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应用傅里叶变换红外光谱可以达到最大信噪比的特性,有效地获得了粘土矿物复合体中的单体差示红外谱图。避免了X衍射光谱中的矿物间衍射线的覆盖和色散型红外光谱中谱带重叠等不利因素,为粘土矿物复合体的鉴定提供了新的途径。研究表明,对痕量和近似的矿物组分都可以得到谱峰不受任何影响的纯正的红外谱图。差示定量结果也十分满意。 相似文献
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用量子理论改造经典的矿物学,建立量子矿物学的新体系,其主要研究手段是矿物谱学.矿物谱学使矿物学由研究矿物内部原子的排列跃迁到研究矿物内部的电子壳层结构的水平,矿物谱学包括穆斯堡尔谱、电子顺磁共振(EPR)谱,核磁共振(NMR)谱,核四极共振(NQR)谱和全部吸收光谱(X射线吸收谱、紫外—可见—近红外吸收光谱、红外光谱和拉曼光谱)以及全部发射光谱(X射线谱、光电子能谱).矿物谱学可直接用来研究晶体中化 相似文献
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蚀变矿物短波红外(SWIR)光谱特征日趋广泛地应用于矿产勘查研究中。绢云母作为热液矿床中最为发育的蚀变矿物之一,通过SWIR光谱技术提取其谱学特征,进而建立与矿床基础地质信息之间的相关性具有重要意义。然而,前人对于绢云母短波红外光谱特征的研究主要集中于单个矿床,缺少不同矿床间的对比。基于此,文章梳理了混合矿物光谱曲线中对单一矿物相对含量的提取方式,系统总结了温度、流体化学成分、流体pH值、寄主岩石、矿物结构、矿物粒度及共(伴)生矿物等因素对绢云母谱学特征空间变化规律的影响,最后,从契尔马克替换效应角度出发,分析对比了5种不同成因类型矿床中近矿端绢云母波长变化。虽然将绢云母短波红外光谱特征有效地应用于矿产勘查仍存在诸多问题,但作者相信,应用绢云母短波红外光谱特征进行矿产勘查依然具有良好的前景。 相似文献
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采用漫反射及衰减全反射红外技术,快速鉴定酞侧基聚砜膜的改性水平,得到了磺化后-SO3H基团的红外光谱差谱。 相似文献
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矿物红外光谱多组分优化计算模式 总被引:1,自引:1,他引:0
梁长林 《物探化探计算技术》1994,16(3):260-261
矿物红外光谱多组分优化计算模式梁长林(华东地质学院)一、权计算公式一个由几种单组分物质(矿物)按一定比例组合而成混合物(岩石),在没有化学反应发生情况下,它的红外光谱也是由这几个单组分物质的谱按相应的比例叠加而成,假设混合物样品的红外光谱(样品谱)为... 相似文献
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本文通过观测在不同温度下加热过的硼酸盐矿物的红外光谱,并与喇曼光谱结果进行比较,讨论了红外光谱谱带的归属。结果表明,通过观测不同温度下加热过的样品的谱带特征有助于谱带的归属。 相似文献
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景德镇地区高岭石红外光谱分析 总被引:3,自引:0,他引:3
采用红外光谱实验结合氢氟酸化学处理方法深入研究景德镇地区高岭石结构特征。通过解析红外光谱图确定该区高岭石为无序高岭石范畴,其结构中含有似地开石结构BCBCBC的八面体空位取代。通过对比氢氟酸处理前后的红外图谱,分析出该地区高岭土不含有地开石和珍珠石这两种多型。实验表明红外光谱分析对高岭土中存在的次要矿物伊利石不灵敏,而利用氢氟酸处理可以有效地鉴别,因而提出了一种利用红外光谱鉴定高岭石-伊利石混合物相的新方法。 相似文献
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《Geomechanics and Geoengineering》2013,8(2):109-115
Experience has shown that to obtain pre-failure deformability of geomaterials in laboratory element tests, it is imperative to make local strain measurements. For torsional shear tests, the local measurement is complicated by coupling of the axial, radial, and rotational movement experienced by the soil specimen during shear. The rotational displacement must be isolated from other modes of movement for the interpretation of test results. Existing techniques designed for torsional shear tests under general stress conditions can be complicated and difficult to use. A simplified scheme using two pairs of linear variable displacement transducers (LVDTs) is proposed for local rotational deformation measurement, specifically for cyclic torsional shear tests under constant normal stress conditions. The subtraction of readings within an LVDT pair nullifies displacements at the measurement point caused by axial and radial movement or bulging of the specimen. The same subtraction accumulates and thus isolates LVDT readings caused by rotational movement. The error associated with the simplified set-up is expected to be <0.125%. A series of hollow cylinder torsional shear tests have been performed to verify the effectiveness of the new measurement scheme. The results are repeatable and consistent with well-documented test data. 相似文献
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本文研究了黔中磷块岩中磷灰石的化学成分、红外光谱、碳和硫同位素组成以及伴生微量元素和稀土元素地球化学特征,获得了若干生物有机质成因的证据.磷灰石红外光谱特征表明CO32-和SO42-以类质同象部分替代PO42-而进入磷灰石晶格,而碳、硫同位素特征表明,这CO32-及SO42-的相当部分是由生物有机质分解演化而来;叠层石磷灰石的P2O5含量与亲生物微量元素关系非常密切,而非叠层石者关系不甚密切;稀土元素地球化学特征表明,磷灰石的形成具有两种既有联系又各不相同的作用机制,即直接的生物作用和间接的有机质作用. 相似文献
