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1.
谢文泉  贾建亮  刘招君 《地质学报》2023,97(7):2363-2377
多环芳烃(PAHs)是古环境、古野火以及古气候的重要地质记录,本文通过气相色谱质谱法(GC- MS)研究了柴达木盆地北缘中侏罗统石门沟组煤中多环芳烃分布特征,检测出一系列二环至七环芳烃化合物,包括高等植物衍生多环芳烃(卡达烯、6- 异丙基- 1- 异己基- 2- 甲基萘、惹烯、西蒙内利烯以及二氢惹烯)和燃烧衍生多环芳烃(荧蒽、芘、苯并\[a\]蒽、、苯并荧蒽、苯并\[e\]芘、苯并\[a\]芘、茚并\[cd\]芘、苯并\[ghi\]苝和晕苯)等。这些多环芳烃的检出表明石门沟组煤沉积于具有显著陆源高等植物输入的微咸水湖沼环境,成熟度较低(平均随机反射率为056%)。石门沟组煤中高等植物衍生多环芳烃以极高的惹烯含量为特征,且存在较高丰度的西蒙内利烯和二氢惹烯,卡达烯丰度极低,反映出成煤期陆地植被类型以松柏类植物的针叶林为主,气候温暖湿润。同时,煤中丰富的燃烧衍生多环芳烃证实了柴达木盆地北缘中侏罗世存在广泛的陆地古野火,较高的大气氧气浓度(256%)可能是该时期野火频发的一个重要诱因。本次研究为柴达木盆地中侏罗世古野火事件的研究提供了重要的分子化石证据,也是对中侏罗世古环境和古气候研究的有益补充。  相似文献   

2.
The origin of perylene, a five-ring polycyclic aromatic hydrocarbon (PAH), in sediments has been a matter of constant debate and its formation mechanisms remain unclear. A perylene record in sediment was described and could support a clear link between perylene and terrigenous organic matter (OM) input. The distributions of PAHs, the variations of organic proxies such as the ratio of terrigenous to aquatic n-alkanes (TAR(HC)) and 5α(H)-stanols/Δ5-sterols ratio in sediments have been investigated. Sediments were sampled from a pond artificially created during the Middle Ages from a swampy area. In the period prior to the pond creation, for which high contributions of terrigenous OM were evidenced, perylene was found to be the predominant PAH. Furthermore, perylene content was shown to increase in response to the establishment of more reducing conditions. This result supports the common idea that the main source of perylene is natural and derives from biogenic precursors under reducing conditions. The creation of the pond in this wetland is marked by the deposition of a wood rich level characterized both by more oxygenated conditions and higher concentrations of perylene. These high concentrations could result from the introduction of high concentrations of biogenic precursors of perylene under oxidative conditions. Subsequently, the progressive burial of the woody level could have allowed the establishment of oxygen depleted conditions and the formation of perylene. These results validate the use of perylene as a paleoenvironmental marker of terrigenous sources but it must be carefully used as a marker for syn- or post-depositional oxygen depleted conditions in lacustrine environments.  相似文献   

3.
黑碳和燃烧源多环芳烃作为大火燃烧的产物有很强的化学惰性及生物惰性,能够在地层中长期稳定地保存,所以成为恢复古代大火历史的最常用指标。近年来世界各地二叠系—三叠系(P-Tr)界线地层中相继发现了黑碳(木炭等)和燃烧源多环芳烃等记录,特别是在煤山P-Tr界线地层,黑碳和燃烧源多环芳烃含量在生物灭绝线附近(25~26层)出现极高的峰值,据此首次明确地提出了P-Tr界线大火事件。P-Tr界线大火的规模、性质如何,与P-Tr界线生物灭绝有什么关系等,值得深入讨论和研究。大火事件发生在陆地上,通过其燃烧及排放的烟尘等,把陆地、大气和海洋密切联系起来,有利于通过系统的整体观来研究当时的气候环境变迁。因此,在回顾和总结P-Tr界线地层中的大火燃烧记录基础上,评述了大火事件与生物灭绝及相关地质事件和环境变化之间的联系,以期引起国内外专家学者的关注,为P-Tr界线生物灭绝及相关研究提供新的思路。  相似文献   

