桂西南早中生代酸性火山岩年代学和地球化学:对钦-杭结合带西南段构造演化的约束

出露于钦-杭结合带西南段的早中生代酸性火山岩,主要沿着桂西南十万大山中新生代盆地两侧分布。其中出露于盆地北西侧的上-中三叠统北泗组火山岩主要由长英质熔岩(玄武安山岩、英安岩和流纹岩)夹火山碎屑岩(主要为集块熔岩、角砾熔岩、凝灰熔岩、熔结角砾凝灰岩和熔结凝灰岩)等岩石组成,获得英安岩锆石 SHRIMP U-Pb谐和年龄为246±2Ma;而出露于盆地南东侧的三叠系板八组火山岩主要由流纹岩夹珍珠岩、凝灰熔岩、集块熔岩和流纹质凝灰岩组成,获得流纹岩锆石 SHRIMP U-Pb谐和年龄为250±2Ma。主量、微量元素及Sr-Nd同位素地球化学研究表明,这些火山岩属于典型的过铝质高钾钙碱性火山岩系,表现出富集大离子亲石元素(如K、U、Ba、Rb和Th)和轻稀土元素,而Nb、Ta、P和Ti 等高场强元素和重稀土元素明显亏损,并具有较高的锶同位素初始比值((⁸⁷Sr/⁸⁶Sr)_i=0.713929~0.722178)和较低的ε_Nd(t)值(-10.33~-9.02),反映其具有俯冲消减作用形成的岛弧型火山岩地球化学特征。结合本区存在有早古生代MORB型变质基性火山岩和二叠纪弧后扩张中心环境形成的E-MORB型玄武岩的资料表明,扬子板块和华夏板块结合带(称之为钦-杭结合带)西南段有古生代洋盆的存在,该洋盆的俯冲消减过程一直延续至中三叠世的印支运动导致扬子板块和华夏板块发生碰撞才终止。     

西藏谢通门县切琼地区典中组流纹岩锆石U-Pb年龄、Hf同位素及地球化学特征

西藏中拉萨地块切琼地区广泛发育的林子宗群火山岩被认为是印度大陆与亚洲大陆碰撞火山作用的响应,对于揭示大陆碰撞的时限和过程具有重要的意义。本文对区内流纹岩进行了LA-ICP-MS锆石U-Pb年龄、Hf同位素及全岩元素地球化学研究,结果显示:研究区流纹岩年龄为67.1±0.1 Ma,符合林子宗群典中组火山岩年龄范围。该流纹岩具有富Si、高K、低Ti、过铝质特征;富集轻稀土元素,亏损重稀土元素,(Gd/Yb)_N=0.57~1.16,普遍出现负Eu异常(δEu=0.05~0.08),相对富集大离子亲石元素(Pb、Rb、Th、U),亏损高场强元素(P、Ti),并且明显亏损Ba和Sr,属于高钾钙碱性过铝质系列,具有陆源弧火山岩的特点;锆石¹⁷⁶Hf/¹⁷⁷Hf值在0.282673~0.282804之间,_εHf(t)在?2.1~+2.3之间,平均为?0.6,t_2DM变化于875~1117 Ma之间。综合分析表明,切琼地区林子宗群典中组流纹岩形成于俯冲构造环境,源于古老地壳物质再循环,且混染了少量幔源物质。对比区域上相关矿床,结合切琼地区已发现矿点,表明切琼地区典中组火山岩具有一定寻找浅成低温热液型、矽卡岩型矿床的潜力。     

