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1.
南窝铺铀矿床位于西拉木伦缝合带以南、康宝—围场—赤峰断裂带(华北北缘断裂带的一部分)以北的白乃庙加里东期岛弧带和华北古板块北缘海西期俯冲—碰撞带,属沽源—红山子铀成矿带北东段红山子—广兴铀成矿亚带的一个铀矿床,铀矿体赋存在额里图组安山岩—英安岩—流纹岩组合中。该组合中的英安岩SHRIMP锆石n(206Pb)/n(238U)加权平均年龄为268.1±2.5 Ma(N=15,MSWD=0.85),结合安山质角砾凝灰岩的锆石U-Pb年龄为277.1±0.9 Ma,指示额里图组安山岩—英安岩—流纹岩的地质时代属早二叠世(乌拉尔世)—中二叠世(瓜德鲁普世)早期;英安岩SiO2=65.49%~68.23%,K2O=1.83%~2.56%,Na2O=4.13%~5.01%,(K2O+Na2O)=5.96%~7.47%,K2O/Na2O=0.43~0.59,(FeO+Fe2O3)=3.13%~4.63%,MgO=1.25%~1.79%,在TAS图解上落入亚碱性系列英安岩区,在FAM图解上落入钙碱性系列范围,在SiO2—K2O图解上落入中钾钙碱性系列范围,在Na2O—K2O图解上落入I型花岗岩区;Al2O3=15.74%~16.77%,CaO=2.87%~3.59%,A/CNK=0.95~1.12(平均为1.04,<1.1),标准矿物刚玉(C)的含量为0~1.74%,平均为0.96%,指示源岩为I型岩浆岩;英安岩稀土元素总量低,富集轻稀土,Eu无明显负异常,ΣREE=76.5×10-6~95.4×10-6,(La/Yb)N=4.97~12.5(平均8.95),δEu=0.80~1.13(平均0.94),稀土配分模式为右倾型,与安第斯型钙碱性系列火山岩基本一致。英安岩明显富集大离子亲石元素Rb、Th、U、K、Sr等和亏损高场强元素Nb、Ta、P、Ti等,微量元素蛛网图与安第斯型钙碱性系列火山岩的形式一致,在Ce—SiO2、Al2O3—Ga图解上均落入I型花岗岩区,在Ta—Yb、Nb—Y构造环境判别图解上落入火山弧花岗岩区域(VAG)及同碰撞花岗岩(syn-COLG)交界处,在Rb—(Y+Nb)、Rb—(Yb+Ta)构造环境判别图解上落入火山弧花岗岩区域(VAG),指示英安岩形成于俯冲作用下的岛弧环境。南窝铺铀矿床英安岩地质时代、岩石系列和形成构造环境的确定,不仅证实了早二叠世—中二叠世早期额里图组是红山子—广兴铀成矿亚带一个新的赋矿层位,而且揭示了岛弧型安山岩—英安岩—流纹岩组合也赋存有与火山岩有关的热液型铀矿,为深入开展热液型铀矿成矿理论的研究和进一步扩大铀矿勘查范围提供了新的基础资料。  相似文献   

2.
塔河地区海西晚期火山岩地球化学特征及地质意义   总被引:1,自引:0,他引:1       下载免费PDF全文
崔泽宏  唐跃 《中国地质》2010,37(2):334-346
通过岩心观察,塔河地区海西晚期先后发育基性火山岩和中酸性火山岩两大类。两类火山岩具有不同地球化学组成:基性火山岩K2O+Na2O=3.49%~4.25%,K2O/Na2O=0.18~0.381,为钠质系列玄武岩,富集大离子亲石元素K、Rb、Ba、Th和高场强元素Nb、Ta、Ti、Zr、P,δEu≈1,无明显亏损;中酸性火山岩表现为高场强元素Nb、Ta、Sr、P、Ti亏损,大离子亲石元素K、Rb、Ba、Th较为富集,稀土元素δEu=0.43~0.661,铕具明显负异常特征,K2O+Na2O=6.86%~8.82%,K2O/Na2O=1.25~1.591,为钾玄或高钾钙碱性系列英安岩。强不相容元素Th/Ta、Nb/U比值说明,玄武岩与英安岩成因没有明显亲缘性,玄武岩来源于地幔,英安岩来源于地壳。结合邻区火成岩对比分析,塔河地区发育的玄武岩、英安岩分别与塔中地区玄武岩和南天山分区花岗岩具有相同的地球化学特征,构造判别图解表明,玄武岩形成于板内主裂陷期,英安岩、花岗岩形成于板块边缘岛弧构造环境,作为特殊古构造位置,塔河地区先后发育的玄武岩、英安岩为板内主裂陷盆地边缘和弧火山边缘相互耦合的产物。  相似文献   

