Hydrogeochemical study of the thermal and mineralized waters of the Banaz (Hamamboğazi) area,western Anatolia,Turkey

The Hamamboğazi spa in western Turkey was built around natural hot springs with discharge temperatures in the range of 30–54°C; the waters have near neutral pH values of 6.50–7.10 and a TDS content between 2,694 and 2,982 mg/l. Thermal water with a temperature of 47.5–73°C has been produced at 325 l/s from five wells since 1994, causing some springs to go dry. A management plan is required in the study area to maximize the benefits of this resource, for which currently proposed direct uses include heating in the district and greenhouses, as well as balneology in new spas in the area. The best use for the water from each spring or well will depend on its temperature, chemistry and location. The thermal waters are mixed Na–Mg–HCO₃–SO₄ fluids that contain a significant amount of CO₂ gas. The chemical geothermometers applied to the Hamamboğazi thermal waters yield a maximum reservoir temperature of 130°C. Isotope results (¹⁸O, ²H, ³H) indicate that the thermal waters have a meteoric origin: rainwater percolates downward along fractures and faults, is heated at depth, and then rises to the surface along fractures and faults that act as a hydrothermal conduit. The basement around the Banaz Hamamboğazi resort is comprised of Paleozoic metamorphic schist and marbles exposed 8 km south and 15 km north of Banaz. Mesozoic marble, limestone and ophiolitic complex are observed a few km west and in the northern part of Banaz. These units were cut at a depth of 350–480 m in boreholes drilled in the area. Overlying lacustrine deposits are composed of fine clastic units that alternate with gypsum, tuff and tuffites of 200–350 m thickness. The marble and limestones form the thermal water aquifer, while lacustrine deposits form the impermeable cap.     

Hydrochemical and isotopic properties of the Mahmutlu and Bağdatoğlu mineralized thermal springs, Kırşehir, Turkey

The present study identifies the hydrochemical and isotopic properties of the Mahmutlu and Ba?dato?lu mineralized thermal springs in K?r?ehir province, a geothermal field in central Anatolia, Turkey. Based on these properties, a hydrogeological regime is proposed in order to explain the Mahmutlu–Ba?dato?lu geothermal system. The relation between the concentrations of the environmental stable isotopes deuterium and oxygen-18 in the water is similar to the relationship in global meteoric water, indicating that the water is of meteoric origin. Evaluation of the geochemical characteristics of the water reveals that these two thermal springs belong to the same hydrogeological system. The hydrogeological system comprises a fractured limestone member of the Çevirme Formation and the Kervansaray Formation as reservoir rocks, and the Delice?rmak Formation as an overlying aquitard. The waters of the Mahmutlu and Ba?dato?lu springs are mainly of the Na-Cl-SO4 type that originate from the Pohrenk evaporite. The thermal waters are undersaturated with respect to calcite, dolomite, halite, and gypsum. The δ 18O and δ 2H contents indicate a δ 18O shift in the Mahmutlu and Ba?dato?lu waters. The temperature range of the two reservoirs is estimated to be 98–158?°C, on the basis of Na+K+Ca and SiO2 geothermometers.     

Hydrogeochemical study of the Terme and Karakurt thermal and mineralized waters from Kirşehir Area,central Turkey