西昆仑东段苏巴什洋向北俯冲:来自早—中二叠世火山岩的证据

西昆仑东段苏巴什蛇绿构造混杂岩带南侧卡拉勒塔什群以大面积分布的酸性和中基性火山岩为特征,本次对卡拉勒塔什群弧火山岩代表性的岩石组合进行了LA-ICP-MS锆石U-Pb年龄、地球化学及锆石Lu-Hf同位素研究。研究结果表明,LA-ICP-MS锆石U-Pb测年获得酸性晶屑凝灰岩、蚀变玄武岩²⁰⁶Pb/²³⁸U加权平均年龄为(284.2±1.6) Ma和(262.6±2.0) Ma,表明研究区卡拉勒塔什群火山岩形成于早—中二叠世。卡拉勒塔什群火山岩具有富铝、钠、铁,富集大离子亲石元素K、Rb、Ba和亏损高场强元素Sr、Ta、Nb、Ti的地球化学特征。其中,基性火山岩属钙碱性-拉斑玄武岩系列,岩石稀土元素配分模式接近大洋拉斑玄武岩,Nd/Th和La/Nb比值为8.91~13.76和0.39~2.28,Lu-Hf同位素ε_Hf(t)值为-0.15~4.95,表现为地幔物质来源,但加入了地壳组分。酸性火山岩属于钙碱性系列,相对亏损P和Zr元素,Nd/Th和La/Nb比值为1.92~4.10和2.52~3.39,Lu-Hf同位素ε_Hf(t)值分别为0.94~3.78和8.26~12.45,二阶段模式年龄分别为1.07~1.25 Ga、0.51~0.78 Ga,表明酸性火山岩物质来源为古老地壳和新生地壳物质重熔后的混合物。卡拉勒塔什群总体地球化学特征表现为岛弧环境。卡拉勒塔什群岛弧火山岩与北侧苏巴什蛇绿构造混杂岩带在形成时代、空间分布以及基性岩地球化学特征均表现成对关系,与苏巴什蛇绿构造混杂岩带内发育的硫磺达坂砂岩组深水复理石建造共同构成造山带沟-弧-盆体系,表明苏巴什洋盆由南向北的俯冲极性,说明苏巴什蛇绿构造混杂岩形成于岛弧偏向于海沟的弧前盆地构造背景。     

俄罗斯极地乌拉尔硬玉岩成因矿物学研究

俯冲带是壳-幔物质循环的重要场所,硬玉岩可以记录这一循环过程。文中总结了俄罗斯极地乌拉尔硬玉岩的研究进展。硬玉岩呈脉状或透镜状产在蛇纹石化的方辉橄榄岩中,主要由硬玉和绿辉石组成。根据结构和颜色,硬玉可识别出两个世代。硬玉韵律环带发育,含有H₂O和CH₄流体包裹体,显示从流体中结晶的特征。硬玉岩中的锆石为热液锆石,锆石稀土元素中La_N/Yb_N=0.001~0.01,Lu_N/Gd_N=10~83,Ce/Ce^*=2.8~72,显示正异常,δEu=0.53~1.02,类似于岩浆锆石。锆石的¹⁷⁶Hf/¹⁷⁷Hf=0.282 708~0.283 017,ε_Hf(t)=+6~+17,类似于N-MORB的Hf同位素组成,锆石δ¹⁸O组成为5.03‰~6.04‰,平均δ¹⁸O为(5.45±0.11)‰,类似于岩浆热液和地幔的氧同位素组成。这可能反映了锆石是被俯冲带流体从途经火成岩中捕获的或者形成锆石的流体与寄主岩(方辉橄榄岩)达到了平衡。硬玉岩稀土元素配分模式近平坦或轻稀土元素略显富集,La_N/Yb_N比值为0.82~2.42,δEu为1.2~1.6,显示正异常,这与寄主岩稀土元素配分模式相似。富集Sr、Ba、Zr、Hf,Nb为负异常,与岛弧岩浆特征类似。(⁸⁷Sr/⁸⁶Sr)_t为0.703 400~0.703 519(t=368 Ma),变化较小,与古海水差别明显;ε_Nd(t)值为+0.77~+5.61,变化较大,与寄主岩(方辉橄榄岩)的Nd同位素组成类似,但不同于海水及沉积物的Nd同位素组成,表明硬玉岩的物质来源与寄主岩有明显继承关系,海水与沉积物的贡献不是主要的。矿物学和岩石学证据支持极地乌拉尔的硬玉岩主要是俯冲带流体与橄榄岩相互作用后并在其中结晶的产物。     