3.
对松辽盆地南部早白垩世火石岭组和营城组火山岩进行的岩石地球化学研究表明,火石岭组火山岩主要以玄武质粗面安山岩和粗安岩为主,存在少量粗面英安岩,其Si O2=53.8%~68.6wt%、K2O+Na2O=7.70%~9.59%、Mg#=26.72~33.89,以富集轻稀土和大离子亲石元素(LILEs,如Rb、Ba、Th、U等),亏损重稀土和高场强元素(HFSEs,如Nb、Ta、Ti、P等)为特征,这些特征与俯冲带火山岩类似。营城组火山岩以流纹岩为主,存在少量的玄武质粗面安山岩、粗面安山岩和英安岩,基性端元具有低硅(Si O2=49.3%~56.6%)、低碱(K2O+Na2O=4.57%~6.60%)、富镁(Mg#=33.49~59.51)的特征,主要属于钙碱性系列,暗示其原始岩浆主要来源于地幔;酸性端元的Si O2=65.4%~74.9%,K2O+Na2O=3.23%~7.75%,低镁(Mg#=21.76~39.18)。营城组火山岩稀土配分型式呈右倾型,富集轻稀土和大离子亲石元素,亏损重稀土和高场强元素,与俯冲环境火山岩相似。其中,营城组流纹岩地球化学特征类似A型花岗岩,暗示形成于伸展环境。结合区域研究成果,认为松辽盆地南部早白垩世火山岩的形成与古太平洋板块向欧亚大陆之下的俯冲作用有关。火石岭组火山岩形成于活动大陆边缘环境,营城组火山岩的形成与岩石圈拆沉作用引发的伸展背景有关。  相似文献   

4.
八宿吉利地区寒武纪变质花岗岩位于曲扎湖-提卡一带,主要由变质二长花岗岩和变质花岗闪长岩组成。这一新发现对于认识和恢复原特提斯构造历史演化具有重要意义。锆石CL图像显示变质花岗岩锆石为岩浆成因。锆石LA-ICP-MS测年得出片理化变质二长花岗岩年龄为503.7±4.7Ma、变质花岗闪长岩年龄为494.7±3.4Ma,表明该岩体形成时代属于寒武纪。通过岩石地球化学分析,变质二长花岗岩SiO2含量介于69.87%~79.89%之间;变质花岗闪长岩SiO2含量介于66.63%~70.15%之间。前者Al2O3含量变化于12.36%~14.82%,Na2O含量为2.54%~7.16%,K2O含量为0.15%~5.95%,K2O/Na2O=0.02~2.34;后者Al2O3含量变化于14.66%~15.41%,Na2O含量为3.60%~5.63%,K2O含量为0.77%~2.78%,K2O/Na2O=0.14~0.77,属于钙碱性-碱性过铝质花岗岩。在侵入岩构造环境Rb-(Y+Nb)判别图解、Rb-(Yb+Ta)判别图解中,样品均落入“火山弧花岗岩”区域中,表明其形成于大陆边缘火山弧环境。结合锆石测年结果及区域地质背景分析,认为吉利地区变质花岗岩形成于冈瓦纳大陆裂离卡穷微陆块阶段,同时表明原特提斯洋形成最早时限可追溯至寒武纪。  相似文献   

