Basin evolution,diagenesis and uranium mineralization in the Paleoproterozic Thelon Basin,Nunavut, Canada

The Paleoproterozoic (Statherian) Thelon Basin is located in the Churchill Province of the Canadian Shield, formed following the Trans‐Hudson Orogeny. Basin formation followed an interval of felsic volcanism and weathering of underlying bedrock. The diagenetic evolution of the Thelon lasted about one billion years and was punctuated by fluid movement influenced by tectonic events. Early quartz cements formed in well‐sorted, quartz‐rich facies during diagenetic stage 1; fluids in which these overgrowths formed had δ¹⁸O values near 0‰ (Vienna Standard Mean Ocean Water). Uranium‐rich apatite cement (P1) also formed during diagenetic stage 1 indicating that oxygenated, uranium‐bearing pore water was present in the basin early in its diagenetic history. Syntaxial quartz cement (Q1) formed in water with δ¹⁸O from ?4 to ?0.8‰ in diagenetic stage 2. Diagenetic stage 3 occurred when the Thelon Formation was at ca. 5 km depth, and was marked by extensive illitization, alteration of detrital grains, and uranium mineralization. Basin‐wide, illite crystallized at ～200 °C by fluids with δ¹⁸O values of 5–9‰ and δD values of ?60 to ?31‰, consistent with evolved basinal brines. Tectonism caused by the accretion of Nena at ca. 1600 Ma may have provided the mechanism for brine movement during deep burial. Diagenetic stage 4 is associated with fracturing and emplacement of mafic dikes at ca. 1300 Ma, quartz cement (Q3) in fractures and vugs, further illitization, and recrystallization of uraninite (U2). Q3 cements have fluid inclusions that suggest variable salinities, δ¹⁸O values of 1.5–9‰, and δD values of ?97 to ?83‰ for stage 4 brines. K‐feldspar and Mg‐chlorite formed during diagenetic stage 5 at ca. 1000 Ma in upper stratigraphic sequences, and in the west. These phases precipitated from low‐temperature, isotopically distinct fluids. Their distribution indicates that the basin hydrostratigraphy remained partitioned for >600 Ma.     

Hydrothermal fluid flow associated to the extensional evolution of the Adriatic rifted margin: Insights from the pre- to post-rift sedimentary sequence (SE Switzerland,N ITALY)

This paper investigates the hydrothermal fluid circulation that was linked to the extensional evolution of the Adriatic rifted margin during the Jurassic opening of the Alpine Tethys. Remnants of this rifted margin are spectacularly preserved in SE Switzerland and N Italy. Five study areas were chosen ranging from the former proximal to the most distal part of the margin. We demonstrate an intimate link between Jurassic extensional tectonics and fluid activity affecting the pre- to early post-rift sedimentary sequences. Nature, composition and origin of fluids are constrained by a multidisciplinary approach based on field observations and including geochemical (O-C, Sr, He isotopes, U-Pb datings, fluid inclusion microthermometry) and petrological methods. Several fluid-related diagenetic products and processes such as dolomitization, veining, hydraulic brecciation, and silicification can be recognized. It appears that different paleogeographic settings and different stratigraphic levels document distinct phases of fluid activity. The fluids reached temperatures of up to 150°C near paleo-seafloor. They were enriched in ¹⁸O, had high ⁸⁷Sr/⁸⁶Sr and low ³He/⁴He ratios, documenting a strong interaction between seawater and a granitic basement. Many lines of evidence point to the occurrence of over-pressured fluids and long-lasting fluid circulation due to fault-valve mechanisms and high thermal gradients. Two main stages with different fluid chemistry can be recognized: (1) a carbonate-rich stage that developed during the stretching phases and was linked to high-angle normal faulting, and (2) a silica-rich stage occurring during late rift exhumation of crustal and mantle rocks in the distal domains in the presence of detachment faults and high thermal gradients. This paper provides, for the first time, a large and robust characterization of fluid–rock interactions occurring during rifting along an almost complete section across a magma-poor rifted margin.     

