藏南扎西康铅锌多金属矿绢云母Ar-Ar年龄及其成矿意义

扎西康脉状铅锌多金属矿位于特提斯喜马拉雅东段中部,是该带内规模最大的多金属矿床,扎西康矿脉受控于数条南北向正断层,这些断层在青藏高原后碰撞伸展阶段形成。矿区发生了两次成矿事件,分别为铅锌成矿期和富锑成矿期,并且后期富锑成矿对早期铅锌成矿具有叠加改造作用。在后期富锑成矿期中方解石-黄铁矿阶段发现了与闪锌矿、黄铁矿等矿物共生的绢云母。本文采用Ar-Ar同位素测年方法对该绢云母进行了测试分析,获得绢云母的坪年龄为12.28±0.45 Ma,对应的等时线年龄为11.7±3.1 Ma。两个年龄在误差范围内相等,表明该绢云母的Ar-Ar年龄具有地质意义,代表了绢云母的形成年龄。该Ar-Ar年龄指示了扎西康富锑成矿期发生于12Ma左右。特提斯喜马拉雅成矿带在主碰撞成矿阶段发育一期金(银)矿化事件,而扎西康绢云母Ar-Ar年龄表明后碰撞阶段矿化事件可以持续到12Ma。由于矿体发育于南北向断裂之中,因此,暗示了扎西康地区NS向正断层系统发育时间早于12Ma。早期铅锌硫化物成矿期矿石普遍破碎,说明受到构造挤压作用影响,而富锑成矿期矿石表现为脉状充填,并无构造挤压破碎,可以推测12Ma后藏南NS向正断层系统可能处于持续伸展环境。     

藏南错那洞铍稀有多金属成矿时代:来自热液白云母Ar-Ar年龄的约束

特提斯喜马拉雅是继华南和新疆阿尔泰之后又一条新发现的大型稀有金属成矿带,其成矿时代受到广泛的关注。本文以代表性矿床错那洞铍稀有多金属矿床为研究对象,挑选出矽卡岩型矿化体中的热液白云母,利用Ar-Ar同位素定年的方式测定热液活动时间,以此限制成矿时代。结果显示错那洞穹窿矽卡岩型矿体中白云母Ar-Ar同位素坪年龄为14.21±0.22Ma,对应的~(40)Ar/~(36)Ar-~(39)Ar/~(36)Ar的等时线年龄为14.21±0.27Ma,与错那洞穹窿中具有高分异特征的白云母花岗岩浆侵位时间(～14Ma)一致,表明错那洞矽卡岩型铍稀有多金属矿床的成矿年龄为～14Ma,而与穹窿内高分异白云母花岗岩一致的年龄暗示了该高分异花岗岩为该期矽卡岩型稀有金属矿化的成矿母岩浆。     