5.
西准噶尔北部谢米斯台山西缘发育的下石炭统黑山头组主要为一套火山碎屑岩-中酸性火山熔岩组合。通过对黑山头组英安岩和安山岩进行岩石地球化学研究,不仅可以提高博什库尔—成吉斯火山弧的研究程度,更有助于对西准噶尔北部岩浆活动及构造演化提供新认识。研究发现二者均具有较高的SiO2(60.52%~71.58%)、全碱Na2O+K2O(6.88%~10.31%)、Al2O3(13.37%~16.31%),较低的P2O5(0.03%~0.27%)和TiO2(0.07%~1.89%)。英安岩属于碱性-亚碱性系列,安山岩属于钙碱性系列。岩石稀土元素总量较高(62.7×10-6~274×10-6),富集轻稀土元素((La/Yb)N=2.75~12.7),具有明显的负铕异常(δEu=0.247~0.501),富集大离子亲石元素(Rb,Ba,Th),相对弱亏损高场强元素(Nb,Ta,Ti),显示岛弧火山岩的地球化学特征。通过对其源区和构造环境分析发现,博什库尔—成吉斯火山弧形成于岛弧俯冲环境下,且在此过程中伴随有消减沉积物熔体的加入。  相似文献   

6.
丰宁大滩盆地位于西拉木伦河断裂带以南的华北古板块北缘,燕辽Mo-U-Ag-Pb-Zn多金属成矿带西段和沽源-红山 子铀成矿带西南段,空间上与赋存张麻井大型铀钼矿床的沽源盆地毗邻。大滩盆地张家口组粗面岩-流纹岩组合构成盆地 的主体,是热液型铀矿的主要围岩。粗面岩SHRIMP锆石U-Pb年龄为140.3 ± 1.4 Ma(2σ, MSWD=1.09),地质时代属于早 白垩世早期。具有较高的SiO2、K2O+Na2O含量,SiO2=61.6%~63.1%,K2O+ Na2O=9.28%~10.2%,在K2O-SiO2图解中投影点落在橄榄玄粗岩系列范围,TAS图解上都落在碱性系列粗面岩或粗面英安岩范围,结合标准矿物Q含量为12.9%~18.4% (小于20%),属典型的粗面岩。稀土元素含量高,富集轻稀土,铕负异常不明显,ΣREE=(279~318) ×10-6,δEu=0.77~ 0.88,稀土配分曲线图表现为右倾的轻稀土富集型,具高压型粗面岩的稀土元素特征;富集大离子亲石元素K、Rb、Ba、 Pb和高场强元素Zr、Y,亏损Nb、Ta、Sr、Ti元素。较低的Ti/Zr(8.40~14.72)、Nb/Ta(14.07~15.26) 比值,较高的Rb/Sr (0.95~1.60),具有高Sr-Ba 英安岩-流纹岩的微量元素的特征;具有较高的(87Sr/86Sr)i (0.7077~0.7096)、较低的εNd(t)(-12.09~ -10.67),较大的TDM2 (1911~1796 Ma),较低的(206Pb/204Pb)t (16.92~17.04)、(207Pb/204Pb)t (15.39~15.42) 和(208Pb/204Pb)t (37.58~37.67),在(87Sr/86Sr)i -t/Ga和(208Pb/204Pb) t-(206Pb/204Pb)t 图解上投影点位于下地壳和地幔之间,并靠近EMⅠ富集地幔,在εNd(t)-(87Sr/86Sr)i 图解上投影点位于EMⅠ富集地幔演化线上,与汉诺坝二辉麻粒岩包体的区域一致。可见,大滩盆地粗面岩的成因可用两阶段模式进行解释:古元古代源于EMⅠ富集地幔的岩浆与少量古老下地壳物质部分熔融产物混合形成年轻下地壳,早白垩世早期在加厚地壳背景下年轻下地壳部分熔融形成的岩浆喷出地表形成粗面岩。  相似文献   