老挝南部帕莱通双峰式火山岩锆石U-Pb定年及岩石地球化学特征

老挝南部帕莱通（Phlaythong）矿区出露了一套双峰式火山岩组合,其基性端元为致密块状玄武岩,酸性端元为流纹岩。流纹岩的锆石SHRIMP U-Pb年龄为（229.0±2.0）Ma,属中-晚三叠世,代表双峰式火山岩形成时代。地球化学数据显示：玄武岩SiO₂质量分数均值为50.70%,富TiO₂、MgO、CaO和TFeO,具较低的全碱和P₂O₅,富集LILE(Sr、Rb、Ba、Th)和轻微亏损HFSE,轻稀土略微富集,Eu负异常不明显;流纹岩具有高的SiO₂（平均质量分数为76.33%）和全碱,富钾（w(K₂O）＞w(Na₂O)）,极低的TiO₂、MgO、CaO和TFeO,富Th、U和Zr,明显亏损Ta、Nb、Ba、Sr和Ti,轻稀土富集,显示明显的Eu负异常（δEu=0.31~0.82）特征。初步研究表明,玄武岩和流纹岩来自不同的岩浆源区,玄武岩由亏损的软流圈地幔受陆壳物质混染作用形成,流纹岩为壳源物质受幔源岩浆底侵加热之后熔融的产物。结合南海-印支地块构造演化特征,认为该双峰式火山岩形成于大陆板内裂谷环境。     

大兴安岭十八站—韩家园地区晚中生代火山岩年龄、地球化学特征及其构造意义

大兴安岭十八站—韩家园地区发育晚中生代基性-中酸性火山岩。选取粗面安山岩、粗面岩、流纹岩进行年代学和岩石地球化学研究。粗面安山岩LA-ICP-MS锆石U-Pb年龄为125.2±0.9 Ma,为早白垩世火山作用的产物。岩石地球化学特征表明,中酸性火山岩属于高钾钙碱性-钾玄岩系列。岩石稀土元素总量∑REE=121.42×10~(-6)~154.43×10~(-6),轻、重稀土元素分异明显(La/Yb)_N=19.25~31.98,在稀土元素配分图上显示右倾型,除一个流纹岩样品具显著负Eu异常外,多数样品无明显Eu负异常(δEu=0.45~0.90)。岩石具弱富集大离子亲石元素Ba、Sr,明显亏损高场强元素Nb、Ta、Ti的特征。结合区域资料,认为十八站—韩家园地区早白垩世中酸性火山岩形成于蒙古-鄂霍茨克洋闭合机制下后碰撞伸展背景。粗面安山岩、粗面岩和流纹岩系同源岩浆部分熔融与结晶分异作用的结果,岩浆来源于受俯冲流体交代的富集岩石圈地幔。     

内蒙古西乌旗罕乌拉地区白音高老组火山岩特征及其形成构造背景

大兴安岭中生代火山岩的成因和构造背景一直存在争议。内蒙古西乌旗地区发育大面积的晚中生代火山岩,是中国东部巨型火山岩带的重要组成部分。本文对西乌旗罕乌拉地区白音高老组火山岩开展了野外地质、岩石学、锆石U-Pb同位素年代学、地球化学研究,以便对其岩石成因和构造背景给予制约。白音高老组火山岩主要由流纹岩及流纹质火山碎屑岩等一套中酸性火山岩组成。采集其中的球粒流纹岩和英安斑岩进行LA-ICP-MS锆石UPb测年,测年锆石的CL图和Th/U值（0.34~1.25）指示其为岩浆成因锆石,测年结果分别为（140±0.8）Ma和（133±0.7）Ma,表明这套火山岩的形成时代为早白垩世早期。岩石地球化学研究表明,白音高老组火山岩属高钾钙碱性系列,具高硅、富碱、贫镁、钙,高FeO^T/MgO比值,低Mg^#值、Nb/Ta比值的特征;相对富集轻稀土元素,亏损重稀土元素;大部分样品富集LILE,而亏损Ba、Sr和HFSE,具A型花岗岩地球化学特征,形成于伸展构造背景,为地壳部分熔融的结果。结合区域中生代火山岩的空间展布特征,认为该火山岩形成应与蒙古—鄂霍茨克洋闭合碰撞后伸展和古太平洋板块的俯冲作用有关。     