喜马拉雅带片麻岩穹窿成矿作用——以扎西康矿集区错那洞穹窿为例

特提斯喜马拉雅发育与造山带平行的片麻岩穹窿构造带,其与喜马拉雅金锑、铅锌多金属、锡钨铍多金属矿具有密切的时空关系.西藏扎西康铅锌多金属矿集区是喜马拉雅造山带最具特色的矿集区,集中产出20余处不同规模的金锑、铅锌、锡钨铍多金属矿床.矿集区内矿床围绕错那洞穹窿呈规律性分布,体现为从穹窿核部向外依次分布铍钨锡稀有金属矿→铅锌多金属矿→金锑矿.这些矿床分布特征与区域1:5万区域水系沉积物分析结果一致,从错那洞片麻岩穹窿核部—淡色花岗岩内部及其接触带到外围表现为W、Sn、Bi、Rb等高温元素→Pb、Zn、Ag、Sb等中温元素→Au、Sb、Ag、Hg、As等中低温元素异常组合.错那洞穹窿形成于中新世,该时期伴有大量的淡色花岗岩(23～14 Ma)侵位,此时也迎来了扎西康矿集区"成矿大爆发"(21～12 Ma).矿集区内典型矿床的H-O同位素组成表明,各矿床均显示有岩浆热液不同程度的贡献.矿石矿物的Pb同位素特征表明,锡钨铍来自于淡色花岗岩,铅锌具有多源性,既可以来自于淡色花岗岩,亦可以来自于古老基底物质,而金锑主要来自于与幔源作用有关的基性岩及玄武岩.结合矿集区内矿床的时空分布特征、流体及物质来源特点,文章认为扎西康矿集区内多金属矿床形成是喜马拉雅带成穹作用引发的构造-岩浆-成矿事件,构成了受穹窿控制的金锑-铅锌-锡钨铍稀有多金属成矿系统.自中新世以来,喜马拉雅造山带处于伸展活动时期,发育多期次的淡色花岗岩深熔作用,并在错那洞侵位形成片麻岩穹窿.深熔淡色花岗岩具有较高的演化程度,演化后期出溶富集Be-W-Sn-Rb的岩浆流体.在岩浆侵位过程引发的高异常地热梯度作用下,岩浆流体向外扩散,在岩浆顶部形成伟晶岩型铍铷稀有金属矿,在岩体边部与大理岩交代形成矽卡岩型铍稀有多金属矿,在错那洞穹窿拆离断裂及近南北向张性断裂中形成锡石-硫化物脉型锡多金属矿.岩浆流体在向外渗流过程中,萃取各类地质体中的成矿元素,并与大气降水、地热循环水不同程度的混合,在外围的张扭性断裂中形成铅锌,在温度更低的压扭性断裂中形成金(锑)矿.     

西藏纳如松多隐爆角砾岩型铅锌矿床绢云母Ar-Ar定年及其地质意义

纳如松多铅锌矿床位于拉萨地块中部隆格尔-工布江达断隆带中段,为冈底斯铜矿带北侧铅锌银多金属成矿带的典型矿床之一。纳如松多铅锌矿床以发育隐爆角砾岩型和矽卡岩型铅锌矿化为特征。利用40Ar-39Ar同位素测年方法对纳如松多东矿段隐爆角砾岩型主矿体成矿阶段形成的绢云母进行了年龄测定,获得绢云母Ar-Ar坪年龄为(57.81±0.66)Ma,对应的正、反等时线年龄分别为(57.90±1.70)Ma、(57.70±0.77)Ma。所测坪年龄与正反等时线年龄具有很好的一致性,可以代表隐爆角砾岩型铅锌矿体的形成年龄。结合区域地质构造背景,纳如松多隐爆角砾岩型铅锌矿床形成于印度-亚洲大陆主碰撞时期。     

西藏南部错那洞矽卡岩型铍钨锡多金属矿体成矿母岩成岩时代及其地球化学特征

错那洞穹窿是北喜马拉雅片麻岩穹窿带(NHGD)中发现的新成员,并发育有超大型铍钨锡多金属成矿作用.错那洞矿床铍钨锡多金属矿体赋存于矽卡岩、断裂构造及(伟晶状)花岗岩中,以矽卡岩型矿体为主,形成矽卡岩型矿体的成矿母岩则为一套弱定向二云母花岗岩.针对弱定向二云母花岗岩开展了年代学及地球化学特征研究工作.年代学结果表明,弱定向二云母花岗岩锆石U-Pb年龄为16.5±0.3 Ma,为中新世淡色花岗岩浆活动,表明错那洞超大型铍钨锡多金属矿床形成于中新世,为喜马拉雅碰撞造山过程中伸展阶段的产物.地球化学结果表明,该套成矿弱定向二云母花岗岩具有富硅(73.36%~73.89%)、贫铁(0.96%~1.58%)、强过铝质的钙碱性花岗岩地球化学特征.其稀土元素总量较低,相对富集轻稀土元素,而相对亏损重稀土元素,具有明显负Eu异常,相对富集Rb、Th等大离子亲石元素,相对亏损Zr、Ti等高场强元素,地球化学特征综合显示其为一套高分异淡色花岗岩,可能为变泥质岩重融的产物,与藏南拆离系(STDS)的活动密切相关.      