Origin of the sedimentary deposits of the Naracoorte Caves, South Australia

The origin of the sediments located in the Naracoorte Caves (South Australia) was investigated via the analysis of strontium isotope ratios (⁸⁷Sr/⁸⁶Sr), elemental geochemistry, and mineralogy. Sedimentary deposits located in Robertson, Wet, Blanche and several other chambers in Victoria Cave are all variable mixes of fine sand and coarse silts, which display similar and consistent strontium isotope ratios (0.717–0.725). This suggests that over the 400 ka time frame that these deposits span there has been minimal variation in the source of the clastic sediments. Increased strontium concentrations for these cave sediments correspond with increasing silt content, yet there is no correlation between ⁸⁷Sr/⁸⁶Sr ratios and silt content. This implies that the silt-sized component of the sediments is the main contributor of strontium to the cave sediments. Comparisons of ⁸⁷Sr/⁸⁶Sr with regional surficial deposits show a significant correlation between the cave sediments (avg: 0.7228; n = 27), the fine silt lunettes of the Bool Lagoon area (avg: 0.7224; n = 4), the sandy A horizons of the Coonawarra Red Brown Earths (RBEs; avg: 0.726; n = 5), and Holocene age podsolic sand deposits (0.723). These data suggest that there has been substantial flux from this group of deposits to the caves, as would be expected considering prevailing winds. This relationship is further supported by a strong correlation between many trace elements, including Ti, Zr, Ce, and Y; however, variations in clay mineralogy suggest that the fine silt-dominated lunettes and Padthaway RBEs were not significant contributors to the cave deposits. Hence, the detritus entering the caves was more than likely from areas proximal to the cave entrance and was dominated by medium grain-sized materials. Major regional deposits, including the coarser-grained, calcite-rich Bridgewater Formation sands, basalts from the lower SE, Padthaway Horst granites, Gambier limestone, and metamorphics from the Adelaide geosyncline show minimal correlation in ⁸⁷Sr/⁸⁶Sr ratios, elemental geochemistry, and mineralogy with the cave sediments, and are discounted as significant sources. In comparison, ⁸⁷Sr/⁸⁶Sr ratios for the Coorong silty sands (0.717–0.724), Lower Murray sands (0.727–0.730), and the medium size silt component of the Murray–Darling River system (0.71–0.72), compare favourably with the cave sediments. This relationship is further supported by similarities in elemental chemistry and mineralogy. Thus, much of the strontium-rich silt that is now located in the Naracoorte Cave sediments likely originated from the Murray–Darling basin. Over time, this material has been transported to the SE of South Australia, where it mixed with the medium sand component of the regressive dune ridge sequence, locally derived organic matter, limestone fragments, and fossil material to produce the unique deposits that we see evident in many of the chambers of the Naracoorte Cave system today.     

Crustal‐scale fluid flow during the tectonic evolution of the Bighorn Basin (Wyoming,USA)

Stable isotope measurements (O, C, Sr), microthermometry and salinity measurements of fluid inclusions from different fracture populations in several anticlines of the Sevier‐Laramide Bighorn basin (Wyoming, USA) were used to unravel the palaeohydrological evolution. New data on the microstructural setting were used to complement previous studies and refine the fracture sequence at basin scale. The latter provides the framework and timing of fluid migration events across the basin during the Sevier and Laramide orogenic phases. Since the Sevier tectonic loading of the foreland basin until its later involvement into the Laramide thick‐skinned orogeny, three main fracture sets (out of seven) were found to have efficiently enhanced the hydraulic permeability of the sedimentary cover rocks. These pulses of fluid are attested by calcite crystals precipitated in veins from hydrothermal (T > 120 °C) radiogenic fluids derived from Cretaceous meteoric fluids that interacted with the Precambrian basement rocks. Between these events, vein calcite precipitated from formational fluids at chemical and thermal equilibrium with surrounding environment. At basin scale, the earliest hydrothermal pulse is documented in the western part of the basin during forebulge flexuring and the second one is documented in basement‐cored folds during folding. In addition to this East/West diachronic opening of the cover rocks to hydrothermal pulses probably controlled by the tectonic style, a decrease in ^87/86Sr values from West to East suggests a crustal‐scale partially squeegee‐type eastward fluid migration in both basement and cover rocks since the early phase of the Sevier contraction. The interpretation of palaeofluid system at basin scale also implies that joints developed under an extensional stress regime are better vertical drains than joints developed under strike‐slip regime and enabled migration of basement‐derived hydrothermal fluids.     