阿勒泰南缘克朗盆地康布铁堡组流纹岩年代学、地球化学及岩石成因

阿勒泰南缘克朗盆地康布铁堡组火山岩广泛分布。为查明克朗盆地康布铁堡组形成时代、源区及构造背景,对其中流纹岩进行了年代学、地球化学和锆石Hf同位素分析。在流纹岩中分别获得(394±1)Ma、(402.72±0.92)Ma的LA-ICP-MS锆石U-Pb年龄。地球化学特征显示,其为与“I”型花岗岩有相似特征的弱过铝质流纹岩,高SiO₂(73.58%~82.54%)、中等Al₂O₃(9.74%~13.29%,平均11.91%)及全碱含量(Na₂O+K₂O=4.11%~10.55%),低CaO(0.08%~3.34%,平均0.88%)、MgO(0.03%~2.72%,平均1.04%)。富集轻稀土,分布图呈右倾型。富集Rb,Th,U等大离子亲石元素,亏损Ba,Nb,Ta,Sr,Ti等,显著负Eu异常,锆石Hf同位素εHf(t)值为6.21~11.08、4.16~11.08。总体显示,该流纹岩形成于与俯冲作用有关的陆缘弧环境,为幔源岩浆加热上覆地壳进而发生部分熔融而成。     

长江中下游宣城水东地区早白垩世酸性火山岩年代学、地球化学及岩石成因

位于长江中下游的宣城水东地区发育一套酸性火山岩,主要由流纹质角砾岩、流纹岩和珍珠岩组成。本文对该套火山岩进行了详细的锆石U-Pb年代学、主量元素、微量元素以及Nd-Hf同位素研究。LA-ICP MS锆石U-Pb定年结果显示3种岩性的火山岩年龄分别为133.2±0.8、133.4±0.8和131.5±0.9 Ma。主量元素组成上,这套酸性火山岩具高硅(72.51%~81.79%)、富钾(K_2O/Na_2O=2.04~14.93,平均6.72)、贫钙镁(Ca O=0.19%~1.57%,Mg O=0.06%~0.29%)的特征,属于弱过铝质(A/CNK=1.02~1.24)的高钾钙碱性-钾玄岩系列岩石。微量元素方面,轻重稀土元素分馏明显[(La/Yb)_N=5.43~9.17],具明显的负铕异常(Eu/Eu~*=0.44~0.60),富集大离子亲石元素(LILE)Rb、Th、K和Pb等,亏损Ba、Sr、Nb、P和Ti等元素,表现出壳源的特征。全岩Sr-Nd和锆石Hf同位素组成变化范围相对较小,(~(87)Sr/~(86)Sr)_i为0.707 3~0.708 8,εNd(t)值为-7.05~-5.56,εHf(t)为-8.6~-1.3。结合区域地质研究成果,认为宣城水东地区酸性火山岩可能是在约135 Ma古太平洋板块俯冲作用之后的伸展-拉伸环境下,由新元古代早期新生地壳重熔而成。     