粤北连平地区钨锡多金属矿床成矿时代研究

粤北连平地区钨锡多金属矿床类型主要为石英脉型.采用云母Ar-Ar法和石英包裹体Rb-Sr法.分别获得:锯板坑含钨锡石英脉中的云母Ar-Ar坪年龄为(139.2±1.5)Ma(等时线年龄为143.6±3.9 Ma,MSWD:0.30):鸡啼石含钨石英脉中石英包裹体Rb-Sr等时线年龄为(155.4±5.1)Ma(MSWD=2.1).结果表明该区存在燕山早期和燕山早晚过渡期两期钨锡多金属成矿作用,并且认为:(1)鸡啼石钨矿为南岭地区中生代大规模成岩成矿作用高峰期(150～160 Ma)的产物;(2)南岭地区140 Ma左右也有大型钨锡多金属矿的形成.这一成果为研究区域成矿规律,指导区域找矿提供了重要同位素年代学依据.     

Genesis of the Maka Pb-Zn-W deposit in southeastern Yunnan" Constraints from sphalerite Rb-Sr dating,cassiterite U-Pb dating and in -situ S,Pb isotopes of sulfideSCIEI北大核心CSCD

马卡铅锌钨矿床地处云南省马关县与麻栗坡县的南温河交界处,位于燕山晚期老君山复式花岗岩体北缘。野外地质调查发现,该矿床主要发育矽卡岩型、石英脉型铅锌矿化和萤石石英脉型白钨矿化,但它们的形成机制仍缺乏系统研究。本文通过闪锌矿Rb-Sr、锡石原位U-Pb同位素定年和硫化物原位S、Pb同位素分析,厘定了马卡矿床不同类型铅锌矿化年龄,并探讨了其成矿物质来源及成因机制。矽卡岩型和石英脉型铅锌矿石中闪锌矿分别获得了88.9±1.9Ma(MSWD=4.5)和85.18±0.72Ma(MSWD=1.2)的Rb-Sr等时线年龄,同时获得石英脉型铅锌矿石中锡石LA-ICP-MS U-Pb年龄为84.3±4.7Ma(MSWD=0.66)。结果指示锌、锡矿化时代为晚白垩世,矽卡岩型和石英脉型铅锌矿化分别与该区广泛出露的老君山花岗岩(-90Ma)和花岗斑岩年龄(80-86Ma)一致。矿石硫化物原位硫同位素测试结果显示,δ34S值范围为2.53‰-9.65‰,均值为4.7‰,与老君山花岗岩中硫化物硫同位素组成(4.07‰)相似,表明硫主要来源于老君山花岗岩,少部分源自沉积地层;原位铅同位素组成特征也表明矿石铅主要源自老君山花岗岩。综合研究认为,老君山花岗岩体南北缘地区具有相似的成矿地质条件。马卡矿床的形成主要与燕山晚期老君山复式花岗岩体有关,可能经历了与花岗岩有关的矽卡岩型矿化和与花岗斑岩有关的热液充填、交代成矿过程。     

西藏错那洞穹窿同构造矽卡岩特征及相关铍钨锡稀有金属矿化的成矿时代

错那洞穹窿位于北喜马拉雅片麻岩穹窿带（NHGD）的东段,是近年来新发现的穹窿构造。穹窿由内向外依次由核部、滑脱系和盖层三部分组成,错那洞铍钨锡稀有金属矿化主要赋存在穹窿滑脱系的矽卡岩和矽卡岩化大理岩中,矿体产在含石榴子石十字石云母片岩中,与强烈变形的淡色花岗岩或伟晶岩密切相关,部分矽卡岩矿物呈定向排列,具强烈的剪切特征;淡色花岗岩与矽卡岩的接触关系部分呈渐变接触,部分呈突变关系,表明矽卡岩与该期岩浆关系密切,矽卡岩与淡色花岗岩属于同构造的产物。本次研究获得错那洞穹窿滑脱系含石榴子石十字石云母片岩中黑云母Ar-Ar坪年龄为（16.6±0.3）Ma,反等时线年龄为（16.7±0.3）Ma,该年龄代表第二期由南向北伸展构造变形时间,即藏南拆离系（STDS）在错那洞穹窿的活动时间;含白云母的矽卡岩化大理岩中白云母Ar-Ar坪年龄为（16.9±0.2）Ma,与含石榴子石十字石云母片岩中黑云母Ar-Ar年龄一致,代表同构造矽卡岩的形成时间,也是错那洞铍钨锡稀有金属矿床的成矿时间。错那洞铍钨锡稀有金属矿床形成于由藏南拆离系强烈活动引起的伸展减薄构造背景,减压熔融形成的岩浆沿着构造通道上涌侵位,并与围岩交代反应形成同构造矽卡岩及其中的富铍钨锡矽卡岩型矿体。     