Fracturing and fluid‐flow during post‐rift subsidence in carbonates of the Jandaíra Formation,Potiguar Basin,NE Brazil

Pervasive fracture networks are common in many reservoir‐scale carbonate bodies even in the absence of large deformation and exert a major impact on their mechanical and flow behaviour. The Upper Cretaceous Jandaíra Formation is a few hundred meters thick succession of shallow water carbonates deposited during the early post‐rift stage of the Potiguar rift (NE Brazil). The Jandaíra Formation in the present onshore domain experienced <1.5 km thermal subsidence and, following Tertiary exhumation, forms outcrops over an area of >1000 km². The carbonates have a gentle, <5?, dip to the NE and are affected by few regional, low displacement faults or folds. Despite their simple tectonic history, carbonates display ubiquitous open fractures, sub‐vertical veins, and sub‐vertical as well as sub‐horizontal stylolites. Combining structural analysis, drone imaging, isotope studies and mathematical modelling, we reconstruct the fracturing history of the Jandaíra Formation during and following subsidence and analyse the impact fractures had on coeval fluid flow. We find that Jandaíra carbonates, fully cemented after early diagenesis, experienced negligible deformation during the first few hundreds of meters of subsidence but were pervasively fractured when they reached depths >400–500 m. Deformation was accommodated by a dense network of sub‐vertical mode I and hybrid fractures associated with sub‐vertical stylolites developed in a stress field characterised by a sub‐horizontal σ₁ and sub‐vertical σ₂. The development of a network of hybrid fractures, rarely reported in the literature, activated the circulation of waters charged in the mountainous region, flowing along the porous Açu sandstone underlying the Jandaíra carbonates and rising to the surface through the fractured carbonates. With persisting subsidence, carbonates reached depths of 800–900 m entering a depth interval characterised by a sub‐vertical σ₁. At this stage, sub‐horizontal stylolites developed liberating calcite which sealed the sub‐vertical open fractures transforming them in veins and preventing further flow. During Tertiary exhumation, several of the pre‐existing veins and stylolites opened and became longer, and new fractures were created typically with the same directions of the older features. The simplicity of our model suggests that most rocks in passive margin settings might have followed a similar evolution and thus display similar structures.     

Chemostratigraphic correlation of carbonate successions in the Gariep and Saldania Belts, Namibia and South Africa

ABSTRACT Inter‐ and intrabasinal correlation of Neoproterozoic carbonate successions and associated glaciogenic deposits from the Pan‐African Gariep Belt and the Kango inlier in the Saldania Belt (Namibia and South Africa) is proposed on the basis of new δ¹³C_Carb and ⁸⁷Sr/⁸⁶Sr_I data. Highly positive δ¹³C_Carb values (as much as + 8.65‰) and low ⁸⁷Sr/⁸⁶Sr_I ratios (0.7071–0.7077) were obtained on carbonate successions of the Hilda Subgroup between an older and a younger diamictite in the Port Nolloth Group (Gariep Belt). These results are in agreement with data elsewhere that suggest deposition between the global ～ 750 Ma Sturtian and ～ 580 Ma Marinoan glaciations. Considerably lower, positive δ¹³C_Carb values (up to + 1.01‰) and higher ⁸⁷Sr/⁸⁶Sr_I ratios (0.7082–0.7085) mark the carbonates (Bloeddrif Member, Holgat Formation) on top of the Numees Formation diamictite and support a correlation of this diamictite with the Marinoan glaciation. In the southern extension of the Gariep Belt, correlation of the Widouw Formation limestone (Gifberg Group) with the Bloeddrif Member carbonates is proposed based on similar isotopic characteristics. In the Kango inlier of the Saldania Belt, two carbonate‐bearing members exist in the Matjies River Formation. The lower one of these two (Nooitgedacht Member) compares well with the Hilda Subgroup, whereas the upper one (Kombuis Member) shows strong similarities to the Bloeddrif Member carbonates. This implies that all younger stratigraphic units of the Kango inlier are not correlatives of the Port Nolloth Group, as previously assumed, but syn‐ to post‐orogenic with respect to the 540–580 Ma Pan‐African orogeny.     

