利用天然粉石英制作耐高温硅酸钙保温材料的研究

研究以天然粉石英为硅质原料,普通建筑用石灰为钙质原料生产硬硅钙石型硅酸钙保温材料的基本反应原理、反应过程和可用于工业化生产的工艺技术。用该项新技术所生产的硬硅钙石型硅酸钙保温材料,其性能达到美国和日本同类产品标准。     

一个浪控三角洲沉积的识别—江西“花屋石英砂岩”矿沉积条件的讨论

“花屋石英砂岩”矿位于江西省瑞昌县花屋地区。含矿地层为中志留统夏家桥组(S_2x)。夏家桥组为一套页岩—粉砂岩—砂岩的碎屑岩沉积组合,下部主要为砂岩,上部为砂质页岩、页岩夹粉砂岩,偶尔夹灰岩。含丰富的腕足类、三叶虫及腹足类化石。总厚在175m—344m间。其沉积环境主要是浅海内陆棚—海岸。夏家桥组地层中的砂质—粉砂质泥页岩,泥质粉砂岩及粉砂质细粒长石石英杂砂岩三种岩石都可以作为优质水泥硅质配套校正原料,     

用粉石英研制焦炉砖成功

用粉石英研制焦炉砖成功粉石英又称硅土。我国８０年代初期才开发此种新型硅质矿物原料，其工业应用领域正在不断拓宽。焦炉砖是砌筑焦炉的主要耐火材料，其用量约占焦炉砌筑材料总量的７５％。用在碳化室壁、储热室、燃烧室、斜道等重要部位。质量要求“三高”，即机械强...     

粉石英增白试验研究

粉石英增白试验研究田中凯，袁楚雄，刘奇，张明（武汉工业大学资源与环境工程系，武汉４３００７０）关键词粉石英，包覆方法，增白天然粉石英在我国是８０年代开发的一种非金属矿物原料，在江西和湖南资源丰富［１，２］。它只需经过擦洗、分级等处理就可获得３２５目或...     

某地平板玻璃原料用石英砂的提纯研究

某地石英矿砂通过磁选分离法、稀酸浸泡法处理后，矿砂不同程度地降低了铁、铝、钙镁的含量；采用磁选分离 稀酸浸泡法联合处理后，使该地石英砂的化学成分达到了优质的生产平板玻璃用硅质原料的国家标准。     

黔东北地区铁丝坳组—大塘坡组细粒沉积岩高精度层序地层特征和充填演化模式

南华系大塘坡组是一套优质烃源岩和潜在非常规油气储层，具有重要的地史研究和油气勘探意义，然而关于其沉积过程及高精度层序地层方面的研究还较为薄弱。作者以黔东北ZK513井岩心描述及薄片观察为主要研究手段，运用了新的细粒沉积物的分类标准，精细划分识别了以石英砂岩、含砾泥质砂岩、灰色泥岩、灰色含砾砂质泥岩、灰色泥质砂岩、黑色炭质–硅质砂质泥岩、黑色含砾炭质–硅质泥质砂岩、灰色石英砂岩、黑色锰质泥岩、黑色泥质粉砂岩、黑灰色泥质粉砂岩、灰黑色泥质粉砂岩、灰色粉砂质泥岩、灰白色泥岩为代表的14种岩相。并根据岩相组合特征识别了陆棚内盆地、深水陆棚、浅水陆棚3种沉积相，以及前滨、冰海浅水陆棚、陆棚内富锰盆地、陆棚内深水盆地、陆棚内盆地边缘、深水陆棚、浅水陆棚7种沉积亚相。据岩相、沉积相分析，认为陆棚内盆地相内LF9黑色锰质泥岩、LF10黑色泥质粉砂岩为烃源岩的有利相区和层段。通过对岩相、沉积相的研究，识别出5个三级层序SQ1—SQ5，以及4个三级层序界面SB1—SB4；在三级层序内部，根据岩相叠加样式并结合沉积构造定量化统计，总结出4种典型的准层序类型，根据准层序的叠加形式识别了三级层序内部若干准层序组...     

由钾长石合成中孔-微孔复合分子筛及其性能表征

本研究以富含硅、铝的天然矿物钾长石为主要原料,以十六烷基三甲基溴化铵(C16TMABr)为模板剂,在碱性条件下水热合成了铝硅质中孔-微孔复合分子筛.     