4.
Polynuclear aromatic hydrocarbons (PAHs) and black carbon (BC) in sediments are powerful tools in the identification of the combustion process throughout geologic history. In this study, combustion-derived PAHs and BC were carefully investigated in sediments from the Global Stratotype Section and Point of the Permian-Triassic (P/Tr) boundary in Meishan, China. Quantitative analyses of combustion-derived PAHs and BC demonstrate anomalously high concentrations in the boundary event beds that coincide with the mass extinction horizon. The prevalence of parent polynuclear aromatics (e.g., phenanthrene) in PAHs, together with non-metric multidimensional scaling analysis, confirms that the PAHs are mainly derived from vegetation burning instead of having a coal and/or oil origin. BC detected in sediment occurs in various forms from large irregular charcoal particles to fine aciniform soot, with an equivalent reflectance of up to 3.5%. The results strongly suggest that a wildfire occurred during the P/Tr boundary, which served as one of the possible triggers of mass extinction on land. The wildfire occurrence indicates that the O2 concentration of the atmosphere during (or before) the P/Tr mass extinction was probably >17%. The temporal coincidence of the mass extinction with intensive volcanic eruption, marine anoxia and wildfire events in the region of the Meishan section provides new insight into the mechanisms of the P/Tr biotic crisis. Our results show that wildfires could have played an important role in the collapse of the ecosystem in the Meishan P/Tr events.  相似文献   

5.
Concentrations and isotope compositions of polycyclic aromatic hydrocarbons (PAHs) were determined in natural soils of Southern Germany. In selected profiles perylene concentrations increased with soil depth when compared to the other PAH compounds present. However, its low solubility made vertical transport by seepage water unlikely. Therefore two mechanisms are discussed that could have caused the unusual distribution of perylene in these soils:
(a) Atmospheric deposition of combustion-derived (i.e. pyrogenic) perylene in the top-soil and
(b) in situ generation in the sub-soil of these specific terrestrial environments. This could have been caused by microbial activities or other catalytic processes yet unknown.
In order to distinguish between pyrogenic and natural generation compound-specific 13C/12C ratios (δ13C) were compared between perylene and other PAHs in samples from the top-soil and sub-soil. Despite successful clean-up of the extracts, low perylene concentrations and peak overlaps with benzo(e)pyrene and benzo(a)pyrene prevented determination of a unique δ13C value for perylene in the upper horizon. However, the δ13C value of perylene in the sub-soil was 5.7 permille more negative than other equal-mass PAHs (with m/z of 252) in the top-soil, which rather supports in situ generation of perylene in the sub-soil.  相似文献   

6.
Perylene formation in sediments of water bodies has been a topic of continual discussion and debate. We report the concentration and age (ca. 660 yr) profiles of perylene and other polycyclic aromatic hydrocarbons (PAHs) in a sediment core from Emerald Peak Lake, the largest high mountain lake in Taiwan. Perylene is dominant at all depths of the sediment (ranging from 60% to 98% of total PAHs), a feature not commonly found in other sediments. The concentration profile of perylene with sediment age fits a first order kinetic model, which might be an indication of a steady sedimentary environment.  相似文献   

7.
Pre-drift sediments of Madagascar (Early Permian-Middle Jurassic) have been studied palynologically. These studies resulted in a more precise dating of individual stratigraphic units and the recognition of minor and major breaks in the succession. Palynostratigraphic and physical evidence of unconformities have been used to subdivide the pre-drift sediments into depositional cycles and to infer rifting events. A comparison with equivalent strata of Mozambique, Tanzania, Kenya, Ethiopia and Somalia shows a general correspondence and provides additional information for the construction of a generalized framework for the East African/Madagascan region which demonstrates the relationships between rifting and sedimentation and elucidates the prehistory of the break-up of Gondwana into a western and eastern fragment during the Middle Jurassic. The predrift succession of East Africa/Madagascar can be subdivided into two major sequences, a Karoo sequence (cycles 1–5, Asselian-early Smithian) and a transitional sequence (cycles 6–9, Ladinian-early Bajocian). The two sequences are separeted by a late Scythian to Anisian hiatus which indicates extensive uplift and erosion before a major rifting event initiated the resumption of sedimentation in the Ladinian. This Middle Triassic event marks the transition from the intracratonic rift stage to the pericratonic basin stage and correlates with a significant event in the Pangaean history, the transition from final coalescence to initial dispersal. The onset of the southward drift of Madagascar is believed to have occurred about 60 Ma later near the Aalenian-Bajocian boundary, contemporaneous with or immediately after the deposition of syntectonic sediments of cycle 9.  相似文献   