藏南地区错那洞钨锡多金属矿床地质特征及成因

前人尚未关注特提斯喜马拉雅铅锌金锑成矿带钨锡成矿问题.错那洞钨锡多金属矿床位于特提斯喜马拉雅东段,产于新发现的错那洞大型片麻岩穹隆构造之中.错那洞钨锡多金属矿床主要富集钨、锡、铍,伴生铜、铅、锌、铋、钼等,其矿化类型主要为矽卡岩型;此外,铍的矿化类型还有伟晶岩型.主要矿石矿物为白钨矿、锡石和硅铍石,含有少量的黄铜矿、方铅矿、闪锌矿、辉铋矿、辉钼矿等,翠砷铜铀矿、晶质铀矿和钍石的发现表明错那洞地区具铀矿成矿潜力.研究结果表明,错那洞钨锡多金属矿床可达到大型-超大型规模.较低的Zr含量、Zr/Hf和Nb/Ta比值表明错那洞大型片麻岩穹隆核部淡色花岗岩为高分异花岗岩;花岗岩具有富钛铁矿、贫磁铁矿特征,Fe₂O₃/FeO < 0.5,锆石Ce/Ce*平均值约为23,暗示错那洞淡色花岗岩为还原性花岗岩.具还原性的高分异花岗岩是错那洞钨锡多金属矿床形成的必要条件,而片麻岩穹隆构造是其空间分布的控制因素,由此认为错那洞钨锡多金属矿受片麻岩穹隆构造和淡色花岗岩的双重控制.      

藏南错那洞淡色花岗岩成因：来自全岩地球化学和锆石U-Pb年龄的约束

藏南错那洞穹隆位于喜马拉雅造山带东部,淡色花岗岩是其核部组成部分之一。对其中的弱定向二云母花岗岩和含石榴子石二云母花岗岩进行LA-ICP-MS锆石U-Pb定年,显示其结晶年龄分别为(20.6±0.3) Ma和(16.7±0.2) Ma,属于喜马拉雅中新世淡色花岗岩。错那洞含石榴子石二云母花岗岩和弱定向二云母花岗岩均具有富硅(w(SiO2)为71.6%~74.6%)、富铝(w(Al2O3)为14.5%~16.1%)、富钾(w(K2O)为4%~4.7%)及高铝饱和指数(A/CNK=1.16~1.22)的特征,属高钾钙碱性系列的强过铝质花岗岩,并且两类花岗岩都富集Rb、U、K、Pb,相对亏损Nb、Ta、Zr、Ti。但含石榴子石淡色花岗岩具有明显的Eu负异常(Eu/Eu*=0.29~0.46),而弱定向二云母花岗岩Eu的负异常相对较弱(Eu/Eu*=0.58~0.80)。弱定向二云母花岗岩的Rb/Sr值为2.4~3.5,Ba含量为(200~253)×10-6,TiO2含量相对较低,表明错那洞弱定向二云母花岗岩是在无水条件下由变泥质岩中的白云母脱水熔融而形成,并且弱定向二云母花岗岩的产生可能与藏南拆离系(STDS)启动造成的构造减压有关。含石榴子石二云母花岗岩的K/Rb、Zr/Hf、Nb/Ta、Y/Ho值呈现出非球粒陨石异常,稀土四分组效应和异常高的Rb/Sr值(18.6~22.2)表明错那洞含石榴子石二云母花岗岩是经过岩浆高度演化而形成的。高度演化的岩浆有利于W、Sn、Be等稀有金属成矿。错那洞含石榴子石二云母花岗岩与错那洞穹隆的W-Sn-Be矿具有相邻的空间位置,两者之间可能存在一定的成因联系;而错那洞弱定向二云母花岗岩与扎西康Pb-Zn矿床在时间上和空间上都具有一致性,两者之间很可能也存在一定的成因联系。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an     

PROSPECTING EXPLORATION

正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of