青海囊谦盆地始新世石膏层沉积环境研究

囊谦盆地出露有晚始新世贡觉组石膏—红色泥岩沉积旋回,对研究古气候演化和沉积环境提供了良好的素材。以往的研究仅限于膏盐地层海陆相判定,而对其形成过程未有报道。采集囊谦盆地的盐泉水、贡觉组第三段的石膏和碎屑沉积物样品,并分析锶同位素比值和孢粉组合特征。结果表明,囊谦盆地盐泉水和石膏~(87)Sr/~(86)Sr比值分布在0.708 53～0.708 98之间,且位于陆源水的比值范围内;红色碎屑层孢粉组合主要以麻黄—白刺—栎粉为主,其中干旱成分占到45%,主要以麻黄粉(30%)和白刺粉(13%)为主,指示了干旱的气候环境;裸子植物杉粉在红色泥岩中的含量有所波动,最高含量达到36%,平均含量为9%,指示气候干湿交替变化。综合Sr同位素分析和孢粉分析认为,在全球中纬度干旱的大背景下,囊谦盆地石膏层形成于相对干旱和相对湿润的气候环境交替变化的陆相环境。     

Impacts of Coal-Fired Power Plants on Trace Metals and Polycyclic Aromatic Hydrocarbons (PAHs) in Lake Sediments in Central Alberta, Canada

Trace metals and polycyclic aromatic hydrocarbons (PAH) were analyzed in sediment cores from three central Alberta lakes to determine the contributions of local coal-fired power plants to contaminant loadings. In Wabamun Lake, with four power plants built since 1950 within a 35-km radius, sediment concentrations of mercury, copper, lead, arsenic and selenium have increased by 1.2- to 4-fold. Trace metal enrichments were less pronounced in Lac Ste. Anne and Pigeon Lake, situated 20 km north and 70 km south of Wabamun Lake, respectively. Total Hg flux to Wabamun Lake sediments (21–32μg m⁻² yr⁻¹) has increased 6-fold since 1950, compared to 2- and 1.5-fold increases in Lac Ste. Anne and Pigeon Lake, respectively, since circa 1900. Total PAH flux to surface sediments was 730–1100μg m⁻² yr⁻¹ in Wabamun Lake, 290–420μg m⁻² yr⁻¹ in Lac Ste. Anne, and 140–240μg m⁻² yr⁻¹ in Pigeon Lake. Without adoption of pollution-abatement technology that compensates for increases in generating capacity, continued expansion of coal-burning industry in Alberta will result in increased contaminant deposition, primarily from local sources.     

Potential water sources for Late Quaternary Megalake Jilantai-Hetao,China, inferred from mollusk shell <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr ratios

Lake Jilantai-Hetao, a megalake, was formed some time before 60–50 ka, along the Great North Bend of the Yellow River. The basin is now dry, with most of the area covered by aeolian sand. We are investigating this profound hydrologic change using a number of research approaches. Paleoshorelines of this megalake are best preserved in the Jilantai area in the southwestern portion of the megalake basin. We collected aquatic mollusk shells from littoral sediments at different altitudes around Jilantai and measured their strontium isotope compositions. ⁸⁷Sr/⁸⁶Sr ratios in shell carbonates are different between the high lake phase (~1,080–1,050 m altitude) and the low lake phase (~1,044–1,030 m altitude), with a small shift in average strontium ratios to more radiogenic values during the low lake phase. Based on regional hydrology and physical geography, we conclude that water from the Yellow River was the dominant water source supplying this megalake. ⁸⁷Sr/⁸⁶Sr ratios of modern water samples suggest the Yellow River was the dominant water source during the high lake phase, but that the relative contribution of Yellow River water to the megalake was reduced, and that the relative contributions of local precipitation and groundwater increased, during the low lake phase.     