8.
中侏罗世-早白垩世华北地台东部的北黄海盆地受古亚洲构造体制向滨太平洋构造体制转换的影响,其构造演化经历了伸展-反转挤压-伸展的转变.构造体制的差异不但表现在大地构造性质及其产生的地质效应上,也表现在盆地沉积特征、古生物及古气候等方面.本文以北黄海盆地东部坳陷X1井中侏罗统至下白垩统为研究对象,利用泥岩元素地球化学特征对古气候的指示,结合盆地沉积特征及古生物资料,对古气候演化展开研究.研究显示,中侏罗世-早白垩世X1井泥岩样品的Sr/Cu比值(2.12~34.10)、Sr/Ba比值(0.16~1.60)、Rb/Sr比值(0.13~1.23)、Fe2O3/FeO比值(0.22~11.10)、V/Cr比值(0.91~1.78)、V/Sc比值(4.89~8.33)、Ni/Co比值(1.14~3.85)、δU比值(0.50~0.84)和U/Th比值(0.11~0.24)的纵向变化反映古气候经历了温湿→整体湿润、短暂干热→干热的演化.沉积物经历了暗色细粒沉积物为主→灰色、灰色夹灰绿色、灰色与红褐色互层细粒沉积物为主→灰色粗粒沉积物和红褐色、灰黄色细粒沉积物为主的变化.古生物经历了喜湿植物丰富→喜热植物出现→喜热植物丰富的过程.结果表明,受古亚洲构造体制和滨太平洋构造体制的影响,华北地台向北漂移,北黄海盆地古气候经历了由中侏罗世-晚侏罗世早期以温湿气候为主,至晚侏罗世晚期-早白垩世早期整体相对湿润,出现短暂干热气候,到早白垩世中期-早白垩世晚期为干热气候的演化.北黄海盆地中侏罗世-早白垩世古气候由温湿向干热的转变正是对华北地台东部晚中生代两大构造体制转换的响应.   相似文献   

9.
位于辽西凌源市南部的牛营子-邓杖子地区侏罗系地质问题多年来困扰着地质学家。争论最多的构造形迹是一套平面上呈狭长矩形,以断层为界的近直立中元古界常州沟组石英岩,及局部长城系顶部地层。这套地层绵延35 km,呈北北东展布。其西界为近直立的大齐子断层(新命名断层)和大部分向东倒转的陡倾下侏罗统邓杖子组;东界为近直立的朱杖子断层(新命名断层)和西倾的中侏罗统郭家店组。前人的构造解释倾向于大齐子断层为邓杖子组一侧下降的陡倾正断层,朱杖子断层为郭家店组一侧下降的陡倾逆断层。文中不同意这样的解释,并发现有证据表明上述两个断层都形成于之前尚未识别出的侏罗纪构造事件时期。将大齐子断层解释为早侏罗世晚期-中侏罗世早期形成的一条向西逆冲的断层,沿着它使长城系推覆于邓杖子组之上,然后,该逆冲断层上、下盘地层共同卷入后期褶皱变形当中。朱杖子断层原本为正断层,形成于原来未识别出的中侏罗世伸展变形阶段,并构成了郭家店半地堑边界断层。朱杖子断层沿着向东倾斜的常州沟组石英岩与串岭沟组页岩的界面发育。随着断层的发育,位于常州沟组石英岩之上的串岭沟组及长城系上部地层发生拆离沉降并被埋藏在半地堑之下。随后,发生在中侏罗世晚期或晚侏罗世早期收缩构造变形,改造了邓杖子-常州沟-郭家店组构造组合的几何形态。本期改造导致以下结果:(1)朱杖子正断层发生反转成为逆断层;(2)蓟县系沿着杨杖子-瓦房店逆冲断层向东掩覆于断层围限的长城系地层及相邻侏罗系之上。同时,邓杖子组倾角加大并向东倒转。研究表明,辽西地区的侏罗纪构造演化过程远比原先所认为的要复杂。  相似文献   