The Terme and Karakurt thermal resorts are located in the center of Kirşehir city in central Anatolia. Thermal waters with temperatures of 44–60°C are used for central heating and balneologic purposes. Paleozoic rocks of the Kirşehir Massif are the oldest units in the study area. The basement of the Massif comprises Paleozoic metamorphic schist and marbles which partly contain white quartzite layers of a few tens of cm thickness. The metamorphic schists which are cut by granites of Paleocene age are overlain by horizontally bedded conglomerate, sandstone, claystone, and limestone of upper Paleocene-Eocene age. Among the thermal and cold waters collected from the areas of Terme and Karakurt, those from thermal waters are enriched with Ca–HCO₃ and cold waters are of Ca–Mg–HCO₃ type waters. The pH values of samples are 6.31–7.04 for the thermal well waters, 6.41 for thermal spring, 7.25 and 7.29 for the cold waters, and 7.52 for the Hirla lake water. EC values are 917–2,295 μS/cm for the thermal well waters, 2,078 μS/cm for thermal spring, and 471 and 820 μS/cm for the cold springs. The lowest TDS content is from water of T10 thermal well in the Terme area (740.6 mg/l). The hot and cold waters of Terme show very similar ion contents while the Karakurt hot waters at western most parts are characterized by distinct chemical compositions. There is ion exchange in thermal waters from the T5 (5), T6 (6), T12 (7), and T1 (8) wells in the Terme area. The thermal waters show low concentrations of Fe, Mn, Ni, Al, As, Pb, Zn and Cu. Waters in the study area are of meteoric origin, and rainwater percolated downwards through faults and fractures, and are heated by the geothermal gradient, later rising to the surface along permeable zones. δ¹³C_VPDB values measured on dissolved inorganic carbon in samples range from −1.65 to +5.61‰ for thermal waters and from −11.81 to −10.15‰ for cold waters. Carbon in thermal waters is derived from marine carbonates or CO₂ of metamorphic origin while carbon in cold waters originates from freshwater carbonates.     

Geology and isotope geochemistry (C–O–S) of the Diyadin gold deposit,Eastern Turkey: A newly-discovered Carlin-like deposit

Diyadin mineralization is the first reported gold deposit located in a collisional tectonic environment in Eastern Anatolia. The mineralization is related to N–S and N10–20°W-trending fault systems and hosted within the Paleozoic metamorphic basement rocks of the Anatolide–Toride microcontinent. Calc-schist, dolomitic marble and Miocene and Quaternary volcanic rocks comprise the exposed units in the mineralized area. Geochemical signatures, alteration types and host rock characteristics of the Diyadin gold deposit resemble those of Carlin-type deposits. Mineralization is constrained by alteration of overlying volcanic rocks to younger than ~ 14 Ma (K–Ar).Carbon and oxygen stable isotope measurements of carbonate rocks were made on six drill holes (n = 81) with an additional four samples of fresh carbonate rocks from surface outcrops. Background carbonate rocks have δ¹³C_V-PDB ~ 1.8‰ and δ¹⁸O_V-SMOW ~ 27‰. Isotopically-altered host rock samples have decreased δ¹⁸O (down to ~+11.4‰) and variable δ¹³C (from − 3.6 to + 4.8‰). Postore carbonate veins and cave-fill material have distinctly different isotopic signatures, particularly carbon (from δ¹³C = + 8.4 to + 9.8‰). Whether this post-ore carbonate is simply very late in mineralization associated with the gold system, or is a completely different, younger system utilizing the same pathways, is unclear at present. Within the host rock sample set, there is no correlation between gold and δ¹³C, and a weak correlation between gold and δ¹⁸O, indicative of water–rock interaction and isotopic alteration. Both the isotopic data and structural mapping suggest that the main upflow zone for the deposit is near the northern portion of the drill fence. Additional data at multiple scales are required to clarify the relationship(s) between fluid flow and mineralization.     

The effects of elevation on thermal bioclimatic conditions in Uludağ (Turkey)

This study compares the thermal bioclimatic conditions recorded at Bursa (100 m) and Uluda? (1878 m) meteorological stations at 7:00, 14:00 and 21:00 LST (local standard time) between 1975 and 2006, by using the physiologically equivalent temperature (PET), which is calculated from meteorological parameters. The effects of elevation-dependent environmental and atmospheric conditions on thermal perception (i.e., PET) values were analyzed and assessed. The analysis showed that the mean annual difference between PET values in Bursa and Uluda? was 12 ºC. The difference was lower in winter (9 ºC PET) and higher in summer (15 ºC PET). The highest difference between PET values occurred in the afternoon (16 ºC PET) and the lowest difference occurred in the morning (8.4 ºC PET). The differences occur as a result of high altitude and higher surface albedo due to snowfall, which leads to lower PET values and thus to less comfortable thermal conditions. The mean PET values of Bursa and Uluda? decrease 0.67 ºC every 100 m.     