大兴安岭南端芝瑞盆地流纹岩年代学、地球化学及岩石成因

芝瑞火山盆地位于大兴安岭南端内蒙古克什克腾旗境内,处于西拉木伦河-长春缝合带以南、赤峰-开源断裂带以北的辽源地块,盆地中的长英质火山岩系不整合于下二叠统大石寨组之上、新近系汉诺坝组玄武岩之下,并见有多处花岗斑岩侵入其中。SHRIMP锆石U-Pb年龄表明,盆地火山岩系中流纹岩锆石的~(206)Pb/~(238)U年龄为(156.9±1.7)Ma,属于晚侏罗世早期岩浆活动的产物。岩石地球化学资料表明,流纹岩具富SiO_2、K_2O和高FeO_T/MgO值,低Al_2O_3、CaO和MgO的特征,属于高钾钙碱性系列岩石,∑REE含量较高,轻重稀土分馏明显,具右倾的稀土分布模式,负Eu异常明显,具有Ga、Zr、Nb、Y含量高和Ba、Sr含量低的微量元素特征,相对富集Rb、Th、U、Pb、Zr、Hf,相对亏损Ba、Sr、P、Ti及Nb、Ta等元素,具有A型流纹岩和低Sr-Ba流纹岩的微量元素特征;在Nb-Y-3Ga和Rb/Nb-Y/Nb图解上显示拉张构造环境的A2型花岗岩的特征;具有较高的Sr初始比值((~(87)Sr/~(86)Sr)_i=0.706510~0.709821),较低的Nd初始比值(ε_(Nd)(t)=-6.32~-4.44)和相对较年轻的Nd模式年龄(1304~1457 Ma)及较低的Pb同位素组成((~(206)pb/~(204)pb)_t=17.15~17.80、(~(207)pb/~(204)pb)_t=15.41~15.48、(~(208)Pb/~(204)Pb)_t=37.38~37.63),在Sr-Nd同位素示踪图解和Pb同位素构造演化图解上流纹岩同时具有下地壳和富集地幔印记。元素、同位素地球化学示踪指示芝瑞流纹岩可能由起源于富集地幔的中元古代年轻下地壳的部分熔融形成,且在岩浆上升过程中经历了结晶分异作用。在(Yb+Ta)-Rb和(Y+Nb)-Rb图解上,芝瑞流纹岩均显示板内拉张构造环境,结合区域上分布的同时代火山岩及A型花岗岩类可以限定流纹岩形成于伸展构造背景,并可能与北部的蒙古-鄂霍茨克缝合带的演化有关。     

西藏纳木错早白垩世流纹岩锆石U-Pb年龄、地球化学及其构造意义

西藏纳木错流纹岩构造上处于北冈底斯南缘,地层角度不整合于中—晚侏罗世拉贡塘组之上,归属于卧荣沟组。其中流纹岩的LA-ICP-MS锆石U-Pb年龄为120~112 Ma,时代为早白垩世中期。岩石具高Si O2、富Al2O3和K2O,贫Ti O2、MgO、Ca O特征,A/CNK=0.94~1.91(平均1.16),属于高钾钙碱性-钾玄岩系列过铝质岩石。(La/Yb)N为1.49~11.08,δEu=0.12~0.55,球粒陨石标准化稀土元素分布模式显示为略右倾V字形。大离子亲石元素及高场强元素Rb、K、Th、Ta、Ce、Zr、Hf相对富集,Nb相对亏损,Ba、Sr、P、Ti强烈亏损,成岩岩浆源自地壳,可以与多尼组酸性火山岩对比。流纹岩具同碰撞型火山特征,不具传统岛弧环境特征,研究认为在早白垩世中期(120 Ma左右),北冈底斯发生了一次重大的构造事件,即班公湖—怒江新特提斯洋俯冲已经结束,冈底斯带与羌塘地块陆-陆碰撞开始,碰撞过程中下地壳增厚并部分发生熔融,纳木错流纹岩是碰撞后部分熔融的产物。     

Isotopic evidence for the origin of Cenozoic volcanic rocks in the Pinacate volcanic field, northwestern Mexico

Six volcanic rocks, reconnaissance samples representing most of the temporal and compositional variation in the Pinacate volcanic field of Sonora and Arizona, are characterized for major element and Nd---Sr isotopic compositions. The samples consist of basanite through trachyte of an early shield volcano, and alkali basalts and a tholeiite from later craters and cinder cones. With the exception of the trachyte sample, which has increased ⁸⁷Sr/⁸⁶Sr due to crustal effects, all ⁸⁷Sr/⁸⁶Sr values fall between 0.70312 and 0.70342, while ε_Nd values are all between + 5.0 and + 5.7. Clinopyroxene in a rare spinel-lherzolite nodule derived from the uppermost mantle beneath the field has ⁸⁷Sr/⁸⁶Sr of 0.70320 but ε_Nd of + 8.8, three ε_Nd units higher than the volcanic rocks. Both the volcanic rocks and the nodule record the presence of asthenospheric, rather than enriched lithospheric mantle beneath Pinacate. This is consistent with one or both of (a) proximity of Pinacate to the Gulf of California spreading center and (b) presence of similar asthenospheric mantle signatures in volcanic rocks over a wide contiguous area of the southwestern USA. We consider the comparison to other southwestern USA magma sources as the more relevant alternative, although a definite conclusion is not possible at this stage.     