10.
The comprehensive biomarker characteristics from previously undescribed Middle Jurassic clays of Poland are presented. The molecular composition of the organic matter (OM) derived from clays of Aalenian to Callovian age has not changed significantly through time. High relative concentrations of many biomarkers typical for terrestrial material suggest a distinct dominance of OM derived from land plants. Increasing concentrations of C29-diaster-13(17)-enes towards the northern part of the basin indicate an increase in terrestrial input. This terrestrial material would have originated from the enhanced transport of organic matter from land situated at the northern bank of the basin, i.e., the Fennoscandian Shield. The organic matter was deposited in an oxic to suboxic environment, as indicated by relatively low concentrations of C33–C35 homohopanes, moderate to high Pr/Ph ratio values, an absence of compounds characteristic for anoxia and water column stratification, such as isorenieratane, aryl isoprenoids and gammacerane, as well as common benthic fauna and burrows. δ18O measurements from calcitic rostra of belemnites suggest that the mean value of the Middle Jurassic sea-water temperature of the Polish Basin was 13.1 °C. It is suggested that this mirrored the temperature of the lower water column because belemnites are considered here to be necto-benthic. The organic matter from the Middle Jurassic basin of Poland is immature. This is clearly indicated by a large concentration of biomarkers with the biogenic configurations, such as ββ-hopanes, hop-13(18)-enes, hop-17(21)-enes, diasterenes and sterenes. The identification of preserved, unaltered biomolecules like ferruginol, 6,7-dehydroferruginol and sugiol in Protopodocarpoxylon wood samples from these sediments present particularly strong evidence for the presence of immature OM in the Middle Jurassic sediments. Moreover, the occurrence of these polar diterpenoids is important due to the fact that they are definitely the oldest known natural products detected in geological samples.  相似文献   

11.
The Kachchh basin is known world over for its rich occurrence of the Middle to Late Jurassic mollusks. The Middle Jurassic sediments in Kachchh range in age from Bajocian (possibly Aalenian) to Callovian. Amongst the Middle Jurassic benthic communities of Kachchh, the pholadomyoid bivalves are one of the dominant groups in both diversity and number. These are represented by 13 genera and 30 constituent species. Distribution of these bivalves was much affected by the evolutionary history of the basin which has been created due to inundation by Tethys sea owing to the opening of Arabian sea sometime in Middle Jurassic. By and large these fauna are typical of the southern Hemisphere and belonged to east African biochore of the Tethyan realm or to the so called Ethiopian faunal province. Analyzing the (palaeo-) autecological behavior of the studied pholadomyoid bivalves and their distribution pattern, an attempt has been made to ascertain the usefulness of these pholadomyoids in evaluating the Middle Jurassic paleobiogeography.  相似文献   

12.
The non-marine Qaidam Basin is a petroliferous basin in northwest China. The Tuanyushan area is located in the Saishiteng Depression in the northern Qaidam Basin. Coal and oil shales are widely developed in the Middle Jurassic Dameigou and Shimengou formations in this area where the sedimentary sequence and controls on coal accumulation have already been well documented. However, the geochemical characteristics of lacustrine fine-grained sediments, including lacustrine oil shales, in the shale member of the Shimengou Formation and the main controlling factors of the formation of the oil shales are ambiguous. This paper aims to reconstruct the lake evolution history during the Middle Jurassic period and reveal its influence on the formation of the oil shales in this area. Oil shales and fine-grained sediments were systematically sampled to determine their mineralogical and geochemical characteristics (major, trace and rare earth elements; stable carbon and oxygen isotopes). Based on lithological variations and total organic carbon (TOC) contents, a complete third-order sequence is identified and can be further divided into four system tracts (lowstand system tract, LST; transgressive system tract, TST; highstand system tract, HST and regressive system tract, RST) that correspond to four lake evolution stages (A–D). Changes in the lake level show an initial shallow lake, followed by a continuous upward deepening trend, followed by a shallowing trend. Shallow lake facies developed in the LST, TST and RST, whereas semi-deep to deep lake facies developed in the HST. Stable carbon and oxygen isotopes indicate that the Shimengou Lake was semi-closed to closed in the Middle Jurassic. Therefore, the water properties responded strongly to climate changes. According to elemental and mineralogical analyses, a moist climate prevailed, except during the early stages of the TST (stage B1) and HST (stage C1) when there was a semiarid climate. The semiarid climate influenced the water properties and detrital input and was the major controlling factor for the formation of the higher quality oil shales within a saline water environment. In comparison, under the moist climatic condition in the HST, the stable semi-deep to deep-water environment was the major controlling factor for the formation of lower quality oil shales within a fresh water environment.  相似文献   