Geothermometry applications for the Balıkesir thermal waters,Turkey

In this study, reservoir temperatures of Balıkesir geothermal waters in northwestern Turkey are estimated with various geochemical models. The geothermal fluids in the region are represented by Na–SO₄, Na–HCO₃ and Ca–HCO₃ type waters with discharge temperatures up to 98°C. It was determined that the solubility of silica in most of the waters is controlled by the chalcedony phase. Equilibrium states of the Balıkesir thermal waters studied by means of Na–K–Mg–Ca diagram, mineral saturation calculations and activity diagrams in the system composed of Na₂O–CaO–K₂O–Al₂O₃–SiO₂–H₂O phases approximate a reservoir temperature of about 120°C. Most of the waters are found to be equilibrated with calcite, chalcedony ± quartz and muscovite at predicted temperature ranges, similar to those calculated from the chemical geothermometers.     

Evaluation of rock falls in an urban area: the case of Boğaziçi (Erzincan/Turkey)

Disasters caused by events such as earthquake, flooding, rock falls, landslides are often encountered. However, generally, the reasons for the destructive and devastating effects of these nature events are that settlement locations were chosen without site investigation studies, or that available studies were inadequate. Such inadequacies in the field are related to inappropriate settlement location and the resulting damage caused by rock falls. This study evaluated rockfall risk in a settlement that developed in a similar manner. The study was carried out in Bo?aziçi village of Kemah (Erzincan/Turkey), which is located in a very important tectonic zone. The study site is located on the lower sections of an area with very steep cliffs and 50–75° slopes. This cliff, which is the source of rockfalls, has a slope dip of approximately 90°. The cliff comprises 25–30 m high, fractured and cracked basaltic volcanic mass. To determine block size in the study area, scanline survey measurements and block size measurements were performed on blocks that loosened and fell from the cliff face. It was found that block sizes reached 6 m³. Rockfall analyses were performed along the selected profiles using the Rockfall V.4.0 software. Kinetic energy, bounce height, horizontal location of rock end-points, and velocity of the rocks along each section were evaluated separately for each profile. This data were used to produce distribution maps for each profile and the settlement was evaluated in terms of rockfall risk. The results indicate that the study area was at risk of future rockfalls and that it would be appropriate to relocate one part of the settlement.     

Hydrogeochemistry and pollution assessment of quaternary–tertiary aquifer in the Liwa area,United Arab Emirates

This study presents the data on the hydrochemical characteristics and isotope chemistry of Liwa aquifer, which could be useful to clarify the hydrochemical facies and hydrogeological regime in the study area. Electric conductivity and total dissolved solid values show that the investigated water is slightly brackish, due to the effect of evaporation and the occurrences of evaporite rocks in the adjacent Sabkhas of Abu Dhabi. Major cations and anions arranged according to their decreasing concentrations are: Na⁺ > Ca⁺² > K⁺ > Mg⁺² and Cl⁻ > HCO₃ ⁻ > SO₄⁻², respectively. As sodium is the dominate cation and chloride is the prevailing anion, hydrochemically the groundwater of Liwa can be classified as Na–Cl rich, predominantly chloridic. Ion concentrations increase towards the northeast and presumably coincide with the lithological sources of ions. Factors affecting the hydrochemistry of the groundwater of the investigated area include the effect of weathering of soil and rocks, evaporation and agricultural activities. Stable isotopes of oxygen and hydrogen show that the shallow aquifers contain a single water type that originated in a distinct climatic regime. This water type deviates from the local meteoric water line, as well as from the Eastern Mediterranean Meteoric Water Line, suggesting potential evaporation of recharged water prior to infiltration. The waters are poor in tritium, and thus can be considered generally as indication for recharge prior to 1952. The degradation of groundwater quality can be attributed to evaporation and agricultural practices in most cases.     