Geochemical constraints on the origin of bimodal magmatism at the Okinawa Trough, an incipient back-arc basin

The magmatism at the axial zone of the middle Okinawa Trough, a young continental back-arc basin, comprises a bimodal basaltic–rhyolitic suite, accompanied by minor intermediate rocks. We report major and trace element and Sr–Nd isotopic data for the intermediate to silicic suites, to provide constraints on their petrogenesis. The rhyolites, recovered as lava and pumice, fall into three geochemical groups (type 1, 2, and 3 rhyolites). Type 1 rhyolites have ⁸⁷Sr/⁸⁶Sr (0.7040–0.7042) and ¹⁴³Nd/¹⁴⁴Nd (0.5128–0.5129) identical to those of associated basalts, and are characterized by highly fractionated REE patterns. Petrogenesis of type 1 rhyolites is explicable in terms of fractional crystallization of the associated basalt. In contrast, type 2 rhyolites and andesite have slightly higher ⁸⁷Sr/⁸⁶Sr (0.7044–0.7047) but similar ¹⁴³Nd/¹⁴⁴Nd (0.5128) compared to those of the basalts. The compositions of type 2 rhyolite and andesite can be explained by assimilation and fractional crystallization (AFC) processes of the basalt magma; quantitative analysis suggests assimilation/fractional crystallization (M_a/M_c) ratios of ≤0.05. Hybrid andesite generated by mixing of evolved basalt and type 1 rhyolite is also present. We emphasize that mechanical extension in this part of the Okinawa Trough involves gabbroic lower crust that resulted from fractionation of mantle-derived basaltic magmas. Type 3 rhyolite occurs only as pumice, which makes its derivation questionable. This rhyolite has major and trace element compositions and Sr–Nd isotopic ratios, which suggests that it may be derived from volcanic activity on the southern Ryukyu volcanic front, and arrived in the Okinawa Trough by drifting on the Kuroshio Current.     

Interrelations between coeval mafic and A-type silicic magmas from composite dykes in a bimodal suite of southern Israel, northernmost Arabian–Nubian Shield: Geochemical and isotope constraints

Late Neoproterozoic bimodal dyke suites are abundant in the Arabian–Nubian Shield. In southern Israel this suite includes dominant alkaline quartz porphyry dykes, rare mafic dykes, and numerous composite dykes with felsic interiors and mafic margins. The quartz porphyry chemically corresponds to A-type granite. Composite dykes with either abrupt or gradational contacts between the felsic and mafic rocks bear field, petrographic and chemical evidence for coexistence and mixing of basaltic and rhyolitic magmas. Mixing and formation of hybrid intermediate magmas commenced at depth and continued during emplacement of the dykes. Oxygen isotope ratios of alkali feldspar in quartz porphyry (13 to 15‰) and of plagioclase in trachydolerite (10–11‰) are much higher than their initial magmatic ratios predicted by equilibrium with unaltered quartz (8 to 9‰) and clinopyroxene (5.8‰). The elevation of δ¹⁸O in alkali feldspar and plagioclase, and extensive turbidization and sericitization call for post-magmatic low-temperature (≤ 100 °C) water–rock interaction. Hydrous alteration of alkali feldspar, the major carrier of Rb and Sr in the quartz–porphyry, also accounts for the highly variable and unusually high I(Sr) of 0.71253 to 0.73648.