13.
The Yan'an Formation of the Ordos Basin is a sequence of four members,consisting of siliciclastic sediments deposited in alluvial,lacustrine and mire settings during the Middle Jurassic.Samples collect...  相似文献   

14.
对鄂尔多斯盆地上古生界68口井110块流体包裹体样品的荧光观察,60口井75块样品的显微测温、测盐等系统分析结果表明,该区上古生界砂岩储层发生过6期热流体活动,均与油气成藏有关,并以第2~6期的天然气成藏为主.结合埋藏史分析可知,油气成藏分别发生在距今220~190 Ma(T3中期-J1中期)、190~150 Ma(J1中期-J2中期)、150~130 Ma(J2中期-J2末期)、130~113 Ma(J2末期-K1中早期)、113~98 Ma(K1中早期-K1中晚期)、98~72 Ma(K1中晚期-K1末期),并认为早侏罗世中期-中侏罗世末期、中侏罗世末期-早白垩世末期是鄂尔多斯盆地上古生界天然气的主要成藏时期.  相似文献   

15.
华南地块的地极移动曲线及其地质意义   总被引:12,自引:1,他引:12       下载免费PDF全文
林金录 《地质科学》1987,(4):306-315
结合最近获得的古地磁数据,作者重新计算编制了华南地块的地极移动曲线,进而讨论了华南和华北地块在早古生代的地理位置,二者最后拼合的时代,以及华南地块和欧亚大陆北部两条极移曲线之间的系统偏差等问题。  相似文献   

16.
Larger benthic foraminifera (LBF) show significant abundance and diversity in the Palaeogene carbonate sediments of Meghalaya, N-E India, but have previously received less attention from the palaeoenvironmental perspective. LBF are important contributors to recent as well as fossil shallow marine, tropical carbonate settings. They find wide application in biostratigraphy and palaeoenvironmental reconstructions. The larger foraminiferal turnover (LFT) during the Palaeocene-Eocene transition is very important with respect to their evolution in several parts of the world including the Eastern Tethys. The present microfacies analysis documents the status of LBF in the Middle Eocene sediments from the Prang Formation of the Sylhet Limestone Group in Meghalaya, N-E India. Five major facies types (MFTs)—miliolid grainstone-packstones, alveolinid-rotaliid grainstone-packstones, nummulitid-alveolinid grainstone-packstones, coralline algal-nummulitid packstone-wackestones and coralline algal wackestones have been recorded in the current study. Evaluation of the palaeoenvironmental parameters aids in understanding the seascape of this Eastern Tethyan domain. It is suggested that an oligotrophic nutrient regime supported the rapid evolution and dominance of the LBF. Most notable is the prolific augmentation in Alveolina and Nummulites populations. High surface water temperatures during the Late Palaeocene-Early Eocene global warming episode possibly persisted to a certain level during the Middle Eocene and continued to favour the larger foraminifera as the major carbonate producers instead of the vulnerable corals.  相似文献   

17.
鲁西南地区分布着近东西向大致平行排列的早第三纪盆地群。在蒙阴、莱芜盆地早第三纪沉积称为官庄组,在平邑盆地称为卞桥组。依据沉积物特征和沉积旋回都能分为下段、中段和上段。通过对哺乳动物、介形类、轮藻、腹足类和孢粉等化石的研究可确定中段的沉积时代为早始新世,通过对轮藻、介形类和哺乳类动物的研究能确定下段和上段分别为始新世早期和中期。在卞桥组中段和官庄组中段发现介形类Cypridea属,该属起源于晚侏罗世或早白垩世,在早白垩世繁盛,晚白垩世逐渐衰落,灭绝于晚古新世或早始新世,在早始新世沉积中的发现,是迄今在我国发现的最高层位。  相似文献   