我国玻璃硅质原料的矿物及化学特征

1.我国玻璃硅质原料概况:我国玻璃硅质原料矿床按其成因可划分为如下类型:(1)正石英岩(沉积变质型):主要产于元古界的辽河群及青山组、钓鱼台;矿层呈层状夹于石英绢云母片岩、云母石英片岩中。厚层状,分布稳定,矿石都经不同程度的变质(压溶)作用,硅质高,铝质、铁质低,多属优质矿石,主要分布在长江以北地区,多为大型或特大型矿床。(2)石英砂岩(沉积型):主要生成于泥盆纪,少部份为震旦纪或寒武纪,即     

广东寒武纪岩石地层划分

广东的寒武系为浅类复理石碎屑岩建造，基本层序为砂岩－粉砂岩－板岩（或粉砂质板岩）的组合，夹有含黄铁矿或含磷硅质扁豆体，碳质板岩及灰岩透镜体，寒武系在桂湘赣、云开和东江３个分区，采用赣西南的岩石地质名称；下部的牛角河组以夹较多碳质板岩及含磷硅质扁豆体为特征；中部的高滩组，底以含砾岩或厚层长石石英砂岩为标志，顶部可见灰岩，泥灰岩透镜体或钙质泥岩；上部为水石组，底部以含砾砂岩为标志，往上以板岩为主，在梅     

川北晚泥盆世硅砂资源的地质特征及开发利用前景

川北晚泥盆世硅砂资源的发现,首次肯定了四川也有华南扬子准地台主要含矿层位——中、上泥盆统的硅质原料矿床,是四川省硅质原料找矿工作及找矿方向上的新突破。硅砂的含矿层出露于龙门山北段一个推覆体中,资源远景可观。由于石英砂岩矿石具质纯、弱固结的特性,易于加工提纯成优质硅砂,其矿石加工技术性能在华南同类矿床中名列前茅,开发利用前景良好。     

粉石英在蓄电池胶壳中的应用

本文着重介绍了粉石英的工艺矿物特性以及其在蓄电池胶壳中的应用效果,证明了粉石英用作蓄电池胶壳的填料,能够改善混炼工艺、提高产品质量、增加填充量、降低生产成本,是一种理想的橡胶填料。     

胶质芽孢杆菌－蒙脱石相互作用实验研究

利用硅酸盐细菌研究了微生物对硅酸盐矿物的分解作用。选取层状硅酸盐矿物蒙脱石在30℃与一株编号为3025的硅酸盐细菌B.mucilaginosus进行交互作用,并利用电感耦合等离子体发射光谱仪(ICP-AES)分析溶液中Si、Al、Mg离子的出溶量,利用X射线衍射(XRD)和显微红外光谱(Micro-FTIR)分析微生物作用后矿物物相和微结构变化。发现经硅酸盐细菌作用后,蒙脱石化学成分及晶体结构发生了细微变化,为微生物活动促进粘土矿物分解作用研究提供了实验和理论依据。     

3种硅酸盐矿物粉体对V79和A549细胞的遗传毒性

通过噻唑蓝(MTT)比色法、微核试验、单细胞凝胶电泳实验(SCGE),检测了3种硅酸盐矿物粉体(绢云母、石英、钠长石)对V79和A549细胞存活率、微核及DNA损伤的影响,比较和探讨了3种硅酸盐矿物粉体细胞遗传毒性的差异。研究结果表明,3种硅酸盐矿物粉体均不同程度抑制细胞增殖,诱发细胞染色体和DNA损伤,作用大小顺序均为绢云母石英钠长石,且对V79细胞的增殖抑制率和DNA损伤率均明显强于A549细胞,推测一定浓度范围内的硅酸盐矿物粉体对细胞遗传物质的稳定性可能存在影响,对人体可能具有遗传毒性。     

An unusual manganese silicate occurrence at the Hoskins mine,Grenfell district,New South Wales

Stratiform manganese silicate rocks overlie jasper and metabasah in the ?Middle Silurian Hoskins Formation at the Hoskins manganese mine near Grenfell, NSW. Two dominant mineral assemblages occur in the Mn silicate rocks: (1) a “reduced’ assemblage, probably gradational into underlying jasper, containing abundant rhodonite and/or tephroite, plus subordinate carbonates, quartz, hausmannite, spessartine and Ba minerals, and (2) a well‐laminated ‘oxidized’ assemblage rich in red Mn‐rich alkali pyroxene and amphibole, braunite, manganoan pectolite and minor Mn‐rich mica, alkali feldspars, carbonates, quartz and barite. Several Mn silicates implicitly contain trivalent Mn. The Mn silicate rocks are rich in Mn, Ba and Sr, and also contain anomalously high Co, Cu, As and W; oxidized assemblages are alkali‐rich. Bulk compositions and geological setting suggest a submarine volcanic exhalative origin for the precursors of the Mn silicate rocks and jasper. Metamorphism has occurred at upper greenschist facies with original high oxygen fugacity conditions in the exhalative sediments being largely reflected in the resulting assemblages. Although analogues of the reduced Mn silicate rocks are widespread in metamorphosed Mn deposits, equivalents of the oxidized assemblages appear to be particularly uncommon.     