Structural controls on non fabric‐selective dolomitization within rift‐related basin‐bounding normal fault systems: Insights from the Hammam Faraun Fault,Gulf of Suez,Egypt

Fault‐controlled dolostone bodies have been described as potential hydrocarbon‐bearing reservoirs. Numerous case studies have described the shape and size of these often non fabric selective dolostone bodies within the vicinity of crustal‐scale lineaments, usually from Palaeozoic or Mesozoic carbonate platforms, which have undergone one or more phases of burial and exhumation. There has been little attention paid, however, to fault‐strike variability in dolostone distribution or the preferential localization of these bodies on particular faults. This study focuses on dolostone bodies adjacent to the Hammam Faraun Fault (HFF), Gulf of Suez. This crustal‐scale normal fault was activated in the Late Oligocene, coincident with the onset of extension within the Suez Rift. Dolomitization in the prerift Eocene Thebes Formation occurred in the immediate footwall of the HFF forming two massive, non facies selective dolostone bodies, ca. 500 m wide. Facies‐controlled tongues of dolostone on the margins of the massive dolostone bodies extend for up to 100 m. The geochemical signature of the dolostone bodies is consistent with replacement by Miocene seawater, contemporaneous with the rift climax and localization of strain along the HFF. A conceptual model of dolomitization from seawater that circulated within the HFF during the rift climax is presented. Seawater was either directly drawn down the HFF or circulated from the hanging wall basin via a permeable aquifer towards the HFF. The lateral extent of the massive dolostone bodies was controlled by pre‐existing HFF‐parallel fracture corridors on the outer margins of the damage zone of the fault. The behaviour of these fracture corridors alternated between acting as barriers to fluid flow before rupture and acting as flow conduits during or after rupture. Multiple phases of dolomitization and recrystallization during the ca. 10 Ma period in which dolomitization occurred led to mottled petrographical textures and wide‐ranging isotopic signatures. The localization of dolomitization on the HFF is interpreted to reflect its proximity to a rift accommodation zone which facilitated vertical fluid flow due to perturbed and enhanced stresses during fault interaction. It is possible that the presence of jogs along the strike of the fault further focused fluid flux. As such, it is suggested that the massive dolostones described in this study provide a window into the earliest stages of formation of fault‐controlled hydrothermal dolostone bodies, which could have occurred in other areas and subsequently been overprinted by more complex diagenetic and structural fabrics.     

Middle to late Holocene initiation of the annual flood pulse in Tonle Sap Lake,Cambodia

Tonle Sap Lake, Cambodia, possesses one of the most productive inland fisheries in the world and is a vital natural resource for the country. The lake is connected to the Mekong River via the Tonle Sap River. Flow in the Tonle Sap River reverses seasonally, with water exiting the lake in the dry season and entering the lake during the summer monsoon. This flood pulse drives the lake’s biological productivity. We used Sr, Nd, and Pb isotopes and elemental concentrations in lake sediment cores to track changes in the provenance of deposits in Tonle Sap Lake. We sought to determine when the lake first began to receive water and sediment input via the Mekong River, which initiated flood pulse processes. The transition from a non-pulsing lake to the Mekong-connected system is marked by shifts to values of ⁸⁷Sr/⁸⁶Sr, ε_Nd, and ²⁰⁷Pb/²⁰⁴Pb that are characteristic of Mekong River sediments. In addition, magnetic susceptibility increased and sediment elemental composition changed. Elemental (P) measures point to enhanced phosphorus loading and C/N and isotope ratios of bulk organic matter indicate a shift to greater relative contribution of organic material from aquatic versus terrestrial environments, coinciding with the initiation of flood pulse processes. On the basis of radiocarbon dating in two cores, we estimate the initiation of the annual flood pulse occurred between ~4,450 and 3,910 cal year BP.     

柴达木盆地中西部背斜构造深层卤水水化学特征与成因

柴达木盆地西部背斜构造深层卤水资源勘查和评价成果显示,第三系背斜构造赋存深层卤水,具有良好的资源成矿条件,且潜力大。采集柴达木盆地中西部(一里坪拗陷和三湖拗陷)9处背斜构造深层卤水,分析了其水化学特征与成因。结果表明,深层卤水矿化度一般低于150 g/L,水化学类型均为氯化物型;K⁺、Na⁺、Mg²⁺含量较低,不具找矿价值;而B₂O₃、Li⁺含量普遍高于评价指标,Br-、I-含量普遍高于综合评价指标,为主要成矿元素;卤水的元素特征系数和分布规律及微量离子组成揭示,深层卤水是大气降水溶滤盆地周缘岩浆岩和火山岩及火山热泉的补给后,汇入古近纪—新近纪湖盆经蒸发浓缩封存在地层中的沉积卤水。     