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采用宜昌劈裂砂岩,在有、无砂岩填充条件下,分别从轴压、围压、劈裂面面积、凹凸高差、迹线长度、劈裂面2D投影面积、进出口长度、结构面粗糙度对渗流量的影响规律进行了对比分析。研究结果表明:有、无砂粒填充下轴压与渗流量均呈线性递增关系;无填充时围压与渗流量呈对数递减关系,有充填时围压与渗流量呈线性关系;无充填时渗流量与流面积呈三次函数关系,而充填后过流面积对渗流量几乎无影响;凹凸高差、2D面积与渗流量的关系也有相似规律,分析认为,这主要是砂粒充填后带来的过流通道要远大于上述三因素对过流通道的改变;无充填时,渗流量随迹线长度线性递减,有填充时该规律被淹没;无论有、无填充,渗流量与过流面粗糙度系数在一定范围内均呈现二次函数关系。这些规律能指导渗流测量时各因素的优先次序,可有效减少对次要影响因素的测量工作,同时可对渗流的数值模拟提供参考。 相似文献
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A. N. Dmitrievskii V. I. Konov I. A. Volodin O. V. Degtyareva E. L. Terpugov S. E. Terpugova V. V. Savranskii 《Doklady Earth Sciences》2011,437(1):401-406
The regularities of reaction of the viscous bitumen (maltha) structure when affected by modulated and impulse electromagnetic
and acoustic fields via recording of infrared emission spectra are studied. It has been found that characteristic reactions
of viscous oil clusters and links between them are located in the THz range for electromagnetic waves and in the MHz range
for acoustic actions, which are revealed in absorption and emission spectra. The reaction of the rest (non-THz) part of the
infrared spectrum is described on the basis of the physical-mathematical model of the process of a photon-phonon soliton,
which causes decrease of emission IR spectrum intensity after microwave action due to fixation of the electromagnetic field
by a soliton. The obtained results, which establish selectability of the maltha specimen reaction on spectral composition
of the affected radiation, are important for increasing the efficiency of ultrasonic and electromagnetic microwave actions
on the productive stratum during application of secondary methods for oil deposit exploration. 相似文献
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Kamil M. Bulatov Pavel V. Zinin Yulia V. Mantrova Aleksey A. Bykov Maksim I. Gaponov Alexsandr S. Machikhin Ivan A. Troyan Igor B. Kutuza 《Comptes Rendus Geoscience》2019,351(2-3):286-294
In this report, we demonstrate that combining the laser heating system in a diamond anvil cell (LH-DAC) with a tandem acoustic-optical tunable filter (LH-DAC–TAOTF) allows for the simultaneous measurement of (a) the relative infrared (IR, 1070 nm) power distribution on a specimen surface in the DAC; (b) the temperature distribution under laser heating of a specimen under high-pressure in a DAC; it also (c) provides an opportunity to control the shape of the IR laser spot on the surface of the heated specimen. The effect of the π-shaper on the shape and the position of the focus of the IR laser beam on a specimen using a TAOTF is also presented. For a 10× long-working distance objective, the smallest diameter of the IR laser was found to be around 10 μm, when the focal plane coincides with that of the imaging optical system of LH-DAC. The highest diameter of the IR laser was shown to be 20 μm when the rim of the π-shaper was set at 3 μm. It is demonstrated also that the TAOFT not only permits to measure the two-dimensional (2-D) distribution of the IR laser power, but also allows for the alignment of the laser before each heating event at different pressures. 相似文献
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在野外地质工作、显微镜下观察、电子探针分析和差热分析的基础上,运用X射线衍射分析、红外光谱分析对印章石(以著名的昌化石为例)进行了谱学分析。昌化石主要矿物成分为高岭石族矿物,主要为迪开石及高岭石-迪开石过渡矿物。通过X射线衍射图谱分析计算其结晶度指数(HI)表明,高岭石族矿物的结晶有序度存在明显的高低变化。红外光谱特征显示,其中属于外部羟基振动的3 697cm-1谱峰强度(A)与属于内部羟基振动的3 620cm-1谱峰强度(B)的比值随着结晶度指数的降低有逐渐升高的趋势,且比值A/B的大小可以大致用来区分高岭石和迪开石:一般高岭石比值大于1,而迪开石小于1。差热分析的结果也印证了高岭石族矿物有序度高低变化的现象,如:高岭石族矿物在加热到400℃~700℃时会出现一个强烈尖锐的吸热峰,吸热峰的强度及温度与其有序度的高低存在正相关性。当主要组成矿物成分为较纯净的迪开石时,其有序度相对较高,透明度也较好;当主要矿物成分为高岭石-迪开石过渡矿物时,其有序度较低,透明度也较差。X射线衍射分析和红外光谱都是研究分析印章石的有效方法,但X射线分析通常为有损分析,且仪器使用条件相对较高;而红外光谱则可以无损且具有扫描时间短等... 相似文献