Magmatic-Hydrothermal Evolution in the “Bottoms” of Porphyry Copper Systems: Evidence from Silicate Melt and Aqueous Fluid Inclusions in Granitoid Intrusions in the Gyeongsang Basin,South Korea

The Gyeongsang Basin of southeastern Korea contains numerous Cretaceous-early Tertiary (120–40 Ma) granitoid intrusions formed at a convergent plate boundary. The geotectonic setting is similar to that associated with porphyry-type mineralization elsewhere in the Circumpacific region. However, erosion has removed higher-level economic mineralization and exposed deeper levels of the granitoids, representing the poorly mineralized “bottoms” of porphyry copper systems. The intrusions of the Gyeongsang Basin thus provide a unique opportunity to advance our understanding of magmatic-hydrothermal evolution in the roots of porphyry-type systems, below the level of economic mineralization.

The physical and chemical environment during crystallization of the magmas has been characterized through studies of silicate melt and aqueous fluid inclusions in the granitoids. Two different types of silicate melt inclusions were recognized based on occurrence and room-temperature appearance. Type-I inclusions contain one or more crystalline phases and vapor; type-II inclusions consist of a cluster of small crystals, partially devitrified glass, and vapor. Petrographic and Raman analyses indicate that most silicate melt inclusions contain muscovite daughter crystals. Some also contain feldspar. Solidus temperatures of type-I inclusions in quartz phenocrysts range from ≈630to 650°C, whereas solidus temperatures of type-I and type-II inclusions in vug quartz are slightly higher (640–670°C). Liquidus temperatures span a much wider range compared to solidus temperatures, with maximum liquidus temperatures of melts in phenocrysts being slightly higher (≤930°C) than those in vug quartz (≤910°C).

Three types of aqueous inclusions were observed based on occurrence and room temperature phase proportions. Type-A inclusions are liquid rich and low to moderate in salinity; type-B inclusions are vapor rich and low in salinity; type-C inclusions are liquid rich and contain a halite daughter mineral. Some type- A inclusions with a salinity of approximately 25 wt% NaCl equivalent are spatially associated with silicate melt inclusions in phenocrysts, where they occur as three-dimensional clusters of tiny inclusions surrounding the silicate melt inclusion. Type-A inclusions also occur along fractures in quartz phenocrysts. Non-fracture-controlled type-C inclusions are rare in phenocryst quartz, but are common in vug quartz, where they are associated with silicate melt inclusions. Type-C inclusions that coexist with silicate melt inclusions generally homogenize by halite dissolution after the vapor bubble and show a wide range in salinity, from about 30 to >60 wt% NaCl equivalent. Coexisting halite-bearing (Type-C) and vapor-rich (Type-B) inclusions in phenocryst quartz suggest local immiscibility in the late-or post-magmatic fluid.

Pressure-temperature conditions during the final stages of magmatic-hydrothermal activity associated with the granitoid intrusions of the Gyeongsang Basin were approximately 630° to 670° C and 1.9 to 2.5 kbars. These results suggest that the granitoids do not contain economic porphyry coppertype mineralization because the magmas crystallized at high pressures (relative to typical porphyry copper magmas) and did not become saturated in water until a relatively late stage in the crystallization history. Failure to reach water saturation resulted in most of the copper in the original melt being sequestered as a trace component in earlier-crystallizing silicate and sulfide phases to produce anomalous but subeconomic copper grades. Furthermore, owing to the depth of emplacement, less energy was available to fracture the rocks when water did exsolve from the magma, and the pressure remained too high for aqueous fluid immiscibility to be an important metal-concentrating or depositing mechanism. Geological, petrographic, and geochemical characteristics suggest that the granitoid rocks of the Gyeongsang Basin represent ethroot zones of porphyry-type systems, and any higher-grade mineralization that may have been present higher in the system has since been removed by erosion.     

Raman Spectrum Study on Quartz Exsolution in Omphacite of Eclogite and Its Tectonic Significances

The studies on ultra-microstructue characteristics of quartz exsolution in eclogite and coesite in UHP eclogite of several localities are done with the appliance of laser Raman spectroscopy and Ustage. Research results show that the phase transformation of coesite-quartz in garnet and/or omphacite is a continuous process. Topological relationship is present between quartz exsolution in omphacite and its host mineral which shows orientations of two long axes of quartz exsolution parallel to (100) and (-101) of omphacite. At present, some scholars suggest that thequartz exsolution in omphacite of eclogite is the evidence of UHP metamorphism. However, temperature and pressure condition and the exsolution mechanism of oriented needlelike quartz in omphacite still remain undear. Tnerefore, further study should be enhanced on experimental research on exsolution mechanism of super-silicate clinopyroxene, which could provide experimental quantitative constraint on quartz exsolution as UHP indicator.     