Burial and exhumation of the western border of the Ukrainian Shield (Podolia): a multi‐disciplinary approach

The Podolia region is located along the western border of the Eastern European Craton, which is also known as Ukrainian Shield. From the Ordovician to the Miocene, this area formed part of an epicontinental basin system. In order to investigate the effects of orogenic cycles occurring along the plate margin, a multi‐disciplinary approach was used in this study. Paleotemperature analysis and low‐temperature thermochronometry were combined with stratigraphic data to obtain a burial model for the Paleozoic succession exposed in the study area. Maximum burial for Silurian and Devonian rocks occurred during the Devonian and Early Carboniferous at depths of 4–5 km, as constrained by vitrinite reflectance and illite content in mixed illite‐smectite layers. Thermochronometric data indicate that exhumation through the 45–120 °C temperature range took place between the Late Triassic and the Early Jurassic, and that no significant burial occurred afterwards (temperatures characterising the stratigraphically lowermost units remaining below ca. 60 °C). These results point to a major exhumation event coeval with the Cimmerian orogenesis, which took place a few hundreds of kilometres away from the study area. On the other hand, no significant effect of the Alpine orogenesis was recorded, although the collisional front was located <100 km from the Podolia region. This work shows how paleothermal and thermochronometric analyses can be successfully integrated with stratigraphic data to reconstruct the burial history, and how the burial history of a basin located on a plate margin can, in some cases, be independent from the distance of the margin from the collisional fronts.     

Strontium isotopic geochemistry of the Devils Lake drainage system, North Dakota: a preliminary study and potential paleoclimatic implications

A series of water samples (precipitation, surface water and ground water) from the Devils Lake drainage basin in central North Dakota have been analyzed for their ¹⁸O and D and ⁸⁷Sr/⁸⁶Sr. The ¹⁸O and D of snow and most ground water samples fall near the meteoric water line, with the ground water being isotopically heavier than the snow, indicating that a portion of the recharge must come from non-winter precipitation events. One ground water and all the surface water samples fall below the meteoric water line, demonstrating extensive evaporation. The 87Sr/⁸⁶Sr ratio of the snow is more radiogenic than those of the ground water samples, indicating that the ground water has increased its ⁸⁶Sr content by the dissolution of mafic rock in the aquifer. Stump Lake has a much more radiogenic Sr isotopic ratio than the waters of Devils Lake suggesting a source of water different from that of Devils Lake. The East Stump Lake water, on the other hand, appears to be either a mix of Devils Lake and Stump Lake waters, or Devils Lake water diluted with precipitation.     

Rb–Sr,Sm–Nd,and Ar–Ar isotopic systematics of lherzolitic shergottite Yamato 000097

Isotopic analysis of the Martian lherzolitic shergottite Yamato 000097 yields a Rb–Sr age of 147 ± 28 Ma with an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.710490 ± 0.000072, a Sm–Nd age of 152 ± 13 Ma with an initial ɛ¹⁴³Nd-value of +11.7 ± 0.2, and a ³⁹Ar–⁴⁰Ar age of ∼260 Ma. The near concordance of these ages, in combination with the Rb–Sr and Sm–Nd initial isotopic signatures, suggests that Yamato 000097 crystallized from low Rb/Sr, light rare earth element depleted source materials ∼150 Ma ago. Although the obtained ³⁹Ar–⁴⁰Ar age is significantly higher than the Rb–Sr and Sm–Nd ages, Yamato 000097 shows little or no evidence of trapped Martian atmospheric ⁴⁰Ar. The trapped ⁴⁰Ar concentration of Yamato 000097 is similar to that of Zagami, suggesting that both basaltic and lherzolitic shergottites may have similarly inherited excess ⁴⁰Ar from their magmas.The Rb–Sr and Sm–Nd ages, and initial ⁸⁷Sr/⁸⁶Sr and ɛ¹⁴³Nd-values of Yamato 000097 and Yamato 793605 lie on the same isotopic ingrowth curves, suggesting that they came from very similar mantle sources. Allan Hills 77005 was also probably derived from the same source, but Lewis Cliff 88516 appears to be from a distinct but similar source. Yamato 000097 represents the most recent known magmatism from its source, and is the youngest Martian meteorite for which concordant Rb–Sr and Sm–Nd ages have been determined.     