Genetic investigation and comparison of Kartaldağ and Madendağ epithermal gold deposits in Çanakkale,NW Turkey

Two epithermal gold deposits (Kartaldağ and Madendağ) located in NW Turkey have been characterized through the detailed examinations involving geologic, mineralogical, fluid inclusion, stable isotope, whole-rock geochemistry, and geochronology data.The Kartaldağ deposit (0.01–17.65 ppm Au), hosted by Eocene dacite porphyry, is associated with four main alteration types with characteristic assemblage of: i) chlorite/smectite–illite ± kaolinite, ii) quartz–kaolinite, iii) quartz–alunite–pyrophyllite, iv) quartz–pyrite, the last being characterized by three distinct quartz generations comprising massive/vuggy (early), fine–medium grained, vug-lining (early), and banded, colloform, comb (late) textures. Observed sulfide minerals are pyrite, covellite, and sphalerite. Oxygen and sulfur isotope analyses, performed on quartz (δ¹⁸O_(quartz): 7.93 to 8.95‰ and calculated δ¹⁸O_(H2O): − 7.95 to 1.49‰) and pyrite (δ³⁴S_(pyrite): − 4.8‰ and calculated δ³⁴S_(H2S): − 6.08 to − 7.20‰) separates, suggest a meteoric water source for water in the hydrothermal fluid, and an igneous source for the sulfur dissolved in ore-related fluids. Microthermometric analyses of primary fluid inclusion assemblages performed on quartz (late quartz generation) yield temperatures (Th) dominantly in the range of 245–285 °C, and generally low salinity values at 0 to 1.7 wt.% NaCl eq. Based on the quartz textures and the associated base metal concentrations, along with fluid inclusion petrography, the early vug-lining quartz is considered to have been associated with the mineralization possibly through a boiling and a late mixing process at > 285 °C.The Madendağ deposit (0.27–20.60 ppm Au), hosted by Paleozoic mica schists, is associated with two main alteration types: sericite–illite–kaolinite, and quartz–pyrite dominated by two distinct quartz generations i) early colloform, comb and banded quartz and ii) late quartz, forming the cement in hydrothermal breccia. Whereas oxygen isotope analyses of quartz (δ¹⁸O_(quartz): 9.55 to 18.19‰ and calculated δ¹⁸O_(H2O): − 2.97 to 5.54‰) suggest varying proportions of meteoric and magmatic sources for the ore bearing fluid, sulfur isotope ratios (δ³⁴S_(pyrite): − 2.2‰ and calculated δ³⁴S_(H2S): (− 3.63) to (− 3.75) ‰) point to an essentially magmatic source for sulfur with or without contribution from sedimentary sources. Microthermometric analysis carried out on primary fluid inclusion populations of a brecciated sample (early quartz), give a temperature (Th) range of 235–255 °C and 0.0 to 0.7 wt.% NaCl eq. salinity. Based on the textural relationship, base metal and high gold contents, the ore precipitation stage is associated with late stage quartz formation via a possible boiling process.The presence of alunite, pyrophyllite and kaolinite, vuggy quartz and covellite suggest a high-sulfidation type of epithermal deposit for Kartaldağ. On the other hand, Madendağ is identified as an adularia-sericite type owing to the presence of significant sericite, neutral pH clays (mostly illite, chlorite/smectite, and kaolinite), low temperature quartz textures (e.g., colloform, comb, and banded quartz), and limited sulfide minerals.Given the geographical proximity of Kartaldağ and Madendağ deposits, the similar temperature and salinity ranges obtained from their fluid inclusions, and the similar ages of igneous rocks in both deposits (Kartaldağ: 40.80 ± 0.36 to 42.19 ± 0.45 Ma, Madendağ: 43.34 ± 0.85 Ma) the mineralizing systems in both deposits are considered to be genetically related.     

