a decrease of the intensity of lake circulation (turnover). Nutrients introduced from artificial fertilizer then increased the primary production (diatoms) to the point of OM surplus and seasonal laminae formation started 40 years later in 1924. In the smaller, shallower Lake Tiefer See in the Uckermark, a massive pulse of iron sulfide was centered around 1960, seven years after installation of piped field drainage into the lake. Anoxia developed rapidly with the nutrients drained from a fertilized groundwater catchment that is 10 times larger than the surface catchment, while surface erosion was reduced. Reducing bottom conditions became regular and the seasonal lamination was preserved after 1967. Morphological criteria to screen lakes for varved sediments should include reductions of natural lake inflow and catchment increase, such as by inflow of field drainage. Similar developments of increased nutrient input or intensity decrease of lake circulation may result from historical human activities but also from natural processes.     

Geochemical reconstruction of late Holocene drainage and mixing in Kluane Lake,Yukon Territory

The level of Kluane Lake in southwest Yukon Territory, Canada, has fluctuated tens of metres during the late Holocene. Contributions of sediment from different watersheds in the basin over the past 5,000 years were inferred from the elemental geochemistry of Kluane Lake sediment cores. Elements associated with organic material and oxyhydroxides were used to reconstruct redox fluctuations in the hypolimnion of the lake. The data reveal complex relationships between climate and river discharge during the late Holocene. A period of influx of Duke River sediment coincides with a relatively warm climate around 1,300 years BP. Discharge of Slims River into Kluane Lake occurred when Kaskawulsh Glacier advanced to the present drainage divide separating flow to the Pacific Ocean via Kaskawulsh and Alsek rivers from flow to Bering Sea via tributaries of Yukon River. During periods when neither Duke nor Slims river discharged into Kluane Lake, the level of the lake was low and stable thermal stratification developed, with anoxic and eventually euxinic conditions in the hypolimnion.     

Porewater geochemistry and solute flux from bottom sediments,Devils Lake,North Dakota

Sediment cores were collected for pore-water analysis from the eastern end of Devils Lake, located in northeastern North Dakota, to determine diagenetic reactions occurring in surficial bottom sediments and to evaluate the impact of these reactions on chemical concentrations in the overlying lake water. Sediment pore waters are enriched in major ions and nutrients relative to lake water. The principal sources of major ions to pore water are saline sediments located in the upper 1 m of bottom sediment. The principal source of titration alkalinity and nutrients to pore water is microbial decomposition of sedimentary organic matter by sulfate reduction. Sediment pore waters in the eastern part of Devils Lake have higher major-ion concentrations and solute-flux rates than the sediment pore waters in the central part of the lake. In contrast, sediment pore waters in the central part of Devils Lake have significantly higher nutrient concentrations and solute-flux rates. Major-ion concentrations and solute-flux rates in sediment pore water increase from west to east. These trends indicate that bottom-sediment diagenetic processes are, in part, responsible for the observed concentration gradient in the lake. The higher nutrient concentrations and the higher nutrient diffusional-flux rates in Main Bay are the result of more labile sedimentary organic matter and the occurrence of sulfate reduction. Environmentally-reactive trace-metal concentrations (Cu, Pb, Zn, and Fe) in bottom sediments decrease from west to east with distance from the surface-water sources and with increasing surface-water salinity.     

Holocene lake-level changes and their reflection in the paleolimnological records of two lakes in northern Estonia

Sediment cores from two neighbouring lakes (Viitna Linajärv and Viitna Pikkjärv) in northern Estonia were studied to determine lake-level fluctuations during the Holocene and their impact on biogeochemical cycling. Organic matter and pollen records dated by radiocarbon and radiolead indicated a water level rise in both lakes during the early Holocene (c. 10 000–8000 BP). A regression followed around 7500 BP and several transgressions occurred during the latter half of the Holocene, c. 6500 and 3000 BP. Human impact during the last centuries has caused short-term lake-level fluctuations and accelerated sediment accumulation in the lakes. The differences in water depth led to variations in sediment formation. During 10 000–8000 BP (Preboreal and Boreal chronozones) mineral-rich sediments with coloured interlayers deposited in L. Linajärv. These sediments indicate intensive erosion from the catchment and oxygen-rich lake, which favoured precipitation of iron oxides and carbonates. Fluctuations in water depth, leaching of nutrients from catchment soils and climatic changes increased the trophy of L. Linajärv around 6000 BP. The subsequent accumulation of gyttja, the absence of CaCO₃ and the decrease in both the C/N ratio and phosphorus content in the sediments also indicate anoxic conditions in the hypolimnion. The similarity in the development of L. Linajärv and L. Pikkjärv and their proximity made it possible to discern the impact of water depths changes on biogeochemical cycling in lakes.     