7.
杨莉  陈文  张斌  尹继元  孙敬博  李洁  喻顺  杨静  袁霞 《地质通报》2016,35(1):152-166
额尔宾山花岗岩岩体位于南天山晚古生代侵入岩带,对该花岗岩进行锆石U-Pb定年获得296.1±1.8Ma的年龄,为早二叠世。岩石主量元素分析结果表明,该花岗岩的Si O2含量为66.96%~67.3%,富碱(Na2O+K2O=7.53%~7.97%),K2O/Na2O1(1.15~1.27),属高钾钙碱性系列岩石;Al2O3为15.56%~15.62%,Al2O3K2O+Na2O+Ca O,属于过铝型。岩石稀土元素配分模式呈现轻稀土元素(LREE)富集((La/Yb)N=27.03~30.62)、重稀土元素(HREE)亏损((LREE/HREE)=18.2~20.1)、具有中等程度的负Eu异常(δEu=0.64~0.68)。微量元素判别结果显示,其具有I-A型花岗岩过渡的特征。结合区域地质背景综合分析,初步认定该岩体可能形成于南天山同碰撞向后碰撞构造体制转换时期,据此可以推测南天山洋盆闭合时限至少应该在早二叠世以前。  相似文献   

8.
哈里努登岩体位于阿拉善地块北缘,主要由花岗闪长岩、黑云母二长花岗岩组成。锆石LA-ICP-MS U-Pb测年显示其形成时代为284.0Ma±1.8Ma,并非以往认为的志留纪。岩石SiO2含量为67%~72%,CaO为2.2%~4.4%,Na2O为3.7%~4.3%,K2O为2.1%~2.9%,具有较高的全碱含量,属钙碱性—高钾钙碱性系列,Al2O3含量为14.5%~17.2%,为准铝—弱过铝质(A/CNK=0.90~1.07),总体显示出I型花岗岩的特征。稀土元素总量较低(35.2×10-6~130.6×10-6),轻稀土元素相对富集,Eu呈正异常(δEu=1.04~1.90)。在原始地幔标准化图解中,大离子亲石元素(K、Rb、Ba、Sr)富集,亏损高场强元素(Ta、Nb、P、Yb、Y等),显示出弧花岗岩的特征。结合区域背景分析,阿拉善北缘在早二叠世时可能还存在与弧物质有关的岩浆活动。  相似文献   

9.
西藏过铝花岗岩的岩石化学特征及成因探讨   总被引:7,自引:1,他引:6  
西藏班公湖—改则—安多—怒江带一线以南分布有61个主要过铝花岗岩体,其岩石类型主要有电气石花岗岩、白云母花岗岩和二云母花岗岩,它们的主量元素组成为SiO2=65.70%~79.52%、K2O Na2O=2.20%~12.51%、K2O/Na2O=0.49~1.04及A/CNK=1.04~1.38。随着SiO2的增加,岩石中Al2O3逐渐下降,而其他的氧化物较离散。岩石系列主要为含钾较高的钙碱性系列,具典型的(强)过铝花岗岩特征。铝饱和指数图解、QAP图解投点大多数落在CCG区,表明其为大陆碰撞构造环境。Ab-Or-Q-H2O相图表明过铝花岗岩形成的压力为0.05~0.2GPa,推断温度低于700℃。根据岩石化学分析,可以得出这样的推论,西藏过铝花岗岩类发生在两个大陆地壳板块的碰撞阶段,源岩来源于上地壳的重熔,成因为S型花岗岩。其中南冈底斯带和拉轨岗日带具有许多相似的性质,这些相似的性质可能暗示二者有相同的岩浆源区或(和)相同的构造环境。  相似文献   

10.
海南岛中部五指山地区发育一套中酸性向酸性演化的火山岩系,总厚度2 299 m,岩性自下而上主要由英安质—流纹质熔岩及相应的火山碎屑岩组成,在TAS火山岩分类图上大部分落入流纹岩区,仅个别落入英安岩、玄武安山岩、粗面安山岩区。岩石具有Si O2、Al2O3、Na2O、K2O偏高,而Ca O、Mg O、Ti O2等偏低的特点。稀土配分模式均表现为呈右倾的轻稀土富集型曲线,轻、重稀土分异较强,LREE/HREE=10.17~22.34(平均13.56)。岩石富集大离子亲石元素,亏损高场强元素,具有正常弧花岗岩浆的特点,推断其形成于伸展的大地构造背景。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
18.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

19.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

20.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

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