The sedimentary record of the Issyk Kul basin,Kyrgyzstan: climatic and tectonic inferences

A broad array of new provenance and stable isotope data are presented from two magnetostratigraphically dated sections in the south‐eastern Issyk Kul basin of the Central Kyrgyz Tien Shan. The results presented here are discussed and interpreted for two plausible magnetostratigraphic age models. A combination of zircon U‐Pb provenance, paleocurrent and conglomerate clast count analyses is used to determine sediment provenance. This analysis reveals that the first coarse‐grained, syn‐tectonic sediments (Dzhety Oguz formation) were sourced from the nearby Terskey Range, supporting previous thermochronology‐based estimates of a ca. 25–20 Ma onset of deformation in the range. Climate variations are inferred using carbonate stable isotope (δ¹⁸O and δ¹³C) data from 53 samples collected in the two sections and are compared with the oxygen isotope compositions of modern water from 128 samples. Two key features are identified in the stable isotope data set derived from the sediments: (1) isotope values, in particular δ¹³C, decrease between ca. 26.0 and 23.6 or 25.6 and 21.0 Ma, and (2) the scatter of δ¹⁸O values increased significantly after ca. 22.6 or 16.9 Ma. The first feature is interpreted to reflect progressively wetter conditions. Because this feature slightly post‐dates the onset of deformation in the Terskey Range, we suggest that it has been caused by orographically enhanced precipitation, implying that surface uplift accompanied late Cenozoic deformation and rock uplift in the Terskey Range. The increased scatter could reflect variable moisture source or availability caused by global climate change following the onset of Miocene glaciations at ca. 22.6 Ma, or enhanced evaporation during the Mid‐Miocene climatic optimum at ca. 17–15 Ma.     

Unravelling the multi-stage burial history of the Swiss Molasse Basin: integration of apatite fission track, vitrinite reflectance and biomarker isomerisation analysis

A complex basin evolution was studied using various methods, including thermal constraints based on apatite fission‐track (AFT) analysis, vitrinite reflectance (VR) and biomarker isomerisation, in addition to a detailed analysis of the regional stratigraphic record and of the lithological properties. The study indicates that (1) given the substantial amount of data, the distinction and characterisation of successive stages of heating and burial in the same area are feasible, and (2) the three thermal indicators (AFT, VR and biomarkers) yield internally consistent thermal histories, which supports the validity of the underlying kinetic algorithms and their applicability to natural basins. All data pertaining to burial and thermal evolution were integrated in a basin model, which provides constraints on the thickness of eroded sections and on heat flow over geologic time. Three stages of basin evolution occurred in northern Switzerland. The Permo‐Carboniferous strike–slip basin was characterised by high geothermal gradients (80–100°C km^?1) and maximum temperature up to 160°C. After the erosion of a few hundreds of metres in the Permian, the post‐orogenic, epicontinental Mesozoic basin developed in Central Europe, with subsidence triggered by several stages of rifting. Geothermal gradients in northern Switzerland during Cretaceous burial were relatively high (35–40°C km^?1), and maximum temperature typically reached 75°C (top middle Jurassic) to 100°C (base Mesozoic). At least in the early Cretaceous, a stage of increased heat flow is needed to explain the observed maturity level. After erosion of 600–700 m of Cretaceous and late Jurassic strata during the Paleocene, the wedge‐shaped Molasse Foreland Basin developed. Geothermal gradients were low at this time (≤20°C km^?1). Maximum temperature of Miocene burial exceeded that of Cretaceous burial in proximal parts (<35 km from the Alpine front), but was lower in more distal parts (>45 km). Thus, maximum temperature as well as maximum burial depth ever reached in Mesozoic strata occurred at different times in different regions. Since the Miocene, 750–1050 m were eroded, a process that still continues in the proximal parts of the basin. Current average geothermal gradients in the uppermost 2500 m are elevated (32–47°C km^?1). They are due to a Quaternary increase of heat flow, most probably triggered by limited advective heat transport along Paleozoic faults in the crystalline basement.     