Geochemistry, mineralogy and genesis of pyrophyllite deposits in the Pötürge Region (Malatya, Eastern Turkey)

In the Pötürge (Malatya, Turkey) area pyrophyllite occurrences are common in the shear zones, mostly in the form of lenses along faults. Mineralogical investigations (XRD, FTIR and SEM) revealed that pyrophyllite, kaolinite (dickite) and quartz are present in the form of major phases and muscovite (sericite), kyanite, chlorite, and alunite are only present in the form of minor phases. This study revealed that the existence of the kyanite phase points out to high pressure and temperature conditions which the rocks were underwent. On the other hand, the minerals such as pyrophyllite, kaolinite, and alunite are products of a low degree metamorphism (retrograde). The mineral paragenesis in the pyrophyllite deposits suggests that the formation of minerals took place in two ways: (1) the transformation of kyanite into pyrophyllite and quartz through retrograde metamorphism by a high degree temperature, (2) then pyrophyllite and probably muscovite were transformed into kaolinite and alunite through reactions with relatively low temperature hydrothermal fluids. The geochemical data indicate that during the retrograde metamorphism the elements K, Rb, Sr, Ba, S, and Fe were mobile, the elements Si, Al, P moderately mobile to immobile and the HPS elements (Zr, Ti, and Nb) were immobile. It was shown that the formation of pyrophyllite, kaolinite and alunite was associated with depletion in alkalis, Mg, Fe and enrichment of elements including Sr, Ba, and S. Mineralogical and geochemical data suggest that parent rocks (pre-metamorphism) of the Pötürge pyrophyllite were probably kaolinite, Al-rich clays or bauxites.     

Hydrogeochemistry and Water Quality Evaluation along the Flow Path in the Unconfined Aquifer of the Düzce Plain,North-western Turkey

The Düzce Plain has a multi-aquifer system, which consists of a near surface unconfined aquifer, along with first and second deeper confined aquifers. Hydrochemical evolution and water quality are related to infiltration of the precipitation, recharge from the formations surrounding the plain, flow path of groundwater and the relationship between surface and groundwater. The groundwater in the unconfined aquifer flows towards the Efteni Lake and the Büyük Melen River. Surface waters are divided into two main hydrochemical facies in the study area: (a) Ca2+–HCO3?; and (b) Ca2+, Mg2+–HCO3-, SO42-. The groundwater has generally three main hydrochemical facies: (a) Ca2+–HCO3-; (b) Ca2+, Mg2+–HCO3-; and (c) Ca2+, Mg2+–HCO3-, Cl-. The hydrochemical facies a and b dominate within shallow depths in recharge areas under rapid flow conditions, while hydrochemical facies c characterizes shallow and mixed groundwater, which dominate intermediate or discharge areas (near Efteni Lake and Büyük Melen River) during low flow conditions and agricultural contamination. Calcium and bicarbonate ions, total hardness and electrical conductivity of total dissolved solids (EC–TDS) values increase along the groundwater flow path; but these parameters remain within the limits specified by the standards set for industrial and agricultural usages.     

Geochronology,geochemistry, and petrology of adakitic Pliocene–Quaternary volcanism in the Şebinkarahisar (Giresun) area,NE Turkey