The initial ¹⁴³Nd/¹⁴⁴Nd ratios, expressed by ε_Nd(T) values, are probably unaltered and show small variation in mafic and felsic rocks within a narrow range from + 1.4 to + 3.3. The Nd isotope signature suggests either a common mantle source for the mafic and silicic magmas or a juvenile crustal source for the felsic rocks (metamorphic rocks from the Elat area). However, oxygen isotope ratios of zircon in quartz porphyry [δ¹⁸O(Zrn) = 6.5 to 7.2‰] reveal significant crustal contribution to the rhyolite magma, suggesting that mafic and A-type silicic magmas are not co-genetic, although coeval. Comparison of ¹⁸O/¹⁶O ratios in zircon allows to distinguish two groups of A-type granites in the region: those with mantle-derived source, δ¹⁸O(Zrn) ranging from 5.5 to 5.8‰ (Timna and Katharina granitoids) and those with major contribution of the modified juvenile crustal component, δ¹⁸O(Zrn) varying from 6.5 to 7.2‰ (Elat quartz porphyry dykes and the Yehoshafat alkaline granite). This suggests that A-type silicic magmas in the northern ANS originated by alternative processes almost coevally.     

江西南部东坑盆地流纹岩地球化学特征及其地质意义

东坑盆地位于南岭构造带东段,其中的流纹岩为该带燕山期最早的“流纹岩—玄武岩”双峰式火山岩组合的酸性端元.主量元素、微量元素、Sr-Nd-Pb-O-Hf同位素研究表明,流纹岩富硅、钾,贫镁、钙、钛,属亚碱性弱过铝质岩石;稀土元素富集,轻重稀土分异和铕负异常明显,表现典型的M型稀土元素4分组效应,富集高场强元素Ta、Hf、Zr、Nb、Ce、Y和大离子亲石元素Rb、Th、U、Ba、Ga,亏损大离子亲石元素Sr,具有A型流纹岩和高Sr-Ba流纹岩的微量元素特征;(87Sr/86Sr)i较高,(206Pb/204Pb)i、(207Pb/204Pb)i和(208Pb/204Pb)i较低,εNd(t)、εHf(t)和δ18OV-SMOW较高,TDM2(Nd)和TDM2(Hf)较小.这些特征表明,东坑盆地流纹岩是拉张构造环境下源于新元古代亏损地幔和少量古老下地壳物质混合而成年轻下地壳部分熔融的产物,为早侏罗世早期南岭构造带东段处于拉张构造环境、地壳属正常厚度提供了岩石学证据.     

沂沭断裂带高桥盆地早白垩世火山岩的地球化学及岩石成因

沂沭断裂带内高桥盆地早白垩世火山岩SiO₂含量为51.97%～68.94%;由玄武粗安岩、 粗面岩和流纹岩组成;都属于碱性岩。岩石富集Rb、 Ba、 K等大离子亲石元素和轻稀土元素;相对亏损Nb、 Ta、 Ti等高场强元素和重稀土元素;并具有富集的Sr-Nd-Pb同位素组成。钾质粗面岩具有高稀土Cr、 Ni含量、 La/Yb、Sr/Y和Th/U高比值;这类似于华北克拉通东南缘早白垩世富集岩石圈来源的基性岩（如方城玄武岩、 沂南辉长岩）;其可能主要来源于富集岩石圈地幔部分熔融。与之相比;钠质玄武粗安岩具有低Cr、 Ni含量 、 ⁸⁷Sr/⁸⁶Sr（t）、 Th/U和高ε_Nd（t）值;表明它可能由岩石圈地幔熔体与软流圈物质混合而成。沂沭断裂带高桥盆地火山岩形成于岩石圈伸展背景下;沂沭断裂带的活动可能诱使软流圈物质的上涌;导致岩石圈地幔升温发生部分熔融;并为软流圈物质的上升提供了通道。     