南极乔治王岛晚白垩世地幔源火山岩Nd、Sr同位素和微量元素证据

对乔治王岛上白垩统半三角组火山岩样品进行了 Rb- Sr同位素等时线年龄测定 ,所获结果为 71 .3 3± 0 .3 Ma。通过 εND(T) - 14 7Sm/14 4Nd,14 3 Nd/14 4Nd- 87Sr/86 Sr,87Sr/86 Sr- Sr和 87Sr/86 Sr- K2 O/(K2 O+Na2 O)的相关性研究表明 ,该火山岩物质主要来自亏损地幔 (DMM)源区 ,基本上未受到地壳物质混染。其中 6个样品的平均 Sm- Nd模式年龄 (TNd DM)为 443 .3± 2 0 .6 Ma,可能反映了在研究地区的岩浆源区化学分异事件的时代。微量元素的特点表明 ,半三角组样品属典型的钙碱性火山岩系列 ,与长城站地区第三系火山岩相类似 ,同属于岛弧火山活动的产物。     

Stable isotopes and trace elements in modern ostracod shells: implications for reconstructing past environments on the Tibetan Plateau,China

Stable isotopes and trace elements in ostracod shells have been used widely in paleolimnological investigations of past lake hydrochemistry and climate because they provide insights into past water balance and solute evolution of lakes. Regional differences in lake characteristics and species-specific element fractionation, however, do not permit generalization of results from other regions or ostracod species to the southern Tibetan Plateau, in part because most common taxa from the southern Tibetan Plateau are endemic to the area. This study evaluated relations between present-day environmental conditions and the geochemical composition of modern ostracod shells from the southern Tibetan Plateau, to assess the suitability of using shell chemistry to infer hydrological conditions. We studied nine lakes and their catchments, located along a west–east transect in the south-central part of the Tibetan Plateau. Stable oxygen and carbon isotope values and trace element concentrations in recent shells from the four most abundant ostracod species (Leucocytherella sinensis, ?Leucocythere dorsotuberosa, Limnocythere inopinata, Tonnacypris gyirongensis) were measured, together with hydrochemical properties of host waters at the time of sampling. Results revealed significant between-species differences in stable isotope fractionation and trace element incorporation into shell calcite. Stable oxygen and carbon isotope values of ostracod shells were correlated significantly with the stable isotope composition of the respective water body \( \left( {\updelta^{18} {\text{O}}_{{{\text{H}}_{ 2} {\text{O}}}} \,{\text{and }}\updelta^{13} {\text{C}}_{{{\text{H}}_{ 2} {\text{O}}}} } \right) \), reflecting salinity and productivity, respectively. Offsets between δ¹⁸O_shell and δ¹³C_shell and inorganic calcite, the latter representing isotopic equilibrium, suggest shell formation of T. gyirongensis during spring melt. L. sinensis reproduces throughout the monsoon season until September and shows several consecutive generations, and L. inopinata molts to the adult stage after the monsoon season in August/September. The influence of pore water δ¹³C was displayed by L. inopinata, suggesting shell calcification within the sediment. Mg/Ca_shell is primarily influenced by water Mg/Ca ratios and salinity and confirms the use of this shell ratio as a proxy for precipitation-evaporation balance and lake level. In addition, Sr/Ca and Ba/Ca can be used to infer changes in salinity, at least in closed-basin lakes with calcite saturation. Observed effects of water Sr/Ca and salinity on Sr/Ca incorporation are biased by the presence of aragonite precipitation in the lakes, which removes bioavailable Sr from the host water, resulting in low Sr/Ca_shell values. Changes in carbonate mineralogy affect the bioavailability of trace elements, a process that should be considered in paleoclimate reconstructions. Oxygen isotopes and Mg/Ca_shell ratios were unaffected by water temperature. Positive correlations among Fe/Ca, Mn/Ca and U/Ca in ostracod shells, and their negative correlation with δ¹³C, which reflects organic matter decay, show the potential to infer changes in redox conditions that can be used to reconstruct past oxygen supply to bottom waters and thus past water-circulation changes within lakes. The intensity of microbial activity, associated with organic matter decomposition, can be inferred from U/Ca ratios in ostracod shells. These findings highlight the value of fossil ostracod records in lake deposits for inferring paleoenvironmental conditions on the southern Tibetan Plateau.