ABSTRACT

The Pliocene–Quaternary volcanics in NE Turkey are mainly hornblende–phyric trachyandesites having a narrow range of SiO₂ from 61.88 to 63.00 wt.% and exhibiting adakitic signatures with their Na₂O (3.67–4.27 wt.%), Al₂O₃ (16.19–16.80 wt.%), Y (14.1–16.5 ppm) contents and K₂O/Na₂O (0.87–1.12), Sr/Y (44.24–54.90), and La/Yb (36.80–43.88) ratios. Plagioclases as the main mineral phases show a wide range of compositions, and weak normal and reverse zoning. Hornblendes are generally edenite and pargasite (Mg#: 0.39–0.74). Clinopyroxenes are augite (Mg#: 0.58–0.76). Biotites have Mg# ranging from 0.45 to 0.66. The textural and compositional variations indicate disequilibrium crystallization possibly arising from magma mixing. The U–Pb zircon dating of the adakitic volcanics yielded 3.4–1.9 Ma. The studied rocks display moderate light rare earth element /heavy rare earth element ratios and enrichment in the lithophile element and depletion in high field strength element, implying that the parental magmas were derived from mantle sources previously enriched by slab-derived fluids and/or subducted sediments. The crystallization temperature and pressure estimations based on the clinopyroxene thermobarometry range from 1144 to 1186°C and from 3.92 to 7.97 kbar, respectively. Hornblende thermobarometry, oxygen fugacity, and hygrometer calculations yielded results as 908–993°C at a pressure of 2.87–5.22 kbar, water content of 4.4–8.4 wt.%, and relative oxygen fugacity (ΔNNO log units) of ?0.6 to 0.9, respectively. Biotite thermobarometry suggests relatively higher oxygen fugacity conditions (10^–13.33 to 10^–17.60) at temperatures of 676–819°C and at pressures from 1.15 to 1.76 kbar. In the light of the obtained data and modelling, it can be concluded that the magmas of the adakitic volcanics were derived from enriched mantle source through relatively higher partial melting and experienced magma mixing with melts at the crustal level. Additionally, the fractional crystallization and assimilation-fractional crystallization processes may have played an important role during the evolution of the studied volcanics.     

Mineral and thermal waters of the Ipelská Pahorkatina hillyland

 Mineral and thermal waters occur at Kalinciakovo, Santovka, Dudince, Slatina and Turovce, in the inner side of the Western Carpathian arc, the south-western margin of the Central Slovak Neovolcanics, and on the so-called Levice spring line. They are important sources of mineral waters for Slovakia, which are used for different purposes (bathing therapy, bottling, recreation). The mineral and thermal waters of Dudince have an extraordinary position among them. The mineral water with its physico-chemical composition and content of gasses enables its wide use for bathing therapy and it occupies a special position among the mineral waters of the Carpathian arc. Received: 9 November 1998 · Accepted: 2 March 1999     

Spatial distribution of some elements and elemental contamination in the sediments of Köyceğiz Lake (SW Turkey)

Elemental accumulation, distribution and relationship profiles for sediment samples taken at 81 localities in the Köyce?iz Lake were investigated. Spatial distribution maps for ten elements (Cu, Pb, Zn, Ni, Cr, Co, Mn, Mo, Al, Fe) were created using the ordinary kriging interpolation method. Statistical tests revealed that the sediments taken from areas close to the Namnam (NamSM) and Karg?cak (KarSM) stream mouths have the highest element content. In addition, sediments close to NamSM have the highest contamination, according to contamination degree and modified contamination degree values. On the other hand, sediments close to KarSM have the highest value on the pollution load index. The enrichment factor and contamination factor values of Cr and Co, and especially Ni, close to NamSM are striking and have significantly higher values compared to the rest of the lake. There are strong correlations between these three elements, which were also confirmed by cluster analysis. Ni is the element having the highest value on the geoaccumulation index. In addition, according to the toxic unit results, it was found that 84–89% of the element-based toxic effect in the lake is due to Ni alone. According to the mean effect range median quotient values, the sediments of Köyce?iz Lake have a potential to show toxic effects of at least 76% in living organisms, which is due to the high levels of Ni. According to the mean probable effect low quotient value, it has been determined that Köyce?iz Lake is at a “highly impacted” level, which is the worst possible value on the quality scale.     