西秦岭中—晚三叠世板块碰撞事件的记录:来自合作地区火山岩的锆石U-Pb年龄和地球化学证据

西秦岭造山带发育了大量印支期钙碱性花岗岩,其中在甘肃合作地区以早印支期形成的为主,并伴有少量中酸性火山岩浆活动。合作地区火山岩主要分布在德乌鲁、扎油沟口一带,整体以安山质晶屑熔岩、安山质熔岩为主,并含英安斑岩、英安岩、火山角砾岩、晶屑岩屑凝灰岩、杏仁状安山岩的中酸性火山岩组合。德乌鲁安山质晶屑熔岩锆石U-Pb测年结果为(237.7±1.9) Ma,扎油沟口安山质熔岩锆石U-Pb测年结果为(234.8±2.1) Ma,限定了其喷发时代为晚三叠世早期。岩石地球化学分析结果显示该区火山岩属于富钾、高铝、高镁钙碱性系列;Rb、Ba、Th、U、La、Ce、Sr元素强烈富集,Ti、Y、Yb等元素略显富集;稀土总量偏低,LREE/HREE值为6.79~17.15;δEu为0.76~0.86,略显负铕异常。以上结果指示火山岩物质源于富集地幔,成岩过程或成岩后有壳源物质的强烈混染。扬子板块与华北板块汇聚时期,其间小洋盆与微板块发生强烈的挤压、俯冲,在后碰撞松弛阶段,出现了强烈的壳幔物质交换和岩浆上升的现象。多次的碰撞挤压-后碰撞松弛运动,在研究区域形成了一系列晚三叠世不同时间段的火山岩。     

Origin and significance of the Permian high-K calc-alkaline magmatism in the central-eastern Southern Alps, Italy

The Atesina Volcanic District, the Monte Luco volcanics, and the Cima d'Asta, Bressanone-Chiusa, Ivigna, Monte Croce and Monte Sabion intrusions, in the central-eastern Southern Alps, form a wide calc-alkaline association of Permian age (ca. 280–260 Ma). The magmatism originated during a period of post-orogenic extensional/transtensional faulting which controlled the magma ascent and emplacement. The magmatic products are represented by a continuum spectrum of rock types ranging from basaltic andesites to rhyolites, and from gabbros to monzogranites, with preponderance of the acidic terms. They constitute a metaluminous to weakly peraluminous series showing mineralogical, petrographic and chemical characteristics distinctive of the high-K calc-alkaline suites. In the MORB-normalized trace element diagrams, the most primitive volcanic and plutonic rocks (basaltic andesites and gabbros with Mg No.=66 to 70; Ni=25 to 83 ppm; Cr=248 to 679 ppm) show LILE and LREE enriched patterns with troughs at Nb–Ta and Ti, a distinctive feature of subduction-related magmas. Field, petrographic, geochemical and isotopic evidence (initial ⁸⁷Sr/⁸⁶Sr ratios from 0.7057 to 0.7114; ε_Nd values from −2.7 to −7.4; ∂¹⁸O values between 7.6 and 9.5‰) support a hybrid nature for both volcanic and plutonic rocks, originating through complex interactions between mantle-derived magmas and crustal materials. Only the scanty andalusite–cordierite and orthopyroxene–cordierite bearing peraluminous granites in the Cima d'Asta and Bressanone-Chiusa intrusive complexes can be interpreted as purely crustal melts (initial ⁸⁷Sr/⁸⁶Sr=0.7143–0.7167; initial ε_Nd values between −7.9 and −9.6, close to average composition of the granulitic metasedimentary crust from the Ivrea Zone in the western Southern Alps). Although the Permian magmatism shows geochemical characteristics similar to those of arc-related suites, palaeogeographic restorations, and geological and tectonic evidence, seem not to support any spatial and/or temporal connection with subduction processes. The magmatism is post-collisional and post-orogenic, and originated in a regime of lithospheric extension and attenuation affecting the whole domain of the European Hercynian belt. A change in the convergence direction between Gondwana and Laurasia, combined with the effects of gravitational collapse of the Hercynian chain, could have been the driving mechanism for lithosphere extension and thinning, as well as for upwelling of hot asthenosphere that caused thermal perturbation and magma generation. In the above context, the calc-alkaline affinity and the orogenic-like signature of the Permian magmatism might result from extensive contamination of basaltic magmas, likely derived from enriched lithospheric mantle source(s), with felsic crustal melts.