Reconstruction of the recent history of a large deep prealpine lake (Lake Bourget,France) using subfossil chironomids,diatoms, and organic matter analysis: towards the definition of a lake-specific reference state

This paper presents the recent history of a large prealpine lake (Lake Bourget) using chironomids, diatoms and organic matter analysis, and deals with the ability of paleolimnological approach to define an ecological reference state for the lake in the sense of the European Framework Directive. The study at low resolution of subfossil chironomids in a 4-m-long core shows the remarkable stability over the last 2.5 kyrs of the profundal community dominated by a Micropsectra-association until the beginning of the twentieth century, when oxyphilous taxa disappeared. Focusing on this key recent period, a high resolution and multiproxy study of two short cores reveals a progressive evolution of the lake’s ecological state. Until AD 1880, Lake Bourget showed low organic matter content in the deep sediments (TOC less than 1%) and a well-oxygenated hypolimnion that allowed the development of a profundal oxyphilous chironomid fauna (Micropsectra-association). Diatom communities were characteristic of oligotrophic conditions. Around AD 1880, a slight increase in the TOC was the first sign of changes in lake conditions. This was followed by a first limited decline in oligotrophic diatom taxa and the disappearance of two oxyphilous chironomid taxa at the beginning of the twentieth century. The 1940s were a major turning point in recent lake history. Diatom assemblages and accumulation of well preserved planktonic organic matter in the sediment provide evidence of strong eutrophication. The absence of profundal chironomid communities reveals permanent hypolimnetic anoxia. From AD 1995 to 2006, the diatom assemblages suggest a reduction in nutrients, and a return to mesotrophic conditions, a result of improved wastewater management. However, no change in hypolimnion benthic conditions has been shown by either the organic matter or the subfossil chironomid profundal community. Our results emphasize the relevance of the paleolimnological approach for the assessment of reference conditions for modern lakes. Before AD 1900, the profundal Micropsectra-association and the Cyclotella dominated diatom community can be considered as the Lake Bourget reference community, which reflects the reference ecological state of the lake.     

Holocene records of carbon and hydrogen isotope ratios of organic matter in annually laminated sediments of Lake Korttajärvi, central Finland

An 11.6 m long continuous succession of annually laminated sediments from Lake Korttajärvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake Päijänne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ¹³C and another HCl-HF-digested organic fraction was analyzed for both δ¹³C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttajärvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ¹³C_HCl-HF values of organic matter from ?31.6 to $-29.2\permilleAn 11.6 m long continuous succession of annually laminated sediments from Lake Korttaj?rvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake P?ij?nne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ¹³C and another HCl-HF-digested organic fraction was analyzed for both δ¹³C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttaj?rvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ¹³C_HCl-HF values of organic matter from −31.6 to , followed by a subtle decrease to . The changes in pH and δ¹³C_HCl-HF are closely related (r = − 0.91, P < 0.01), and apparently reflect changing environmental conditions in the lake and in its catchment area. δD values show a marked shift to higher values during the early Holocene, which may be partly related to a climatic amelioration leading to the Holocene Climatic Optimum in 6000–2500 BC. The Medieval Warm Period in AD 980–1250 is associated with a local maximum in δD, lending support for a significant warming during that time.     

我国东部土壤有机碳的密度及转化的控制因素

根据第二次土壤普查资料，计算了我国东部土壤的有机密度和储量，并通过田间和室内试验的结果，分析了影响农田土壤中有机碳转化的因素。结果表明，我国东北地区土壤有机碳密度变幅为2．5－73．3kg C/m^2，平均值为10．5kg C/m^2，而在东南热带亚热带地区，剖面土壤有机碳密度变幅为3．9－16．7kg C/m^2，平均值为9．52％kg C/m^2。随着木质素含量和土壤粘粒含量的增加，植物物质的分速率下降，而土壤温度，pH和游离碳酸钙含量的增加促进了 植物物质的分解；淹水的水田中植物物质的分解速率通常低于旱地；土壤性质和有机物组成对植物物质分解的影响可以掩盖气候条件的影响，而土壤游离碳酸钙可以掩盖土壤质地的影响。