Composition and origin of the Çaldağ oxide nickel laterite,W. Turkey

The Çalda? nickel laterite deposit located in the Aegean region of W. Turkey contains a reserve of 33 million tons of Ni ore with an average grade of 1.14% Ni. The deposit is developed on an ophiolitic serpentinite body which was obducted onto Triassic dolomites in the Late Cretaceous. The deposit weathering profile is both laterally and vertically variable. A limonite zone, which is the main ore horizon, is located at the base of the profile. A hematite horizon is located above the limonite, which in the south of the deposit is capped by Eocene freshwater limestones and in the north by a siliceous horizon. The deposit is unusual in lacking a significant saprolite zone with little development of Ni-silicates. The boundary between the limonite zone and serpentinite below is sharp with a marked decrease in concentrations of MgO from 13 to 1 wt.% over a distance of 2 mm representing the ‘Mg discontinuity’. Ni concentrations within goethite, the main ore mineral, reach a maximum of ~3 wt.% near the base of the limonite zone. Silica concentrations are high throughout most of the laterite with up to 80 wt.% silica in the upper portion of some profiles. The combination of a serpentinite protolith and a high water table at Çalda?, in association with an aggressive weathering environment in a tropical climate, resulted in the formation of an oxide-dominated deposit. The precipitation of silica may coincide with a change in climate with silica precipitation linked to an increase in seasonality. Additional variations within profile morphology are attributed to transportation during and after laterite development as a result of faulting, pocket type laterite formation and slumping, each of which produces a contrasting set of textural and geochemical features.     

Geochemical/isotopic evolution of Pb–Zn deposits in the Central and Eastern Taurides,Turkey

The Central and Eastern Taurides contain numerous carbonate-hosted Pb–Zn deposits, mainly in Devonian and Permian dolomitized reefal–stramatolitic limestones, and in massive Jurassic limestones. We present and compare new fluid inclusion and isotopic data from these ore deposits, and propose for the first time a Mississippi Valley-type (MVT) mode of origin for them.

Fluid inclusion studies reveal that the ore fluids were highly saline (13–26% NaCl equiv.), chloride-rich (CaCl₂) brines, and have average homogenization temperatures of 112°C, 174.5°C, and 211°C for the Celal Da?, Delikkaya, and Ayrakl? deposits, respectively. Furthermore, the δ³⁴S values of carbonate-hosted Pb–Zn deposits in the Central and Eastern Taurides vary between –5.4‰ and?+13.70‰. This indicates a possible source of sulphur from both organic compounds and crustal materials. In contrast, stable sulphur isotope data (average δ³⁴S –0.15‰) for the Çad?rkaya deposit, which is related to a late Eocene–Oligocene (?) granodioritic intrusion, indicates a magmatic source. The lead isotope ratios of galena for all investigated deposits are heterogeneous. In particular, with the exception of the Suçat? district, all deposits in the Eastern (Delikkaya, Ayrakl?, Denizovas?, Çad?rkaya) and Central (Katranba??, Küçüksu) Taurides have high radiogenic lead isotope values (²⁰⁶Pb/²⁰⁴Pb between 19.058 and 18.622; ²⁰⁷Pb/²⁰⁴Pb between 16.058 and 15.568; and ²⁰⁸Pb/²⁰⁴Pb between 39.869 and 38.748), typical of the upper continental crust and orogenic belts.

Fluid inclusion, stable sulphur, and radiogenic lead isotope studies indicate that carbonate-hosted metal deposits in the Eastern (except for the Çad?rkaya deposit) and the Central Taurides are similar to MVT Pb–Zn deposits described elsewhere. The primary MVT deposits are associated with the Late Cretaceous–Palaeocene closure of the Tethyan Ocean, and formed during the transition from an extensional to a compressional regime. Palaeogene nappes that typically limit the exposure of ore bodies indicate a pre-Palaeocene age of ore formation. Host rock lithology, ore mineralogy, fluid inclusion, and sulphur?+?lead isotope data indicate that the metals were most probably leached from a crustal source such as clastic rocks or a crystalline massif, and transported by chloride-rich hydrothermal solutions to the site of deposition. Localization of the ore deposits on autochthonous basement highs indicates long-term basinal fluid migration, characteristic of MVT depositional processes. The primary MVT ores were oxidized in the Miocene, resulting in deposition of Zn-carbonate and Pb-sulphate–carbonate during karstification. The ores underwent multiple cycles of oxidation and, in places, were re-deposited to form clastic deposits. Modified deposits resemble the ‘wall-rock replacement’ and the ‘residual and karst fill’ of non-sulphide zinc deposits and are predominantly composed of smithsonite.     