甘肃省礼县上坝金矿床载金矿物特征及其矿床成因

礼县上坝金矿床是甘肃省近年来在南秦岭微板块发现的矿体规模较大、主要赋矿岩石为硅质岩、氧化带深度大、矿石可浸出性好、金成色高的岩金矿床。通过对上坝金矿床矿石组构、矿物共生组合及载金矿物特征研究发现：金矿物主要为自然金、银金矿、金银矿。载金矿物主要为石英。褐铁矿、粘土矿物和少量碳质矿物也含金。金的赋存形式为粒间金和裂隙金。金矿物的形成富集与硅化一硫化物交代充填作用关系密切,矿床成因为低温热液型金矿床。     

Experimental studies of granitoids from the Central and Southern Coast Ranges,California

Summary The mineral phase relationships have been determined in the presence of excess water to a water pressure of 10 kb for three quartz diorites, a granodiorite, and a quartz monzonite from the Central and Southern Coast Ranges of California. Water pressure-temperature curves were constructed to locate the beginning of melting and the disappearance of K-feldspar, quartz, biotite, plagioclase and hornblende. Results indicate that plagioclase is the silicate liquidus phase in all granitoids studied at low water pressures, while hornblende or biotite is the silicate liquidus phase at high water pressure. New data illustrate the potent effect of water pressure on magma composition at temperatures 50° to 100°C above the solidus. At a water pressure of 1 kb, magmas are granitic to quartz monzonitic, while at water pressures of 10 kb, they are granodioritic to quartz dioritic.

---

Des études expérimentales des granitoids des chaînes du centre et du sud de la côte de la Californie

Résumé On a determiné en présence d'un excès d'eau jusqu'à une pression d'eau de 10 kb les corrélations entre les phases minérales de trois diorites quartziques, une granodiorite, et une monzonite quartzique obtenues des chaînes du centre et du sud de la côte de la Californie. On a utilisé des courbes de pression d'eau contre température afin de fixer le commencement de fusion et la disparition de K-feldspath, quartz, biotite, plagioclase, et hornblende. Les résultats indiquent que plagioclase est la phase liquidus de silicate pour tous les granitoids examinés aux pressions d'eau basses, en même temps que soit hornblende, soit biotite la phase liquidus de silicate aux pressions d'eau hautes. Des données nouvelles manifestent l'effet puissant de la pression d'eau sur la composition de magma aux températures élevées 50° ou 100°C plus que le solidus. Avec une pression d'eau de 1 kb les magmas sont granitiques à quartz monzonitiques; avec une pression d'eau de 10 kb ils sont granodioritiques à quartz dioritiques.

---

---

With 8 Figures     

Immiscibility between silicate magmas and aqueous fluids: a melt inclusion pursuit into the magmatic-hydrothermal transition in the Omsukchan Granite (NE Russia)

Exsolution (unmixing) of the volatile element-rich phases from cooling and crystallising silicate magmas is critical for element transport from the Earth’s interior into the atmosphere, hydrosphere, crustal hydrothermal systems, and the formation of orthomagmatic ore deposits. Unmixing is an inherently fugitive phenomenon and melt inclusions (droplets of melt trapped by minerals) provide robust evidence of this process. In this study, melt inclusions in phenocrystic and miarolitic quartz were studied to better understand immiscibility in the final stages of cooling of, and volatile exsolution from, granitic magmas, using the tin-bearing Omsukchan Granite (NE Russia) as an example.

Primary magmatic inclusions in quartz phenocrysts demonstrate the coexistence of silicate melt and magma-derived Cl-rich fluids (brine and vapour), and emulsions of these, during crystallisation of the granite magma. Microthermometric experiments, in conjunction with PIXE and other analytical techniques, disclose extreme heterogeneity in the composition of the non-silicate phases, even in fluid globules within the same silicate melt inclusion. We suggest that the observed variability is a consequence of strong chemical heterogeneity in the residual silicate-melt/brine/vapour system on a local scale, owing to crystallisation, immiscibility and failure of individual phases to re-equilibrate. The possible evolution of non-silicate volatile magmatic phases into more typical “hydrothermal” chloride solutions was examined using inclusions in quartz from associated miarolitic cavities.