18.
In this study the abundances of several polycyclic aromatic hydrocarbons (PAHs Table 1, I–XXI) have been measured throughout three Permian/Triassic (P/Tr) sections from Meishan (South China), Kap Stosch area (East Greenland) and Peace River Basin (Western Canada). Dibenzothiophene (I) and dibenzofuran (II) were found to decrease in abundance just before or shortly after the P/Tr transition in all three sections while perylene (III) was observed to increase in abundance at the onset of the main extinction horizon (bed 25) in Meishan. Perylene has been attributed to a wood degrading fungal source and, therefore, it seems possible these phenomena are related to the demise of land plants. Further, distinct patterns of various combustion-derived PAHs occurring in each section imply that forest fire events occurred within the Late Permian and Early Triassic. In the Meishan section high amounts of combustion-derived PAHs [pyrene (IV), fluoranthene (V), benzo[a]anthracene (VI), benzofluoranthenes (sum, i.e. VII), benzo[a]pyrene (VIII), benzo[e]pyrene (IX) and coronene (X)] occur within bed 25, also containing ash attributed to the fallout from massive volcanic eruptions in Siberia and/or China.  相似文献   

19.
Regional mapping (1:50,000) and U-Pb and K-Ar geochronology in the El Indio region refines the knowledge of the distribution, lithostratigraphy, and age of the sedimentary, volcanic, and intrusive rocks that comprise the regionally extensive Pastos Blancos Group which is equivalent to the Choiyoi Group of the Argentine Frontal Cordillera. The Pastos Blancos Group (which we elevate to Group status herein) includes at least two diachronous volcanic–sedimentary sequences: an older felsic volcanic and volcaniclastic unit, the Guanaco Sonso sequence, that is Permian in age, and a younger bimodal volcanic and volcaniclastic unit, the Los Tilos sequence that is Middle Triassic to Early Jurassic. Sedimentary rocks of the Los Tilos sequence are transitional upward into the overlying Early to Middle Jurassic shallow marine limestones of the Lautaro Formation.Intrusions that make up the regionally extensive Permian to Early Jurassic plutons of the Chollay and Elqui-Limarı́ batholiths that were previously mapped as a single plutonic association, the Ingaguás Complex, include in the El Indio region at least three discrete intrusive units. These include: Early Permian (280–270 Ma) biotite granites, Early to Middle Triassic (242–238 Ma) silica-rich leucocratic granites and rhyolitic porphyries that made up the bulk of the Chollay Batholith, and a younger Late Triassic–Early Jurassic unit (221–200 Ma) of mainly intrusive rhyolitic porphyries, extrusive domes, and subordinate mafic intrusions and both felsic and mafic dikes, which are coeval with volcanic rocks of the Los Tilos sequence.Our data show that latest Paleozoic to Early Jurassic intrusive, volcanic, and sedimentary rocks in the El Indio region of the High Andes of Chile between 29–30°S likely formed during extension driven processes after the cessation of Carboniferous–Early Permian subduction along the western edge of Gondwana. These processes began by Late Permian time, but instead of recording a single and protracted magmatic event, as has been previously suggested, rocks that belong to the Pastos Blancos Group and the Ingaguás Intrusive Complex record at least three discrete periods of silicic to bimodal magmatism which occurred during the Middle Permian to Early Jurassic interval.  相似文献   

20.
Apatite fission‐track analyses on samples from eastern Sardinia document a complex tectonic history, whose reconstruction is problematic because of the reactivation of faults and structures at different times from Jurassic to Miocene. The oldest ages (150–154 Ma) have been detected on the southern margin of the Gulf of Orosei and are related to the extensional tectonics that characterize the European passive margin during Early and Middle Jurassic times. Thermal modelling of these data allows reconstruction of the burial history of the Mesozoic basin and estimation of a sedimentary thickness of 2000 m. Part of these sediments was eroded during the following uplift, documented by mid‐Cretaceous fission‐track ages. A further exhumation episode of Eocene age has been revealed by fission‐track data on granite samples, and has been inferred to be related to the Alpine orogenic phase. This tectonic episode caused the exhumation of crustal blocks bound by faults that were finally reactivated during the Late Oligocene–Early Miocene.  相似文献   

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