Application of the content–area (C–A) fractal model and prediction–area (P–A) plot for mineral prospectivity modeling in the Luchun area of Yunnan Province,China

This method of assigning weights based on expert opinion introduces bias when we are evaluating the relative importance of evidence values. In this paper, we used a prediction–area (P–A) plot method and content–area (C–A) fractal model to estimate the weight of each evidence map. In this paper, we used the content region (C–A) fractal model to divide the evidence maps to the threshold of the corresponding dimensions. The P–A plot approach is an objective data-driven approach for evaluating map weights. Using geochemical layer and remote sensing, hydroxyl layers as weight evidence maps are the highlights of this study. We use the P–A method from which we can evaluate the predictive ability of each evidence map with respect to the known ore occurrences. We used the P–A plot for weighting each evidence map and choosing the appropriate threshold for predictor maps in the Luchun area of Yunnan Province, China. The method adopted in this paper can improve the prediction efficiency of ore prospecting.     

Delineation of the porphyry-skarn mineralized zones (NW Turkey) using concentration–volume fractal model

This study is carried out for delineation of the Tepeoba porphyry-skarn Cu-Mo ± Au mineralized zones at the Biga peninsula (NW Turkey) using the concentration–volume (C–V) fractal model. The power-law C–V relationships of Cu, Mo, and Au reveal five mineralized zones of Cu, three zones of Mo, and five zones for gold in the Tepeoba deposit. The main phase of the mineralization has average ore grades of 0.257% Cu, 0.357% Mo and 5.3083 ppm Au. Cu–Mo sulfide-rich hypogene ore zone overlain by mineralized oxidation zone are encompassed by three main alteration types, which are represented by biotite ± muscovite-K-feldspar, actinolite-albite and outer chlorite-epidote-calcite mineral associations occurring within the porphyritic microgranite and hornfels in the mine area. The delineated mineralization trend, based on the C–V fractal model, suggested that Cu and Mo enrichment zones were controlled by the same geochemical processes in the deposit due to their similar trends with the C–V log-log plot. Cu and Mo occurred mainly within the breccia zones along with stockwork veining at the contact between the hornfels and the biotite (±muscovite)-K-feldspar-altered Eybek microgranite. The main mineralization zone of Au developed in the oxidation zone due to of supergene enrichment processes.     

Evaluating the anthropogenic and geologic impacts on water quality of the Eğirdir Lake, Turkey

E?irdir Lake is the second largest fresh water lake with 482 km² surface area of Turkey. The lake is an indispensable water source for our country and region because of available water capacity and usage aims such as drinking-irrigation water, tourism, and fishing. However, especially contaminants located in the E?irdir Lake catchment affect the lake water quality negatively in times. Therefore, determination of the water quality of the lake has quite importance for region human health and sustainable usage of the lake. The major factors that control the quality of the E?irdir Lake water are agricultural activities in the basin, water–rock interaction, and domestic and industrial wastes. This study investigates the anthropogenic and geologic impact originated from pollution sources and water–rock interaction in the lake watershed basin to the E?irdir Lake water quality. For this purpose, geological, hydrogeological, and hydrological properties of the lake basin with point and nonpoint pollution sources were investigated. To determine the water quality of the lake, 48 water samples were collected especially from locations representing effects of pollutants in May and October 2009. The analysis results were compared with maximum permissible limit values recommended by World Health Organization and Turkish drinking water standards. The contents of all chemical and physical parameters are higher in dry periods than wet period, and water pollution was observed at discharge points of the streams into the lake. Also, pH, turbidity, potassium, chemical oxygen demand, ammonium, aluminum, iron, and lead concentrations were found to be above drinking water standards.